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GJ1214b is the archetype sub-Neptune for which thick aerosols have prevented us from constraining its atmospheric properties for over a decade. In this study, we leverage the panchromatic transmission spectrum of GJ1214b established by HST and JWST to investigate its atmospheric properties using a suite of atmospheric radiative transfer, photochemistry, and aerosol microphysical models. We find that the combined HST, JWST/NIRSpec and JWST/MIRI spectrum can be well-explained by atmospheric models with an extremely high metallicity of [M/H]$\sim$3.5 and an extremely high haze production rate of $F_{\rm haze}{\sim}10^{-8}$--$10^{-7}$ g cm$^{-2}$ s$^{-1}$. Such high atmospheric metallicity is suggested by the relatively strong CO2 feature compared to the haze absorption feature or the CH4 feature in the NIRSpec-G395H bandpass of 2.5--5 $\mu$m. The flat 5--12 $\mu$m MIRI spectrum also suggests a small scale height with a high atmospheric metallicity that is needed to suppress a prominent 6 $\mu$m haze feature. We tested the sensitivity of our interpretation to various assumptions for uncertain haze properties, such as optical constants and production rate, and all models tested here consistently suggest extremely high metallicity. Thus, we conclude that GJ1214b likely has a metal-dominated atmosphere where hydrogen is no longer the main atmospheric constituent. We also find that different assumptions for the haze production rate lead to distinct inferences for the atmospheric C/O ratio. We stress the importance of high precision follow-up observations to confirm the metal-dominated atmosphere and to constrain the C/O ratio, which provides further insights on the planet formation process. The confirmation of the metal-dominated atmosphere is particularly crucial, as it challenges the conventional understanding of interior structure and evolution of sub-Neptunes., Comment: 21 pages, 9 figures, Submitted to AAS Journals, Please also see a companion paper Schlawin et al. (2024)

Sub-Neptune planets with radii smaller than Neptune (3.9 Re) are the most common type of planet known to exist in The Milky Way, even though they are absent in the Solar System. These planets can potentially have a large diversity of compositions as a result of different mixtures of rocky material, icy material and gas accreted from a protoplanetary disk. However, the bulk density of a sub-Neptune, informed by its mass and radius alone, cannot uniquely constrain its composition; atmospheric spectroscopy is necessary. GJ 1214 b, which hosts an atmosphere that is potentially the most favorable for spectroscopic detection of any sub-Neptune, is instead enshrouded in aerosols (thus showing no spectroscopic features), hiding its composition from view at previously observed wavelengths in its terminator. Here, we present a JWST NIRSpec transmission spectrum from 2.8 to 5.1 um that shows signatures of carbon dioxide and methane, expected at high metallicity. A model containing both these molecules is preferred by 3.3 and 3.6 sigma as compared to a featureless spectrum for two different data analysis pipelines, respectively. Given the low signal-to-noise of the features compared to the continuum, however, more observations are needed to confirm the carbon dioxide and methane signatures and better constrain other diagnostic features in the near-infrared. Further modeling of the planet's atmosphere, interior structure and origins will provide valuable insights about how sub-Neptunes like GJ 1214 b form and evolve., Comment: 22 pages, 11 figures, Accepted in ApJL, Please also see a companion paper Ohno et al. (2024)

Fabrication of semiconductor heterostructures is now so precise that metrology has become a key challenge for progress in science and applications. It is now relatively straightforward to characterize classic III-V and group IV heterostructures consisting of slabs of different semiconductor alloys with thicknesses of $\sim$5 nm and greater using sophisticated tools such as X-ray diffraction, high energy X-ray photoemission spectroscopy, and secondary ion mass spectrometry. However, profiling thin layers with nm or sub-nm thickness, e.g. atomically thin dopant layers ($\delta$-layers), of impurities required for modulation doping and spin-based quantum and classical information technologies is more challenging. Here, we present theory and experiment showing how resonant-contrast X-ray reflectometry meets this challenge. The technique takes advantage of the change in the scattering factor of atoms as their core level resonances are scanned by varying the X-ray energy. We demonstrate the capability of the resulting element-selective, non-destructive profilometry for single arsenic $\delta$-layers within silicon, and show that the sub-nm electronic thickness of the $\delta$-layers corresponds to sub-nm chemical thickness. In combination with X-ray fluorescence imaging, this enables non-destructive three-dimensional characterization of nano-structured quantum devices. Due to the strong resonances at soft X-ray wavelengths, the technique is also ideally suited to characterize layered quantum materials, such as cuprates or the topical infinite-layer nickelates.

DarkSide-20k (DS-20k) is a dark matter detection experiment under construction at the Laboratori Nazionali del Gran Sasso (LNGS) in Italy. It utilises ~100 t of low radioactivity argon from an underground source (UAr) in its inner detector, with half serving as target in a dual-phase time projection chamber (TPC). The UAr cryogenics system must maintain stable thermodynamic conditions throughout the experiment's lifetime of >10 years. Continuous removal of impurities and radon from the UAr is essential for maximising signal yield and mitigating background. We are developing an efficient and powerful cryogenics system with a gas purification loop with a target circulation rate of 1000 slpm. Central to its design is a condenser operated with liquid nitrogen which is paired with a gas heat exchanger cascade, delivering a combined cooling power of >8 kW. Here we present the design choices in view of the DS-20k requirements, in particular the condenser's working principle and the cooling control, and we show test results obtained with a dedicated benchmarking platform at CERN and LNGS. We find that the thermal efficiency of the recirculation loop, defined in terms of nitrogen consumption per argon flow rate, is 95 % and the pressure in the test cryostat can be maintained within $\pm$(0.1-0.2) mbar. We further detail a 5-day cool-down procedure of the test cryostat, maintaining a cooling rate typically within -2 K/h, as required for the DS-20k inner detector. Additionally, we assess the circuit's flow resistance, and the heat transfer capabilities of two heat exchanger geometries for argon phase change, used to provide gas for recirculation. We conclude by discussing how our findings influence the finalisation of the system design, including necessary modifications to meet requirements and ongoing testing activities., Comment: 45 pages, 24 figures

Although exoplanetary science was not initially projected to be a substantial part of the Spitzer mission, its exoplanet observations set the stage for current and future surveys with JWST and Ariel. We present a comprehensive reduction and analysis of Spitzer's 4.5 micron phase curves of 29 hot Jupiters on low-eccentricity orbits. The analysis, performed with the Spitzer Phase Curve Analysis (SPCA) pipeline, confirms that BLISS mapping is the best detrending scheme for most, but not all, observations. Visual inspection remains necessary to ensure consistency across detrending methods due to the diversity of phase curve data and systematics. Regardless of the model selection scheme - whether using the lowest-BIC or a uniform detrending approach - we observe the same trends, or lack thereof. We explore phase curve trends as a function of irradiation temperature, orbital period, planetary radius, mass, and stellar effective temperature. We discuss the trends that are robustly detected and provide potential explanations for those that are not observed. While it is almost tautological that planets receiving greater instellation are hotter, we are still far from confirming dynamical theories of heat transport in hot Jupiter atmospheres due to the sample's diversity. Even among planets with similar temperatures, other factors like rotation and metallicity vary significantly. Larger, curated sample sizes and higher-fidelity phase curve measurements from JWST and Ariel are needed to firmly establish the parameters governing day-night heat transport on synchronously rotating planets., Comment: 16 pages, 6 figures, submitted to AAS journal

We present the latest results from the Chicago Carnegie Hubble Program (CCHP) to measure the Hubble constant using data from the James Webb Space Telescope (JWST). This program is based upon three independent methods: (1) Tip of the Red Giant Branch (TRGB) stars, (2) JAGB (J-Region Asymptotic Giant Branch) stars, and (3) Cepheids. Our program includes 10 nearby galaxies, each hosting Type Ia supernovae, suitable for measuring the Hubble constant (Ho). It also includes NGC 4258, which has a geometric distance, setting the zero point for all three methods. The JWST observations have significantly higher signal-to-noise and finer angular resolution than previous observations with the Hubble Space Telescope (HST). We find three independent values of Ho = 69.85 +/- 1.75 (stat) +/- 1.54 (sys) for the TRGB, Ho = 67.96 +/- 1.85 (stat) +/- 1.90 (sys) for the JAGB, and Ho = 72.05 +/- 1.86 (stat) +/- 3.10 (sys) km/s/Mpc for Cepheids. Tying into supernovae, and combining these methods adopting a flat prior, yields our current estimate of Ho = 69.96 +/- 1.05 (stat) +/- 1.12 (sys) km/s/Mpc. The distances measured using the TRGB and the JAGB method agree at the 1% level, but differ from the Cepheid distances at the 2.5-4% level. The value of Ho based on these two methods with JWST data alone is Ho = 69.03 +/- 1.75 (total error) km/sec/Mpc. These numbers are consistent with the current standard Lambda CDM model, without the need for the inclusion of additional new physics. Future JWST data will be required to increase the precision and accuracy of the local distance scale., Comment: 61 pages, 20 figures

The J-region asymptotic giant branch (JAGB) method is a new standard candle based on the constant luminosities of carbon-rich asymptotic giant branch stars in the J band. The JAGB method is independent of the Cepheid and TRGB distance indicators. Therefore, we can leverage it to both cross-check Cepheid and TRGB distances for systematic errors and use it to measure an independent local Hubble constant. The JAGB method also boasts a number of advantages in measuring distances relative to the TRGB and Cepheids, several of which are especially amplified when combined with JWST's revolutionary resolving power. First, JAGB stars are 1 mag brighter in the NIR than the TRGB, and can be discovered from single-epoch NIR photometry unlike Cepheids which require congruent optical imaging in at least 12 epochs. Thus, JAGB stars can be used to measure significantly farther distances than both the TRGB stars and Cepheids using the same amount of observing time. Further advantages include: JAGB stars are easily identified solely via their colors and magnitudes, dust extinction is reduced in near-infrared observations, and JAGB stars are ubiquitous in all galaxies with intermediate-age populations. In this paper, we present a novel algorithm that identifies the optimal location in a galaxy for applying the JAGB method, so as to minimize effects from crowding. We then deploy this algorithm in JWST NIRCam imaging of seven SN Ia host galaxies to measure their JAGB distances, undertaking a completely blind analysis. The zero-point of this JAGB distance scale is set in the water mega-maser galaxy NGC 4258. In our CCHP overview paper Freedman et al. (2024), we apply the JAGB distances measured in this paper to the Carnegie Supernova Program (CSP) SNe Ia sample, measuring a Hubble constant of H0 = 67.96 +/- 1.85 (stat) +/- 1.90 (sys) km/s/Mpc., Comment: 24 pages, 10 figures, 5 tables, submitted to AAS Journals, v2 now includes systematic uncertainty in abstract

Observing exoplanets through transmission spectroscopy supplies detailed information on their atmospheric composition, physics, and chemistry. Prior to JWST, these observations were limited to a narrow wavelength range across the near-ultraviolet to near-infrared, alongside broadband photometry at longer wavelengths. To understand more complex properties of exoplanet atmospheres, improved wavelength coverage and resolution are necessary to robustly quantify the influence of a broader range of absorbing molecular species. Here we present a combined analysis of JWST transmission spectroscopy across four different instrumental modes spanning 0.5-5.2 micron using Early Release Science observations of the Saturn-mass exoplanet WASP-39b. Our uniform analysis constrains the orbital and stellar parameters within sub-percent precision, including matching the precision obtained by the most precise asteroseismology measurements of stellar density to-date, and further confirms the presence of Na, K, H$_2$O, CO, CO$_2$, and SO$_2$ atmospheric absorbers. Through this process, we also improve the agreement between the transmission spectra of all modes, except for the NIRSpec PRISM, which is affected by partial saturation of the detector. This work provides strong evidence that uniform light curve analysis is an important aspect to ensuring reliability when comparing the high-precision transmission spectra provided by JWST., Comment: 34 pages, 11 figures, 3 tables. Nat Astron (2024)

Boasting a 6.5m mirror in space, JWST can increase by several times the number of supernovae (SNe) to which a redshift-independent distance has been measured with a precision distance indicator (e.g., TRGB or Cepheids); the limited number of such SN calibrators currently dominates the uncertainty budget in distance ladder Hubble constant (H0) experiments. JWST/NIRCAM imaging of the Virgo Cluster galaxy NGC4536 is used here to preview JWST program GO-1995, which aims to measure H0 using three stellar distance indicators (Cepheids, TRGB, JAGB/carbon stars). Each population of distance indicator was here successfully detected -- with sufficiently large number statistics, well-measured fluxes, and characteristic distributions consistent with ingoing expectations -- so as to confirm that we can acquire distances from each method precise to about 0.05mag (statistical uncertainty only). We leverage overlapping HST imaging to identify TRGB stars, cross-match them with the JWST photometry, and present a preliminary constraint on the slope of the TRGB's F115W-(F115W}-F444W) relation equal to -0.99 +/- 0.16 mag/mag. This slope is consistent with prior slope measurements in the similar 2MASS J-band, as well as with predictions from the BASTI isochrone suite. We use the new TRGB slope estimate to flatten the two-dimensional TRGB feature and measure a (blinded) TRGB distance relative to a set of fiducial TRGB colors, intended to represent the absolute fiducial calibrations expected from geometric anchors such as NGC4258 and the Magellanic Clouds. In doing so, we empirically demonstrate that the TRGB can be used as a standardizable candle at the IR wavelengths accessible with JWST., Comment: Revised version after submission to AAS journals; 20 pages, 12 figures; Fig. 1 compressed to reduce file size

The dual-phase liquid argon time projection chamber is presently one of the leading technologies to search for dark matter particles with masses below 10 GeV/c$^2$. This was demonstrated by the DarkSide-50 experiment with approximately 50 kg of low-radioactivity liquid argon as target material. The next generation experiment DarkSide-20k, currently under construction, will use 1,000 times more argon and is expected to start operation in 2027. Based on the DarkSide-50 experience, here we assess the DarkSide-20k sensitivity to models predicting light dark matter particles, including Weakly Interacting Massive Particles (WIMPs) and sub-GeV/c$^2$ particles interacting with electrons in argon atoms. With one year of data, a sensitivity improvement to dark matter interaction cross-sections by at least one order of magnitude with respect to DarkSide-50 is expected for all these models. A sensitivity to WIMP--nucleon interaction cross-sections below $1\times10^{-42}$ cm$^2$ is achievable for WIMP masses above 800 MeV/c$^2$. With 10 years exposure, the neutrino fog can be reached for WIMP masses around 5 GeV/c$^2$., Comment: submitted to Nature Communications

Transmission spectroscopy has enabled unprecedented insights into the makeup of exoplanet atmospheres. A transmission spectrum combines contributions from a planet's morning and evening limbs, but these limbs may have different temperatures, compositions, and aerosol properties due to atmospheric circulation. High-resolution ground-based observations have detected limb asymmetry on several ultra-hot (>2000 K) exoplanets, but space-based investigation into limb asymmetry is in its infancy, and limb asymmetry's prevalence in the broader exoplanet population remains unexplored. We find evidence for limb asymmetry on the exoplanet WASP-107b via transmission spectroscopy from 2.5 to 4.0 micrometers with JWST/NIRCam. This is one of the first low-resolution space-based measurements of limb asymmetry and is unique because, at 770 K, WASP-107b is in a relatively cool regime where planetary terminators are expected to be homogeneous. These observations imply a difference in temperature and cloud properties between WASP-107b's limbs, challenging our models of limb asymmetry in this cooler regime., Comment: This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes. 9 figures, 3 tables, 39 pages

We report observations of the atmospheric transmission spectrum of the sub-Neptune exoplanet GJ 3470 b taken using the Near-Infrared Camera (NIRCam) on JWST. Combined with two archival HST/WFC3 transit observations and fifteen archival Spitzer transit observations, we detect water, methane, sulfur dioxide, and carbon dioxide in the atmosphere of GJ 3470 b, each with a significance of >3-sigma. GJ 3470 b is the lowest mass -- and coldest -- exoplanet known to show a substantial sulfur dioxide feature in its spectrum, at $M_{p}$=11.2${\,{\rm M}_{\oplus}}$ and $T_{eq}$=600$\,$K. This indicates disequilibrium photochemistry drives sulfur dioxide production in exoplanet atmospheres over a wider range of masses and temperatures than has been reported or expected. The water, carbon dioxide, and sulfur dioxide abundances we measure indicate an atmospheric metallicity of approximately $100\times$ Solar. We see further evidence for disequilibrium chemistry in our inferred methane abundance, which is significantly lower than expected from equilibrium models consistent with our measured water and carbon dioxide abundances., Comment: 25 pages, 9 figures, 6 tables. Accepted in Astrophysical Journal Letters

Spectroscopic phase curves of hot Jupiters measure their emission spectra at multiple orbital phases, thus enabling detailed characterisation of their atmospheres. Precise constraints on the atmospheric composition of these exoplanets offer insights into their formation and evolution. We analyse four phase-resolved emission spectra of the hot Jupiter WASP-43b, generated from a phase curve observed with the MIRI/LRS onboard the JWST, to retrieve its atmospheric properties. Using a parametric 2D temperature model and assuming a chemically homogeneous atmosphere within the observed pressure region, we simultaneously fit the four spectra to constrain the abundances of atmospheric constituents, thereby yielding more precise constraints than previous work that analysed each spectrum independently. Our analysis reveals statistically significant evidence of NH3 (4$\sigma$) in a hot Jupiter's emission spectra for the first time, along with evidence of H2O (6.5$\sigma$), CO (3.1$\sigma$), and a non-detection of CH4. With our abundance constraints, we tentatively estimate the metallicity of WASP-43b at 0.6-6.5$\times$solar and its C/O ratio at 0.6-0.9. Our findings offer vital insights into the atmospheric conditions and formation history of WASP-43b by simultaneously constraining the abundances of carbon, oxygen, and nitrogen-bearing species., Comment: 17 pages, 14 figures, accepted for publication in MNRAS. Comments welcome!

The signal from a transiting planet can be diluted by astrophysical contamination. In the case of circumstellar debris disks, this contamination could start in the mid-infrared and vary as a function of wavelength, which would then change the observed transmission spectrum for any planet in the system. The MIRI/LRS WASP-39b transmission spectrum shows an unexplained dip starting at $\sim$10 $\mu$m that could be caused by astrophysical contamination. The spectral energy distribution displays excess flux at similar levels to that which are needed to create the dip in the transmission spectrum. In this article, we show that this dip is consistent with the presence of a bright circumstellar debris disk, at a distance of $>$2 au. We discuss how a circumstellar debris disk like that could affect the atmosphere of WASP-39b. We also show that even faint debris disks can be a source of contamination in MIRI exoplanet spectra., Comment: accepted to ApJL

The current standard model of cosmology successfully describes a variety of measurements, but the nature of its main ingredients, dark matter and dark energy, remains unknown. Euclid is a medium-class mission in the Cosmic Vision 2015-2025 programme of the European Space Agency (ESA) that will provide high-resolution optical imaging, as well as near-infrared imaging and spectroscopy, over about 14,000 deg^2 of extragalactic sky. In addition to accurate weak lensing and clustering measurements that probe structure formation over half of the age of the Universe, its primary probes for cosmology, these exquisite data will enable a wide range of science. This paper provides a high-level overview of the mission, summarising the survey characteristics, the various data-processing steps, and data products. We also highlight the main science objectives and expected performance., Comment: Accepted for publication in the A&A special issue`Euclid on Sky'

Interactions between exoplanetary atmospheres and internal properties have long been hypothesized to be drivers of the inflation mechanisms of gaseous planets and apparent atmospheric chemical disequilibrium conditions. However, transmission spectra of exoplanets has been limited in its ability to observational confirm these theories due to the limited wavelength coverage of HST and inferences of single molecules, mostly H$_2$O. In this work, we present the panchromatic transmission spectrum of the approximately 750 K, low-density, Neptune-sized exoplanet WASP-107b using a combination of HST WFC3, JWST NIRCam and MIRI. From this spectrum, we detect spectroscopic features due to H$_2$O (21$\sigma$), CH$_4$ (5$\sigma$), CO (7$\sigma$), CO$_2$ (29$\sigma$), SO$_2$ (9$\sigma$), and NH$_3$ (6$\sigma$). The presence of these molecules enable constraints on the atmospheric metal enrichment (M/H is 10--18$\times$ Solar), vertical mixing strength (log$_{10}$K$_{zz}$=8.4--9.0 cm$^2$s$^{-1}$), and internal temperature ($>$345 K). The high internal temperature is suggestive of tidally-driven inflation acting upon a Neptune-like internal structure, which can naturally explain the planet's large radius and low density. These findings suggest that eccentricity driven tidal heating is a critical process governing atmospheric chemistry and interior structure inferences for a majority of the cool ($<$1,000K) super-Earth-to-Saturn mass exoplanet population., Comment: This preprint has not undergone any substantive post-submission improvements or corrections. The Version of Record of this article is published in Nature here: https://www.nature.com/articles/s41586-024-07514-w

Experiments aimed at direct searches for WIMP dark matter require highly effective reduction of backgrounds and control of any residual radioactive contamination. In particular, neutrons interacting with atomic nuclei represent an important class of backgrounds due to the expected similarity of a WIMP-nucleon interaction, so that such experiments often feature a dedicated neutron detector surrounding the active target volume. In the context of the development of DarkSide-20k detector at INFN Gran Sasso National Laboratory (LNGS), several R&D projects were conceived and developed for the creation of a new hybrid material rich in both hydrogen and gadolinium nuclei to be employed as an essential element of the neutron detector. Thanks to its very high cross-section for neutron capture, gadolinium is one of the most widely used elements in neutron detectors, while the hydrogen-rich material is instrumental in efficiently moderating the neutrons. In this paper results from one of the R&Ds are presented. In this effort the new hybrid material was obtained as a poly(methyl methacrylate) (PMMA) matrix, loaded with gadolinium oxide in the form of nanoparticles. We describe its realization, including all phases of design, purification, construction, characterization, and determination of mechanical properties of the new material.

We present eclipse maps of the two-dimensional thermal emission from the dayside of the hot Jupiter WASP-43b, derived from an observation of a phase curve with the JWST MIRI/LRS instrument. The observed eclipse shapes deviate significantly from those expected for a planet emitting uniformly over its surface. We fit a map to this deviation, constructed from spherical harmonics up to order $\ell_{\rm max}=2$, alongside the planetary, orbital, stellar, and systematic parameters. This yields a map with a meridionally-averaged eastward hot-spot shift of $(7.75 \pm 0.36)^{\circ}$, with no significant degeneracy between the map and the additional parameters. We show the latitudinal and longitudinal contributions of the day-side emission structure to the eclipse shape, finding a latitudinal signal of $\sim$200 ppm and a longitudinal signal of $\sim$250 ppm. To investigate the sensitivity of the map to the method, we fix the non-mapping parameters and derive an "eigenmap" fitted with an optimised number of orthogonal phase curves, which yields a similar map to the $\ell_{\rm max}=2$ map. We also fit a map up to $\ell_{\rm max}=3$, which shows a smaller hot-spot shift, with a larger uncertainty. These maps are similar to those produced by atmospheric simulations. We conclude that there is a significant mapping signal which constrains the spherical harmonic components of our model up to $\ell_{\rm max}=2$. Alternative mapping models may derive different structures with smaller-scale features; we suggest that further observations of WASP-43b and other planets will drive the development of more robust methods and more accurate maps., Comment: Accepted for publication in The Astronomical Journal

In this article, we discuss a new software tool that interacts with Grail+, a library of automata-theoretic command-line utilities. Our software, the Grail+ Visualizer, takes the textual representation of a finite automaton produced by Grail+ and generates TikZ code to illustrate the finite automaton, with automatic layout of states and transitions. In addition to giving an overview of the basics of automata theory and Grail+, we discuss how the Grail+ Visualizer works in detail and suggest avenues for future work.

We report the discovery of ten new pulsars in the globular cluster Terzan 5 as part of the Transients and Pulsars with MeerKAT (TRAPUM) Large Survey Project. We observed Terzan 5 at L-band (856--1712 MHz) with the MeerKAT radio telescope for four hours on two epochs, and performed acceleration searches of 45 out of 288 tied-array beams covering the core of the cluster. We obtained phase-connected timing solutions for nine discoveries, covering nearly two decades of archival observations from the Green Bank Telescope for all but one. Highlights include PSR J1748$-$2446ao which is an eccentric ($e = 0.32$) wide-orbit (orbital period $P_{\rm b} = 57.55$ d) system. We were able to measure the rate of advance of periastron ($\dot{\omega}$) for this system allowing us to determine a total mass of $3.17 \pm \, 0.02\, \rm M_{\odot}$. With a minimum companion mass ($M_{\rm c}$) of $\sim 0.8\, \rm M_{\odot}$, PSR J1748$-$2446ao is a candidate double neutron star (DNS) system. If confirmed to be a DNS, it would be the fastest spinning pulsar ($P = 2.27$ ms) and the longest orbital period measured for any known DNS system. PSR J1748$-$2446ap has the second highest eccentricity for any recycled pulsar ($e \sim 0.905$) and for this system we can measure the total mass ($1.997 \pm 0.006\, \rm M_{\odot}$) and also estimate the individual pulsar and companion masses. PSR J1748$-$2446ar is an eclipsing redback (minimum $M_{\rm c} \sim 0.34\, \rm M_{\odot}$) system whose properties confirm it to be the counterpart to a previously published source identified in radio and X-ray imaging. With these discoveries, the total number of confirmed pulsars in Terzan 5 is 49, the highest for any globular cluster so far. These discoveries further enhance the rich set of pulsars known in Terzan 5 and provide scope for a deeper understanding of binary stellar evolution, cluster dynamics and ensemble population studies., Comment: 23 pages, 11 figures, 5 tables, published in A&A

We build on recent research on polynomial randomized approximation (PRAX) algorithms for the hard problems of NFA universality and NFA equivalence. Loosely speaking, PRAX algorithms use sampling of infinite domains within any desired accuracy $\delta$. In the spirit of experimental mathematics, we extend the concept of PRAX algorithms to be applicable to the emptiness and universality problems in any domain whose instances admit a tractable distribution as defined in this paper. A technical result here is that a linear (w.r.t. $1/\delta$) number of samples is sufficient, as opposed to the quadratic number of samples in previous papers. We show how the improved and generalized PRAX algorithms apply to universality and emptiness problems in various domains: ordinary automata, tautology testing of propositions, 2D automata, and to solution sets of certain Diophantine equations.

We use electrostatic force microscopy to spatially resolve random telegraph noise at the Si/SiO$_2$ interface. Our measurements demonstrate that two-state fluctuations are localized at interfacial traps, with bias-dependent rates and amplitudes. These two-level systems lead to correlated carrier number and mobility fluctuations with a range of characteristic timescales; taken together as an ensemble, they give rise to a $1/f$ power spectral trend. Such individual defect fluctuations at the Si/SiO$_2$ interface impair the performance and reliability of nanoscale semiconductor devices, and will be a significant source of noise in semiconductor-based quantum sensors and computers. The fluctuations measured here are associated with a four-fold competition of rates, including slow two-state switching on the order of seconds and, in one state, fast switching on the order of nanoseconds which is associated with energy loss.

Hot Jupiters are among the best-studied exoplanets, but it is still poorly understood how their chemical composition and cloud properties vary with longitude. Theoretical models predict that clouds may condense on the nightside and that molecular abundances can be driven out of equilibrium by zonal winds. Here we report a phase-resolved emission spectrum of the hot Jupiter WASP-43b measured from 5-12 $\mu$m with JWST's Mid-Infrared Instrument (MIRI). The spectra reveal a large day-night temperature contrast (with average brightness temperatures of 1524$\pm$35 and 863$\pm$23 Kelvin, respectively) and evidence for water absorption at all orbital phases. Comparisons with three-dimensional atmospheric models show that both the phase curve shape and emission spectra strongly suggest the presence of nightside clouds which become optically thick to thermal emission at pressures greater than ~100 mbar. The dayside is consistent with a cloudless atmosphere above the mid-infrared photosphere. Contrary to expectations from equilibrium chemistry but consistent with disequilibrium kinetics models, methane is not detected on the nightside (2$\sigma$ upper limit of 1-6 parts per million, depending on model assumptions)., Comment: 61 pages, 13 figures, 4 tables. This preprint has been submitted to and accepted in principle for publication in Nature Astronomy without significant changes

We have conducted an extensive towed-magnetic-sled survey during the period of June 14-28, 2023, over the seafloor about 85 km north of Manus Island, Papua New Guinea, centered around the calculated path of the bolide CNEOS 2014-01-08 (IM1). We found about 850 spherules of diameter 0.1-1.3 millimeters in our samples. The samples were analyzed by micro-XRF, Electron Probe Microanalyzer and ICP Mass spectrometry. Here we report major and trace element compositions of the samples and classify spherules based on that analysis. Spherules comprising 22% of the collection, appear to all reflect planetary igneous differentiation and are all different from previously described spherules. A subset of the differentiated-spherules show an excess of Be, La and U, by up to three orders of magnitude relative to the solar system standard of CI chondrites. Detailed mass spectrometry of 12 of these "BeLaU"-type spherules, the population of which may constitute up to ~10% of our entire collected sample, suggests that they are derived from material formed by planetary igneous fractionation. Their chemical composition is unlike any known solar system material. The "BeLaU"-type spherules reflect a highly differentiated, extremely evolved composition of an unknown source., Comment: Accepted for publication in Chemical Geology

Interactive notebooks are a precious tool for creating graphical user interfaces and teaching materials. Python and Jupyter are becoming increasingly popular in this context, with Jupyter widgets at the core of the interactive functionalities. However, while packages and libraries which offer a broad range of general-purpose widgets exist, there is limited development of specialized widgets for computational physics, chemistry and materials science. This deficiency implies significant time investments for the development of effective Jupyter notebooks for research and education in these domains. Here, we present custom Jupyter widgets that we have developed to target the needs of these communities. These widgets constitute high-quality interactive graphical components and can be employed, for example, to visualize and manipulate data, or to explore different visual representations of concepts, clarifying the relationships existing between them. In addition, we discuss with one example how similar functionality can be exposed in the form of JupyterLab extensions, modifying the JupyterLab interface for an enhanced user experience when working with applications within the targeted scientific domains., Comment: 19 pages, 8 figures

We investigate the local geometry of a pair of independent contact structures on 3-manifolds under maps that independently preserve each contact structure. We discover that such maps are homotheties on the contact 1-forms and we discover differential invariants associated to such structures under these equivalences. This allows us to generalize the notion of contact circles and (equilateral) hyperbolas to contact ellipses and hyperbolas. Moreover, these invariants may sometimes be used to define a complete local normal form and in at least one case are related to symplectic structures through a natural $e$-structure on a bundle arising from the Cartan equivalence method. Finally, there is a type of natural Riemannian metric (but not necessarily the well-known associated contact metric) and we discover certain curvatures may be written in terms of the bi-contact differential invariants., Comment: Updated typos and added Theorem 5, which is a new local normal form theorem

Artificial lattices constructed from individual dopant atoms within a semiconductor crystal hold promise to provide novel materials with tailored electronic, magnetic, and optical properties. These custom engineered lattices are anticipated to enable new, fundamental discoveries in condensed matter physics and lead to the creation of new semiconductor technologies including analog quantum simulators and universal solid-state quantum computers. In this work, we report precise and repeatable, substitutional incorporation of single arsenic atoms into a silicon lattice. We employ a combination of scanning tunnelling microscopy hydrogen resist lithography and a detailed statistical exploration of the chemistry of arsine on the hydrogen terminated silicon (001) surface, to show that single arsenic dopants can be deterministically placed within four silicon lattice sites and incorporated with 97$\pm$2% yield. These findings bring us closer to the ultimate frontier in semiconductor technology: the deterministic assembly of atomically precise dopant and qubit arrays at arbitrarily large scales.

Ultra-cool dwarf stars are abundant, long-lived, and uniquely suited to enable the atmospheric study of transiting terrestrial companions with JWST. Amongst them, the most prominent is the M8.5V star TRAPPIST-1 and its seven planets. While JWST Cycle 1 observations have started to yield preliminary insights into the planets, they have also revealed that their atmospheric exploration requires a better understanding of their host star. Here, we propose a roadmap to characterize the TRAPPIST-1 system -- and others like it -- in an efficient and robust manner. We notably recommend that -- although more challenging to schedule -- multi-transit windows be prioritized to mitigate the effects of stellar activity and gather up to twice more transits per JWST hour spent. We conclude that, for such systems, planets cannot be studied in isolation by small programs, but rather need large-scale, jointly space- and ground-based initiatives to fully exploit the capabilities of JWST for the exploration of terrestrial planets.

We present the characterisation of the two transiting planets around HD 152843 (TOI 2319, TIC 349488688) using an intensive campaign of HARPS-N radial velocities, and two sectors of TESS data. These data reveal a unique and fascinating system: HD 152843 b and c have near equal masses of around 9 M$_\oplus$ but differing radii of $3.05 \pm 0.11$ R$_\oplus$ and $5.94^{+0.18}_{-0.16}$ R$_\oplus$ , respectively, and orbital periods of $11.62071^{+9.6e-05}_{-0.000106}$ days and $19.502104^{+7.4e-05}_{-8.5e-05}$ days. This indicates that HD 152843 c is in the lowest fifth percentile in density of the known exoplanet population, and has the longest orbital period among these low density planets. Further, HD 152843 c's radius places it in the Saturn valley, the observed lack of planets larger than Neptune, but smaller than Saturn. The orbital periods of these planets indicate they are near a 5:3 mean motion resonance, indicating the possibility of transit timing variations, and hints at the possibility of interaction with a third planet at some point in the evolution of this system. Further, the brightness of the host star and the low density of HD 152843 c make it a key target for atmospheric characterisation., Comment: Submitted for review to the Monthly Notices of the Royal Astronomical Society. 13 pages, 16 figures

In this work, we show the feasibility of extreme ultraviolet (EUV) patterning on an HF-treated Si(100) surface in the absence of a photoresist. EUV lithography is the leading lithography technique in semiconductor manufacturing due to its high resolution and throughput, but future progress in resolution can be hampered because of the inherent limitations of the resists. We show that EUV photons can induce surface reactions on a partially H-terminated Si surface and assist the growth of an oxide layer, which serves as an etch mask. This mechanism is different from the H-desorption in scanning tunneling microscopy-based lithography. We achieve SiO2/Si gratings with 75 nm half-pitch and 31 nm height, demonstrating the efficacy of the method and the feasibility of patterning with EUV lithography without the use of a photoresist. Further development of the resistless EUV lithography method can be a viable approach to nm-scale lithography by overcoming the inherent resolution and roughness limitations of photoresist materials., Comment: 15 pages, 7 figures

Two-dimensional dopant layers ($\delta$-layers) in semiconductors provide the high-mobility electron liquids (2DELs) needed for nanoscale quantum-electronic devices. Key parameters such as carrier densities, effective masses, and confinement thicknesses for 2DELs have traditionally been extracted from quantum magnetotransport. In principle, the parameters are immediately readable from the one-electron spectral function that can be measured by angle-resolved photoemission spectroscopy (ARPES). Here, buried 2DEL $\delta$-layers in silicon are measured with soft X-ray (SX) ARPES to obtain detailed information about their filled conduction bands and extract device-relevant properties. This study takes advantage of the larger probing depth and photon energy range of SX-ARPES relative to vacuum ultraviolet (VUV) ARPES to accurately measure the $\delta$-layer electronic confinement. The measurements are made on ambient-exposed samples and yield extremely thin ($\approx 1$ $nm$) and dense ($\approx$ $10^{14}$ $cm^2$) 2DELs. Critically, this method is used to show that $\delta$-layers of arsenic exhibit better electronic confinement than $\delta$-layers of phosphorus fabricated under identical conditions., Comment: Published in Advanced Science as a Research Article

We introduce a geometric analysis of turbulent mixing in density-stratified flows based on the alignment of the density gradient in two orthogonal bases that are locally constructed from the velocity gradient tensor. The first basis connects diapycnal mixing to rotation and shearing motions, building on the recent 'rortex-shear decomposition' in stratified shear layers (Jiang et al., J. Fluid Mech. 947, A30, 2022), while the second basis connects mixing to the principal axes of the viscous dissipation tensor. Applying this framework to datasets taken in the stratified inclined duct laboratory experiment reveals that density gradients in locations of high shear tend to align preferentially (i) along the direction of minimum dissipation and (ii) normal to the plane spanned by the rotex and shear vectors. The analysis of the local alignment across increasingly turbulent flows offers new insights into the intricate relationship between the density gradient and dissipation, and thus diapycnal mixing.

The abundances of major carbon and oxygen bearing gases in the atmospheres of giant exoplanets provide insights into atmospheric chemistry and planet formation processes. Thermochemistry suggests that methane should be the dominant carbon-bearing species below $\sim$1000 K over a range of plausible atmospheric compositions; this is the case for the Solar System planets and has been confirmed in the atmospheres of brown dwarfs and self-luminous directly imaged exoplanets. However, methane has not yet been definitively detected with space-based spectroscopy in the atmosphere of a transiting exoplanet, but a few detections have been made with ground-based, high-resolution transit spectroscopy including a tentative detection for WASP-80b. Here we report transmission and emission spectra spanning 2.4-4.0 micrometers of the 825 K warm Jupiter WASP-80b taken with JWST's NIRCam instrument, both of which show strong evidence for methane at greater than 6-sigma significance. The derived methane abundances from both viewing geometries are consistent with each other and with solar to sub-solar C/O and ~5$\times$ solar metallicity, which is consistent with theoretical predictions., Comment: 23 pages, 10 figures, 3 tables. This preprint has been submitted to and accepted in principle for publication in Nature without significant changes

The Australian, Chinese, European, Indian, and North American pulsar timing array (PTA) collaborations recently reported, at varying levels, evidence for the presence of a nanohertz gravitational wave background (GWB). Given that each PTA made different choices in modeling their data, we perform a comparison of the GWB and individual pulsar noise parameters across the results reported from the PTAs that constitute the International Pulsar Timing Array (IPTA). We show that despite making different modeling choices, there is no significant difference in the GWB parameters that are measured by the different PTAs, agreeing within $1\sigma$. The pulsar noise parameters are also consistent between different PTAs for the majority of the pulsars included in these analyses. We bridge the differences in modeling choices by adopting a standardized noise model for all pulsars and PTAs, finding that under this model there is a reduction in the tension in the pulsar noise parameters. As part of this reanalysis, we "extended" each PTA's data set by adding extra pulsars that were not timed by that PTA. Under these extensions, we find better constraints on the GWB amplitude and a higher signal-to-noise ratio for the Hellings and Downs correlations. These extensions serve as a prelude to the benefits offered by a full combination of data across all pulsars in the IPTA, i.e., the IPTA's Data Release 3, which will involve not just adding in additional pulsars, but also including data from all three PTAs where any given pulsar is timed by more than as single PTA., Comment: 21 pages, 9 figures, submitted to ApJ

The direct search for dark matter in the form of weakly interacting massive particles (WIMP) is performed by detecting nuclear recoils (NR) produced in a target material from the WIMP elastic scattering. A promising experimental strategy for direct dark matter search employs argon dual-phase time projection chambers (TPC). One of the advantages of the TPC is the capability to detect both the scintillation and charge signals produced by NRs. Furthermore, the existence of a drift electric field in the TPC breaks the rotational symmetry: the angle between the drift field and the momentum of the recoiling nucleus can potentially affect the charge recombination probability in liquid argon and then the relative balance between the two signal channels. This fact could make the detector sensitive to the directionality of the WIMP-induced signal, enabling unmistakable annual and daily modulation signatures for future searches aiming for discovery. The Recoil Directionality (ReD) experiment was designed to probe for such directional sensitivity. The TPC of ReD was irradiated with neutrons at the INFN Laboratori Nazionali del Sud, and data were taken with 72 keV NRs of known recoil directions. The direction-dependent liquid argon charge recombination model by Cataudella et al. was adopted and a likelihood statistical analysis was performed, which gave no indications of significant dependence of the detector response to the recoil direction. The aspect ratio R of the initial ionization cloud is estimated to be 1.037 +/- 0.027 and the upper limit is R < 1.072 with 90% confidence level, Comment: 20 pages, 10 figures, submitted to Eur. Phys. J. C