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Context: Mutual neutralization between cations and anions play an important role in determining the charge-balance in certain astrophysical environments. However, empirical data for such reactions involving complex molecular species has been lacking due to challenges in performing experimental studies, leaving the astronomical community to rely on decades old models with large uncertainties for describing these processes in the interstellar medium. Aims: To investigate the mutual neutralization (MN) reaction, C$_{60}^+$ + C$_{60}^-$ $\rightarrow$ C$_{60}^*$ + C$_{60}$, for collisions at interstellar-like conditions. Methods: The mutual neutralization reaction between C$_{60}^+$ and C$_{60}^-$ at collision energies of 100\,meV was studied using the Double ElectroStatic Ion Ring ExpEriment, DESIREE, and its merged-beam capabilities. To aid in the interpretation of the experimental results, semi-classical modeling based on the Landau-Zener approach was performed for the studied reaction. Results: We experimentally identify a narrow range of kinetic energies for the neutral reaction products. Modeling was used to calculate the quantum state-selective reaction probabilities, absolute cross sections, and rate coefficients of these MN reactions, using the experimental results as a benchmark. The MN cross sections are compared with model results for electron attachment to C$_{60}$ and electron recombination with C$_{60}^+$. Conclusions: The present results show that it is crucial to take mutual polarization effects, the finite sizes, and the final quantum states of both molecular ions into account for reliable predictions of MN rates expected to strongly influence the charge-balance and chemistry in, e.g., dense molecular clouds., Comment: 9 pages, 4 figures

Mid-infrared emission features probe the properties of ionized gas, and hot or warm molecular gas. The Orion Bar is a frequently studied photodissociation region (PDR) containing large amounts of gas under these conditions, and was observed with the MIRI IFU aboard JWST as part of the "PDRs4All" program. The resulting IR spectroscopic images of high angular resolution (0.2") reveal a rich observational inventory of mid-IR emission lines, and spatially resolve the substructure of the PDR, with a mosaic cutting perpendicularly across the ionization front and three dissociation fronts. We extracted five spectra that represent the ionized, atomic, and molecular gas layers, and measured the most prominent gas emission lines. An initial analysis summarizes the physical conditions of the gas and the potential of these data. We identified around 100 lines, report an additional 18 lines that remain unidentified, and measured the line intensities and central wavelengths. The H I recombination lines originating from the ionized gas layer bordering the PDR, have intensity ratios that are well matched by emissivity coefficients from H recombination theory, but deviate up to 10% due contamination by He I lines. We report the observed emission lines of various ionization stages of Ne, P, S, Cl, Ar, Fe, and Ni, and show how certain line ratios vary between the five regions. We observe the pure-rotational H$_2$ lines in the vibrational ground state from 0-0 S(1) to 0-0 S(8), and in the first vibrationally excited state from 1-1 S(5) to 1-1 S(9). We derive H$_2$ excitation diagrams, and approximate the excitation with one thermal (~700 K) component representative of an average gas temperature, and one non-thermal component (~2700 K) probing the effect of UV pumping. We compare these results to an existing model for the Orion Bar PDR and highlight the differences with the observations., Comment: 26 pages, 12 figures, 3 tables. Submitted to A&A, under review (1st revision)

We compute all refined sheaf counting invariants -- Vafa-Witten, reduced DT, stable pairs and Gopakumar-Vafa -- for all classes on local $K3$ surfaces. Along the way we develop rank 0 Vafa-Witten theory on $K3$ surfaces. An important feature of the calculation is that the ``instanton contribution" -- of sheaves supported scheme theoretically on $S$ -- to any of the invariants depends only on the square of the class, not its divisibility., Comment: 16 pages

Given one quasi-smooth derived space cut out of another by a section of a 2-term complex of bundles, we give two formulae for its virtual cycle. They are modelled on the the $p$-fields construction of Chang-Li and the Quantum Lefschetz principle, and recover these when applied to moduli spaces of (stable or quasi-) maps. When the complex is a single bundle we recover results of Kim-Kresch-Pantev., Comment: 16 pages

Most low-mass stars form in stellar clusters that also contain massive stars, which are sources of far-ultraviolet (FUV) radiation. Theoretical models predict that this FUV radiation produces photo-dissociation regions (PDRs) on the surfaces of protoplanetary disks around low-mass stars, impacting planet formation within the disks. We report JWST and Atacama Large Millimetere Array observations of a FUV-irradiated protoplanetary disk in the Orion Nebula. Emission lines are detected from the PDR; modelling their kinematics and excitation allows us to constrain the physical conditions within the gas. We quantify the mass-loss rate induced by the FUV irradiation, finding it is sufficient to remove gas from the disk in less than a million years. This is rapid enough to affect giant planet formation in the disk.

(Abridged) We investigate the impact of radiative feedback from massive stars on their natal cloud and focus on the transition from the HII region to the atomic PDR (crossing the ionisation front (IF)), and the subsequent transition to the molecular PDR (crossing the dissociation front (DF)). We use high-resolution near-IR integral field spectroscopic data from NIRSpec on JWST to observe the Orion Bar PDR as part of the PDRs4All JWST Early Release Science Program. The NIRSpec data reveal a forest of lines including, but not limited to, HeI, HI, and CI recombination lines, ionic lines, OI and NI fluorescence lines, Aromatic Infrared Bands (AIBs including aromatic CH, aliphatic CH, and their CD counterparts), CO2 ice, pure rotational and ro-vibrational lines from H2, and ro-vibrational lines HD, CO, and CH+, most of them detected for the first time towards a PDR. Their spatial distribution resolves the H and He ionisation structure in the Huygens region, gives insight into the geometry of the Bar, and confirms the large-scale stratification of PDRs. We observe numerous smaller scale structures whose typical size decreases with distance from Ori C and IR lines from CI, if solely arising from radiative recombination and cascade, reveal very high gas temperatures consistent with the hot irradiated surface of small-scale dense clumps deep inside the PDR. The H2 lines reveal multiple, prominent filaments which exhibit different characteristics. This leaves the impression of a "terraced" transition from the predominantly atomic surface region to the CO-rich molecular zone deeper in. This study showcases the discovery space created by JWST to further our understanding of the impact radiation from young stars has on their natal molecular cloud and proto-planetary disk, which touches on star- and planet formation as well as galaxy evolution., Comment: 52 pages, 30 figures, submitted to A&A

The JWST has captured the most detailed and sharpest infrared images ever taken of the inner region of the Orion Nebula, the nearest massive star formation region, and a prototypical highly irradiated dense photo-dissociation region (PDR). We investigate the fundamental interaction of far-ultraviolet photons with molecular clouds. The transitions across the ionization front (IF), dissociation front (DF), and the molecular cloud are studied at high-angular resolution. These transitions are relevant to understanding the effects of radiative feedback from massive stars and the dominant physical and chemical processes that lead to the IR emission that JWST will detect in many Galactic and extragalactic environments. Due to the proximity of the Orion Nebula and the unprecedented angular resolution of JWST, these data reveal that the molecular cloud borders are hyper structured at small angular scales of 0.1-1" (0.0002-0.002 pc or 40-400 au at 414 pc). A diverse set of features are observed such as ridges, waves, globules and photoevaporated protoplanetary disks. At the PDR atomic to molecular transition, several bright features are detected that are associated with the highly irradiated surroundings of the dense molecular condensations and embedded young star. Toward the Orion Bar PDR, a highly sculpted interface is detected with sharp edges and density increases near the IF and DF. This was predicted by previous modeling studies, but the fronts were unresolved in most tracers. A complex, structured, and folded DF surface was traced by the H2 lines. This dataset was used to revisit the commonly adopted 2D PDR structure of the Orion Bar. JWST provides us with a complete view of the PDR, all the way from the PDR edge to the substructured dense region, and this allowed us to determine, in detail, where the emission of the atomic and molecular lines, aromatic bands, and dust originate.

(Abridged) Mid-infrared observations of photodissociation regions (PDRs) are dominated by strong emission features called aromatic infrared bands (AIBs). The most prominent AIBs are found at 3.3, 6.2, 7.7, 8.6, and 11.2 $\mu$m. The most sensitive, highest-resolution infrared spectral imaging data ever taken of the prototypical PDR, the Orion Bar, have been captured by JWST. We provide an inventory of the AIBs found in the Orion Bar, along with mid-IR template spectra from five distinct regions in the Bar: the molecular PDR, the atomic PDR, and the HII region. We use JWST NIRSpec IFU and MIRI MRS observations of the Orion Bar from the JWST Early Release Science Program, PDRs4All (ID: 1288). We extract five template spectra to represent the morphology and environment of the Orion Bar PDR. The superb sensitivity and the spectral and spatial resolution of these JWST observations reveal many details of the AIB emission and enable an improved characterization of their detailed profile shapes and sub-components. While the spectra are dominated by the well-known AIBs at 3.3, 6.2, 7.7, 8.6, 11.2, and 12.7 $\mu$m, a wealth of weaker features and sub-components are present. We report trends in the widths and relative strengths of AIBs across the five template spectra. These trends yield valuable insight into the photochemical evolution of PAHs, such as the evolution responsible for the shift of 11.2 $\mu$m AIB emission from class B$_{11.2}$ in the molecular PDR to class A$_{11.2}$ in the PDR surface layers. This photochemical evolution is driven by the increased importance of FUV processing in the PDR surface layers, resulting in a "weeding out" of the weakest links of the PAH family in these layers. For now, these JWST observations are consistent with a model in which the underlying PAH family is composed of a few species: the so-called 'grandPAHs'., Comment: 25 pages, 10 figures, to appear in A&A

We develop a theory of complex Kuranishi structures on projective schemes. These are sufficiently rigid to be equivalent to weak perfect obstruction theories, but sufficiently flexible to admit global complex Kuranishi charts. We apply the theory to projective moduli spaces M of stable sheaves on Calabi-Yau 4-folds. Using real derived differential geometry, Borisov-Joyce produced a virtual homology cycle on M. In the prequel to this paper we constructed an algebraic virtual cycle on M. We prove the cycles coincide in homology after inverting 2 in the coefficients. And when Borisov-Joyce's real virtual dimension is odd, their virtual cycle is 2-torsion., Comment: Incorrect proof (that Borisov-Joyce class is 2-torsion when virtual dimension is odd) replaced by a correct one. 63 pages

Massive stars disrupt their natal molecular cloud material through radiative and mechanical feedback processes. These processes have profound effects on the evolution of interstellar matter in our Galaxy and throughout the Universe, from the era of vigorous star formation at redshifts of 1-3 to the present day. The dominant feedback processes can be probed by observations of the Photo-Dissociation Regions (PDRs) where the far-ultraviolet photons of massive stars create warm regions of gas and dust in the neutral atomic and molecular gas. PDR emission provides a unique tool to study in detail the physical and chemical processes that are relevant for most of the mass in inter- and circumstellar media including diffuse clouds, proto-planetary disks and molecular cloud surfaces, globules, planetary nebulae, and star-forming regions. PDR emission dominates the infrared (IR) spectra of star-forming galaxies. Most of the Galactic and extragalactic observations obtained with the James Webb Space Telescope (JWST) will therefore arise in PDR emission. In this paper we present an Early Release Science program using the MIRI, NIRSpec, and NIRCam instruments dedicated to the observations of an emblematic and nearby PDR: the Orion Bar. These early JWST observations will provide template datasets designed to identify key PDR characteristics in JWST observations. These data will serve to benchmark PDR models and extend them into the JWST era. We also present the Science-Enabling products that we will provide to the community. These template datasets and Science-Enabling products will guide the preparation of future proposals on star-forming regions in our Galaxy and beyond and will facilitate data analysis and interpretation of forthcoming JWST observations., Comment: Submitted to PASP

Fix a Calabi-Yau 3-fold $X$ satisfying the Bogomolov-Gieseker conjecture of Bayer-Macr\`i-Toda, such as the quintic 3-fold. We express Joyce's generalised DT invariants counting Gieseker semistable sheaves of any rank $r$ on $X$ in terms of those counting sheaves of rank 1. By the MNOP conjecture they are therefore determined by the Gromov-Witten invariants of $X$., Comment: Referee's corrections, added one figure. To appear in JAMS. 33 pages, 4 figures

Borisov-Joyce constructed a real virtual cycle on compact moduli spaces of stable sheaves on Calabi-Yau 4-folds, using derived differential geometry. We construct an algebraic virtual cycle. A key step is a localisation of Edidin-Graham's square root Euler class for $SO(r,\mathbb C)$ bundles to the zero locus of an isotropic section, or to the support of an isotropic cone. We prove a torus localisation formula, making the invariants computable and extending them to the noncompact case when the fixed locus is compact. We give a $K$-theoretic refinement by defining $K$-theoretic square root Euler classes and their localised versions. In a sequel we prove our invariants reproduce those of Borisov-Joyce., Comment: v2 fixed sign problem pointed out by J{\o}rgen Rennemo and convergence problem pointed out by Andrei Okounkov. v3 referees' corrections. To appear in Duke. 65 pages

Intimate partner violence (IPV) is an urgent, prevalent, and under-detected public health issue. We present machine learning models to assess patients for IPV and injury. We train the predictive algorithms on radiology reports with 1) IPV labels based on entry to a violence prevention program and 2) injury labels provided by emergency radiology fellowship-trained physicians. Our dataset includes 34,642 radiology reports and 1479 patients of IPV victims and control patients. Our best model predicts IPV a median of 3.08 years before violence prevention program entry with a sensitivity of 64% and a specificity of 95%. We conduct error analysis to determine for which patients our model has especially high or low performance and discuss next steps for a deployed clinical risk model.

We work on a projective threefold $X$ which satisfies the Bogomolov-Gieseker conjecture of Bayer-Macr\`i-Toda, such as $\mathbb P^3$ or the quintic threefold. We prove certain moduli spaces of 2-dimensional torsion sheaves on $X$ are smooth bundles over Hilbert schemes of ideal sheaves of curves and points in $X$. When $X$ is Calabi-Yau this gives a simple wall crossing formula expressing curve counts (and so ultimately Gromov-Witten invariants) in terms of counts of D4-D2-D0 branes. These latter invariants are predicted to have modular properties which we discuss from the point of view of S-duality and Noether-Lefschetz theory., Comment: Referee's corrections implemented; journal version. 25 pages, 4 figures

Consider a smooth projective 3-fold $X$ satisfying the Bogomolov-Gieseker conjecture of Bayer-Macr\`{i}-Toda (such as $\mathbb P^3$, the quintic threefold or an abelian threefold). Let $L$ be a line bundle supported on a very positive surface in $X$. If $c_1(L)$ is a primitive cohomology class then we show it has very negative square., Comment: Referee's corrections. To appear in Quarterly Journal of Mathematics, special issue dedicated to the memory of Sir Michael Atiyah. 19 pages, appendix by Claire Voisin

We express nested Hilbert schemes of points and curves on a smooth projective surface as "virtual resolutions" of degeneracy loci of maps of vector bundles on smooth ambient spaces. We show how to modify the resulting obstruction theories to produce the virtual cycles of Vafa-Witten theory and other sheaf-counting problems. The result is an effective way of calculating invariants (VW, SW, local PT and local DT) via Thom-Porteous-like Chern class formulae., Comment: 42 pages. Two referees' corrections. To appear in Compositio

Fulton defined classes in the Chow group of a quasi-projective scheme $M$ which reduce to its Chern classes when $M$ is smooth. When $M$ has a perfect obstruction theory, Siebert gave a formula for its virtual cycle in terms of its total Fulton class. We describe K-theory classes on $M$ which reduce to the exterior algebra of differential forms when $M$ is smooth. When $M$ has a perfect obstruction theory, we give a formula for its K-theoretic virtual structure sheaf in terms of these classes., Comment: 10 pages. Referee's corrections

In [MT2] the Vafa-Witten theory of complex projective surfaces is lifted to oriented $\mathbb C^*$-equivariant cohomology theories. Here we study the K-theoretic refinement. It gives rational functions in $t^{1/2}$ invariant under $t^{1/2}\leftrightarrow t^{-1/2}$ which specialise to numerical Vafa-Witten invariants at $t=1$. On the "instanton branch" the invariants give the virtual $\chi_{-t}^{}$-genus refinement of G\"ottsche-Kool. Applying modularity to their calculations gives predictions for the contribution of the "monopole branch". We calculate some cases and find perfect agreement. We also do calculations on K3 surfaces, finding Jacobi forms refining the usual modular forms, proving a conjecture of G\"ottsche-Kool. We determine the K-theoretic virtual classes of degeneracy loci using Eagon-Northcott complexes, and show they calculate refined Vafa-Witten invariants. Using this Laarakker [Laa] proves universality results for the invariants., Comment: Gap pointed out by Martijn Kool fixed by more general result in arXiv:2403.12741. References updated. 51 pages

There are two natural ways to count stable pairs or Joyce-Song pairs on $X=\mathrm{K3}\times\mathbb C$; one via weighted Euler characteristic and the other by virtual localisation of the reduced virtual class. Since $X$ is noncompact these need not be the same. We show their generating series are related by an exponential. As applications we prove two conjectures of Toda, and a conjecture of Tanaka-Thomas defining Vafa-Witten invariants in the semistable case., Comment: Referee's corrections. 21 pages

Given a map of vector bundles on a smooth variety, consider the deepest degeneracy locus where its rank is smallest. We show it carries a natural perfect obstruction theory whose virtual cycle can be calculated by the Thom-Porteous formula. We show nested Hilbert schemes of points on surfaces can be expressed as degeneracy loci. We show how to modify the resulting obstruction theories to recover the virtual cycles of Vafa-Witten and reduced local DT theories. The result computes some Vafa-Witten invariants in terms of Carlsson-Okounkov operators. This proves and extends a conjecture of Gholampour-Sheshmani-Yau and generalises a vanishing result of Carlsson-Okounkov., Comment: Published version. 29 pages

We propose a definition of Vafa-Witten invariants counting semistable Higgs pairs on a polarised surface. We use virtual localisation applied to Mochizuki/Joyce-Song pairs. For $K_S\le0$ we expect our definition coincides with an alternative definition using weighted Euler characteristics. We prove this for deg $K_S<0$ here, and it is proved for $S$ a K3 surface in \cite{MT}. For K3 surfaces we calculate the invariants in terms of modular forms which generalise and prove conjectures of Vafa and Witten., Comment: Error found by Laarakker fixed. To appear in Pure Appl. Math. Quart. (2017), issue in honour of 60th birthday of Simon Donaldson. 37 pages