Search

The objective of this work is to investigate experimentally controlling cavitating flow over NACA66 (MOD) hydrofoils by means of an active water injection along its suction surface. The continuous water vertically jets out of the chamber inside the hydrofoil through evenly distributed surface holes. Experiments were carried out in cavitation water tunnel, using high-speed visualization technology and the particle image velocimetry (PIV) system to study the sheet/cloud cavity behaviors. We studied the effects of this active control on cavity evolution with four kinds of jet flow at two different jet positions. We analyzed the effect of water injection on the mechanism of the cavitating flow control. The results were all compared with that for the original hydrofoil without jet and show that the active jet can effectively suppress the sheet/cloud cavitation characterized by shrinking the attached cavity size and breaking the large-scaled cloud shedding vortex cavity into small-scaled ones. The optimum effectiveness of cavitation suppression is affected by the jet flow rates and jet positions. The water injection at flow rate coefficient 0.0245 with the jet position of 0.45C reduces the maximum sheet cavity length by 79.4 $$\%$$ and the cavity shedding is diminished completely, which gives the most superior effect of sheet cavitation suppression. The jet blocks the re-entrant jet moving upstream and weakens the power of re-entrant jet and thus restrains the cavitation development effectively and stabilizes the flow field.

We demonstrate a simple and cost-effective approach to realize two combined surface features of different scales together, namely submillimeter-sized protrusion array and microwrinkles, atop a polystyrene shape-memory polymer. Two different types of protrusions, namely flat-top protrusion and crown-shaped protrusion, were studied. The array of protrusions was produced by the Indentation-Polishing-Heating (IPH) process. Compactly packed steel balls were used for making array of indents. A thin gold layer was sputter deposited atop the polymer surface right after polishing. After heating for shape recovery, array of protrusions with wrinkles on the top due to the buckling of gold layer was produced.

A new p-phenylene–vinylene–thiophene-based siloxane block copolymer has been synthesized. The copolymer consists of alternating rigid and flexible blocks. The rigid blocks are composed of phenylene–vinylene–thiophene-based units, and the flexible blocks are derived from 1,3-dialkyldisiloxane units. The former component acts as the chromophore, and allows fine tuning of band gap for blue-light emission, while the latter imparts good solubility of the copolymer in organic solvents, and thus, should enhance processibility of the resulting copolymer. The thermal properties of the copolymer have been characterized by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The photoluminescence (PL) of the copolymer in solution and in cast film has been studied. The effects of concentration on the PL intensity of the new copolymer in polymer blends with poly(methyl methacrylate) (PMMA) and poly(vinyl carbazole) (PVK) have also been described. Efficient energy transfer from PVK to the new block copolymer in the blended film was observed. © 2000 John Wiley & Sons, Inc. J Polym Sci A: Polym Chem 38: 1450–1456, 2000

Three types of liquid crystalline compound containing a 4-ring mesogenic core with a lateral alkoxy chain on one of the inner rings were synthesized, and their mesogenic properties studied. The 4-ring core of these compounds bears an electron-accepting nitro group at one end and an electron-donating alkylamino moiety at or near the other end. Therefore, they are highly coloured and have lambda max 473 nm. One of these three types of compound has a wide enantiotropic nematic range. Twelve homologous analogues in this series with different lengths for the terminal alkyl chain and the lateral alkoxy chain were synthesized and compared.

The orientational ordering of six liquid crystalline compounds in two homologous series, namely 4-n-alkoxybenzilidene-4′-n-alkylanilines (nO. m) and 4, 4′-di-n-alkyldiphenyldiacetylenes (PTTP), has been studied at different temperatures by 2D C-13 NMR with variable angle sample spinning. The carbon-proton dipolar coupling constants were obtained and the order parameters of the aromatic cores were calculated. The C-13 chemical shifts for each carbon nucleus in the aromatic cores were also measured as a function of temperature by 1D C-13 NMR. A linear correlation between the chemical shifts and the order parameters was observed for each homologous series. The results furnish a useful and convenient database for the evaluation of order parameters for these two series of liquid crystals from simple measurements of C-13 chemical shifts.

The orientational ordering of nine classes of liquid crystals, namely 4-n-alkyl-413 cyanobiphenyls (nCB), 4-n-alkoxy-4-cyanobiphenyls (nOCB), 4-n-alkoxybenzilidene-4-nalkylanilines (nO.m), 4-cyanophenyl 4-alkylbenzoates (nCPB), 4-n-alkylphenyl 4-n-alkoxycinnamates (Cin-n-m), esters of alpha-chloro carboxylic acids and 4-n-alkyl-4-hydroxybiphenyls (An, Bn and Cn), 4,4-di-n-alkyldiphenyldiacetylenes (PTTP), 4-n-alkylphenyl 4-n-alkoxybenzoates (nOm), and 4-n-alkoxyphenyl 4-n-alkoxybenzoates (nOm), have been investigated by the use of 13C NMR. The order parameters of the phenyl rings were determined by using a 2D 13C NMR technique known as separated local field (SLF) spectroscopy in combination with variable angle spinning (VAS). The order parameters obtained were then correlated with their corresponding anisotropic 1D C chemical shifts in their nematic and smectic phases to give a linear relationship in each case. The parameters obtained in the linear correlations provide a convenient way to obtain the order...

We have previously demonstrated that various types of patterns at different scales can be easily realized atop shape memory polymers (SMPs) through a procedure in three steps, namely, indentation, polishing and heating (IPH). On the other hand, by coating a thin metallic layer (e.g., a few nanometers thick of gold) atop SMPs with or without prestraining, different types of wrinkles could be generated. In this paper, we investigate the wrinkling patterns formed on the top of SMPs with a patterned surface, i.e., wrinkling atop a surface with a protrusion pattern. As the wrinkles are resulted simultaneously by two phenomena upon heating, namely the shape recovery of the SMP substrate and buckling of the elastic metallic layer, the wrinkle pattern varies from one location to another depending on the exact local strain. Utilizing this technique, we are able to simultaneously produce a surface with complicate surface patterns at both micro and millimeter levels. Such surfaces could significantly enhance many surface properties, e.g., bonding, adhesion and friction etc.

A mass tagging approach is described for mitochondrial thiol proteins under nondenaturing conditions. This approach utilizes stable isotope-coded, thiol-reactive (4-iodobutyl)triphenylphosphonium (IBTP) reagents, i.e., the isotopomers IBTP-d(0) and IBTP-d(15). The mass spectrometric properties of IBTP-labeled peptides were evaluated using an ESI-q-TOF and a MALDI-TOF/TOF instrument. High energy collision induced dissociation (CID) in the TOF/TOF instrument caused side-chain fragmentation in the butyltriphenylphosphonium moiety-containing Cys-residue. By contrast, low energy CID in the qTOF instrument yielded sequence tags of IBTP-labeled peptides that were suitable for automated database searching. The IBTP labeling strategy was then applied to the analysis of a protein extract obtained from cardiac mitochondria. The relative abundance measurements for identified IBTP-labeled peptides showed an average variability for peptide quantitation of approximately 10% based on peak area ratios of ion signals for the d(0)/d(15)-tagged peptide pairs. The reactivity of the IBTP reagents was further studied by molecular modeling and visualization. The present study suggests that the IBTP reagent seems to show a bias toward highly surface-exposed protein thiols. Hence, the described mass tagging approach might become potentially useful in redox proteomics studies designed to identify protein thiols that are particularly prone to oxidative modifications.