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Here, we report new estimates of local marine radiocarbon reservoir ages from northwestern Luzon Island in the Philippines, on the east side of the South China Sea. Data for two periods, through the 1940’s and the mid-Holocene, were derived from modern and fossil corals. Our results from Luzon Island show variable ΔR values, from −39 ± 25 to 337 ± 27 14C yr over the past 6000 years and highlight the importance of understanding temporal ΔR changes to obtain accurate radiocarbon dates for mid-Holocene samples. An abrupt shift in ΔR at ∼5.5 ka BP, in the east side of the South China Sea, can be attributed to changes in the intensity of the upwelling, in the eastern Pacific, and to the East Asian Monsoon. Additional reservoir age data from the Pacific is likely to reveal details of oceanographic and climate changes at this time.

The Great Barrier Reef (GBR) is an internationally recognized and widely studied ecosystem, yet little is known about its sea surface temperature evolution since the Last Glacial Maximum (LGM) (~20 kyr BP). Here, we present the first paleo‐application of Isopora coral‐derived SST calibrations to a suite of 25 previously published fossil Isopora from the central GBR spanning ~25‐11 kyr BP. The resultant multi‐coral Sr/Ca‐ and δ18O‐derived sea surface temperature anomaly (SSTA) histories are placed within the context of published relative sea level, reef sequence and coralgal reef assemblage evolution. Our new calculations indicate SSTs were cooler on average by ~5‐5.5°C at Noggin Pass (~17°S) and ~7‐8°C at Hydrographer's Passage (~20°S) (Sr/Ca‐derived) during the LGM, in line with previous estimates (Felis et al., 2014). We focus on contextualizing the Younger Dryas Chronozone (YDC, ~12.9‐11.7 kyr BP), whose southern hemisphere expression, in particular in Australia, is elusive and poorly constrained. Our record does not indicate cooling during the YDC with near modern temperatures reached during this interval on the GBR, supporting an asymmetric hemispheric presentation of this climate event. Building on a previous study (Felis et al., 2014), these fossil Isopora SSTA data from the GBR provide new insights into the deglacial reef response, with near‐modern warming during the YDC, since the LGM.

International audience; Previous drilling through submerged fossil coral reefs has greatly improved our understanding of the general pattern of sea-level change since the Last Glacial Maximum, however, how reefs responded to these changes remains uncertain. Here we document the evolution of the Great Barrier Reef (GBR), the world’s largest reef system, to major, abrupt environmental changes over the past 30 thousand years based on comprehensive sedimentological, biological and geochronological records from fossil reef cores. We show that reefs migrated seaward as sea level fell to its lowest level during the most recent glaciation (~20.5–20.7 thousand years ago (ka)), then landward as the shelf flooded and ocean temperatures increased during the subsequent deglacial period (~20–10 ka). Growth was interrupted by five reef-death events caused by subaerial exposure or sea-level rise outpacing reef growth. Around 10 ka, the reef drowned as the sea level continued to rise, flooding more of the shelf and causing a higher sediment flux. The GBR’s capacity for rapid lateral migration at rates of 0.2–1.5 m yr$^{−1}$ (and the ability to recruit locally) suggest that, as an ecosystem, the GBR has been more resilient to past sea-level and temperature fluctuations than previously thought, but it has been highly sensitive to increased sediment input over centennial–millennial timescales.

Microcracks are one of the main reasons for decreasing service life of concrete structures. Recent research in the field of concrete materials suggested that it might be possible to develop a cement-based material that is capable of remediating microcracks by triggering biogenic calcium carbonate (CaCO3). This paper summarizes the study undertaken to investigate the influence of a 2-pahse biogenic self-healing agent on fresh and hardened properties of cement-based materials. To develop biogenic self-healing agent, S. pasteurii cells were immobilized to the locally available, lightweight and porous natural minerals such as bentonite, diatomaceous earth, and sepiolite. In addition, a portion of the minerals was saturated with a nutrient medium including urea and calcium acetate. Upon immobilization, minerals including cells and the nutrient medium were incorporated in the mortar mix. The mortar mix samples were evaluated in terms of fresh and hardened state performance such as workability, initial set and, compressive strength. Incorporation of cells, as well as the nutrient media with the minerals did not affect the initial setting of the mix negatively, however, a substantial decrease was observed in compressive strength of samples particularly prepared by minerals only including nutrient medium . However, depending on the practical application of the mortar, this two-phase immobilization system can be potentially used for self-healing., Academic Journal of Civil Engineering, Vol 37 No 2 (2019): Special Issue - ICBBM 2019

The approximately 10,000-year-long Last Glacial Maximum, before the termination of the last ice age, was the coldest period in Earth’s recent climate history1. Relative to the Holocene epoch, atmospheric carbon dioxide was about 100 parts per million lower and tropical sea surface temperatures were about 3 to 5 degrees Celsius lower2,3. The Last Glacial Maximum began when global mean sea level (GMSL) abruptly dropped by about 40 metres around 31,000 years ago4 and was followed by about 10,000 years of rapid deglaciation into the Holocene1. The masses of the melting polar ice sheets and the change in ocean volume, and hence in GMSL, are primary constraints for climate models constructed to describe the transition between the Last Glacial Maximum and the Holocene, and future changes; but the rate, timing and magnitude of this transition remain uncertain. Here we show that sea level at the shelf edge of the Great Barrier Reef dropped by around 20 metres between 21,900 and 20,500 years ago, to −118 metres relative to the modern level. Our findings are based on recovered and radiometrically dated fossil corals and coralline algae assemblages, and represent relative sea level at the Great Barrier Reef, rather than GMSL. Subsequently, relative sea level rose at a rate of about 3.5 millimetres per year for around 4,000 years. The rise is consistent with the warming previously observed at 19,000 years ago1,5, but we now show that it occurred just after the 20-metre drop in relative sea level and the related increase in global ice volumes. The detailed structure of our record is robust because the Great Barrier Reef is remote from former ice sheets and tectonic activity. Relative sea level can be influenced by Earth’s response to regional changes in ice and water loadings and may differ greatly from GMSL. Consequently, we used glacio-isostatic models to derive GMSL, and find that the Last Glacial Maximum culminated 20,500 years ago in a GMSL low of about −125 to −130 metres. © 2018, Macmillan Publishers Ltd., part of Springer Nature. Japan Society for the Promotion of Science-JP16H06309,JP17H01168,JP26247085,JP15KK0151 Australian Research Council-DP1094001 National Eye Research Centre-NE/H014136/1 Institut National Polytechnique de Toulouse

The approximately 10,000-year-long Last Glacial Maximum, before the termination of the last ice age, was the coldest period in Earth's recent climate history

Shallow-water corals provide the only direct way of determining the absolute timing and magnitude of sea levels over the past 600,000 years. Their uranium and thorium abundances and uranium isotope ratios, combined with coral-reef elevations, help to determine past sea levels ( 1 ). The veracity of the dating results depends on the state of preservation of fossil corals over extended time periods. Models have been developed to correct for specific complications. Deep-sea corals (see the photo) do not provide sea-level information. However, as Chen et al. ( 2 ) show on page 626 of this issue, they appear to be responsive to ocean circulation changes and continental riverine and ice-sheet meltwater inputs to the oceans. In addition, the data help to resolve one of the most contentious issues in uranium series dating, namely whether systematic variations in 234U are due to physical ocean processes or are artifacts of poor preservation.

Milankovitch orbital forcing theory has been used to assign time scales to many paleoclimate records. However, the validity of this theory remains uncertain, and independent sea-level chronologies used to test its applicability have been restricted largely to the past approximately 135,000 years. Here, we report U-series ages for coral reefs formed on Henderson Island during sea-level high-stands occurring at approximately 630,000 and approximately 330,000 years ago. These data are consistent with the hypothesis that interglacial climates are forced by Northern Hemisphere summer solar insolation centered at 65 degrees N latitude, as predicted by Milankovitch theory.

Tropical south-western Pacific temperatures are of vital importance to the Great Barrier Reef (GBR), but the role of sea surface temperatures (SSTs) in the growth of the GBR since the Last Glacial Maximum remains largely unknown. Here we present records of Sr/Ca and δ(18)O for Last Glacial Maximum and deglacial corals that show a considerably steeper meridional SST gradient than the present day in the central GBR. We find a 1-2 °C larger temperature decrease between 17° and 20°S about 20,000 to 13,000 years ago. The result is best explained by the northward expansion of cooler subtropical waters due to a weakening of the South Pacific gyre and East Australian Current. Our findings indicate that the GBR experienced substantial meridional temperature change during the last deglaciation, and serve to explain anomalous deglacial drying of northeastern Australia. Overall, the GBR developed through significant SST change and may be more resilient than previously thought.

Globally, rivers supply uranium to the oceans with excess 234 U relative to secular equilibrium and 234 U taken-up by corals can be used for dating. In addition, the 234 U abundance in sea water, at the time the coral was growing, can be measured independently. The veracity of U-series ages used in determining past sea-level variations is dependent on selecting pristine corals free from diagenetic alteration. A quantitative test for alteration assumes invariant 234 U abundances in the oceans for at least the past half a million years and results from samples outside of a narrow range in modern ocean 234 U abundance are excluded from data sets. Here, we have used previously published data to show that 234 U in the oceans appears to be variable and directly related to changes in sea-level, not only over long glacial–interglacial timescales but also at very short, centennial timescales. Most of the previously discarded data can be used to provide valuable additional sea-level information. The process permits a unique insight into the interplay between sources and sinks of uranium in the oceans mediated by sea-level changes at rates far faster than previously thought possible. Similar, rapid sea-level, forcing of other trace element abundances in the oceans is likely.

The penultimate interglacial period was punctuated by three sea-level highstands. Uranium–thorium ages obtained from speleothems in Italian caves show that the relationship between the timing of the peaks in sea level and Northern Hemisphere insolation is dependent on the previous extent of continental ice sheets. Earth’s climate has oscillated between short-lived interglacial and extended glacial periods for the past million years. Before the last interglacial, absolutely dated markers of sea level become increasingly rare; hence, our knowledge of sea-level change driven by the waxing and waning of continental ice sheets before that time is largely based on proxy records from deep-sea cores1,2,3 that lack direct age control. Here we present precise U–Th ages for a remarkable collection of submerged speleothems4,5 from Italy, which record three sea-level highstands during the penultimate interglacial period, Marine Isotope Stage 7, from 245,000 to 190,000 years ago. We find that sea level rose above −18 m (relative to modern sea level) several thousand years before maximum Northern Hemisphere insolation during the first and third highstands. In contrast, the second highstand, Marine Isotope Stage 7.3, is essentially synchronous with the insolation maximum, and sea level during this highstand only peaked at about −18 m, even though the concurrent insolation forcing was the strongest of the three highstands. We attribute the different phasing and amplitude of the Marine Isotope Stage 7.3 highstand to the extensive continental glaciation that preceded it. This finding highlights the significance of cryosphere response time to the climate system.

Radiocarbon calibration beyond the extent of tree-ring records depends on U-series dating of fossil corals or speleothem, both of which can provide independent calendar ages. Less direct methods rely on layer counting and comparison with other well-dated records. In spite of considerable effort to provide a reliable radiocarbon calibration curve beyond 25,000 years, the majority of the data show large atmospheric radiocarbon peaks which are inconsistent both in magnitude and timing between different determinations. The results of the most recent work [Chiu, T.-C., Fairbanks, R.G., Mortlock, R.A., Bloom, A.L., 2005. Extending the radiocarbon calibration beyond 26,000 years before present using fossil corals. Quaternary Science Reviews 24 (16–17), 1797–1808], from Araki Island fossil corals, indicate a monotonic variation from about 33 to 49 ka, with no radiocarbon peaks, but with some gaps in the data. The difference between this and previous results, from fossil corals, has been attributed to selection of better-quality samples and rigorous analytical methods. However, previous results from Huon Peninsula [Yokoyama, Y., Esat, T.M., Lambeck, K., Fifield, L.K., 2000. Last ice age millennial scale climate changes recorded in Huon Peninsula corals. Radiocarbon 42 (3), 383–401; Cutler, K.B., Gray, S.C., Burr, G.S., Edwards, R.L., Taylor, F.W., Cabioch, G., Beck, J.W., Cheng, H., Moore, J., 2004. Radiocarbon calibration and comparison to 50 kyr BP with paired 14 C and 230 Th dating of corals from Vanuatu and Papua New Guinea. Radiocarbon 46 (3), 1127–1160] show radiocarbon peaks exclusively located within the gaps in the Araki data. The timing of the gaps are not random, but appear to be related to severe climate and sea-level variations associated with Heinrich events initiated in the North Atlantic. We propose that the Huon and Araki data sets are complementary rather than exclusive and that the absence of coral growth at Araki Island during Heinrich events presumably reflect local adverse conditions for coral growth.

At Huon Peninsula, Papua New Guinea, prolific coral growth during the last-glacial was episodic and in response to a series of sea-level rises. The resultant step-like coral terraces are currently situated from 20 m up to 140 m above sea-level due to continuous tectonic uplift of the Peninsula. The sea-level rises were in response to periodic partial disintegration of Northern Hemisphere ice sheets associated with severe climate swings and occurred within decadal timescales. The relatively rapid 15 m to 35 m rise in sea-levels exposed new head-room for corals to colonize. The resulting terrace structures contain individual corals that do not appear to have grown sequentially in time and with elevation. Additionally, following the peak, sea level fell relatively slowly over several thousand years and corals grew and filled in the flanks of the terrace such that younger corals now occupy lower elevations. We have labeled these structures “pack-up” reefs. This is in contrast to coral terraces formed during major sea-level rises from glacial to interglacial or glacial to interstadial transitions where the rate of sea level rise is commensurate with coral growth rates and corals can keep up with sea-level rise by growing on top of each other in a time orderly sequence. Deriving sea-level information from pack-up terraces is difficult and is likely to be ambiguous. The periodic fluctuations in climate were associated with atmospheric radiocarbon swings that seem to have varied smoothly with time. The same corals that show a scatter in stratigraphic temporal ordering appear regularly distributed in time and with radiocarbon content attesting to the veracity of the age measurements and at the same time confirm the disordered distribution of corals in “pack-up” type reefs.

Uranium-series mass spectrometric analyses of corals from the uplifted last glacial terraces at Huon Peninsula, Papua New Guinea, that grew from 50,000 years ago to 30,000 years ago show systematically low values of 234U/238U, at the time of coral growth, compared with modern corals. When combined with coral data from other studies a systematic trend emerges indicating shifts in the 234U/238U ratio at times of major glacial–interglacial transitions that involve large variations in sea-levels. From last glacial to Holocene, the rate of change in δ234U is approximately 1‰ per thousand years. The variations in the U budget of the oceans appear to be due to accumulation of excess 234U in near shore areas in anoxic and suboxic sediments, in salt marshes and mangroves, in estuaries, and in continental margins during periods of warm climate and high sea-levels. These near-shore areas are exposed during periods of low sea level resulting in rapid oxidation of U into highly soluble phases. The subsequent release of 234U-enriched uranium into the oceans occurs over a sustained period, in step with rising sea-levels.

Initial 187Os/188Os isotopic compositions for geochronologically and geologically well -constrained 3.8-Ga spinel peridotites from the Itsaq Gneiss Complex of southern West Greenland and chromite separates from 3.46-Ga komatiites from the Pilbara region of Western Australia have been determined to investigate the osmium isotopic evolution of the early terrestrial mantle. The measured compositions of 187Os/188Os(0) = 0.10262 ± 2, from an olivine separate, and 0.10329 ± 3, for a spinel separate from ∼3.8-Ga peridotite G93/42, are the lowest yet reported from any terrestrial sample. The corrections for in situ decay over 3.8 Ga for these low Re/Os phases are minimal and change the isotopic compositions by only 0.5 and 2.2% for the spinel and the olivine, respectively, resulting in 187Os/188Os(3.8 Ga) = 0.1021 ± 0.0002 and 0.1009 ± 0.0002, respectively. These data extend direct measurement of Os isotopic compositions to much earlier periods of Earth history than previously documented and provide the best constraints on the Os isotopic composition of the early Archean terrestrial mantle. Analyses of Pilbara chromites yield 3.46-Ga mantle compositions of 0.1042 ± 0.0002 and 0.1051 ± 0.0002. These new data, combined with published initial Os isotopic compositions from late Archean and early Proterozoic samples, are compatible with the mantle, or at least portions of it, evolving from a solar system initially defined by meteorites to a modern composition of 187Os/188Os(0) = 0.1296 ± 0.0008 as previously suggested from peridotite xenolith data ( Meisel et al., 2001); the associated 187Re/188Os(0) = 0.435 ± 0.005. Thus, chondritic 187Os/188Os compositions were a feature of the upper mantle for at least 3.8 billion years, requiring chondritic Re/Os ratios to have been a characteristic of the very early terrestrial mantle. In contrast, nonchondritic initial compositions of some Archean komatiites demonstrate that Os isotopic heterogeneity is an ancient feature of plume materials, reflecting the development of variable Re/Os mantle sources early in Earth history. The lower average 187Os/188Os = 0.1247 for abyssal peridotites (Snow and Reisberg, 1995) indicate that not all regions of the modern mantle have evolved with the same Re/Os ratio. The relative sizes of the various reservoirs are unknown, although mass balance considerations can provide some general constraints. For example, if the unradiogenic 187Os/188Os modern abyssal peridotite compositions reflect the prevalent upper mantle composition, then the complementary high Re/Os basaltic reservoir must represent 20 to 40% by mass of the upper mantle (taken here as 50% of the entire mantle), depending on the mean storage age. The difficulties associated with efficient long-term storage of such large volumes of subducted basalt suggest that the majority of the upper mantle is not significantly Re-depleted. Rather, abyssal peridotites sample anomalous mantle regions. The existence of 3.8-Ga mantle peridotites with chondritic 187Os/188Os compositions and with Os concentrations similar to the mean abundances measured in modern peridotites places an upper limit on the timing of a late accretionary veneer. These observations require that any highly siderophile element -rich component must have been added to the Earth and transported into and grossly homogenized within the mantle by 3.8 Ga. Either large-scale mixing of impact materials occurred on very short (0–100 myr) timescales or (the interpretation preferred here) the late veneer of highly siderophile elements is unrelated to the lunar terminal cataclysm estimated to have occurred at ∼3.8 to 3.9 Ga.