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3. Supported Gold Catalysts for Base-Free Furfural Oxidation: The State of the Art and Machine-Learning-Enabled Optimization

Author

Thuriot-Roukos, Joëlle, primary, Ferraz, Camila Palombo, additional, K. Al Rawas, Hisham, additional, Heyte, Svetlana, additional, Paul, Sébastien, additional, Itabaiana Jr, Ivaldo, additional, Pietrowski, Mariusz, additional, Zieliński, Michal, additional, Ghazzal, Mohammed N., additional, Dumeignil, Franck, additional, and Wojcieszak, Robert, additional

Published
2023
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4. Efficient Promoters and Reaction Paths in the CO2 Hydrogenation to Light Olefins over Zirconia-Supported Iron Catalysts

Author

Barrios, Alan J., primary, Peron, Deizi V., additional, Chakkingal, Anoop, additional, Dugulan, Achim Iulian, additional, Moldovan, Simona, additional, Nakouri, Kalthoum, additional, Thuriot-Roukos, Joëlle, additional, Wojcieszak, Robert, additional, Thybaut, Joris W., additional, Virginie, Mirella, additional, and Khodakov, Andrei Y., additional

Published
2022
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8. Carbon-based catalysts for Fischer–Tropsch synthesis

Author

Ordomsky, Vitaly, Wang, Qiyan, Zhou, Wen-Juan, Heyte, Svetlana, Thuriot-Roukos, Joëlle, Marinova, Maya, Addad, Ahmed, Rouzière, Stéphan, Simon, Pardis, Capron, Mickael, Zhang, Linjie, Grimaud, Alexis, Schwiedernoch, Renate, Hernández, Willinton Yesid, Naghavi, Negar, Pedrolo, Débora, Schwaab, Marcio, Marcilio, Nilson, Khodakov, Andrei, Santos, Sara, Urbina-Blanco, César, Zhou, Wenjuan, Yang, Yong, Joelle, Thuriot-Roukos, Ersen, Ovidiu, Baaziz, Walid, Safonova, Olga, Saeys, Mark, Gu, Bang, Peron, Deizi, Barrios, Alan, Virginie, Mirella, La Fontaine, Camille, Briois, Valérie, Vorokhta, Mykhailo, Šmíd, Břetislav, Moldovan, Simona, Koneti, Siddardha, Gambu, Thobani, Hernández, Willinton, Impéror-Clerc, Marianne, Vovk, Evgeny, Wu, Dan, Nuns, Nicolas, Palčić, Ana, Jaén, Sara Navarro, Cai, Mengdie, Liu, Chong, Pidko, Evgeny, Valtchev, Valentin, Yan, Zhen, Zhang, Songwei, Li, Jerry Pui Ho, Zhao, Jingpeng, Yuan, Biao, He, Tao, Yu, Yi, Li, Tao, Hu, Di, Chen, Yanping, Wei, Jiatong, Duyar, Melis, Liu, Jian, Dalian Institute of Chemical Physics - Chinese Academy of Sciences, University of Surrey (UNIS), Unité de Catalyse et Chimie du Solide - UMR 8181 (UCCS), Université d'Artois (UA)-Centrale Lille-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS), ANR-16-CE06-0013,NANO4FuT,Synthèse des carburants alternatifs et des molécules plateforme sur nanoréacteurs(2016), CNRS, Centrale Lille, ENSCL, Univ. Artois, Université de Lille, Unité de Catalyse et Chimie du Solide (UCCS) - UMR 8181, Ordomsky, Vitaly, Centrale Lille Institut (CLIL)-Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, Eco-Efficient Products &Processes Laboratory (E2PL2), Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-RHODIA, Laboratoire de Chimie - UMR5182 (LC), Centre National de la Recherche Scientifique (CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon)-Institut de Chimie du CNRS (INC), Institut Michel Eugène Chevreul - FR 2638 (IMEC), Université d'Artois (UA)-Institut de Chimie du CNRS (INC)-Université de Lille-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Centrale Lille Institut (CLIL), Unité Matériaux et Transformations - UMR 8207 (UMET), Institut de Chimie du CNRS (INC)-Institut National de la Recherche Agronomique (INRA)-Centre National de la Recherche Scientifique (CNRS)-Université de Lille-Ecole Nationale Supérieure de Chimie de Lille (ENSCL), Laboratoire de Physique des Solides (LPS), Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Chimie du solide et de l'énergie (CSE), Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Solvay (France), Instituto Federal do Rio Grande do Sul (IFRS), Institut de Physique et Chimie des Matériaux de Strasbourg (IPCMS), Université de Strasbourg (UNISTRA)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA), Institut de chimie et procédés pour l'énergie, l'environnement et la santé (ICPEES), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), Paul Scherrer Institute (PSI), Synchrotron SOLEIL (SSOLEIL), Centre National de la Recherche Scientifique (CNRS), Charles University [Prague] (CU), Groupe de physique des matériaux (GPM), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences appliquées Rouen Normandie (INSA Rouen Normandie), Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Institut National des Sciences Appliquées (INSA)-Normandie Université (NU)-Université de Rouen Normandie (UNIROUEN), Normandie Université (NU), Ruđer Bošković Institute (IRB), Delft University of Technology (TU Delft), Laboratoire catalyse et spectrochimie (LCS), Centre National de la Recherche Scientifique (CNRS)-École Nationale Supérieure d'Ingénieurs de Caen (ENSICAEN), Normandie Université (NU)-Normandie Université (NU)-Institut de Chimie du CNRS (INC)-Université de Caen Normandie (UNICAEN), ShanghaiTech University [Shanghai], Beihang University (BUAA), School of Physics Science and Engineering, Tongji University, Université de Strasbourg (UNISTRA)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Réseau nanophotonique et optique, Université de Strasbourg (UNISTRA)-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS)-Matériaux et nanosciences d'Alsace (FMNGE), Institut de Chimie du CNRS (INC)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS)-Université de Strasbourg (UNISTRA)-Université de Haute-Alsace (UHA) Mulhouse - Colmar (Université de Haute-Alsace (UHA))-Institut National de la Santé et de la Recherche Médicale (INSERM)-Centre National de la Recherche Scientifique (CNRS), Université d'Artois (UA)-Centrale Lille-Centre National de la Recherche Scientifique (CNRS)-Institut de Chimie du CNRS (INC)-Université de Lille, Eco-Efficient Products & Processes Laboratory (E2P2L), RHODIA-Institut de Chimie du CNRS (INC)-Centre National de la Recherche Scientifique (CNRS), and Centre National de la Recherche Scientifique (CNRS)-Collège de France (CdF (institution))-Institut de Chimie du CNRS (INC)-Sorbonne Université (SU)

Subjects
Materials science, chemistry.chemical_element, 02 engineering and technology, Carbon nanotube, 010402 general chemistry, 01 natural sciences, 7. Clean energy, law.invention, Catalysis, law, [CHIM] Chemical Sciences, medicine, [CHIM]Chemical Sciences, Coal, Gasoline, Carbon nanofiber, business.industry, Fischer–Tropsch process, General Chemistry, 021001 nanoscience & nanotechnology, 0104 chemical sciences, Chemical engineering, chemistry, 0210 nano-technology, business, Carbon, Activated carbon, medicine.drug
Abstract

International audience; Fischer-Tropsch synthesis (FTS) is an essential approach to convert coal, biomass, and shale gas into fuels and chemicals, such as lower olefins, gasoline, diesel, and so on. In recent years, there has been increasing motivation to deploy FTS at commercial scales which has been boosting the discovery of high performance catalysts. In particular, the importance of support in modulating the activity of metals has been recognized and carbonaceous materials have attracted attention as supports for FTS. In this review, we summarised the substantial progress in the preparation of carbon-based catalysts for FTS by applying activated carbon (AC), carbon nanotubes (CNTs), carbon nanofibers (CNFs), carbon spheres (CSs), and metal-organic frameworks (MOFs) derived carbonaceous materials as supports. A general assessment of carbon-based catalysts for FTS, concerning the support and metal properties, activity and products selectivity, and their interactions is systematically discussed. Finally, current challenges and future trends in the development of carbon-based catalysts for commercial utilization in FTS are proposed.

Published
2021

11. Hybrid monometallic and bimetallic copper–palladium zeolite catalysts for direct synthesis of dimethyl ether from CO2.

Author

Navarro-Jaén, Sara, Virginie, Mirella, Morin, Jean-Charles, Thuriot-Roukos, Joëlle, Wojcieszak, Robert, and Khodakov, Andrei Y.

Subjects
ZEOLITE catalysts, METHYL ether, CATALYST synthesis, ETHER synthesis, ATMOSPHERIC carbon dioxide, BIMETALLIC catalysts
Abstract

Currently, carbon dioxide in the atmosphere is the major contributor toward global climate change. Direct CO2 hydrogenation to dimethyl ether produces an important platform molecule for the synthesis of fuels and chemicals and at the same time, utilizes large amounts of this greenhouse gas. In this paper, we prepared a series of hybrid catalysts, which are composed of alumina supported copper–palladium nanoparticles and HZSM-5 zeolite for the direct synthesis of dimethyl ether from CO2. Copper active sites showed a higher intrinsic activity for CO2 hydrogenation compared to palladium. The low palladium content in the copper–palladium bimetallic catalysts was particularly beneficial for the dimethyl ether production. Undesirable methane and ethane production was completely suppressed, while the dimethyl ether selectivity was considerably increased. Extensive catalyst characterization combined with catalytic measurements was indicative of the presence of copper and palladium monometallic and bimetallic particles with different sizes and reducibility in the hybrid catalysts. The presence of even small amounts of palladium significantly improved copper reducibility and copper dispersion. Some decrease in the Brønsted acidity in the copper containing catalysts was due to the migration of unreduced copper ions in the zeolite channels during the reduction. The methanol dehydration to dimethyl ether was only slightly affected by the amounts of Brønsted acid sites in the hybrid catalysts. [ABSTRACT FROM AUTHOR]

Published
2022
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12. Structure–performance correlations in the hybrid oxide-supported copper–zinc SAPO-34 catalysts for direct synthesis of dimethyl ether from CO2.

Author

Navarro-Jaén, Sara, Virginie, Mirella, Thuriot-Roukos, Joëlle, Wojcieszak, Robert, and Khodakov, Andrei Y.

Subjects
ETHER synthesis, CATALYST synthesis, METHYL ether, CATALYST supports, ZINC catalysts, CATALYTIC hydrogenation, HYDROGEN as fuel
Abstract

Growing CO2 emissions lead to global warming, which is currently one of the most challenging environmental phenomena. Direct catalytic hydrogenation to dimethyl ether over hybrid catalysts enables CO2 utilization, hydrogen and energy storage and produces sustainable fuels and an important platform molecule. In this paper, we evaluated structure–performance correlations in the bifunctional hybrid copper–zinc SAPO-34 catalysts for direct synthesis of dimethyl ether via CO2 prepared using zirconia, alumina and ceria used as oxide carriers. Higher copper dispersion and higher CO2 conversion rate were uncovered over the alumina and zirconia supported catalysts followed by ceria supported counterpart. The CO2 hydrogenation seems to be principally favoured by higher copper dispersion and to a lesser extent depends on the concentration of Bronsted acid sites in the studied catalysts. Because of lower reverse water gas-shift activity, the alumina supported catalyst exhibited a higher dimethyl ether yield compared to the zirconia and ceria supported counterparts. [ABSTRACT FROM AUTHOR]

Published
2022
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14. 5-Hydroxymethylfurfural and Furfural Base-Free Oxidation over AuPd Embedded Bimetallic Nanoparticles

Author

P. Ferraz, Camila, primary, Costa, Natalia J. S., additional, Teixeira-Neto, Erico, additional, Teixeira-Neto, Ângela A., additional, Liria, Cleber W., additional, Thuriot-Roukos, Joëlle, additional, Machini, M. Teresa, additional, Froidevaux, Rénato, additional, Dumeignil, Franck, additional, Rossi, Liane M., additional, and Wojcieszak, Robert, additional

Published
2020
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16. Study of the Direct CO 2 Carboxylation Reaction on Supported Metal Nanoparticles.

Author

Drault, Fabien, Snoussi, Youssef, Thuriot-Roukos, Joëlle, Itabaiana Jr., Ivaldo, Paul, Sébastien, Wojcieszak, Robert, and Hermans, Sophie

Subjects
METAL nanoparticles, CARBON dioxide, CARBOXYLATION, HETEROGENEOUS catalysts, POLYMERIZATION, FUSED salts, MATRIX-assisted laser desorption-ionization, MAGNETIC nanoparticles
Abstract

2,5-furandicarboxylic acid (2,5-FDCA) is a biomass derivate of high importance that is used as a building block in the synthesis of green polymers such as poly(ethylene furandicarboxylate) (PEF). PEF is presumed to be an ideal substitute for the predominant polymer in industry, the poly(ethylene terephthalate) (PET). Current routes for 2,5-FDCA synthesis require 5-hydroxymethylfurfural (HMF) as a reactant, which generates undesirable co-products due to the complicated oxidation step. Therefore, direct CO2 carboxylation of furoic acid salts (FA, produced from furfural, derivate of inedible lignocellulosic biomass) to 2,5-FDCA is potentially a good alternative. Herein, we present the primary results obtained on the carboxylation reaction of potassium 2-furoate (K2F) to synthesize 2,5-FDCA, using heterogeneous catalysts. An experimental setup was firstly validated, and then several operation conditions were optimized, using heterogeneous catalysts instead of the semi-heterogeneous counterparts (molten salts). Ag/SiO2 catalyst showed interesting results regarding the K2F conversion and space–time yield of 2,5-FDCA. [ABSTRACT FROM AUTHOR]

Published
2021
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17. Structure–performance correlations in the hybrid oxide-supported copper–zinc SAPO-34 catalysts for direct synthesis of dimethyl ether from CO2.

Author

Navarro-Jaén, Sara, Virginie, Mirella, Thuriot-Roukos, Joëlle, Wojcieszak, Robert, and Khodakov, Andrei Y.

Subjects
*ETHER synthesis, *CATALYST synthesis, *METHYL ether, *CATALYST supports, *ZINC catalysts, *CATALYTIC hydrogenation, *HYDROGEN as fuel
Abstract

Growing CO2 emissions lead to global warming, which is currently one of the most challenging environmental phenomena. Direct catalytic hydrogenation to dimethyl ether over hybrid catalysts enables CO2 utilization, hydrogen and energy storage and produces sustainable fuels and an important platform molecule. In this paper, we evaluated structure–performance correlations in the bifunctional hybrid copper–zinc SAPO-34 catalysts for direct synthesis of dimethyl ether via CO2 prepared using zirconia, alumina and ceria used as oxide carriers. Higher copper dispersion and higher CO2 conversion rate were uncovered over the alumina and zirconia supported catalysts followed by ceria supported counterpart. The CO2 hydrogenation seems to be principally favoured by higher copper dispersion and to a lesser extent depends on the concentration of Bronsted acid sites in the studied catalysts. Because of lower reverse water gas-shift activity, the alumina supported catalyst exhibited a higher dimethyl ether yield compared to the zirconia and ceria supported counterparts. [ABSTRACT FROM AUTHOR]

Published
2022
Full Text
View/download PDF

18. Hybrid monometallic and bimetallic copper–palladium zeolite catalysts for direct synthesis of dimethyl ether from CO2.

Author

Navarro-Jaén, Sara, Virginie, Mirella, Morin, Jean-Charles, Thuriot-Roukos, Joëlle, Wojcieszak, Robert, and Khodakov, Andrei Y.

Subjects
*ZEOLITE catalysts, *METHYL ether, *CATALYST synthesis, *ETHER synthesis, *ATMOSPHERIC carbon dioxide, *BIMETALLIC catalysts
Abstract

Currently, carbon dioxide in the atmosphere is the major contributor toward global climate change. Direct CO2 hydrogenation to dimethyl ether produces an important platform molecule for the synthesis of fuels and chemicals and at the same time, utilizes large amounts of this greenhouse gas. In this paper, we prepared a series of hybrid catalysts, which are composed of alumina supported copper–palladium nanoparticles and HZSM-5 zeolite for the direct synthesis of dimethyl ether from CO2. Copper active sites showed a higher intrinsic activity for CO2 hydrogenation compared to palladium. The low palladium content in the copper–palladium bimetallic catalysts was particularly beneficial for the dimethyl ether production. Undesirable methane and ethane production was completely suppressed, while the dimethyl ether selectivity was considerably increased. Extensive catalyst characterization combined with catalytic measurements was indicative of the presence of copper and palladium monometallic and bimetallic particles with different sizes and reducibility in the hybrid catalysts. The presence of even small amounts of palladium significantly improved copper reducibility and copper dispersion. Some decrease in the Brønsted acidity in the copper containing catalysts was due to the migration of unreduced copper ions in the zeolite channels during the reduction. The methanol dehydration to dimethyl ether was only slightly affected by the amounts of Brønsted acid sites in the hybrid catalysts. [ABSTRACT FROM AUTHOR]

Published
2022
Full Text
View/download PDF

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