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Context. The spectra of fast-rotating A-type stars have strongly broadened absorption lines. This effect causes blending of the absorption lines, hindering the measurement of the abundances of the elements that are in the stellar photosphere. Aims. As the exoplanet transits across its host star, it obscures the stellar spectrum that is emitted from directly behind the planet. We aim to extract this obscured spectrum because it is less affected by rotational broadening, resolving the blending of weak lines of elements that would otherwise remain inaccessible. This allows us to more precisely measure the metal abundances in ultra-hot Jupiter systems, many of which have fast rotating host stars. Methods. We develop a novel method that isolates the stellar spectra behind the planet during a spectral time-series, and reconstructs the disc-integrated non-broadened spectrum of the host star. We have systematically tested this method with model-generated spectra of the transit of WASP-189 b across its fast-rotating A-type host star, assessing the effects of limb darkening, choice of absorption lines, signal to noise regime; and demonstrating the sensitivity to photospheric parameters ($T_{\text{eff}}$, $\log g$) and elemental abundances. We apply the method to observations by the HARPS high-resolution spectrograph. Results. For WASP-189, we obtain the metallicity and photospheric abundances for several species previously not reported in literature, Mg, Ca and Ti, with significantly improved accuracy compared to the ordinary broadened stellar spectrum. This method can be generally applied to other transiting systems in which abundance determinations via spectral synthesis are imprecise due to severe line blending. It is important to accurately determine the photospheric properties of exoplanet host stars, as it can provide further insight into the formation and evolution of the planets., Comment: 13 pages, 6 figures

The nuclear stellar disc (NSD) is a flat and dense stellar structure at the centre of the Milky Way. Previous work has identified the presence of metal-rich and metal-poor stars in the NSD, suggesting that they have different origins. The recent publication of photometric, metallicity, proper motion, and orbital catalogues allows the NSD stellar population to be characterised with unprecedented detail. We aim to explore the proper motions and orbits of NSD stars with different metallicities to assess whether they have different origins and to better understand the metallicity distribution in the NSD. We distinguished between metal-rich and metal-poor stars by applying a Gaussian mixture model, as done in previous work, and analysed the proper motions, orbits, and spatial distribution of stars with different metallicities. We find that metal-rich stars exhibit a lower velocity dispersion, suggesting that they trace a kinematically cooler component compared to metal-poor ones. Furthermore, z-tube orbits are predominant among metal-rich stars, while chaotic/box orbits are more common among metal-poor ones. We also find that metal-rich and metal-poor stars show a similar extinction and are present throughout the analysed regions. As a secondary result, we detected a metallicity gradient in the metal-rich population with higher metallicity towards the centre of the NSD and a tentative gradient for the metal-poor stars, which is consistent with previous studies that did not distinguish between the two populations. Our results suggest that metal-rich stars trace the NSD, whereas metal-poor ones are related to the Galactic bar and probably constitute Galactic bar interlopers and/or are NSD stars that originated from accreted clusters. The detected metallicity gradients aligns with the currently accepted inside-out formation of the NSD., Comment: Accepted for publication in A&A. 11 pages, 12 figures

Exoplanets in the ultra-hot Jupiter regime provide an excellent laboratory for testing the impact of stellar irradiation on the dynamics and chemical composition of gas giant atmospheres. In this study, we observed two transits of the ultra-hot Jupiter WASP-189 b with MAROON-X/Gemini-North to probe its high-altitude atmospheric layers, using strong absorption lines. We derived posterior probability distributions for the planetary and stellar parameters by calculating the stellar spectrum behind the planet at every orbital phase during the transit. This was used to correct the Rossiter-McLaughlin imprint on the transmission spectra. Using differential transmission spectroscopy, we detect strong absorption lines of Ca+, Ba+, Na, H$\alpha$, Mg, Fe, and Fe+, providing an unprecedented and detailed view of the atmospheric chemical composition. Ca+ absorption is particularly well suited for analysis through time-resolved narrow-band spectroscopy, owing to its transition lines formed in high-altitude layers. The spectral absorption lines show no significant blueshifts that would indicate high-altitude day-to-night winds, and further analysis is needed to investigate the implications for atmospheric dynamics. These high signal-to-noise observations provide a benchmark data set for testing high-resolution retrievals and the assumptions of atmospheric models. We also simulate observations of WASP-189 b with ANDES/ELT, and show that ANDES will be highly sensitive to the individual absorption lines of a myriad of elements and molecules, including TiO and CO., Comment: 34 pages, 31 figures, accepted for publication in A&A on 16 February 2024

In order to investigate the chemical history of the entire MilkyWay, it is imperative to also study the dust-obscured regions, where most of the mass lies. The Galactic Center is an example of such a region of interest, where due to the intervening dust along the line-of-sight, near-infrared spectroscopic investigations are necessary. We demonstrate that M giants observed at high spectral resolution in the H and K bands (1.5-2.4 {\mu}m) can yield useful abundance-ratio trends versus metallicity for 21 elements. These elements can therefore be studied also for heavily dust-obscured regions of the Galaxy, such as the Galactic Center, and will be important for the further investigation of the Galactic chemical evolution in these regions. We have observed near-infrared spectra of 50 M giants in the solar neighbourhood at high SNR and at a high spectral resolution (R = 45, 000) with the IGRINS spectrometer on the GEMINI South telescope. We adopted the fundamental stellar parameters for these stars from Nandakumar et al. (2023a), with Teff ranging from 3400 to 3800 K. With a manual spectral synthesis method, we have derived stellar abundances for 21 elements, namely F, Mg, Si, S, Ca, Na, Al, K, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Y, Ce, Nd, and Yb. We demonstrate what elements can be analysed from H- and K-band high-resolution spectra, and we show which spectral lines can be used for abundance analysis, showing them line by line. We discuss the 21 abundance-ratio trends and compared them with those determined from APOGEE and from the optical GILD sample. Especially, we determine the trends of the heavy elements Cu, Zn, Y, Ce, Nd, and Yb. This opens up these nucleosynthetic channels, including both the s- and the r-process, in dust-obscured populations. The [Mn/Fe] versus [Fe/H] trend is shown to be more or less flat at low metallicities, implying that existing NLTE correction are relevant., Comment: 21 pages, 27 figures, Accepted for publication in A&A

Cross-correlation spectroscopy is an invaluable tool in the study of exoplanets. However, aliasing between spectral lines makes it vulnerable to systematic biases. This work strives to constrain the aliases of the cross-correlation function to provide increased confidence in the detections of elements in the atmospheres of ultra-hot Jupiters (UHJs) observed with high-resolution spectrographs. We use a combination of archival transit observations of the UHJ KELT-9 b obtained with the HARPS-N and CARMENES spectrographs and show that it is possible to leverage each instrument's strengths to produce robust detections at substantially reduced signal-to-noise. Aliases that become present at low signal-to-noise regimes are constrained through a linear regression model. We confirm previous detections of H I, Na I, Mg I, Ca II, Sc II, Ti II, Cr II, Fe I, and Fe II, and detect eight new species Ca I, Cr I, Ni I, Sr II, Tb II at the 5$\sigma$ level and Ti I, V I, Ba II above the 3$\sigma$ level. Ionised terbium (Tb II) has never before been seen in an exoplanet atmosphere. We further conclude that a 5$\sigma$ threshold may not provide a reliable measure of confidence when used to claim detections, unless the systematics in the cross-correlation function caused by aliases are taken into account., Comment: Accepted for publication on the 1st of April 2023

Observations of WASP-121 b have suggested an under-abundance of titanium and titanium-oxide from its terminator region. In this study, we aim to determine whether this depletion is global by investigating the day-side emission spectrum. We analyse 8 epochs of high-resolution spectra obtained with ESPRESSO, targeting orbital phases when the day-side is in view. We use a cross-correlation method to search for various atoms, TiO and VO and compare to models. We constrain the velocities and phase-function of the emission signal using a Bayesian framework. We report significant detections of Ca I, V I, Cr I, Mn I, Fe I, Co I and Ni I, but not T i or TiO. Models containing Ti are unable to reproduce the data. The detected signals are consistent with the known orbital and systemic velocities and with peak emission originating from the sub-stellar point. We find that Ti is depleted from regions of the atmosphere where transmission and emission spectroscopy are sensitive. We interpret this as evidence for the night-side condensation of titanium, preventing it from being mixed back into the upper layers of the atmosphere elsewhere on the planet. Species with lower condensation temperatures are unaffected, implying sharp chemical transitions exist between ultra-hot Jupiters that have slight differences in temperature or dynamical properties. As TiO can act as a strong source of stratospheric heating, cold-trapping creates a coupling between the thermal structures on the day-side and night-side, and thus condensation chemistry needs to be included in global circulation models. Observed elemental abundances in hot Jupiters are not reliably representative of bulk abundances unless night-side condensation is accounted for or the planet is hot enough to avoid night-side cold-traps entirely. Planetary rotation may significantly lower the apparent orbital velocity of emission signals., Comment: 23 pages, submitted to A\&A on September 13, 2022, accepted on October 6, 2023

Aims. Stars with strong enhancements of r-process elements are rare and tend to be metal-poor, with generally [Fe/H] <-2 dex and found in the halo. In this work we aim to investigate a candidate r-process enriched bulge star with a relatively high metallicity of -0.65 dex, and compare it with a previously published r-rich candidate star in the bulge. Methods. We reconsider the abundance analysis of a high-resolution optical spectrum of the red-giant star 2MASS J18082459-2548444 and determine its europium (Eu) and molybdenum (Mo) abundance, using stellar parameters from five different previous studies. Applying 2MASS photometry, Gaia astrometry and kinematics, we estimate distance, orbits, and population membership of 2MASS J18082459-2548444 and a previously reported r-enriched star 2MASS J18174532-3353235. Results. We find that 2MASS J18082459-2548444 is a relatively metal rich enriched r-process star that is enhanced in Eu and Mo but not substantially enhanced in s-process elements. It has a high probability of membership in the Galactic bulge based on its distance and orbit. We find that both stars show r-process enhancement with elevated [Eu/Fe]-values, even though 2MASS J18174532-3353235 is 1 dex lower in metallicity. Additionally, we find that 2MASS J18174532-3353235 plausibly has a halo or thick disc origin. Conclusions. We conclude that 2MASS J18082459-2548444 represents the first example of a confirmed r-process enhanced star confined to the inner bulge, possibly a relic from a period of enrichment associated with the formation of the bar., Comment: 9 pages, 8 figures, 3 tables, accepted for publication in A&A

Phosphorus (P) is considered to be one of the key elements for life, making it an important element to look for in the abundance analysis of spectra of stellar systems. Yet, there exists only a handful of spectroscopic studies to estimate the P abundances and investigate its trend across a range of metallicities. We have observed full HK band spectra at a spectral resolving power of R=45,000 with IGRINS instrument. Abundances are determined using SME in combination with 1D MARCS stellar atmosphere models. The investigated sample of stars have reliable stellar parameters estimated using optical FIES spectra (GILD; J\"onsson et al. in prep.). In order to determine the P abundances from the 16482.92 Angstrom P line, we take special care of the CO($\nu=7-4$) blend. We determine the C, N, O abundances from atomic carbon and a range of non-blended molecular lines (CO, CN, OH) which are aplenty in the H band region of K giant stars, assuring an appropriate modelling of the blending CO($\nu=7-4$) line. We present [P/Fe] vs [Fe/H] trend for 38 K giant stars in the metallicity range of -1.2 dex $<$ [Fe/H] $<$ 0.4 dex. We find that our trend matches well with the compiled literature sample of prominently dwarf stars and limited number of giant stars. Our trend is found to be higher by $\sim$ 0.05 - 0.1 dex compared to the theoretical chemical evolution trend in Cescutti et al. 2012 resulting from core collapse supernova (type II) of massive stars with the P yields from Kobayashi et al. (2006) arbitrarily increased by a factor of 2.75. Thus the enhancement factor might need to be $\sim$ 0.05 - 0.1 dex higher to match our trend. We also find an empirically determined primary behaviour for phosphorus. Furthermore, the phosphorus abundance is found to be elevated by $\sim$ 0.6 - 0.9 dex in two metal poor s-enriched stars compared to the theoretical chemical evolution trend., Comment: 13 pages, 9 figures, accepted for publication in Astronomy and Astrophysics

Measuring the abundances of neutron-capture elements in Galactic disk stars is an important part of understanding key stellar and galactic processes. In the optical wavelength regime a number of different neutron-capture elements have been measured, however from the infrared H-band only the s-process dominated element cerium has been accurately measured for a large sample of disk stars. The more r-process dominated element ytterbium has only been measured in a small subset of stars so far. In this study we aim to measure the ytterbium (Yb) abundance of local disk giants using the Yb II line at $\lambda_\text{air}$=16498\AA. We also compare the resulting abundance trend with Ce and Eu abundances for the same stars to analyse the s- and r-process contributions. We analyse 30 K-giants with high-resolution H-band spectra using spectral synthesis. The very same stars have already been analysed using high-resolution optical spectra using the same method, but the abundance of Yb was not possible to determine from those spectra due to blending issues for stars with [Fe/H]>-1. In this present analysis, we utilise the stellar parameters determined from the optical analysis. We determined the Yb abundances with an estimated uncertainty for [Yb/Fe] of 0.1 dex. From comparison, the trend of [Yb/Fe] follows closely the [Eu/Fe] trend and has clear s-process enrichment in identified s-rich stars. From the comparison, both the validity of the Yb abundances are ensured, and the theoretical prediction of a roughly 40/60 s-/r-process contribution to Yb's origin is supported. These results show that with a careful and detailed analysis of infrared spectra, reliable Yb abundances can be derived for a wider sample of cooler giants in the range -1.1<[Fe/H]<0.3. This is promising for further studies of the production of Yb and for the r-process channel, key for Galactochemical evolution, in the infrared., Comment: Accepted for publication in A&A. 11 pages, 7 figures

We present a detailed study of the composition of 20 M giants in the Galactic center with 15 of them confirmed to be in the Nuclear Star Cluster. As a control sample we have also observed 7 M giants in the Milky Way Disk with similar stellar parameters. All 27 stars are observed using the NIRSPEC spectograph on the KECK II telescope in the K-band at a resolving power of R=23,000. We report the first silicon abundance trends versus [Fe/H] for stars in the Galactic center. While finding a disk/bulge like trend at subsolar metallicities, we find that [Si/Fe] is enhanced at supersolar metallicities. We speculate on possible enrichment scenarios to explain such a trend. However, the sample size is modest and the result needs to be confirmed by additional measurements of silicon and other \textalpha-elements. We also derive a new distribution of [Fe/H] and find the most metal rich stars at [Fe/H]=+0.5 dex, confirming our earlier conclusions that the Galactic center hosts no stars with extreme chemical composition., Comment: 13 pages, 10 figures, accepted for publication in ApJ, Figure 7 corrected

Context. In the advent of new infrared, high-resolution spectrometers, accurate and precise atomic data in the infrared is urgently needed. Identifications, wavelengths, strengths, broadening and hyper-fine splitting parameters of stellar lines in the near-IR are in many cases not accurate enough to model observed spectra, and in other cases even non existing. Some stellar features are unidentified. Aims. The aim with this work is to identify a spectral feature at lambda(vac) = 1063.891 nm or lambda(air) = 1063.600 nm seen in spectra of stars of different spectral types, observed with the GIANO-B spectrometer. Methods. Searching for spectral lines to match the unidentified feature in linelists from standard atomic databases was not successful. However, by investigating the original, published laboratory data we were able to identify the feature and solve the problem. To confirm its identification, we model the presumed stellar line in the solar intensity spectrum and find an excellent match. Results. We find that the observed spectral feature is a stellar line originating from the 4s'-4p' transition in S I, and that the reason for its absence in atomic line databases is a neglected air-to-vacuum correction in the original laboratory measurements from 1967 for this line only. From interpolation we determine the laboratory wavelength of the S I line to be lambda(vac) = 1063.8908 nm or lambda(air) = 1063.5993 nm, and the excitation energy of the upper level to be 9.74978 eV., Comment: Accepted for publication in A&A Letters

Although there have been numerous studies of chemical abundances in the Galactic bulge, the central two degrees have been relatively unexplored due to the heavy and variable interstellar extinction, extreme stellar crowding, and the presence of complex foreground disk stellar populations. In this paper we discuss the metallicity distribution function, vertical and radial gradients and chemical abundances of $\alpha$-elements in the inner two degrees of the Milky Way, as obtained by recent IR spectroscopic surveys. We use a compilation of recent measurements of metallicities and $\alpha$-element abundances derived from medium-high resolution spectroscopy. We compare these metallicities with low-resolution studies. Defining "metal-rich" as stars with $ \rm [Fe/H]>0$, and "metal-poor" as stars with $\rm [Fe/H]<0$, we find compelling evidence for a higher fraction ($\sim 80\%$) of metal-rich stars in the Galactic Center (GC) compared to the values (50-60\%) measured in the low latitude fields within the innermost 600 pc. The high fraction of metal-rich stars in the GC region implies a very high mean metallicity of +0.2 dex, while in the inner 600 pc of the bulge the mean metallicity is rather homogenous around the solar value. A vertical metallicity gradient of -0.27 dex/kpc in the inner 600 pc is only measured if the GC is included, otherwise the distribution is about flat and consistent with no vertical gradient. In addition to its high stellar density, the Galactic center/nuclear star cluster is also extreme in hosting high stellar abundances, compared to the surrounding inner bulge stellar populations; this has implications for formation scenarios and strengthens the case for the NSC being a distinct stellar system., Comment: 9 pages, 8 figures, accepted for Astronomy&Astrophysics

Context. Recent observations of the Bulge, e.g., its X-shape, cylindrical stellar motions, and a potential fraction of young stars propose that it formed through secular evolution of the disk and not through gas dissipation and/or mergers, as thought previously. Aims. We measure abundances of six iron-peak elements (Sc, V, Cr, Mn, Co and Ni) in the local thin and thick disks as well as the Bulge to provide additional observational constraints for Galaxy formation and chemical evolution models. Methods. We use high-resolution optical spectra of 291 K giants in the local disk mostly obtained by the FIES at NOT (signal-to-noise (S/N) ratio of 80-100) and 45 K giants in the Bulge obtained by the UVES/FLAMES at VLT (S/N ratio of 10-80). We measure abundances in SME and apply NLTE corrections to the [Mn/Fe] and [Co/Fe] ratios. To discriminate between the thin and thick, we use stellar metallicity, [Ti/Fe]-ratios, and kinematics from Gaia DR2 (proper motions and the radial velocities). Results. The observed disk trend of V is more enhanced in the thick disk, while the Co disk trend shows a minor enhancement in the thick disk. The Bulge trends of V and Co appear even more enhanced w.r.t. the thick disk, but within the uncertainties. The [Ni/Fe] ratio seems slightly overabundant in the thick disk and the Bulge w.r.t. the thin disk, although the difference is minor. The disk and Bulge trends of Sc, Cr and Mn overlap strongly. Conclusions. The somewhat enhanced [(V,Co)/Fe] ratios observed in the Bulge suggest that the local thick disk and the Bulge might have experienced different chemical enrichment and evolutionary paths. However, we are unable to predict the exact evolutionary path of the Bulge solely based on these observations. Galactic chemical evolution models could, on the other hand, provide that using these results., Comment: Accepted for publication in A&A; 25 pages, 15 figures

Very strong Sc I lines have been found recently in cool M giants in the Nuclear Star Cluster in the Galactic Center. Interpreting these as anomalously high scandium abundances in the Galactic Center would imply a unique enhancement signature and chemical evolution history for nuclear star clusters, and a potential test for models of chemical enrichment in these objects. We present high resolution K-band spectra (NIRSPEC/Keck II) of cool M giants situated in the solar neighborhood and compare them with spectra of M giants in the Nuclear Star Cluster. We clearly identify strong Sc I lines in our solar neighborhood sample as well as in the Nuclear Star Cluster sample. The strong Sc I lines in M giants are therefore not unique to stars in the Nuclear Star Cluster and we argue that the strong lines are a property of the line formation process that currently escapes accurate theoretical modeling. We further conclude that for giant stars with effective temperatures below approximately 3800 K these Sc I lines should not be used for deriving the scandium abundances in any astrophysical environment until we better understand how these lines are formed. We also discuss the lines of vanadium, titanium, and yttrium identified in the spectra, which demonstrate a similar striking increase in strength below 3500 K effective temperature., Comment: 11 pages, 6 figures, accepted for publication in ApJ

While the number of stars in the Galactic bulge with detailed chemical abundance measurements is increasingly rapidly, the inner Galactic bulge ( |b| < 2$^\circ$) remains poorly studied, due to heavy interstellar absorption and photometric crowding. We have carried out a high-resolution IR spectroscopic study of 72 M giants in the inner bulge using the CRIRES (ESO/VLT) facility. Our spectra cover the wavelength range of 2.0818 - 2.1444 $\mu$m with the resolution of R$\sim$50,000 and have signal-to-noise ratio of 50 - 100. Our stars are located along the bulge minor axis at l = 0$^\circ$, b = $\pm$0$^\circ$, $\pm$1$^\circ$, $\pm$2$^\circ$ and +3$^\circ$, selected with the aim of investigating any North-South asymmetries in the metallicity distribution function and composition, and comparing them to the outer bulge fields. Our sample was analysed in a homogeneous way using the most current K-band line list. We clearly detect a bimodal MDF with a metal-rich peak at $\rm \sim +0.3\,dex$ and a metal-poor peak at $\rm \sim -0.5\,dex$. Only a single star is found to exceed $\rm [Fe/H]=+0.5\,dex$. They show a symmetric behaviour along the $\pm$1$^\circ$, $\pm$2$^\circ$ fields. The Galactic Center field reveals in contrast a mainly metal-rich population with a mean metallicity of $\rm +0.3\,dex$. We derived $\rm [Mg/Fe]$ and $\rm [Si/Fe]$ abundances which are consistent with trends from the outer bulge, with a gradually decreasing trend with increasing metallicity. We confirm for the supersolar metallicity stars the decreasing trend in \mgfe\ and \sife\ as expected from chemical evolution models. With the caveat of a relatively small sample, we do not find significant differences in the chemical abundances between the Northern and the Southern fields, hence the evidence is consistent with symmetry in chemistry between North and South., Comment: 17 pages, 15 figures, Accepted for publication in MNRAS

We report the first high spectral resolution study of 17 M giants kinematically confirmed to lie within a few parsecs of the Galactic Center, using R=24,000 spectroscopy from Keck/NIRSPEC and a new linelist for the infrared K band. We consider their luminosities and kinematics, which classify these stars as members of the older stellar population and the central cluster. We find a median metallicity of <[Fe/H]>=-0.16 and a large spread from approximately -0.3 to +0.3 (quartiles). We find that the highest metallicities are [Fe/H]<+0.6, with most of the stars being at or below the Solar iron abundance. The abundances and the abundance distribution strongly resembles that of the Galactic bulge rather than disk or halo; in our small sample we find no statistical evidence for a dependence of velocity dispersion on metallicity., Comment: 18 pages, 14 figures, accepted for publication in AJ

Owing to their extreme crowding and high and variable extinction, stars in the Galactic Bulge, within +-2 degrees of the Galactic plane, and especially those in the Nuclear Star Cluster, have only rarely been targeted for an analyses of their detailed abundances. There is also some disagreement about the high end of the abundance scale for these stars. It is now possible to obtain high dispersion, high S/N spectra in the infrared K band (2.0-2.4 microns) for these giants; we report our progress at Keck and VLT in using these spectra to infer the composition of this stellar population., Comment: 4 pages, contributed talk at the IAU Symposium 334 "Rediscovering our Galaxy" in Potsdam, July 10-14, 2017

We report the first results from our program to examine the metallicity distribution of the Milky Way nuclear star cluster connected to SgrA*, with the goal of inferring the star formation and enrichment history of this system, as well as its connection and relationship with the central 100 pc of the bulge/bar system. We present the first high resolution (R~24,000), detailed abundance analysis of a K=10.2 metal-poor, alpha-enhanced red giant projected at 1.5 pc from the Galactic Center, using NIRSPEC on Keck II. A careful analysis of the dynamics and color of the star locates it at about 26 pc line-of-sight distance in front of the nuclear cluster. It probably belongs to one of the nuclear components (cluster or disk), not to the bar-bulge or classical disk. A detailed spectroscopic synthesis, using a new linelist in the K band, finds [Fe/H]~-1.0 and [alpha/Fe]~+0.4, consistent with stars of similar metallicity in the bulge. As known giants with comparable [Fe/H] and alpha enhancement are old, we conclude that this star is most likely to be a representative of the ~10 Gyr old population. This is also the most metal poor confirmed red giant yet discovered in vicinity of the nuclear cluster of the Galactic Center. We consider recent reports in the literature of a surprisingly large number of metal poor giants in the Galactic Center, but the reported gravities of log g ~4 for these stars calls into question their reported metallicities., Comment: Accepted for publication in ApJ