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Multistage tungsten mineralization was recently discovered in the Mamupu copper‐polymetallic deposit in the southern Yulong porphyry copper belt (YPCB), Tibet. This study reports the results of cathodoluminescence, trace element and Sr isotope analyses of Mamupu scheelite samples, undertaken in order to better constrain the mechanism of W mineralization and the sources of the ore‐forming fluids. Three different types of scheelite are identified in the Mamupu deposit: scheelite A (Sch A) mainly occurs in breccias during the prograde stage, scheelite B (Sch B) forms in the chlorite‐epidote alteration zone in the retrograde stage, while scheelite C (Sch C) occurs in distal quartz sulfide veins. The extremely high Mo content and negative Eu anomaly in Sch A represent high oxygen fugacity in the prograde stage. Compared with ore‐related porphyries, Sch A has a similar REE pattern, but with higher ΣREE, more depleted HREE and slightly lower (87Sr/86Sr)i ratios. These features suggest that Sch A is genetically related to ore‐related porphyries, but extensive interaction with carbonate surrounding rocks affects the final REE and Sr isotopic composition. Sch B shows dark (Sch B‐I) and light (Sch B‐II) domains under CL imaging. From Sch B‐I to Sch B‐II, LREEs are gradually depleted, with MREEs being gradually enriched. Sch C has the highest LREE/HREE ratio, which indicates that it inherited the geochemical characteristics of fluids after the precipitation of HREE‐rich minerals, such as diopside and garnet, in the early prograde stage. The Mo content in Sch B and Sch C gradually decreased, indicating that the oxygen fugacity of the fluids changed from oxidative in the early stages to reductive in the later, the turbulent Eu anomaly in Sch B and Sch C indicating that the Eu anomaly in the Mamupu scheelite is not solely controlled by oxygen fugacity. The extensive interaction of magmatic‐hydrothermal fluids and carbonate provides the necessary Ca2+ for the precipitation of scheelite in the Mamupu deposit. [ABSTRACT FROM AUTHOR]

The Jiama deposit, a significant porphyry‐skarn‐type copper polymetallic deposit located within the Gangdese metallogenic belt in Tibet, China, exemplifies a typical porphyry metallogenic system. However, the mineral chemistry of its accessory minerals remains under‐examined, posing challenges for resource assessment and ore prospecting. Utilizing electron microprobe analysis and LA‐ICP‐MS analysis, this study investigated the geochemical characteristics of apatite in ore‐bearing granite and monzogranite porphyries, as well as granodiorite, quartz diorite, and dark diorite porphyries in the deposit. It also delved into the diagenetic and metallogenic information from these geochemical signatures. Key findings include: (1) The SiO2 content, rare earth element (REE) contents, and REE partition coefficients of apatite indicate that the dark diorite porphyry possibly does not share a cogenetic magma source with the other four types of porphyries; (2) the volatile F and Cl contents in apatite, along with their ratio, indicate the Jiama deposit, formed in a collisional setting, demonstrates lower Cl/F ratios in apatite than the same type of deposits formed in a subduction environment; (3) compared to non‐ore‐bearing rock bodies in other deposits formed in a collisional setting, apatite in the Jiama deposit exhibits lower Ce and Ga contents. This might indicate that rock bodies in the Jiama deposit have higher oxygen fugacity. Nevertheless, the marginal variation in oxygen fugacity between ore‐bearing and non‐ore‐bearing rock bodies within the deposit suggests oxygen fugacity may not serve as the decisive factor in the ore‐hosting potential of rock bodies in the Jiama deposit. [ABSTRACT FROM AUTHOR]

Rubidium (Rb) deposits mostly occur in the South China and Central Asia orogenic belts and are often closely associated with highly differentiated granites. This study investigates a newly‐discovered giant Rb deposit at Gariatong in the Central Lhasa terrane in Tibet. Detailed field studies and logging data revealed that the Rb mineralization mainly occurs in monzogranite and is related to greisenization. LA‐ICP‐MS U‐Pb dating of zircon yielded ages of 19.1 ± 0.2 Ma and 19.0 ± 0.2 Ma for greisenized monzogranite and fresh monzogranite, respectively. The monzogranites are characterized as strongly peraluminous, with high contents of SiO2, Al2O3, K2O and Na2O as well as a high differentiation index. They are enriched in light rare earth and large ion lithophile elements with significant negative Eu anomalies and depleted high field‐strength elements. Petrological and geochemical features of these ore‐related monzogranites suggest that they are highly fractionated S‐type granites, derived from remelting of crustal materials in a post‐collisional setting. The geochemistry of zircon and apatite points to a low oxygen fugacity of the ore‐related monzogranite during the magma's evolution. The discovery of the Gariatong Rb deposit suggests that the Central Lhasa terrane may be an important region for rare metal mineralization. [ABSTRACT FROM AUTHOR]

Jiama is a giant, high‐grade porphyry copper system in the Gangdese metallogenic belt, Tibet. Multistage intermediate–felsic porphyries intruded in this deposit, some of which are strongly associated with copper‐polymetallic mineralization. These ore‐bearing porphyries include monzogranite, granodiorite, and quartz diorite porphyries. A new granite aplite dyke was found in the south of Jiama. Its age, genesis, and relationship with ore‐related magmatism are obscure. Here, its emplacement age and petrogenesis were determined using mineralogy, zircon U‐Pb dating, geochemistry, and Sr‐Nd‐Pb isotope studies. The zircon LA‐ICP‐MS U‐Pb age of the aplite dyke is 16.66 ± 0.21 Ma (n = 14, MSWD = 0.66), earlier than that of the ore‐bearing porphyries (∼15 Ma) in Jiama. Furthermore, the aplite exhibits high amounts of silicon (SiO2 = 73.39%–74.74%), potassium (K2O = 5.12%–6.61%), aluminum (Al2O3 = 14.25%–14.69%), and light/heavy rare earth elements (LREE/HREE = 12.12–16.19) as well as negative europium (δEu = 0.47–0.72) and weak negative cerium anomalies (δCe = 0.84–0.93). The aplite dyke is characteristic of metaluminous–peraluminous I‐type granite, which is rich in large‐ion lithophile elements (Rb, Ba, Th and U) and depleted in high‐field‐strength elements (Nb, P and Ti). The aplite dyke and ore‐bearing porphyries in the Jiama deposit are the results of a partial melting of the juvenile lower crust, according to whole‐rock geochemistry and Sr‐Nd‐Pb isotope data, but the dyke and ore‐bearing porphyries were emplaced from the same magma chamber at different times. Thus, the aplite dyke shows the composition of the early evolution stage of shallow magma in the Jiama deposit and is the product of rapid condensation and crystallization. [ABSTRACT FROM AUTHOR]

The Xiongcun Cu–Au ore district is in the southern middle Gangdese Metallogenic Belt, Tibet, and formed during Neo-Tethyan oceanic subduction. The Xiongcun ore district mainly comprises two deposits, the No. I and No. II deposits, which were formed by two individual mineralization events according to deposit geology and Re–Os isotopic dating of molybdenite. The No. I deposit is similar to a reduced porphyry copper–gold deposit, given the widespread occurrence of primary and/or hydrothermal pyrrhotite and common CH4-rich and rare N2-rich fluid inclusions. The No. II deposit, similar to classic oxidized porphyry copper–gold deposits, contains highly oxidized minerals, including magnetite, anhydrite, and hematite. The halogen chemistry of the ore-forming fluid from the No. I and No. II deposits is still unclear. Biotite geochemistry with halogen contents was used to investigate the differences in ore-forming fluid between the No. I and No. II deposits. Hydrothermal biotite from the No. I deposit, usually intergrown with sphalerite, is Mg-rich and classified as phlogopite and Mg-biotite, and hydrothermal biotite from the No. II deposit is classified as Mg-biotite. Hydrothermal biotite from the No. I deposit has significantly higher SiO2, MnO, MgO, F, Li, Sc, Zn, Rb, Tl, and Pb contents and lower Al2O3, FeOtot, Cl, Ba, Cr, V, Co, Ni, Y, Sr, Zr, Th, and Cu contents than the biotite from the No. II deposit. Hydrothermal biotites from the No. I and No. II deposits yield temperatures ranging from 230 °C to 593 °C and 212 °C to 306 °C, respectively. The calculated oxygen fugacity and fugacity ratios indicate that the hydrothermal fluid of the No. I deposit has a higher F content, oxygen fugacity, and log(fHF/fHCl) value and a lower log(fH2O/fHF) value than the hydrothermal fluid from the No. II deposit. The biotite geochemistry shows that the No. I and No. II deposits formed from different hydrothermal fluids. The hydrothermal fluid of the No. I deposit was mixed with meteoric waters containing organic matter, resulting in a decrease in oxygen fugacity and more efficient precipitation of gold. The No. I and No. II deposits were formed by a Cl-rich hydrothermal system conducive to transporting Cu and Au. The decreasing Cl, oxygen fugacity, and temperature may be the key factors in Cu and Au precipitation. Biotite geochemistry allows a more detailed evaluation of the halogen chemistry of hydrothermal fluids and their evolution within porphyry Cu systems. [ABSTRACT FROM AUTHOR]

The subduction of the Bangong–Nujiang Ocean is important in the geological evolution of the Tibetan Plateau. In this paper, we report new zircon U-Pb age and Lu-Hf isotopic data and whole-rock elemental and Sr-Nd-Pb isotopic data for Early Cretaceous dacites from the Rena-Co area (RCA) in the southern Qiangtang Terrane (QT), central Tibet and use these data to better understand the tectonic evolution of the Bangong–Nujiang suture. LA–ICP-MS dating of zircons yields ages of 109.5 ± 0.6 Ma to 109.6 ± 0.8 Ma for the dacites from the RCA. Geochemically, these dacites are medium-K calc-alkaline and show high SiO2 contents of 64.79–70.37 wt.%, high Sr contents of 517–598 ppm and low Y contents of 8.45–10.7 ppm, similar to those of typical adakites. Additionally, all the rocks are strongly enriched in light rare earth elements and some large ion lithophile elements (e.g. Rb, U, K and Cs) but significantly depleted in high-field-strength elements (e.g. Nb, Ta and Ti), consistent with the geochemical characteristics of arc-type magmas formed in the subduction zone. Moreover, these adakite-like dacites show whole-rock initial (87Sr/86Sr)i ratios of 0.705119 to 0.705491, (206Pb/204Pb)i ratios of 18.489 to 18.508, (207Pb/204Pb)i ratios of 15.591 to 15.612, (208Pb/204Pb)i ratios of 38.599 to 38.686, ϵ Nd (t) values of −0.28 to +1.25 and single-stage Nd model ages of 642 to 818 Ma, as well as significantly positive zircon ϵ Hf(t) values of 3.9–13.1, with young Hf-depleted mantle ages of 331 to 923 Ma. These geochemical and isotopic data indicate that they are most likely derived from the juvenile thickened mafic lower continental crust, which contains partial melts of metasomatized peridotite and subduction-related fluids in the magma source region. Based on previous studies and our new data, we propose that the RCA adakite-like dacites are most likely a result of the northwards subduction of the Bangong–Nujiang Ocean lithosphere beneath the southern QT during the Early Cretaceous and that a slab rollback model could explain the formation of the RCA adakite-like dacites. [ABSTRACT FROM AUTHOR]

The Sinongduo mining region includes two types of mineralizations: the epithermal and the carbonate‐hosted Pb‐Zn‐Ag deposits. Despite being studied for many years, the ore formation process and genesis of the carbonate‐hosted Pb‐Zn‐Ag deposits remain poorly understood. The Pb‐Zn‐Ag ore bodies occur as veins and are hosted by limestone and dolostone of the Permian Xiala Formation. Three sulfide mineralization substages have been identified at the Sinongduo carbonate‐hosted deposit. Indium coupled with Cu, Co and Sn was incorporated into sphalerite as substitutions: 2Zn2+ ↔ Cu+ + In3+, (3n/2 + 1)Zn2+ ↔ Co2+ + nIn3+ or (2n + 1)Zn2+ ↔ Co2+ + n(Cu+ + In3+) (n > 1) and 4Zn2+ ↔ Sn2+ + 2In3+. Sphalerite and pyrite in the mineralization stage display δ34S values in a narrow range of +5.7‰ to +11.3‰, which are similar to those of Palaeocene igneous rocks, indicative of a magmatic source of sulfur. We present systematic carbon‐hydrogen‐oxygen isotope results that further support a magmatic source for the ore‐forming fluids that were influenced by meteoric water. Furthermore, the Pb isotope compositions of sulfide minerals in the Sinongduo carbonate‐hosted deposit overlap with the values of coeval Linzizong volcanic rocks and are similar to those of Indian Ocean sediments, indicating upper crustal sources of metals. We conclude that the Sinongduo carbonate‐hosted Pb‐Zn‐Ag deposit is a medium‐ to low‐temperature magmatic‐hydrothermal deposit related to Linzizong magmatism. [ABSTRACT FROM AUTHOR]

The Baingoin batholith is one of the largest granitic plutons in the North Lhasa terrane. Its petrogenesis and tectonic setting have been studied for decades, but remain controversial. Here we report data on geochronology, geochemistry and isotopes of Early Cretaceous granitoids within the Baingoin batholith, which provide more evidence to uncover its petrogenesis and regional geodynamic processes. The Early Cretaceous magmatism yields ages of 134.4–132.0 Ma and can be divided into I‐type, S‐type and highly fractionated granites. The I‐ and S‐type granites exhibit medium SiO2, high K2O/Na2O with negative εNd(t) and εHf(t) values, whereas, the albite granites have very high SiO2 (79.04%–80.40%), very low K2O/N2O, negative εNd(t) and a large variation in εHf(t). Our new data indicate that these granitoids are derived from unbalanced melting in a heterogeneous source area. The granodiorites involved had a hybrid origin from partial melting of basalt‐derived and Al‐rich rocks in the crust, the porphyritic monzogranites being derived from partial melting of pelitic rocks. The albite granites crystallized from residual melt separated from K‐rich magma within the 'mush' process and underwent fractionation of K‐feldspar. We believe that the Early Cretaceous magmatism formed in an extensional setting produced by the initial and continuous rollback of a northward‐subducting slab of the NTO. [ABSTRACT FROM AUTHOR]

The Tibetan Plateau is a product of the continental collision between the Indian and Asian plates along the Indus-Yarlung suture zone that started in the early Cenozoic. This collision initially produced stress at the collisional boundary and later propagated with time on both the Indian plate and Asian plate. Many studies have reported tectonic deformation in the Himalayas representing the immediate response of continental collision on the Indian side near the collisional boundary. However, there have been only few studies on the early Cenozoic shortening structures in the Lhasa block that forms the southernmost part of the Asian plate. In this study, we performed Ar/Ar geochronology of syntectonic muscovite from the Sinongduo thrust system in the central Lhasa block. The results show that the Sinongduo thrust system was active in the Early Eocene. We interpret the Sinongduo thrust system as an immediate response to the India-Asia collision in the Lhasa block. This study reconciles the early Cenozoic India-Asia collision with the lack of tectonic response in the Lhasa block. [ABSTRACT FROM AUTHOR]

Explanation: From Lakange Mo (Cu) deposit to Jiama Cu polymetallic deposit to Bangpu Mo mineralization to Qulong Cu-Mo deposit to Bangpu Cu mineralization, the Cl contents in apatite gradually increase, but the F contents in apatite gradually decrease, and the S content is similar but variation. It indicates that the Mo-dominated porphyry deposit formed from F-S-rich magma, whereas the Cu-dominated porphyry deposit formed from Cl-S-rich magma. [Display omitted] • There are two different magmatic-hydrothermal systems that formed the Bangpu Mo-Cu deposit. • Cu and Mo mineralization contain zircon and apatite with different geochemical features. • Cu mineralization was related to Cl-rich porphyry system, whereas Mo-mineralization was related to F-rich porphyry system. The Bangpu deposit, located in the eastern part of the Gangdese Porphyry Copper Belt, Tibet, is a porphyry Mo-Cu deposit in a continental collisional orogenic belt. Cu and Mo mineralization occurred separately in the Bangpu deposit. Mo (Cu) mineralization occurred mainly in the monzogranite porphyry (MP), while Cu (Mo) mineralization occurred mainly in the diorite porphyry (DP). The cause of such spatial differences in Cu and Mo mineralization in the Bangpu deposit remains unclear. In this study, the mineral chemistry of apatite and zircon was investigated to reveal the differences in the nature of ore-forming magma between Cu (Mo) and Mo (Cu) mineralization in the Bangpu deposit. The chondrite-normalized REE patterns of the apatite grains from the MP were enriched in LREEs with negative Eu anomalies, whereas those from the DP and biotite monzonitic granite (BM) had strong negative Eu anomalies with no obvious differentiation between LREEs and HREEs. The DP, MP, and BM have a low T TiZ range from 657 °C to 917 °C and a high AST range from 687 °C to 1079 °C. The zircon grains from the DP and MP had different Th/U ratios and T TiZ values, indicating that these porphyry samples probably experienced different magma crystallization or crystal fractionation histories. The zircon Ce4+/Ce3+ and Eu/Eu* ratios indicate that the ore-bearing DP and MP have higher oxygen fugacity than the BM. The F, Cl, and S contents in the apatite showed that the DP magmas were Cl- and S- rich, whereas the MP magmas magmas were F- and S- rich. The Bangpu porphyry Mo-Cu deposit results from two superimposed magmatic-hydrothermal systems. Mo was mainly partitioned into the F-rich magmatic-hydrothermal system released from the MP, and Cu was mainly partitioned into the Cl-rich magmatic-hydrothermal system released from the DP. Our results show that zircon and apatite geochemistry can be used to explain the spatial distribution of Cu and Mo mineralization in porphyry Cu-Mo systems. [ABSTRACT FROM AUTHOR]

Continental crust has long been considered too buoyant to be subducted beneath another continent, although geophysical evidence in collision zones predict continental crust subduction. This is particularly significant where upper continental crust is detached allowing the lower continental crust to subduct, albeit the mechanism of such subduction and recycling of the upper continental crust remain poorly understood. Here, we investigate Paleocene S-type magmatic and volcanic rocks from the Linzizong volcanic succession in the southern Lhasa block of Tibet. These rocks exhibit highly enriched 87Sr/86Sr, 207Pb/206Pb and 208Pb/206Pb together with depleted 143Nd/144Nd isotope ratios. The geochemical and isotopic features of these rocks are consistent with those of modern upper continental crust. We conclude that these Paleocene S-type volcanic and magmatic rocks originated from the melting of the upper continental crust from microcontinent subduction during the late stage of India–Asia convergence. [ABSTRACT FROM AUTHOR]

This paper presents new apatite fission track (AFT) and apatite (U-Th)/He (AHe) data from the Duolong ore district. The corresponding AFT and AHe ages provide insights into the uplift and exhumation history of the Duolong ore district, revealing rapid exhumation with an erosional exhumation rate of 0.067 km/Ma between 65 and 35 Ma, and slow exhumation with an erosional exhumation rate of 0.023 km/Ma since 35 Ma. The new data in this study, along with previous low-temperature thermochronology data, show that samples with ages from 130 to 83 Ma are distributed close to Shuanghu in the central Qiangtang, samples with ages from 65 to 45 Ma are distributed evenly across the whole Qiangtang terrane, and several samples with ages from 20 to 7 Ma are distributed at the edge of the Qiangtang terrane. The Qiangtang terrane experienced heterogeneous surface uplift. The central Qiangtang was initially uplifted during the Early Cretaceous, and the weathered paleosoil dated between 120 and 110 Ma in the Duolong ore district is consistent with the exhumation during this period. Large-scale uplift and exhumation of the Qiangtang terrane between the Palaeocene and Eocene is consistent with the rapid exhumation of the Duolong ore district between 65 and 35 Ma; finally, the uplift and exhumation at the edge of the Qiangtang terrane since the Eocene caused the Duolong ore district to be uplifted to its present elevation. [ABSTRACT FROM AUTHOR]

[Display omitted] • Zircon U-Pb dating results refine the emplacement age of the Xikeng pluton at 232.2 ± 1.1 Ma. • Cassiterite and wolframite U-Pb dating constrains the timing of W-Sn mineralization from Xigkeng deposit at 228.4 ± 0.90 Ma and 227.8 ± 1.60 Ma, respectively. • Source of magmatic materials was derived from reworking of crustal materials under an extensional setting. The Chongyi–Shangyou–Dayu ore-concentrated district represents one of the most important wolframite production bases in China, and most of the W-Sn deposits formed in the early Yanshanian period. The Xikeng quartz vein-type W-Sn deposit is located spatially not far from the Triassic Keshuling granitic pluton. The deposit contains 43 ore-bearing quartz veins, in which the ore minerals are mainly cassiterite and wolframite. These ore veins are concentrated in the Sinian metasandstone and sandy slate of the Laohutang Formation and extend down to the top of the concealed granite. The concealed intrusion is composed of medium- to fine-grained muscovite granites, which relate to the Indosinian Keshuling granite, according to geophysical data. Zircon grains from the concealed Xikeng granitic intrusion have a concordant U-Pb age of 232.1 ± 1.1 Ma (MSWD = 0.9). The zircon εHf(t) values range from −11.0 to −7.9, indicating primary reworking of the ancient crustal materials. Wolframite and cassiterite grains yield Tera-Wasserburg concordia intercept ages of 228.4 ± 0.9 Ma (MSWD = 1.2) and 227.8 ± 1.6 Ma (MSWD = 0.3) for the Xikeng deposit, respectively. These data demonstrate that the Indosinian W-Sn mineralization events were genetically related to granitic magma activities that share similar magmatic sources with the Yanshanian W-Sn mineralization-associated granitic intrusions. Combined with previous robust granitic and metallogenic ages, this paper identifies a new Indosinian W-Sn mineralization event in southern Jiangxi Province, Nanling Range. [ABSTRACT FROM AUTHOR]

The Xin'gaguo deposit is representative of the skarn Pb–Zn polymetallic zone in the northern Gangdese porphyry metallogenic belt, Tibet. Pb–Zn mineralization is hosted in the Take'na formation skarn. The Xin'gaguo ore‐forming process can be divided into prograde skarn, retrograde skarn and quartz‐sulfides. Skarn minerals include garnet, diopside, and epidote, with minor wollastonite, actinolite, and chlorite. Metallic minerals are mainly sphalerite, galena, chalcopyrite, magnetite, and pyrrhotite, with minor arsenopyrite, marcasite, native bismuth, cosalite, and gersdorffite. The LA–ICP–MS zircon U–Pb age of the diorite is 59.66±0.52 Ma. Diorite samples are characterized by fractioned REE patterns with marked positive Eu anomalies, enriched LILEs (Rb, Ba, Th, U, and K) and depleted HFSEs (Ta, Nb, Zr, Hf, and Ti), belong to the calc‐alkaline series and have metaluminous compositions. Zircon εHf(t) values of the diorite are positive (5.7–11) and lie between the chondrite and mantle values. These geochemical characteristics suggest that the diorite was formed by the partial melting of a young metasomatized asthenospheric mantle wedge deriving basaltic rocks. The δ34S values of sulfides range from −4.7 to 4.5‰ and show a bimodal distribution, indicating interactions of magma‐derived ore fluid with biogenic sulfide minerals from the Take'na formation. The 206Pb/204Pb (18.5–18.629), 207Pb/204Pb (15.599–15.704), and 208Pb/204Pb (38.616–38.975) of sulfides show that ore‐forming metals were derived from mixed sources, in part from the Lhasa Terrane basement. Skarn mineral compositions imply that the ore‐forming environment was variable, and underwent at least three changes in oxidation‐reduction state. The geochemical characteristics of diorite indicate that the Xin'gaguo deposit formed within the Indo‐Asian continental collision tectonic setting. [ABSTRACT FROM AUTHOR]

[Display omitted] • Accessory minerals geochemistry characteristics are affected by prior or cocrystallizing minerals. • The Cl contents in melts are important for forming porphyry Cu-Au deposits. • Zircon and apatite geochemistry combination is useful for refining targets in the SLT. The products of long-lasting magmatism (ca. 170 Myr) related to the northward subduction of the Neo-Tethys Ocean are preserved in the southern Lhasa subterrane (SLT). However, only a few large porphyry Cu–Au deposits related to these igneous rocks have been discovered in the Xiongcun ore concentration area. Here, we present zircon and apatite data on Jurassic fertile suites (FS), barren suites (BS), and recently proposed prospecting target suites (PTS) in the SLT, intending to present a case study of the regional-scale porphyry metallogenic potential. The zircon geochemical data with Rayleigh fractionation modeling show that the zircon geochemical characteristics of the FS and PTS were affected by high proportions of amphibole and titanite crystallization, whereas the zircon geochemistry of the BS displays the effects of plagioclase fractionation or mixing with the least evolved melts. The zircon Ce4+/Ce3+ and Eu/Eu* values cannot be used to trace the oxygen fugacity of the magma due to prior or simultaneous mineral crystallization. However, the zircon Ce/Ce* and Ce/Nd ratios may be used as semiquantitative measures of the magma redox conditions. This result is similar to that calculated by the new magmatic oxybarometer using trace elements in zircon, showing that the FS (ΔFMQ = 1.21 ± 0.42) and PTS (ΔFMQ = 1.29 ± 0.51) have higher oxygen fugacity levels than the BS (ΔFMQ = 0.40 ± 0.88). The melt S contents estimated from magmatic apatites are lower in the FS and PTS than in the BS, which is attributed to prior anhydrite crystallization under high oxygen fugacity and low temperature conditions. The higher Cl in the melt of the FS (average 0.098 wt%) than in the melts of the PTS (average 0.045 wt%) and BS (average 0.04 wt%) shows that elevated Cl contents in melts are likely important for forming porphyry Cu–Au deposits. The combined geochemical characteristics of zircon and apatite suggest that a high oxygen fugacity (ΔFMQ > 1.2), prior or concurrent anhydrite crystallization, and high zircon Eu/Eu* (>0.6), Ce4+/Ce3+, and (Yb/Dy) N values can be used to refine potential porphyry Cu–Au targets on a regional scale in the SLT. High melt Cl contents and apatite MnO and Pb contents can effectively indicate fertile suites at the deposit scale. [ABSTRACT FROM AUTHOR]

The Zegulangbei deposit develops a complete porphyry metallogenetic system, whose magmatic emplacement and mineralization was similarly related to an isolated apophysis derived from a uniform shallow magmatic chamber as the Main deposit. Jiama is a complex porphyry metallogenetic system composed of several isolated magmatic-hydrothermal centers. Multi-types of mineralization and alteration coexist among these metallogenetic centers, partially overlapped, developed with complicated and various metallogenic elements. [Display omitted] • Geological features of Zegulangbei deposit were identified in the Jiama ore district. • Precise geochronology redefine the magmatism, alteration and mineralization age. • Main deposit and Zegulangei deposit have originated from the same magma source. • Jiama is a polycentric, complex porphyry mineralization system. Jiama is a typical giant-scale collisional-type porphyry mineralization system of in the Gangdese metallogenic belt, Tibet. The Zegulangbei deposit is located in the northern part of the ore district, which was a recent discovery. In the Zegulangbei deposit, intrusions have developed in multiple stages and led to the formation of complex porphyry intrusions (2# porphyries), of which granodiorite porphyry and Ⅱ-quartz diorite porphyry occurred related to mineralization. Hydrothermal alteration surrounding the 2# porphyries is characterized by potassic, phyllic, and chlorite–sericite alteration, with minor propylitization, argillization and tourmalinization. Furthermore, veinlet-disseminated copper and molybdenum mineralization mainly occurred within the potassic and phyllic alteration zones. Partial copper mineralization developed within the chlorite–sericite alteration zone. The mineralization is comprised of porphyry Cu–Mo, hornfels Cu–Mo and skarn Cu–polymetallic ore bodies. Hydrothermal vein system developed well, including 5-staged veins (M-, A-, B-, C-, and D-type vein). The similar ages of intrusive rocks (15.8–14.5 Ma, U–Pb), biotite and sericite alteration minerals (15.04–15.02 Ma, 40Ar–39Ar), and molybdenite (14.9 Ma, Re–Os) indicate that the intermediate–felsic magmatic rock emplacement triggered the hydrothermal alteration and mineralization in the Zegulangbei deposit. Geochemistry and Sr–Nd–Pb isotopes of the intrusions in Zegulangbei are consistent with those of the intrusions in the Main deposit (1# porphyries) and the Miocene adakites that developed in the eastern Gangdese belt, implying they were generated from the partial melting of the thickened phlogopite-bearing juvenile crust that had been reworked by diapirs of the arc magma during subduction. The evidence presented in this study suggests that Zegulangbei developed a complete porphyry Cu–polymetallic mineralization system, which was related to the same magma chamber in the upper crust that caused the mineralization in the Main deposit. [ABSTRACT FROM AUTHOR]

• The Sinongduo deposit is the first discovered low-sulfidation epithermal deposit. • The Pb-Zn mineralization is mainly concentrated in the range of 60.9–63.7 Ma. The Sinongduo Ag-Pb-Zn deposit is the first documented low-sulfidation epithermal deposit in Tibet and located on the southern side of the Longge'er-Gongbujiangda arc fault belt of the Lhasa terrane. The Ag-rich base metal veins and relatively low-grade breccias and stockworks in the Sinongduo deposit occur in the Paleocene high-potassium calc-alkaline to shoshonitic series volcanic rocks, including rhyolitic welded tuff breccia and volcanic breccia, rhyolitic ignimbrite, rhyolitic crystal fragment tufflava, rhyolite, and rhyolitic tuff. A nearly N-S-trending fault is the most important ore-controlling structure in the deposit. Galena and sphalerite are the dominant ore minerals in quartz-sericite-illite ± adularia veins, with subordinate argentite, pyrargyrite, native silver, chalcopyrite, pyrite and tennantite. The most widespread silver minerals are argentite, pyrargyrite, pearceite and native silver, which occur in fissures in Fe-Mn carbonates, jasper and early sulfides. The mineralization process can be divided into a pre-ore stage, main ore stage, and post-ore stage, and the main metallogenic stage is divided into the galena substage, sphalerite substage and silver minerals substage. Microthermometric analyses of the primary liquid-rich and vapour-rich fluid inclusions (FIs) in the sphalerite (SpII), main ore stage quartz (QzII) and post-ore stage quartz (QzIII) of the Sinongduo deposit indicate that the FIs in SpII, QzII and QzIII are mainly homogenized at temperatures of 197.2–280.8 °C, 185.6–290.4 °C and 148.2–218.7 °C with salinities of 1.40–5.71 wt% NaCl equiv., 1.59–5.71 wt% NaCl equiv. and 2.07–8.94 wt% NaCl equiv., respectively. These data indicate that the deposit was formed in a low-temperature and low-salinity environment, corroborating an epithermal system of mineralization. The O and H isotope compositions of the ore-forming fluids (δ18O = −0.6 to −6.3‰; δD = −177 to −151‰) indicate there was a major contribution from a meteoric water component to metallogenesis. All of the Pb isotope data from the metal sulfides and country rocks in the Sinongduo deposit in this study are similar and imply a close genetic relationship. The δ34S values of galena and sphalerite exhibit narrow distributions, ranging from +4.1‰ to +5.6‰ and from +7.6‰ to +8.4‰ respectively, with average values of +5.0‰ and +8.1‰, respectively, suggesting a uniform source. The Ar-Ar ages determined from sericite in the quartz-sericite-illite-sulfide veins range from 60.9 ± 0.7 to 63.1 ± 0.7 Ma, showing that the timing of epithermal Ag-Pb-Zn mineralization in the study area is consistent with the eruption of the Dianzhong Formation volcanic rocks (DVR) (U-Pb dating, 65–62 Ma), which indicates a genetic relationship. The characteristics of FIs, the H-O-S-Pb isotope data and the mineralization ages suggest that the ore-forming fluids were primarily sourced from circulating meteoric water, while S and Pb were derived from the DVR. Our results, combined with previous data on the regional geology, ore geology, FIs, and tectonic setting, indicate that the Sinongduo Ag-Pb-Zn deposit was produced in an epithermal system that formed on the southern side of the Longge'er-Gongbujiangda fault-block uplift belt, following the northward subduction of the Neo-Tethyan oceanic plate beneath the Asian continent. [ABSTRACT FROM AUTHOR]

Graphical abstract Highlights • First reported of 84–95 Ma high Mg# adakites in the west central Lhasa subterrane. • New geodynamic setting for the 80–95 Ma porphyry-skarn Cu-Mo-Au deposits in the BNMT. • Modified juvenile crust components played key roles in the Cu-Mo-Au mineralization. Abstract The Ga'erqiong-Galale ore district in the Bangong-Nujiang metallogenic belt hosts two large skarn Cu-Au deposits, associated with voluminous Late Cretaceous volcanism and plutonism. In this study, we present new zircon U-Pb age and Hf isotopic data, whole-rock geochemical and Sr-Nd-Pb isotopic data to constrain the geodynamic mechanisms of Late Cretaceous magmatism and metallogenesis within the Ga'erqiong-Galale ore district. The intrusive rocks in the district include diorite, quartz diorite, granodiorite, granite, and dioritic porphyrite. Zircon U-Pb analyses suggest those rocks mainly emplaced at early Late Cretaceous (84–95 Ma), which coincide with the ore-forming age of Ga'erqiong and Galale deposits (87 and 88 Ma, respectively). Geochemically, the granodiorite and dioritic porphyrite are metaluminous with depletion of Nb, Ta, and Ti and characterized by high MgO (2.68–4.16 wt%), Mg# (55–87), Sr (414–616 ppm), Sr/Y (30–56), Cr (22.5–105.0 ppm), and Ni (26.6–59.7 ppm), low Y (10.6–14.0 ppm), and heavy rare earth elements (HREE), showing geochemical signatures of high Mg# adakitic rocks. Four dioritic porphyrite and three granodiorite samples exhibit homologous Sr-Nd-Pb isotope compositions and have positive whole rock ε Nd (t) values of +1.1 to +3.0, (87Sr/86Sr) i values of 0.7045–0.7048, (206Pb/204Pb) t ratios of 18.42–18.73, (207Pb/204Pb) t ratios of 15.58–15.63, and (208Pb/204Pb) t ratios of 38.54–38.88. Besides, 116 analyses from the Ga'erqiong-Galale adakitic rocks give positive zircon ε Hf (t) values (+4.3 to +12.1). The geochemical and isotopic data indicate that the early Late Cretaceous high Mg# adakitic rocks in the Ga'erqiong-Galale ore district originated from the delaminated juvenile lower mafic crust that has been modified by the previously subduction. Partial melting of previously subduction modified, delaminated juvenile lower crust not only formed the hydrous adakitic melts in highly oxidation state, but also provided the ore metals (e.g., Cu, Au, Mo) for the subsequent mineralization. Such melts reacted with surrounding mantle peridotite to elevate the contents of metallic elements again. Then the melts experienced varying degrees of fractional crystallization process in the shallow magma chamber to form the dioritic and granodioritic magmas. Those magmas emplaced into the limestone of Duo'ai and Jiega Formation to form the Ga'erqiong and Galale skarn Cu-Au deposits, respectively. Field observation, together with geochronological and geochemical data, indicate that the early Late Cretaceous mineralization events in the northern and central Lhasa subterranes took place in a transition tectonic setting from collisional orogeny to extension and the input of subduction modified juvenile crust play an important role in the Late Cretaceous ore-forming events. [ABSTRACT FROM AUTHOR]

The Jurassic magmatism distributed in the southern Lhasa subterrane (SLT) has been recognized as a record of the early-stage evolution of the Neo-Tethys ocean; however, the magma compositions and detailed crystallization histories remain an enigma. Zircon, apatite, and titanite in igneous rocks can serve as effective petrogenetic indicators. In this paper, we present the whole-rock geochemical, zircon U Pb data, zircon Hf isotopic analyses, and major and trace elemental compositions of zircon, apatite, and titanite from Baiga granite porphyry (EGP), Shanba granodiorite (EGD), Pengcuolin granodiorite porphyry (MGP), and Dazhuqu monzonite (LM) rocks in the SLT to constrain their source and petrogenesis. The results from this study show that a combination of zircon Ti, Th/U, Hf, and rare earth element (REE) contents, apatite halogen, REE and Sr contents, and titanite REEs can be used to track the detailed magmatic crystallization histories. Higher Sr contents are found in apatite (Sr Ap ) from EGP (ca. 192 Ma) and EGD (ca. 176 Ma) than those in their host rocks (Sr WR ), indicating that their magma genesis may have involved some mafic magma. The magma genesis of LM (ca. 159 Ma) may have involved more reduced mafic (or least evolved) magma, as evidenced by the higher Th/U but lower Yb/Gd ratios, higher zircon saturation and Ti-in-zircon temperatures in zircon, highest Sr Ap /Sr WR ratios, and large positive Eu anomalies in titanite from LM. The lower Cl contents and higher (La/Sm) N values in apatite from MGP (ca. 172 Ma) are inherited from the low-Cl melts. The MGP rocks have higher zircon Ce 4+ /Ce 3+ and Eu N /Eu N * ratios, a greater apatite SO 3 content, and a higher titanite total REE content, which indicates that MGP has a higher oxidation state than do EGP, EGD, and LM. The MGP also exhibits a higher H 2 O content (>11 wt%) dissolved in the melt, greater Ba/La and Nb/Ta ratios in whole rock, and higher Nb/Ta ratios in zircon. However, MGP demonstrates lower zircon saturation and Ti-in-zircon temperatures, which suggest that MGP was generated by fluid-fluxed melting below 750 °C. The low Ti-in-zircon temperatures but high La/Yb and Sr/Y ratios of MGP indicate that a local thickened crust likely existed in the Middle Jurassic period in the SLT due to mafic magma underplating during this time. [ABSTRACT FROM AUTHOR]

The Lietinggang deposit is a representative skarn iron polymetallic deposit in the Nyainqêntanglha skarn polymetallic zone (NSP) in Lhasa Terrane, Tibet. The mineralization is hosted in skarn of the Early and Middle Triassic Chaqupu Formation. Plutons in the deposit include gabbro, diorites (divided into the D1 and D2 diorites), granodiorite, syenogranite and porphyritic granite, and the D2 diorite and syenogranite are the mineralization associated plutons. In this study, we present LA-ICP-MS zircon U-Pb dating, zircon Hf isotopic and whole rock geochemical data of the diorites and porphyritic granite and S-Pb isotopic compositions of the ore sulfides in the Lietinggang deposit. Zircon U-Pb dating results for these intrusions yield Paleocene ages of 62.2–59.0 Ma. All the intermediate and felsic intrusions are I-type, and characterized by arc magma geochemical features, enriched in LREE and LILE, well developed negative Eu anomalies and depletion in HFSE, with most having positive εHf (t) values. These geochemical characteristics are similar with the coeval intrusions of the Gangdese batholith and Linzizong Group volcanic rocks, indicating they share a similar magma source. This magma source is proposed to be partial melting of the young metasomatized asthenospheric mantle wedge-derived basaltic rocks. During the magma evolution the fractionated crystallization has also play an important role. δ 34 S values for sulfides have features of magma source. The 206 Pb/ 204 Pb (18.043–18.711), 207 Pb/ 204 Pb (15.520–15.776), and 208 Pb/ 204 Pb (38.288–39.215) values of sulfides show that ore-forming metals were derived from mixing sources of mantle with upper crust materials. Geochemical characteristics of the intermediate and felsic intrusions, combined with the dating results, indicate that the Lietinggang magmatism and mineralization were formed within the India-Asia continental-collision tectonic setting. [ABSTRACT FROM AUTHOR]

The Jurassic magmatic and volcanic rocks are widespread along the west central Lhasa subterrane. However, the petrogenesis of these rocks is poorly understood because of lacking high-quality geochronology and geochemical data. Here, we present new zircon U-Pb age and Hf isotopic data, whole-rock geochemical and Sr-Nd-Pb isotopic data for the Songduole and Qiangnong plutons in Geji area. LA-ICP-MS dating of zircon yield crystallization ages of 172.1 ± 1.9 and 155.9 ± 1.2 Ma for the Songduole and Qiangnong plutons, respectively. Geochemically, Songduole and Qiangnong granodiorite are characterized by high MgO (2.63-3.49 wt%), high Mg# (49-50), and low TiO2 (0.48-0.57 wt%). Besides, all rocks show metaluminous, calc-alkaline signatures, with strong depletion of Nb, Ta, and Ti, enrichment of large-ion lithophile (e.g. Rb, Th, K), and a negative correlation between SiO2 and P2O5. All these features are indicative of arc-related I-type magmatism. Five samples from the Songduole granodiorite have whole rock (87Sr/86Sr)i of 0.71207-0.71257, εNd(t) values of −15.1 to −13.9, zircon εHf(t) values of −17.4 to −10.5, (206Pb/204Pb)t ratios of 18.402-18.854, (207Pb/204Pb)t ratios of 15.660-15.736, and (208Pb/204Pb)t ratios of 38.436-39.208. Samples from the Qiangnong granodiorite have (87Sr/86Sr)i of 0.71230-0.71252, εNd(t) values of −15.1 to −14.2, zircon εHf(t) values of −12.6 to −6.4, (206Pb/204Pb)t ratios of 18.688-18.766, (207Pb/204Pb)t ratios of 15.696-15.717, and (208Pb/204Pb)t ratios of 38.546-39.083. These geochemical signatures indicate that the two plutons most likely originated from partial melting of the ancient Lhasa lower crust with obvious inputs of mantle-derived melts. Combined with regional geology, our results indicate that the Jurassic magmatism in the west central Lhasa subterrane most likely resulted from the southward subduction of the Bangong Ocean lithosphere beneath the central Lhasa terrane. [ABSTRACT FROM AUTHOR]

The Xiongcun district, a unique area where oxidized porphyry copper-gold deposits (OPCD) and reduced porphyry copper-gold deposits (RPCD) coexist, is located in the central part of the Gangdese porphyry copper belt (GPCB) in Tibet, China, and hosts the only known mineralization related to the Neo-Tethyan oceanic subduction. Apatite and zircon major and trace elements, in situ oxygen isotopes in zircon from fertile quartz diorite porphyry (QDP) of the No. I deposit, fertile hornblende quartz diorite porphyry (HQDP) of the No. II deposit, and barren hornblende quartz diorite porphyry with coarse quartz eyes (QQDP) in the Xiongcun district were determined by EPMA, LA-ICP-MS, and SHRIMP II ion microprobe to investigate the petrogenesis, magma oxidation state, and mineralization differences between the No. I and No. II deposits, as well as the potential of apatite as a metallogenic indicator. The results from this study show that a combination of REE, Ti, oxygen isotopes, and the Th/U ratios in zircon and REE as well as Sr in apatite can be used to track the magma compositions and crystallization histories in porphyry systems. Multiple indicators, including the apatite SO 3 content, apatite Mn oxybarometer, and zircon Ce 4+ /Ce 3+ ratio, indicate that (1) the parental magmas of fertile QDP and HQDP containing Cu and Au mineralization were more reduced than that of barren QQDP; (2) despite barren QQDP having higher oxygen fugacity than QDP and HQDP, the lower Cu and water contents in the magma result in a lower potential for ore formation; and (3) the similar oxidation states of QDP and HQDP show that the mineralization differences between RPCD (No. I deposit) and OPCD (No. II deposit) were not caused by the oxidation states of the magmas but were likely caused by the different processes of hydrothermal fluid evolution. Apatite grains from fertile porphyries (QDP and HQDP) have much higher Cl/F ratios than those from barren porphyry (QQDP), indicating that the Cl/F ratio of apatite can be used as a proxy for porphyry Cu-Au mineralization related to the Jurassic porphyry intrusions in the Gangdese porphyry copper belt. [ABSTRACT FROM AUTHOR]

The Longmala deposit is a representative of the skarn Pb-Zn-Cu deposits found in the Nyainqêntanglha area of Tibet, China. The mineralization is hosted by skarn and marble of the Permian Wululong Formation intruded by an early Eocene biotite monzogranite, which is associated with the Pb-Zn-Cu mineralization. The genesis of the deposit is related to a four-stage progression involving: Stage I involves the development of prograde skarn; Stage II is a pre-ore retrograde skarn; Stage III is the emplacement of quartz-sulfides ore; and Stage IV is the emplacement of post-ore carbonate. The biotite monzogranite is a high-K calc-alkaline highly fractionated I-type granite characterized by its elevated SiO 2 (68.38–72.62 wt%), Fe T (4.09–6.19 wt%), and K 2 O + Na 2 O (7.82–8.33 wt%) contents. Its aluminum saturation index of 0.97–0.99 and a high differentiation index of 79–86 are indicative of a last-stage fractionation of the magma. The monzogranite is relatively enriched in light rare-earth elements, Th, U, and Rb, depleted in Sr, Ba, K, Nb, P, and Ti, and has a negative Eu anomaly. The εHf (t) values (−6.2 to +1.5), two-stage Hf model ages (average T DM2 = 1224 Ma) for zircons, and whole rock Pb isotopic compositions ( 206 Pb/ 204 Pb = 18.806–18.938, 207 Pb/ 204 Pb = 15.676–15.697, and 208 Pb/ 204 Pb = 39.234–39.376) indicate that the source of the magma is the crust of Lhasa Terrane. The study of fluid inclusions from each of the four stages mentioned above show that garnet and diopside from the prograde skarn (Stage I) are characterized by high temperatures and high oxygen fugacity indicative of magmatic fluids. The succeeding mineralization (Stage III) is characterized by moderate to high temperature and a reducing fluid, and final carbonate veining (Stage IV) with a decreased fluid temperature and salinity. The δ 18 O w values range from 1.3 to 10.8‰, and the δD w values are −123.5 to −93.4‰, indicating that the ore-forming fluids were derived from mixture magmatic and meteoric fluids, and the δ 34 S values of sulfides have a relatively narrow range of 0.3–3.6‰, suggestive of a magmatic source. The 206 Pb/ 204 Pb (18.571–18.722), 207 Pb/ 204 Pb (15.707–15.796), and 208 Pb/ 204 Pb (39.116–39.448) values of sulfides show that ore-forming metals were derived from the crust in the Lhasa Terrane. Major and trace elements characteristics of the ore-associated biotite monzogranite, combined with the dating results, suggest that the Longmala deposit were formed within the India-Asia continental-collision tectonic setting. [ABSTRACT FROM AUTHOR]

Stable Zn isotopes may be applied to trace the source of ore-forming metals in various types of Pb Zn deposits. To test this application, Zn and Pb isotope systematics for sulfides and associated basement rocks as well as Fe Mn carbonates (gangue) from the Zhaxikang Pb Zn deposit in South Tibet have been analyzed. The basement in this region includes metamorphosed mafic to felsic rocks (dolerite, quartz diorite, rhyolite porphyry, pyroclastics and porphyritic monzogranite). These rocks have similar δ 66 Zn values of 0.33 to 0.37‰, with an average value of 0.36 ± 0.03‰ (2σ), except for the more evolved porphyritic monzogranite that has a heavier value of 0.49‰. Fe Mn carbonates are present as hydrothermal veins and were probably precipitated from magmatic fluids. They have an average δ 66 Zn value of 0.27 ± 0.05‰, which is slightly lighter than the basement rocks, possibly representing δ 66 Zn isotopic compositions of the hydrothermal fluids. Sphalerite and galena have similar Zn isotopic compositions with δ 66 Zn ranging from 0.03 to 0.26‰ and 0.21 to 0.28‰, respectively. Considering the Zn isotope fractionation factor between sphalerite and fluids of − 0.2‰ at ~ 300 °C as reported in literature, hydrothermal fluids from which these sulfides precipitated will have δ 66 Zn values of ca. 0.39 ± 0.10‰, which are consistent with the values of basement rocks and the Fe Mn carbonates. This similarity supports a magmatic-hydrothermal origin of the Zhaxikang Pb Zn deposit. Both Pb and S isotopes in these sphalerite and galena show large variations and are consistent with being derived from a mixture of basement and sedimentary rocks in various proportions. Zn isotopic compositions of the sulfides significantly extend the range of regional basement rocks, suggesting that sedimentary rocks (e.g., shales) are also a significant source of Zn. However, the Zn isotopic compositions of sphalerite and galena differ from those of marine carbonates and those of typical SEDEX-type deposits (e.g. Kelley et al., 2009), confirming a magmatic-hydrothermal model. Combined with regional geological observations and the age constraints of ~ 20 Ma (Zheng et al., 2012, 2014), the results of our investigation indicate that the Zhaxikang Pb Zn deposit is most likely a magmatic-hydrothermal deposit. [ABSTRACT FROM AUTHOR]

We report the copper isotopic composition of Cu sulfides in the Tiegelongnan high-sulfidation (HS) copper deposit, Tibet, and investigate the possible application of Cu isotopes to mineral exploration. The copper isotopic values of samples from four drill holes display consistent progressive increase with depth to 400 m below surface, with an overall variation of δCu of up to 7.60‰ (−4.76 to 2.84‰). Such a large range is very different from that observed in Cu porphyry deposits which commonly exhibit a small δCu range (<1‰), with decreasing values with depth. The large δCu variation is likely of supergene origin and reflects strong leaching under oxidized conditions. The systematic increase of δCu with depth can be explained by the release of isotopically heavy Cu at the top and its transport downward, which is supported by the coupling of positive δCu values with high Cu grade and the occurrence of both negative and positive δCu values in two drill holes. Mass-balance consideration on the basis of Cu isotopes can indicate mineralized zones which have been eroded or have not been found yet. Such mineralized targets, if buried at depth, could be located using Cu isotopes. [ABSTRACT FROM AUTHOR]

The Jiama deposit, located in the eastern part of the well-known Gangdese Metallogenic Belt on the Tibetan Plateau, is the largest porphyry Cu–polymetallic system in the region, with the largest exploration budget, and is economically viable in the Gangdese Belt to undergo large-scale development. The deposit is well preserved and has experienced little erosion. The proven resources of the deposit are 7.4 Mt Cu, 0.6 Mt Mo, 1.8 Mt Pb + Zn, 6.65 Moz Au, and 360.32 Moz Ag. The results presented in this paper are based on geological and tectonic mapping, geological logging, and other exploration work performed by members of the Jiama Exploration Project Team over a period of 6 years. We propose that the Jiama porphyry Cu–polymetallic system is composed of skarn Cu–polymetallic, hornfels Cu–Mo, porphyry Mo ± Cu, and distal Au mineralization. The development of skarn Cu–polymetallic orebodies at the Jiama deposit was controlled mainly by the contact zone between porphyries and marbles, an interlayer detachment zone, and the front zone of a gliding nappe structure. The hornfels Cu–Mo and porphyry Mo ± Cu orebodies were controlled mainly by a fracture system related to intrusions, and the distal Au mineralization resulted from late-stage hydrothermal alteration. On the basis of field geological logging, optical microscopy, and chemical analysis, we verify that the alteration zones in the Jiama deposit include potassic, phyllic, propylitic, and argillic alteration, with a local lithocap, as well as endoskarn and exoskarn zones. The endoskarn occurs mainly as epidote alteration in quartz diorite porphyry and granite porphyry, and is cut by massive andradite veins. The exoskarn includes garnet–pyroxene and wollastonite skarn, in which the mineralogy and mineral chemical compositions display an outward zonation with respect to the source porphyry. From the proximal skarn to the intermediate skarn to the distal skarn, the garnet/pyroxene ratio varies from > 20:1 to ~ 10:1 to ~ 5:1, the garnet color varies from red-brown to brown-green to green-yellow, and the average composition of garnet varies from Ad 80.1 Gr 18.9 (Sp + Py) 1.0 to Ad 76.3 Gr 23 (Sp + Py) 0.7 to Ad 59.5 Gr 39.5 (Sp + Py) 1.0 , respectively. The pyroxene is not as variable in composition as the garnet, and is primarily light green to white diopside with a maximum hedenbergite content of ~ 20% and an average composition of Di 88.6 Hd 8.9 Jo 2.5 . From the proximal skarn to the intermediate skarn to the distal skarn, the mineralization changes from Cu–Mo to Cu ± Mo to Pb–Zn ± Cu ± Au ores, respectively. The wollastonite skarn displays no zonation and hosts mainly bornite mineralization. The Cu and Mo mineralization is closely related to the potassic and phyllic zones in the porphyry–hornfels. Zircons from four mineralized porphyries yield U–Pb ages of 15.96 ± 0.5 Ma, 15.72 ± 0.14 Ma, 15.59 ± 0.09 Ma, and 15.48 ± 0.08 Ma. The Re–Os ages of molybdenite from the skarn, hornfels, and porphyry are 15.37 ± 0.15 Ma, 14.67 ± 0.37 Ma, and 14.66 ± 0.27 Ma, respectively. The present results are consistent with the findings of previous research on fluid inclusions, isotopes, and other such aspects. On the basis of the combined evidence, we propose a porphyry Cu–polymetallic system model for the Jiama deposit and suggest a regional exploration strategy that can be applied to prospecting for porphyry-skarn mineralization in the Lhasa area. [ABSTRACT FROM AUTHOR]

The Longmala and Mengya’a deposits are two representative skarn Pb–Zn deposits of the Nyainqêntanglha Pb–Zn–(Cu–Mo–Ag) polymetallic belt in the Gangdese region, Tibet, China. Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon U–Pb dating of the mineralization-related biotite monzogranite from the Longmala deposit yielded a weighted mean age of 55.7 Ma, which can be interpreted as the emplacement age of the pluton. Re–Os dating of three molybdenite samples from the Longmala deposit yielded model ages of 51.8–54.3 Ma, with a weighted mean age of 53.3 Ma, which is interpreted as the mineralization age of the deposit and overlaps the age of the causative intrusion. The Re–Os dating of four molybdenite samples from the Mengya’a deposit yielded model ages of 60.4–65.8 Ma, with a weighted mean age of 63.6 Ma, which represents the mineralization age of this deposit. Our new precise age data for these two deposits are consistent with the existing ages of ca. 65–51 Ma for other skarn polymetallic deposits in the Nyainqêntanglha metallogenic belt. In addition, these new age data, combined with existing information on the geological evolution history of the Lhasa terrane, indicate that the belt of skarn deposits is closely related to initial collision between India and the Asian continents. [ABSTRACT FROM PUBLISHER]

The Xiongcun district, located in the western segment of the Gangdese porphyry copper belt (GPCB), hosts the only known Jurassic mineralization in the GPCB, Tibet, PRC. The No. I deposit in the Xiongcun district is related to the Middle Jurassic quartz diorite porphyry (167–161 Ma) and the mineralization was formed at ca. 161.5 ± 2.7 Ma. Ore-bearing Middle Jurassic quartz diorite porphyry emplaced into the Early Jurassic volcano-sedimentary rock sequences of the Xiongcun Formation. Veinlets and disseminated mineralization developed within the Middle Jurassic quartz diorite porphyry and the surrounding metamorphosed tuff, hosting a measured and indicated resource of 1.04 Mt copper, 143.31 t gold and 900.43 t silver with an average grade of 0.48% copper, 0.66 g/t gold, and 4.19 g/t silver. The mineralization can be assigned to four stages, including three main stages of hypogene mineralization and one epigenetic stage. The main alteration associated with mineralization is potassic. Seven mineralization-related hydrothermal veins have been recognized, including quartz–sulfide, biotite–sulfide, magnetite–sulfide, quartz–molybdenite–sulfide, chalcopyrite–pyrite–pyrrhotite, pyrite and polymetallic veins. The S and Pb isotopic compositions of the ore sulfides and the Re contents of the molybdenite suggest a mantle source for the ore-forming materials with minor contamination from the subducted sediments. Hydrogen and oxygen isotope compositions of quartz in the ores suggest that both magmatic and meteoric waters were involved in the ore-forming process. The ore-bearing porphyry (167–161 Ma) and ore-forming (161.5 ± 2.7 Ma) ages of the No. I deposit correspond to the time of northward subduction of Neo-Tethys oceanic slab. The geochemical data of the ore-bearing porphyry indicate that the No. I deposit formed in an intra-oceanic island arc setting and the ore-bearing porphyry originated from the partial melting of mantle with limited contribution of subducted sediments. The genesis of the ore-bearing porphyry and No. I deposit is interpreted as being related to northward intra-oceanic subduction of Neo-Tethys oceanic slab in the Middle Jurassic time (167–161 Ma). [ABSTRACT FROM AUTHOR]

We evaluate the controlling factors of hydrothermal wolframite and scheelite precipitation in the quartz vein-type Jiaoxi tungsten deposit situated in the western part of the Lhasa terrane (Tibet, China) using texture, major and trace element mineral geochemistry, and sulfur stable isotope geochemistry. Pyrite and chalcopyrite that are intergrown with Fe-enriched wolframite and siderite, have distinct in situ S isotope compositions (δ34SV-CDT) of −31.38 to +1.77‰, and +2.07 to +2.30‰, respectively. Major and trace element contents and in situ S isotope compositions of pyrite and chalcopyrite indicate that the hydrothermal evolution involved fluid-fluid mixing and greisenization. We report evidence for an early magmatic fluid, which is characterized by the enrichment of W, Mn, Zr, Ti, Sc, and Sn and depletion of Fe. This magmatic fluid was diluted by meteoric water and interacted with biotite monzogranite porphyry to leach Fe, Mg, and Zn into the system to form wolframites with variable Fe/(Fe+Mn) ratios ranging between 0.06–0.84. The late Fe-enriched magmatic fluid released from the muscovite granite mixed with meteoric water that leached minor Fe and S from shale to form late shale-hosted wolframite with a Fe/(Fe+Mn) mass ratio of >0.75 and coeval siderite and sulfides. This study highlights that multiple Fe sources were present in the system, including muscovite granite-released Fe through fluid exsolution, biotite monzogranite porphyry-released Fe during greisenization, and minor Fe released from the shale as a result of meteoric water leaching. [ABSTRACT FROM AUTHOR]

The Bangpu porphyry Mo–Cu deposit is a representative Mo-dominated deposit besides the Sharang porphyry Mo deposit in the Gangdese metallogenic belt. The Mo–Cu mineralization has a close relationship with the monzogranite porphyry and diorite porphyrite. We identify three stages during the ore formation: a pre-ore stage, a main-ore stage with Mo–Cu deposited dominantly, and a post-ore stage. In this study, He–Ar, H–O, S and Pb isotopic compositions of the Bangpu deposit were determined. Based on these determinations, integrated isotope geochemistry studies were performed to constrain the possible sources of the ore-forming fluids and metals. The 3 He/ 4 He and 40 Ar/ 36 Ar ratios of fluid inclusions exhibit a range of 0.12209–0.36370 Ra and 275.6–346.1, respectively. The 4 He and 40 Ar concentrations vary from 1.51 to 3.57 (10 −7 cm 3 STP g −1 ) and 0.49 to 9.31 (10 −7 cm 3 STP g −1 ), respectively. He–Ar isotopic compositions suggest dominantly crustal-derived fluid with minor amount of meteoric water in the main ore stage. The δ 18 O fluid and δD fluid values vary from −1.3‰ to 3.9‰ and −140.5‰ to −73.7‰, respectively, indicating that magma fluids mixed with meteoric water. The average δ 34 S value of the sulfides (0.3‰) in the main-ore stage is close to the ore-forming porphyries, indicating a magmatic source. The lead isotopic components of ore sulfides exhibit restricted ranges with 206 Pb/ 204 Pb, 207 Pb/ 204 Pb, and 208 Pb/ 204 Pb ratios of 18.450–18.728, 15.602–5.672, and 38.715–39.211, respectively and μ values in the range of and 9.46–9.58, indicating ore-forming metals of primarily an upper crust source with a small amount of mantle materials. Compared to the Bangpu deposit, the ore metals derived from mantle are even greater in the Jiama and Qulong deposits, which leads to Cu being the dominant mineralization in the Jiama and Qulong deposit. [ABSTRACT FROM AUTHOR]

The coexistence of aqueous fluid inclusions and silicate melt inclusions in quartz phenocrysts from porphyrites at the Bangpu porphyry Mo–Cu deposit, Tibet, China were examined to characterize the immiscibility processes during the magmatic to hydrothermal transition. The physical and chemical environment during crystallization of the magmas has been reconstructed on the basis of microthermometric experiments and trace element microanalysis. Compositions of melt and brine fluid phases are determined using Synchrotron radiation X-ray fluorescence analysis, SEM–EDS and Laser Raman spectroscopy analyses. Brine fluids were directly exsolved by a crystallizing melt, and the simultaneous entrapment of volatile-rich (brine fluid) and volatile-poor immiscible phases (silicate melt) occurred at 670–700 °C and 1.6–1.95 kbar when the magma had H 2 O contents between 5 and 6 wt% and crystal contents of 60–80%. A later low-density fluid with a higher Mo concentration exsolved after about 80–90% crystallization had occurred. This fluid contained significant concentrations of Cl, Na, K, Ca, Fe, Cu, Zn, Rb, and small amounts of Mn, Br and Pb. Immiscibility of magmatic fluids can lead to different metal partitioning behaviors between residual melt and volatile phases, which generate variable metal ratios. Copper was partitioned preferentially into the brine phase, in contrast to the behavior observed in other porphyry Cu deposits. Ore deposition by a dense brine could explain the partially deep Cu mineralization. Condensation of brine from a later low-density parental fluid could be an efficient mechanism to concentrate shallow Cu mineralization and broadly distributed Mo mineralization. The source of the Mo mineralizing fluids probably was a particularly large magma chamber that crystallized and fractionated at depth greater than upper continental crust level. [ABSTRACT FROM AUTHOR]

The Jiama copper deposit is one of the largest deposits recently found in Tibet and is composed of three types of mineralization including skarn, hornfels and porphyry. To investigate the relationship between mineralization, structure and alteration, we report new zircon U-Pb age and present field observations on the deformation characteritics associated with the copper mineralization in Jiama. Two main periods of deformation were identified, represented by D1 and D2 in Jiama. The first deformation ( D1) occurred around 50 Ma, whereas the second deformation ( D2) that was closely related to mineralization occurred later. Previous zircon U-Pb and molybnite Re-Os dating results indicate that the mineralizatoin occurred at ∼15 Ma and thus the D1 regional deformation significantly occurred before the mineralization time, although the D1 deformation probably provided important space for the development of significant copper deposition. Our new mapping and observations on the D2 deformation demonstrate that the mineralization was closely coeval with or slightly later than the time of D2 deformation. The new U-Pb zircon age further indicates that the aplite formed in ∼17.0 Ma and thus the D2 deformation happened later than this time because the D2 deformation cut across the aplite, which is proposed to be the key control for copper mineralization. Altered laminated hornfels including three types of alteration ( A-, K- and S-type) were found spatially associated with the D2 deformation. The type- A is mainly silicification, with fine sericite or chlorite, as well as abundant disseminated sulphides on fracture surfaces; the type- S is mainly fine-grained silicification with patches of chlorite, epidote and common sulphides; the type- K (potassic alteration) appears to be fine-grained biotite. Such types of alteration indicate the presence of skarns at depth where ore shoots are located. Taken together, the multiple structural-magmatic-mineralization events contributed to the formation of the supergiant Jiama porphyry copper deposit in Tibet. The results have general implication for regional exploration. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Duolong ore district experienced two periods of exhumation and two periods of burial. • The periods of burial are attributed to northeast-southwest striking fault and thrust nappe structure related to the Lhasa-Qiangtang collision. • The India-Asia collision is the main reason for the exhumation and uplift of the Duolong ore district since Paleocene. The Early Cretaceous Duolong porphyry-epithermal copper ore district is one of the largest copper ore districts in the central Tibetan Plateau. In order to investigate the preservation mechanism of Early Cretaceous porphyry-epithermal mineralization, new apatite and zircon fission track dating and (U-Th)/He dating of pre-ore sandstone, ore-related and barren intrusive rocks, and post-ore igneous rock, thermal modeling together with previous thermochronological data of the Duolong ore district were combined to study the burial and exhumation processes. Apatite fission track ages range from 68 ± 4 to 40 ± 4 Ma, with mean track lengths varying from 12.1 ± 2.0 to 12.8 ± 2.4 μm. Zircon fission track ages range from 106 ± 4 to 86 ± 4 Ma. In addition, apatite (U-Th)/He yields average age ranging from 62.7 ± 4.2 to 22.6 ± 1.2 Ma, and zircon (U-Th)/He yields average age of 112.3 ± 5.1 Ma. The thermal modeling shows that the Duolong ore district experienced two periods of exhumation and two stages of burial. The first period of exhumation with rate of 0.14 km/m.y. took place immediately after the ore formation which caused the erosion of orebody. Two periods of burial are thought to be related to northeast-southwest striking fault and thrust nappe structure induced by Lhasa-Qiangtang collision between 110 and 65 Ma when the overlying rocks of orebodies were thickened to 4 km. The last period of exhumation with rate of 0.062 km/m.y. (since 65 Ma) is attributed to lithospheric delamination related to India-Asia collision. The preservation of the Duolong ore district mainly benefited from the burial related to the Lhasa-Qiangtang collision. The exhumation and uplift of Duolong ore district was mainly attributed to the India-Asia collision since Paleocene. [ABSTRACT FROM AUTHOR]

The Qushenla Formation volcanic rocks are widely exposed in the northern margin of the Bangong-Nujiang suture zone (BNSZ). Research on these rocks is of great significance for understanding the tectonic evolution of the Bangong-Nujiang Tethys Ocean (BNTO). In this study, a systematic geological survey was conducted on the Qushenla Formation volcanic rocks that are widely exposed in the Nawucuo area, in the northern margin of the western segment along the BNSZ. The whole-rock geochemistry, zircon U-Pb dating, and in situ zircon Lu-Hf isotopes were carried out in this study, aiming to constrain the formation age, rock genesis, magma source and tectonic setting of the volcanic rocks. The zircon U-Pb dating shows that the Qushenla Formation volcanic rocks in the western BNSZ erupted during the period of 120–108 Ma, i.e., Early Cretaceous. The Qushenla Formation volcanic rocks are a suite of intermediate-basic volcanic and pyroclastic rocks belonging to the medium-K calc-alkaline series. They are relatively enriched in light rare earth elements (LREEs) and incompatible elements such as Rb, K, La, Th, Sm, and Hf, whereas depleted in heavy REEs (HREEs) and high field strength elements (HFSEs) such as Nb, P, Zr, and Ti. The in situ zircon εHf(t) values of the volcanic rocks range from 8.95 to 12.57, with an average of 10.40. The Mg#, Th/La and Th/Ce values are between those of the mantle-derived magma and the continental crust. The formation of the Qushenla Formation volcanic rocks can be explained through the following process: (1) As the nospheric materials that upwelled during the rollback of the subducting Tethys Ocean slab induced the large-scale partial melting of the mantle wedge and the formation of the initial basaltic magma. (2) These mantle-derived magmas ascended and induced the partial melting of the lower crust to generate peraluminous melts. (3) The mixing of the peraluminous melts and mantle-derived melts generated the initial magma with homogeneous Sr-Nd isotope compositions. (4) Last, the eruption of the magma produced the widespread Qushenla Formation volcanic rocks at the surface. When combining this information with the regional geological background, it is believed that the Qushenla Formation volcanic rocks, the Meiriqicuo Formation volcanic rocks and the Late Jurassic–Early Cretaceous intrusive rocks together constitute the tectonic magmatic arc of the active continental margin on the southern margin of Qiangtang, which was formed in the tectonic setting of the northward subduction of the Bangong-Nujiang oceanic crust beneath the Qiangtang Block. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Jiaoxi tungsten deposit comprises three stages, i.e., the oxide, sulfide, and fluorite stage. • Mineralization involves a low-salinity aqueous fluid. • Mineralization occurred as a result of fluid-fluid mixing induced cooling and dilution. The Jiaoxi deposit, located in the western part of the Lhasa terrane, is the first discovered Miocene (ca. 13 Ma) quartz vein-type tungsten deposit in this belt. Ore bodies mainly occur as wolframite-bearing veins hosted in the shales and granite. Three stages were identified for the formation of the Jiaoxi deposit, including the oxide stage (dominated by wolframite and quartz), the sulfide stage (quartz-sulfides veins) and the fluorite stage (late veins comprising fluorite, calcite, and quartz). Here, we investigate the genesis of this deposit based on fluid inclusion and H-O-S-Pb isotope studies. Fluid inclusion microthermometry and oxygen isotope data reveal that the wolframite precipitated from a moderate temperature (340–380 °C), low salinity (2.1–7.5 wt% NaCl equivalent) hydrothermal fluid at a depth of ∼ 6 km. The sulfides from the oxide and sulfide stage have uniform δ34S CDT values (+2.5 to + 3.7‰), and consistent Pb isotope compositions with the coeval granites (206Pb/204Pb: 17.866–18.789; 207Pb/204Pb: 15.555–15.743; 208Pb/204Pb: 37.157–39.335). The δ18O VSMOW value of the hydrothermal fluid decreased from the oxide (δ18O VSMOW = +7.2 to +14.2‰) to the fluorite stage (δ18O VSMOW = +2.1 to +5.7‰), indicating that the exsolved magmatic hydrothermal fluid mixed with meteoric water. This is also suggested by the positive correlation between the salinity and homogenization temperature of the aqueous fluid inclusions. LA-ICP-MS analysis of individual fluid inclusion reveals that the W concentrations of ore-forming fluid in the oxide stage (1.2–70.2 ppm) are much higher than those in the sulfide and fluorite stage (1.1–2.2 ppm) and show positive correlations with the homogenization temperatures and the Cl concentrations. We propose that fluid dilution and cooling due to fluid mixing played an important role during the wolframite precipitation in the Jiaoxi deposit. [ABSTRACT FROM AUTHOR]

Highlights: [•] The Xiongcun district present two middle Jurassic mineralizing episodes separated by 10m.y. [•] The porphyry mineralization in the Xiongcun district formed in island arc setting. [•] Four major metallogenic events existed in the Gangdese porphyry copper belt. [ABSTRACT FROM AUTHOR]

We report zircon U Pb age and Hf isotope and whole-rock major and trace element and Sr Nd isotope data for magnesian andesites from the Kongnongla area, central Tibet. These Kongnongla magnesian andesites are directly in contact with high-Nb basalts and are part of the Baila–Lanong ophiolitic mélanges. Zircon U Pb dating shows that the magnesian andesites crystallized at ca. 158 Ma. The samples are characterized by moderate SiO 2 (59.3–61.7 wt%), high MgO (3.74–4.69 wt%), Fe 2 OT 3 (4.95–5.30 wt%), Ba (570–1320 ppm), and Th (6.5–7.0 ppm) contents, and low (87Sr/86Sr) i (0.704491–0.704857), and Sr/Y (17.5–24.0) ratios. The samples also exhibit enrichments of compatible elements, such as Cr (110–150 ppm) and Ni (24.7–36.5 ppm), and display fractionated rare earth element (REE) patterns with light REE enrichment relative to heavy REEs. Negative zircon ε Hf (t) values (−10.8 to −15.7) and whole-rock ε Nd (t) values (−3.85 to −6.12) of the Kongnongla magnesian andesites are similar to those of DaruTso magnesian andesites, Hohxili high magnesian andesites, and sediments of the Mugagangri Group. We propose that the Kongnongla magnesian andesites were formed by the interaction between slab fluids, subducting sediments, and overlying mantle under high-temperature–low-pressure conditions. Based on previously published data and the regional geology, we also suggest that these magnesian andesites were generated in a back-arc setting caused by the southward subduction of the Bangong–Nujiang oceanic lithosphere during the Late Jurassic. • The Dongqiao area is a microcontinent preserved in the Bangong–Nujiang suture. • The Kongnongla magnesian andesites formed in a back-arc setting. • Southward subduction of the Bangong-Nujiang Ocean triggered back-arc spreading. [ABSTRACT FROM AUTHOR]

The Mamupu skarn‐type Cu‐Au polymetallic deposit represents the first discovery of a medium deposit in the southern Yulong porphyry copper belt (YPCB), eastern Tibet. The Cu‐Au mineralization mainly occurs as chalcopyrite in breccia, within the plate‐like carbonate interlayer, being closely related to chloritization (e.g., chlorite, magnetite and epidote) and skarnization (e.g., diopside, tremolite and garnet). The ore‐related quartz syenite porphyry (QSP) and granodiorite porphyry (GP) were emplaced at 40.1 ± 0.2 Ma and 39.9 ± 0.3 Ma, respectively. The QSP of Mamupu is an alkaline‐rich intrusion, relatively enriched in LREE, LILE, depleted in HFSE, with no significant negative Eu and Ce anomalies, slightly high (87Sr/86Sr)i, low ∊Nd(t), uniform (206Pb/204Pb)i and ∊Hf(t) values, which indicates that the porphyry magma may be caused by both the mixing of metasomatized EM II enriched mantle and thickened juvenile lower crust. The QSP in the Mamupu deposit shares a similar genesis of petrology to other ore‐related porphyries within the YPCB. High oxygen fugacity and water content of the magmas are essential for the formation of porphyry and skarn Cu deposits. The QSP has similar high magmatic oxidation states and water content to the Yulong deposit, which indicates that the Mamupu has a high prospecting potential. Differences in the geological characteristics and scale of mineralization between the Mamupu and other YPCB deposits may be due to the different emplacement depths of ore‐related intrusions, as well as differences in the surrounding rocks. [ABSTRACT FROM AUTHOR]

The article discusses a study that focuses on the minerals, geological alteration and fluid basics of the first high sulfidation epithermal-porphyry copper-gold deposits in Tibet, China. Topics discussed include discovery of some new copper-sulfur and copper-iron-sulfur minerals; role of temperature and salinity in fluid inclusions and mixing of meteoricwater and porphyry fluid to form deposits in low temperature and salinity.

The article discusses the petrogeochemistral features of the acid intrusive rocks in Zhaxikang Deposit, Xizang Region. Topics discussed include geochemical analysis of granite porphyry samples that revealed high alumina, high silica and low magnesium oxide; rare earth element geochemistry of granite porphyry samples; and positive Europium (Eu) anomalies in which concentration of Eu increases in the mineral.

The article discusses a study that focuses on the geological characteristics of Rongna copper-gold-silver epithermal ore deposits located in Duolong copper ore concentration area in Northern Tibet, China. Topics discussed include classification of epithermal-porphyry copper mineralization system into high-sulfidation, medium sulfidation and low sulfidation types; composition of copper sulfides including digenite, enargite, bornite; and impact of deposits discovery on mineral prospecting.

The article offers information on the research "Construction of the Three-dimensional Model for Jiama Deposit, Tibet, and its Significance in Geological Study" by Tang Pan and colleagues. Topics discussed include copper-polymetallic porphyry deposit, the rock forming and ore-forming chronology, and the construction of a 3D deposit model by Micromine software. Also mentioned are the geological and mineralized model of the Jiama deposit, the porphyry orebody output, and dikes and apophysis.

Northern Tibet exhibits abundant placer gold deposits, with a longstanding history of mining activities. Despite the widespread placer gold occurrences, the reports on the primary rock gold deposits or occurrences remain scarce. The central Lhasa terrane in northern Tibet hosts well-developed Zenong Group volcanic rocks, indicating great potential for the exploration of porphyry-epithermal copper (gold) deposits. Here, we select the Dangreyongcuo area in this region to investigate its metallogenetic potentiality, through a comprehensive 1:50,000 stream sediment geochemical survey, analyzing 12 elements (Au, As, Sb, Ag, Te, Cu, Pb, Zn, W, Sn, Bi, and Mo), and a detailed geological mapping. We aim to identify gold-related mineralization anomalies and provide clues for further bedrock gold exploration in this region. Based on the stream sediment geochemical data, zones 1–4, have been delineated using single-element indicator Au and element association indicator Au + As + Sb, which was determined through robust principal component analysis (RPCA) and using the exploratory data analysis (EDA) method. Subsequent validation exercises evaluating these four delineated zones reveal that Zone 1, Xinlong-Langmeila area, is the most promising prospect due to its high element concentrations, large size, and marked coincidence of element assemblages (also referred to as high-large-coincidence anomalies; HLCAs) and its characteristics are in line with those of epithermal deposits. Notably, the Xinlong deposit represents the first documented epithermal gold deposit hosted within the Zenong Group volcanic rocks. The identification of this deposit offers valuable insights and strategic directions for the broader understanding of Zenong Group volcanic rocks across the central Lhasa terrane. Additionally, subsequent strategies have been proposed for mineral exploration at both Xinlong camp and regional scales. • Gold anomalies were detected in the western Dangreyongcuo area, Tibet. • Xinlong deposit is a newly discovered high-sulfidation epithermal gold deposit. • Xinlong gold deposit is linked to Zenong Group volcanic rocks. • Promising prospecting potential exists within regional Zenong Group volcanic rocks. [ABSTRACT FROM AUTHOR]

• The Shesuo deposit is related to the intermediate-felsic magmatism (117–112 Ma). • The Shesuo deposit associated with slab break-off during a postcollisional period. • The addition of reducing materials limited the magma fertility. The Bangong-Nujiang metallogenic belt is a newly discovered copper-polymetallic belt in the Tethyan domain. To date, the Shesuo skarn Cu-polymetallic deposit is the only productive Early Cretaceous Cu deposit in the middle segment of this belt. We conducted zircon U-Pb and molybdenite Re-Os dating of this deposit, and the results show that the Shesuo skarn Cu-polymetallic deposit formed at 117–112 Ma. Within the mining area, granodiorites and monzogranites are the main metallogenic granitic bodies. The petrogeochemical features imply that the granodiorites and monzogranites were derived from the partial melting of juvenile lower crust resulting from mantle-derived magmatic underplating, with the additional involvement of ancient crust in the magma chamber, whereas the monzogranites experienced significant fractional crystallization. The δ34S values of sulfide ores suggest that they were mainly sourced from the magma and slightly contaminated by surrounding strata. The Pb isotope compositions of sulfides and Re contents of molybdenite indicate that the metals were derived from the juvenile lower crust, with a small fraction from ancient crustal materials. Our study suggests that the generation of the Shesuo deposit was most likely triggered by slab breakoff during the southward subduction of the Bangong-Nujiang Ocean lithosphere. The Shesuo and Xiongmei deposits have low zircon Ce4+/Ce3+ and Eu N /Eu* ratios and low whole-rock average V/Sc, Sr/Y and (Eu N /Eu*)/Yb N ratios. We propose that these values are due to the input of reduced components, leading to the generation of metallogenic magmas with relatively low magmatic oxidation states and water contents and rendering the magmas infertile for later porphyry-skarn Cu formation in the Xiongmei area. [ABSTRACT FROM AUTHOR]

The Lakang'e porphyry Mo (Cu) deposit, intermediate to large in size, is located in the eastern part of the southern Gangdese metallogenic belt. It is associated with a Miocene granodiorite porphyry (GDP). The alteration styles are mainly potassic and phyllic alteration, with minor argillic, chlorite, and carbonation alteration. In this study, we present whole-rock geochemical compositions, zircon LA-ICP-MS U-Pb data, zircon Hf isotope analyses, and zircon and apatite major and trace element compositions for the ore-bearing GDP and postmineralization quartz diorite porphyry (QDP) to constrain the formation of the Lakang'e Mo (Cu) deposit. The ore-bearing GDP, with a zircon U-Pb age of 13.83 ± 0.20 Ma, was intruded after mineralization by the QDP, which was emplaced at 13.00 ± 0.16 Ma. The GDP and QDP are high-K calc-alkaline series rocks with adakite-like features characterized by high contents of K 2 O and Al 2 O 3 , high Sr/Y ratios, strongly fractionated REE patterns, LILE enrichment, and HFSE depletion. The GDP and QDP have relatively low (87Sr/86Sr) i values (0.7051–0.7054) and high εNd(t) values (−0.87 to 0.59). Zircon grains from the QDP have high εHf(t) values (7.0–9.6), while zircon grains from the GDP show large εHf(t) variations ranging from −4 to 9.6, indicating that the magma source of the ore-bearing GDP included more continental crust than that of the postmineralization QDP. The zircon Ce4+/Ce3+ and Eu/Eu* ratios and apatite Mn and SO 3 contents indicate that the postmineralization QDP had higher oxygen fugacity than the ore-bearing GDP. The oxygen fugacity of the ore-bearing magma present during apatite crystallization (generally below the Ni-Ni-O (NNO) buffer), was lower than that present during zircon crystallization (above the hematite-magnetite (HM) buffer). The F, Cl, and S contents in apatite show that the GDP and QDP were F and S rich and that the GDP had a higher F content than the QDP. A high oxygen fugacity, a F- and S-rich magma and a Mo-rich crustal source were the key factors for the formation of the Lakang'e porphyry Mo (Cu) deposit. From Lakange Mo (Cu) deposit to Jiama Cu polymetallic deposit to Qulong Cu-Mo deposit to Xiongcun Cu-Au deposits, the Cl contents in apatite gradually increase, but the F contents in apatite gradually decrease, and the S content is similar but variation. It indicates that the Mo-dominated porphyry deposit formed from F-S-rich magma, whereas the Cu-dominated porphyry deposit formed from Cl-S-rich magma. Unlabelled Image • Geological features were identified in the Lakange porphyry Mo (Cu) deposit. • Precise geochronology redefines the magmatism and mineralization age. • High f O 2 , F- and S-rich and Mo-rich crustal source are favorable for mineralization. [ABSTRACT FROM AUTHOR]

• Stable isotopes of fluids are comparable to those of typical orogenic gold deposits. • Ore fluids were likely generated through prograde metamorphic devolatilization. • Ore-forming materials were probably sourced from diagenetic pyrite at depth. • During transportation, gold-bearing fluids variably reacted with country rocks. Shangxu is an orogenic gold deposit in the Bangong-Nujiang suture zone, central Tibet, China, formed in the Early Cretaceous orogene, related to convergence and collision between the Qiangtang and Lhasa terranes. The mineralization at Shangxu is hosted by Jurassic turbidite sedimentary rocks of the Mugagangri Group, and is associated with a regional fault system. Hydrothermal minerals develop muscovite, carbonate, sulfides and chlorite. Hydrothermal fluids record three main hydrothermal stages based on mineral paragenesis. The earliest is barren quartz stage (H1), which is pre-ore. During the early mineralization quartz-pyrite stage (H2a), defined by massive quartz veins with minor euhedral pyrite and gold, hydrothermal fluids had a δ18O fluid of 6.1–6.4‰, δD of −74 to −116‰, δ13C CO2 of −5.4 to −7.6‰, and δ30Si of −0.1‰. In the quartz-pyrite-sulfides stage (H2b), characterized by abundant quartz, granular pyrite, muscovite with minor chalcopyrite, galena, sphalerite and gold, fluids had a δ18O fluid of 7–8.2‰, δD of −109 to −120‰, δ13C CO2 of −9.6‰ and δ30Si of −0.1 to −0.2‰. During the ankerite-sulfide stage (H3a), distinguished by abundant ankerite, muscovite, sulfides with minor quartz and chlorite, hydrothermal system had a fluid with δ18O fluid of 4.9–5.3‰, δD of −125.3‰, δ30Si of −0.1‰, δ13C CO2 of −12.4‰ in quartz inclusion fluid and δ13C CO2 of −2.7‰ in ankerite. The calcite-sulfide stage (H3b) is characterized by calcite, sulfides, with minor quartz and chlorite. Quartz formed earlier than calcite from a fluid having a δ18O fluid of 6.4‰, δD of −112.6‰, δ30Si of −0.1‰, and δ13C CO2 of −7.4‰, after which calcite precipitated from a hydrothermal fluid with δ18O fluid of 5.5–9‰, δ13C CO2 of −0.5 to −2.8‰. Hydrothermal fluids in H2b pyrite have 3He/4He ratios of 0.27–0.42Ra and 40Ar/36Ar ratios of 313–372. The stable isotope composition of hydrothermal fluids from the Shangxu gold deposit is similar to that of typical orogenic gold deposits. The early stage (H1), methane-bearing fluids were probably sourced from the basin sediments, leading to precipitation of early barren quartz veins and siderite alteration. From the quartz-sulfide stage (H2) to carbonate-sulfide stage (H3), hydrothermal fluids were likely derived from dissolution of the marine carbonate cement from sedimentary host rocks during metamorphism at depth. The decreasing δD and δ13C of the ore-forming fluids from early to late suggests mixing with δ13C-depleted oxidized graphite in sedimentary rocks, meteoric waters or reation between δD-depleted organic matters. Generally, these fluids were likely generated at depth through prograde metamorphic devolatilization of hydrous minerals in the deeper equivalents of the sedimentary rocks of the Mugagangri Group. Sulfur and gold, by inference, likely originated from sedimentary/diagenetic pyrite or the metasedimentary rocks between the greenschist and amphibolite facies, and migrated with the metamorphic fluids. During transportation to the site of deposition, gold-bearing fluids variably reacted with country rocks. [ABSTRACT FROM AUTHOR]

The Tiegelongnan porphyry mineralization and alteration firstly formed at ~ 120 Ma. After that, the porphyry system is unroofed with supergene oxidation on the top. The first pulse of epithermal hydrothermal event took place at ~ 116 Ma, which is followed by the second epithermal pulse at ~ 112 Ma, with continuing weathering, paleo-surface declining, and erosion. Andesite covered at the top of this porphyry-epithermal system at ~ 110 Ma, preserving the deposit from erosion. The youngest magmatic event at Tiegelongnan happened with the formation of alunite at ~100 Ma. Andesite is partly eroded with formation of supergene enrichment until present. • CA-ID-TIMS zircon U-Pb dating constrain the porphyry magmatic event at 119.9 ± 0.2 Ma. • Muscovite 40Ar-39Ar ages of 120.9 ± 0.8 Ma and 108.7 ± 0.7 Ma, alunite 40Ar-39Ar ages of 116.3 ± 0.8 Ma, 112.5 ± 0.8 Ma, 111.7 ± 1.0 Ma, 100.6 ± 2.0 Ma to illustrate the multiple discrete hydrothermal alteration pulses. • Geology and geochronology show the multiple pulses of epithermal overprinting porphyry alteration and mineralization processes at Tiegelongnan. • Cold weather, plat plateau, and mild compressive environment at Early Cretaceous Tibet are combined to explain the slow and long (~10 m.y) exhumation of the Tiegelongnan deposit. The Tiegelongnan (Rongna) deposit is a giant porphyry-epithermal Cu (Au) deposit within the Duolong porphyry district, in the south Qiangtang terrane, central-western Tibet, China. The deposit is centered on multiphase granodiorite porphyry (GP) intrusions intruded in Jurassic sandstone. Phase 1 and 2 GP are associated with biotite and sericite alteration, whereas GP3 and 4 occur in middle and shallow parts of the deposit affected by sericite and advanced argillic alteration (alunite-kaolinite-dickite-pyrophyllite). Sericite alteration is pervasive in the deep part of the deposit replacing biotite alteration and hosting porphyry stage chalcopyrite-bornite-pyrite ± molybdenite mineralization. Advanced argillic alterationis associated with epithermal stage high sulfidation (tennantite, enargite, bornite, and digenite) mineralization, overprints the sericite and biotite alteration from the shallow part of the deposit. The top of the Tiegelongnan hydrothermal system was weathered with a layer of supergene oxidation and enrichment zone, exhumated, and covered by andesite and gravel. Muscovite sampled from deep sericite alteration yields a 40Ar-39Ar age of 120.9 ± 0.8 Ma, which is consistent with previously reported hydrothermal biotite 40Ar-39Ar age of 121.1 ± 0.6 Ma, molybdenite Re-Os ages of 121.2 ± 0.6 and 119.0 ± 1.4 Ma, and GP 1 and 2 zircon U-Pb ages of 121.5 ± 1.5, 120.2 ± 1.0 Ma (LA-ICP-MS results), and 118.7 ± 0.9 Ma (SIMS result). Phase 3 GP 3 yields a CA-ID-TIMS zircon U-Pb age of 119.9 ± 0.2 Ma, which constrains the age of porphyry magmatic-hydrothermal events. The porphyry system was then unroofed, weathered, and superimposed by discrete stages of advanced argillic alteration and high sulfidation mineralization. Two pulses of alunite events yield 40Ar-39Ar ages of 116.3 ± 0.8 Ma and 111.7 ± 1.0 Ma, which represent the principal epithermal alteration and mineralization ages at Tiegelongnan. The first alunite pulse age is consistent with younger porphyry (GP4) age of 116.2 ± 0.4 Ma (zircon LA-ICP-MS age). Weathering and exhumation of the porphyry-epithermal deposit were continuing until the cover of andesite at ~110 Ma and by post-andesite gravel. The andesite was affected by a younger weak hydrothermal alteration at 108.7 ± 0.7 Ma, constrained by a muscovite 40Ar-39Ar age. Another barren alunite yields a 40Ar-39Ar age of 100.6 ± 2.0 Ma, which may represent the youngest hydrothermal event. The long life-span discrete hydrothermal activities from ~120 to ~100 Ma in the Tiegelongnan deposit is consistent with the long-lasting tectonic-magmatic events of the Bangong-Nujiang suture zone. The discrete epithermal mineralization events at Tiegelongan are younger than the porphyry mineralization events, which is analogous to several other epithermal deposits worldwide. The ~10 m.y exhumation history at Tiegelongan is slower than the typical and rapid erosion history of ~1–2 m.y porphyry deposits in low-altitude tropical climates regions, and during a specific abrupt uplift pulse in the Andean region. The slow exhumation at Tiegelongnan is interpreted to be an integrated result of an arid climate environment, relatively flat topography, and a slow uplift condition during Cretaceous in central-western Tibet. [ABSTRACT FROM AUTHOR]

In order to understand how the metallogenic process of porphyry deposit specifically and directly respond to regional uplifting and exhumation, we compiled previous fluid inclusion data of 32 porphyry deposits in China by recalculating the fluid trapping depths and trapping depth reduction magnitude from early to late mineralization stage veins. The data reveal that the average trapping pressure ratio (Ave TPE/TPL) between early‐ and late‐stage veins of the these deposits are 1.2–18.4, mainly in the range of 1.35–5.83, with average trapping pressure reduction (1–Ave TPL/TPE) from early‐ to late‐ stage veins are 17%–95%, and mainly in the range of 25%–83%. The fluid trapping pressure based mineralization depths most of the porphyry deposits in China had decreased from early to late vein stages by at least 450 m (900–5800 m predominant), or greater than 950 m when take the average depth reduction value, which is greater than the current gap between early‐ and late‐ stage veins of each deposit. We propose that the apparently greater mineralization depth reduction magnitude than the current elevation gaps between early and late veins are likely a consequence of syn‐mineralization uplifting and exhumation process that often occurs in porphyry systems. [ABSTRACT FROM AUTHOR]

• Gold mineralization is enveloped by zones of Au, As and W enrichment. • Muscovite, carbonate and sulfide constitute a progressive alteration front from gold. • Hydrothermal alteration is marked by introduction of K 2 O, CO 2 , S and leaching of Na 2 O. • Pyrite develops with time and records the formation process of the gold deposit. • Geochemical, mineralogical changes related to alteration are useful for exploration. Shangxu is an orogenic gold deposit within the Bangong-Nujiang suture zone, central Tibet, China. It is hosted by turbidite sedimentary rocks of the Jurassic Mugagangri Group. The host rocks were metamorphosed to subgreenschist facies prior to being hydrothermally altered adjacent to mineralization. Hydrothermal minerals in wall rocks consist of muscovite, carbonate, sulfides and chlorite. Whole rock geochemistry indicates hydrothermal alteration is characterized by the introduction of K 2 O, CO2 and S, and leaching of Na 2 O. Increasing 3 K/Al and decreasing Na/Al alteration indexes approaching the ore correlate to muscovitization. CO 2 concentration reflects the degree of carbonation, which in conjunction with molar (Mn + Fe)/(Fe + Ca + Mg + Mn) and CO 2 /CaO can be used to distinguish siderite from ankerite in carbonate alteration. Mass transfer analysis shows gains in As, Au, CO 2 , W, Ca, Cd, Ni, Cr, Sr, Rb, K and losses in Na, Pb, Cu during hydrothermal alteration. In the muscovite alteration zone, muscovite within shear zones (Ms1) shows an increase in Fe, Mg and Na towards the ore, whereas metamorphic muscovite along cleavage planes and in pressure shadows (Ms2), and hydrothermal muscovite (Ms3) change in composition from phengitic (Mg, Fe) distal to mineralization, to paragonitic (Na) adjacent to gold. In carbonate alteration, the composition in carbonate phases changes from early magnesian siderite to ankerite, and then to calcite and dolomite during the evolution of the hydrothermal system. Siderite spots in host rocks and ankerite in veins, wall rock or its replacement of siderite are all enriched in Fe, Mn and depleted in Mg from proximal to distal alteration zones. Pyrite is a dominant mineral in sulfide alteration of the Shangxu deposit. The earliest framboidal pyrite (Py1) formed during diagenesis, and overprinted by Py2, which is recrystallized pyrite associated with burial metamorphism. Py3 rims and enlarges previous pyrite aggregates, or recrystallizes into cubic grains with cracks and quartz pressure shadows during deformation. Py4 is ore-related euhedral pyrite, disseminated near gold, and formed in hydrothermal stage. Vein pyrite (Py5) coexists with marcasite, and fills cracks in quartz veins. Hydrothermal alteration minerals form overlapping alteration haloes surrounding the main auriferous lodes. Distal muscovitization, carbonatization and proximal sulfidation constitute a progressive alteration front from gold. The alteration envelope is tabular in shape, following the strike and dip of the mineralization, and tends to be the widest around the thickest parts of the ore, such that the occurrence and thickness of the alteration envelope can be used as an approximate guide to the size of gold mineralization. Shangxu shares many diagnostic features with turbidite-hosted orogenic gold deposits, such as Bendigo, Reefton and Meguma districts, in deposit geology, alteration mineralogy and lithogeochemistry. [ABSTRACT FROM AUTHOR]

• Highly evolved parental magma controls formation of the Jiaoxi W deposit. • New geodynamic setting for Miocene granite-related W deposits in central Lhasa subterrane. • Mantle-derived melts play an important role in mobilizing the W from crust materials. The Jiaoxi deposit is the first Miocene quartz vein-type W deposit discovered in the western part of the Lhasa Terrane comprising with 39,000 metric tons of WO 3. The mineralization occurs in wolframite-bearing hydrothermal tensional quartz veins and is associated with Miocene granites. The mineralization event can be divided into an early quartz-oxide stage succeeded by a sulfide stage, and a final fluorite-carbonate stage. Magmatic intrusions at the deposit include biotite monzogranite porphyry, biotite monzogranite, granite porphyry, and muscovite granite at depth and show crystallization ages ranging between 14.5 and 13.7 Ma. Whole-rock geochemistry shows that the intrusions are alkali-rich peraluminous granites that experienced strong fractional crystallization. The most evolved muscovite granite has high W, Nb and Cs contents and is considered to be the source for mineralization. During the late crystallization stage of the highly fractionated muscovite granite, exsolved hydrothermal fluids interacted with the muscovite granite magma and migrated along extensional fractures forming the Jiaoxi deposit. Zircon grains from the granites show uniform ε Hf (t) values with a wide range between −7.08 and +3.87. The granites have initial Sr isotopic compositions ranging between 0.7094 and 0.7124 and negative ε Nd (t) values ranging between −4.9 and −9.4. The Sr-Nd-Hf isotope data indicate that the granites were derived from partial melting of a crustal source with minor contributions from the lithospheric mantle. The 3He/4He ratios for wolframite and pyrite vary between 0.30 and 0.74 Ra (Ra = 1.4 × 10–6 for air), confirming that W was mainly sourced from the crust. Collectively, the regional geology, geochronology and geochemistry, indicate that the Miocene post-collisional peraluminous granites and associated W mineralization were triggered by the roll-back and gradual break-off of the northward-subducting Indian continental lithosphere slab. The less evolved biotite monzogranite porphyry, which contains ore-bearing veins and local greisen alteration, appears to be unrelated to W mineralization. [ABSTRACT FROM AUTHOR]