26 results on '"Tiwari RN"'
Search Results
2. A Compact Wearable Textile Antenna for NB-IoT and ISM Band Patient Tracking Applications.
- Author
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Sharma D, Tiwari RN, Kumar S, Sharma S, and Matekovits L
- Subjects
- Humans, Wireless Technology instrumentation, Equipment Design, Textiles, Wearable Electronic Devices, Radio Frequency Identification Device methods, Internet of Things
- Abstract
This paper proposes a novel multi-band textile monopole antenna for patient tracking applications. The designed antenna has compact footprints (0.13 λ
0 2 ) and works in the narrow band-internet of things (NB-IoT) 1.8 GHz, radio frequency identification (RFID), and industrial, scientific, and medical (ISM) 2.45 GHz and 5.8 GHz bands. The impedance bandwidths and gain of the antenna at 1.8 GHz, 2.45 GHz, and 5.8 GHz are 310 MHz, 960 MHz, and 1140 MHz; 3.7 dBi, 5.3 dBi, and 9.6 dBi, respectively. Also, the antenna's behavior is checked on different body parts of the human body in various bending scenarios. As per the evaluated link budget, the designed antenna can easily communicate up to 100 m of distance. The specific absorption rate values of the designed antenna are also within acceptable limits as per the (FCC/ICNIRP) standards at the reported frequency bands. Unlike traditional rigid antennas, the proposed textile antenna is non-intrusive, enhancing user safety and comfort. The denim material makes it comfortable for extended wear, reducing the risk of skin irritation. It can also withstand regular wear and tear, including stretching and bending. The presented denim-based antenna can be seamlessly integrated into clothing and accessories, making it less obtrusive and more aesthetically pleasing.- Published
- 2024
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- View/download PDF
3. Quad-Band 1 × 4 Linear MIMO Antenna for Millimeter-Wave, Wearable and Biomedical Telemetry Applications.
- Author
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Tiwari RN, Malya KG, Nandini G, Nikhitha PB, Sharma D, Singh P, and Kumar P
- Subjects
- Humans, Wireless Technology instrumentation, Equipment Design, Wearable Electronic Devices, Telemetry instrumentation, Telemetry methods
- Abstract
In this paper, we present the design of a millimeter-wave 1 × 4 linear MIMO array antenna that operates across multiple resonance frequency bands: 26.28-27.36 GHz, 27.94-28.62 GHz, 32.33-33.08 GHz, and 37.59-39.47 GHz, for mm-wave wearable biomedical telemetry application. The antenna is printed on a flexible substrate with dimensions of 11.0 × 44.0 mm
2 . Each MIMO antenna element features a modified slot-loaded triangular patch, incorporating 'cross'-shaped slots in the ground plane to improve impedance matching. The MIMO antenna demonstrates peak gains of 6.12, 8.06, 5.58, and 8.58 dBi at the four resonance frequencies, along with a total radiation efficiency exceeding 75%. The proposed antenna demonstrates excellent diversity metrics, with an ECC < 0.02, DG > 9.97 dB, and CCL below 0.31 bits/sec/Hz, indicating high performance for mm-wave applications. To verify its properties under flexible conditions, a bending analysis was conducted, showing stable S-parameter results with deformation radii of 40 mm (Rx) and 25 mm (Ry). SAR values for the MIMO antenna are calculated at 28.0/38.0 GHz. The average SAR values for 1 gm/10 gm of tissues at 28.0 GHz are found to be 0.0125/0.0079 W/Kg, whereas, at 38.0 GHz, average SAR values are 0.0189/0.0094 W/Kg, respectively. Additionally, to demonstrate the telemetry range of biomedical applications, a link budget analysis at both 28.0 GHz and 38.0 GHz frequencies indicated strong signal strength of 33.69 dB up to 70 m. The fabricated linear MIMO antenna effectively covers the mm-wave 5G spectrum and is suitable for wearable and biomedical applications due to its flexible characteristics.- Published
- 2024
- Full Text
- View/download PDF
4. On body and off body communication using a compact wideband and high gain wearable textile antenna.
- Author
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Sharma D, Kumar S, Tiwari RN, Choi HC, and Kim KW
- Abstract
In this paper, a compact low-profile dual-band wearable textile antenna is proposed for on-body and off-body communications. The presented antenna works efficiently in the 5G n79 frequency band (4.4 - 5 GHz) and the ISM band (5.725 - 5.875 GHz). The designed antenna has an ultra-wide impedance bandwidth of 2.01 GHz and peak realized gains of 10.5 dBi and 12 dBi at 4.5 GHz and 5.8 GHz, respectively. The antenna has a small footprint (π × 0.3λ
0 2 ), which is inspired by circular fractal geometry. The performance of the presented wearable antenna is evaluated at various body parts, including the arm, wrist, and chest. The link margin is evaluated in the on-body and off-body communication scenarios, i.e., communication with the implantable antenna and the outside-body antenna, which is 80 dB and 65 dB at 4.5 GHz and 5.8 GHz, respectively. The 1 gm/10 gm specific absorption rate values at 4.5 GHz and 5.8 GHz are 0.12/0.098 and 0.11/0.082, respectively, which are significantly lower than the standard values, making the proposed antenna suitable for modern wearable applications., (© 2024. The Author(s).)- Published
- 2024
- Full Text
- View/download PDF
5. A flexible dual-band 4 × 4 MIMO antenna for 5G mm-wave 28/38 GHz wearable applications.
- Author
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Tiwari RN, Sharma D, Singh P, and Kumar P
- Abstract
This paper presents a novel, dual-band, four-port multi-input-multi-output (MIMO) antenna for 28/38 GHz millimeter wave 5G wearable applications. In the proposed work, we have used a novel design approach to get the dual-band behavior from a MIMO design with a small footprint of 18 × 8.5 × 0.25 mm
3 . For this purpose, each MIMO element is designed as a composite form of a circular and elliptical structure connected with a narrow strip and fed by a tapered feedline. The peak realized gains and total efficiencies of the antenna, evaluated in free space, are 4.15 dBi, 7.73 dBi and 80.13%, 85.44% at 28 GHz and 38 GHz frequencies, respectively. To appraise the thorough behavior of the MIMO antenna, we have evaluated all the parameters of the antenna: Envelope Correlation Coefficient (ECC), Diversity Gain (DG), Mean Effective Gain (MEG), Channel Capacity Loss (CCL), and Total Active Reflection Coefficient (TARC), and found them satisfactory. Channel capacity of the antenna at SNR = 20 dB is found to be 21.61 bps/Hz. For wearable applications, the proposed 4-port MIMO antenna is designed on a flexible Rogers 3003 substrate, and the performance is checked by evaluating bending analysis. The safety of the antenna is verified by analyzing the 1 g/10 g SAR at 28/38 GHz and the corresponding average SAR values are 0.11/0.08 W/kg and 0.05/0.04 W/kg, respectively. All the average SAR values for the proposed MIMO antenna are within the acceptable limits according to FCC/ICNIRP standards., (© 2024. The Author(s).)- Published
- 2024
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6. SCAPS study on the effect of various hole transport layer on highly efficient 31.86% eco-friendly CZTS based solar cell.
- Author
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Ranjan R, Anand N, Tripathi MN, Srivastava N, Sharma AK, Yoshimura M, Chang L, and Tiwari RN
- Abstract
Copper Zinc Tin Sulphide (CZTS) is a propitious semiconductor for active absorber material in thin-film solar cells (SCs). Here, SC architecture comprising FTO/ZnS/CZTS/variable HTLs/Au is discussed. Fluorine-doped tin oxide (FTO) and gold (Au) are used as front and back contacts, respectively. Zinc sulphide (ZnS) is used as an active electron transport layer (ETL), while different Cu-based materials (Cu
2 O, CuO, CuI, and CuSCN) are used as hole transport layers (HTL). A one-dimensional solar cell capacitance simulator (SCAPS-1D) is utilized to simulate the SC structure. Among different Cu-based HTLs, Cu2 O is preferred as a potential candidate for high cell performance of CZTS-based SC. The effects of various layer parameters such as thickness, doping density, and carrier concentrations, electron affinity of HTL and absorber, respectively, are also discussed. After optimization of the device, variation of operating temperature and the effect of series and shunt resistance are also taken into consideration. The optimized results of thickness and acceptor concentration (NA ) of absorber material are 1.5 µm and approx. 1.0 × 1019 cm-3 , respectively. In addition, the function of HTL (with and without) in the designed SC structure is also studied. Capacitance-voltage (C-V) characteristics are also discussed to get an insight of built-in potential. We have achieved cell performances viz. efficiency = 31.86%, short circuit current density = 32.05 mA/cm2 , open circuit voltage = 1.19 V, and fill factor = 83.37%., (© 2023. The Author(s).)- Published
- 2023
- Full Text
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7. MIMO Antennas: Design Approaches, Techniques and Applications.
- Author
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Sharma P, Tiwari RN, Singh P, Kumar P, and Kanaujia BK
- Subjects
- Reproducibility of Results, Equipment Design, Wireless Technology
- Abstract
The excessive use of digital platforms with rapidly increasing users in the wireless domain enforces communication systems to provide information with high data rates, high reliability and strong transmission connection quality. Wireless systems with single antenna elements are not able to accomplish the desired needs. Therefore, multiple-input multiple-output (MIMO) antennas are getting more attention in modern high-speed communication systems and play an essential part in the current generation of wireless technology. However, along with their ability to significantly increase channel capacity, it is a challenge to achieve an optimal isolation in a compact size for fifth-generation (5G) terminals. Portable devices, automobiles, handheld gadgets, smart phones, wireless sensors, radio frequency identification and other applications use MIMO antenna systems. In this review paper, the fundamentals of MIMO antennas, the performance parameters of MIMO antennas, and different design approaches and methodologies are discussed to realize the three most commonly used MIMO antennas, i.e., ultra-wideband (UWB), dual-band and circularly polarized antennas. The recent MIMO antenna design approaches with UWB, dual band and circularly polarized characteristics are compared in terms of their isolation techniques, gain, efficiency, envelope correlation coefficient (ECC) and channel capacity loss (CCL). This paper is very helpful to design suitable MIMO antennas applicable in UWB systems, satellite communication systems, GSM, Bluetooth, WiMAX, WLAN and many more. The issues with MIMO antenna systems in the indoor environment along with possible solutions to improve their performance are discussed. The paper also focuses on the applications of MIMO characteristics for future sixth-generation (6G) technology.
- Published
- 2022
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8. LC, MS n and LC-MS/MS studies for the characterization of degradation products of amlodipine.
- Author
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Tiwari RN, Shah N, Bhalani V, and Mahajan A
- Abstract
In the present study, comprehensive stress testing of amlodipine (AM) was carried out according to International Conference on Harmonization (ICH) Q1A(R2) guideline. AM was subjected to acidic, neutral and alkaline hydrolysis, oxidation, photolysis and thermal stress conditions. The drug showed instability in acidic and alkaline conditions, while it remained stable to neutral, oxidative, light and thermal stress. A total of nine degradation products (DPs) were formed from AM, which could be separated by the developed gradient LC method on a C
18 column. The products formed under various stress conditions were investigated by LC-MS/MS analysis. The previously developed LC method was suitably modified for LC-MS/MS studies by replacing phosphate buffer with ammonium acetate buffer of the same concentration (pH 5.0). A complete fragmentation pathway of the drug was first established to characterize all the degradation products using LC-MS/MS and multi-stage mass (MSn ) fragmentation studies. The obtained mass values were used to study elemental compositions, and the total information helped with the identification of DPs, along with its degradation pathway.- Published
- 2015
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9. Low vacuum annealing of cellulose acetate on nickel towards transparent conductive CNT-graphene hybrid films.
- Author
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Nguyen DD, Tiwari RN, Matsuoka Y, Hashimoto G, Rokuta E, Chen YZ, Chueh YL, and Yoshimura M
- Abstract
We report a versatile method based on low vacuum annealing of cellulose acetate on nickel (Ni) surface for rapid fabrication of graphene and carbon nanotube (CNT)-graphene hybrid films with tunable properties. Uniform films mainly composed of tri-layer graphene can be achieved via a surface precipitation of dissociated carbon at 800 °C for 30 seconds under vacuum conditions of ∼0.6 Pa. The surface precipitation process is further found to be efficient for joining the precipitated graphene with pre-coated CNTs on the Ni surface, consequently, generating the hybrid films. As expected, the hybrid films exhibit substantial opto-electrical and field electron emission properties superior to their individual counterparts. The finding suggests a promising route to hybridize the graphene with diverse nanomaterials for constructing novel hybrid materials with improved performances.
- Published
- 2014
- Full Text
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10. Interconnected Pt-nanodendrite/DNA/reduced-graphene-oxide hybrid showing remarkable oxygen reduction activity and stability.
- Author
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Tiwari JN, Kemp KC, Nath K, Tiwari RN, Nam HG, and Kim KS
- Abstract
Controlling the morphology and size of platinum nanodendrites (PtDs) is a key factor in improving their catalytic activity and stability. Here, we report the synthesis of PtDs on genomic-double-stranded-DNA/reduced-graphene-oxide (gdsDNA/rGO) by the NaBH4 reduction of H(2)PtCl(6) in the presence of plant gdsDNA. Compared to industrially adopted catalysts (i.e., state-of-the-art Pt/C catalyst, Pt/rGO, Pt(3)Co, etc.), the as-synthesized PtDs/gdsDNA/rGO hybrid displays very high oxygen reduction reaction (ORR) catalytic activities (much higher than the 2015 U.S. Department of Energy (DOE) target values), which are the rate-determining steps in electrochemical energy devices, in terms of onset-potential, half-wave potential, specific-activity, mass-activity, stability, and durability. Moreover, the hybrid exhibits a highly stable mass activity for the ORR over a wide pH range of 1-13. These exceptional properties would make the hybrid applicable in next-generation electrochemical energy devices.
- Published
- 2013
- Full Text
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11. Thermal transformation of carbon hybrid materials to graphene films.
- Author
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Tiwari RN, Ishihara M, Tiwari JN, and Yoshimura M
- Abstract
We demonstrate a simple approach to grow graphene films on polycrystalline nickel (Ni) foils, in which polycrystalline carbon hybrid materials (CHMs) were used in sandwich structures (molybdenum-CHMs-Ni-molybdenum) as a carbon source for graphene, and pressure was then applied to the sandwich. The CHMs were transformed into single as well as few layer graphene by a segregation-precipitation process. The applied pressure not only increased the density of the graphene films but also reduced the vaporization of dissociated carbon molecules of the CHMs. We have explored the possibility to grow graphene films in low vacuum (5 × 10(-1) Pa) at relatively low temperatures (≤750 °C). The formation of the graphene films at 750 °C is simple and cost-effective and can be scaled up.
- Published
- 2013
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12. Bilateral large traumatic basal ganglia haemorrhage in a conscious adult: a rare case report.
- Author
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Jain SK, Sundar IV, Sharma V, Prasanna KL, Kulwal G, and Tiwari RN
- Subjects
- Accidental Falls, Adult, Basal Ganglia Hemorrhage rehabilitation, Brain Injuries rehabilitation, Consciousness, Hematoma, Epidural, Cranial rehabilitation, Humans, Male, Tomography, X-Ray Computed, Treatment Outcome, Basal Ganglia Hemorrhage diagnosis, Basal Ganglia Hemorrhage etiology, Brain Injuries complications, Brain Injuries diagnosis, Hematoma, Epidural, Cranial diagnosis, Hematoma, Epidural, Cranial etiology
- Abstract
Background: Bilateral traumatic basal ganglia haematoma is an extremely rare event in traumatic brain injuries, with only five reported cases. The presumed mechanism is due to shearing forces leading to haemorrhage from the lenticulostriate or anterior choroidal artery. The prognosis appears to be dependent on the extent and severity of underlying brain injury., Case Study: A case of a 38 year old fully conscious male, who presented with bilateral basal ganglia haematoma and extradural haematoma, is presented and the relevant literature is briefly reviewed.
- Published
- 2013
- Full Text
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13. Stable platinum nanoclusters on genomic DNA-graphene oxide with a high oxygen reduction reaction activity.
- Author
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Tiwari JN, Nath K, Kumar S, Tiwari RN, Kemp KC, Le NH, Youn DH, Lee JS, and Kim KS
- Subjects
- Arabidopsis genetics, Catalysis, Electrochemistry, Hydrogen-Ion Concentration, Metal Nanoparticles ultrastructure, Oxidation-Reduction, Particle Size, Solutions, DNA, Plant metabolism, Genome, Plant genetics, Graphite chemistry, Metal Nanoparticles chemistry, Oxygen chemistry, Platinum chemistry
- Abstract
Nanosize platinum clusters with small diameters of 2-4 nm are known to be excellent catalysts for the oxygen reduction reaction. The inherent catalytic activity of smaller platinum clusters has not yet been reported due to a lack of preparation methods to control their size (<2 nm). Here we report the synthesis of platinum clusters (diameter ≤1.4 nm) deposited on genomic double-stranded DNA-graphene oxide composites, and their high-performance electrocatalysis of the oxygen reduction reaction. The electrochemical behaviour, characterized by oxygen reduction reaction onset potential, half-wave potential, specific activity, mass activity, accelerated durability test (10,000 cycles) and cyclic voltammetry stability (10,000 cycles) is attributed to the strong interaction between the nanosize platinum clusters and the DNA-graphene oxide composite, which induces modulation in the electronic structure of the platinum clusters. Furthermore, we show that the platinum cluster/DNA-graphene oxide composite possesses notable environmental durability and stability, vital for high-performance fuel cells and batteries.
- Published
- 2013
- Full Text
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14. Telemedicine in neurosurgical emergency: Indian perspective.
- Author
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Sinha VD, Tiwari RN, and Kataria R
- Abstract
Telemedicine is rapidly developing telecommunication technology to provide medical information and services. The importance of telemedicine for neurosurgical emergencies was established with the fact that majority of the neurosurgical specialists are practicing in urban settings and in most of the rural areas, neurosurgical care is far off or non-existing. Countries with inadequate health care must incorporate telemedicine in their health care system. Telemedicine offers real benefits in a country as vast as India, where the majority of the population lives in remote areas with no access to even the most basic healthcare. Issues pertaining security, privacy, maintaining standards, and legal aspects are relevant. A recommended set of standards and guidelines for telemedicine needs to be set in place and constantly refined to promote the integrated growth of telemedicine in the country. The paper discusses various issues, shortcomings, and utility of telemedicine in India.
- Published
- 2012
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15. Synthesis of graphene film from fullerene rods.
- Author
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Tiwari RN, Ishihara M, Tiwari JN, and Yoshimura M
- Abstract
Here we demonstrate a facile approach to grow uniform and large area single layer graphene directly over polycrystalline metal foil from fullerene, where fullerene molecules formed rod-like polycrystals in the toluene solvent. The generated pressure on sandwich structures has enhanced the density (scalable) as well as quality of graphene at partially low temperatures.
- Published
- 2012
- Full Text
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16. Development and validation of stability indicating method for the determination of exemestane by reverse phase high performance liquid chromatography.
- Author
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Konda B, Tiwari RN, and Fegade H
- Subjects
- Androstadienes chemistry, Androstadienes standards, Drug Stability, Least-Squares Analysis, Reproducibility of Results, Sensitivity and Specificity, Temperature, Androstadienes analysis, Chromatography, High Pressure Liquid methods, Chromatography, Reverse-Phase methods
- Abstract
Exemestane is an aromatase inhibitor used in the treatment of breast cancer. A selective stability-indicating reversed-phase high performance liquid chromatography (RP-HPLC) method has been developed which can separate and accurately quantitate low levels of exemestane. The stability-indicating capability of the method was demonstrated by adequate separation of exemestane and all the degradation product peaks from exemestane peak and also from each other in stability samples of exemestane. Chromatographic separation of exemestane and its degraded products were achieved by using isocratic elution at a flow rate of 1.0 mL/min on a C18 reverse phase column (Phenomenex, size: 250 × 4.60 mm, particle size 5 μm) at ambient temperature. The mobile phase used for the analysis was acetonitrile-water (60:40, %v/v) with UV visible detection at 242 nm. The proposed method was used to study the degradation behavior of drug under various stress conditions as per ICH recommended guidelines.
- Published
- 2011
- Full Text
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17. LC, LC-MS/TOF and MS(n) studies for the identification and characterization of degradation products of nelfinavir mesylate.
- Author
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Tiwari RN and Bonde CG
- Subjects
- Chromatography, High Pressure Liquid instrumentation, Drug Stability, Guidelines as Topic, HIV Protease Inhibitors chemistry, Hydrolysis, Mass Spectrometry instrumentation, Models, Chemical, Molecular Structure, Nelfinavir chemistry, Oxidation-Reduction, Photolysis, Reproducibility of Results, Technology, Pharmaceutical instrumentation, Temperature, Chromatography, High Pressure Liquid methods, HIV Protease Inhibitors analysis, Mass Spectrometry methods, Nelfinavir analysis, Technology, Pharmaceutical methods
- Abstract
The objective of the present investigation was to separate, identify and characterize the major degradation products (DPs) of nelfinavir mesylate generated under hydrolytic, oxidative, photolytic and thermal stress conditions as advised in International Conference on Harmonization (ICH) guideline Q1A(R2). The drug was found to degrade under acidic, basic, oxidative and photolytic stress, while it was stable in neutral and thermal stress conditions. A total of three degradation products were formed, which were separated on a C-18 column employing a gradient HPLC method. A complete mass fragmentation pathway of the drug was first established with the help of multi-stage (MS(n)) and MS/TOF accurate mass studies. Then stressed samples were subjected to LC-MS/TOF studies, which provided their fragmentation pattern and accurate masses. The mass spectral data were employed to characterize the DPs and assign structures to them. The total information was also used to establish the degradation pathway of the drug. The degradation products were identified as 3-hydroxy-N-((2R,3R)-3-hydroxy-1-(phenylthio)butan-2-yl)-2-methylbenzamide and (3S,4aS,8aS)-N-tert-butyl-2-((2R,3R)-2-hydroxy-3-(3-hydroxy-2-methylbenzamido)-4-(phenylsulfinyl)butyl)decahydroisoquinoline-3-carboxamide., (Copyright © 2011 Elsevier B.V. All rights reserved.)
- Published
- 2011
- Full Text
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18. Thin-film composite materials as a dielectric layer for flexible metal-insulator-metal capacitors.
- Author
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Tiwari JN, Meena JS, Wu CS, Tiwari RN, Chu MC, Chang FC, and Ko FH
- Subjects
- Materials Testing, Metals, Surface Properties, Electric Capacitance, Electronics instrumentation, Nanocomposites chemistry
- Abstract
A new organic-organic nanoscale composite thin-film (NCTF) dielectric has been synthesized by solution deposition of 1-bromoadamantane and triblock copolymer (Pluronic P123, BASF, EO20-PO70-EO20), in which the precursor solution has been achieved with organic additives. We have used a sol-gel process to make a metal-insulator-metal capacitor (MIM) comprising a nanoscale (10 nm-thick) thin-film on a flexible polyimide (PI) substrate at room temperature. Scanning electron microscope and atomic force microscope revealed that the deposited NCTFs were crack-free, uniform, highly resistant to moisture absorption, and well adhered on the Au-Cr/PI. The electrical properties of 1-bromoadamantane-P123 NCTF were characterized by dielectric constant, capacitance, and leakage current measurements. The 1-bromoadamantane-P123 NCTF on the PI substrate showed a low leakage current density of 5.5 x 10(-11) A cm(-2) and good capacitance of 2.4 fF at 1 MHz. In addition, the calculated dielectric constant of 1-bromoadamantane-P123 NCTF was 1.9, making them suitable candidates for use in future flexible electronic devices as a stable intermetal dielectric. The electrical insulating properties of 1-bromoadamantane-P123 NCTF have been improved due to the optimized dipole moments of the van der Waals interactions.
- Published
- 2010
- Full Text
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19. Synthesis of Pt nanopetals on highly ordered silicon nanocones for enhanced methanol electrooxidation activity.
- Author
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Tiwari JN, Tiwari RN, and Lin KL
- Subjects
- Aluminum Oxide chemistry, Catalysis, Oxidation-Reduction, Silicon Dioxide chemistry, Spectrum Analysis, Raman, Fossil Fuels, Methanol chemistry, Nanotechnology methods, Platinum chemistry, Silicon chemistry
- Abstract
Platinum (Pt) nanopetals were electrodeposited on highly ordered silicon nanocones (SiNCs) and explored as the electrocatalyst for methanol oxidation reaction (MOR) for direct methanol fuel cells applications. Highly ordered SiNCs array fabricated using the porous anodic aluminum oxide as the template had a high surface area. Well-dispersed Pt nanopetals possessing high electrocatalytic surface area was synthesized by pulse-electrodeposition on the SiNCs. Pt nanopetals loaded on highly ordered SiNC support exhibited very good catalytic activity for MOR and a high tolerance against CO poisoning, as compared to Pt nanoflowers/flat Si, Pt nanoparticles/flat Si, and many previously reported works. The abundance of a large surface area for facile transport of methanol, SiO(2) sites in the vicinity of the SiNCs, as well as less contact area between the Pt nanopetals catalyst and SiNCs are suggested to be the major factors enhancing the electrocatalytic performance of the Pt nanopetal/SiNC electrode. Moreover, we believe this new nanostructure (Pt nanopetals/SiNCs) will enable many new advances in nanotechnology.
- Published
- 2010
- Full Text
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20. A promising approach to the synthesis of 3D nanoporous graphitic carbon as a unique electrocatalyst support for methanol oxidation.
- Author
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Tiwari JN, Tiwari RN, Chang YM, and Lin KL
- Subjects
- Alloys chemistry, Catalysis, Electrochemistry, Microscopy, Electron, Scanning, Oxidation-Reduction, Photoelectron Spectroscopy, Platinum chemistry, Porosity, Ruthenium chemistry, Temperature, Graphite chemistry, Methanol chemistry, Nanostructures chemistry
- Abstract
A 3D nanoporous graphitic carbon (g-C) material is synthesized by using an adamantane (C(10)H(16)) flame, and utilized to support a Pt(50)-Ru(50) alloy catalyst. The physico-chemical properties of the Pt(50)-Ru(50)/3D nanoporous g-C electrode are examined by a range of spectroscopy techniques as well as Brunauer-Emmett-Teller surface area analysis. Cyclic voltammetry measurements are used for electrochemical characterization of the Pt(50)-Ru(50)/3D nanoporous g-C electrode. The electrochemical investigations show that the supported Pt(50)-Ru(50) has excellent activity and stability towards methanol electro-oxidation. Good CO tolerance is also shown, and considered to be due to the presence of Ru nanoparticles. It is proposed that Ru is able to promote the oxidation of strongly adsorbed CO on Pt by supplying an oxygen source: Ru(OH)(ad). Moreover, the presence of 3D nanopores in the g-C support may also contribute to the observed higher current density by virtue of the easy transport of methanol and the oxidation products through these nanopores.
- Published
- 2010
- Full Text
- View/download PDF
21. Facile synthesis of continuous Pt island networks and their electrochemical properties for methanol electrooxidation.
- Author
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Tiwari JN, Pan FM, Tiwari RN, and Nandi SK
- Subjects
- Catalysis, Electrochemistry, Microscopy, Electron, Scanning, Oxidation-Reduction, Methanol chemistry, Platinum Compounds chemical synthesis
- Abstract
A two-dimensional continuous Pt island network was successfully synthesized by pulse-potentiostatic electrodeposition on a flat silicon substrate, which showed markedly enhanced catalytic activity toward methanol electrooxidation and high CO tolerance, probably due to the synergistic effect of the Pt island catalyst and surrounding SiO(2) surface layer.
- Published
- 2008
- Full Text
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22. Evaluation of pollution susceptibility of Karst aquifers of Rewa Town (Madhya Pradesh) using "DRASTIC" approach.
- Author
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Dubey DP, Tiwari RN, and Dwivedi U
- Subjects
- Calcium Carbonate, Geological Phenomena, Geology, India, Porosity, Soil, Water Movements, Algorithms, Water Pollution prevention & control, Water Supply
- Abstract
Pollution susceptibility of groundwater of Rewa town situated on karstified Bhander limestones of the Bhander group is discussed in this paper. Pollution potential of selected localities in the town has been determined using the DRASTIC INDEX methodology. Pollution potential for these localities varied between 162 to 217. Shallow aquifers in karstified limestones having direct access to surface water were found more susceptible to pollution. Accordingly, remedial measures were suggested for minimising pollution.
- Published
- 2006
23. Electromagnetic mass models in general relativity: Lane-Emden-type models.
- Author
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Tiwari RN, Rao JR, and Kanakamedala RR
- Published
- 1986
- Full Text
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24. Slowly rotating charged fluid spheres in general relativity.
- Author
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Tiwari RN, Rao JR, and Kanakamedala RR
- Published
- 1986
- Full Text
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25. Coexistent duodenal and multiple gastric ulcers.
- Author
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Sinha SN and Tiwari RN
- Subjects
- Adult, Chronic Disease, Humans, Male, Middle Aged, Pyloric Stenosis complications, Duodenal Ulcer complications, Stomach Ulcer complications
- Published
- 1975
26. Influence of the dwarfing gene dw on egg production and viability under summer heat stress.
- Author
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Khan AG, Tiwari RN, Baghel KK, and Gupta RD
- Subjects
- Animals, Female, Genotype, Poultry Diseases mortality, Species Specificity, Stress, Physiological mortality, Stress, Physiological physiopathology, Chickens genetics, Genes, Hot Temperature adverse effects, Oviposition, Poultry Diseases physiopathology, Stress, Physiological veterinary
- Abstract
1. Dwarf egg layer (Narmada XL) dwarf broiler (DB) and normal bodied sib (NB) hens were studied under cyclic summer hot and dry heat stress of 21.1 to 45.5 degrees C for a period of 50 d. The genotype effect for egg production was significant (P less than 0.01). 2. N-XL and DB genotypes laid 12.1% more eggs than NB. Egg production declined by 3.17, 1.27 and 3.25% for a rise in temperature (maximum) of 1 degree C for N-XL, DB and NB genotypes respectively. 3. Egg production in Narmada XL declined by 42% compared to 25% in the dwarf broilers. The regression coefficients differed significantly. 4. For polygenically identical DB and NB broiler breeder hens the heat stressor significantly reduced egg production 1.98% more in the NB genotype compared with DB with a 1 degree C rise in temperature. 5. Mortality was less in the N-XL as compared to DB, but NB hens showed 11.7% more mortality than dwarfs.
- Published
- 1987
- Full Text
- View/download PDF
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