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Single-photon avalanche detectors (SPADs) are well-suited for satellite-based quantum communication because of their advantageous operating characteristics as well as their relatively straightforward and robust integration into satellite payloads. However, space-borne SPADs will encounter damage from space radiation, which usually manifests itself in the form of elevated dark counts. Methods for mitigating this radiation damage have been previously explored, such as thermal and optical (laser) annealing. Here we investigate in a lab, using a CubeSat payload, laser annealing protocols in terms of annealing laser power and annealing duration, for their possible later use in orbit. Four Si SPADs (Excelitas SLiK) irradiated to an equivalent of 10 years in low Earth orbit exhibit very high dark count rates (>300 kcps at -22 C operating temperature) and significant saturation effects. We show that annealing them with optical power between 1 and 2 W yields reduction in dark count rate by a factor of up to 48, as well as regaining SPAD sensitivity to a very faint optical signal (on the order of single photon) and alleviation of saturation effects. Our results suggest that an annealing duration as short as 10 seconds can reduce dark counts, which can be beneficial for power-limited small-satellite quantum communication missions. Overall, annealing power appears to be more critical than annealing duration and number of annealing exposures.

We present the experimental results of the first reference frame independent time bin quantum key distribution. Despite a lack of active phase stabilization of the interferometers, 0.078 asymptotic secret key bits per second were generated.

Spin-orbit entangled photon states with a 2D lattice structure are generated and implemented in a remote state preparation protocol. These novel structured waves provide a method for quantum sensing and manipulation of periodic structures.

Theoretical modeling and experimental verification demonstrate that pair of identical polarization maintaining fibers (PMF), with a relative rotation angle of 90°, will preserve any linear polarization state entering the fiber pair.

We build and test a single-photon detector based on a Si avalanche photodiode Excelitas 30902SH thermoelectrically cooled to -100 deg. C. Our detector has dark count rate below 1 Hz, 500 um diameter photosensitive area, photon detection efficiency around 50%, afterpulsing less than 0.35%, and timing jitter under 1 ns. These characteristics make it suitable for long-distance free-space quantum communication links, which we briefly discuss. We also report an improved method that we call long-time afterpulsing analysis, used to determine and visualise long trap lifetimes at different temperatures., Comment: 10 pages, 9 figures, 1 table

Higher dimensional quantum systems (qudits) present a potentially more efficient means, compared to qubits, for implementing various information theoretic tasks. One of the ubiquitous resources in such explorations is entanglement. Entanglement monotones (EMs) are of key importance, particularly for assessing the efficacy of a given entangled state as a resource for information theoretic tasks. Till date, investigations towards determination of EMs have focused on providing their tighter lower bounds. There is yet no general scheme available for direct determination of the EMs. Consequently, an empirical determination of any EM has not yet been achieved for entangled qudit states. The present paper fills this gap, both theoretically as well as experimentally. First, we derive analytical relations between statistical correlation measures i.e. mutual predictability (MP), mutual information (MI) and Pearson correlation coefficient (PCC) and standard EMs i.e. negativity (N) and entanglement of formation (EOF) in arbitrary dimensions. As a proof of concept, we then experimentally measure MP, MI and PCC of two-qutrit pure states and determine their N and EOF using these derived relations. This is a useful addition to the experimenter’s toolkit wherein by using a limited number of measurements (in this case 1 set of measurements), one can directly measure the EMs in a bipartite arbitrary dimensional system. We obtain the value of N for our bipartite qutrit to be 0.907 ± 0.013 and the EOF to be 1.323 ± 0.022. Since the present scheme enables determination of more than one EM by the same limited number of measurements, we argue that it can serve as a unique experimental platform for quantitatively comparing and contrasting the operational implications of EMs as well as showing their non-monotonicity for a given bipartite pure qudit state.

Quantum information processing and quantum communication are novel protocols that originate from the very fundamental and philosophical questions on superposition and entanglement raised since the early days of quantum mechanics. Strikingly, these new protocols offer capabilities beyond communication task possible with classical physics. One very important example is the secure key exchange based on the transmission of individual quantum signals between communication partners. The big vision and frontier in the field of quantum communication research is the development of a Quantum Internet, which establishes entanglement between many different users and devices. Extending today’s internet, the Quantum Internet will readily transfer quantum bits, rather than classical bits, between users near and far and over multiple different channels and could be used for secure communications, quantum computer networks and metrological applications. I will discuss recent advances on implementations and tools useful for generating and distributing photonic quantum entanglement over robust channels including. Time-bin encoding and reference-frame-free protocols. I will also present an overview of the upcoming Canadian quantum communication satellite QEYSSAT.

Concerted efforts are underway to establish an infrastructure for a global quantum internet to realise a spectrum of quantum technologies. This will enable more precise sensors, secure communications, and faster data processing. Quantum communications are a front-runner with quantum networks already implemented in several metropolitan areas. A number of recent proposals have modelled the use of space segments to overcome range limitations of purely terrestrial networks. Rapid progress in the design of quantum devices have enabled their deployment in space for in-orbit demonstrations. We review developments in this emerging area of space-based quantum technologies and provide a roadmap of key milestones towards a complete, global quantum networked landscape. Small satellites hold increasing promise to provide a cost effective coverage required to realised the quantum internet. We review the state of art in small satellite missions and collate the most current in-field demonstrations of quantum cryptography. We summarise important challenges in space quantum technologies that must be overcome and recent efforts to mitigate their effects. A perspective on future developments that would improve the performance of space quantum communications is included. We conclude with a discussion on fundamental physics experiments that could take advantage of a global, space-based quantum network., 26 pages, 9 figures. Comments welcome. This paper is a preprint of a paper submitted to IET Quantum Communication. If accepted, the copy of record will be available at the IET Digital Library

Optical beams with periodic lattice structures have broadened the study of structured waves. In the present work, we generate spin-orbit entangled photon states with a lattice structure and use them in a remote state preparation protocol. We sequentially measure spatially-dependent correlation rates with an electron-multiplying intensified CCD camera and verify the successful remote preparation of spin-orbit states by performing pixel-wise quantum state tomography. Control of these novel structured waves in the quantum regime provides a method for quantum sensing and manipulation of periodic structures., 6 pages, 4 figures

Honeywell Aerospace is implementing on behalf of the Canadian Space Agency the Quantum Encryption and Science Satellite (QEYSSat), a Canadian-owned and operated scientific and technology demonstration mission aimed at developing the next-generation of secure communications infrastructure backed by quantum physics. The mission management is led by the Canadian Space Agency and the science is led by the Institute for Quantum Computing at the University of Waterloo. Quantum key distribution (QKD) is a method for issuing, via single-photon transmission, verifiably-confidential encryption keys between two parties. This capability is a powerful tool for the transfer of sensitive data (e.g. financial transactions, health records, etc.), however current terrestrial QKD networks are limited to a few hundred kilometres in geographic reach between nodes. The QEYSSat mission will use a satellite receiver as a trusted node to demonstrate the distribution of secure keys between ground stations separated by at least 400 km. In addition, Honeywell intends to fly an optical intersatellite link (OISL) terminal as a hosted payload on this mission. The QEYSSat mission will utilize both weak coherent pulse (WCP) sources and entangled photon sources in an uplink configuration to study the performance of QKD, and to perform Bell tests of long-range quantum entanglement. Honeywell is building the QKD receiver terminal consisting of a front-end telescope, a precision pointing and tracking system and single-photon detectors. Major technical challenges include polarization management throughout the optical chain, accurate pointing and tracking, and suppression of background and stray light sources. To address these challenges, Honeywell is leveraging its existing commercial optical communications solutions to meet the more stringent performance requirements for space-based QKD. The QKD terminal architecture consists of an afocal front-end telescope, a wide FOV high-precision pointing and tracking assembly, a polarization analyzer and single-photon photodetector system. A large-diameter on-axis telescope for geostationary optical communications forms the basis for the terminal’s front-end optics, and Honeywell’s commercial Optical Pointing and Tracking Relay Assembly for intersatellite Communications (OPTRAC) has been adapted as a quantum-ready pointing and tracking unit (QTRAC). For each element, substantial effort has been made to develop an optical system that preserves single-photon states with high fidelity despite the large number of optical surfaces in the chain. The optical assembly for the QKD terminal was developed and tested at the breadboard level in 2020; this paper will highlight the development and testing of these units as well as the overall architecture and concept of the QEYSSat mission.

For quantum communications, the use of Earth-orbiting satellites to extend distances has gained significant attention in recent years, exemplified in particular by the launch of the Micius satellite in 2016. The performance of applied protocols such as quantum key distribution (QKD) depends significantly upon the transmission efficiency through the turbulent atmosphere, which is especially challenging for ground-to-satellite uplink scenarios. Adaptive optics (AO) techniques have been used in astronomical, communication, and other applications to reduce the detrimental effects of turbulence for many years, but their applicability to quantum protocols, and their requirements specifically in the uplink scenario, are not well established. Here, we model the effect of the atmosphere on link efficiency between an Earth station and a satellite using an optical uplink, and how AO can help recover from loss due to turbulence. Examining both low-Earth-orbit and geostationary uplink scenarios, we find that a modest link transmissivity improvement of about 3dB can be obtained in the case of a co-aligned downward beacon, while the link can be dramatically improved, up to 7dB, using an offset beacon, such as a laser guide star. AO coupled with a laser guide star would thus deliver a significant increase in the secret key generation rate of the QKD ground-to-space uplink system, especially as reductions of channel loss have favourably nonlinear key-rate response within this high-loss regime., 9 pages, 5 figures, clarifying updates and simulation updates

We develop a polarization characterization platform for optical devices in free-space quantum communications. We demonstrate an imaging polarimeter, which analyzes both incident polarization states and the angle of incidence, attached to a six-axis collaborative robot arm, enabling polarization characterization at any position and direction with consistent precision. We present a detailed description of each subsystem including the calibration and polarization-test procedure, and analyze polarization-measurement errors caused by imperfect orientations of the robot arm using a Mueller-matrix model of polarimeters at tilt incidence. We perform a proof-of-principle experiment for an angle-dependent polarization test for a commercial silver-coated mirror for which the polarization states of the reflected light can be accurately calculated. Quantitative agreement between the theory and experiment validates our methodology. We demonstrate the polarization test for a 20.3 cm lens designed for a quantum optical transmitter in Canada's Quantum Encryption and Science Satellite (QEYSSat) mission., Comment: 10 pages, 7 figures, 1 table

Secure optical communications networks are a functional requirement for many military, government, and civilian applications. Optical free space links provide security due to the small ground footprint of highly collimated laser beam patterns. Space-based optical communications provide an additional layer of security due to dynamic angular tracking requirements and remote orbiting infrastructure. The addition of Quantum Key Distribution (QKD) adds a third layer of safety through the use of physically unbreakable keys. The QEYSSat mission is scheduled to launch in 2022. This mission will carry a primary QKD science payload and a secondary high-speed optical communications demonstration payload. The QEYSSat secondary communications payload (QP2) is the latest space-based optical communications terminal designed to be amenable to low cost mass production methods, meeting the price targets of many planned low-earth-orbit optical communications constellations. The successful demonstration of both technologies on a single micro-satellite platform demonstrates the key technologies necessary to enable next generation high speed secure communications networks. In this paper we present an overview of the QEYSSAT optical payloads and describe secure architectures for QKD-enabled optical communications network applications.

The self-imaging, or Talbot Effect, that occurs with the propagation of periodically structured waves has enabled several unique applications in optical metrology, image processing, data transmission, and matter-wave interferometry. In this work, we report on the first demonstration of a Talbot Effect with single photons prepared in a lattice of orbital angular momentum (OAM) states. We observe that upon propagation, the wavefronts of the single photons manifest self-imaging whereby the OAM lattice intensity profile is recovered. Furthermore, we show that the intensity at fractional Talbot distances is indicative of a periodic helical phase structure corresponding to a lattice of OAM states. This phenomenon is a powerful addition to the toolbox of orbital angular momentum and spin-orbit techniques that have already enabled many recent developments in quantum optics., Comment: 6 pages, 3 figures, 1 table

The Hong-Ou-Mandel (HOM) effect ranks among the most notable quantum interference phenomena, and is central to many applications in quantum technologies. The fundamental effect appears when two independent and indistinguishable photons are superimposed on a beam splitter, which achieves a complete suppression of coincidences between the two output ports. Much less studied, however, is when the fields share coherence (continuous-wave lasers) or mode envelope properties (pulsed lasers). In this case, we expect the existence of two distinct and concurrent HOM interference regimes: the traditional HOM dip on the coherence length time scale, and a structured HOM interference pattern on the pulse length scale. We develop a theoretical framework that describes HOM interference for laser fields having arbitrary temporal waveforms and only partial overlap in time. We observe structured HOM interference from a continuous-wave laser via fast polarization modulation and time-resolved single photon detection fast enough to resolve these structured HOM dips., Comment: 11 pages, 4 figures

Avalanche photodiodes (APDs) are well-suited for single-photon detection on quantum communication satellites as they are a mature technology with high detection efficiency without requiring cryogenic cooling. They are, however, prone to significantly increased thermal noise caused by in-orbit radiation damage. Previous work demonstrated that a one-time application of thermal annealing reduces radiation-damage-induced APD thermal noise. Here we examine the effect of cyclical proton irradiation and thermal annealing. We use an accelerated testing environment which emulates a realistic two-year operating profile of a satellite in low-Earth-orbit. We show that repeated thermal annealing is effective at maintaining thermal noise of silicon APDs within a range suitable for quantum key distribution throughout the nominal mission life, and beyond. We examine two strategies -- annealing at a fixed period of time, and annealing only when the thermal noise exceeds a pre-defined limit. We find both strategies exhibit similar thermal noise at end-of-life, with a slight overall advantage to annealing conditionally. We also observe that afterpulsing probability of the detector increases with cumulative proton irradiation. This knowledge helps guide design and tasking decisions for future space-borne quantum communication applications., Comment: 7 pages, 8 figures

We investigate the impact of fiber birefringence and spontaneous Raman scattering on the properties of photon pairs that are generated by the spontaneous four-wave mixing process in birefringent fibers. Starting from the formulation of the theory of four-wave mixing, we show a theoretical model for a generated optical field with the consideration of the Raman scattering and a Gaussian-distributed pump. The theoretical model is then applied for deriving the closed expressions of the photon-pair spectral properties as a function of the fiber birefringence. Also, with the modeled Raman gain, we evaluate the reduction of the pair production rate due to the presence of the Raman effect as well as the contributions of the Raman-scattered photons over a broad wavelength range. The predictions are experimentally verified with a commercial polarization-maintaining fiber.

Optical coatings are widespread in everyday life, from camera lenses and glasses, to complex optics experiments. Thus, a simple, reliable sensor that can quickly and inexpensively analyze optical coatings is a valuable laboratory tool. Such a device can help identify optical coatings and characterize the transmission spectra of optical components used in an experiment. We present the design and characterization of a LED-based spectrophotometer and demonstrate its ability to identify different optical coatings. Our approach uses ten LEDs that cover a spectrum from 365 nm to 1000 nm. The optical coating sensor is automated, portable, inexpensive, user-friendly, and simple to build.

The ability of an eavesdropper (Eve) to perform an intercept-resend attack on a free-space quantum key distribution (QKD) receiver by precisely controlling the incidence angle of an attack laser has been previously demonstrated. However, such an attack could be ineffective in the presence of atmospheric turbulence due to beam wander and spatial mode aberrations induced by the air's varying index of refraction. We experimentally investigate the impact turbulence has on Eve's attack on a free-space polarization-encoding QKD receiver by emulating atmospheric turbulence with a spatial light modulator. Our results identify how well Eve would need to compensate for turbulence to perform a successful attack by either reducing her distance to the receiver, or using beam wavefront correction via adaptive optics. Furthermore, we use an entanglement-breaking scheme to find a theoretical limit on the turbulence strength that hinders Eve's attack., Comment: 10 pages, 5 figures

We demonstrate two approaches for unbalanced interferometers as time-bin qubit analyzers for quantum communication, robust against mode distortions and polarization effects as expected from free-space quantum communication systems including wavefront deformations, path fluctuations, pointing errors, and optical elements. Despite strong spatial and temporal distortions of the optical mode of a time-bin qubit, entangled with a separate polarization qubit, we verify entanglement using the Negative Partial Transpose, with the measured visibility of up to $0.85\ifmmode\pm\else\textpm\fi{}0.01$. The robustness of the analyzers is further demonstrated for various angles of incidence up to $0.{2}^{\ensuremath{\circ}}$. The output of the interferometers is coupled into multimode fiber yielding a high system throughput of 0.74. Therefore, these analyzers are suitable and efficient for quantum communication over multimode optical channels.

Despite its widespread use in fiber optics, encoding quantum information in photonic time-bin states is usually considered impractical for free-space quantum communication as turbulence-induced spatial distortion impedes the analysis of time-bin states at the receiver. Here, we demonstrate quantum key distribution using time-bin photonic states distorted by turbulence and depolarization during free-space transmission. Utilizing a novel analyzer apparatus, we observe stable quantum bit error ratios of 5.32 %, suitable for generating secure keys, despite significant wavefront distortions and polarization fluctuations across a 1.2 km channel. This shows the viability of time-bin quantum communication over long-distance free-space channels, which will simplify direct fiber/free-space interfaces and enable new approaches for practical free-space quantum communication over multi-mode, turbulent, or depolarizing channels.

We study a novel protocol for reference frame independent (RFI) quantum key distribution (QKD) using six states for Alice and four states for Bob, while previous RFI protocols require a six state analyzer for Bob. Our protocol can generate a secure key for any possible phase of the entangled state, provided the variation is small compared to the measurement rate, shown by our numerical key rate analysis. We perform a proof-of-principle experiment using polarization entangled photon pairs. In the presence of a varying rotational phase, we obtain a consistently low error rate of less than $4\%$ indicating the feasibility of this protocol for QKD. Our protocol is hence beneficial but not limited to applications in satellite or mobile free-space QKD, where a communication node must limit resources and restrict the number of measured states to four instead of six., Comment: 5 pages, 3 figures

We designed and implemented a novel combination of a Sagnac-interferometer with a Mach–Zehnder interferometer for a source of polarization-entangled photons. The new versatile configuration does not require multi-wavelength polarization optics, yet it performs with a good polarization quality and phase-stability over a wide wavelength range. We demonstrate the interferometer using only standard commercial optics to experimentally realize the pulsed generation of polarization-entangled photon-pairs at wavelengths of 764 nm and 1221 nm via type-I spontaneous four-wave mixing in a polarization-maintaining fiber. Polarization entanglement was verified by a polarization-correlation measurement with a visibility of 95.5% from raw coincidence counts and the violation of the Clauser–Horne–Shimony–Holt (CHSH) inequality with S = 2.70 ± 0.04. The long-term phase-stability was characterized by an Allan deviation of 8° over an integration time of about 1 h with no active phase-stabilization.

Bringing quantum science and technology to the space frontier offers exciting prospects for both fundamental physics and applications such as long-range secure communication and space-borne quantum probes for inertial sensing with enhanced accuracy and sensitivity. But despite important terrestrial pathfinding precursors on common microgravity platforms and promising proposals to exploit the significant advantages of space quantum missions, large-scale quantum test beds in space are yet to be realised due to the high costs and lead times of traditional ‘Big Space’ satellite development. But the ‘small space’ revolution, spearheaded by the rise of nanosatellites such as CubeSats, is an opportunity to greatly accelerate the progress of quantum space missions by providing easy and affordable access to space and encouraging agile development. We review space quantum science and technology, CubeSats and their rapidly developing capabilities and how they can be used to advance quantum satellite systems.

We experimentally demonstrate optical control of negative-feedback avalanche diode (NFAD) detectors using bright light. We deterministically generate fake single-photon detections with a better timing precision than normal operation. This could potentially open a security loophole in quantum cryptography systems. We then show how monitoring the photocurrent through the avalanche photodiode can be used to reveal the detector is being blinded.

Quantum key distribution (QKD) promises information theoretic secure key as long as the device performs as assumed in the theoretical model. One of the assumptions is an absence of information leakage about individual photon detection outcomes of the receiver unit. Here we investigate the information leakage from a QKD receiver due to photon emission caused by detection events in single-photon detectors (backflash). We test commercial silicon avalanche photodiodes and a photomultiplier tube, and find that the former emit backflashes. We study the spectral, timing and polarization characteristics of these backflash photons. We experimentally demonstrate on a free-space QKD receiver that an eavesdropper can distinguish which detector has clicked inside it, and thus acquire secret information. A set of countermeasures both in theory and on the physical devices are discussed., Comment: 9 pages, 7 figures

Satellite based quantum communications will enable long distances, or even global quantum networking, of quantum optical signals. We give an overview on the activities towards implementing proposed Canadian Quantum Satellite Mission, Quantum Encryption and Science Satellite (QEYSSat) [1]. We will summarize laboratory tests of the payload components and its demonstration to establish quantum links between a ground station and an aircraft. These results establish the viability of a quantum communication receiver satellite.

Models of quantum systems on curved space-times lack sufficient experimental verification. Some speculative theories suggest that quantum properties, such as entanglement, may exhibit entirely different behavior to purely classical systems. By measuring this effect or lack thereof, we can test the hypotheses behind several such models. For instance, as predicted by Ralph and coworkers [T C Ralph, G J Milburn, and T Downes, Phys. Rev. A, 79(2):22121, 2009, T C Ralph and J Pienaar, New Journal of Physics, 16(8):85008, 2014], a bipartite entangled system could decohere if each particle traversed through a different gravitational field gradient. We propose to study this effect in a ground to space uplink scenario. We extend the above theoretical predictions of Ralph and coworkers and discuss the scientific consequences of detecting/failing to detect the predicted gravitational decoherence. We present a detailed mission design of the European Space Agency's (ESA) Space QUEST (Space - Quantum Entanglement Space Test) mission, and study the feasibility of the mission schema., Comment: 18 pages, 13 figures, included radiation damage to detectors in appendix

Nature Communications 5: Article number: 4997 (2014); Published: 26 September 2014; Updated: 26 March 2018 The original HTML version of this Article had an incorrect article number of 3997; it should have been 4997. This has now been corrected in the HTML; the PDF version of the Article was correct from the time of publication.

We proposed tests of quantum communication in space, whereby an entangled photon Source is placed onboard the ISS, and two entangled photons are transmitted via a simultaneous down link and received at two distant ground stations.

The aim of the QIPS project (financed by ESA) is to explore quantum phenomena and to demonstrate quantum communication over long distances. Based on the current state-of-the-art a first study investigating the feasibility of space based quantum communication has to establish goals for mid-term and long-term missions, but also has to test the feasibility of key issues in a long distance ground-to-ground experiment. We have therefore designed a proof-of-concept demonstration for establishing single photon links over a distance of 144 km between the Canary Islands of La Palma and Tenerife to evaluate main limitations for future space experiments. Here we report on the progress of this project and present first measurements of crucial parameters of the optical free space link.

Quantum teleportation is a quintessential prerequisite of many quantum information-processing protocols.

Multiparticle quantum interference is critical for our understanding and exploitation of quantum information, and for fundamental tests of quantum mechanics. A remarkable example of multi-partite correlations is exhibited by the Greenberger-Horne-Zeilinger (GHZ) state. In a GHZ state, three particles are correlated while no pairwise correlation is found. The manifestation of these strong correlations in an interferometric setting has been studied theoretically since 1990 but no three-photon GHZ interferometer has been realized experimentally. Here we demonstrate three-photon interference that does not originate from two-photon or single photon interference. We observe phase-dependent variation of three-photon coincidences with 90.5 \pm 5.0 % visibility in a generalized Franson interferometer using energy-time entangled photon triplets. The demonstration of these strong correlations in an interferometric setting provides new avenues for multiphoton interferometry, fundamental tests of quantum mechanics and quantum information applications in higher dimensions., 7 pages, 7 figures

Avalanche photodiodes (APDs) are a practical option for space-based quantum communications requiring single-photon detection. However, radiation damage to APDs significantly increases their dark count rates and reduces their useful lifetimes in orbit. We show that high-power laser annealing of irradiated APDs of three different models (Excelitas C30902SH, Excelitas SLiK, and Laser Components SAP500S2) heals the radiation damage and substantially restores low dark count rates. Of nine samples, the maximum dark count rate reduction factor varies between 5.3 and 758 when operating at minus 80 degrees Celsius. The illumination power to reach these reduction factors ranges from 0.8 to 1.6 W. Other photon detection characteristics, such as photon detection efficiency, timing jitter, and afterpulsing probability, remain mostly unaffected. These results herald a promising method to extend the lifetime of a quantum satellite equipped with APDs., Comment: 10 pages, 9 figures, 2 tables

Quantum correlations are critical to our understanding of nature, with far-reaching technological and fundamental impact. These often manifest as violations of Bell's inequalities, bounds derived from the assumptions of locality and realism, concepts integral to classical physics. Many tests of Bell's inequalities have studied pairs of correlated particles; however, the immense interest in multi-particle quantum correlations is driving the experimental frontier to test systems beyond just pairs. All experimental violations of Bell's inequalities to date require supplementary assumptions, opening the results to one or more loopholes, the closing of which is one of the most important challenges in quantum science. Individual loopholes have been closed in experiments with pairs of particles and a very recent result closed the detection loophole in a six ion experiment. No experiment thus far has closed the locality loopholes with three or more particles. Here, we distribute three-photon Greenberger-Horne-Zeilinger entangled states using optical fibre and free-space links to independent measurement stations. The measured correlations constitute a test of Mermin's inequality while closing both the locality and related freedom-of-choice loopholes due to our experimental configuration and timing. We measured a Mermin parameter of 2.77 +/- 0.08, violating the inequality bound of 2 by over 9 standard deviations, with minimum tolerances for the locality and freedom-of-choice loopholes of 264 +/- 28 ns and 304 +/- 25 ns, respectively. These results represent a significant advance towards definitive tests of the foundations of quantum mechanics and practical multi-party quantum communications protocols., 13 pages, 8 figures