411 results on '"T. Egami"'
Search Results
2. Structural magnetic glassiness in the spin ice Dy_{2}Ti_{2}O_{7}
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Anjana M. Samarakoon, André Sokolowski, Bastian Klemke, Ralf Feyerherm, Michael Meissner, R. A. Borzi, Feng Ye, Qiang Zhang, Zhiling Dun, Haidong Zhou, T. Egami, Jonathan N. Hallén, Ludovic Jaubert, Claudio Castelnovo, Roderich Moessner, S. A. Grigera, and D. Alan Tennant
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Physics ,QC1-999 - Abstract
The origin and nature of glassy dynamics presents one of the central enigmas of condensed-matter physics across a broad range of systems ranging from window glass to spin glasses. The spin-ice compound Dy_{2}Ti_{2}O_{7}, which is perhaps best known as hosting a three-dimensional Coulomb spin liquid with magnetically charged monopole excitations, also falls out of equilibrium at low temperature. How and why it does so remains an open question. Based on an analysis of low-temperature diffuse neutron-scattering experiments employing different cooling protocols alongside recent magnetic noise studies, combined with extensive numerical modeling, we argue that upon cooling, the spins freeze into what may be termed a “structural magnetic glass,” without an a priori need for chemical or structural disorder. Specifically, our model indicates the presence of frustration on two levels, first producing a near-degenerate constrained manifold inside which phase ordering kinetics is in turn frustrated. A remarkable feature is that monopoles act as sole annealers of the spin network and their pathways and history encode the development of glass dynamics, allowing the glass formation to be visualized. Our results suggest that spin ice Dy_{2}Ti_{2}O_{7} provides one prototype of magnetic glass formation specifically and a setting for the study of kinetically constrained systems more generally.
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- 2022
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3. Pressure Induced Liquid-to-Liquid Transition in Zr-based Supercooled Melts and Pressure Quenched Glasses
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W. Dmowski, S. Gierlotka, Z. Wang, Y. Yokoyama, B. Palosz, and T. Egami
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Medicine ,Science - Abstract
Abstract Through high-energy x-ray diffraction and atomic pair density function analysis we find that Zr-based metallic alloy, heated to the supercooled liquid state under hydrostatic pressure and then quenched to room temperature, exhibits a distinct glassy structure. The PDF indicates that the Zr-Zr distances in this glass are significantly reduced compared to those quenched without pressure. Annealing at the glass transition temperature at ambient pressure reverses structural changes and the initial glassy state is recovered. This result suggests that pressure causes a liquid-to-liquid phase transition in this metallic alloy supercooled melt. Such a pressure induced transition is known for covalent liquids, but has not been observed for metallic liquids. The High Pressure Quenched glasses are stable in ambient conditions after decompression.
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- 2017
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4. Observation of dynamic atom-atom correlation in liquid helium in real space
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W. Dmowski, S. O. Diallo, K. Lokshin, G. Ehlers, G. Ferré, J. Boronat, and T. Egami
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Science - Abstract
Liquid helium can be treated as an ideal gas or a condensed liquid and displays intriguing features like Bose–Einstein condensation. Here the authors show that roton excitation reveals information on real space dynamic atom-atom correlations in superfluid helium, which could be used to benchmark models.
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- 2017
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5. Strain-relaxation and critical thickness of epitaxial La1.85Sr0.15CuO4 films
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T. L. Meyer, L. Jiang, S. Park, T. Egami, and H. N. Lee
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Biotechnology ,TP248.13-248.65 ,Physics ,QC1-999 - Abstract
We report the thickness-dependent strain-relaxation behavior and the associated impacts upon the superconductivity in epitaxial La1.85Sr0.15CuO4 films grown on different substrates, which provide a range of strain. We have found that the critical thickness for the onset of superconductivity in La1.85Sr0.15CuO4 films is associated with the finite thickness effect and epitaxial strain. In particular, thin films with tensile strain greater than ∼0.25% revealed no superconductivity. We attribute this phenomenon to the inherent formation of oxygen vacancies that can be minimized via strain relaxation.
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- 2015
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6. Complexity at mesoscopic lengthscale
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T. Egami
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doped ceria ,disorder ,pair distribution function ,high-resolution X-ray powder diffraction ,percolation ,hierarchy ,solid electrolytes ,electron spin resonance ,Crystallography ,QD901-999 - Published
- 2015
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7. Spin-Lattice Coupling and Superconductivity in Fe Pnictides
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T. Egami, B. V. Fine, D. Parshall, A. Subedi, and D. J. Singh
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Physics ,QC1-999 - Abstract
We consider strong spin-lattice and spin-phonon coupling in iron pnictides and discuss its implications on superconductivity. Strong magneto-volume effect in iron compounds has long been known as the Invar effect. Fe pnictides also exhibit this effect, reflected in particular on the dependence of the magnetic moment on the atomic volume of Fe defined by the positions of the nearest neighbor atoms. Through the phenomenological Landau theory, developed on the basis of the calculations by the density functional theory (DFT) and the experimental results, we quantify the strength of the spin-lattice interaction as it relates to the Stoner criterion for the onset of magnetism. We suggest that the coupling between electrons and phonons through the spin channel may be sufficiently strong to be an important part of the superconductivity mechanism in Fe pnictides.
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- 2010
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8. Experimental determination of the temperature-dependent Van Hove function in a Zr80Pt20 liquid
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R. Ashcraft, Z. Wang, D. L. Abernathy, D. G. Quirinale, T. Egami, and K. F. Kelton
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- 2020
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9. Nuclear magnetic moment of the neutron-rich nucleus O21
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Y. Ishibashi, A. Gladkov, Y. Ichikawa, A. Takamine, H. Nishibata, T. Sato, H. Yamazaki, T. Abe, J. M. Daugas, T. Egami, T. Fujita, G. Georgiev, K. Imamura, T. Kawaguchi, W. Kobayashi, Y. Nakamura, A. Ozawa, M. Sanjo, N. Shimizu, D. Tominaga, L. C. Tao, K. Asahi, H. Ueno, Direction des Applications Militaires (DAM), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), and Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)
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[PHYS.NUCL]Physics [physics]/Nuclear Theory [nucl-th] - Abstract
International audience; The ground-state magnetic dipole moment of the neutron-rich O21 isotope has been measured via β-ray-detected nuclear magnetic resonance (β-NMR) spectroscopy by using a spin-polarized secondary beam of O21 produced from the Ne22 primary beam. From the present measurement, the g factor |gexp(Og.s.21)|=0.6036(14) has been determined. Based on the comparison of this value with Schmidt values, we unambiguously confirm the νd5/2 configuration with spin and parity assignments Iπ=5/2+ for the O21 ground state, suggested by previously reported studies. Consequently, the magnetic moment has been determined as μexp(Og.s.21)=(−)1.5090(35)μN. The obtained experimental magnetic moment is in good agreement with the predictions of the shell-model calculations using the USD, YSOX, and SDPF-M interactions as well as random phase approximation (RPA) calculations. This observation indicates that the O21 nucleus in its ground state does not manifest any anomalous structure and is not influenced by the proximity of the drip line.
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- 2023
10. g Factor of the Zr99 ( 7/2+ ) Isomer: Monopole Evolution in the Shape-Coexisting Region
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Naoki Fukuda, T. Nishizaka, Georgi Georgiev, Ish Mukul, Megumi Niikura, W. Kim, D. L. Balabanski, A. Kusoglu, Yoji Kobayashi, Koichiro Asahi, Hiroki Nishibata, T. Egami, DeukSoon Ahn, S. Kisyov, Yuichi Ohtomo, Yoko Ishibashi, Hiroshi Suzuki, K. Imamura, Gary Simpson, T. Kawaguchi, L. C. Tao, T. Fujita, Satoru Momiyama, Michael Hass, A. Gladkov, C. Funayama, Atsuko Odahara, Takuso Sato, Takashi Kawamura, Naohito Inabe, J. M. Daugas, R. Lozeva, F. Boulay, Hiroaki Ueno, Shuichiro Kojima, D. Ralet, Takeshi Furukawa, Toshiyuki Sumikama, Y. Shimizu, H. Yamazaki, D. Tominaga, Yasuhiro Togano, H. Baba, Yuichi Ichikawa, Xiaofei Yang, A. Takamine, D. Bucurescu, and H. Takeda
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Physics ,Angular distribution ,medicine.anatomical_structure ,Magnetic moment ,0103 physical sciences ,Magnetic monopole ,medicine ,General Physics and Astronomy ,Parity (physics) ,Atomic physics ,010306 general physics ,01 natural sciences ,Nucleus - Abstract
The gyromagnetic factor of the low-lying E=251.96(9) keV isomeric state of the nucleus ^{99}Zr was measured using the time-dependent perturbed angular distribution technique. This level is assigned a spin and parity of J^{π}=7/2^{+}, with a half-life of T_{1/2}=336(5) ns. The isomer was produced and spin aligned via the abrasion-fission of a ^{238}U primary beam at RIKEN RIBF. A magnetic moment |μ|=2.31(14)μ_{N} was deduced showing that this isomer is not single particle in nature. A comparison of the experimental values with interacting boson-fermion model IBFM-1 results shows that this state is strongly mixed with a main νd_{5/2} composition. Furthermore, it was found that monopole single-particle evolution changes significantly with the appearance of collective modes, likely due to type-II shell evolution.
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- 2020
11. Interplay between nuclear shell evolution and shape deformation revealed by the magnetic moment of $^{75}$Cu
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Y. Ichikawa, H. Nishibata, Y. Tsunoda, A. Takamine, K. Imamura, T. Fujita, T. Sato, S. Momiyama, Y. Shimizu, D. S. Ahn, K. Asahi, H. Baba, D. L. Balabanski, F. Boulay, J. M. Daugas, T. Egami, N. Fukuda, C. Funayama, T. Furukawa, G. Georgiev, A. Gladkov, N. Inabe, Y. Ishibashi, T. Kawaguchi, T. Kawamura, Y. Kobayashi, S. Kojima, A. Kusoglu, I. Mukul, M. Niikura, T. Nishizaka, A. Odahara, Y. Ohtomo, T. Otsuka, D. Ralet, G. S. Simpson, T. Sumikama, H. Suzuki, H. Takeda, L. C. Tao, Y. Togano, D. Tominaga, H. Ueno, H. Yamazaki, X. F. Yang, Direction des Applications Militaires (DAM), Commissariat à l'énergie atomique et aux énergies alternatives (CEA), Grand Accélérateur National d'Ions Lourds (GANIL), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Centre de Sciences Nucléaires et de Sciences de la Matière (CSNSM), Université Paris-Sud - Paris 11 (UP11)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Physique Subatomique et de Cosmologie (LPSC), Université Joseph Fourier - Grenoble 1 (UJF)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Institut Polytechnique de Grenoble - Grenoble Institute of Technology-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA), Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3), Centre National de la Recherche Scientifique (CNRS)-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Université Paris-Sud - Paris 11 (UP11), Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes (UGA)-Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP ), Université Grenoble Alpes (UGA), and Institut polytechnique de Grenoble - Grenoble Institute of Technology (Grenoble INP )-Institut National de Physique Nucléaire et de Physique des Particules du CNRS (IN2P3)-Centre National de la Recherche Scientifique (CNRS)-Université Grenoble Alpes [2016-2019] (UGA [2016-2019])
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Physics ,Magnetic moment ,Nuclear Theory ,Shell (structure) ,General Physics and Astronomy ,FOS: Physical sciences ,[PHYS.NEXP]Physics [physics]/Nuclear Experiment [nucl-ex] ,01 natural sciences ,Molecular physics ,010305 fluids & plasmas ,medicine.anatomical_structure ,Nucleosynthesis ,0103 physical sciences ,medicine ,Nuclear force ,Neutron ,Nuclear Experiment (nucl-ex) ,010306 general physics ,Nucleon ,Spin (physics) ,Nuclear Experiment ,Nucleus - Abstract
Exotic nuclei are characterized by a number of neutrons (or protons) in excess relative to stable nuclei. Their shell structure, which represents single-particle motion in a nucleus, may vary due to nuclear force and excess neutrons, in a phenomenon called shell evolution. This effect could be counterbalanced by collective modes causing deformations of the nuclear surface. Here, we study the interplay between shell evolution and shape deformation by focusing on the magnetic moment of an isomeric state of the neutron-rich nucleus 75Cu. We measure the magnetic moment using highly spin-controlled rare-isotope beams and achieving large spin alignment via a two-step reaction scheme that incorporates an angular-momentum-selecting nucleon removal. By combining our experiments with numerical simulations of many-fermion correlations, we find that the low-lying states in 75Cu are, to a large extent, of single-particle nature on top of a correlated 74Ni core. We elucidate the crucial role of shell evolution even in the presence of the collective mode, and within the same framework, we consider whether and how the double magicity of the 78Ni nucleus is restored, which is also of keen interest from the perspective of nucleosynthesis in explosive stellar processes., 10 pages, 4 figures
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- 2019
12. Absolute optical absorption cross-section measurement of Rb atoms injected into superfluid helium using energetic ion beams
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K , Imamura, Y, Matsuo, W , Kobayashi, T, Egami, M, Sanjo, A , Takamine, T, Fujita, D, Tominaga, Y , Nakamura, T, Furukawa, Wakui, Takashi, Y , Ichikawa, H, Nishibata, T, Sato, A , Gladkov, LC , Tao, T , Kawaguchi, Y, Baba, M , Iijima, H , Gonda, Y , Takeuchi, R, Nakazato, H , Odashima, and H , Ueno
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Physics::Accelerator Physics ,Physics::Atomic Physics - Abstract
We report on a new in situ laser spectroscopy technique using superfluid helium and a highly energetic ion beam. In taking advantage of superfluid helium as a host matrix for laser spectroscopy, we were able to develop an extremely low background detection system. The first demonstration using Rb-85(31+) ion beam (66 MeV/nucleon) accelerated at the RIKEN accelerator facility shows improvement of detection limit by two orders of magnitude. A quantitative evaluation of Rb atoms in the observation region enables an analysis of their optical absorption cross-section in superfluid helium from the fluorescence intensity dependence on ion-beam intensity and applied laser power. (C) 2018 The Japan Society of Applied Physics
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- 2018
13. High rectification and photovoltaic effect in oxide nano-junctions
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T Choi, L Jiang, S Lee, T Egami, and H N Lee
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Science ,Physics ,QC1-999 - Abstract
Polar oxide-based heterostructures composed of ferroelectric PbZr _0.2 Ti _0.8 O _3 and hole-doped La _0.8 Sr _0.2 MnO _3 ultrathin epitaxial films were fabricated on Nb:SrTiO _3 substrates to check the viability of all oxide-based photovoltaic (PV) nano-junctions. We observed clear diode-like behavior, yielding a rectification ratio up to ∼ 1000. This large enhancement could be attributed to the presence of an ultrathin ferroelectric layer (
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- 2012
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14. Negative Parity States in 39Cl Configured by Crossing Major Shell Orbits*
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Long Chun Tao, Hideki Ueno, T. Nishizaka, T. Egami, T. Fujita, H. Yamazaki, D. Tominaga, J. L. Lou, Tomoya Sato, A. Takamine, Yan-Lin Ye, K. Imamura, Koichiro Asahi, Cenxi Yuan, Yuichi Ichikawa, A. Gladkov, C. Funayama, Xiaofei Yang, T. Kawaguchi, and Yoko Ishibashi
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Physics ,Light nucleus ,Angular momentum ,Particle properties ,Isotope ,Quantum state ,Isotopes of chlorine ,General Physics and Astronomy ,Parity (physics) ,Atomic physics ,Spectroscopy - Abstract
Traditional “magic numbers” were once regarded as immutable throughout the nuclear chart. However, unexpected changes were found for unstable nuclei around N = 20. With both proton and neutron numbers around the magic number of 20, the neutron-rich 39Cl isotope provides a good test case for the study of the quantum-state evolution across the major shell. In the present work, the negative parity states in 39Cl are investigated through the β decay spectroscopy of 39S. Newly observed γ transitions together with a new state are assigned into the level scheme of 39Cl. The spin parity of 5/2− for the lowest negative parity state in 39Cl is reconfirmed using the combined γ transition information. These systematic observations of the negative parity states in 39Cl allow a comprehensive comparison with the theoretical descriptions. The lowest 5/2− state in 39Cl remains exotic in terms of comparisons with existing theoretical calculations and with the neighboring isotopes having similar single-particle configurations. Further experimental and theoretical investigations are suggested.
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- 2019
15. Absolute optical absorption cross-section measurement of Rb atoms injected into superfluid helium using energetic ion beams
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Yutaro Nakamura, A. Takamine, T. Kawaguchi, Hiroki Nishibata, T. Egami, Wataru Kobayashi, Tomoya Sato, T. Wakui, Yukari Matsuo, Takeshi Furukawa, Mari Iijima, Hideki Ueno, A. Gladkov, Hitoshi Odashima, T. Fujita, Yosuke Baba, Makoto Sanjo, Yuichi Ichikawa, Haruka Gonda, Long Chun Tao, Yasuharu Takeuchi, Rio Nakazato, D. Tominaga, and K. Imamura
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010302 applied physics ,Materials science ,Ion beam ,General Engineering ,Absorption cross section ,General Physics and Astronomy ,02 engineering and technology ,021001 nanoscience & nanotechnology ,01 natural sciences ,Ion ,0103 physical sciences ,Physics::Accelerator Physics ,Physics::Atomic Physics ,Laser power scaling ,Atomic physics ,0210 nano-technology ,Spectroscopy ,Absorption (electromagnetic radiation) ,Superfluid helium-4 ,Order of magnitude - Abstract
We report on a new in situ laser spectroscopy technique using superfluid helium and a highly energetic ion beam. In taking advantage of superfluid helium as a host matrix for laser spectroscopy, we were able to develop an extremely low background detection system. The first demonstration using 85Rb31+ ion beam (66 MeV/nucleon) accelerated at the RIKEN accelerator facility shows improvement of detection limit by two orders of magnitude. A quantitative evaluation of Rb atoms in the observation region enables an analysis of their optical absorption cross-section in superfluid helium from the fluorescence intensity dependence on ion-beam intensity and applied laser power.
- Published
- 2018
16. Nanoscale oscillatory fracture propagation in metallic glasses
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T Egami and Yehuda Braiman
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Statistics and Probability ,Physics ,Brittleness ,Amorphous metal ,Condensed matter physics ,Oscillation ,Fracture mechanics ,Condensed Matter Physics ,Nanoscopic scale ,Fracture propagation - Abstract
We describe the oscillatory crack propagation for small propagation velocities at the atomistic scale that was recently observed for brittle metallic glasses [G. Wang, Y.T. Wang, Y.H. Liu, M.X. Pan, D.Q. Zhao, W.H. Wang, Appl. Lett. 89 (2006) 121909; G. Wang, D.Q. Zhao, H.Y. Bai, M.X. Pan, A.L. Xia, B.S. Han, X.K. Xi, Y. Wu, W.H. Wang, Phys. Rev. Lett. 98 (2007) 235501]. Based on a simple model of crack propagation [Y. Braiman, T. Egami, Phys. Rev. E, 77 (2008) 065101(R)], we derived and analyzed expressions for the feature size, oscillation period, and maximum strain accumulated in the material.
- Published
- 2009
17. Local Structure of Ferroelectric Materials
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T. Egami
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Crystallography ,Materials science ,Condensed matter physics ,Complex system ,General Materials Science ,Neutron scattering ,Piezoelectricity ,Local structure ,Ferroelectricity ,Characterization (materials science) ,Ion ,Relaxation behavior - Abstract
Most of the ferroelectric and piezoelectric materials used in transducers and electronics are complex mixed-ion alloys, in which atomic disorder plays an important role in the ferroelectric properties. The extreme case is relaxor ferroelectric solids with diffuse ferroelectric transition and glass-like relaxation behavior. In this review I discuss how advanced characterization techniques, such as neutron scattering, enabled a determination of the local structure and facilitated the understanding of the ferroelectric and piezoelectric properties of these complex systems. In particular, I focus on the role of Pb2+ ions in mixed ferroelectrics and the atomistic mechanism of relaxor ferroelectrics.
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- 2007
18. Middle- and Neighborhood-Scale Variations of PM10 Source Contributions in Las Vegas, Nevada
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Richard T. Egami, John A. Gillies, Mark C. Green, Judith C. Chow, Steven D. Kohl, John G. Watson, David Dubois, C. F. Rogers, Clifton A. Frazier, Douglas H. Lowenthal, and Cates W
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Hydrology ,Las vegas ,Meteorology ,Air pollution ,Sampling (statistics) ,Chemical mass balance ,Management, Monitoring, Policy and Law ,Neighborhood scale ,medicine.disease_cause ,Aerosol ,medicine ,Environmental science ,Waste Management and Disposal ,Air quality index - Abstract
The Las Vegas Valley PM10 Study was conducted during 1995 to determine the contributions to PM10 aerosol from fugitive dust, motor vehicle exhaust, residential wood combustion, and secondary aerosol sources. Twenty-four-hr PM10 samples were collected at two neighborhood-scale sites every sixth day for 13 months. Five week-long intensive studies were conducted over a middle-scale sub-region at 29 locations that contained many construction projects emitting fugitive dust. The study found that the zone of influence around individual emitters was less than 1 km. Most of the sampling sites in residential and commercial areas yielded equivalent PM10 concentrations in the neighborhood region, even though they were more distant from each other than they were from the nearby construction sources. Based on chemical mass balance (CMB) receptor modeling, fugitive dust accounted for 80-90% of the PM10, and motor vehicle exhaust accounted for 3-9% of the PM10 in the Las Vegas Valley.
- Published
- 2015
19. New Science Opportunities Enabled by LCLS-II X-Ray Lasers
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M. Wei, R. Coffee, Y. Zhu, Richard A. Kirian, Jerry LaRue, Mark S. Hunter, Sébastien Boutet, Dennis Nordlund, D. Osborn, D. Lu, P. Abbamonte, C.J. Kenney, A. Lanzara, H. Kim, L. Young, U. Lundstrom, Musa Ahmed, C. McGuffey, Daniel Slaughter, Oleg Shpyrko, A. Thomas, Robert G. Moore, J. B. Hastings, Brenda G. Hogue, Gabriel Blaj, K. Sokolowski Tinten, Kimberly L. Nelson, M. Dantus, Robert W. Schoenlein, L. Fou car, P. Denes, Abbas Ourmazd, D. Parkinson, Oliver Gessner, S. Nozawa, Vittal K. Yachandra, Junko Yano, David A. Reis, A. MacDowell, C. Taatjes, Z. Huang, S. Nemšák, H. Michelsen, S. Arizona, Michael P. Minitti, J. S. Robinson, Thomas M. Weiss, F. Abild Pedersen, Y. Chuang, Pontus Fischer, William E. White, M. Hashimoto, Shambhu Ghimire, C. Pelle grini, Georgi L. Dakovski, Daniel Rolles, Shantanu Sinha, Richard Neutze, Wilfried Wurth, Greg L. Hura, W. Mao, Gordon E. Brown, Allen M. Orville, Peter M. Weber, H. A. Dürr, Paul H. Fuoss, C. Jacobsen, Steven A. Kivelson, Todd J. Martínez, Sashwati Roy, D. Yarotski, Reinhard Dörner, Nora Berrah, Y. Tsui, Artem Rudenko, Zahid Hussain, Jonathan P. Marangos, Hendrik Ohldag, Sebastian Doniach, Stefan Moeller, John Hill, Luke Fletcher, James P. Cryan, A. Cordones Hahn, Alan Fry, J. Lee, Geraldine McDermott, G. Kovácsová, Y. Ding, S. M. Vinko, Ilme Schlichting, Heinz Frei, Nils Huse, Philippe Wernet, Y. Lee, C. Bolme, Anton Barty, Timur Osipov, Uwe Bergmann, S. Mukamel, Hendrik Bluhm, P.A. Heimann, I. Lindau, Y. Feng, Phillip Bucksbaum, Arvinder Sandhu, James S. Fraser, M. Cargnello, Jens K. Nørskov, Paul D. Adams, Adi Natan, George N. Phillips, Z. Liu, M. Schoeffler, W. Lee, Villy Sundström, Claudiu A. Stan, A. Scholl, Hasan DeMirci, Andrea Cavalleri, Tony F. Heinz, Stephen D. Kevan, A. Reid, S. Hansen, M. Armstrong, Joachim Stöhr, Thomas P. Devereaux, Gabriella Carini, Philip R. Willmott, Paul Emma, Arianna Gleason, J. Kim, Diling Zhu, R. Schlögl, Petra Fromme, C. Kliewer, S. Southworth, Nicholas K. Sauter, Matthias Fuchs, Christoph Bostedt, Mariano Trigo, Z. Shen, Petrus H. Zwart, Markus Ilchen, Gilbert Collins, Roger Falcone, D. Sokaras, S. Miyabe, William F. Schlotter, Alexander X. Gray, T. Rasing, R. Alonso Mori, Thomas N. Rescigno, S.H. Glenzer, Robert M. Stroud, A. Aqui la, Frederico Fiuza, Robert B. Sandberg, Kelly J. Gaffney, E. J. Gamboa, A. Hexemer, A. W. van Buuren, Jan Kern, Soichi Wakatsuki, David Fritz, Jen Schneider, Justin Wark, John V. Arthur, F. Himpsel, Anders Nilsson, D. Eisenberg, J. Bargar, C. Fadley, Thorsten Weber, Patrick S. Kirchmann, J. Guo, Daniele Cocco, Philip A. Anfinrud, Matthias Frank, Mike Dunne, Aymeric Robert, P. Ho, Karol Nass, Felicie Albert, Markus Guehr, Jonathan Sobota, Daniel J. Haxton, K. Wilson, Aaron M. Lindenberg, Jan M. Rost, William McCurdy, H. Lee, Thomas P. Russell, Marius Schmidt, Joshua J. Turner, J. Ko ralek, Tor Raubenheimer, Vadim Cherezov, T. Silva, T. Egami, W. Chiu, P. Hart, Tais Gorkhover, Hirohito Ogasawara, Janos Hajdu, Gabriel Marcus, and Daniel M. Neumark
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Physics ,law ,business.industry ,X-ray ,Optoelectronics ,Laser ,business ,law.invention - Published
- 2015
20. Anatomy of the Para-Vestibular Canaliculus1
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T. Egami and I. Sando
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Vestibular system ,Vestibular aqueduct ,medicine.anatomical_structure ,Materials science ,Posterior cranial fossa ,H&E stain ,medicine ,Anatomy ,Artery - Abstract
A histologic study of the para-vestibular canaliculus (PVC), its contents, and its relationship to the vestibular aqueduct (VA), is presented. 20 normal human temporal bones were fixed in 10% formalin solution, embedded in celloidin, and sectioned horizontally at intervals of 20 micrometers. Every tenth section was stained with hematoxylin and eosin (HE) and studied under a light microscope. Three significant observations were made. First, in 80% of the specimens, two rather than one PVC were found in the area of the vestibular orifice of the VA. Second, in 70% of the specimens, the PVC was found to merge with the VA rather than to enter the posterior cranial fossa (PCF) separately. Third, in all the specimens examined, a vein was seen to traverse the entire length of the PVC. However, in 17 specimens, no artery could be identified within the PVC. In the 13 (65%) specimens in which arteries could be identified in the PVC, the arteries extended only half the length of the PVC, from the PCF to the VA. In no specimen examined could arteries be seen extending the full length of the PVC from the PCF to the vestibule.
- Published
- 2015
21. Atomic transport in amorphous metals
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T. Egami
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Condensed Matter::Soft Condensed Matter ,Metallic alloy ,Self-diffusion ,Fragility ,Amorphous metal ,Materials science ,Chemical physics ,Diffusion ,Metals and Alloys ,Condensed Matter::Disordered Systems and Neural Networks ,Local structure ,Instability ,Amorphous solid - Abstract
A novel mechanism of atomic transport in amorphous metallic alloys, or metallic glasses, is proposed based upon the fluctuations in the local structure. The proposed mechanism is very different from those in crystalline solids and from the free volume model, and is characterized by the bond-exchange action triggered by the local topological instability of the atomic environment. The implications of this mechanism on the liquid fragility and bulk metallic glass formation are discussed.
- Published
- 2002
22. The comparison of source contributions from residential coal and low-smoke fuels, using CMB modeling, in South Africa
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Johann Engelbrecht, Leon Swanepoel, John G. Watson, Judith C. Chow, and Richard T. Egami
- Subjects
Smoke ,Power station ,business.industry ,Ammonium nitrate ,Geography, Planning and Development ,Air pollution ,Environmental engineering ,Coal combustion products ,Management, Monitoring, Policy and Law ,medicine.disease_cause ,Combustion ,complex mixtures ,chemistry.chemical_compound ,chemistry ,Mining engineering ,Fly ash ,medicine ,Environmental science ,Coal ,business - Abstract
D-grade residential coal is being widely used as a fuel source for heating and cooking by most of the lower-income urban communities in South Africa. Emissions from residential coal combustion have been a major cause of elevated air pollution levels in the industrialized areas of South Africa. The adverse health effects resulting from exposure to residential coal combustion emissions have been a major public concern for many years. To address this, the Department of Minerals and Energy of South Africa conducted a macro-scale experiment in the township of Qalabotjha during the winter of 1997 to assess the technical and social benefits of combusting low-smoke fuels. This paper reports the PM2.5 and PM10 chemical mass-balance (CMB) source apportionment results from Qalabotjha during a 30-day sampling period, including a 10-day period when a large proportion of low-smoke fuels was combusted. Though emission rates of D-grade coal and low-smoke fuels may vary, their chemical abundances are too similar to be separated in CMB calculations. The source apportionment study confirmed that residential coal combustion is by far the greatest source of air pollution, accounting for 62.1% of PM2.5 and 42.6% of PM10 at the three Qalabotjha sites. Biomass burning is also a major source, accounting for 13.8% of PM2.5 and 19.9% of PM10. Fugitive dust is only significant in the coarse particle fraction, accounting for 11.3% of PM10. Contributions from secondary ammonium sulfate are three–four times greater than from ammonium nitrate, accounting for 5–6% of PM mass. Minor contributions (less than 1%) were found for power plant fly ash, motor vehicle exhaust, and agricultural lime. Average PM2.5 and PM10 mass decreased by 20 and 25%, respectively, from the D-grade coal combustion period (days 1–10) to the majority of the low-smoke fuel period (days 11–20). Relative source contribution estimates (SCE) were quite similar among the three sampling periods for PM2.5, and were quite different for PM10 during the second period when 14% higher residential coal combustion and 9% lower biomass burning source contributions were found.
- Published
- 2002
23. Speciated non-methane organic compounds emissions from food cooking in Mexico
- Author
-
José Luis Arriaga, Judith C. Chow, Elizabeth Vega, E. Reyes, John G. Watson, V. Mugica, Gabriela Sánchez, and Richard T. Egami
- Subjects
Atmospheric Science ,Waste management ,Xylene ,Butane ,Combustion ,Methane ,Propene ,chemistry.chemical_compound ,chemistry ,Propane ,Environmental chemistry ,Gas chromatography ,Benzene ,General Environmental Science - Abstract
Non-methane organic compound (NMOC) emissions from different sorts of food preparation sites, were quantified for the first time in Mexico, in order to develop emission profiles for further application in the chemical mass balance receptor model (CMB). Restaurants using charcoal grills and LP gas stoves, “tortillerias”, food frying places and rotisseries were sampled using SUMMA ® stainless-steel canisters to analyse NMOC by high-resolution gas chromatography. The results obtained show that profiles determined from food cooking processes have similarities to those found in LP gas combustion, which is the most common fuel in Mexico used for this purpose, although there were differences in the relative composition of propane and butane in both cases. This suggests that, the rates of combustion of propane and butane are different. It has also been detected that propene, a reactive olefin is produced during the combustion process. The obtained profiles of restaurants, rotisseries and fried food show an important contribution of two carbon compounds (ethane, ethylene and acetylene) that can be attributed to the complex process of grease and meat cooking. The presence of these compounds cannot be attributed to vehicular sources since the concentrations are higher than in ambient air. These were also determined from aromatic compounds such as benzene, toluene and xylene in the combustion of vegetal charcoal. The measured concentrations indicate that NMOC emissions from cooking may become an important indoor source of NMOC under crowded conditions in closed places.
- Published
- 2001
24. Reaction of NO on CeO2 and Rh/CeO2 thin films supported on α-Al2O3(0001) and YSZ(100)
- Author
-
G.S. Wong, T. Egami, R.M. Ferrizz, and John M. Vohs
- Subjects
Thermal desorption spectroscopy ,Inorganic chemistry ,Oxide ,chemistry.chemical_element ,Surfaces and Interfaces ,Condensed Matter Physics ,Surfaces, Coatings and Films ,Catalysis ,Rhodium ,chemistry.chemical_compound ,Adsorption ,chemistry ,X-ray photoelectron spectroscopy ,Materials Chemistry ,Aluminium oxide ,Physical chemistry ,Yttria-stabilized zirconia - Abstract
The adsorption and reaction of NO on ceria-based model catalysts was studied using a combination of temperature programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). Specific systems investigated included: CeO 2 (1 1 1), CeO 2 /α-Al 2 O 3 (0 0 0 1), CeO 2 /YSZ(1 0 0), Rh/α-Al 2 O 3 (0 0 0 1), Rh/CeO 2 /α-Al 2 O 3 (0 0 0 1), and Rh/CeO 2 /YSZ(1 0 0). The results of this study show that NO does not adsorb on fully oxidized CeO 2 surfaces, while on partially reduced CeO 2 surfaces NO adsorbs and dissociates. The reaction of NO on Rh supported on a ceria thin film was found to be similar to that for reaction on Rh/α-Al 2 O 3 (0 0 0 1) and Rh single crystals as long as the surface of the ceria film was fully oxidized. For Rh supported on partially reduced CeO 2 , adsorbed oxygen atoms, formed via dissociation of NO, migrated from the Rh to the ceria resulting in oxidation of the surface of the oxide film. The results of this study also demonstrate that interactions at the CeO 2 –YSZ(1 0 0) interface influence the extent of reduction of the ceria film, its thermal stability, and oxygen ion transport properties.
- Published
- 2001
25. [Untitled]
- Author
-
Leon Swanepoel, Johann Engelbrecht, Judith C. Chow, John G. Watson, and Richard T. Egami
- Subjects
business.industry ,Air pollution ,Environmental engineering ,Coal combustion products ,General Medicine ,Management, Monitoring, Policy and Law ,Particulates ,medicine.disease_cause ,complex mixtures ,Pollution ,Aerosol ,chemistry.chemical_compound ,chemistry ,Nitrate ,medicine ,Environmental science ,Coal ,Sulfate ,business ,Air quality index ,General Environmental Science - Abstract
This article presents results from the particulate monitoringcampaign conducted at Qalabotjha in South Africa during the winter of 1997. Combustion of D-grade domestic coal and low-smoke fuels were compared in a residential neighborhood to evaluate the extent of air quality improvement by switchinghousehold cooking and heating fuels.Comparisons are drawn between the gravimetric results from the two types of filter substrates (Teflon-membrane and quartz-fiber) as well as between the integrated and continuous samplers. It is demonstrated that the quartz-fiber filters reported 5 to 10% greater particulate mass than the Teflon-membrane filters, mainly due to the adsorption of organic gases onto the quartz-fiber filters. Due to heating of sampling stream to 50 °C in the TEOM continuous sampler and the high volatile content of the samples, approximately 15% of the particulate mass was lost during sampling.The USEPA 24-hr PM2.5 and PM10 National Ambient Air Quality Standards (NAAQS) of 65 μg m-3 and 150 μg m-3, respectively, were exceeded on several occasions during the 30-day field campaign. Average PMconcentrations are highest when D-grade domestic coal was used, and lowest between day 11 and day 20 of the experiment when a majority of the low-smoke fuels were phased in. Source impacts from residential coal combustion are also found to be influenced by changes in meteorology, especially wind velocity.PM2.5 and PM10 mass, elements, water-soluble cations (sodium, potassium, and ammonium), anions (chloride, nitrate, and sulfate), as well as organic and elemental carbonwere measured on 15 selected days during the field campaign. PM2.5 constituted more than 85% of PM10 at three Qalabotjha residential sites, and more than 70% of PM10 at the gradient site in the adjacent community of Villiers. Carbonaceous aerosol is by far the most abundant component, accounting for more than half of PM mass at the three Qalabotjha sites, and for more than a third of PM mass at the gradient site. Secondary aerosols such as sulfate, nitrate,and ammonium are also significant, constituting 8 to 12% of PM mass at the three Qalabotjha sites and 15 to 20% at the Villiers gradient site.
- Published
- 2001
26. Temperature programmed desorption study of the reaction of C2H4 and CO on Rh supported on α-Al2O3(0001), YSZ(100) and CeO2 thin films
- Author
-
R.M. Ferrizz, T. Egami, and John M. Vohs
- Subjects
Cerium oxide ,Materials science ,Thermal desorption spectroscopy ,Inorganic chemistry ,Oxide ,Surfaces and Interfaces ,Condensed Matter Physics ,Surfaces, Coatings and Films ,Catalysis ,chemistry.chemical_compound ,chemistry ,Materials Chemistry ,Aluminium oxide ,Cubic zirconia ,Thin film ,Yttria-stabilized zirconia - Abstract
The reaction of CO and ethylene on oxide-supported Rh particles was studied using temperature programmed desorption. The model systems investigated consisted of Rh particles on the following oxide supports: α-Al2O3(0001), yttria-stabilized zirconia (100) [YSZ(100)], CeO2 thin film on α-Al2O3(0001) and CeO2 thin film on YSZ(100). The results of this study demonstrate that both the ceria and YSZ supports are able to donate oxygen for reaction with carbon species adsorbed on the supported Rh particles. The reducibility of the ceria thin films was found to be influenced by the underlying oxide supports. Ceria films supported on YSZ(100) underwent reduction upon heating to 900 K, while those on α-Al2O3(0001) did not.
- Published
- 2000
27. Modelling PM10 aerosol data from the Qalabotjha low-smoke fuels macro-scale experiment in South Africa
- Author
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Judith C. Chow, Leon Swanepoel, John G. Watson, Johann Engelbrecht, Richard T. Egami, and M Zunckel
- Subjects
business.industry ,Ecological Modeling ,Air pollution ,Coal combustion products ,Particulates ,Combustion ,medicine.disease_cause ,Atmospheric sciences ,Aerosol ,medicine ,Environmental science ,Coal ,business ,Energy source ,Air quality index - Abstract
D-grade (i.e. poor quality) coal is widely used for household cooking and heating purposes by lower-income urban communities in South Africa. The smoke from the combustion of coal has had a severe impact on the health of society in the townships and cities. To alleviate this escalating problem, the Department of Minerals and Energy of South Africa evaluated low-smoke fuels as an alternative source of energy. The technical and social implications of such fuels were investigated in the course of the Qalabotjha Low-Smoke Fuels Macro-Scale Experiment. Three low-smoke fuels (Chartech, African Fine Carbon [AFC], and Flame Africa) were tested in Qalabotjha during the winter of 1997. This paper examines diurnal variations of PM 10 (particles with aerodynamic diameters less than 10 μm) concentrations at the clinic site in Qalabotjha. Both the fuel type and the wind were found to have an effect on the air particulate concentrations. This paper demonstrates how continuous PM 10 data together with wind measurements can be modelled. Pronounced dual-peak diurnal variations of PM 10 concentrations were found in winter’s stable atmosphere with 30-min PM 10 levels often exceeding 1000 μg/m 3 around 07:00–08:00 h in the morning and around 18:00 h in the evening. PM 10 diurnal variations coincided with surface radiation inversions and residential cooking activity, suggesting that human exposure is confined to a very localized environment. On windy days, very low PM 10 concentrations with very little to no diurnal variations were found. Much of the locally generated cooking emissions may have been diluted by dispersion and transport. An exponential model that allowed for all measured particulate concentrations to be re-calculated to ‘zero wind’ values was created to estimate the impact of D-grade coal combustion. From analysis of variance (ANOVA) calculations on the ‘zero wind’ concentrations, it is concluded that the combustion of low-smoke fuels would make a significant improvement to the air quality in Qalabotjha.
- Published
- 2000
28. High Resolution TOF Neutron Powder Diffractometer with Supermirror Guide
- Author
-
Soya Satoh, Takashi Kamiyama, Hidefumi Asano, Katsunori Mori, Katsunari Oikawa, Shuki Torii, T. Egami, Fujio Izumi, Michihiro Furusaka, and Shinji Itoh
- Subjects
Crystallography ,Materials science ,Mechanics of Materials ,Rietveld refinement ,Powder Diffractometer ,Mechanical Engineering ,High resolution ,General Materials Science ,Neutron ,Condensed Matter Physics - Published
- 2000
29. Ceria films on zirconia substrates: models for understanding oxygen-storage properties
- Author
-
R.J. Gorte, R.E Lakis, X.L Fan, T. Egami, T. Bunluesin, John M. Vohs, and E.S. Putna
- Subjects
Cerium oxide ,Lattice constant ,Materials science ,Chemical engineering ,Electron diffraction ,Mineralogy ,Cubic zirconia ,General Chemistry ,Crystallite ,Thin film ,Catalysis ,Yttria-stabilized zirconia ,Overlayer - Abstract
The oxygen-storage properties of ceria in three-way automotive catalysts are promoted and stabilized by mixing with zirconia. In the present study, this promotion was investigated using model catalysts in which ceria films were vapor deposited onto α-Al2O3, polycrystalline ZrO2, polycrystalline Y2O3-stabilized ZrO2 (YSZ), and YSZ(1 0 0), (1 1 1), and (1 1 0) single crystals. Following deposition of Pd, both TPD of CO and steady-state CO-oxidation kinetics suggest that the ceria films on the zirconia-based substrates were much more easily reduced than films on α-Al2O3. Polycrystalline zirconia and YSZ and the YSZ single crystals were equally effective in promoting ceria reducibility. Structural studies of ceria on YSZ(1 0 0), using both TEM and EDSXD (energy-dispersive, surface X-ray diffraction), demonstrate that ceria forms ordered overlayers on YSZ(1 0 0), oriented with respect to the YSZ surface. The lattice parameter for ceria is decreased by only 0.6% compared to bulk CeO2, but the coherence length suggests that the overlayer may have a high defect density. It is suggested that the structure-directing properties of zirconia are responsible for the enhanced properties of ceria–zirconia mixed oxides.
- Published
- 1999
30. [Untitled]
- Author
-
T. Egami, John M. Vohs, and R.M. Ferrizz
- Subjects
Ethylene ,Chemistry ,Inorganic chemistry ,chemistry.chemical_element ,General Chemistry ,Heterogeneous catalysis ,Oxygen ,Catalysis ,Rhodium ,chemistry.chemical_compound ,Transition metal ,Cubic zirconia ,Dehydrogenation - Abstract
The reaction of ethylene on a model automotive emissions control catalyst consisting of Rh particles on an epitaxial ceria film grown on the (100) surface of an yttria‐stabilized zirconia single crystal was studied using TPD. The TPD results showed that ethylene undergoes dehydrogenation on the model catalyst at temperatures below 500 K depositing carbon on the Rh particles. Surface carbon formed in this manner was oxidized to CO upon heating to above 550 K using oxygen supplied by the ceria lattice. Heating to 900 K was found to induce reduction of the ceria film resulting in a marked decrease in oxidation activity.
- Published
- 1999
31. Atomic Structure of PbZrO3 Determined by Pulsed Neutron Diffraction
- Author
-
S. Teslic and T. Egami
- Subjects
Diffraction ,Crystallography ,Distribution function ,Chemistry ,Rietveld refinement ,Superlattice ,Phase (matter) ,Neutron diffraction ,Pair distribution function ,General Medicine ,Crystal structure ,General Biochemistry, Genetics and Molecular Biology - Abstract
The atomic structure of lead zirconate, PbZrO3 (PZ), was studied using Rietveld refinement and atomic pair distribution function analysis of pulsed neutron powder diffraction data for the antiferroelectric, intermediate and paraelectric phases. The symmetry of PZ at T = 20 K in the antiferroelectric phase was determined to be Pbam. The structure was characterized by distortions of the ZrO6 octahedra which are smaller than in previous studies. Locally correlated displacements of Pb in the c direction develop with increasing temperature. The average magnitude was 0.06 Å at room temperature, 0.14 Å at T = 473 K and 0.20 Å in the intermediate phase at T = 508 K. The intermediate phase was characterized by in-plane antiferroelectric Pb displacements which produce 1\over 2{110} superlattice diffraction peaks. Above 473 K the local structure of PZ remains largely unchanged, in spite of the transitions in the long-range order from the antiferroelectric to the intermediate and to the paraelectric phases.
- Published
- 1998
32. Spatial and temporal variations of particulate precursor gases and photochemical reaction products during SJVAQS/AUSPEX ozone episodes
- Author
-
Paul A. Solomon, Douglas H. Lowenthal, Richard T. Egami, Karen L. Magliano, Judith C. Chow, A. J. Ranzieri, Richard H. Thuillier, and John G. Watson
- Subjects
Peroxyacetyl nitrate ,Atmospheric Science ,chemistry.chemical_compound ,Ozone ,Nitrate ,Chemistry ,Nitric acid ,Particulates ,San Joaquin ,Photochemistry ,Sulfur dioxide ,NOx ,General Environmental Science - Abstract
SJVAQS/AUSPEX acquired PM2.5, PM10, and gas samples at ten sites in central California during five ozone episodes over a period of 14 intensive sampling days. Four sample sets per day were collected for 5-and 7-hour durations during this period and analyzed for particulate mass, elements, ions, and organic and elemental carbon (OC and EC). Gaseous ammonia, nitric acid, and sulfur dioxide were collected with absorbing filters. Ozone (O3), nitrogen oxides (NOx), and peroxyacetyl nitrate (PAN) were measured continuously. Concentrations varied by sampling site, time of the day, and ozone episode. The highest concentrations of most chemical species were found at sites in the southern San Joaquin Valley. Nitrate occurred mainly in the gas phase during the daytime when temperatures exceeded 25°C, and in the particulate phase during the nighttime when temperatures decreased to less than 10°C. Significant amounts of nitrate volatilized from particles collected on quartz-fiber filters. Diurnal patterns of ozone, nitrogen oxides, PAN, nitric acid, and total particle nitrate were similar at most of the sites, which were separated by hundreds of kilometers, showing evidence of both photochemical conversion and transport of polluted air masses.
- Published
- 1998
33. Electron-lattice interaction in cuprates
- Author
-
T. Egami
- Subjects
Physics ,Superconductivity ,Condensed matter physics ,Hubbard model ,Electron ,Condensed Matter Physics ,Atomic and Molecular Physics, and Optics ,Inelastic neutron scattering ,Lattice (order) ,Condensed Matter::Strongly Correlated Electrons ,General Materials Science ,Neutron ,Cuprate ,Charge carrier - Abstract
Experimental studies of local structure by pulsed neutron PDF analysis on manganites and cuprates suggest that these oxides are locally distorted due to a strong electron-lattice interaction, and charge carriers organize themselves most likely into a tweed-like state. Measurements by inelastic neutron scattering as well as calculations on the Hubbard model show that the electron-lattice interaction is strongest at the zone boundaries, enhanced by phonon-induced spin-correlations. Such a strong electron-lattice interaction must be the origin of these local distortions, and may form the basis for the microscopic mechanism of superconductivity.
- Published
- 1996
34. Real Time Virtual Desired Signal Design and Its Application
- Author
-
T. Egami and Takeshi Tsuchiya
- Subjects
Model predictive control ,Engineering ,State variable ,business.industry ,Control theory ,Control system ,Feed forward ,Control engineering ,Air traffic control ,Linear motor ,business ,Optimal control ,Signal - Abstract
A real time virtual desired signal design method for the control system which has already designed is proposed in this paper. The virtual desired signal is introduced to improve the tracking performance for the real desired signal. Points of the proposed design method are real time design and consideration on the designed control characteristics. Those are realized by feedback of the state variables of the control system which has already been designed and by feedforward from the real desired signal. In addition to the basic method, the design method with consideration on the preview action is proposed. An optimal control system with this real time virtual desired signal is designed and it is applied to an air slide linear dc brushless motor. Some experimental studies are carried out for confirming the effectiveness.
- Published
- 1996
35. Domain Nucleation and Wall Velocity in Magneto-Optical Amorphous Thin Films
- Author
-
T. Egami, M. Hirscher, and Ernesto E. Marinero
- Subjects
Kerr effect ,Magnetic domain ,Condensed matter physics ,Chemistry ,business.industry ,Nucleation ,Coercivity ,Condensed Matter Physics ,Electronic, Optical and Magnetic Materials ,Amorphous solid ,Magnetization ,Optics ,Domain wall (magnetism) ,Thin film ,business - Abstract
Domain nucleation and growth kinetics were investigated in sputter-deposited amorphous thin films of Tb 20.2 Fe 67.8 Co 12.0 . After magnetically saturating the films, a reverse external field was applied and the specimens were pulse-heated by an excimer laser. During this heat treatment the reversal of the magnetization was observed in-situ using the magneto-optical Kerr effect. In addition the domain nucleation was studied using a polarizing microscope. Combining the nucleation and magnetization reversal measurements the domain wall velocity was determined as a function of temperature at three different applied external fields. The results are discussed with reference to existing models for domain wall motion.
- Published
- 1996
36. Structure of oxide overlayer studied by energy dispersive X-ray diffraction
- Author
-
W. Dmowski, R.J. Gorte, T. Egami, and John M. Vohs
- Subjects
Diffraction ,Materials science ,Scattering ,business.industry ,chemistry.chemical_element ,Yttrium ,Condensed Matter Physics ,Epitaxy ,Molecular physics ,Electronic, Optical and Magnetic Materials ,Overlayer ,Condensed Matter::Materials Science ,Lattice constant ,Optics ,chemistry ,Cubic zirconia ,Electrical and Electronic Engineering ,Energy-dispersive X-ray diffraction ,business - Abstract
The atomic structure of CeO2 overlayers on the (001) surface of cubic Yttrium stabilized zirconia was studied by energy-dispersive surface X-ray diffraction. It is shown that the CeO2 layers form epitaxial islands with 5–15 monolayers in thickness with a nearly relaxed lattice constant. The results demonstrate that the energy-dispersive surface X-ray scattering is a powerful tool in certain cases of surface structural studies.
- Published
- 1996
37. Reformist and Conservative Divide in Postwar Okinawan Politics
- Author
-
T. Egami
- Subjects
Politics ,History ,Gender studies - Published
- 1996
38. Short and intermediate range structural and chemical order in the relaxor ferroelectric lead magnesium niobate
- Author
-
T. Egami and H. D. Rosenfeld
- Subjects
Materials science ,Condensed matter physics ,Lead magnesium niobate ,Condensed Matter Physics ,Synchrotron ,Electronic, Optical and Magnetic Materials ,law.invention ,Condensed Matter::Materials Science ,Electron diffraction ,law ,Lattice (order) ,Neutron ,High-resolution transmission electron microscopy ,Powder diffraction ,Relaxor ferroelectric - Abstract
We have obtained a model of short and intermediate range atomic structure in the relaxor ferroelectric Pb(Mg1/3,Nb2/3)O3 (PMN) by pair-density function (PDF) analysis of pulsed neutron and synchrotron x-ray powder diffraction data. All atomic species are found to be displaced from their ideal cubic perovskite lattice sites in a manner consistent with an eight site crystallographic disorder model. Use of the pair-density function in analyzing the structure of PMN has allowed short and intermediate range displacement correlations to be explored. Our structural model shows strong local displacement correlations resulting in two structurally distinct regions. Here we show that this model is in agreement with observed electron diffraction patterns and high resolution transmission electron microscopy images, and examine how it may be used in interpreting them. Differences in the local structure of the two regions may be important in explaining the relaxor behavior.
- Published
- 1995
39. Local Atomic Structure and Morphotropic Phase Boundary
- Author
-
T. Egami and W. Dmowski
- Subjects
Phase boundary ,Phase transition ,Materials science ,Condensed matter physics - Published
- 2012
40. A laboratory resuspension chamber to measure fugitive dust size distributions and chemical compositions
- Author
-
Richard T. Egami, C. Fred Rogers, James E. Houck, Lyle C. Pritchett, Judith C. Chow, John G. Watson, Clifton A. Frazier, and Bridget M. Ball
- Subjects
Atmospheric Science ,Chemistry ,Ion chromatography ,Rectangular array ,Mineralogy ,Filter (aquarium) ,Optical reflection ,law.invention ,Chemical species ,law ,Thermal ,Gravimetric analysis ,Atomic absorption spectroscopy ,General Environmental Science - Abstract
A laboratory resuspension chamber is described that segregates dried and sieved geological material into size fractions less than 0, 1.0, 2.5, 10 and ∼30 gmm aerodynamic diameters onto filter media suitable for chemical analysis. Eight impactor inlets located in a rectangular array within a 0.4 m 3 chamber provide the size segregation. Tests show that mass concentrations across the array vary by no more than ± 10%. Filter samples are normally submitted to gravimetric, X-ray fluorescence, ion chromatography, automated colorimetric, atomic absorption spectrophotometric, and thermal/optical reflection analysis for ∼ 50 chemical species. Chemical profiles and size distribution have been measured on more than 200 dust samples throughout the world.
- Published
- 1994
41. A model of short and intermediate range atomic structure in the relaxor ferroelectric Pb(Mg1/3, Nb2/3)O3
- Author
-
H. D. Rosenfeld and T. Egami
- Subjects
Phase transition ,Range (particle radiation) ,Materials science ,Condensed matter physics ,Electron diffraction ,Condensed Matter Physics ,Ferroelectricity ,Electronic, Optical and Magnetic Materials ,Relaxor ferroelectric ,Perovskite (structure) - Abstract
Relaxor ferroelectrics are a particularly interesting and technologically important subset of the perovskite family of ferroelectrics. Ferroelectric relaxors undergo a diffuse paraelectric-ferroelectric phase transition, the origin of which is not well understood. An understanding of the microscopic origin of this behavior may lead to a more systematic approach to the development of materials with applications-tailored properties and may provide important insight into the phenomenon of ferroelectricity in general. Recently we reported a model of local atomic structure in the relaxor ferroelectric Pb(Mg1/3, Nb2/3)O3 1. Here we present refinements to that model, and simulated electron diffraction images based upon this model.
- Published
- 1994
42. Extended phonon collapse and the origin of the charge-density wave in 2H-NbSe2
- Author
-
F, Weber, S, Rosenkranz, J-P, Castellan, R, Osborn, R, Hott, R, Heid, K-P, Bohnen, T, Egami, A H, Said, and D, Reznik
- Abstract
We report inelastic x-ray scattering measurements of the temperature dependence of phonon dispersion in the prototypical charge-density-wave (CDW) compound 2H-NbSe2. Surprisingly, acoustic phonons soften to zero frequency and become overdamped over an extended region around the CDW wave vector. This extended phonon collapse is dramatically different from the sharp cusp in the phonon dispersion expected from Fermi surface nesting. Instead, our experiments, combined with ab initio calculations, show that it is the wave vector dependence of the electron-phonon coupling that drives the CDW formation in 2H-NbSe2 and determines its periodicity. This mechanism explains the so far enigmatic behavior of CDW in 2H-NbSe2 and may provide a new approach to other strongly correlated systems where electron-phonon coupling is important.
- Published
- 2011
43. Disturbance Suppression Control with Preview Action of Linear DC Brushless Motor
- Author
-
T. Egami and Takeshi Tsuchiya
- Subjects
Engineering ,Disturbance (geology) ,business.industry ,Control theory ,Control system ,Control engineering ,business ,DC motor ,Signal ,Action (physics) ,Inner loop ,Compensation (engineering) ,Group delay and phase delay - Abstract
This paper proposes a disturbance suppression control with preview action for brushless & coreless type linear DC motor (LDM). Brushless & coreless type linear DC motor is coggingless and has long life. It is suitable for high speed and precise positioning control. Parameter variation and load change are regarded as equivalent disturbance signal and the compensation action is applied by utilizing the estimated value of the equivalent disturbance in the inner loop. Next, optimal preview control system is synthesized including the disturbance suppression control system mentioned above. Disturbance suppression, improving of phase delay and lowing of input peak value are attained in this control system for LDM. Experimental studies applied to LDM and linear X-Y table made by LDM are shown and these effects are also confirmed.
- Published
- 1993
44. Decoupled Preview Control System and its Application to Induction Motor Drive
- Author
-
Takeshi Tsuchiya, Akihiko Matsushita, and T. Egami
- Subjects
Engineering ,Vector control ,Quadratic equation ,Relation (database) ,Property (programming) ,business.industry ,Control theory ,Control system ,Control (management) ,Control engineering ,business ,Induction motor ,Weighting - Abstract
This paper shows that optimal preview control system approaches to a decoupled preview control system as weighting (actors for control input variables in quadratic performance index tends to zero. By this property, relation between design parameters and response of optimal preview control system becomes clear. The decoupled preview control method is applied to vector control system for induction motor drive. By this application, trade off between conditions of vector control and the magnitude of input variables becomes easy.
- Published
- 1993
45. Preview Control of Wheeled Vehicle
- Author
-
T. Egami, D. Xiang, and Takeshi Tsuchiya
- Subjects
Engineering ,business.industry ,Control theory ,Feedback control ,Control (management) ,Feed forward ,Vibration control ,Control engineering ,Terrain ,business ,Control methods ,Position control ,Compensation (engineering) - Abstract
This paper deals with vibration control of a wheeled vehicle running over an irregular terrain. The following four control metheds mainly utilizing future terrain information are considered. (1) Whole preview control methed utilizing present and future terrain information; (2) Partial preview control method utilizing present (all wheel's) and future (only rear wheel's) terrain information; (3) Feedforward compensation control methed utilizing only present terrain information; (4) Feedback control methed utilizing no future terrain information. In the simulation studies, it is shown that position control and vibration control are much improved by utilizing future terrain information.
- Published
- 1993
46. Many-body potentials for Cu-Ti intermetallic alloys and a molecular dynamics study of vitrification and amorphization
- Author
-
Mojmír Šob, Graeme J. Ackland, D.T. Kulp, Vaclav Vitek, and T Egami
- Subjects
Bulk modulus ,Materials science ,Ab initio ,Intermetallic ,Thermodynamics ,Crystal structure ,Condensed Matter Physics ,Enthalpy of mixing ,Computer Science Applications ,Crystallography ,Tetragonal crystal system ,Molecular dynamics ,Mechanics of Materials ,Modeling and Simulation ,General Materials Science ,Glass transition - Abstract
The authors present central force many-body potentials for the Cu-Ti system which were constructed so as to reproduce a number of properties of the CuTi2 compound (tetragonal structure). The authors fitted the potentials not only to the available experimental data (equilibrium lattice parameters and enthalpy of mixing) but employed an ab initio method to determine additional data, in particular the bulk modulus. It is shown that these potentials ensure the stability of the CuTi2 crystal structure against alternate structures and changes in the c/a ratio and closely reproduce the melting temperature of CuTi2. The authors then employ these potentials in simulations of the glass transition and amorphization by irradiation and use the concept of atomic level stresses to interpret the results.
- Published
- 1993
47. Spinor and Twistor Formulations of Tensionless Bosonic Strings in Four Dimensions
- Author
-
S. Deguchi, T. Egami, and J.-i. Note
- Subjects
Physics ,High Energy Physics - Theory ,Spinor ,Physics and Astronomy (miscellaneous) ,FOS: Physical sciences ,Mathematical Physics (math-ph) ,String (physics) ,Action (physics) ,Twistor theory ,General Relativity and Quantum Cosmology ,High Energy Physics::Theory ,High Energy Physics - Theory (hep-th) ,Simple (abstract algebra) ,Minkowski space ,Homogeneous space ,Mathematics::Differential Geometry ,Mathematical Physics ,Mathematical physics - Abstract
Spinor and twistor formulations of tensionless bosonic strings in 4-dimensional Minkowski space are constructed. We begin with a first-order action that is equivalent to the Nambu-Goto action in the tensionful case and that leads to a spinorial action in the tensionless case. From this spinorial action, we find an alternative spinorial action useful for constructing a simple twistor formulation of tensionless strings. The twistor formulation is steadily constructed in accordance with a fundamental concept of twistor theory. We investigate local internal symmetries inherent in the twistorial action for a tensionless string and carry out some classical analyses of the tensionless string expressed in a twistorial form., Comment: 30 pages, no figures, minor corrections, a footnote added, published version
- Published
- 2010
- Full Text
- View/download PDF
48. The effect of salt concentration on the local atomic structure and conductivity of PEO-based NiBr2 electrolytes
- Author
-
H. Cai, Gregory C. Farrington, R. Hu, and T. Egami
- Subjects
chemistry.chemical_classification ,Ethylene oxide ,Chemistry ,Inorganic chemistry ,technology, industry, and agriculture ,Analytical chemistry ,Salt (chemistry) ,macromolecular substances ,General Chemistry ,Electrolyte ,Conductivity ,Condensed Matter Physics ,chemistry.chemical_compound ,Differential scanning calorimetry ,Phase (matter) ,Ionic conductivity ,General Materials Science ,Powder diffraction - Abstract
High molecular weight poly (ethylene oxide) (PEO) ( MW = 5 × 10 6 ) based NiBr 2 electrolytes of compositions, NiBr 2 (PEO) n , n = 2, 4, 8, 16, 32, 100, where n is the number of oxygen per Ni(II) ion, were prepared by solution casting. An unusually high oxygen/metal ratio of 2 could be achieved with NiBr 2 salt. X-ray powder diffraction study and pair distribution function (PDF) analysis indicate that no crystalline PEO-salt complex phase exists until n ≤16. At low salt concentration ( n > 16), the electrolyte consists of two components: amorphous PEO containing dissolved salt and crystalline PEO in which salt ions may exist as imperfections. The interchain correlation of PEO is virtually unaffected by dilute concentrations of salt. With increasing salt concentration, a new PEO-salt crystalline complex starts to form and the interchain correlation of PEO is drastically increased. These results are consistent with those obtained from differential scanning calorimetry (DSC) analysis and show a possible correlation between changes in local atomic structure and ionic conductivity.
- Published
- 1992
49. Role of local polarizations in superconductivity of hightcoxides
- Author
-
T. Egami
- Subjects
Superconductivity ,High-temperature superconductivity ,Materials science ,Condensed matter physics ,Neutron scattering ,Condensed Matter Physics ,Polarization (waves) ,Ferroelectricity ,Instability ,Electronic, Optical and Magnetic Materials ,law.invention ,Condensed Matter::Materials Science ,law ,Condensed Matter::Superconductivity ,Antiferroelectricity ,Cuprate - Abstract
The significance of a structural instability against ferroelectric or antiferroelectric polarization for the high temperature superconductivity in cuprates and bismuthates has long been recognized. Such polarizations on the local scale have indeed been suggested in a number of oxide superconductors by pulsed neutron scattering. We discuss the possible roles these local polarizations could play in producing the high temperature superconductivity in these oxides.
- Published
- 1992
50. Local intermolecular correlations inC60
- Author
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J. S. Lannin, T. Egami, Ruizhong Hu, and Fang Li
- Subjects
Orientation (vector space) ,chemistry.chemical_compound ,Buckminsterfullerene ,Distribution function ,Materials science ,chemistry ,Chemical physics ,Neutron diffraction ,Intermolecular force ,Molecule ,Pair distribution function ,Crystal structure - Abstract
A neutron-powder-diffraction real-space structural refinement method is applied to study the local intermolecular correlations in bulk C{sub 60} solid at 10 K. We found that the orientation of the C{sub 60} molecules often deviates locally from the long-range average structure, and a significant number (30--40 %) of molecules have the sixfold face oriented toward adjacent molecules.
- Published
- 1992
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