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Quantum droplets are formed in quantum many-body systems when the competition of quantum corrections with the mean-field interaction yields a stable self-bound quantum liquid. We predict the emergence of a quantum droplet when a Bose-Einstein condensate is placed in an optical resonator with transverse pumping. The strong coupling between the atoms and the cavity mode induces long-range interactions in the atoms and a roton mode for negative cavity detuning emerges. Using a Bogoliubov theory, we show that the roton mode competes with the repulsive atomic $s$-wave scattering. Due to the favorable scaling of the quantum fluctuations with respect to the volume, a self-bound stable quantum liquid emerges., Comment: 6 pages, 2 figures more...

We investigate a dilute Bose gas with both a short-range contact and an effective long-range interaction between the atoms. The latter is induced by the strong coupling to a cavity light mode and is spatially characterized by a periodic signature and a tunable envelope rooted in the pumping of the cavity. We formulate a Bogoliubov theory which is based on a homogeneous mean-field description and quantum fluctuations around it. We find that the repulsive mean-field contact interaction could be destabilized by quantum fluctuation corrections rooting in the long-range interaction. The competition between both allows for the formation of self-bound quantum droplets. This generic approach is applied to two cavity setups without and with a momentum-conserving effective long-range interaction between the atoms in the form of a driven dispersive cavity mode and a multimode cavity, respectively. For both cases we show analytically how the size and the central density of the cavity-induced quantum droplets depend on the contact interaction strength and on the shape of the spatial envelope of the long-range interaction., Comment: 16 pages, 8 figures more...

The texture in antiferromagnets hosting a topologically protected skyrmion can be viewed as two effectively coupled ferromagnetic skyrmions. Assuming rigid magnetic configurations, we show that this coupling results in an effective mass of the antiferromagnetic skyrmion and that its dynamics can be viewed as due to a relative displacement of the two sublattice ferromagnetic skyrmions. The theory holds for different antiferromagnetic systems and includes effects from dissipation and external forces caused by electric currents. We verify our analytical results by micromagnetic simulations. more...

Easy-plane quantum magnets are strikingly similar to superconductors, allowing for spin supercurrent and an effective superconducting phase stemming from their $U(1)$ rotation symmetry around the $z$-axis. We uncover a generalized fractional Josephson effect with a periodicity that increases linearly with system size in one-dimensional spin-$1/2$ chains at selected anisotropies and phase-fixing boundary fields. The effect combines arbitrary integer periodicities in a single system, exceeding the $4\pi $ and $8\pi $ periodicity of superconducting Josephson effects of Majorana zero modes and other exotic quasiparticles. We reveal a universal energy-phase relation and connect the effect to the recently discovered phantom helices., Comment: 11 pages, 5 figures, 2 ancillary videos more...

We report on a nonequilibrium quantum phase transition (NQPT) in a hybrid quantum many-body system consisting of a vibrational mode of a damped nanomembrane interacting optomechanically with a cavity, whose output light couples to two internal states of an ultracold Bose gas held in an external quasi-one-dimensional box potential. For small effective membrane-atom couplings, the system is in a homogeneous Bose-Einstein condensate (BEC) steady state, with no membrane displacement. Depending on the transition frequency between the two internal atomic states, either one or both internal states are occupied. By increasing the atom-membrane couplings, the system transitions to a symmetry-broken self-organized BEC phase, which is characterized by a considerably displaced membrane steady-state and density-wave-like BEC profiles. This NQPT can be both discontinuous and continuous for a certain interval of transition frequencies and is purely discontinuous outside of it., Comment: 12 pages, 7 figures more...

Photosystem II (PSII) reaction center is a unique protein-chromophore complex that is capable of efficiently separating electronic charges across the membrane after photoexcitation. In the PSII reaction center, the primary energy- and charge-transfer (CT) processes occur on comparable ultrafast timescales, which makes it extremely challenging to understand the fundamental mechanism responsible for the near-unity quantum efficiency of the transfer. Here, we elucidate the role of quantum coherences in the ultrafast energy and CT in the PSII reaction center by performing two-dimensional (2D) electronic spectroscopy at the cryogenic temperature of 20 K, which captures the distinct underlying quantum coherences. Specifically, we uncover the electronic and vibrational coherences along with their lifetimes during the primary ultrafast processes of energy and CT. We also examine the functional role of the observed quantum coherences. To gather further insight, we construct a structure-based excitonic model that provided evidence for coherent energy and CT at low temperature in the 2D electronic spectra. The principles, uncovered by this combination of experimental and theoretical analyses, could provide valuable guidelines for creating artificial photosystems with exploitation of system-bath coupling and control of coherences to optimize the photon conversion efficiency to specific functions. more...

We show that a Skyrmion in a classical bipartite antiferromagnetic lattice can be spatially displaced in a controlled manner by externally applied spin waves. We reveal the relation between the Skyrmion motion and the spin wave properties. To this end, we derive a classical spin wave formalism which is tailored to the antiferromagnetic two-dimensional square lattice. The antiferromagnetic spin waves can be classified into two types with respect to their polarization, with two modes each. The circularly polarized spin waves oscillate with different amplitudes in the respective sublattices and induce a Skyrmion Hall effect. The two modes are symmetric under sublattices exchange and determine the overall sign of the Hall angle. Linearly polarized spin waves oscillate elliptically, however, with the same amplitude on each sublattice. These accelerate the Skyrmion solely into their own propagation direction. The two modes are symmetric under component x-y exchange and impact Bloch- or N\'eel Skyrmions differently. Our results indicate possible technical applications of spin-wave driven Skyrmion motion. As one example we propose a racetrack where spin waves pump Skyrmions along the track in antiferromagnets. more...

Dephasing in quantum systems is typically the result of its interaction with environmental degrees of freedom. We investigate within a spin-boson model the influence of a super-Ohmic environment on the dynamics of a quantum two-state system. A super-Ohmic enviroment, thereby, models typical bulk phonons which are a common disturbance for solid state quantum systems as, for example, NV centers. By applying the numerically exact quasi-adiabatic path integral approach we show that for strong system-bath coupling, pseudo-coherent dynamics emerges, i.e., oscillatory dynamics at short times due to slaving of the quantum system to the bath dynamics. We extend the phase diagram known for sub-Ohmic and Ohmic environments into the super-Ohmic regime and observe a pronounced non-monotonous behaviour. Super-Ohmic purely dephasing fluctuations strongly suppress the amplitude of coherent dynamics at very short times with no subsequent further decay at later times. Nevertheless, they render the dynamics overdamped. The according phase separation line shows also a non-monotonous behaviour, very similar to the pseudo-coherent dynamics., Comment: 5 pages, 3 figures more...

A quantum two-level system immersed in a sub-Ohmic bath experiences enhanced low-frequency quantum statistical fluctuations which render the nonequilibrium quantum dynamics highly non-Markovian. Upon using the numerically exact time-evolving matrix product operator approach, we investigate the phase diagram of the polarization dynamics. In addition to the known phases of damped coherent oscillatory dynamics and overdamped decay, we identify a new third region in the phase diagram for strong coupling showing an aperiodic behaviour. We determine the corresponding phase boundaries. The dynamics of the quantum two-state system herein is not coherent by itself but slaved to the oscillatory bath dynamics. more...

We develop a microscopic theory for the two-dimensional spectroscopy of one-dimensional topological superconductors. We consider a ring geometry as a realization of the Kitaev chain with periodic boundary conditions. We show numerically and analytically that the cross-peak structure of the 2D spectra carries unique signatures of the topological phases of the chain. Our work reveals how 2D spectroscopy can identify topological phases in bulk properties, bypassing energy-specific differences caused by topologically protected or trivial boundary modes that are otherwise hard to distinguish., Comment: 16 pages, 10 figures more...

When a hydrophilic solute in water is suddenly turned into a hydrophobic species, for instance, by photoionization, a layer of hydrated water molecules forms around the solute on a time scale of a few picoseconds. We study the dynamic build-up of the hydration shell around a hydrophobic solute on the basis of a time-dependent dielectric continuum model. Information about the solvent is spectroscopically extracted from the relaxation dynamics of a test dipole inside a static Onsager sphere in the nonequilibrium solvent. The growth process is described phenomenologically within two approaches. First, we consider a time-dependent thickness of the hydration layer which grows from zero to a finite value over a finite time. Second, we assume a time-dependent complex permittivity within a finite layer region around the Onsager sphere. The layer is modeled as a continuous dielectric with a much slower fluctuation dynamics. We find a time-dependent frequency shift down to the blue of the resonant absorption of the dipole, together with a dynamically decreasing line width, as compared to bulk water. The blue shift reflects the work performed against the hydrogen bonded network of the bulk solvent and is a directly measurable quantity. Our results are in agreement with an experiment on the hydrophobic solvation of iodine in water. more...

Magnetic skyrmions and their anti-particles, the antiskyrmions, are stable magnetic solitons existing down to the nanometer scale. Their stability and size as well as the possibility to propel them by, e.g., electric currents make them promising candidates for the use in memory devices, such as racetrack memories. Skyrmions and antiskyrmions share those same advantages individually, but may annihilate each other when they coexist in the same device. Yet, combining them to represent logical bits of 0 (skyrmion) and 1 (antiskyrmion) in one device opens new possibilities to create new types of densely packed racetrack memory devices. For this, a controlled creation and annihilation procedure, i.e., a writing or deletion operation, is necessary. Here, we propose a method to create arbitrary sequences of coexisting skyrmions and antiskyrmions by rotations of the magnetic moments at the edge of a rectangular slab. The skyrmions and antiskyrmions remain stable and do not annihilate each other. more...

We study the creation of quantum skyrmions in quadratic nanoscopic lattices of quantum spins coupled by Dzyaloshinkii-Moriya and exchange interactions. We numerically show that different kinds of quantum skyrmions, characterized by the magnitude of their spin expectation values and strong differences in their stability, can appear as ground state and as metastable excitations. In dependence on the coupling strengths and the lattice size, an adiabatic rotation scheme of the magnetization at the lattice boundaries allows for a controlled creation of quantum skyrmions. more...

In the primary step of light-harvesting, the energy of a photon is captured in antenna chlorophyll as an exciton. Its efficient conversion to stored chemical potential occurs in the special pair reaction center, which has to be reached by down-hill ultrafast excited state energy transport. The interaction between the chromophores leads to spatial delocalization and quantum coherence effects, the importance of which depends on the coupling between the chlorophylls in relation to the intensity of the fluctuations and reorganization dynamics of the protein matrix, or bath. The latter induce uncorrelated modulations of the site energies, and thus quantum decoherence, and localization of the exciton. Current consensus is that under physiological conditions quantum decoherence occurs on the 10 fs time scale, and quantum coherence plays little role for the observed picosecond energy transfer dynamics. In this work, we reaffirm this from a different point of view by finding that the true onset of electronic quantum coherence only occurs at extremely low temperatures of ~20 K. We have directly determined the exciton coherence times by two-dimensional electronic spectroscopy of the Fenna-Matthew-Olson complex over an extensive temperature range with a supporting theoretical modelling. At 20 K, electronic coherences persist out to 200 fs (close to the antenna) and marginally up to 500 fs at the reaction-center side. It decays markedly faster with modest increases in temperature to become irrelevant above 150 K. This temperature dependence also allows disentangling the previously reported long-lived beatings. We show that they result from mixing vibrational coherences in the electronic ground state ... more...

Braiding Majorana zero-modes around each other is a promising route towards topological quantum computing. Yet, two competing maxims emerge when implementing Majorana braiding in real systems: On the one hand, perfect braiding should be conducted adiabatically slowly to avoid non-topological errors. On the other hand, braiding must be conducted fast such that decoherence effects introduced by the environment are negligible, which are generally unavoidable in finite-size systems. This competition results in an intermediate time scale for Majorana braiding that is optimal, but generally not error-free. Here, we calculate this intermediate time scale for a T-junction of short one-dimensional topological superconductors coupled to a bosonic bath that generates fluctuations in the local electric potential, which stem from, e.g., environmental photons or phonons of the substrate. We thereby obtain boundaries for the speed of Majorana braiding with a predetermined gate fidelity. Our results emphasize the general susceptibility of Majorana-based information storage in finite-size systems and can serve as a guide for determining the optimal braiding times in future experiments., Comment: 13 pages, 4 figures more...

Topologically distinct magnetic structures like skyrmions, domain walls, and the uniformly magnetized state have multiple applications in logic devices, sensors, and as bits of information. One of the most promising concepts for applying these bits is the racetrack architecture controlled by electric currents or magnetic driving fields. In state-of-the-art racetracks, these fields or currents are applied to the whole circuit. Here, we employ micromagnetic and atomistic simulations to establish a concept for racetrack memories free of global driving forces. Surprisingly, we realize that mixed sequences of topologically distinct objects can be created and propagated over far distances exclusively by local rotation of magnetization at the sample boundaries. We reveal the dependence between the chirality of the rotation and the direction of propagation and define the phase space where the proposed procedure can be realized. The advantages of this approach are the exclusion of high current and field densities as well as its compatibility with an energy-efficient three-dimensional design., Comment: 23 pages, 7 figures more...

The time-dependent fluorescence Stokes shifts monitors the relaxation of the polarization of a polar solvent in the surroundings of a photoexcited solute molecule, but also the structural variation of the solute following photoexcitation and the subsequent molecular charge redistribution. Here, we formulate a simple nonequilibrium quantum theory of solvation for an explicitly time-dependent continuous solvent. The time-dependent solvent induces nonequilibrium fluctuations on the solvent dynamics which are directly reflected in different time components in the time-dependent Stokes shift. We illustrate the structural dynamics in the presence of an explicitly time-dependent solvent by the example of a dynamically shrinking solute which leads to a bi-modal Stokes shift. Interestingly, both contributions are mutually coupled. Furthermore, we can explain a prominent long-tail decay of the Stokes shift associated to slow structural dynamical variations. more...

Organic-inorganic perovskites have shown great promise towards their application in optoelectronics. The success of this class of material is dictated by the complex interplay between various underlying microscopic phenomena. The structural dynamics of organic cations and the inorganic sublattice after photoexcitation is hypothesized to have a direct effect on the material properties, thereby affecting the overall device performance. Here, we use two-dimensional (2D) electronic spectroscopy to reveal impulsively excited vibrational modes of methylammonium (MA) lead iodide perovskite, which drive the structural distortion after photoexcitation. The vibrational analysis of the measured data allows us to directly monitor the time evolution of the librational motion of the MA cation along with the vibrational coherences of inorganic sublattice. Wavelet analysis of the observed vibrational coherences uncovers the interplay between these two types of phonons. It reveals the coherent generation of the librational motion of the MA cation within ~300 fs, which is complemented by the coherent evolution of the skeletal motion of the inorganic sublattice. We have employed time-dependent density functional theory (TDDFT) to study the atomic motion of the MA cation and the inorganic sublattice during the process of photoexcitation. The TDDFT calculations support our experimental observations of the coherent generation of librational motions in the MA cation and highlight the importance of the anharmonic interaction between the MA cation and the inorganic sublattice. Our calculations predict the transfer of the photoinduced vibrational coherence from the MA cation to the inorganic sublattice, which drives the skeleton motion to form a polaronic state leading to long lifetimes of the charge carriers. This work may lead to novel design principles for next generation of solar cell materials. more...

Molecular conduction operating in dielectric solvent environments are often described using kinetic rates based on Marcus theory of electron transfer at a molecule-metal electrode interface. However, the successive nature of charge transfer in such system implies that the solvent does not necessarily reach equilibrium in such process. Here we generalize the theory to account for solvent nonequilibrium and consider a molecular junction consisting of an electronic donor-acceptor system coupled to two metallic electrodes and placed in a polarizable solvent. We determine the nonequilbrium distribution of the solvent by solving diffusion equations in the strong- and weak-friction limits and calculate the charge current and its fluctuating behavior. In extreme limits: the absence of the solvent or fast solvent relaxation, the charge transfer statistics is Poissonian, while it becomes correlated by the dynamic solvent in between these limits. A Kramers-like turnover of the nonequilibrium current as a function of the solvent damping is found. Finally, we propose a way to tune the solvent-induced damping using geometrical control of the solvent dielectric response in nanostructured solvent channels. more...

Singlet fission is a spin-allowed exciton multiplication process in organic semiconductors that converts one spin-singlet exciton to two triplet excitons. It offers the potential to enhance solar energy conversion by circumventing the Shockley-Queisser limit on efficiency. Recently, the mechanism of the primary singlet fission process in pentacene and its derivatives have been extensively investigated, however, the nature of the primary ultrafast process in singlet fission is still a matter of debate. Here, we study the singlet fission process in a pentacene film by employing a combination of transient-grating (TG) and two-dimensional (2D) electronic spectroscopy complemented by quantum chemical and nonadiabatic dynamics calculations. The high sensitivity of heterodyne detected TG spectroscopy enabled us to capture the vibrational coherence and to show that it mediates the transition from the singlet excited electronic state to the triplet-pair state. This coherent process is further examined by 2D electronic spectroscopy. Detailed analysis of the experimental data reveals that significant vibronic couplings of a few key modes in the low- and high-frequency region connect the excited singlet and triplet-pair states. Based on quantum chemical calculations, we identify these key intermolecular rocking modes along the longitudinal molecular axis between the pentacene molecules. They play the essential role of an electronic bridge between the singlet and triplet-pair states. Along with high-frequency local vibrations acting as tuning modes, these rocking motions drive the ultrafast dynamics at the multidimensional conical intersection in the singlet fission process. more...

Abrikosov vortices in Fe-based superconductors are a promising platform for hosting Majorana zero modes. Their adiabatic exchange is a key ingredient for Majorana-based quantum computing. However, the adiabatic braiding process can not be realized in state-of-the-art experiments. We propose to replace the infinitely slow, long-path braiding by only slightly moving vortices in a special geometry without actually physically exchanging the Majoranas, like a Majorana carousel. Although the resulting finite-time gate is not topologically protected, it is robust against variations in material specific parameters and in the braiding-speed. We prove this analytically. Our results carry over to Y-junctions of Majorana wires. more...

The light-harvesting efficiency of a photoactive molecular complex is largely determined by the properties of its electronic quantum states. Those, in turn, are influenced by molecular vibrational states of the nuclear degrees of freedom. Here, we reexamine two recently formulated concepts that a coherent vibronic coupling between molecular states would either extend the electronic coherence lifetime or enhance the amplitude of the anticorrelated vibrational mode at longer times. For this, we study a vibronically coupled dimer and calculate the nonlinear two-dimensional (2D) electronic spectra which directly reveal electronic coherence. The timescale of electronic coherence is initially extracted by measuring the anti-diagonal bandwidth of the central peak in the 2D spectrum at zero waiting time. Based on the residual analysis, we identify small-amplitude long-lived oscillations in the cross-peaks, which, however, are solely due to groundstate vibrational coherence, regardless of having resonant or off-resonant conditions. Our studies neither show an enhancement of the electronic quantum coherence nor an enhancement of the anticorrelated vibrational mode by the vibronic coupling under ambient conditions. more...

In a hybrid atom-optomechanical system, the optical coupling of a mechanical mode of a nanomembrane in an optical cavity with a distant interacting atom gas permits highly non-classical quantum many-body states. We show that the mechanical mode can be squeezed by the back-action of internal excitations of the atoms in the gas. A Bogoliubov approach reveals that these internal excitations form a fluctuating environment of quasi-particle excitations for the mechanical mode with a gaped spectral density. Nanomechanical squeezing arises due to quasi-particle excitations in the interacting atom gas when the mechanical frequency is close to resonance with the internal atomic transitions. Interestingly, nanomechanical squeezing is enhanced by atom-atom interactions. more...

We show that a hybrid atom-optomechanical quantum many-body system with two internal atom states undergoes both first- and second-order nonequilibrium quantum phase transitions. A nanomembrane is placed in a pumped optical cavity, whose outcoupled light forms a lattice for an ultracold Bose gas. By changing the pump strength, the effective membrane-atom coupling can be tuned. Above a critical intensity, a symmetry-broken phase emerges which is characterized by a sizeable occupation of the high-energy internal states and a displaced membrane. The order of this nonequilibrium quantum phase transition can be changed by tuning the transition frequency. For a symmetric coupling, the transition is continuous below a certain transition frequency and discontinuous above. For an asymmetric coupling, a first-order phase transition occurs. more...

Magnetic domain walls can be moved by spin-polarized currents due to spin-transfer torques. This opens the possibility to use them in spintronic memory devices as, e.g., in racetrack storage. Naturally, in miniaturized devices domain walls can get very close to each other and affect each others dynamics. In this work we consider two separated domain walls in different layers which interact via an interlayer exchange coupling. One of these walls is moved by a spin-polarized current. Depending on several parameters as the current density, the interlayer coupling or the pinning potential, the combined dynamics of the two domain walls can change very strongly allowing, e.g., for a correlated motion of the walls. In addition, more subtle effect appear as a suppression of the Walker breakdown accompanied by an increase of the domain wall velocity. more...

A magnetic helix can be wound into a classical Heisenberg chain by fixing one end while rotating the other one. We show that in quantum Heisenberg chains \new{of finite length}, the magnetization slips back to the trivial state beyond a finite turning angle. Avoided level crossings thus undermine classical topological protection. Yet, for special values of the axial Heisenberg anisotropy, stable spin helices form again, which are non-locally entangled. Away from these sweet spots, spin helices can be stabilized dynamically or by dissipation. For half-integer spin chains of odd length, a spin slippage state and its Kramers partner define a qubit with a non-trivial Berry connection., Comment: 5 pages article, 5 pages Supplemental Material, 8 figures more...

We determine the frequency-dependent response characteristics of a quantum system to a driven Caldeira-Leggett bath. The bath degrees of freedom are explicitly driven by an external time-dependent force, in addition to the direct time-dependent forcing of the system itself. After general considerations of driven Caldeira-Leggett baths, we consider the Rubin model of a chain of quantum particles coupled by linear springs as an important model of a quantum dissipative system. We show that in the presence of time-dependent driving of the chain, this model can be mapped to a quantum system which couples to a driven Caldeira-Leggett bath. The effect of the bath driving is captured by a time-dependent force on the central system, which is, in principle, non-Markovian in nature. We study two specific examples, the exactly solvable case of a harmonic potential, and a quantum two-state system for which we assume a weak system-bath coupling. We evaluate the dynamical response to a periodic driving of the system and the bath. The dynamic susceptibility is shown to be altered qualitatively by the bath drive: The dispersive part is enhanced at low frequencies and acquires a maximum at zero frequency. The absorptive part develops a shoulder-like behavior in this frequency regime. These features seem to be generic for quantum systems in a driven Caldeira-Leggett bath., Comment: 11 pages, accepted for publication in Phys. Rev. E more...

We formulate a theory of nonequilibrium quantum solvation in which parameters of the solvent are explicitly depending on time. We assume in a simplest approach a spherical molecular Onsager cavity with a time-dependent radius. We analyze the relaxation properties of a test molecular point dipole in a dielectric solvent and consider two cases: (i) a shrinking Onsager sphere, and, (ii) a breathing Onsager sphere. Due to the time-dependent solvent, the frequency-dependent response function of the dipole becomes time-dependent. For a shrinking Onsager sphere, the dipole relaxation is in general enhanced. This is reflected in a temporally increasing line width of the absorptive part of the response. Furthermore, the effective frequency-dependent response function shows two peaks in the absorptive part which are symmetrically shifted around the eigenfrequency. In contrast, a breathing sphere reduces damping as compared to the static sphere. Interestingly, we find a non-monotonous dependence of the relaxation rate on the breathing rate and a resonant suppression of damping when both rates are comparable. Moreover, the line width of the absorptive part of the response function is strongly reduced for times when the breathing sphere reaches its maximal extension., Comment: 12 pages, 14 figures, Supplementary Material more...

We consider a hybrid quantum many-body system formed by both a vibrational mode of a nanomembrane, which interacts optomechanically with light in a cavity, and an ultracold atom gas in the optical lattice of the out-coupled light. After integrating over the light field, an effective Hamiltonian reveals a competition between the localizing potential force and the membrane displacement force. For increasing atom-membrane interaction we find a nonequilibrium quantum phase transition from a localized non-motional phase of the atom cloud to a phase of collective motion. Near the quantum critical point, the energy of the lowest collective excitation vanishes, while the order parameter of the condensate becomes non-zero in the symmetry-broken state. The effect occurs when the atoms and the membrane are non-resonantly coupled. more...

(Dated: July 17, 2017) We calculate the electric charge current flowing through a vibrating molecular nanojunction, which is driven by an ac voltage, in its regime of nonlinear oscillations. Without loss of generality, we model the junction by a vibrating molecule which is doubly clamped to two metallic leads which are biased by time-periodic ac voltages. Dressed-electron tunneling between the leads and the molecule drives the mechanical degree of freedom out of equilibrium. In the deep quantum regime, where only a few vibrational quanta are excited, the formation of coherent vibrational resonances affects the dressed-electron tunneling. In turn, back action modifies the electronic ac current passing through the junction. The concert of nonlinear vibrations and ac driving induces quantum transport currents which are antiresonant to the applied ac voltage. Quantum back action on the flowing nonequilibriun current allows us to obtain rather sharp spectroscopic information on the population of the mechanical vibrational states., Comment: 12 pages, 3 figures; replaced with accepted version more...

Magnetic skyrmions can be considered as topologically protected localized vortex-like spin textures. Due to their stability, their small size, and the possibility to move them by low electric currents they are promising candidates for spintronic devices. Without violating topological protection, it is possible to create skyrmion-antiskyrmion pairs, as long as the total charge remains unchanged. We derive a skyrmion equation of motion which reveals how spin-polarized charge currents create skyrmion-antiskyrmion pairs. It allows to identify general prerequisites for the pair creation process. We corroborate these general principles by numerical simulations. On a lattice, where topological protection becomes imperfect, the antiskyrmion partner of the pairs is annihilated and only the skyrmion survives. This eventually changes the total skyrmion number and yields a new way of creating and controlling skyrmions., Comment: Please find additional videos of the skyrmion-antiskyrmion pair creation process on the article's arXiv page. The videos can also be downloaded from the "other formats" section as a compressed file more...

During the first steps of photosynthesis, the energy of impinging solar photons is transformed into electronic excitation energy of the light-harvesting biomolecular complexes. The subsequent energy transfer to the reaction center is understood in terms of exciton quasiparticles which move on a grid of biomolecular sites on typical time scales less than 100 femtoseconds (fs). Since the early days of quantum mechanics, this energy transfer is described as an incoherent Forster hopping with classical site occupation probabilities, but with quantum mechanically determined rate constants. This orthodox picture has been challenged by ultrafast optical spectroscopy experiments with the Fenna-Matthews-Olson protein in which interference oscillatory signals up to 1.5 picoseconds were reported and interpreted as direct evidence of exceptionally long-lived electronic quantum coherence. Here, we show that the optical 2D photon echo spectra of this complex at ambient temperature in aqueous solution do not provide evidence of any long-lived electronic quantum coherence, but confirm the orthodox view of rapidly decaying electronic quantum coherence on a time scale of 60 fs. Our results give no hint that electronic quantum coherence plays any biofunctional role in real photoactive biomolecular complexes. Since this natural energy transfer complex is rather small and has a structurally well defined protein with the distances between bacteriochlorophylls being comparable to other light-harvesting complexes, we anticipate that this finding is general and directly applies to even larger photoactive biomolecular complexes. more...

We analyze the real-time dynamics of a quantum two-state system in the presence of nonequilibrium quantum fluctuations. The latter are generated by a coupling of the two-state system to a single electronic level of a quantum dot which carries a nonequilibrium tunneling current. We restrict to the sequential tunneling regime and calculate the dynamics of the two-state system, of the dot population, and of the nonequilibrium charge current on the basis of a diagrammatic perturbative method valid for a weak tunneling coupling. We find a nontrivial dependence of the relaxation and dephasing rates of the two-state system due to the nonequilibrium fluctuations which is directly linked to the structure of the unperturbed central system. In addition, a Heisenberg-Langevin-equation of motion allows us to calculate the correlation function of the nonequilibrium fluctuations. By this, we obtain a generalized nonequilibrium fluctuation relation which includes the equilibrium fluctuation-dissipation theorem. A straightforward extension to the case with a time-periodic ac voltage is shown. more...

In one spatial dimension, anyons in the original description of Leinaas and Myrheim are formally equivalent to locally interacting bosons described by the Lieb-Liniger model. This admits an interesting reinterpretation of interacting bosons in the context of anyons. We elaborate on this parallel, particularly including the many-body bound states from the attractive Lieb-Liniger model. In the anyonic context these bound states are created purely by quantum-statistical attraction and coined quantum-statistical condensate, which is more robust than the Bose-Einstein condensate. We introduce the second quantization formalism for the present anyons and construct the generalized Jordan-Wigner transformation that connects them to the bosons of the Lieb-Liniger model., Comment: 8 pages, 3 figures. Connection to the Lieb-Liniger model included, title changed compared to version 1 more...

When an open quantum system is driven by an external time-dependent force, the coupling of the driving to the central system is usually included whereas the impact of the driving field on the bath is neglected. We investigate the effect of a quantum bath of linearly driven harmonic oscillators on the relaxation dynamics of a quantum two-level system which itself is not directly driven. In particular, we calculate the frequency-dependent response of the system when the bath is subject to a Dirac and a Gaussian driving-pulse. We show that a time-retarded effective force on the system is induced by the driven bath which depends on the full history of the perturbation and the spectral characteristics of the underlying bath. In particular, when a structured Ohmic bath with a pronounced Lorentzian peak is considered, the dynamical response of the system to a driven bath is qualitatively different as compared to the undriven bath. Specifically, additional resonances appear which can be directly associated to a Jaynes-Cummings-like effective energy spectrum., Comment: 11 pages, 9 figures more...

We provide a general procedure to calculate the current-induced spin-transfer torque which acts on a general steep magnetic texture due to the exchange interaction with an applied spin-polarized current. As an example, we consider a one-dimensional ferromagnetic quantum wire and also include a Rashba spin-orbit interaction. The spin-transfer torque becomes generally spatially non-local. Likewise, the Rashba spin-orbit interaction induces a spatially nonlocal field-like nonequilibrium spin-transfer torque. We also find a spatially varying nonadiabaticity parameter and markedly different domain wall dynamics for very steep textures as compared to wide domain walls. more...

We combine the coherent modified Redfield theory (CMRT) with the equation of motion-phase matching approach (PMA) to calculate two-dimensional photon echo spectra for photoactive molecular complexes with an intermediate strength of the coupling to their environment. Both techniques are highly efficient, yet they involve approximations at different levels. By explicitly comparing with the numerically exact quasi-adiabatic path integral approach, we show for the Fenna-Matthews-Olson complex that the CMRT describes the decay rates in the population dynamics well, but final stationary populations and the oscillation frequencies differ slightly. In addition, we use the combined CMRT+PMA to calculate two-dimensional photon-echo spectra for a simple dimer model. We find excellent agreement with the exact path integral calculations at short waiting times where the dynamics is still coherent. For long waiting times, differences occur due to different final stationary states, specifically for strong system-bath coupling. For weak to intermediate system-bath couplings, which is most important for natural photosynthetic complexes, the combined CMRT+PMA gives reasonable results with acceptable computational efforts. more...

The macroscopic magnetic moment of a superparamagnetic system has to overcome an energy barrier in order to switch its direction. This barrier is formed by magnetic anisotropies in the material and may be surmounted typically after 10^9 to 10^12 attempts per second by thermal fluctuations. In a first step, the associated switching rate may be described by a Neel-Brown-Arrhenius law, in which the energy barrier is assumed as constant or a given temperature. Yet, magnetic anisotropies in general depend on temperature themselves which is known to modify the Neel-Brown-Arrhenius law. We illustrate quantitatively the implications of a temperature-dependent anisotropy on the switching rate and in particular for the interpretation of the prefactor as an attempt frequency. In particular, we show that realistic numbers for the attempt frequency are obtained when the temperature dependence of the anisotropy is taken into account., Comment: 15 pages, 5 figures more...

We investigate the nonlinear light-matter interaction of a Bose-Einstein condensate trapped in an external periodic potential inside an optical cavity which is weakly coupled to vacuum radiation modes and driven by a transverse pump field. Based on a generalized Bose-Hubbard model which incorporates a single cavity mode, we include the collective backaction of the atoms on the cavity light field and determine the nonequilibrium quantum phases within the nonperturbative bosonic dynamical mean-field theory.With the system parameters adapted to recent experiments, we find a quantum phase transition from a normal phase to a self-organized superfluid phase, which is related to the Hepp-Lieb-Dicke superradiance phase transition. For even stronger pumping, a self-organized Mott insulator phase arises., Comment: 5 pages, 4 figures. published version more...

We solve the two-particle s-wave scattering for an ultracold atom gas confined in a quasi-one-dimensional trapping potential which is periodically modulated. The interaction between the atoms is included in terms of Fermi's pseudopotential. For a modulated isotropic transverse harmonic confinement, the atomic center of mass and relative degrees of freedom decouple and an exact solution is possible. We use the Floquet approach to show that additional photon-assisted resonant scattering channels open up due to the harmonic modulation. Applying the Bethe-Peierls boundary condition, we obtain the general scattering solution of the time-dependent Schr\"odinger equation which is universal at low energies. The binding energies and the effective one-dimensional scattering length can be controlled by the external driving. more...

In conventional domain wall systems the aim of a high domain wall velocity may be hindered by the occurrence of a Walker breakdown at comparably low current density. We show how a Rashba interaction can stabilize the domain wall dynamics and thereby shift the Walker breakdown to higher current densities. The Rashba interaction creates a field like spin torque, which breaks the symmetry of the system and modifies the internal structure of the domain wall. Besides a shift of the Walker breakdown it can additionally induce a chirality switch of the domain wall at sufficient Rashba fields. The preferred chirality may then be chosen by the direction of the current flow. Both, the suppression of the Walker breakdown and the chirality switching, affect the domain wall velocity. This is even more pronounced for short current pulses, where an additional domain wall movement after the pulse in either positive or negative direction can determine the final position of the domain wall., Comment: 10 pages, 9 figures more...

We study the effects of spin-orbit interaction (SOI) on the current-induced motion of a magnetic (Bloch) domain wall in ultrathin ferromagnetic nanowires. The conspiracy of spin relaxation and SOI is shown to generate a novel strong nonequilibrium Rashba field, which is dominant even for moderate SOI. This field causes intricate spin precession and a transition from translatory to oscillatory wall dynamics with increasing SOI. We show that current pulses of different lengths can efficiently be used to control the domain wall motion., Comment: published version, minor modifications more...

We study the non-equilibrium dynamics of a spinful single-orbital quantum dot with an incorporated quantum mechanical spin-1/2 magnetic impurity. Due to the spin degeneracy, double occupancy is allowed, and Coulomb interaction together with the exchange coupling of the magnetic impurity influence the dynamics. By extending the iterative summation of real-time path integrals (ISPI) to this coupled system, we monitor the time-dependent non-equilibrium current and the impurity spin polarization to determine features of the time-dependent non-equilibrium dynamics. We particulary focus on the deep quantum regime, where all time and energy scales are of the same order of magnitude and no small parameter is available. We observe a significant influence of the non-equilibrium decay of the impurity spin polarization both in the presence and in the absence of Coulomb interaction. The exponential relaxation is faster for larger bias voltages, electron-impurity interactions and temperatures. We show that the exact relaxation rate deviates from the corresponding perturbative result. In addition, we study in detail the impurity's back action on the charge current and find a reduction of the stationary current for increasing coupling to the impurity. Moreover, our approach allows us to systematically distinguish mean-field Coulomb and impurity effects from the influence of quantum fluctuations and flip-flop scattering, respectively. In fact, we find a local maximum of the current for a finite Coulomb interaction due to the presence of the impurity., Comment: 32 pages, 15 figures more...

We present numerically exact results for the quantum coherent energy transfer in the Fenna-Matthews-Olson molecular aggregate under realistic physiological conditions, including vibrational fluctuations of the protein and the pigments for an experimentally determined fluctuation spectrum. We find coherence times shorter than observed experimentally. Furthermore we determine the energy transfer current and quantify its "quantumness" as the distance of the density matrix to the classical pointer states for the energy current operator. Most importantly, we find that the energy transfer happens through a "Schr\"odinger-cat" like superposition of energy current pointer states., Comment: enlarged and final version, 7 pages, 5 figures more...

We study Landau-Zener transitions in a dissipative environment by means of the numerically exact quasiadiabatic propagator path-integral. It allows to cover the full range of the involved parameters. We discover a nonmonotonic dependence of the transition probability on the sweep velocity which is explained in terms of a simple phenomenological model. This feature, not captured by perturbative approaches, results from a nontrivial competition between relaxation and the external sweep., Comment: 4 pages, 5 figures; published version (minor changes) more...