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Increasing energy demands combined with local scarcities and rising prices make the valorisation of energy from domestic wastewater seen as a valuable resource. Chemically enhanced primary treatment (CEPT) enables an increased redirection of organic compounds into sludge in the primary stage of a wastewater treatment for a transformation into biogas (carbon capture). Traditionally used coagulants consist of metallic salts, but in the last two decades, the development of polymers, based on petroleum or synthesized from renewable sources such as plants, has been intensified. However, a direct comparison of the effectiveness of these products is missing. In this paper, we analysed data of peer-reviewed research from jar tests to full-scale studies, highlighting key parameters for successful carbon capture. More than 100 studies were identified, with a majority presenting results from tests under static conditions (jar tests), while data on full-scale applications are scarce. Overall, for TSS and COD, a clear correlation between inflow concentration and removal efficiency was found, irrespective of the product used. Comparison between the effectiveness of the different types of products is difficult, but bio-based coagulants need to be generally added in higher product concentrations for a considerable removal efficiency. While CEPT seems to increase the general sludge and biogas output, future studies should focus on harmonising laboratory analysis to make results comparable. Another important issue that should be addressed is the provision of experimental details, especially for full-scale trials, to enable for reliable conclusions., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Florent Chazarenc reports financial support was provided by Rhone Mediterranee Corsica Region Water Agency. Katharina Tondera reports a relationship with EUR H2O'Lyon that includes: funding grants., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

In the context of climate change and global trend towards greenfield urbanisation, stormwater and transported pollutants are expected to increase, impairing receiving environments. Constructed floating wetlands (CFWs) can improve stormwater retention pond performance. However, performance data are currently largely restricted to mesocosm experiments, limiting design enhancement fit for field implementation. The present 12-month field study aims to fill part of these gaps by identifying limitations and necessary design improvements for CFWs on a large retention pond/lake. Water in a 2.6-ha lake receiving stormwater from a 45-ha urban area under development in subtropical Queensland, Australia, was recirculated during dry weather periods to minimise algal growth and the risks of blooms. Pollutant removal efficiencies of two full-scale CFWs were evaluated during storm events and dry weather periods as a function of inlet and outlet pollutant concentrations, flow and rainfall. Inlet TSS and TN concentrations in runoff during the construction phase of the development exceeded required water quality limits while TP inflow concentrations were low and often below the detection limit. Median pollutant load reduction efficiencies during storm-events were - 20 % TSS, -2 % TN and 22 % TP at CFW1 and 51 % TSS, 3 % TN and 17 % TP at CFW2, respectively. TSS and TN concentration removal efficiencies at CFW1 were low and highly variable, partly due to low inlet concentrations, high flow velocities and short hydraulic retention times (<1 day). However, CFW1 significantly reduced TSS concentrations during dry weather periods. In contrast, CFW2 significantly reduced TSS concentrations during both storm events and during inter-event periods. This study highlights treatment limitations associated to the operational conditions of CFWs at field-scale not identifiable in a mesocosm-scale study. Further research is necessary to investigate treatment performance of CFWs during the operational phase of the development with higher nutrient levels., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 Elsevier B.V. All rights reserved.)

Root fungal endophytes have been shown to play a positive role in soil phytoremediation by immobilizing or degrading contaminants. In comparison, little is known about their ecological functions and possible role in improving plant performance in treatment wetlands. In a greenhouse study, we compared the structure of fungal communities associated with Phragmites australis roots in treatment wetland mesocosms fed with pre-treated wastewater to mesocosms fed with drinking water. We evaluated the role of water source as an environmental filter structuring fungal communities, and correlated the relative abundances of fungal taxa with key services delivered by the wetlands (i.e., biomass production and nutrient removal). Mesocosms fed with wastewater had higher fungal alpha-diversity. Contrary to expectations, many fungi were unique to drinking water-fed mesocosms, suggesting that the oligotrophic conditions prevailing in these mesocosms benefited specific fungal taxa. On the other hand, wastewater-fed mesocosms had a slightly higher proportion of sequence reads belonging to fungal species recognized as potential endophytes and phytopathogens, highlighting the potential role of wastewater as a source of plant-associated fungi. Interestingly, we found contrasted association patterns between fungal species' relative abundances and different treatment wetland services (e.g., N vs P removal), such that some fungi were positively associated with N removal but negatively associated with P removal. This suggests that fungal endophytes may be functionally complementary in their contribution to distinct mesocosm services, thus supporting arguments in favor of microbial diversity in phytotechnologies. Because of the wide alpha-diversity of fungal communities, and the fact that with current databases, most species remained unassigned to a specific function (or even guild), further investigation is needed to link fungal community structure and service delivery in treatment wetlands., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022 Elsevier B.V. All rights reserved.)

In response to the growing global resource scarcity, wastewater is increasingly seen as a valuable resource to recover and valorise for the benefit of the society rather than another waste that needs treatment before disposal. Conventional wastewater treatment plants (WWTPs) oxidise most of the organic matter present in wastewater, instead of recovering it as a feedstock for biomaterials or to produce energy in the form of biogas. In contrast, an A-Stage is capable of producing a concentrated stream of organic matter ready for valorisation, ideally suited to retrofit existing large plants. This technology is based on the principle of high-rate activated sludge process that favours biosorption and storage over oxidation. In this paper, we summarize peer-reviewed research of both pilot-scale and full-scale studies of A-Stage process under real conditions, highlighting key operational parameters. In the majority of published studies, the sludge retention time (SRT) was identified as a key operational parameter. An optimal SRT of 0.3 days seems to maximize the redirection of influent COD - up to 50% to the sludge flux, while simultaneously keeping mineralization under 25% of total influent COD. Other key optimal parameters are a hydraulic residence time of 30 min and dissolved oxygen levels of 0.5 mg⋅L - 1 . In addition, nutrient removal efficiencies of 15-27% for total nitrogen and 13-38% for total phosphorus are observed. Influence of mixing on settling efficiencies remain largely underexplored, as well as impact of wet weather flow and temperature on overall recovery efficiencies, which hinders to provide recommendations on these aspects. Evolution of modelling efforts of A-Stage process are also critically reviewed. The role of extracellular polymeric substances remain unclear and measures differ greatly according to the different studies and protocols. Better understanding the settling processes by adding Limit of Stokesian and Threshold of Flocculation measures to Sludge Volume Index could help to reach a better understanding of the A-Stage process. Reliable modelling can help new unit processes find their place in the whole treatment chain and help the transition from WWTPs towards Wastewater Resource Recovery Facilities., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2022. Published by Elsevier Ltd.)

Floating treatment wetlands (FTWs), artificial systems constructed from buoyant mats and planted with emergent macrophytes, represent a potential retrofit to enhance the dissolved nutrient removal performance of existing retention ponds. Treatment occurs as water flows through the dense network of roots suspended in the water column, providing opportunities for pollutants to be removed via filtration, sedimentation, plant uptake, and adsorption to biofilms in the root zone. Despite several recent review articles summarizing the growing body of research on FTWs, FTW design guidance and strategies to optimize their contributions to pollutant removal from stormwater are lacking, due in part to a lack of statistical analysis on FTW performance at the field scale. A meta-analysis of eight international FTW studies was performed to investigate the influence of retention pond, catchment, and FTW design characteristics on effluent concentrations of nutrients and total suspended solids (TSS). Random forest regression, a tree-based machine learning approach, was used to model complex interactions between a suite of predictor variables to identify design strategies for both retention ponds and FTWs to enhance treatment of nutrient and sediment. Results indicate that pond design features, especially loading ratio and pond depth (which should be limited to 200:1 and 1.75 m, respectively), are most influential to effluent water quality, while the benefits of FTWs were limited to improving mitigation of phosphorus species and TSS which was primarily influenced by FTW coverage and planting density. Findings from this work inform wet retention pond and FTW design, as well as guidance on scenarios where FTW implementation is most appropriate, to improve dissolved nutrient and sediment removal in urban runoff., (Copyright © 2022 Elsevier Ltd. All rights reserved.)

The scope of this study was to investigate if using zeolite as a reactive material in a vertical-flow wetland under field conditions improves ammonium removal from domestic wastewater in the long term. The experimental setup consisted of two pilot-scale first stage French vertical flow treatment wetlands (2.3 m 2 surface area each), which were implemented under field scale conditions inside a wastewater treatment plant in the central region of France (L'Encloitre, 37360). The filters were operated during 27 months. A compact pilot containing Leca ® as a main filtration layer (Ø 1-5 mm) was compared to a similar one filled with natural zeolite (Ø 2-5 mm). The pilots were fed according to regular feeding/resting periods (3½/7 days) and the nominal loading rate was of 300 g COD m -2 d -1 and 33 g·N·m -2 ·d -1 during operation. In both pilots, results showed a removal efficiency of more than 90 and 85% for TSS and COD, respectively. They also showed an increased NH 4 -N removal of 9% on average (total removal efficiency of 84%) with the use of zeolite compared to Leca ® . The ion exchange capacity of zeolite seemed not to be affected after 27 months of experiments; however, the material was compacted and more friable after operation.

Bioaugmentation in the form of artificial mycorrhization of plant roots and bacterial inoculation has been successfully implemented in several fields including soil remediation or activated sludge treatment. Likewise, bioaugmentation seems a promising approach to improve the functioning of treatment wetlands, considering that natural mycorrhization has been detected in treatment wetlands and that bacteria are the main driver of contaminant degradation processes. However, to date, full scale implementation seems to be rare. This review synthesizes the effects of bioaugmentation on different types of treatment wetlands, to a large extent performed on a microcosm (<0.5 m 2 ) or mesocosm scale (0.51 to 5 m 2 ). While inoculation with arbuscular mycorrhizal fungi tended to show a positive effect on the growth of some wetland plants (e.g. Phragmites australis), the mechanisms underlying such positive effects are not well understood and the effects of upscaling to full scale treatment wetlands remain unknown. Bacterial inoculation tended to promote plant growth and pollutant degradation, but longer term data is required., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2021 Elsevier B.V. All rights reserved.)

Combined sewer overflows are contaminated with various micropollutants which pose risk to both environmental and human health. Some micropollutants, such as carbamazepine and sulfamethoxazole, are very persistent and difficult to remove from wastewater. Event loaded vertical-flow constructed wetlands (retention soil filters; RSFs) have proven to be effective in the treatment of combined sewer overflows for a wide range of pollutants. However, little is known about how microbial communities contribute to the treatment efficiency, specifically to the reduction of micropollutants. To the best of our knowledge, this is the first study attempting to close this gap. Microbial communities in pilot-scale RSFs were investigated, which showed explicit grouping of metabolic activity at different filter depths with some differential abundance of identified genera. The highest microbial activity was found in the top layer of 0.75 m deep filters, whereas homogeneous activity dominated in a 0.50 m deep filter, indicating oxygen availability to be a limiting factor of the metabolic activity in RSFs. The removal efficiencies of all investigated organic trace substances were correlated to the utilization of specific carbon sources. Most notable is the correlation between the carbon source glucose-1-phosphate and the removal of metoprolol. The strongest correlations for other substances were the removal of diclofenac to the utilization of the carbohydrate i-erythritole; bisphenol A to carbohydrate α-d-lactose, and 1-H-benzotriazole to carbonic acid D-galacturonic acid. Those results are supported by positive correlations of specific microbial genera with both the utilization of the above mentioned carbon sources and the removal efficiency for the respective micropollutants. Most notable is correlation of Tetrasphaera and the removal of benzotriazole and diclofenac., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2020 Elsevier B.V. All rights reserved.)

Municipal wastewater can contain large amounts of organic micropollutants. Some of these substances are harmful to the environment, even at low concentrations, e.g. when being discharged untreated into surface water bodies in case of combined sewer overflows (CSOs) during or after heavy rainfall events. Constructed wetlands can be very effective in treating CSOs. To date, there have only been few investigations about the retention of micropollutants using retention soil filters (RSFs), which basically are vertical flow constructed wetlands with an additional retention area. Thus, focus of this study was set on the interaction between dry periods, loading events, filter operation time, and the resulting removal of micropollutants originating from CSOs. The removal of 1-H-benzotriazole, carbamazepine, diclofenac, metoprolol, sulfamethoxazole and bisphenol A was examined in four test-scale RSFs. Removal efficiencies of approximately 70% were found for metoprolol. 1-H-benzotriazole, diclofenac and bisphenol A were removed moderately between 30 and 40%. For carbamazepine and sulfamethoxazole, negative retention rates were found. No significant correlations were found between removal efficiencies and the length of the antecedent dry period and/or filter operation time. However, the study showed that removal efficiencies depend strongly on respective inflow concentrations. Thickness of the filter layer seems to have an influence as well; does not lead to uniform results, though., (Copyright © 2019 Elsevier Ltd. All rights reserved.)

Repeated investigations on constructed wetlands for the treatment of combined sewer overflows, also named bioretention filters or retention soil filters, are necessary to provide information on their long-term performance. In this study, a sampling campaign was conducted on micropollutants, indicator microorganisms and standard parameters ten years after such filters were in operation and three years after the first investigation; it revealed that the filters lost capacity to remove chemical substances with no or only slow biological degradability. This was the case e.g. for phosphate (decrease from 29 to 11%), diclofenac (67 to 34%) and TCPP (34% to negative reduction). They continued to remove easily degradable parameters such as COD (stable around 75%) stably. The indicator microorganisms Escherichia coli (1.1/0.8 log 10 ), intestinal enterococci (1.3/0.8 log 10 ) and somatic coliphages (0.6/1.0 log 10 ) showed comparably low process variations given the difficulties in sampling and analysing microbial parameters representatively as well as given natural variations in microbial behaviour and growth. Additionally, for bisphenol A, we found a temperature-related difference of removal efficiencies: while in the cold months (winter), the removal was only 53% on average, it increased to 90% in the warm months (summer). As for the long-term prospective of retention soil filters, decision-makers need to identify the most important pollutants in a specific catchment area and adapt the filter design accordingly. If pollutants are targeted that lead to an exhausted filtration capacity, post treatment or the exchange of charged filter material is necessary. However, for easily biologically degradable substances, so far, there is no limit in their use., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Retention soil filters (RSFs) protect water bodies from pollutant loads originating from combined sewer overflows (CSOs) by filtering the wastewater through a filter layer having a depth of 0.75 to 1 m. The microbiological processes in the filter material are influenced by the redox potential (Eh). This potential is a strong indicator of the prevailing environmental conditions and the possible type of microbial activity. Previous investigations of filter bodies have been confined to constructed wetlands (CWs) with regular intermittent wastewater inflow. Compared to CWs, RSFs are characterized by higher oxygen availability due to alternating operating and dry periods. This study aimed to determine the Eh in RSFs and investigate its influence on the removal efficiency for different substances. We established a conceptual model for the standard Eh curve following a loading event, and the variations to this standard in two depths and between treatments. Correlations were determined with a canonical correlation analysis between the pollutant removal of COD, ammonium, phosphorous, E. coli, somatic coliphages and diclofenac and the Eh. Although the removal efficiency is influenced by several additional operating factors such as the preceding dry period, filter age and the respective inflow concentrations, our results show that the Eh is an adequate approach to assess the removal efficiency of RSFs for these substances., (Copyright © 2018 Elsevier B.V. All rights reserved.)

Constructed Floating Wetlands (CFWs) are increasingly being used globally in freshwater environments such as urban lakes and ponds to remove pollutants from urban stormwater runoff. However, to date there has been limited research into the use and performance of these systems in saline environments. This study compared the root and shoot biomass growth and nutrient uptake of five different plant species, Chrysopogon zizanioides , Baumea juncea , Isolepis nodosa , Phragmites australis and Sarcocornia quinqueflora , in three different saltwater treatments over a 12-week period. The aim of the study was to identify which of the plant species may be most suitable for use in CFWs in saline environments. Plant nutrient uptake testing revealed that Phragmites australis had the greatest percentage increase (1473⁻2477%) of Nitrogen mass in the shoots in all treatments. Sarcocornia quinqueflora also had impressive Nitrogen mass increase in saltwater showing an increase of 966% (0.208 ± 0.134 g). This suggests that the use of Phragmites australis and Sarcocornia quinqueflora plants in CFWs installed in saline water bodies, with regular harvesting of the shoot mass, may significantly reduce Nitrogen concentrations in the water. Isolepis nodosa had the greatest percentage increase (112% or 0.018 ± 0.020 g) of Phosphorous mass in the shoots in the saltwater treatment. Baumea juncea had the greatest percentage increase (315% or 0.026 ± 0.012 g) of Phosphorous mass in the roots in the saltwater treatment. This suggests that the use of Isolepis nodosa and Baumea juncea plants in CFWs installed in saline water bodies may significantly reduce Phosphorous concentrations in the water if there was a way to harvest both the shoots above and the roots below the CFWs. The study is continuing, and it is anticipated that more information will be available on CFW plants installed in saline environments in the near future.

Combined sewer overflows (CSOs) introduce numerous pathogens from fecal contamination, such as bacteria and viruses, into surface waters, thus endangering human health. In Germany, retention soil filters (RSFs) treat CSOs at sensitive discharge points and can contribute to reducing these hygienically relevant microorganisms. In this study, we evaluated the extent of how dry period, series connection and filter layer thickness influence the reduction efficiency of RSFs for Escherichia coli (E. coli), intestinal enterococci (I. E.) and somatic coliphages. To accomplish this, we had four pilot scale RSFs built on a test field at the wastewater treatment plant Aachen-Soers. While two filters were replicates, the other two filters were installed in a series connection. Moreover, one filter had a thinner filtration layer than the other three. Between April 2015 and December 2016, the RSFs were loaded in 37 trials with pre-conditioned CSO after dry periods ranging from 4 to 40 days. During 17 trials, samples for microbial analysis were taken and analyzed. The series connection of two filters showed that the removal increases when two systems with a filter layer of the same height are operated in series. Since the microorganisms are exposed twice to the environmental conditions on the filter surface and in the upper filter layers, there is a greater chance for abiotic adsorption increase. The same effect could be shown when filters with different depths were compared: the removal efficiency increases as filter thickness increases. This study provides new evidence that regardless of seasonal effects and dry period, RSFs can improve hygienic situation significantly., (Copyright © 2018 Elsevier GmbH. All rights reserved.)

After rain events in densely populated areas, combined sewer overflows (CSOs) can have severe health-related effects upon surface water quality, as well as diffuse overland runoff and wastewater treatment plants (WWTPs). All of these sources emit pathogens and fecal indicator bacteria into the surface water, which the EU Bathing Water Directive addresses by giving threshold values for the indicators Escherichia coli and intestinal enterococci. This study presents a comparison between 21 scenarios of costs for processes that reduce the load of Escherichia coli and intestinal enterococci into the Ruhr River during and shortly after rain events. The methods examined include UV irradiation for WWTPs, integrated sewer management and treatment of CSOs with vertical flow constructed wetlands or performic acid. For pollution by diffuse overland flow, we evaluated organizational measures. The treatment of only diffuse pollution shows merely a slight effect on intestinal enterococci, but none on Escherichia coli and hence, was not considered further. Combining all three CSO reduction methods with the irradiation of WWTP effluent provides the best simulation results in terms of reducing both indicator bacteria.

Combined sewer overflows contribute significantly to pathogen loads in surface water. Some chemical disinfectants such as chlorine have proved to reduce the levels of microorganisms even in complex matrices such as wastewater in combined sewer systems; however, some of them release toxic by-products into water bodies and increase costs of plant maintenance and repair. In this study, we determined if performic acid (PFA) disinfection units can be operated at decentralized treatment facilities and reduce bacteria, viruses, and protozoan parasites in combined sewer overflows (CSOs). The PFA dosing unit at the inflow of a CSO storage tank dosed a fixed flow volume into the inflowing stormwater and, thus, concentrations varied between approximately 12-24mgl -1 . The results showed a reduction of most hygienically relevant bacteria with mean removal efficiencies of 1.8log 10 for Aeromonas spp. and 3.1log 10 for E. coli. For viruses, however, reduction was only observed for somatic coliphages with 2.7log 10 . In this setting, PFA does not seem to be suitable to remove e.g. protozoan parasites such as Giardia lamblia. In terms of operation, dosing the substance is uncritical in decentralized facilities, but the PFA needs too much time to react with pathogens after being dosed into the overflow of CSO storage tanks and before dilution with surface water in most facilities., (Copyright © 2016 Elsevier GmbH. All rights reserved.)

Swimming in inner-city surface waters is popular in the warm season, but can have negative consequences such as gastro-intestinal, ear and skin infections. The pathogens causing these infections commonly enter surface waters via several point source discharges such as the effluents from wastewater treatment plants and sewer overflows, as well as through diffuse non-point sources such as surface runoff. Nonetheless, the recreational use of surface waters is attractive for residents. In order to save financial and organizational resources, local authorities need to estimate the most relevant pathways of pathogens into surface waters. In particular, when detailed data on a local scale are missing, this is quite difficult to achieve. For this reason, we have developed an easy-to-apply model using the example of Escherichia coli and intestinal enterococci as a first approach to the local situation, where missing data can be replaced by data from literature. The model was developed based on a case study of a river arm monitored in western Germany and will be generalized for future applications. Although the limits of the EU Bathing Water Directive are already fulfilled during dry weather days, we showed that the effluent of wastewater treatment plants and overland flow had the most relevant impact on the microbial surface water quality. On rainy weather days, combined sewer overflows are responsible for the highest microbial pollution loads. The results obtained in this study can help decision makers to focus on reducing the relevant pathogen sources within a catchment area., (Copyright © 2015 Elsevier GmbH. All rights reserved.)

Fecal contamination of water resources is a major public health concern in densely populated areas since these water bodies are used for drinking water production or recreational purposes. A main source of this contamination originates from combined sewer overflows (CSOs) in regions with combined sewer systems. Thus, the treatment of CSO discharges is urgent. In this study, we explored whether ozonation or UV irradiation can efficiently reduce pathogenic bacteria, viruses, and protozoan parasites in CSOs. Experiments were carried out in parallel settings at the outflow of a stormwater settling tank in the Ruhr area, Germany. The results showed that both techniques reduce most hygienically relevant bacteria, parasites and viruses. Under the conditions tested, ozonation yielded lower outflow values for the majority of the tested parameters., (Copyright © 2015 Elsevier GmbH. All rights reserved.)

A main source of surface water pollution in Western Europe stems from combined sewer overflow. One of the few technologies available to reduce this pollution is the retention soil filter. In this research project, we evaluated the cleaning efficiency of retention soil filters measuring the concentration ratio of standard wastewater parameters and bacteria according to factors limiting efficiency, such as long dry phases or phases of long-lasting retention. Furthermore, we conducted an initial investigation on how well retention soil filters reduce certain micropollutants on large-scale plants. There was little precipitation during the 1-year sampling phase, which led to fewer samples than expected. Nevertheless, we could verify how efficiently retention soil filters clean total suspended solids. Our results show that retention soil filters are not only able to eliminate bacteria, but also to retain some of the micropollutants investigated here. As the filters were able to reduce diclofenac, bisphenol A and metoprolol by a median rate of almost 75%, we think that further investigations should be made into the reduction processes in the filter. At this point, a higher accuracy in the results could be achieved by conducting bench-scale experiments.