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The composition of several exoplanet atmospheres has been largely debated with contrasting results in the literature. Low- and high-resolution spectroscopy offer complementary views, although sometimes appear to be in sparkling contrast. We present a new approach to simultaneously model low- and high-resolution observation and apply this method to resolve known controversies in the literature. We show that the synergy between different techniques of observations is significantly more informative than the separate analyses. We recommend the joint analysis of low- and high-resolution exoplanet spectra to fully exploit the potential of upcoming space missions, such as JWST, Twinkle and Ariel.

The origin of phosphorus, one of the essential elements for life on Earth, is currently unknown. Prevalent models of Galactic chemical evolution (GCE) underestimate the amount of P compared to observations. The recently discovered P-rich ([P/Fe] > 1 dex) and metal-poor giants further challenge current theories on stellar nucleosynthesis. Since the observed stars are low-mass giants, our primary goal is to find clues on their progenitor. By increasing the number of known P-rich stars, we aim to narrow down a reliable chemical abundance pattern and to place robust constraints on the responsible nucleosynthetic mechanism. In the long term, identifying the progenitor of the P-rich stars may contribute to the search for the source of P in our Galaxy. We performed a detailed chemical abundance analysis based on the H-band spectra from APOGEE-2 (DR17). Employing the BACCHUS code, we measured the abundances of 13 elements in the sample, which is mainly composed of a recent collection of Si-enhanced giants. We also analyzed the orbital motions and compared the abundance results to possible nucleosynthetic formation scenarios, and also to detailed GCE models. We enlarged the sample of confirmed P-rich stars from 16 to 78 giants, which represents the largest sample of P-rich stars to date. Significant enhancements in O, Al, Si and Ce, as well as systematic correlations among the elements, unveil the chemical fingerprint of the P-rich stars. The high Mg and C+N found in some of the P-rich stars with respect to P-normal stars is not confirmed over the full sample. Strikingly, the strong over-abundance in the $\alpha$-element Si is accompanied by normal Ca and S abundances. Our analysis of the orbital motion showed that the P-rich stars do not belong to a specific sub-population. In addition, we confirm that the majority of the sample stars are not part of binary systems., Comment: 29 pages, 18 figures, 8 tables, accepted for publication in Astronomy & Astrophysics

Full list of authors: Turtelboom, Emma V.; Weiss, Lauren M.; Dressing, Courtney D.; Nowak, Grzegorz; Pallé, Enric; Beard, Corey; Blunt, Sarah; Brinkman, Casey; Chontos, Ashley; Claytor, Zachary R.; Dai, Fei; Dalba, Paul A.; Giacalone, Steven; Gonzales, Erica; Harada, Caleb K.; Hill, Michelle L.; Holcomb, Rae; Korth, Judith; Lubin, Jack; Masseron, Thomas; MacDougall, Mason; Mayo, Andrew W.; Močnik, Teo; Akana Murphy, Joseph M.; Polanski, Alex S.; Rice, Malena; Rubenzahl, Ryan A.; Scarsdale, Nicholas; Stassun, Keivan G.; Tyler, Dakotah B.; Zandt, Judah Van; Crossfield, Ian J. M.; Deeg, Hans J.; Fulton, Benjamin; Gandolfi, Davide; Howard, Andrew W.; Huber, Dan; Isaacson, Howard; Kane, Stephen R.; Lam, Kristine W. F.; Luque, Rafael; Martín, Eduardo L.; Morello, Giuseppe; Orell-Miquel, Jaume; Petigura, Erik A.; Robertson, Paul; Roy, Arpita; Van Eylen, Vincent; Baker, David; Belinski, Alexander A.; Bieryla, Allyson; Ciardi, David R.; Collins, Karen A.; Cutting, Neil; Della-Rose, Devin J.; Ellingsen, Taylor B.; Furlan, E.; Gan, Tianjun; Gnilka, Crystal L.; Guerra, Pere; Howell, Steve B.; Jimenez, Mary; Latham, David W.; Larivière, Maude; Lester, Kathryn V.; Lillo-Box, Jorge; Luker, Lindy; Mann, Christopher R.; Plavchan, Peter P.; Safonov, Boris; Skinner, Brett; Strakhov, Ivan A.; Wittrock, Justin M.; Caldwell, Douglas A.; Essack, Zahra; Jenkins, Jon M.; Quintana, Elisa V.; Ricker, George R.; Vanderspek, Roland; Seager, S.; Winn, Joshua N.-- This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited., Multiplanet systems are valuable arenas for investigating exoplanet architectures and comparing planetary siblings. TOI-1246 is one such system, with a moderately bright K dwarf (V = 11.6, K = 9.9) and four transiting sub-Neptunes identified by TESS with orbital periods of 4.31, 5.90, 18.66, and 37.92 days. We collected 130 radial velocity observations with Keck/HIRES and TNG/HARPS-N to measure planet masses. We refit the 14 sectors of TESS photometry to refine planet radii (2.97 ± 0.06 R⊕, 2.47 ± 0.08 R⊕, 3.46 ± 0.09 R⊕, and 3.72 ± 0.16 R⊕) and confirm the four planets. We find that TOI-1246 e is substantially more massive than the three inner planets (8.1 ± 1.1 M⊕, 8.8 ± 1.2 M⊕, 5.3 ± 1.7 M⊕, and 14.8 ± 2.3 M⊕). The two outer planets, TOI-1246 d and TOI-1246 e, lie near to the 2:1 resonance (Pe/Pd = 2.03) and exhibit transit-timing variations. TOI-1246 is one of the brightest four-planet systems, making it amenable for continued observations. It is one of only five systems with measured masses and radii for all four transiting planets. The planet densities range from 0.70 ± 0.24 to 3.21 ± 0.44 g cm−3, implying a range of bulk and atmospheric compositions. We also report a fifth planet candidate found in the RV data with a minimum mass of 25.6 ± 3.6 M⊕. This planet candidate is exterior to TOI-1246 e, with a candidate period of 93.8 days, and we discuss the implications if it is confirmed to be planetary in nature. © 2022. The Author(s). Published by the American Astronomical Society., We thank the time assignment committees of the University of California, the California Institute of Technology, NASA, and the University of Hawaii for supporting the TESS-Keck Survey with observing time at Keck Observatory. We thank NASA for funding associated with our Key Strategic Mission Support project. We gratefully acknowledge the efforts and dedication of the Keck Observatory staff for support of HIRES and remote observing. We recognize and acknowledge the very significant cultural role and reverence that the summit of Maunakea has within the indigenous Hawaiian community. We are deeply grateful to have the opportunity to conduct observations from this mountain. We thank Ken and Gloria Levy, who supported the construction of the Levy Spectrometer on the Automated Planet Finder. We thank the University of California and Google for supporting Lick Observatory, and the UCO staff for their dedicated work scheduling and operating the telescopes of Lick Observatory. This paper is based on data collected by the TESS mission. Funding for the TESS mission is provided by the NASA Explorer Program. C.D. gratefully acknowledges support from the David & Lucile Packard Foundation and the Alfred P. Sloan Foundation. A.A.B., B.S.S., and I.A.S. acknowledge the support of the Ministry of Science and Higher Education of the Russian Federation under the grant 075-15-2020-780(N13.1902.21.0039). J.K. gratefully acknowledges the support of the Swedish National Space Agency (SNSA; DNR 2020-00104). A.W.M. is supported by the NSF Graduate Research Fellowship grant No. DGE 1752814. J.M.A.M. is supported by the National Science Foundation Graduate Research Fellowship Program under grant No. DGE-1842400. J.M.A.M. acknowledges the LSSTC Data Science Fellowship Program, which is funded by LSSTC, NSF Cybertraining grant No. 1829740, the Brinson Foundation, and the Moore Foundation; his participation in the program has benefited this work. C.K.H. acknowledges support from the National Science Foundation Graduate Research Fellowship Program under grant No. DGE 2146752. M.R. is supported by the National Science Foundation Graduate Research Fellowship Program under grant No. DGE-1752134. R.A.R. is supported by an NSF Graduate Research Fellowship, grant No. DGE 1745301. P.D. is supported by a National Science Foundation (NSF) Astronomy and Astrophysics Postdoctoral Fellowship under award AST-1903811. R.L. acknowledges financial support from the Centre of Excellence "Severo Ochoa" award to the Instituto de Astrofísica de Andalucía (SEV-2017-0709). D.H. acknowledges support from the Alfred P. Sloan Foundation and the National Aeronautics and Space Administration (80NSSC20K0593, 80NSSC21K0652). T.M. acknowledges financial support from the Spanish Ministry of Science and Innovation (MICINN) through the Spanish State Research Agency, under the Severo Ochoa Program 2020-2023 (CEX2019-000920-S). K.W.F.L. acknowledges support by DFG grants RA714/14-1 within the DFG Schwerpunkt SPP 1992, "Exploring the Diversity of Extrasolar Planets."

Elements with weak and blended spectral features in stellar spectra are challenging to measure and require specialized analysis methods to precisely measure their chemical abundances. In this work, we have created a catalog of approximately 120,000 giants with high signal-to-noise APOGEE DR17 spectra, for which we explore weak and blended species to measure Na, P, S, V, Cu, Ce, and Nd abundances and $^{12}$C/$^{13}$C isotopic ratios. We employ an updated version of the BACCHUS (Brussels Automatic Code for Characterizing High accUracy Spectra) code to derive these abundances using the stellar parameters measured by APOGEE's DR17 ASPCAP pipeline, quality flagging to identify suspect spectral lines, and a prescription for upper limits. Combined these allow us to provide our BACCHUS Analysis of Weak Lines in APOGEE Spectra (BAWLAS) catalog of precise chemical abundances for these weak and blended species that agrees well with literature and improves upon APOGEE abundances for these elements, some of which are unable to be measured with APOGEE's current, grid-based approach without computationally expensive expansions. This new catalog can be used alongside APOGEE and provide measurements for many scientific applications ranging from nuclear physics to Galactic chemical evolution and Milky Way population studies. To illustrate this we show some examples of uses for this catalog, such as, showing that we observe stars with enhanced s-process abundances or that we can use the our $^{12}$C/$^{13}$C ratios to explore extra mixing along the red giant branch., Comment: 49 Pages, 30 figures, 7 Tables. Accepted for publishing in The Astrophysical Journal Supplement Series. The BAWLAS chemical abundance catalog to be made publicly available as an SDSS DR17 value-added catalog: https://www.sdss.org/dr17/data_access/value-added-catalogs/

Individual chemical abundances for fourteen elements (C, O, Na, Mg, Al, Si, K, Ca, Ti, V, Cr, Mn, Fe, and Ni) are derived for a sample of M-dwarfs using high-resolution near-infrared $H$-band spectra from the SDSS-IV/APOGEE survey. The quantitative analysis included synthetic spectra computed with 1-D LTE plane-parallel MARCS models using the APOGEE DR17 line list to determine chemical abundances. The sample consists of eleven M-dwarfs in binary systems with warmer FGK-dwarf primaries and ten measured interferometric angular diameters. To minimize atomic diffusion effects, [X/Fe] ratios are used to compare M-dwarfs in binary systems and literature results for their warmer primary stars, indicating good agreement ($, Comment: 19 pages. Accepted to ApJ

Barium stars are one of the important probes to understand the origin and evolution of slow neutron-capture process elements in the Galaxy. These are extrinsic stars, where the observed s-process element abundances are believed to have an origin in the now invisible companions that produced these elements at their asymptotic giant branch (AGB) phase of evolution. We have attempted to understand the s-process nucleosynthesis, as well as the physical properties of the companion stars through a detailed comparison of observed elemental abundances of 10 barium stars with the predictions from AGB nucleosynthesis models, FRUITY. For these stars, we have presented estimates of abundances of several elements, C, N, O, Na, Al, α-elements, Fe-peak elements, and neutron-capture elements Rb, Sr, Y, Zr, Ba, La, Ce, Pr, Nd, Sm, and Eu. The abundance estimates are based on high resolution spectral analysis. Observations of Rb in four of these stars have allowed us to put a limit to the mass of the companion AGB stars. Our analysis clearly shows that the former companions responsible for the surface abundance peculiarities of these stars are low-mass AGB stars. Kinematic analysis has shown the stars to be members of Galactic disc population.

Abdurro’uf et al., This paper documents the seventeenth data release (DR17) from the Sloan Digital Sky Surveys; the fifth and final release from the fourth phase (SDSS-IV). DR17 contains the complete release of the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey, which reached its goal of surveying over 10,000 nearby galaxies. The complete release of the MaNGA Stellar Library accompanies this data, providing observations of almost 30,000 stars through the MaNGA instrument during bright time. DR17 also contains the complete release of the Apache Point Observatory Galactic Evolution Experiment 2 survey that publicly releases infrared spectra of over 650,000 stars. The main sample from the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), as well as the subsurvey Time Domain Spectroscopic Survey data were fully released in DR16. New single-fiber optical spectroscopy released in DR17 is from the SPectroscipic IDentification of ERosita Survey subsurvey and the eBOSS-RM program. Along with the primary data sets, DR17 includes 25 new or updated value-added catalogs. This paper concludes the release of SDSS-IV survey data. SDSS continues into its fifth phase with observations already underway for the Milky Way Mapper, Local Volume Mapper, and Black Hole Mapper surveys., This publication uses data generated via the Zooniverse.org platform, development of which is funded by generous support, including a Global Impact Award from Google, and by a grant from the Alfred P. Sloan Foundation. This publication makes use of data products from the Two Micron All Sky Survey, which is a joint project of the University of Massachusetts and the Infrared Processing and Analysis Center/California Institute of Technology, funded by the National Aeronautics and Space Administration and the National Science Foundation. This work has made use of data from the European Space Agency (ESA) mission Gaia (https://www.cosmos.esa.int/gaia), processed by the Gaia Data Processing and Analysis Consortium (DPAC; https://www.cosmos.esa.int/web/gaia/dpac/consortium). Funding for the DPAC has been provided by national institutions, in particular the institutions participating in the Gaia Multilateral Agreement.

We describe the atomic and molecular data that were used for the abundance analyses of FGK-type stars carried out within the Gaia-ESO Survey. We present an unprecedented effort to create a homogeneous line list, which was used by several abundance analysis groups to calculate synthetic spectra and equivalent widths. The atomic data are accompanied by quality indicators and detailed references to the sources. The atomic and molecular data are made publicly available in electronic form. In general experimental transition probabilities were preferred but theoretical values were also used. Astrophysical gf-values were avoided due to the model-dependence of such a procedure. For elements whose lines are significantly affected by hyperfine structure or isotopic splitting a concerted effort has been made to collate the necessary data for the individual line components. We also performed a detailed investigation of available data for line broadening due to collisions with neutral hydrogen atoms. Synthetic spectra calculated for the Sun and Arcturus were used to assess the blending properties of the lines. Among a subset of over 1300 lines of 35 elements in the wavelength ranges from 475 nm to 685 nm and from 850 nm to 895 nm we identified about 200 lines of 24 species which have accurate gf-values and are free of blends in the spectra of the Sun and Arcturus. For the broadening due to collisions with neutral hydrogen we recommend data based on Anstee-Barklem-O'Mara theory, where available, and to avoid lines of neutral species otherwise. Theoretical broadening data by R.L. Kurucz should be used for Sc II, Ti II, and Y II lines. For ionised rare-earth species the Uns\"old approximation with an enhancement factor of 1.5 for the line width can be used. Desirable improvements in atomic data were identified for a number of species, including Al I, S I, Cr II, Na I, Si I, Ca II, and Ni I., Comment: Accepted for publication in section 12. Atomic, molecular, and nuclear data of Astronomy and Astrophysics; main part 25 pages, 8 tables, 5 figures; appendices 53 pages, 23 tables, 29 figures

Boyajian's star is an apparently normal main sequence F-type star with a very unusual light curve. The dipping activity of the star, discovered during the Kepler mission, presents deep, asymmetric, and aperiodic events. Here we present high resolution spectroscopic follow-up during some dimming events recorded post-Kepler observations, from ground-based telescopes. We analise data from the HERMES, HARPS-N and FIES spectrographs to characterise the stellar atmosphere and to put some constraints on the hypotheses that have appeared in the literature concerning the occulting elements. The star's magnetism, if existing, is not extreme. The spots on the surface, if present, would occupy 0.02% of the area, at most. The chromosphere, irrespective of the epoch of observation, is hotter than the values expected from radiative equilibrium, meaning that the star has some degree of activity. We find no clear evidence of the interstellar medium nor exocoments being responsible for the dimmings of the light curve. However, we detect at 1-2 sigma level, a decrease of the radial velocity of the star during the first dip recorded after the \emph{\emph{Kepler}} observations. We claim the presence of an optically thick object with likely inclined and high impact parameter orbits that produces the observed Rossiter-McLaughlin effect., Comment: submitted to MNRAS

Elemental abundances of CH stars can provide observational constraints for theoretical studies on the nucleosynthesis and evolution of low- and intermediate-mass stars. However, available abundance data in literature are quite scanty. In our pursuit to generate a homogeneous database of elemental abundances of CH stars we have performed a detailed chemical abundance study for a sample of 12 potential CH star candidates based on high resolution spectroscopy. We present first time abundance analysis for the objects HE 0308-1612, CD-28 1082, HD 30443, and HD 87853. For the other objects, although limited information is available, detailed chemical composition studies are missing. Our analysis shows CD-28 1082 to be a very metal-poor object with [Fe/H] = -2.45 and enriched in carbon with [C/Fe] = 2.19. With a ratio of [Ba/Eu] ~ 0.02 the star satisfies the classification criteria of a CEMP-r/s star. The objects CD-38 2151 with [Fe/H] = -2.03 and HD 30443 with [Fe/H] ~ -1.68 are found to show the characteristic properties of CH stars. HE 0308-1612 and HD 87853 are found to be moderately metal-poor with [Fe/H]~ -0.73; while HE 0308-1612 is moderately enhanced with carbon ([C/Fe] ~ 0.78) and shows the spectral properties of CH stars, the abundance of carbon could not be estimated for HD 87853. Among the two moderately metal-poor objects, HD 87080 ([Fe/H] = -0.48) shows near solar carbon abundance, and HD 176021 ([Fe/H] = -0.63) is mildly enhanced in carbon with [C/Fe] = 0.52. HD 176021 along with HD 202020 a known binary, exhibit the characteristic properties of CH stars as far as the heavy element abundances are concerned. Five objects in our sample show spectral properties that are normally seen in barium stars., Comment: 23 pages, 23 figures (Table A5 - A8 and 2 figures will be available online), Accepted in MNRAS

It has recently been suggested that all giant stars with mass below 2 $M_{\odot}$ suffer an episode of surface lithium enrichment between the tip of the red giant branch (RGB) and the red clump (RC). We test if the above result can be confirmed in a sample of RC and RGB stars that are members of open clusters. We discuss Li abundances in six open clusters with ages between 1.5 and 4.9 Gyr (turn-off masses between 1.1 and 1.7 $M_{\odot}$). These observations are compared with the predictions of different models that include rotation-induced mixing, thermohaline instability, mixing induced by the first He flash, and energy losses by neutrino magnetic moment. In six clusters, we find about 35\% RC stars with Li abundances that are similar or higher than those of upper RGB stars. This can be a sign of fresh Li production. Because of the extra-mixing episode connected to the luminosity bump, the expectation was for RC stars to have systematically lower surface Li abundances. However, we cannot confirm that the possible Li production is ubiquitous. For about 65\% RC giants we can only determine abundance upper limits that could be hiding very low Li abundances. Our results indicate a possible production of Li during the RC, at levels that would not classify the stars as Li rich. Determination of their carbon isotopic ratio would help to confirm that the RC giants have suffered extra mixing followed by Li enrichment. The Li abundances of the RC stars can be qualitatively explained by the models with an additional mixing episode close to the He flash., Comment: Accepted for publication in A&A, 8 pages, 5 figures, tables available online and under request

We study the multiple populations of $\omega$ Cen by using the abundances of Fe, C, N, O, Mg, Al, Si, K, Ca, and Ce from the high-resolution, high signal-to-noise (S/N$>$70) spectra of 982 red giant stars observed by the SDSS-IV/APOGEE-2 survey. We find that the shape of the Al-Mg and N-C anticorrelations changes as a function of metallicity, continuous for the metal-poor groups, but bimodal (or unimodal) at high metallicities. There are four Fe populations, similar to what has been found in previously published investigations, but we find seven populations based on Fe, Al, and Mg abundances. The evolution of Al in $\omega$ Cen is compared to its evolution in the Milky Way and in five representative globular clusters. We find that the distribution of Al in metal-rich stars of $\omega$ Cen closely follows what is observed in the Galaxy. Other $\alpha-$elements and C, N, O, and Ce are also compared to the Milky Way, and significantly elevated abundances are observed over what is found in the thick disk for almost all elements. However, we also find some stars with high metallicity and low [Al/Fe], suggesting that $\omega$ Cen could be the remnant core of a dwarf galaxy, but the existence of these peculiar stars needs an independent confirmation. We also confirm the increase in the sum of CNO as a function of metallicity previously reported in the literature and find that the [C/N] ratio appears to show opposite correlations between Al-poor and Al-rich stars as a function of metallicity., Comment: Accepted for publication in MNRAS, 17 pages, 16 figures, 3 tables

We present an on-going project consisting of analysis of a sample of twenty-five metal-poor stars, most of them carbon-enriched and thus tagged carbon-enhanced metal-poor (CEMP) stars, observed with the high-resolution HERMES spectrograph mounted on the Mercator telescope (La Palma), the UVES spectrograph on VLT (ESO Chile), or the HIRES spectrograph on KECK (Hawaii). This sample consists of CEMP-s stars, which are CEMP stars enriched in slow-neutron-capture (s-process) elements, as well as CEMP-rs stars enriched with both s-process and rapid-neutron-capture (r-process) elements. We also included an r-process-enriched star for comparison purposes. The origin of the abundance differences between CEMP-s and CEMP-rs stars is presently unknown. It has been claimed that the i-process (intermediate nucleosynthesis process), whose site still remains to be identified, could better reproduce CEMP-rs abundances than the s-process. We aim at understanding whether the i-process and its putative site can reproduce the abundance pattern measured in CEMP-rs stars., SCOPUS: ar.j, info:eu-repo/semantics/published

Context. In the present-day panorama of large spectroscopic surveys, the amount, diversity, and complexity of the available data continuously increase. The overarching goal of studying the formation and evolution of our Galaxy is hampered by the heterogeneity of instruments, selection functions, analysis methods, and measured quantities. Aims. We present a comprehensive catalogue, the Survey of Surveys (SoS), built by homogeneously merging the radial velocity (RV) determinations of the largest ground-based spectroscopic surveys to date, such as APOGEE, GALAH, Gaia-ESO, RAVE, and LAMOST, using Gaia as a reference. This pilot study serves to prove the concept and to test the methodology that we plan to apply in the future to the stellar parameters and abundance ratios as well. Methods. We have devised a multi-staged procedure that includes: (i) the cross match between Gaia and the spectroscopic surveys using the official Gaia cross-match algorithm, (ii) the normalisation of uncertainties using repeated measurements or the three-cornered hat method, (iii) the cross calibration of the RVs as a function of the main parameters on which depend (magnitude, effective temperature, surface gravity, metallicity, and signal-to-noise ratio) to remove trends and zero point offsets, and (iv) the comparison with external high-resolution samples, such as the Gaia RV standards and the Geneva-Copenhagen survey, to validate the homogenisation procedure and to calibrate the RV zero-point of the SoS catalogue. Results. We provide the largest homogenised RV catalogue to date, containing almost 11 million stars, of which about half come exclusively from Gaia and half in combination with the ground-based surveys. We estimate the accuracy of the RV zero-point to be about 0.16−0.31 km s−1 and the RV precision to be in the range 0.05−1.50 km s−1 depending on the type of star and on its survey provenance. We validate the SoS RVs with open clusters from a high resolution homogeneous samples and provide the systemic velocity of 55 individual open clusters. Additionally, we provide median RVs for 532 clusters recently discovered by Gaia data. Conclusions. The SoS is publicly available and ready to be applied to various research projects, such as the study of star clusters, Galactic archaeology, stellar streams, or the characterisation of planet-hosting stars, to name a few. We also plan to include survey updates and more data sources in future versions of the SoS.

Among Carbon-Enhanced Metal-Poor (CEMP) stars, some are found to be enriched in s-process elements (CEMP-s), in r-process elements (CEMP-r) or in both s- and r-process elements (CEMP-rs). The origin of the abundance differences between CEMP-s and CEMP-rs stars is presently unknown. It has been claimed that the i-process, whose site still remains to be identified, could better reproduce CEMP-rs abundances than the s-process. We analyze high-resolution spectra of 25 metal-poor stars, observed with the high-resolution HERMES spectrograph mounted on the Mercator telescope, La Palma, or with the UVES/VLT and HIRES/KECK spectrographs. We propose a new, robust classification method for CEMP-s and CEMP-rs stars using eight heavy element abundances. The abundance profiles of CEMP-s and CEMP-rs stars are derived and there appears to be an abundance continuum between the two stellar classes. CEMP-rs stars present most of the characteristics of extrinsic stars such as CEMP-s, CH, Barium and extrinsic S stars, with an even larger binarity rate among CEMP-rs stars than among CEMP-s stars. Stellar evolutionary tracks of an enhanced carbon composition (consistent with our abundance determinations) are necessary to explain the position of CEMP-s and CEMP-rs stars in the HR diagram using Gaia DR2 parallaxes; they are found to lie mostly on the RGB. CEMP-rs stars can be explained as being polluted by a low-mass, low-metallicity TP-AGB companion experiencing i-process nucleosynthesis after proton ingestion during its first convective thermal pulses. The global fitting of our i-process models to CEMP-rs stars is as good as the one of our s-process models to CEMP-s stars. As such, CEMP-rs stars could be renamed as CEMP-sr stars, since they represent a particular manifestation of the s-process at low-metallicities. For these objects a call for an exotic i-process site may not necessarily be required anymore., 35 pages, 26 figures, Accepted for publication in A&A, Final version

Context. NGC 2264 is a young cluster whose accretion properties can be investigated in detail by taking advantage of the FLAMES data in the context of the Gaia-ESO Survey. In fact, the analysis of the Hα emission line profile can provide us with information about the accretion and ejection activity of young stars. However, a strong nebular emission that contributes to the Hα emission can alter the profiles, with consequences for their physical interpretation. Aims. Our study is aimed at investigating the accretion and ejection properties of NGC 2264 by applying a proper treatment of the sky contribution to the Hα and forbidden emission lines (FELs; [SII] and [NII] doublets). Methods. We developed a tool, the OHαNA-method, to handle the strong nebular contribution and spectra with spurious profiles of the Hα and FELs, namely altered Hα profiles or absorption features artificially created where emission lines (FELs) are expected. We derived the quantitative measurements of relevant parameters to describe the accretion and ejection processes in young members of NGC 2264, focusing on reliable quantities derived from the width of the lines, which is relatively unaffected by the nebular emission, unlike the intensity peak, which can be altered significantly. Results. We derive the quantitative measurements related to the Hα emission line and discuss the comparison between the original and sky-subtracted spectra. We thus reveal possible profile alterations with consequences for their physical interpretation. Furthermore, we show the analysis of the variability for multi-epoch observations, also deriving the velocity of the infalling and outflowing plasma from the wings of the broad Hα emission line (in accreting stars). We also explore the mass accretion rate versus full width at zero intensity of the Hα line, namely Ṁ versus FWZI(Hα), a correlation based on the width of the emission line, which is expected to be more robust with respect to any measurement derived from the peak (e.g., Hα10%) and possibly altered by the nebular contribution. Conclusions. We are able to ascertain that more than 20% of the confirmed accretors, which have already been identified in NGC 2264, are affected by the alteration of their line profiles due to the contribution of the nebular emission. Therefore, this is an important issue to consider when investigating accretion and ejection processes in young stellar clusters. While a small fraction of spectra can be unequivocally classified as either unaffected by nebular emission or dominated by nebular emission, the majority (> 90%) represent intermediate cases whose spectral features have to be investigated in detail to derive reliable measurements of the relevant parameters and their physical implications.

This paper documents the 16th data release (DR16) from the Sloan Digital Sky Surveys (SDSS), the fourth and penultimate from the fourth phase (SDSS-IV). This is the first release of data from the Southern Hemisphere survey of the Apache Point Observatory Galactic Evolution Experiment 2 (APOGEE-2); new data from APOGEE-2 North are also included. DR16 is also notable as the final data release for the main cosmological program of the Extended Baryon Oscillation Spectroscopic Survey (eBOSS), and all raw and reduced spectra from that project are released here. DR16 also includes all the data from the Time Domain Spectroscopic Survey and new data from the SPectroscopic IDentification of ERosita Survey programs, both of which were co-observed on eBOSS plates. DR16 has no new data from the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) survey (or the MaNGA Stellar Library "MaStar"). We also preview future SDSS-V operations (due to start in 2020), and summarize plans for the final SDSS-IV data release (DR17)., Funding for the Sloan Digital Sky Survey IV has been provided by the Alfred P. Sloan Foundation, the U.S. Department of Energy Office of Science, and the Participating Institutions. SDSS-IV acknowledges support and resources from the Center for High-Performance Computing at the University of Utah. The SDSS website is www.sdss.org.

Full list of authors: Gutiérrez Albarrán, M. L.; Montes, D.; Gómez Garrido, M.; Tabernero, H. M.; González Hernández, J. I.; Marfil, E.; Frasca, A.; Lanzafame, A. C.; Klutsch, A.; Franciosini, E.; Randich, S.; Smiljanic, R.; Korn, A. J.; Gilmore, G.; Alfaro, E. J.; Baratella, M.; Bayo, A.; Bensby, T.; Bonito, R.; Carraro, G. Delgado Mena, E.; Feltzing, S.; Gonneau, A.; Heiter, U.; Hourihane, A.; Jiménez Esteban, F.; Jofre, P.; Masseron, T.; Monaco, L.; Morbidelli, L.; Prisinzano, L.; Roccatagliata, V.; Sousa, S.; Van der Swaelmen, M.; Worley, C. C.; Zaggia, S., Context. Previous studies of open clusters have shown that lithium depletion is not only strongly age dependent but also shows a complex pattern with other parameters that is not yet understood. For pre- and main-sequence late-type stars, these parameters include metallicity, mixing mechanisms, convection structure, rotation, and magnetic activity. Aims. We perform a thorough membership analysis for a large number of stars observed within the Gaia-ESO survey (GES) in the field of 20 open clusters, ranging in age from young clusters and associations, to intermediate-age and old open clusters. Methods. Based on the parameters derived from the GES spectroscopic observations, we obtained lists of candidate members for each of the clusters in the sample by deriving radial velocity distributions and studying the position of the kinematic selections in the EW(Li)-versus-Teff plane to obtain lithium members. We used gravity indicators to discard field contaminants and studied [Fe/H] metallicity to further confirm the membership of the candidates. We also made use of studies using recent data from the Gaia DR1 and DR2 releases to assess our member selections. Results. We identified likely member candidates for the sample of 20 clusters observed in GES (iDR4) with UVES and GIRAFFE, and conducted a comparative study that allowed us to characterize the properties of these members as well as identify field contaminant stars, both lithium-rich giants and non-giant outliers. Conclusions. This work is the first step towards the calibration of the lithium-age relation and its dependence on other GES parameters. During this project we aim to use this relation to infer the ages of GES field stars, and identify their potential membership to young associations and stellar kinematic groups of different ages. © ESO 2020., Financial support was provided by the Universidad Complutense de Madrid and by the Spanish Ministry of Economy and Competitiveness (MINECO) from project AYA2016-79425-C3-1-P. We acknowledge the support from INAF and Ministero dell' Istruzione, dell' Universita' e della Ricerca (MIUR) in the form of the grant "Premiale VLT 2012". T.B. was funded by the project grant "The New Milky Way" from the Knut and Alice Wallenberg Foundation. J.I.G.H. acknowledges financial support from the Spanish Ministry of Science, Innovation and Universities (MICIU) under the 2003 Ramon y Cajal program RYC-2013-14875, and also from the Spanish Ministry project MICIU AYA2017-86389-P. E.M. acknowledges financial support from the Spanish Ministerio de Ciencia e Innovacion through fellowship FPU15/01476. A.G. acknowledges support from the European Union FP7 programme from the UK space agency. U.H. acknowledges support from the Swedish National Space Agency (SNSA/Rymdstyrelsen). F.J.E. acknowledges financial support from the Spanish MINECO/FEDER through the grant AyA2017-84089. S.G.S acknowledges the support of Fundacao para a Ciencia e Tecnologia (FCT) through national funds and research grant (project ref. UID/FIS/04434/2013, and PTDC/FIS-AST/7073/2014). S.G.S also acknowledges the support from FCT through Investigador FCT contract of reference IF/00028/2014 and POPH/FSE (EC) by FEDER funding through the program "Programa Operacional de Factores de Competitividad" - COMPETE MT also acknowledges support from the FCT - Fundacao para a Ciencia e a Tecnologia through national funds (PTDC/FIS-AST/28953/2017) and by FEDER -Fundo Europeu de Desenvolvimento Regional through COMPETE2020 - Programa Operacional Competitividade e Internacionalizacao (POCI-01-0145-FEDER-028953). TM acknowledges support from the State Research Agency (AEI) of the Spanish Ministry of Science, Innovation and Universities (MCIU) and the European Regional Development Fund (FEDER) under grant AYA2017-88254-P Based on data products from observations made with ESO Telescopes at the La Silla Paranal Observatory under programme focusID 188.B-3002. These data products have been processed by the Cambridge Astronomy Survey Unit (CASU) at the Institute of Astronomy, University of Cambridge, and by the FLAMES/UVES reduction team at INAF-Osservatorio Astrofisico di Arcetri. These data have been obtained from the GES Data Archive, prepared and hosted by theWide Field Astronomy Unit, Institute for Astronomy, University of Edinburgh, which is funded by the UK Science and Technology Facilities Council. This work was partly supported by the European Union FP7 programme through ERC grant number 320360 and by the Leverhulme Trust through grant RPG-2012-541. The results presented here benefit from discussions held during GES workshops and conferences supported by the ESF (European Science Foundation) through the GREAT Research Network Programme. This work was also supported by Fundacao para a Ciencia e Tecnologia (FCT) through the research grants UID/FIS/04434/2019, UIDB/04434/2020 and UIDP/04434/2020. This work has made use of data from the European Space Agency (ESA) mission Gaia (https://www.cosmos.esa.int/gaia), processed by the Gaia Data Processing and Analysis Consortium (DPAC, https://www.cosmos.esa.int/web/gaia/dpac/consortium).Funding for the DPAC has been provided by national institutions, in particular the institutions participating in the Gaia Multilateral Agreement. This publication makes use of the VizieR database (Ochsenbein et al. 2000) and the SIMBAD database (Wenger et al. 2000), both operated at CDS, Centre de Donnees astronomiques de Strasbourg, France. This research also made use of the WEBDA database, operated at the Department of Theoretical Physics and Astrophysics of the Masaryk University, and the interactive graphical viewer and editor for tabular data TOPCAT (Taylor 2005). For the analysis of the distributions of RV and metallicity we used RStudio Team (2015). Integrated Development for R. RStudio, Inc., Boston, MA (http://www.rstudio.com/).Finally, we would like to thank the anonymous referee for helpful comments and suggestions.

The spectral analysis and data products in Data Release 16 (DR16; 2019 December) from the high-resolution near-infrared Apache Point Observatory Galactic Evolution Experiment (APOGEE)-2/Sloan Digital Sky Survey (SDSS)-IV survey are described. Compared to the previous APOGEE data release (DR14; 2017 July), APOGEE DR16 includes about 200,000 new stellar spectra, of which 100,000 are from a new southern APOGEE instrument mounted on the 2.5 m du Pont telescope at Las Campanas Observatory in Chile. DR16 includes all data taken up to 2018 August, including data released in previous data releases. All of the data have been re-reduced and re-analyzed using the latest pipelines, resulting in a total of 473,307 spectra of 437,445 stars. Changes to the analysis methods for this release include, but are not limited to, the use of MARCS model atmospheres for calculation of the entire main grid of synthetic spectra used in the analysis, a new method for filling "holes"in the grids due to unconverged model atmospheres, and a new scheme for continuum normalization. Abundances of the neutron-capture element Ce are included for the first time. A new scheme for estimating uncertainties of the derived quantities using stars with multiple observations has been applied, and calibrated values of surface gravities for dwarf stars are now supplied. Compared to DR14, the radial velocities derived for this release more closely match those in the Gaia DR2 database, and a clear improvement in the spectral analysis of the coolest giants can be seen. The reduced spectra as well as the result of the analysis can be downloaded using links provided on the SDSS DR16 web page. (Less)

Recent detections of thermal inversions in the dayside atmospheres of some hot Jupiters are motivating new avenues to understand the interplay between their temperature structures and other atmospheric conditions. In particular, TiO has long been proposed to cause thermal inversions in hot Jupiters, depending on other factors such as stellar irradiation, C/O, and vertical mixing. TiO also has spectral features in the optical and near-infrared that have been detected. However, interpretations of TiO signatures rely on the accuracy of TiO opacity used in the models. The recently reported Toto TiO line list provides a new opportunity to investigate these dependencies, which is the goal of the present work. First, we investigate how the Toto line list affects observable transmission and emission spectra of hot Jupiters at low and high resolution. The improvement in the Toto line list compared to a previous line list results in observable differences in the model spectra, particularly in the optical at high resolution. Secondly, we explore the interplay between temperature structure, irradiation and composition with TiO as the primary source of optical opacity, using 1D self-consistent atmospheric models. Among other trends, we find that the propensity for thermal inversions due to TiO peaks at C/O$\sim$0.9, consistent with recent studies. Using these models, we further assess metrics to quantify thermal inversions due to TiO, compared to frequently-used Spitzer photometry, over a range in C/O, irradiation, metallicity, gravity and stellar type., Accepted for publication in MNRAS, 19 pages, 14 figures

A new line list for the A 2 Σ + − X 2 Π electronic transition of OH has been calculated. Line positions have been taken from the literature and refitted with Western’s PGOPHER program. Line intensities were calculated using a new ab initio Transition Dipole Moment Function (TDMF) obtained with Molpro 2012. The new TDMF and the potential functions from LeRoy’s RKR program have been used as input to LeRoy’s LEVEL program in order to calculate Transition Dipole Moment Matrix Elements (TDMMEs). These matrix elements were transformed from Hund’s case (b) to Hund’s case (a) as required for the PGOPHER program using the method of Brooke et al. [JQSRT 2016; 168: 142–157] The line list was calculated with PGOPHER for bands with v ′ = 0 − 4 in the A 2 Σ + state and v ″ = 0 − 9 for the X2Π state.

A new linelist for the A3Π– X 3 Σ − electronic transition of NH has been prepared using line positions from the literature and calculated line intensities. High level ab initio calculations were performed with the MOLPRO program to obtain the A–X transition dipole moment function. Potential energy curves and line strengths were calculated with Le Roy’s RKR1 and LEVEL programs. Line intensities and Einstein A values were calculated with Western’s PGOPHER program after converting the Hund’s case (b) output of LEVEL to Hund’s case (a) input needed for PGOPHER . The Herman–Wallis effect is included in the Einstein A calculations of the bands for the levels with v ′ = 0 − 2 and v ″ = 0 − 6 .

We investigate the Fe, C, N, O, Mg, Al, Si, K, Ca, Ce and Nd abundances of 2283 red giant stars in 31 globular clusters from high-resolution spectra observed in both the northern and southern hemisphere by the SDSS-IV APOGEE-2 survey. This unprecedented homogeneous dataset, largest to date, allows us to discuss the intrinsic Fe spread, the shape and statistics of Al-Mg and N-C anticorrelations as a function of cluster mass, luminosity, age and metallicity for all 31 clusters. We find that the Fe spread does not depend on these parameters within our uncertainties including cluster metallicity, contradicting earlier observations. We do not confirm the metallicity variations previously observed in M22 and NGC 1851. Some clusters show a bimodal Al distribution, while others exhibit a continuous distribution as has been previously reported in the literature. We confirm more than 2 populations in $\omega$ Cen and NGC 6752, and find new ones in M79. We discuss the scatter of Al by implementing a correction to the standard chemical evolution of Al in the Milky Way. After correction, its dependence on cluster mass is increased suggesting that the extent of Al enrichment as a function of mass was suppressed before the correction. We observe a turnover in the Mg-Al anticorrelation at very low Mg in $\omega$ Cen, similar to the pattern previously reported in M15 and M92. $\omega$ Cen may also have a weak K-Mg anticorrelation, and if confirmed, it would be only the third cluster known to show such a pattern., Comment: Published in MNRAS, 31 pages, 24 figures, 7 tables. Further typos are corrected, now identical in text, figures and tables to the published paper

Gas cells containing ammonia and methane at atmospheric pressure were custom-made in our chemical laboratory. Low-resolution near-infrared spectroscopy of these gas cells were collected in our optical laboratory. They are compared with simulated spectra using the high-resolution transmission molecular absorption database (HITRAN) for temperatures of 300 K and 500 K, and with near-infrared spectra of late-T and Y dwarfs, Jupiter and Saturn. We selected for this investigation the spectral region between 1.5 and 1.7 microns (H-band) because it is covered by the Euclid red grism, it is particularly sensitive to the relative proportions of ammonia and methane opacity, and it is free from strong contributions of other abundant molecules such as water vapour. The laboratory spectra showed that the ammonia and methane features that are present in the simulations using the HITRAN database are incomplete. Using our laboratory spectra, we propose a modified version of the NH3-H spectral ratio with expanded integration limits that increases the amplitude of variation of the index with respect to spectral type. Combinations of our laboratory spectra were used to find the best fits to the observed spectra with the relative absorption ratio of ammonia to methane as a free parameter. A relationship was found between the T$\rm_{eff}$ and the ratio of ammonia to methane from spectral classes T5 to Y2 (1100 K -- 350 K), in qualitative fairly good agreement with theoretical predictions for high gravity objects and temperatures from 1100 K to 500 K. The ammonia to methane ratios in late-T and Y dwarfs are similar to that of Jupiter, suggesting a similar chemical composition. Simulations of the spectroscopic performance of Euclid suggest that it will yield T$\rm_{eff}$ values and ratios of ammonia to methane for over 10$^3$ late T dwarfs in the whole wide survey., 5 pages, 5 figures, accepted for publication in Astronomy & Astrophysics Letters

The updated H-band spectral line list (from \lambda 15,000 - 17,000\AA) adopted by the Apache Point Observatory Galactic Evolution Experiment (APOGEE) for the SDSS IV Data Release 16 (DR16) is presented here. The APOGEE line list is a combination of atomic and molecular lines with data from laboratory, theoretical, and astrophysical sources. Oscillator strengths and damping constants are adjusted using high signal-to-noise, high-resolution spectra of the Sun and alpha Boo (Arcturus) as "standard stars". Updates to the DR16 line list, when compared to the previous DR14 version, are the inclusion of molecular H_2O and FeH lines, as well as a much larger (by a factor of ~4) atomic line list, which includes significantly more transitions with hyperfine splitting. More recent references and line lists for the crucial molecules CO and OH were used, as well as for C_2 and SiH. In contrast to DR14, DR16 contains measurable lines from the heavy neutron-capture elements cerium (as Ce II), neodymium (as Nd II), and ytterbium (as Yb II), as well as one line from rubidium (as Rb I), that may be detectable in a small fraction of APOGEE red giants., Comment: 29 pages, 11 figures, accepted by AJ

The combination of asteroseismologically-measured masses with abundances from detailed analyses of stellar atmospheres challenges our fundamental knowledge of stars and our ability to model them. Ancient red-giant stars in the Galactic thick disc are proving to be most troublesome in this regard. They are older than 5 Gyr, a lifetime corresponding to an initial stellar mass of about $1.2{\mathrm{M}_{\odot}}$. So why do the masses of a sizeable fraction of thick-disc stars exceed $1.3{\mathrm{M}_{\odot}}$, with some as massive as $2.3{\mathrm{M}_{\odot}}$ ? We answer this question by considering duplicity in the thick-disc stellar population using a binary population-nucleosynthesis model. We examine how mass transfer and merging affect the stellar mass distribution and surface abundances of carbon and nitrogen. We show that a few per cent of thick-disc stars can interact in binary star systems and become more massive than $1.3{\mathrm{M}_{\odot}}$. Of these stars, most are single because they are merged binaries. Some stars more massive than $1.3{\mathrm{M}_{\odot}}$ form in binaries by wind mass transfer. We compare our results to a sample of the APOKASC data set and find reasonable agreement except in the number of these thick-disc stars more massive than $1.3{\mathrm{M}_{\odot}}$. This problem is resolved by the use of a logarithmically-flat orbital-period distribution and a large binary fraction., Comment: This is a pre-copyedited, author-produced version of an article accepted for publication in Monthly Notices of the Royal Astronomical Society following peer review. The version of record [Robert Izzard, 'Binary stars in the Galactic thick disc', Monthly Notices of the Royal Astronomical Society, accepted 7th Sep. 2017] is at https://academic.oup.com/mnras/article-lookup/doi/10.1093/mnras/stx2355

Increasing the statistics of evolved massive stars in the Local Group enables investigating their evolution at different metallicities. During the late stages of stellar evolution, the physics of some phenomena, such as episodic and systematic mass loss, are not well constrained. For example, the physical properties of red supergiants (RSGs) in different metallicity regimes remain poorly understood. Thus, we initiated a systematic study of RSGs in dwarf irregular galaxies (dIrrs) in the Local Group. The target selection is based on 3.6 $\mu$m and 4.5 $\mu$m photometry from archival Spitzer Space Telescope images of nearby galaxies. We selected 46 targets in the dIrrs IC 10, IC 1613, Sextans B, and the Wolf-Lundmark-Melotte (WLM) galaxy that we observed with the GTC-OSIRIS and VLT-FORS2 instruments. We used several photometric techniques together with a spectral energy distribution analysis to derive the luminosities and effective temperatures of known and newly discovered RSGs. We identified and spectroscopically confirmed 4 new RSGs, 5 previously known RSGs, and 5 massive asymptotic giant branch (AGB) stars. We added known objects from previous observations. In total, we present spectral classification and fundamental physical parameters of 25 late-type massive stars in the following dIrrs: Sextans A, Sextans B, IC 10, IC 1613, Pegasus, Phoenix, and WLM. This includes 17 RSGs and 8 AGB stars that have been identified here and previously. Based on our observational results and PARSEC evolutionary models, we draw the following conclusions: (i) a trend to higher minimum effective temperatures at lower metallicities and (ii) the maximum luminosity of RSGs appears to be constant at $log$($L/L$$_{\odot}$) $\approx$ $5.5$, independent of the metallicity of the host environment (up to $\mathrm{[Fe/H]}$ $\approx$ $-1$ dex)., Comment: 22 pages, 17 figures, in press (A&A)

In the era of large high-resolution spectroscopic surveys, high-quality spectra can contribute to our understanding of the Galactic chemical evolution, providing chemical abundances belonging to the different nucleosynthesis channels, and also providing constraints to stellar age. Some abundance ratios have been proven to be excellent indicators of stellar ages. We aim at providing an empirical relationship between stellar ages and [C/N] using, as calibrators, open star clusters observed by both the Gaia-ESO and APOGEE surveys. We use stellar parameters and abundances from the Gaia-ESO and APOGEE of the Galactic field and open cluster stars. Ages of star clusters are retrieved from the literature sources and validated using a common set of isochrones. We use the same isochrones to determine, for each age and metallicity, the surface gravity at which the first dredge-up and red giant branch bump occur. We study the effect of extra-mixing processes in our sample of giant stars, and we derive the mean [C/N] in evolved stars, including only stars without evidence of extra-mixing. Combining the Gaia-ESO and APOGEE samples of open clusters, we derive a linear relationship between [C/N] and logarithmic cluster ages. We apply our relationship to selected giant field stars in both Gaia-ESO and APOGEE. We find an age separation between thin and thick disc stars and age trends within their populations, with an increasing age towards lower metallicity populations. With such empirical relationship, we are able to provide an age estimate for giant stars in which C and N abundances are measured. Isochrone fitting is less sensitive for giant than dwarf stars at the turn off. The present method can be thus considered as an additional tool to give an independent estimate of the age of giant stars, with uncertainties in their ages comparable to those obtained using isochrone fitting for dwarf stars., Comment: 28 pages, 24 figures. Accepted by A&A

We previously explored the circumstellar effects on the Rb and Zr abundances in massive Galactic O-rich AGB stars. Here we are interested in the role of the extended atmosphere in the case of Li and Ca. Li is an important indicator of HBB while the total Ca in these stars could be affected by neutron captures. The Li abundances were previously studied with hydrostatic models, while the Ca abundances have been determined for the first time. We use a modified version of Turbospectrum and consider the presence of a gaseous circumstellar envelope and radial wind. The new Li abundances derived with the pseudo-dynamical models are very similar to those obtained from hydrostatic models (the average difference is 0.18 dex), with no difference for Ca. The Li and Ca content in these stars is only slightly affected by the presence of a circumstellar envelope. We also found that the Li I and Ca I line profiles are not very sensitive to variations of the model wind parameters. The new Li abundances confirm the Li-rich nature of the sample stars, supporting the activation of HBB in massive Galactic AGB stars. This is in good agreement with the theoretical predictions for solar metallicity AGB models from ATON, Monash, and NuGrid/MESA but is at odds with the FRUITY database, which predicts no HBB leading to the production of Li. Most sample stars display nearly solar Ca abundances that are consistent with the available s-process nucleosynthesis models for solar metallicity massive AGB stars, which predict overproduction of 46Ca relatively to the other Ca isotope and the creation of the radiactive isotope 41Ca but no change in the total Ca abundance. A minority of the stars seem to show a significant Ca depletion (by up to 1.0 dex). Possible explanations are offered to explain their apparent and unexpected Ca depletion., 14 pages, 8 figures, accepted in A&A

We present elemental abundance analysis of high-resolution spectra for five giant stars, deriving Fe, Mg, Al, C, N, O, Si and Ce abundances, and spatially located within the innermost regions of the bulge globular cluster NGC 6522, based on H-band spectra taken with the multi-object APOGEE-north spectrograph from the SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey. Of the five cluster candidates, two previously unremarked stars are confirmed to have second-generation (SG) abundance patterns, with the basic pattern of depletion in C and Mg simultaneous with enrichment in N and Al as seen in other SG globular cluster populations at similar metallicity. } In agreement with the most recent optical studies, the NGC 6522 stars analyzed exhibit (when available) only mild overabundances of the s-process element Ce, contradicting the idea of the NGC 6522 stars being formed from gas enriched by spinstars and indicating that other stellar sources such as massive AGB stars could be the primary intra-cluster medium polluters. The peculiar abundance signature of SG stars have been observed in our data, confirming the presence of multiple generations of stars in NGC 6522., Comment: 13 pages, 8 figures, 4 tables, matches the accepted version in A&A

Accurate line lists are crucial for correctly modelling a variety of astrophysical phenomena, including stellar photospheres and the atmospheres of extrasolar planets. This paper presents a new line database Toto for the main isotopologues of titanium oxide (TiO): $^{46}\text{Ti}^{16}\text{O}$, $^{47}\text{Ti}^{16}\text{O}$, $^{48}\text{Ti}^{16}\text{O}$, $^{49}\text{Ti}^{16}\text{O}$, and $^{50}\text{Ti}^{16}\text{O}$. The $^{48}\text{Ti}^{16}\text{O}$ line list contains transitions with wave-numbers up to 30 000 cm−1, i.e. longwards of 0.33 μm. The Toto line list includes all dipole-allowed transitions between 13 low-lying electronic states (X 3Δ, a1Δ, d 1Σ+, E 3Π, A 3Φ, B3Π, C 3Δ, b 1Π, c1Φ, f1Δ, e 1Σ+). Ab initio potential energy curves (PECs) are computed at the icMRCI level and combined with spin–orbit and other coupling curves. These PECs and couplings are iteratively refined to match known empirical energy levels. Accurate line intensities are generated using ab initio dipole moment curves. The Toto line lists are appropriate for temperatures below 5000 K and contain 30 million transitions for $^{48}\text{Ti}^{16}\text{O}$; it is made available in electronic form via the CDS data centre and via www.exomol.com. Tests of the line lists show greatly improved agreement with observed spectra for objects such as M-dwarfs GJ876 and GL581.

CEMP-no stars, a subclass of carbon-enhanced metal-poor (CEMP) stars, are one of the most significant stellar populations in Galactic Archaeology, because they dominate the low end of the metallicity distribution function, providing information on the early star-formation and chemical-evolution history of the Milky Way and its satellite galaxies. Here we present an analysis of medium-resolution ($R \sim 1,800$) optical spectroscopy for a CEMP giant, SDSS J132755.56+333521.7, observed with the Large Binocular Telescope (LBT), one of the brightest ($g \sim 20.5$) members of the classical dwarf spheroidal galaxy, Canes Venatici I (CVn I). Many CEMP stars discovered to date have very cool effective temperatures ($T_{\mathrm{eff}}< 4500$ K), resulting in strong veiling by molecular carbon bands over their optical spectra at low/medium spectral resolution. We introduce a technique to mitigate the carbon-veiling problem to obtain reliable stellar parameters and validate this method with the LBT medium-resolution optical spectra of the ultra metal-poor ([Fe/H] = $-4.0$) CEMP-no dwarf, G 77-61, and seven additional very cool CEMP stars, which have published high-resolution spectroscopic parameters. We apply this technique to the LBT spectrum of SDSS J132755.56+333521.7. We find that this star is well-described with parameters $T_{\mathrm{eff}}=4530$ K, log $g=$ 0.7, [Fe/H] $ = -3.38$, and absolute carbon abundance $A$(C) = 7.23, indicating that it is likely the first Group III CEMP-no star identified in CVn I. The Group III identification of this star suggests that it is a member of the extremely metal-poor population in CVn I, which may have been accreted into its halo., 18 pages, 3 tables, 9 figures, accepted to the Astrophysical Journal (with minor revisions made after the referee's report)

We analyze a large sample of 885 GCs giants from the APOGEE survey. We used the Cannon results to separate the red giant branch and the asymptotic giant branch stars, not only allowing for a refinement of surface gravity from isochrones, but also providing an independent H-band spectroscopic method to distinguish stellar evolutionary status in clusters. We then use the BACCHUS code to derive metallicity, microturbulence, acroturbulence and many light-element abundances as well as the neutron-capture elements Nd and Ce for the first time from the APOGEE GCs data. Our independent analysis helped us to diagnose issues regarding the standard analysis of the APOGEE DR14 for low-metallicity GC stars. Furthermore, while we confirm most of the known correlations and anti-correlation trends (Na-O, Mg-Al,C-N), we discover that some stars within our most metal-poor clusters show an extreme Mg depletion and some Si enhancement but at the same time show some relative Al depletion, displaying a turnover in the Mg-Al diagram. These stars suggest that Al has been partially depleted in their progenitors by very hot proton-capture nucleosynthetic processes. Furthermore, we attempted to quantitatively correlate the spread of Al abundances with the global properties of GCs. We find an anti-correlation of the Al spread against clusters metallicity and luminosity, but the data do not allow to find clear evidence of a dependence of N against metallicity in the more metal-poor clusters. Large and homogeneously analyzed samples from on-going spectroscopic surveys unveil unseen chemical details for many clusters, including a turnover in the Mg-Al anti-correlation, thus yielding new constrains for GCs formation evolution models., 17 pages, 23 figures, accepted in A&A

Hydrodynamical (or 3D) and non-local thermodynamic equilibrium (NLTE) effects are known to affect abundance analyses. However, there are very few observational abundance testsof 3D and NLTE models. We developed a new way of testing the abundance predictions of 3D and NLTE models, taking advantage of large spectroscopic survey data. We use a line-by-line analysis of the Apache Point Observatory Galactic Evolution Experiment (APOGEE) spectra (H band) with the Brussels Automatic Code for Characterizing High accUracy Spectra (BACCHUS). We compute line-by-line abundances of Mg, Si, Ca, and Fe for a large number of globular cluster K giants in the APOGEE survey. We compare this line-by-line analysis against NLTE and 3D predictions. While the 1D-NLTE models provide corrections in the right direction, there are quantitative discrepancies between different models. We observe a better agreement with the data for the models including reliable collisional cross-sections. The agreement between data and models is not always satisfactory when the 3D spectra are computed in LTE. However, we note that for a fair comparison, 3D corrections should be computed with self-consistently derived stellar parameters, and not on 1D models with identical stellar parameters. Finally, we focus on 3D and NLTE effects on Fe lines in the H band, where we observe a systematic difference in abundance relative to the value from the optical. Our results suggest that the metallicities obtained from the H band are more accurate in metal-poor giants. More atomic data and extended self-consistent 3D-NLTE computations need to be made. The method we have developed for testing 3D and NLTE models could be extended to other lines and elements, and is particularly suited for large spectroscopic surveys., Comment: 13 pages, 9 figures, accepted in A&A

The recently discovered phosphorus-rich stars pose a challenge to stellar evolution and nucleosynthesis theory, as none of the existing models can explain their extremely peculiar chemical abundances pattern. Apart from the large phosphorus enhancement, such stars also show enhancement in other light (O, Mg, Si, Al) and heavy (e.g., Ce) elements. We have obtained high-resolution optical spectra of two optically bright phosphorus-rich stars (including a new P-rich star), for which we have deter-mined a larger number of elemental abundances (from C to Pb). We confirm the unusual light-element abundance pattern with very large enhancements of Mg, Si, Al, and P, and possibly some Cu enhancement, but the spectra of the new P-rich star is the only one to reveal some C(+N) enhancement.When compared to other appropriate metal-poor and neutron-capture enhanced stars, the two P-rich stars show heavy-element overabundances similar to low neutron density s-process nucleosynthesis,with high first- (Sr, Y, Zr) and second-peak (Ba, La, Ce, Nd) element enhancements (even some Pb enhancement in one star) and a negative [Rb/Sr] ratio. However, this s-process is distinct from the one occurring in asymptotic giant branch (AGB) stars. The notable distinctions encompass larger[Ba/La] and lower Eu and Pb than their AGB counterparts. Our observations should guide stellar nucleosynthesis theoreticians and observers to identify the P-rich star progenitor, which represents anew site for s-process nucleosynthesis, with important implications for the chemical evolution of our Galaxy., Comment: 10 pages, 4 figures, 1 table, accepted in ApJL

We present spectroscopic determinations of the effective temperatures, surface gravities and metallicities for 21 M-dwarfs observed at high-resolution (R $\sim$ 22,500) in the \textit{H}-band as part of the SDSS-IV APOGEE survey. The atmospheric parameters and metallicities are derived from spectral syntheses with 1-D LTE plane parallel MARCS models and the APOGEE atomic/molecular line list, together with up-to-date H$_{2}$O and FeH molecular line lists. Our sample range in $T_{\rm eff}$ from $\sim$ 3200 to 3800K, where eleven stars are in binary systems with a warmer (FGK) primary, while the other 10 M-dwarfs have interferometric radii in the literature. We define an $M_{K_{S}}$--Radius calibration based on our M-dwarf radii derived from the detailed analysis of APOGEE spectra and Gaia DR2 distances, as well as a mass-radius relation using the spectroscopically-derived surface gravities. A comparison of the derived radii with interferometric values from the literature finds that the spectroscopic radii are slightly offset towards smaller values, with $\Delta$ = -0.01 $\pm$ 0.02 $R{\star}$/$R_{\odot}$. In addition, the derived M-dwarf masses based upon the radii and surface gravities tend to be slightly smaller (by $\sim$5-10\%) than masses derived for M-dwarf members of eclipsing binary systems for a given stellar radius. The metallicities derived for the 11 M-dwarfs in binary systems, compared to metallicities obtained for their hotter FGK main-sequence primary stars from the literature, shows excellent agreement, with a mean difference of [Fe/H](M-dwarf - FGK primary) = +0.04 $\pm$ 0.18 dex, confirming the APOGEE metallicity scale derived here for M-dwarfs., Comment: Accepted to ApJ, 2 tables and 11 figures

Context. Barium stars are s-process enriched giants. They owe their chemical peculiarities to a past mass transfer phase. During this phase they were polluted by their binary companion, which at the time was an asymptotic giant branch (AGB) star, but is now an extinct white dwarf. Barium stars are thus ideal targets for understanding and constraining the s-process in low-and intermediate-mass AGB stars. Aims. We derive the abundances of a large number of heavy elements in order to shed light on the conditions of operation of the neutron source responsible for the production of s-elements in the former companions of the barium stars. Methods. Adopting a recently used methodology, we analyse a sample of eighteen highly enriched barium stars observed with the high-resolution HERMES spectrograph mounted on the Mercator telescope (La Palma). We determine the stellar parameters and abundances using MARCS model atmospheres. In particular, we derive the Nb-Zr ratio which was previously shown to be a sensitive thermometer for the s-process nucleosynthesis. Indeed, in barium stars, 93Zr has fully decayed into mono-isotopic 93Nb, so Nb/Zr is a measure of the temperature-sensitive 93Zr/Zr isotopic ratio. Results. HD 28159, previously classified as K5III and initially selected to serve as a reference cool K star for our abundance analysis, turns out to be enriched in s-process elements, and as such is a new barium star. Four stars are characterised by high nitrogen abundances, and among those three have high [Nb/Zr] and [hs/ls] ratios. The derived Zr and Nb abundances provide more accurate constraints on the s-process neutron source, identified to be 13C(α, n)16O for barium stars. The comparison with stellar evolution and nucleosynthesis models shows that the investigated barium stars were polluted by a low-mass (M ∼ 2-3 M⊙) AGB star. HD 100503 is potentially identified as a high metallicity analogue of carbon-enhanced metal-poor star enriched in both r-and s-process elements (CEMP-rs)., SCOPUS: ar.j, info:eu-repo/semantics/published

IC 166 is an intermediate-age open cluster ($\sim 1$ Gyr) which lies in the transition zone of the metallicity gradient in the outer disc. Its location, combined with our very limited knowledge of its salient features, make it an interesting object of study. We present the first high-resolution spectroscopic and precise kinematical analysis of IC 166, which lies in the outer disc with $R_{GC} \sim 12.7$ kpc. High resolution \textit{H}-band spectra were analyzed using observations from the SDSS-IV Apache Point Observatory Galactic Evolution Experiment (APOGEE) survey. We made use of the Brussels Automatic Stellar Parameter (BACCHUS) code to provide chemical abundances based on a line-by-line approach for up to eight chemical elements (Mg, Si, Ca, Ti, Al, K, Mn and Fe). The $\alpha-$element (Mg, Si, Ca and whenever available Ti) abundances, and their trends with Fe abundances have been analysed for a total of 13 high-likelihood cluster members. No significant abundance scatter was found in any of the chemical species studied. Combining the positional, heliocentric distance, and kinematic information we derive, for the first time, the probable orbit of IC 166 within a Galactic model including a rotating boxy bar, and found that it is likely that IC 166 formed in the Galactic disc, supporting its nature as an unremarkable Galactic open cluster with an orbit bound to the Galactic plane., Comment: 16 pages, 7 tables, 8 figures, accepted for publication in AJ

Aims. We report 20 new lithium-rich giants discovered within the Gaia-ESO Survey, including the first Li-rich giant with an evolutionary stage confirmed by CoRoT (Convection, Rotation and planetary Transits) data. We present a detailed overview of the properties of these 20 stars., Methods. Atmospheric parameters and abundances were derived in model atmosphere analyses using medium-resolution GIRAFFE or high-resolution UVES (Ultraviolet and Visual Echelle Spectrograph) spectra. These results are part of the fifth internal data release of the Gaia-ESO Survey. The Li abundances were corrected for non-local thermodynamical equilibrium effects. Other stellar properties were investigated for additional peculiarities (the core of strong lines for signs of magnetic activity, infrared magnitudes, rotational velocities, chemical abundances, and Galactic velocities). We used Gaia DR2 parallaxes to estimate distances and luminosities., Results. The giants have A(Li) > 2.2 dex. The majority of them (14 of 20 stars) are in the CoRoT fields. Four giants are located in the field of three open clusters, but are not members. Two giants were observed in fields towards the Galactic bulge, but likely lie in the inner disc. One of the bulge field giants is super Li-rich with A(Li) = 4.0 dex., Conclusions. We identified one giant with infrared excess at 22 mu m. Two other giants, with large v sin i, might be Li-rich because of planet engulfment. Another giant is found to be barium enhanced and thus could have accreted material from a former asymptotic giant branch companion. Otherwise, in addition to the Li enrichment, the evolutionary stages are the only other connection between these new Li-rich giants. The CoRoT data confirm that one Li-rich giant is at the core-He burning stage. The other giants are concentrated in close proximity to the red giant branch luminosity bump, the core-He burning stages, or the early-asymptotic giant branch. This is very clear from the Gaia-based luminosities of the Li-rich giants. This is also seen when the CoRoT Li-rich giants are compared to a larger sample of 2252 giants observed in the CoRoT fields by the Gaia-ESO Survey, which are distributed throughout the red giant branch in the T-eff-log g diagram. These observations show that the evolutionary stage is a major factor for the Li enrichment in giants. Other processes, such as planet accretion, contribute at a smaller scale.

Metal-poor globular clusters (GCs) exhibit intriguing Al-Mg anti-correlations and possible Si-Al correlations, which are important clues to decipher the multiple-population phenomenon. NGC 5053 is one of the most metal-poor GCs in the nearby Universe, and has been suggested to be associated with the Sagittarius (Sgr) dwarf galaxy, due to its similarity in location and radial velocity with one of the Sgr arms. In this work, we simulate the orbit of NGC 5053, and argue against a physical connection between Sgr and NGC 5053. On the other hand, the Mg, Al, and Si spectral lines, which are difficult to detect in the optical spectra of NGC 5053 stars, have been detected in the near-infrared APOGEE spectra. We use three different sets of stellar parameters and codes to derive the Mg, Al, and Si abundances. Regardless of which method is adopted, we see a large Al variation, and a substantial Si spread. Along with NGC 5053, metal-poor GCs exhibit different Mg, Al, and Si variations. Moreover, NGC 5053 has the lowest cluster mass among the GCs that have been identified to exhibit an observable Si spread until now., Comment: ApJ accepted. 14 pages, 12 figures

We present elemental abundance results from high resolution spectral analysis of three nitrogen-enhanced barium stars. The analysis is based on spectra obtained with the FEROS attached to 1.52m telescope at ESO, Chile. The spectral resolution is R~48000 and the spectral coverage spans from 3500-9000��\,. For the objects HD 51959 and HD 88035, we present the first time abundance analyses results. Although a few studies are available in literature on the object HD 121447, the results are significantly different from each other. We have therefore carried out a detailed chemical composition study for this object based on a high resolution spectrum with high S/N ratio, for a better understanding of the origin of the abundance patterns observed in this star. Stellar atmospheric parameters, the effective temperature, surface gravity, microturbulence and metallicity of the stars are determined from the LTE analysis using model atmospheres. The metallicity of HD 51959 and HD 88035 are found to be near-solar; they exhibit enhanced abundances of neutron-capture elements. HD 121447 is found to be moderately metal-poor with [Fe/H]=-0.65. While carbon is near-solar in the other two objects, HD 121447 shows carbon enhancement at a level, [C/Fe]=0.82. Neutron-capture elements are highly enhanced with [X/Fe]>2 (X: Ba, La, Pr, Nd, Sm) in this object. The alpha- and iron-peak elements show abundances very similar to field giants with the same metallicity. From kinematic analysis all the three objects are found to be members of thin disk population with a high probability of 0.99, 0.99 and 0.92 for HD 51959, HD 88035 and HD 121447 respectively., 13 pages, 13 figures, Accepted for publication in MNRAS

Context. Several works have found an increase of the abundances of the s-process neutron-capture elements in the youngest Galactic stellar populations. These trends provide important constraints on stellar and Galactic evolution and they need to be confirmed with large and statistically significant samples of stars spanning wide age and distance intervals. Aims. We aim to trace the abundance patterns and the time evolution of five s-process elements - two belonging to the first peak, Y and Zr, and three belonging to the second peak, Ba, La, and Ce - using the Gaia-ESO IDR5 results for open clusters and disc stars. Methods. From the UVES spectra of cluster member stars, we determined the average composition of clusters with ages >0.1 Gyr. We derived statistical ages and distances of field stars, and we separated them into thin and thick disc populations. We studied the time-evolution and dependence on metallicity of abundance ratios using open clusters and field stars whose parameters and abundances were derived in a homogeneous way. Results. Using our large and homogeneous sample of open clusters, thin and thick disc stars, spanning an age range larger than 10 Gyr, we confirm an increase towards young ages of s-process abundances in the solar neighbourhood. These trends are well defined for open clusters and stars located nearby the solar position and they may be explained by a late enrichment due to significant contribution to the production of these elements from long-living low-mass stars. At the same time, we find a strong dependence of the s-process abundance ratios on the Galactocentric distance and on the metallicity of the clusters and field stars. Conclusions. Our results, derived from the largest and most homogeneous sample of s-process abundances in the literature, confirm the growth with decreasing stellar ages of the s-process abundances in both field and open cluster stars. At the same time, taking advantage of the abundances of open clusters located in a wide Galactocentric range, these results offer a new perspective on the dependence of the s-process evolution on the metallicity and star formation history, pointing to different behaviours at various Galactocentric distances.© 2018 ESO., We are grateful to the referee for her/his comments and suggestions, which improved the quality of the paper. These data products have been processed by the Cambridge Astronomy Survey Unit (CASU) at the Institute of Astronomy, University of Cambridge, and by the FLAMES/UVES reduction team at INAF/Osservatorio Astrofisico di Arcetri. These data have been obtained from the Gaia-ESO Survey Data Archive, prepared and hosted by the Wide Field Astronomy Unit, Institute for Astronomy, University of Edinburgh, which is funded by the UK Science and Technology Facilities Council. This work was partly supported by the European Union FP7 programme through ERC grant number 320360 and by the Leverhulme Trust through grant RPG-2012-541. We acknowledge the support from INAF and Ministero dell' Istruzione, dell' Universita' e della Ricerca (MIUR) in the form of the grant >Premiale VLT 2012>. The results presented here benefit from discussions held during the Gaia-ESO workshops and conferences supported by the ESF (European Science Foundation) through the GREAT Research Network Programme. F.J.E. acknowledges financial support from ASTERICS project (ID: 653477, H2020-EU.1.4.1.1. - Developing new world-class research infrastructures). S. D. acknowledges support from Comite Mixto ESO-GOBIERNO DE CHILE. AB thanks for support from the Millenium Science Initiative, Chilean Ministry of Economy. This project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 664931. E.D.M., V.A. and S.G.S. acknowledge the support from Fundacao para a Ciencia e a Tecnologia (FCT, Portugal) through the research grant through national funds and by FEDER through COMPETE2020 by grants UID/FIS/04434/2013 & POCI-01-0145-FEDER-007672, PTDC/FIS-AST/1526/2014 & POCI-01-0145-FEDER-016886 and PTDC/FIS-AST/7073/2014 & POCI-01-0145-FEDER-016880. E.D-M., V.A. and S.G.S also acknowledge support from FCT through Investigador FCT contracts nr. IF/00849/2015/CP1273/CT0003, IF/00650/2015/CP1273/CT0001 and IF/00028/2014/CP1215/CT0002. T.B. was supported by the project grant >The New Milky> from the Knut and Alice Wallenberg foundation. T.M. acknowledges support provided by the Spanish Ministry of Economy and Competitiveness (MINECO) under grant AYA-2017-88254-P. R.S. acknowledges support from the Polish Ministry of Science and Higher Education. E.J.A. acknowledges financial support from MINECO, Spain, and FEDER funds through grant AYA2016-75931-C2-1-P.