Search

Spectral observations of Neptune made in 2019 with the MUSE instrument at the Very Large Telescope in Chile have been analysed to determine the spatial variation of aerosol scattering properties and methane abundance in Neptune's atmosphere. The darkening of the South Polar Wave (SPW) at $\sim$ 60$^\circ$S, and dark spots such as the Voyager 2 Great Dark Spot is concluded to be due to a spectrally-dependent darkening ($\lambda < 650$nm) of particles in a deep aerosol layer at $\sim$ 5 bar and presumed to be composed of a mixture of photochemically-generated haze and H$_2$S ice. We also note a regular latitudinal variation of reflectivity at wavelengths of very low methane absorption longer than $\sim$ 650 nm, with bright zones latitudinally separated by $\sim$ 25$^\circ$. This feature, similar to the spectral characteristics of a discrete deep bright spot DBS-2019 found in our data, is found to be consistent with a brightening of the particles in the same $\sim$5-bar aerosol layer at $\lambda > 650 $ nm. We find the properties of an overlying methane/haze aerosol layer at $\sim$ 2 bar are, to first-order, invariant with latitude, while variations in the opacity of an upper tropospheric haze layer reproduce the observed reflectivity at methane-absorbing wavelengths, with higher abundances found at the equator and also in a narrow `zone' at $80^\circ$S. Finally, we find the mean abundance of methane below its condensation level to be 6--7% at the equator reducing to $\sim$3% south of $\sim$25$^\circ$S, although the absolute abundances are model dependent., Comment: 32 pages, 13 figures. Accepted in JGR: Planets

Previous observations of dark vortices in Neptune's atmosphere, such as Voyager-2's Great Dark Spot, have been made in only a few, broad-wavelength channels, which has hampered efforts to pinpoint their pressure level and what makes them dark. Here, we present Very Large Telescope (Chile) MUSE spectrometer observations of Hubble Space Telescope's NDS-2018 dark spot, made in 2019. These medium-resolution 475 - 933 nm reflection spectra allow us to show that dark spots are caused by a darkening at short wavelengths (< 700 nm) of a deep ~5-bar aerosol layer, which we suggest is the H$_2$S condensation layer. A deep bright spot, named DBS-2019, is also visible on the edge of NDS-2018, whose spectral signature is consistent with a brightening of the same 5-bar layer at longer wavelengths (> 700 nm). This bright feature is much deeper than previously studied dark spot companion clouds and may be connected with the circulation that generates and sustains such spots., Comment: 1 table. 3 figures. Nature Astronomy (2023)

We present a reanalysis (using the Minnaert limb-darkening approximation) of visible/near-infrared (0.3 - 2.5 micron) observations of Uranus and Neptune made by several instruments. We find a common model of the vertical aerosol distribution that is consistent with the observed reflectivity spectra of both planets, consisting of: 1) a deep aerosol layer with a base pressure > 5-7 bar, assumed to be composed of a mixture of H2S ice and photochemical haze; 2) a layer of photochemical haze/ice, coincident with a layer of high static stability at the methane condensation level at 1-2 bar; and 3) an extended layer of photochemical haze, likely mostly of the same composition as the 1-2-bar layer, extending from this level up through to the stratosphere, where the photochemical haze particles are thought to be produced. For Neptune, we find that we also need to add a thin layer of micron-sized methane ice particles at ~0.2 bar to explain the enhanced reflection at longer methane-absorbing wavelengths. We suggest that methane condensing onto the haze particles at the base of the 1-2-bar aerosol layer forms ice/haze particles that grow very quickly to large size and immediately 'snow out' (as predicted by Carlson et al. 1988), re-evaporating at deeper levels to release their core haze particles to act as condensation nuclei for H2S ice formation. In addition, we find that the spectral characteristics of 'dark spots', such as the Voyager-2/ISS Great Dark Spot and the HST/WFC3 NDS-2018, are well modelled by a darkening or possibly clearing of the deep aerosol layer only., Comment: 58 pages, 23 figures, 4 tables

Atmospheric circulation patterns derived from multi-spectral remote sensing can serve as a guide for choosing a suitable entry site for a future in situ probe mission. Since the Voyager-2 flybys in the 1980s, three decades of observations from ground- and space-based observatories have generated a picture of Ice Giant circulation that is complex, perplexing, and altogether unlike that seen on the Gas Giants. This review seeks to reconcile the various competing circulation patterns from an observational perspective, accounting for spatially-resolved measurements of: zonal albedo contrasts and banded appearances; cloud-tracked zonal winds; temperature and para-H$_2$ measurements above the condensate clouds; and equator-to-pole contrasts in condensable volatiles (methane and hydrogen sulphide) in the deeper troposphere. These observations identify three distinct latitude domains: an equatorial domain of deep upwelling and upper-tropospheric subsidence, potentially bounded by peaks in the retrograde zonal jet and analogous to Jovian cyclonic belts; a mid-latitude transitional domain of upper-tropospheric upwelling, vigorous cloud activity, analogous to Jovian anticyclonic zones; and a polar domain of strong subsidence, volatile depletion, and small-scale (and potentially seasonally-variable) convective activity. Taken together, the multi-wavelength observations suggest a tiered structure of stacked circulation cells (at least two in the troposphere and one in the stratosphere), potentially separated in the vertical by (i) strong molecular weight gradients associated with cloud condensation, and by (ii) transitions from a thermally-direct circulation regime at depth to a wave-driven circulation regime at high altitude. The inferred circulation can be tested in the coming decade by 3D simulations and by observations from future world-class facilities. [Abridged], Comment: 29 pages, 8 figures, review article accepted to SSRv special issue on "In Situ Exploration of the Ice Giants"

Observations of Neptune, made in 2018 using the new Narrow Field Adaptive Optics mode of the Multi Unit Spectroscopic Explorer (MUSE) instrument at the Very Large Telescope (VLT) from 0.48 - 0.93 micron, are analysed here to determine the latitudinal and vertical distribution of cloud opacity and methane abundance in Neptune's observable troposphere (0.1 - ~3 bar). Previous observations at these wavelengths in 2003 by HST/STIS (Karkoschka and Tomasko 2011, Icarus 205, 674-694) found that the mole fraction of methane above the cloud tops (at ~2 bar) varied from ~4% at equatorial latitudes to ~2% at southern polar latitudes, by comparing the observed reflectivity at wavelengths near 825 nm controlled primarily by either methane absorption or H2-H2/H2-He collision-induced absorption. We find a similar variation in cloud-top methane abundance in 2018, which suggests that this depletion of methane towards Neptune's pole is potentially a long-lived feature, indicative of long-term upwelling at mid-equatorial latitudes and subsidence near the poles. By analysing these MUSE observations along the central meridian with a retrieval model, we demonstrate that a broad boundary between the nominal and depleted methane abundances occurs at between 20 - 40S. We also find a small depletion of methane near the equator, perhaps indicating subsidence there, and a local enhancement near 60 - 70S, which we suggest may be associated with South Polar Features (SPFs) seen in Neptune's atmosphere at these latitudes. Finally, by the use of both a reflectivity analysis and a principal component analysis, we demonstrate that this depletion of methane towards the pole is apparent at all locations on Neptune's disc, and not just along its central meridian.

Recent analysis of Gemini-North/NIFS H-band (1.45 - 1.8 $\mu$m) observations of Uranus, recorded in 2010, with recently updated line data has revealed the spectral signature of hydrogen sulphide (H$_2$S) in Uranus's atmosphere (Irwin et al., 2018). Here, we extend this analysis to Gemini-North/NIFS observations of Neptune recorded in 2009 and find a similar detection of H$_2$S spectral absorption features in the 1.57 - 1.58 $\mu$m range, albeit slightly less evident, and retrieve a mole fraction of $\sim1-3$ ppm at the cloud tops. We find a much clearer detection (and much higher retrieved column abundance above the clouds) at southern polar latitudes compared with equatorial latitudes, which suggests a higher relative humidity of H$_2$S here. We find our retrieved H$_2$S abundances are most consistent with atmospheric models that have reduced methane abundance near Neptune's south pole, consistent with HST/STIS determinations (Karkoschka and Tomasko, 2011). We also conducted a Principal Component Analysis (PCA) of the Neptune and Uranus data and found that in the 1.57 - 1.60 $\mu$m range, some of the Empirical Orthogonal Functions (EOFs) mapped closely to physically significant quantities, with one being strongly correlated with the modelled H$_2$S signal and clearly mapping the spatial dependence of its spectral detectability. Just as for Uranus, the detection of H$_2$S at the cloud tops constrains the deep bulk sulphur/nitrogen abundance to exceed unity (i.e. $ > 4.4 - 5.0$ times the solar value) in Neptune's bulk atmosphere, provided that ammonia is not sequestered at great depths, and places a lower limit on its mole fraction below the observed cloud of (0.4 - 1.3) $\times 10^{-5}$. The detection of gaseous H$_2$S at these pressure levels adds to the weight of evidence that the principal constituent of the 2.5 - 3.5-bar cloud is likely to be H$_2$S ice., Comment: 13 Figures

Observations of Uranus were made on the 8/9th November with HST/WFC3 at a time when a huge cloud complex was present at 30 - 40N. We imaged Uranus in seven filters spanning 467 - 924 nm, and analysed these observations with the NEMESIS radiative-transfer and retrieval code. The same system was also observed in the H-band with VLT/SINFONI ON 31st October and 11th November (Irwin et al., 2016). To constrain the background cloud particle sizes and scattering properties we conducted a limb-darkening analysis of the background cloud structure at 30-40N by simultaneously fitting: a) these HST/OPAL observations at a range of zenith angles; b) the VLT/SINFONI observations at a range of zenith angles; and c) IRTF/SpeX observations made in 2009 (Irwin et al., 2015). We find that the observations are well modelled with a three-component cloud comprised of: 1) a vertically thin, but optically thick 'deep' tropospheric cloud at a pressure of ~2 bars; 2) a methane-ice cloud at the methane-condensation level with variable vertical extent; and 3) a vertically extended tropospheric haze. We find that the particles sizes in both haze and tropospheric cloud have an effective radius of ~0.1 micron, although we cannot rule out larger particle sizes in the tropospheric cloud. We find that the particles in both the tropospheric cloud and haze are more scattering at short wavelengths, giving them a blue colour, but are more absorbing at longer wavelengths, especially for the tropospheric haze. For the particles in the storm clouds, which we assume to be composed of methane ice particles, we find that their mean radii must be ~0.5 micron. We find that the high clouds have low integrated opacity, and that "streamers" reminiscent of thunderstorm anvils are confined to levels deeper than 1 bar. These results argue against vigorous moist convective origins for the cloud features., Comment: 57 pages, 21 figures, 3 tables