179 results on '"Tatsuya Kawae"'
Search Results
2. Invariable Simultaneous Emergence of Antiferromagnetic Order and Tetragonal Deformation in CoO Nanocrystals.
- Author
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Yoichi Ishiwata, Gaku Kawahara, Keisuke Akase, Taisuke Tominaga, Hayato Miyazaki, Hirofumi Ishii, Akira Matsuo, Koichi Kindo, Yuji Inagaki, Kenta Akashi, Tatsuya Kawae, Tetsuya Kida, Satoshi Suehiro, Masashi Nantoh, and Koji Ishibashi
- Abstract
It remains unclear why type-II antiferromagnetic order with a propagation vector along a trigonal axis and a tetragonal Jahn-Teller deformation coexist in a low-temperature phase of CoO. Nanocrystals generally have a lower magnetic transition temperature but crystal size reduction does not affect structural transition locally induced by a crystal field. On this basis, we investigated the magnetic and structural properties of CoO nanocrystals. Both transition temperatures were equally reduced in nanocrystals, which indicates that magnetic order triggers the tetragonal deformation. This observation is consistent with a model that the Jahn-Teller deformation is assisted by spin-orbit energy splitting of t2g electrons in the high-spin Co2+ ion, proposed by Kugel and Khomskii. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
3. Resistivity Measurements in Palladium Hydride Film Prepared by Low-Temperature Hydrogen Absorption Method.
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Ryoma Kato, Ten-ichiro Yoshida, Riku Iimori, Tai Zizhou, Masanobu Shiga, Yuji Inagaki, Takashi Kimura, and Tatsuya Kawae
- Abstract
We investigated the superconducting properties of a palladium hydride (PdHx; x = H=Pd) film with a thickness of ~100 nm prepared by a low-temperature hydrogen (H) absorption method. H atoms were loaded to a Pd film in H2 gas pressure of ~0.25 MPa at temperatures of T = 180 and 150 K. At T = 180 K, after the resistivity variation due to H absorption was almost stopped, the PdHx film was cooled rapidly to low temperatures for the resistivity measurements. A superconducting transition was observed at T
c ~ 1.1 K, where the transition width is smaller than 0.1 K. This indicates that a high-quality sample with a sharp transition can be obtained by providing sufficient time for H absorption. At T = 150 K, although the resistivity variation remained, the film was cooled. The transition temperature Tc increased to ~2.1 K, whereas the transition width increased owing to the inhomogeneity of the H concentration in the film. Curiously, regardless of the H homogeneity, there remained a similar T-dependent residual resistivity in both films prepared at T = 180 and 150 K after the superconducting transition. This implies that the observed residual resistivity is essential for the future of the system, although its origin is not clear. [ABSTRACT FROM AUTHOR]- Published
- 2024
- Full Text
- View/download PDF
4. Over-the-Gap Conductance Oscillations in Superconducting Vanadium Nanocontacts Induced by Hydrogen Impurities
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Md. Saiful Islam, Hiroki Takata, Yuji Inagaki, Kenichi Hashizume, and Tatsuya Kawae
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General Engineering ,General Physics and Astronomy ,General Materials Science - Abstract
We have investigated the current-voltage (
- Published
- 2022
5. Superconducting Properties of Palladium Hydride Systems Prepared by Low-Temperature Absorption
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Ryoma Kato, Rikuo Koga, Kazuki Miyakawa, Masanobu Shiga, Yuji Inagaki, and Tatsuya Kawae
- Published
- 2023
6. Observation of Hybridization Gap in Heavy Fermion System EuNi2(P1−xGex)2 via Point-Contact Spectroscopy
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Masanobu Shiga, Takuya Takahashi, Tsubasa Teramoto, Isao Maruyama, Akihiro Mitsuda, Hirofumi Wada, and Tatsuya Kawae
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- 2023
7. Electronic Density of States in CeSi2−x Studied by Point-Contact Spectroscopy
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Takuya Takahashi, Tsubasa Teramoto, Masanobu Shiga, Isao Maruyama, Keisuke Ida, Kousei Ishiwatari, Masashi Ohashi, and Tatsuya Kawae
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- 2023
8. Observation of Kondo Resonance and Low-Energy Excitation in CeB6 Using Point-Contact Spectroscopy
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Masanobu Shiga, Takuya Takahashi, Tsubasa Teramoto, Fumitoshi Iga, and Tatsuya Kawae
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General Physics and Astronomy - Published
- 2022
9. Precise magnetization measurements down to 500 mK using a miniature 3He cryostat and a closed-cycle 3He gas handling system installed in a SQUID magnetometer without continuous-cooling functionality
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Kazutoshi Shimamura, Hiroki Wajima, Hayato Makino, Satoshi Abe, Yoshinori Haga, Yoshiaki Sato, Tatsuya Kawae, and Yasuo Yoshida
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Superconductivity (cond-mat.supr-con) ,Condensed Matter - Materials Science ,Condensed Matter - Strongly Correlated Electrons ,Physics and Astronomy (miscellaneous) ,Strongly Correlated Electrons (cond-mat.str-el) ,Condensed Matter - Superconductivity ,General Engineering ,General Physics and Astronomy ,Materials Science (cond-mat.mtrl-sci) ,FOS: Physical sciences - Abstract
We have conducted precise magnetization measurements down to 0.5 K with a miniature 3He cryostat and a closed-cycle 3He gas handling system (GHS) for a superconducting quantum interference device magnetometer. The GHS contains two sorption pumps filled with granular charcoals. We pressurize 3He gas up to ambient pressure for the liquification at 3 K and then pump the vapor for cooling. The lowest sample temperature is ∼0.5 K and it can persist for 34 h. We demonstrate the performance of the system by observing the Meissner effect of aluminum below the superconducting transition temperature ∼1 K. We also measured the magnetization curve of the heavy-fermion superconductor CeCoIn5 resulting in successful observation of the lower critical field at 0.5 K.
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- 2022
10. Temperature dependence of spherical electron transfer in a nanosized [Fe14] complex
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Motohiro Nakano, Dayu Wu, Guilin Zhuang, Norimichi Kojima, Takumi Nakanishi, Shinji Kanegawa, Shuqi Wu, Yoshihito Shiota, Mariko Noguchi, Tatsuya Kawae, Michael L. Baker, Xiangwei Gu, Atsushi Okazawa, Yao Li, Kazunari Yoshizawa, Osamu Sato, Shinya Hayami, Yuji Inagaki, Peter Bencok, Wei Huang, and Yuji Miyazaki
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Materials science ,Science ,Intermetallic ,General Physics and Astronomy ,Electronic structure ,Electron ,010402 general chemistry ,01 natural sciences ,Article ,General Biochemistry, Genetics and Molecular Biology ,Electron transfer ,Delocalized electron ,Transition metal ,Organic-inorganic nanostructures ,lcsh:Science ,Multidisciplinary ,Valence (chemistry) ,010405 organic chemistry ,General Chemistry ,0104 chemical sciences ,Crystallography ,Organometallic chemistry ,lcsh:Q ,Ground state - Abstract
The study of transition metal clusters exhibiting fast electron hopping or delocalization remains challenging, because intermetallic communications mediated through bridging ligands are normally weak. Herein, we report the synthesis of a nanosized complex, [Fe(Tp)(CN)3]8[Fe(H2O)(DMSO)]6 (abbreviated as [Fe14], Tp−, hydrotris(pyrazolyl)borate; DMSO, dimethyl sulfoxide), which has a fluctuating valence due to two mobile d-electrons in its atomic layer shell. The rate of electron transfer of [Fe14] complex demonstrates the Arrhenius-type temperature dependence in the nanosized spheric surface, wherein high-spin centers are ferromagnetically coupled, producing an S = 14 ground state. The electron-hopping rate at room temperature is faster than the time scale of Mössbauer measurements (, Fast intermetallic electron transfer is expected in principle in nanozised transition metal complexes, but has been prevented by the bridging ligands. Here the authors synthesize a mixed-valence iron metal-ligand nanocluster with cyanide bridges, showing extended delocalized electronic structure
- Published
- 2019
11. A straightforward DC-reversal method for the Thomson coefficient measurement
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Yasutaka Amagai, Takeshi Shimazaki, Kenjiro Okawa, Tatsuya Kawae, Hiroyuki Fujiki, and Nobu-Hisa Kaneko
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Applied Mathematics ,Electrical and Electronic Engineering ,Condensed Matter Physics ,Instrumentation - Published
- 2022
12. Crystallographic and superconducting properties of filled skutterudite SrOs4P12
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Shingo Deminami, Chihiro Sekine, Leonid Salamakha, Tatsuya Kawae, Keiki Takeda, Yoshiya Uwatoko, Herwig Michor, Jun Gouchi, Ernst Bauer, Toshihiro Kuzuya, and Yukihiro Kawamura
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Physics ,Superconductivity ,Rietveld refinement ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Fractional coordinates ,01 natural sciences ,Magnetization ,symbols.namesake ,Crystallography ,Lattice constant ,0103 physical sciences ,symbols ,Density of states ,Einstein solid ,010306 general physics ,0210 nano-technology ,Powder diffraction - Abstract
The crystallographic and physical properties of the recently discovered filled skutterudite superconductor ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$, synthesized by a high-pressure and -temperature technique, are studied by measuring electrical resistivity, specific heat, and magnetization, and by performing electronic band calculations. X-ray powder diffraction with Rietveld refinement indicates that the lattice parameter of ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$ is 8.093(2) \AA{} and that fractional coordinates of the P site are [0, 0.3607(9), 0.1450(9)], which is also confirmed by calculations based on density functional theory. The electrical resistivity indicates a metallic nature of ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$, which is consistent with the density of states at Fermi energy with 7.5 (states/eV)/f.u. deduced from the electronic band calculations. The Sommerfeld coefficient $\ensuremath{\gamma}$ and Einstein temperature $\ensuremath{\theta}{}_{\mathrm{E}}$ of ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$ are deduced as $\ensuremath{\gamma}\ensuremath{\sim}26\phantom{\rule{4pt}{0ex}}\mathrm{mJ}/{\mathrm{mol}\phantom{\rule{0.16em}{0ex}}\mathrm{K}}^{2}$ and $\ensuremath{\theta}{}_{\mathrm{E}}\ensuremath{\sim}150$ K, respectively. A larger isotropic atomic displacement parameter ${U}_{\mathrm{eq}}$ of Sr compared to other atomic species as obtained from a Rietveld analysis and a specific heat anomaly around 30 K refers to anharmonic lattice vibrations of Sr in ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$. ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$ exhibits two superconducting transitions at ${T}_{\mathrm{c}1}=1.6$ K and ${T}_{\mathrm{c}2}=1.0$ K. Specific-heat data indicate that the observed superconductivity is of bulk nature with approximate volume fractions of $27%$ and $38%$ for superconductivity at ${T}_{\mathrm{c}1}$ and ${T}_{\mathrm{c}2}$, respectively. The electrical resistivity under field and pressure as well as the specific heat under field indicate that ${T}_{\mathrm{c}1}$ is sensitive to the magnetic field and ${T}_{\mathrm{c}2}$ is sensitive to pressure. The results show that ${\mathrm{SrOs}}_{4}{\mathrm{P}}_{12}$ is an $s$-wave weakly coupled superconductor with an electron-phonon mass enhancement ${\ensuremath{\lambda}}_{\text{ep}}\ensuremath{\sim}0.47$.
- Published
- 2021
13. Spin order in the classical spin kagome antiferromagnet MgxMn4−x(OH)6Cl2
- Author
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Takashi Kamiyama, Md. Mahbubur Rahman Bhuiyan, Xu-Guang Zheng, Tatsuya Kawae, Shuki Torii, and Masato Hagihala
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Physics ,Neutron diffraction ,Order (ring theory) ,02 engineering and technology ,Crystal structure ,engineering.material ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetic susceptibility ,Crystallography ,0103 physical sciences ,Spin model ,engineering ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,Herbertsmithite ,Quantum spin liquid ,010306 general physics ,0210 nano-technology - Abstract
Geometrically frustrated kagome-lattice antiferromagnets have received much attention because of their exotic magnetic behaviors. Here we report the synthesis, structure, and magnetism of an $S=5/2$ quasiclassical new spin kagome compound. Polycrystalline compounds of $\mathrm{M}{\mathrm{g}}_{x}\mathrm{M}{\mathrm{n}}_{4\ensuremath{-}x}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$, with a nominal ideal chemical formula of $\mathrm{MgM}{\mathrm{n}}_{3}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$, have been successfully synthesized by selectively substituting the triangular-lattice-plane $\mathrm{M}{\mathrm{n}}^{2+}$ with nonmagnetic $\mathrm{M}{\mathrm{g}}^{2+}$. The compounds studied crystallize in rhombohedral structure in space group $R\text{\ensuremath{-}}3m$, in a similar crystal structure to the much-researched quantum spin liquid candidates herbertsmithite $\mathrm{ZnC}{\mathrm{u}}_{3}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$ and tondiite $\mathrm{MgC}{\mathrm{u}}_{3}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$. Antiferromagnetic transition below ${T}_{\mathrm{N}}\ensuremath{\sim}8\phantom{\rule{0.16em}{0ex}}\mathrm{K}$ and a 120\ifmmode^\circ\else\textdegree\fi{} nearest-neighbor spin ordering confined in the kagome plane with positive spin chirality have been revealed by magnetic susceptibility measurements and neutron diffraction experiment. The obtained value of critical exponent $\ensuremath{\beta}=0.35$ agrees with a three-dimensional Heisenberg spin model. The present work suggests the intrinsic nature of long-range order in classical Heisenberg kagome aniferromagnet and provides a classical reference system to quantum kagome antiferromagnets.
- Published
- 2020
14. Point-Contact Spectroscopy Study of Kondo Insulator SmB6
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Takurou Harada, Kengo Okimura, Tatsuya Kawae, Yuji Inagaki, Masanobu Shiga, and F. Iga
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Point contact ,Materials science ,Condensed matter physics ,Kondo insulator ,Spectroscopy - Published
- 2020
15. Point-Contact Spectroscopy Study of YbPd/W Interface
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Yuji Inagaki, Akihiro Mitsuda, Tatsuya Kawae, Takurou Harada, Takuya Takahashi, Hirofumi Wada, and Masanobu Shiga
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Point contact ,Materials science ,Condensed matter physics ,Interface (Java) ,Spectroscopy - Published
- 2020
16. In-situ Investigation of Electronic Properties in Yttrium-hydride Prepared at Low Temperature
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Tatsuya Kawae, Taishi Yamaguchi, H. Takata, Yuji Inagaki, and Kazuki Miyakawa
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In situ ,chemistry.chemical_compound ,Materials science ,chemistry ,Inorganic chemistry ,Yttrium hydride ,Electronic properties - Published
- 2020
17. Corundum insulating phases in highly Ti-doped V2O3 nanocrystals
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Koji Ishibashi, Ku Ding Tsuei, Hirofumi Ishii, Masaki Imamura, Sho Otsuru, Tatsuya Kawae, Masashi Nantoh, Kazutoshi Takahashi, Tetsuya Kida, Yoichi Ishiwata, Toru Maruyama, Yen Fa Liao, Yuji Inagaki, Takuto Tsukahara, and Satoshi Suehiro
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Materials science ,Doping ,Corundum ,Crystal structure ,engineering.material ,Crystal ,Condensed Matter::Materials Science ,Paramagnetism ,Crystallography ,Lattice constant ,engineering ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,Monoclinic crystal system - Abstract
Doping ${\mathrm{V}}_{2}{\mathrm{O}}_{3}$ with Ti stabilizes the corundum paramagnetic metallic phase and restricts the transition to the monoclinic antiferromagnetic insulating phase at lower temperatures. In this study, we investigated the dependence of phase stability on Ti concentration for ${\mathrm{V}}_{2}{\mathrm{O}}_{3}$ nanocrystals as small as 20 nm. Ti doping of several percent induces a high-temperature insulating phase preserving the magnetic transition without the crystal symmetry change. The emergence of the insulating phases, which are peculiar to this crystal size, can be attributed to the enhancement of the on-site Coulomb interaction $U$ and increased mixing between ${a}_{1g}$ and ${e}_{g}^{\ensuremath{\pi}}$ states accompanied by characteristic lattice parameter changes in the high Ti doping region.
- Published
- 2020
18. Correlation between ferromagnetism and dopant 3d metal-oxygen hybridized state lying at the bottom of conduction band in ZnO-based diluted magnetic semiconductor system
- Author
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Takuto Tsukahara, Satoshi An, Sho Otsuru, Yasuhisa Tezuka, Shunsuke Nozawa, Junichi Adachi, Kenta Akashi, Yuji Inagaki, Tatsuya Kawae, Hirofumi Ishii, Yen-Fa Liao, Tetsuya Kida, Satoshi Suehiro, Masashi Nantoh, Koji Ishibashi, and Yoichi Ishiwata
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General Physics and Astronomy - Published
- 2021
19. Hydrogen-impurity-induced conductance peaks in constriction type Josephson junctions
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Kazuki Miyakawa, Hiroki Takata, Taishi Yamaguchi, Yuji Inagaki, Kazumasa Makise, and Tatsuya Kawae
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Condensed Matter::Superconductivity ,General Engineering ,General Physics and Astronomy ,Condensed Matter::Mesoscopic Systems and Quantum Hall Effect - Abstract
We studied hydrogen (H) and deuterium (D) impurity effects of superconducting Josephson current flowing through the superconductor-constriction-superconductor Josephson junctions (ScS-JJ). When H or D impurities are adsorbed on the surface of the ScS-JJ prepared by niobium or lead, many spike-like peaks with almost the same spacing appear inside the superconducting gap in addition to anomalies owing to the multiple Andreev reflection in the differential conductance spectra. The spacing between the adjacent peaks is independent of the temperature variation. These indicate that H or D impurities adsorbed on the JJ are sources of noise for the Josephson current.
- Published
- 2021
20. Fano profiles in palladium nanoconstrictions
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Tatsuya Kawae, H. Tsujii, Koichiro Ienaga, Yuji Inagaki, M. S. Islam, and H. Takata
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Condensed matter physics ,Chemistry ,Fano resonance ,chemistry.chemical_element ,02 engineering and technology ,General Chemistry ,Condensed Matter::Mesoscopic Systems and Quantum Hall Effect ,021001 nanoscience & nanotechnology ,Condensed Matter Physics ,01 natural sciences ,Atomic units ,Spectral line ,Ferromagnetism ,0103 physical sciences ,Materials Chemistry ,Condensed Matter::Strongly Correlated Electrons ,Kondo effect ,Anomaly (physics) ,010306 general physics ,0210 nano-technology ,Break junction ,Palladium - Abstract
We have performed the differential conductance (dI/dV) measurements of palladium (Pd) nanoconstrictions made by a mechanically controllable break junction technique to examine the origin of Fano resonance observed in atomic sized contacts of ferromagnetic metals such as Ni. As a quasimagnetic metal of Pd undergoing ferromagnetic transition by downsizing, the dI/dV spectra exhibit zero-bias anomalies with a dip, peak or asymmetric shape and are well-fitted by the Fano formula. Moreover, the amplitude of the anomalies varies with the temperature in logarithmic scale, suggesting that the origin of the anomaly is caused by the Kondo effect. These results indicate that the appearance of Kondo effect would be ubiquitous in ferromagnetic atomic scale contacts.
- Published
- 2017
21. Quasi-antiferromagnetic multilayer stacks with 90 degree coupling mediated by thin Fe oxide spacers
- Author
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Kohei Ohnishi, Robert M. Reeve, Yuji Inagaki, Mathias Kläui, Daniel Schönke, Pascal Krautscheid, Takashi Kimura, Terumitsu Tanaka, Hiromi Yuasa, Yongshi Zhong, Gen Nagashima, Yuichiro Kurokawa, Kimihide Matsuyama, Tatsuya Kawae, and Shuu Horiike
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010302 applied physics ,Materials science ,Condensed matter physics ,Magnetic domain ,Atomic force microscopy ,530 Physics ,Oxide ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,530 Physik ,01 natural sciences ,Inductive coupling ,Buffer (optical fiber) ,Magnetization ,chemistry.chemical_compound ,chemistry ,0103 physical sciences ,Antiferromagnetism ,0210 nano-technology ,Antiparallel (electronics) - Abstract
We fabricated quasiantiferromagnetic (quasi-AFM) layers with alternating antiparallel magnetization in the neighboring domains via 90° magnetic coupling through an Fe-O layer. We investigated the magnetic properties and the relationship between the magnetic domain size and the 90° magnetic coupling via experiments and calculations. Two types of samples with a Ru buffer and a (Ni80Fe20)Cr40 buffer were prepared, and we found that with the NiFeCr buffer, the sample has a flatter Fe-O layer, leading to stronger 90° magnetic coupling and a smaller domain size compared with the Ru buffer sample. This trend is well explained by the bilinear and biquadratic coupling coefficients, A12 and B12, in Landau–Lifshitz–Gilbert simulations, suggesting the possibility of using both AFM and FM properties by controlling the quasi-AFM domain size.
- Published
- 2019
- Full Text
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22. Breakdown voltages of cryogenic gaseous helium and in liquid helium
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Tatsuya Kawae, Hiroharu Kawasaki, Toshinobu Shigematsu, and Bunji Ono
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History ,Materials science ,Liquid helium ,law ,Physics::Atomic and Molecular Clusters ,Gaseous helium ,Physics::Atomic Physics ,Atomic physics ,Computer Science Applications ,Education ,Voltage ,law.invention - Abstract
As practical applications of superconductivity have been made in electric power engineering, the breakdown voltage superconductor coolants, such as liquid helium or supercritical helium, have been needed intensively. Furthermore, in our discharge experiment in liquid helium to search for a novel carbon nanotube structure, it was predicted that the breakdown voltage was much higher. So, using the metal spherical electrodes, d.c. breakdown voltages in 4.2K gaseous helium (just above the liquid helium) and in liquid helium have been measured. As a result of the experiment, it was observed that the value is several times larger. Moreover, it found that there was no difference in the discharge phenomenon before and after the superfluid transition temperature.
- Published
- 2021
23. Erratum: 'Anisotropic Magnetic Field Dependence of Specific Heat in the Cubic Symmetric Quadrupolar Kondo Compound Pr0.05La0.95Pb3' [J. Phys. Soc. Jpn. 89, 063704 (2020)]
- Author
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Hiroyuki Suzuki, Tetsuo Kitai, Yuji Inagaki, Tatsuya Kawae, Tetsuya Fujiwara, Mikito Koga, and Yoshiaki Sato
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Physics ,Condensed matter physics ,Specific heat ,General Physics and Astronomy ,Anisotropy ,Magnetic field - Published
- 2020
24. High-accuracy compensation of radiative heat loss in Thomson coefficient measurement
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Takeshi Shimazaki, Kenjiro Okawa, Nobu-Hisa Kaneko, Yasutaka Amagai, Tatsuya Kawae, and Hiroyuki Fujiki
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010302 applied physics ,Accuracy and precision ,Materials science ,Physics and Astronomy (miscellaneous) ,Joule ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Computational physics ,Thermal conductivity ,Electrical resistance and conductance ,0103 physical sciences ,Heat transfer ,Thermoelectric effect ,Emissivity ,0210 nano-technology ,Joule heating - Abstract
We report a simple and accurate method to address the inevitable radiative heat loss in the Thomson coefficient measurement. The additional steps required are the measurement of the Joule heat arising from the ac current, measurement of the electrical resistance of the sample, and calculation of the ratio of the two measurement signals arising from the Joule and Thomson effects. The underlying concept is that most of the radiative heat loss that occurs during the measurement of Joule and Thomson heats can be compensated for by calculating the ratio of the two signals. This is because the heat loss during the Joule heat measurement will be highly similar to that during the Thomson heat measurement. Heat transfer analysis indicates that radiative heat loss is reduced by at least a factor of six. Once the Thomson coefficient is measured, accurate Seebeck and Peltier coefficients can be obtained in a single run. This approach was demonstrated by performing measurements on fine platinum wires in the temperature range of 80 K–300 K. The difference between the compensated and uncompensated curves became significant as the temperature increased; moreover, this difference was proportional to the cube of the temperature for a long fine-wire sample, where there is substantial radiative heat loss. Thus, the proposed approach is completely different from a conventional one, wherein the measurement accuracy degrades owing to inevitable radiative heat loss without prior knowledge of the thermal conductivity and emissivity of the sample.
- Published
- 2020
25. Anisotropic Magnetic Field Dependence of Specific Heat in the Cubic Symmetric Quadrupolar Kondo Compound Pr0.05La0.95Pb3
- Author
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Tetsuya Fujiwara, Yuji Inagaki, Yoshiaki Sato, Hiroyuki Suzuki, Tetsuo Kitai, Mikito Koga, and Tatsuya Kawae
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Materials science ,Condensed matter physics ,Specific heat ,General Physics and Astronomy ,Anisotropy ,Magnetic field - Abstract
We studied the dependence of the electronic specific heat Cel/T on the magnetic field up to H = 8 T in a dilute quadrupolar compound Pr0.05La0.95Pb3 with a non-Kramers Γ3 doublet in the crystal-ele...
- Published
- 2020
26. Superconductivity in Palladium Hydride Systems
- Author
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Tatsuya Kawae, Takashi Kimura, Yuji Inagaki, Souhei Hirota, Daiki Itou, and Si Wen
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Superconductivity ,chemistry.chemical_compound ,Materials science ,chemistry ,0103 physical sciences ,General Physics and Astronomy ,chemistry.chemical_element ,Physical chemistry ,Palladium hydride ,010306 general physics ,01 natural sciences ,010305 fluids & plasmas ,Palladium - Abstract
The superconductivity of palladium–hydride (Pd–H) system was discovered by Skoskiewicz in 1972. Thereafter, many studies have been carried out on Pd–H and palladium deuteride (Pd–D) systems along w...
- Published
- 2020
27. Precise absolute Seebeck coefficient measurement and uncertainty analysis using high-Tc superconductors as a reference
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Hiroyuki Fujiki, Tatsuya Kawae, Yasutaka Amagai, Kenjiro Okawa, Takeshi Shimazaki, and Nobu-Hisa Kaneko
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010302 applied physics ,Superconductivity ,Materials science ,Temperature control ,Condensed matter physics ,01 natural sciences ,010305 fluids & plasmas ,Meissner effect ,Thermocouple ,Condensed Matter::Superconductivity ,Seebeck coefficient ,0103 physical sciences ,Thermoelectric effect ,Measurement uncertainty ,Instrumentation ,Uncertainty analysis - Abstract
The intrinsic properties of superconductors enable the direct determination of the absolute Seebeck coefficient at low temperature due to the disappearance of the Seebeck effect to obey the Meissner effect. We report a precision absolute Seebeck coefficient measurement for the fine Pt sample determined using the high-Tc YBa2Cu3O7-x (YBCO) superconductor as a reference and an analysis of the measurement uncertainty. To make a precision measurement and aid in the verification of the uncertainty components, we developed a cryostat system that enables temperature control in a stable manner. The expected performance of the reference superconductor yielded a zero value well below Tc, which was validated by a superconductor-superconductor thermocouple experiment. Uncertainty analysis shows that the main limiting factor for this measurement is the accuracy of the temperature difference measurement using the resistance temperature sensors, along with its analog noise. We obtained values of S = 5.6 ± 0.2 µV/K with a relative expanded uncertainty of 3% at 80 K and precisely compared the Pt value with that determined by the high-Tc Bi2Sr2Ca2Cu3O8+δ (Bi-2223) superconductor, which has a higher Tc. We found that there was no difference between the Seebeck coefficient values obtained from the YBCO and Bi-2223 references up to its Tc within the expanded measurement uncertainties of 0.3 µV/K (2σ). These results provide accurate validation that the high-Tc superconductor is a useful reference up to the liquid nitrogen temperature.
- Published
- 2020
28. Two-dimensional triangular-lattice Cu(OH)Cl, belloite, as a magnetodielectric system
- Author
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Takashi Kamiyama, I Yamauchi, Masato Hagihala, Shuki Torii, Xu-Guang Zheng, Masayoshi Fujihala, Shigeto Kitajima, Sanghyun Lee, Makoto Maki, and Tatsuya Kawae
- Subjects
Materials science ,Physics and Astronomy (miscellaneous) ,Condensed matter physics ,media_common.quotation_subject ,Center (category theory) ,Frustration ,02 engineering and technology ,Spin structure ,021001 nanoscience & nanotechnology ,01 natural sciences ,Heat capacity ,Magnetic susceptibility ,0103 physical sciences ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,Hexagonal lattice ,010306 general physics ,0210 nano-technology ,Spin-½ ,media_common - Abstract
Quantum spins on a triangular lattice may bring out intriguing and exotic quantum ground states. Here we report a magnetodielectric system of CuOHCl wherein $S=1/2\mathrm{C}{\mathrm{u}}^{2+}$ spins constitute a two-dimensional triangular lattice with the layers weakly coupled via Cl-H-O bonding. Despite strong magnetic interactions, as expected from the relatively high value of ${\ensuremath{\theta}}_{\mathrm{CW}}=\ensuremath{-}100\phantom{\rule{0.16em}{0ex}}\mathrm{K}$, antiferromagnetic transition occurred at ${T}_{N}=11\phantom{\rule{0.16em}{0ex}}\mathrm{K}$, followed by an uprising turn of the magnetic susceptibility below \ensuremath{\sim}7 K. Neutron-diffraction experiment revealed a coplanar spin structure on the triangular lattice below the ${T}_{N}$, with each spin pointing toward the center of a triangle. Of the three spins on a triangle, two are antiparallel and the third one is angled ${120}^{\ensuremath{\circ}}$ to the antiparallel spins. A concerted effect of geometric frustration in the triangular lattice and superexchange interactions through a zig-zag path via double Cu-O-Cu and double Cu-Cl-Cu bridges counted for this spin arrangement. Further investigation using dielectric constant and heat capacity measurements, as well as a microscopic probe of muon spin rotation, revealed a magnetodielectric effect and the possibility of multiferroic transition at ${T}^{*}\ensuremath{\sim}5\phantom{\rule{0.16em}{0ex}}\mathrm{K}$, which is suspected to be in close relation to geometric frustration in this triangular lattice. The present paper presents a magnetodielectric system on a two-dimensional triangular lattice with chemical stoichiometry. It can also serve as a rare reference to the hotly debated quantum spin-orbital liquid compound $\mathrm{LiNi}{\mathrm{O}}_{2}$.
- Published
- 2018
29. Cluster-Based Haldane State in an Edge-Shared Tetrahedral Spin-Cluster Chain: Fedotovite K2Cu3O(SO4)3
- Author
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Takami Tohyama, Keisuke Tomiyasu, H. Morodomi, Richard A. Mole, Tatsuya Kawae, Dehong Yu, Shinichiro Yano, K. Kindo, Akira Matsuo, Takanori Sugimoto, Yoichi Murakami, Reiji Kumai, Setsuo Mitsuda, H. Sagayama, Masayoshi Fujihala, and Yuji Inagaki
- Subjects
Physics ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Molecular physics ,Magnetic susceptibility ,Heat capacity ,Inelastic neutron scattering ,Magnetization ,0103 physical sciences ,Tetrahedron ,Cluster (physics) ,Condensed Matter::Strongly Correlated Electrons ,010306 general physics ,0210 nano-technology ,Ground state ,Spin (physics) - Abstract
Fedotovite K_{2}Cu_{3}O(SO_{4})_{3} is a candidate of new quantum spin systems, in which the edge-shared tetrahedral (EST) spin clusters consisting of Cu^{2+} are connected by weak intercluster couplings forming a one-dimensional array. Comprehensive experimental studies by magnetic susceptibility, magnetization, heat capacity, and inelastic neutron scattering measurements reveal the presence of an effective S=1 Haldane state below T≅4 K. Rigorous theoretical studies provide an insight into the magnetic state of K_{2}Cu_{3}O(SO_{4})_{3}: an EST cluster makes a triplet in the ground state and a one-dimensional chain of the EST induces a cluster-based Haldane state. We predict that the cluster-based Haldane state emerges whenever the number of tetrahedra in the EST is even.
- Published
- 2018
30. Spin order in the Heisenberg kagome antiferromagnet MgFe3(OH)6Cl2
- Author
-
Tatsuya Kawae, Masayoshi Fujihala, Koichi Kindo, Takashi Kamiyama, X. G. Zheng, Sanghyun Lee, and Akira Matsuo
- Subjects
Physics ,Muon ,Pyrochlore ,Order (ring theory) ,02 engineering and technology ,Spin structure ,engineering.material ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetization ,Crystallography ,0103 physical sciences ,engineering ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,010306 general physics ,0210 nano-technology ,Realization (systems) ,Spin-½ - Abstract
Spin behaviors on kagome lattices have received increased attention because of their exotic magnetic states. Here, we report magnetic ordering in the $S=2$ kagome antiferromagnet $\mathrm{MgF}{\mathrm{e}}_{3}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$. The compound has been synthesized by selectively replacing the magnetic ions in the triangular planes of its parent compound of deformed pyrochlore $\mathrm{F}{\mathrm{e}}_{2}{(\mathrm{OH})}_{3}\mathrm{Cl}$ with nonmagnetic Mg. Whereas $\mathrm{F}{\mathrm{e}}_{2}{(\mathrm{OH})}_{3}\mathrm{Cl}$ showed antiferromagnetic order below ${T}_{\mathrm{N}}=8.5\phantom{\rule{0.16em}{0ex}}\mathrm{K}$ with persistent spin fluctuations, $\mathrm{MgF}{\mathrm{e}}_{3}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$ showed an antiferromagnetic transition at an enhanced ${T}_{\mathrm{N}}$ value of 9.9 K. Susceptibility, high-field magnetization, and neutron-diffraction studies suggest that $\mathrm{MgF}{\mathrm{e}}_{3}{(\mathrm{OH})}_{6}\mathrm{C}{\mathrm{l}}_{2}$ is a Heisenberg-like spin system with a ${120}^{\ensuremath{\circ}}$ nearest-neighbor spin structure confined in the kagome plane and spin-vector chirality of $q=\ensuremath{-}1$ below ${T}_{\mathrm{N}}$. Muon spin-rotation/-relaxation studies demonstrate that the persisting spin fluctuations are suppressed relative to $\mathrm{F}{\mathrm{e}}_{2}{(\mathrm{OH})}_{3}\mathrm{Cl}$. The present paper reports the experimental realization of an $S=2$ kagome antiferromagnet, highlighting a real system with a quasiclassical Heisenberg spin, which may also be a valuable reference system for quantum Heisenberg kagome antiferromagnets.
- Published
- 2017
31. Long-range magnetic order in the Heisenberg pyrochlore antiferromagnets Gd2Ge2O7 and Gd2Pt2O7 synthesized under high pressure
- Author
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Haidong Zhou, Chiming Jin, Jinguang Cheng, Kazuyuki Matsubayashi, J.-S. Zhou, Xiaoqin Li, Zhiling Dun, J. B. Goodenough, Tatsuya Kawae, Yoshiya Uwatoko, S. J. Lv, Qiliang Cui, Chaojing Lin, Yukio Sato, and Yunqi Cai
- Subjects
Physics ,Condensed matter physics ,Specific heat ,Magnetic order ,Pyrochlore ,02 engineering and technology ,engineering.material ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetic susceptibility ,Crystallography ,High pressure ,0103 physical sciences ,engineering ,Antiferromagnetism ,010306 general physics ,0210 nano-technology - Abstract
$\mathrm{G}{\mathrm{d}}_{2}\mathrm{S}{\mathrm{n}}_{2}{\mathrm{O}}_{7}$ and $\mathrm{G}{\mathrm{d}}_{2}\mathrm{T}{\mathrm{i}}_{2}{\mathrm{O}}_{7}$ have been regarded as good experimental realizations of the classical Heisenberg pyrochlore antiferromagnet with dipolar interaction. The former was found to adopt the Palmer-Chalker state via a single, first-order transition at ${T}_{\mathrm{N}}\ensuremath{\approx}1\phantom{\rule{0.16em}{0ex}}\mathrm{K}$, while the latter enters a distinct, partially ordered state through two successive transitions at ${T}_{\mathrm{N}1}\ensuremath{\approx}1\phantom{\rule{0.16em}{0ex}}\mathrm{K}$ and ${T}_{\mathrm{N}2}=0.75\phantom{\rule{0.16em}{0ex}}\mathrm{K}$. To shed more light on their distinct magnetic ground states, we have synthesized two more gadolinium-based pyrochlore oxides, $\mathrm{G}{\mathrm{d}}_{2}\mathrm{G}{\mathrm{e}}_{2}{\mathrm{O}}_{7}$ and $\mathrm{G}{\mathrm{d}}_{2}\mathrm{P}{\mathrm{t}}_{2}{\mathrm{O}}_{7}$, under high-pressure conditions and performed detailed characterizations via x-ray powder diffraction, dc and ac magnetic susceptibility, and specific heat measurements down to 100 mK. We found that both compounds enter a long-range antiferromagnetically ordered state through a single, first-order transition at ${T}_{\mathrm{N}}=1.4\phantom{\rule{0.16em}{0ex}}\mathrm{K}$ for $\mathrm{G}{\mathrm{d}}_{2}\mathrm{G}{\mathrm{e}}_{2}{\mathrm{O}}_{7}$ and ${T}_{\mathrm{N}}=1.56\phantom{\rule{0.16em}{0ex}}\mathrm{K}$ for $\mathrm{G}{\mathrm{d}}_{2}\mathrm{P}{\mathrm{t}}_{2}{\mathrm{O}}_{7}$, with the specific heat anomaly similar to that of $\mathrm{G}{\mathrm{d}}_{2}\mathrm{S}{\mathrm{n}}_{2}{\mathrm{O}}_{7}$ rather than $\mathrm{G}{\mathrm{d}}_{2}\mathrm{T}{\mathrm{i}}_{2}{\mathrm{O}}_{7}$. Interestingly, the low-temperature magnetic specific heat values of both $\mathrm{G}{\mathrm{d}}_{2}\mathrm{G}{\mathrm{e}}_{2}{\mathrm{O}}_{7}$ and $\mathrm{G}{\mathrm{d}}_{2}\mathrm{P}{\mathrm{t}}_{2}{\mathrm{O}}_{7}$ were found to follow nicely the ${T}^{3}$ dependence as expected for a three-dimensional antiferromagnet with gapless spin-wave excitations. We have rationalized the enhancement of ${T}_{\mathrm{N}}$ in terms of the reduced Gd-Gd distances for the chemically pressurized $\mathrm{G}{\mathrm{d}}_{2}\mathrm{G}{\mathrm{e}}_{2}{\mathrm{O}}_{7}$ and the addition of extra superexchange pathways through the empty $\mathrm{Pt}\ensuremath{-}{e}_{g}$ orbitals for $\mathrm{G}{\mathrm{d}}_{2}\mathrm{P}{\mathrm{t}}_{2}{\mathrm{O}}_{7}$. Our current study has expanded the family of gadolinium-based pyrochlores and permits us to achieve a better understanding of their distinct magnetic properties in a more comprehensive perspective.
- Published
- 2016
32. Precise measurement of absolute Seebeck coefficient from Thomson effect using ac-dc technique
- Author
-
Hiroyuki Fujiki, Nobu-Hisa Kaneko, Tatsuya Kawae, Kenjiro Okawa, Yasutaka Amagai, and Takeshi Shimazaki
- Subjects
010302 applied physics ,Materials science ,Joule effect ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,Thermoelectric materials ,01 natural sciences ,lcsh:QC1-999 ,Computational physics ,Thermal conductivity ,Electrical resistance and conductance ,Thermocouple ,Seebeck coefficient ,0103 physical sciences ,Heat transfer ,Measurement uncertainty ,0210 nano-technology ,lcsh:Physics - Abstract
The Seebeck coefficient is the most widely measured property specific to thermoelectric materials. The absolute Seebeck coefficient S determined from the Thomson effect is highly sensitive to systematic errors incurred in the determination of the material thermal conductivity and geometry and heat loss from the sample to surroundings caused by temperature differences. Here, we report a technique for the precision measurement of S based on the Thomson effect using an ac-dc technique. This technique utilizes accurate equivalent-amplitude ac and dc currents, which can eliminate the need for acquiring accurate thermal conductivity and geometry values. These parameters can be replaced by the precisely and readily measurable parameters of electrical resistance and temperature changes caused by the Joule effect. The correction term of the heat loss owing to heat transfer via the thermocouple vanishes upon calculating the ratio of the measured temperature changes for both ac and dc excitations. We obtain an S value of -4.8 μV/K ± 0.2 μV/K at a temperature of 300 K for platinum, which is most widely used as a reference, with an expanded relative uncertainty of 4% (2σ). The obtained S value of Pt is closely consistent with that obtained from the conventional method using the Thomson effect within the uncertainty, and importantly, the measurement uncertainty improves to an acceptable level, which is four times more precise.
- Published
- 2019
33. In situ Magnetization Measurement of Superconducting Transition in PdH0.82 and PdD0.79 Prepared by Low-Temperature Absorption
- Author
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H. Takata, Tatsuya Kawae, Yousuke Kawasaki, Yuji Inagaki, Yuji Furukawa, and Si Wen
- Subjects
010302 applied physics ,In situ ,Superconductivity ,Materials science ,Hydride ,Analytical chemistry ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Magnetization ,0103 physical sciences ,0210 nano-technology ,Absorption (electromagnetic radiation) - Abstract
We studied the superconducting properties of Pd hydride and deuteride prepared by a low temperature absorption method using in situ magnetization measurements down to T = 0.5 K. The absorption was ...
- Published
- 2018
34. Recent Progress in Multi-Extreme Condition by Miniature High-Pressure Cell
- Author
-
Tatsuya Kawae, Yoshiya Uwatoko, Akihiko Hisada, and Kazuyuki Matsubayashi
- Subjects
Materials science ,Nuclear engineering ,High pressure cell ,General Materials Science ,General Chemistry ,Condensed Matter Physics - Published
- 2012
35. Impurity effects of hydrogen and deuterium in vanadium nanoconstrictions
- Author
-
Y. Ueno, M. S. Islam, Yuji Inagaki, K. Hashizume, H. Takata, and Tatsuya Kawae
- Subjects
History ,Materials science ,Deuterium ,Hydrogen ,chemistry ,Impurity ,Inorganic chemistry ,chemistry.chemical_element ,Vanadium ,Computer Science Applications ,Education - Published
- 2018
36. Volume shrinkage dependence of ferromagnetic moment in lanthanide ferromagnets gadolinium, terbium, dysprosium, and holmium
- Author
-
Masahiko Tokita, Takayuki Tajiri, T. Iwamoto, Hiroyuki Deguchi, Seishi Takagi, Tatsuya Kawae, Masaki Mito, Kazuyoshi Takeda, Y. Komorida, and Kazuya Matsumoto
- Subjects
Lanthanide ,D. Magnetic properties ,C. High pressure ,A. Elements ,Condensed matter physics ,Magnetic moment ,Gadolinium ,chemistry.chemical_element ,Terbium ,General Chemistry ,Condensed Matter Physics ,Magnetization ,Nuclear magnetic resonance ,chemistry ,Ferromagnetism ,D. Crystal structure ,Dysprosium ,General Materials Science ,Holmium ,A. Magnetic materials - Abstract
The Gd–Ho series of lanthanide ferromagnets, which includes gadolinium (Gd), terbium (Tb), dysprosium (Dy), and holmium (Ho), undergoes similar structural transitions, e.g., the hcp→Sm-type→dhcp→fcc transitions, under pressure. Through high-field DC magnetic measurements and structural analyses, we found that the ferromagnetic moments disappeared at a specified critical pressure, which resulted in volume shrinkage of 16.7±1.7% for each ferromagnet. The results of the present study suggest that the disappearance of the ferromagnetic moments of Gd–Ho under pressure could be understood within the framework of a band picture related to volume shrinkage.
- Published
- 2009
37. Defect-Free Nanocrystals: Impurity-Induced First-Order Phase Transitions in Highly Crystalline V2O3Nanocrystals (Adv. Mater. Interfaces 12/2015)
- Author
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Tatsuya Kawae, Yen-Fa Liao, Masashi Nantoh, Junpei Azuma, Yoichi Ishiwata, Yasuhisa Tezuka, Yuji Inagaki, Hirofumi Ishii, Masaki Imamura, Kazutoshi Takahashi, Eiko Takahashi, Koji Ishibashi, Tetsuya Kida, Kenta Akashi, Daisuke Nishio-Hamane, and Masao Kamada
- Subjects
Phase transition ,Materials science ,Condensed matter physics ,Nanocrystal ,Mechanics of Materials ,Impurity ,Mechanical Engineering ,Inorganic chemistry ,Defect free ,Impurity doping ,Metal–insulator transition ,First order - Published
- 2015
38. Non-Fermi liquid behavior in Pr-based dilute quadrupolar system
- Author
-
Y. Nakaie, Chenshu Li, Yasuo Yoshida, Keiichiro Kinoshita, N. Tateiwa, Tetsuo Kitai, Tatsuya Kawae, M. Hidaka, and Kazuyoshi Takeda
- Subjects
Condensed matter physics ,Chemistry ,Mechanical Engineering ,Metals and Alloys ,Thermal conduction ,Magnetic susceptibility ,Ion ,Mechanics of Materials ,Materials Chemistry ,Kondo effect ,Fermi liquid theory ,Ground state ,Residual entropy ,Doublet state - Abstract
We have studied the low temperature properties of PrPb3 and PrInAg2 with the crystal-electric-field ground state of a non-Kramers Γ 3 doublet diluted by non-magnetic La ions to examine the correlation between the Γ 3 quadrupolar moments and the conduction electrons. In PrxLa1−xPb3, a non-Fermi liquid (NFL) behavior is observed at Pr concentrations of x ≤ 0.05 . The specific heat C / T increases monotonically below T = 1.5 K, which can be scaled with a characteristic temperature T ∗ defined at each concentration x. Application of magnetic field raises C / T rapidly, which demonstrates the presence of the residual entropy at lower temperatures. In PrxLa1−xInAg2, NFL behavior is confirmed for x = 0.05 and 0.1 in the susceptibility below 15 K and in the specific heat below 7 K. It is supposed that the Kondo effect arising from the correlation between the dilute Γ 3 moments and the conduction electrons gives rise to NFL behavior in both systems.
- Published
- 2006
39. Single-crystal growth of layered Ce–Ni–Ge ternary compounds
- Author
-
Gendo Oomi, Kiyotaka Ishida, Takemi Komatsubara, Tatsuya Kawae, Kazuyoshi Takeda, Isamu Satoh, and Masashi Ohashi
- Subjects
Ternary numeral system ,Chemistry ,Mechanical Engineering ,Metals and Alloys ,Space group ,Crystal structure ,Magnetic susceptibility ,Crystallography ,Mechanics of Materials ,Materials Chemistry ,Orthorhombic crystal system ,Crystallite ,Ternary operation ,Powder diffraction - Abstract
We have attempted to grow single crystals of Ce-Ni-Ge ternary system having layered structure. Several polycrystalline samples, CeNiGe, (2 < x < 3), Ce 3 Ni x Ge y (1.6 < x < 2, 6.5 < y < 8.5) and Ce 2 NiGe 6 , were prepared by an arc-melting of constituent elements. All samples grown by the Czochralsky method are found to contain the phase of the orthorhombic CeNiGe 2 type structure. A Rietveld method was applied to analyze the crystal structure of CeNiGe 2.2 using X-ray powder diffraction data at room temperature. The refined lattice parameters were a = 4.260 A, b = 16.81 A and c = 4.209 A with the space group Cmmm. The temperature dependence of magnetic susceptibility showsa significant variation in the magnetic properties depending on the concentration of Ge, that is, magnetic phase transition temperature depends on starting materials. It may come from the fact that the magnetic property relies on a structural homogeneity and a stoichiometry.
- Published
- 2006
40. Specific Heat Study of Novel Spin-Gapped System: (CH3)2NH2CuCl3
- Author
-
Osamu Wada, Tatsuya Kawae, Yasuo Yoshida, Kazuyoshi Takeda, Kenji Takeo, Yuji Inagaki, Yoshitami Ajiro, and Takayuki Asano
- Subjects
Physics ,Strongly Correlated Electrons (cond-mat.str-el) ,Condensed matter physics ,FOS: Physical sciences ,General Physics and Astronomy ,Magnetic field ,Condensed Matter - Strongly Correlated Electrons ,Gapless playback ,Ferromagnetism ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,Ground state ,Spin (physics) ,Saturation (magnetic) ,Phase diagram - Abstract
Specific heat measurements down to 120mK have been performed on a quasi-one-dimensional $S=1/2$ spin-gapped system (CH$_3$)$_2$NH$_2$CuCl$_3$ in a magnetic field up to 8 T. This compound has a characteristic magnetization curve which shows a gapless ground state and a plateau at 1/2 of the saturation value. We have observed a spontaneous antiferromagnetic ordering and a field-induced one below and above the 1/2 plateau field range, respectively. The field versus temperature phase diagram is quite unusual and completely different from those of the other quantum spin systems investigated so far. In the plateau field range, a double-structure in the specific heat is observed, reflecting the coexistence of ferromagnetic and antiferromagnetic excitations. These behaviors are discussed on the basis of a recently proposed novel quantum spin chain model consisting of weakly coupled ferromagnetic and antiferromagnetic dimers., Comment: 4 pages, 3 figures, submitted to J. Phys. Soc. Jpn
- Published
- 2005
41. Low-Temperature Properties in Dilute Quadrupolar Compound PrxLa1-xInAg2
- Author
-
Tatsuya Kawae, Takayuki Asano, Kazuyoshi Takeda, Tetsuo Kitai, Chenshu Li, and Yasuo Yoshida
- Subjects
Range (particle radiation) ,Materials science ,Condensed matter physics ,Electrical resistivity and conductivity ,General Physics and Astronomy ,Electron ,Kondo effect ,Thermal conduction ,Ground state ,Magnetic susceptibility ,Ion - Abstract
The low-temperature properties of Pr x La 1- x InAg 2 have been studied for a wide concentration range of Pr ions between 0≤ x ≤0.6. The susceptibility above T =15 K is well reproduced by the crystal-electric-field level scheme with a non-Kramers Γ 3 doublet in the ground state for each concentration, while that below T =15 K shows a non-Fermi-liquid behavior with a logarithmic temperature dependence. The temperature dependence of the specific heat C / T shows a monotonic enhancement below T =10 K, which can be scaled by a characteristic temperature T * defined at each concentration. These results suggest that the anomalous low-temperature properties are understood as the single-ion nature of Γ 3 quadrupolar moments. The origin of the anomalous properties is discussed in connection with the quadrupolar Kondo effect arising from the correlation between the Γ 3 moments and the conduction electrons.
- Published
- 2005
42. Pressure-induced stabilization of an intermediate phase in the triangular lattice antiferromagnet CsNiCl3
- Author
-
Tatsuya Kawae, Takayuki Asano, Yoshitami Ajiro, Kazuyoshi Takeda, and Ito M
- Subjects
Phase transition ,Magnetic moment ,Condensed matter physics ,Chemistry ,Antiferromagnetism ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,Hexagonal lattice ,Pressure dependence ,Condensed Matter Physics ,Anisotropy ,Heat capacity ,Ion - Abstract
Pressure effects on the magnetic properties of the triangular lattice Heisenberg antiferromagnet CsNiCl3 have been studied through heat capacity measurements up to the pressure of 6.6 kbar. With increasing pressure, two successive phase transitions at TN1 = 4.74 K and TN2 = 4.24 K at 0 kbar, which result from a small Ising-type anisotropy of S = 1 moments on Ni2+ ions, shift to higher temperatures in proportion to the pressure. Moreover, the pressure dependence of the entropy indicates that the intermediate phase AF1 (TN2
- Published
- 2003
43. Heat Capacity Study of the Doping Effect of Paramagnetic Radicals on the Organic Spin–Peierls System (p-CyDOV Radical Crystal)
- Author
-
Shuichi Tanaka, Kazuo Mukai, Kazuyoshi Takeda, Masaki Mito, Tatsuya Kawae, and Masanobu Yanagimoyo
- Subjects
Paramagnetism ,Materials science ,Condensed matter physics ,Impurity ,Radical ,Transition temperature ,Doping ,Analytical chemistry ,General Physics and Astronomy ,Antiferromagnetism ,Magnetic susceptibility ,Heat capacity - Abstract
The doping effect of paramagnetic organic radical impurities ( p -CyDTV) on the organic spin–Peiels (SP) system of p -CyDOV (3-(4-cyanophenyl)-1,5-dimethyl-6-oxoverdazyl; the SP transition temperature T SP =15.0 K) was studied by the heat capacity measurement down to 0.1 K. At low temperatures below 1 K, quite a sharp heat capacity peak was detected for each system with small impurity concentration ( x ) at the temperature T N ( x ); T N (0)=0.135 K (±0.002 K), T N (0.01)=0.290 K and T N (0.07)=0.164 K. The appearance of the peak for the system with x =0 is considered to be due to minute and inevitable impurities in the pure p -CyDOV. From the dependence of T N ( x ), T N (0)< T N (0.01), and the heat capacity behavior on x , the peaks for x =0 and 0.01 are explained to be accompanied with the three-dimensional (3D) antiferromagnetic (AFM) transition in the SP phase. While the decrease of T N ( x ) for higher impurities x =0.07 than that for x =0.01 may be interpreted as merely a 3D AFM transition from th...
- Published
- 2003
44. Heat capacity study of the doping effect of paramagnetic impurity in organic spin-Peierls system: p -CyDOV radical crystal
- Author
-
Masaki Mito, Masanobu Yanagimoto, Tatsuya Kawae, Kyohei Mukai, Shuichi Tanaka, and Kazuyoshi Takeda
- Subjects
Condensed matter physics ,Chemistry ,Transition temperature ,Heat capacity ,Inorganic Chemistry ,Crystal ,Paramagnetism ,Crystallography ,Impurity ,Materials Chemistry ,Antiferromagnetism ,Physical and Theoretical Chemistry ,Magnetic impurity ,Phase diagram - Abstract
Heat capacity studies were performed for the doped verdazyl radical crystals, ( p -CyDOV) 1− x ( p -CyDTV) x ( x =0, 0.01, and 0.07), to clarify the effect of magnetic impurity ( p -CyDTV) on the spin-Peierls (SP) transition ( T SP =15.0 K) of 3-(4-cyanophenyl)-1,5-dimethyl-6-oxoverdazyl ( p -CyDOV) radical crystal, where the >C O group in p -CyDOV is replaced by the >C S group in p -CyDTV. The antiferromagnetic (AFM) transitions were observed at T N =0.135, 0.290, and 0.164 K for the crystals with x =0, 0.01, and 0.07, respectively, indicating the coexistence of AFM order and SP state in the systems with x =0 and 0.01, and the appearance of the single phase of AFM order in the system with x =0.07 below T N =0.164 K. However, the heat capacity anomaly associated with the SP transition was not found at T SP =15.0 K for the pure p -CyDOV crystal ( x =0), whereas the anomalous broad peak in the heat capacity was observed at T ′ SP =5.6 K. The entropy consumption in the above broad peak was about 3% of the total spin entropy R ln 2, suggesting that this transition may relate to SP transition. The pressure induced by the solidification of the Apiezon-N grease, which was used as the thermal binder for the heat capacity measurement, at low temperature may affect the shift of the SP transition temperature. The doping effects for the organic SP system ( p -CyDOV), which include the temperature ( T : T SP and T N )—impurity ( x ) phase diagram, are similar to those for the inorganic SP system (CuGeO 3 ), although the one-dimensionality, i.e., ∣ zJ ′/ J ∣≅6×10 −4 , in the organic p -CyDOV system is much higher than that (∼10 −1 ) in the inorganic CuGeO 3 system, where zJ ′ and J are inter- and intra-chain exchange interactions. This work is the first report of the heat capacity study of the doping effect on the organic SP transition system.
- Published
- 2003
45. Pressure Effects on anS= 1 Haldane Compound Ni(C5H14N2)2N3(PF6)
- Author
-
Seishi Takagi, Hironori Nakao, Yoichi Murakami, Tomohiko Ishii, Shoji Yamamoto, Kazuyoshi Takeda, Masaki Mito, Hironori Akama, Hiroyuki Deguchi, Masahiro Yamashita, and Tatsuya Kawae
- Subjects
Quantum monte carlo simulation ,Materials science ,Molecular geometry ,Condensed matter physics ,Monte Carlo method ,General Physics and Astronomy ,Crystal structure ,Magnetic susceptibility ,Ammonium compounds - Abstract
The pressure effects on an S = 1 Haldane compound Ni(C 5 H 14 N 2 ) 2 N 3 (PF 6 ) (NDMAP) have been investigated through the magnetic susceptibility (χ) measurements using single crystalline sample...
- Published
- 2003
46. Spin Correlations on a Site Diluted Square Lattice Heisenberg Antiferromagnet Covering the Percolation Threshold
- Author
-
Kazuyoshi Takeda, Osamu Fujita, Masaki Mito, Tatsuya Kawae, Masako Hitaka, Hiroyuki Deguchi, Yoshinori Muraoka, and Kazuo Yamagata
- Subjects
General Materials Science ,General Chemistry ,Condensed Matter Physics - Published
- 2002
47. Magnetic Properties of a Random-bond Ladder Cu 2 (C 5 H 12 N 2 ) 2 (Cl 1− x Br x ) 4 at Low Temperatures
- Author
-
Hiroyuki Deguchi, Tatsuya Kawae, Hiroyuki Nojiri, Shuichi Yamamoto, Hatsuo Watanabe, Kazuyoshi Takeda, Masaki Mito, Seishi Takagi, and Mitsuhiro Motokawa
- Subjects
Magnetic measurements ,Condensed matter physics ,Specific heat ,Chemistry ,General Chemistry ,Condensed Matter Physics ,Magnetic susceptibility ,Magnetization ,Crystallography ,Paramagnetism ,Phase (matter) ,General Materials Science ,Ground state ,Spin-½ - Abstract
Magnetic measurements have been performed to investigate random-bond effects on a spin-ladder system. We synthesize a random mixture compound Cu 2 (C 5 H 12 N 2 ) 2 (Cl 1− x Br x ) 4 which is expected to form a spin ladder with random-exchange legs and rungs. The magnetic properties of the compound are rather different from those of the pure systems. Paramagnetic divergence is significantly observed for the susceptibility at low temperatures and the magnetization appears even at low fields. The results suggest that the ground state of the random-bond ladder is a Griffiths phase.
- Published
- 2002
48. Development of point-contact spectrometer for spin polarization measurements
- Author
-
Kenichi Tenya, Tatsuya Kawae, Yuji Inagaki, Masanobu Shiga, H. Takata, N. Nishimura, and Hiroshi Kambara
- Subjects
Physics ,Superconductivity ,History ,Helium-4 ,Spin polarization ,Spectrometer ,Measuring instrument ,Atomic physics ,Spin (physics) ,Polarization (waves) ,Piezoelectricity ,Computer Science Applications ,Education - Published
- 2017
49. Low-temperature hydrogen absorption in metallic nanocontacts studied by point-contact spectroscopy measurements
- Author
-
Tatsuya Kawae, M. S. Islam, Koichiro Ienaga, Yuji Inagaki, H. Takata, and K. Hashizume
- Subjects
History ,Materials science ,Analytical chemistry ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Computer Science Applications ,Education ,Metal ,Point contact ,visual_art ,0103 physical sciences ,visual_art.visual_art_medium ,Hydrogen absorption ,010306 general physics ,0210 nano-technology ,Spectroscopy - Published
- 2017
50. Kondo-Fano resonance in atomic-scale contacts for ferromagnetic metals
- Author
-
H. Tsujii, Koichiro Ienaga, Islam, Yuji Inagaki, Tatsuya Kawae, Y. Ueno, and H. Takata
- Subjects
History ,Materials science ,Condensed matter physics ,Ferromagnetism ,Fano resonance ,Atomic units ,Computer Science Applications ,Education - Published
- 2017
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