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The low-frequency variability of the δ 18 O recorded in ice cores (FK17 and TIR18) recently drilled at two different locations in Dronning Maud Land (Antarctica), is investigated using multi-taper spectral method and singular spectrum analysis. Multiple dominant peaks emerge in these records with periods between 3 and 20 years. The two sites show distinct spectral signatures, despite their relative proximity in space (about 100 km apart), suggesting that different processes are involved in generating the variability at these two sites. In order to clarify which processes are acting on δ 18 O at these two locations, the impact of several climate indices as well as sea ice area is investigated using a causal method, known as the Liang-Kleeman rate of information transfer. The analysis of the origin of this low-frequency variability from external sources reveals that the El Niño-Southern Oscillation (ENSO), the Pacific Decadal Oscillation (PDO), the Southern Annular Mode (SAM), the Dipole Mode Index (DMI) and the sea ice area display important causal influences on δ 18 O at FK17. For TIR18, the main influences are from ENSO, PDO, DMI, the sea ice area, and the Atlantic Multidecadal Oscillation (AMO), revealing the complexity of the interactions in Dronning Maud Land. The two locations share several drivers, but also show local specificities potentially linked to ocean proximity and differences in air mass trajectories. [ABSTRACT FROM AUTHOR]

Basal materials in ice cores hold information about paleoclimate conditions, glacial processes, and the timing of past ice-free intervals, all of which aid understanding of ice sheet stability and its contribution to sea level rise in a warming climate. Only a few cores have been drilled through ice sheets into the underlying sediment and bedrock, producing limited material for analysis. The last of three Camp Century ice cores, which the U.S. Army collected in northwestern Greenland from 1963–1966 CE, recovered about 3.5 m of subglacial material, including ice and sediment. Here, we document the scientific history of the Camp Century subglacial material. We present our recent core-cutting, sub-sampling, and processing methodology and results for this unique archive. In 1972 CE, curators at the Buffalo, New York, Ice Core Laboratory cut the original core sections into 32 segments that were each about 10 cm long. Since then, two segments were lost and are unaccounted for, two were thawed, and two were cut as pilot samples in 2019 CE. Except for the two thawed segments, the rest of the extant core has remained frozen since collection. In 2021 CE, we documented, described, and then cut each of the remaining frozen archived segments (n=26). We saved an archival half and cut the working half into eight oriented sub-samples under controlled temperature and light conditions for physical, geochemical, isotopic, sedimentological, magnetic, and biological analyses. Our approach was designed to maximize sample usage for multiproxy analysis, minimize contamination, and preserve archive material for future analyses of this legacy subglacial material. Grain size, bulk density, sedimentary features, magnetic susceptibility, and ice content, as well as pore ice pH and conductivity, suggest that the basal sediment contains five stratigraphic units. We interpret these stratigraphic units as representing different depositional environments in subglacial or ice-free conditions: from bottom to top, a diamicton with subhorizontal ice lenses (Unit 1), vertically fractured ice with dispersed fine-grained sediments (<20 % in mass) (Unit 2), a normally graded bed of pebbles to very fine sand in an icy matrix (Unit 3), bedded very fine to fine sand (Unit 4), and stratified medium to coarse sand (Unit 5). Plant macrofossils are present in all samples and are most abundant in Units 3 and 4; insect remains are present in some samples (Units 1, 3, and 5). Our approach provides a working template for future studies of ice core basal materials because it includes intentional planning of core sub-sampling, processing methodologies, and archiving strategies to optimize the collection of paleoclimate, glacial process, geochemical, geochronological, and sediment properties from archives of limited size. Our work benefited from a carefully curated and preserved archive, allowing the application of analytical techniques not available in 1966 CE. Preserving uncontaminated core material for future analyses that use currently unavailable tools and techniques is an important consideration for rare archive materials such as these from Camp Century. [ABSTRACT FROM AUTHOR]

Over the past two decades, with recognition that the ocean's sea-ice cover is neither insensitive to climate change nor a barrier to light and matter, research in sea-ice biogeochemistry has accelerated significantly, bringing together a multi-disciplinary community from a variety of fields. This disciplinary diversity has contributed a wide range of methodological techniques and approaches to sea-ice studies, complicating comparisons of the results and the development of conceptual and numerical models to describe the important biogeochemical processes occurring in sea ice. Almost all chemical elements, compounds, and biogeochemical processes relevant to Earth system science are measured in sea ice, with published methods available for determiningbiomass, pigments, net community production, primary production, bacterial activity, macronutrients, numerous natural and anthropogenic organic compounds, trace elements, reactive and inert gases, sulfur species, the carbon dioxide system parameters, stable isotopes, and water-ice-Atmosphere fluxes of gases, liquids, and solids. For most of these measurements, multiple sampling and processing techniques are available, but to date there has been little intercomparison or intercalibration between methods. In addition, researchers collect different types of ancillary data and document their samples differently, further confounding comparisons between studies. These problems are compounded by the heterogeneity of sea ice, in which even adjacent cores can have dramatically different biogeochemical compositions. We recommend that, in future investigations, researchers design their programs based on nested sampling patterns, collect a core suite of ancillary measurements, and employ a standard approach for sample identification and documentation. In addition, intercalibration exercises are most critically needed for measurements of biomass, primary production, nutrients, dissolved and particulate organic matter (including exopolymers), the CO2 system, air-ice gas fluxes, and aerosol production. We also encourage the development of in situ probes robust enough for long-Term deployment in sea ice, particularly for biological parameters, the CO2 system, and other gases.

Basal materials in ice cores contain information about paleoclimate conditions, glacial processes, and the timing of past ice-free intervals, all of which aid understanding of ice-sheet stability and its contribution to sea-level rise in a warming climate. Only a few ice cores have been drilled through ice sheets to the underlying sediment and bedrock, producing limited material for analysis. The Camp Century ice core, which the US Army drilled in northwest Greenland from 1960–1966 CE, recovered about 3.5 meters of sub-glacial sediment. Here, we document the scientific history of the Camp Century sub-glacial sediment, and present our recent core-cutting, sub-sampling, and processing methodology and results for what remains of this unique archive. In 1972, curators in the Buffalo Ice Core Laboratory cut the original core segments into 32 segments each about 10-cm long. Since then, two segments are unaccounted for, two were thawed, and two were cut as pilot samples in 2019. With the exception of the two thawed segments, the rest of the extant core remained frozen since collection. In fall 2021, we documented, described, and then cut each of the remaining frozen archived segments (n=26). We saved an archival half and then cut the working half into eight oriented sub-samples under controlled temperature and light conditions for physical, geochemical, isotopic, sedimentological, magnetic, and biological analyses. Our approach maximized sample usage for multi-proxy analysis, minimized contamination, and preserved archive material for future analyses of this legacy sample material. Grain size, bulk density, sedimentary features, magnetic susceptibility, ice content, as well as pore-ice pH and conductivity, suggest that the basal sediment contains five stratigraphic units. We interpret these stratigraphic units as representing different depositional environments in sub-glacial or ice-free conditions: from bottom to top, a diamicton with sub-horizontal ice lenses (Unit 1); vertically-fractured ice with dispersed fine-grain sediments (< 20 % in mass) (Unit 2); a normally graded bed of pebbles to very fine sand in an icy matrix (Unit 3); bedded very fine to fine sand (Unit 4); and stratified medium to coarse sand (Unit 5). Plant macrofossils are present in all samples and most abundant in Units 3 and 4; insect remains are present in some samples (Units 1, 3, and 5). Our approach provides a working template for future studies of ice-core basal sediment because it includes intentional planning of core sub-sampling, processing methodologies, and archiving strategies in order to optimize the collection of paleoclimate, glacial process, geochemical, geochronological, and sediment properties from archives of limited size. Our work benefited from a carefully curated and preserved archive, allowing for the application of techniques not available in 1966. Preserving uncontaminated core material for future analytical capabilities is an important consideration for rare archive materials such as these from Camp Century. [ABSTRACT FROM AUTHOR]

Surface mass balance (SMB) of the Antarctic Ice Sheet must be better understood to document the current Antarctic contribution to sea-level rise. In situ point data using snow stakes and ice cores are often used to evaluate the state of the ice sheet's mass balance, as well as to assess SMB derived from regional climate models, which are then used to produce future climate projections. However, spatial representativeness of individual point data remains largely unknown, particularly in the coastal regions of Antarctica with highly variable terrain. Here, we compare ice core data collected at the summit of eight ice rises along the coast of Dronning Maud Land, as well as at the Dome Fuji site, and shallow ice-penetrating radar data over these regions. Shallow radar data have the advantage of being spatially extensive, with a temporal resolution that varies between a yearly and multi-year resolution, from which we can derive a SMB record over the entire radar survey. This comparison therefore allows us to evaluate the spatial variability of SMB and the spatial representativeness of ice-core-derived SMB. We found that ice core mean SMB is very local, and the difference with radar-derived SMB increases in a logarithmic fashion as the surface covered by the radar data increases, with a plateau ∼ 1–2 km away from the ice crest for most ice rises, where there are strong wind–topography interactions, and ∼ 10 km where the ice shelves begin. The relative uncertainty in measuring SMB also increases rapidly as we move away from the ice core sites. Five of our ice rise sites show a strong spatial representativeness in terms of temporal variability, while the other three sites show that it is limited to a surface area between 20–120 km 2. The Dome Fuji site, on the other hand, shows a small difference between pointwise and area mean SMB, as well as a strong spatial representativeness in terms of temporal variability. We found no simple parameterization that could represent the spatial variability observed at all the sites. However, these data clearly indicate that local spatial SMB variability must be considered when assessing mass balance, as well as comparing modeled SMB values to point field data, and therefore must be included in the estimate of the uncertainty of the observations. [ABSTRACT FROM AUTHOR]