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Nitrogen dioxide (NO2) is a short-lived atmospheric pollutant that serves as an air quality indicator and is itself a health concern. The Airborne Compact Atmospheric Mapper (ACAM) was flown on board the NASA UC-12 aircraft during the Deriving Information on Surface Conditions from Column and Vertically Resolved Observations Relevant to Air Quality Maryland field campaign in July 2011. The instrument collected hyperspectral remote sensing measurements in the 304-910 nm range, allowing daytime observations of several tropospheric pollutants, including nitrogen dioxide (NO2), at an unprecedented spatial resolution of 1.5 × 1.1 sq. km. Retrievals of slant column abundance are based on the differential optical absorption spectroscopy method. For the air mass factor computations needed to convert these retrievals to vertical column abundance, we include high-resolution information for the surface reflectivity by using bidirectional reflectance distribution function data from the Moderate Resolution Imaging Spectroradiometer. We use high-resolution simulated vertical distributions of NO2 from the Community Multiscale Air Quality and Global Modeling Initiative models to account for the temporal variation in atmospheric NO2 to retrieve middle and lower tropospheric NO2 columns (NO2 below the aircraft). We compare NO2 derived from ACAM measurements with in situ observations from NASA's P-3B research aircraft, total column observations from the ground-based Pandora spectrometers, and tropospheric column observations from the space-based Ozone Monitoring Instrument. The high-resolution ACAM measurements not only give new insights into our understanding of atmospheric composition and chemistry through observation of subsampling variability in typical satellite and model resolutions, but they also provide opportunities for testing algorithm improvements for forthcoming geostationary air quality missions.

Observations show that the cooling of global stratospheric temperatures from 1979 to 2015 took place in two major steps coincident with the 1982 El Chichon and 1991 Mount Pinatubo eruptions. In order to attribute the features of the global stratospheric temperature time series to the main forcing agents, we performed a set of simulations with the NASA Goddard Earth Observing System Chemistry Climate Model. Our results show that the characteristic step-like behavior is to be attributed to the effects of the solar cycle, except for the post-1995 flattening of the lower stratospheric temperatures, where the decrease in ozone depleting substances due to the Montreal Protocol slowed ozone depletion and therefore also the cooling of the stratosphere. Volcanic eruptions also caused a significant warming of the stratosphere after 1995. The observed general cooling is mainly caused by increasing ozone depleting substances in the lower stratosphere, and greenhouse gases in the middle and upper stratosphere.

Nitrogen oxides (NOx =NO+NO2) are important atmospheric trace constituents that impact tropospheric air pollution chemistry and air quality. We have developed a new NASA algorithm for the retrieval of stratospheric and tropospheric NO2 vertical column densities using measurements from the nadir-viewing Ozone Monitoring Instrument (OMI) on NASA's Aura satellite. The new products rely on an improved approach to stratospheric NO2 column estimation and stratosphere-troposphere separation and a new monthly NO2 climatology based on the NASA Global Modeling Initiative chemistry-transport model. The retrieval does not rely on daily model profiles, minimizing the influence of a priori information. We evaluate the retrieved tropospheric NO2 columns using surface in situ (e.g., AQS/EPA), ground-based (e.g., DOAS), and airborne measurements (e.g., DISCOVER-AQ). The new, improved OMI tropospheric NO2 product is available at high spatial resolution for the years 200S-present. We believe that this product is valuable for the evaluation of chemistry-transport models, examining the spatial and temporal patterns of NOx emissions, constraining top-down NOx inventories, and for the estimation of NOx lifetimes.

The 11-year solar cycle in solar spectral irradiance (SSI) inferred from measurements by the SOlar Radiation & Climate Experiment (SORCE) suggests a much larger variation in the ultraviolet than previously accepted. We present middle atmosphere ozone and temperature responses to the solar cycles in SORCE SSI and the ubiquitous Naval Research Laboratory (NRL) SSI reconstruction using the Goddard Earth Observing System chemistry-climate model (GEOS CCM). The results are largely consistent with other recent modeling studies. The modeled ozone response is positive throughout the stratosphere and lower mesosphere using the NRL SSI, while the SORCE SSI produces a response that is larger in the lower stratosphere but out of phase with respect to total solar irradiance above 45 km. The modeled responses in total ozone are similar to those derived from satellite and ground-based measurements, 3-6 Dobson Units per 100 units of 10.7-cm radio flux (F10.7) in the tropics. The peak zonal mean tropical temperature response 50 using the SORCE SSI is nearly 2 K per 100 units 3 times larger than the simulation using the NRL SSI. The GEOS CCM and the Goddard Space Flight Center (GSFC) 2-D coupled model are used to examine how the SSI solar cycle affects the atmosphere through direct solar heating and photolysis processes individually. Middle atmosphere ozone is affected almost entirely through photolysis, whereas the solar cycle in temperature is caused both through direct heating and photolysis feedbacks, processes that are mostly linearly separable. Further, the net ozone response results from the balance of ozone production at wavelengths less than 242 nm and destruction at longer wavelengths, coincidentally corresponding to the wavelength regimes of the SOLar STellar Irradiance Comparison Experiment (SOLSTICE) and Spectral Irradiance Monitor (SIM) on SORCE, respectively. A higher wavelength-resolution analysis of the spectral response could allow for a better prediction of the atmospheric response to arbitrary SSI variations.

Results for the solar heating rates in ambient air due to absorption by black-carbon (BC) containing particles and ozone are presented as calculated from airborne observations made in the tropical tropopause layer (TTL) in January-February 2006. The method uses airborne in situ observations of BC particles, ozone and actinic flux. Total BC mass is obtained along the flight track by summing the masses of individually detected BC particles in the range 90 to 600-nm volume-equivalent diameter, which includes most of the BC mass. Ozone mixing ratios and upwelling and partial downwelling solar actinic fluxes were measured concurrently with BC mass. Two estimates used for the BC wavelength-dependent absorption cross section yielded similar heating rates. For mean altitudes of 16.5, 17.5, and 18.5 km (0.5 km) in the tropics, average BC heating rates were near 0.0002 K/d. Observed BC coatings on individual particles approximately double derived BC heating rates. Ozone heating rates exceeded BC heating rates by approximately a factor of 100 on average and at least a factor of 4, suggesting that BC heating rates in this region are negligible in comparison.

A unique dataset of airborne in situ observations of HCl, O3, HNO3, H2O, CO, CO2 and CH3Cl has been made in and near the tropical tropopause layer (TTL). A total of 16 profiles across the tropopause were obtained at latitudes between 10degN and 3degs from the NASA WB-57F high-altitude aircraft flying from Costa Rica. Few in situ measurements of these gases, particularly HCl and HNO3, have been reported for the TTL. The general features of the trace gas vertical profiles are consistent with the concept of the TTL as distinct from the lower troposphere and lower stratosphere. A combination of the tracer profiles and correlations with O3 is used to show that a measurable amount of stratospheric air is mixed into this region. The HCl measurements offer an important constraint on stratospheric mixing into the TTL because once the contribution from halocarbon decomposition is quantified, the remaining HCl (>60% in this study) must have a stratospheric source. Stratospheric HCl in the TTL brings with it a proportional amount of stratospheric O3. Quantifying the sources of O3 in the TTL is important because O3 is particularly effective as a greenhouse gas in the tropopause region.

The Gas and Aerosol Measurement Sensor (GAMS) was deployed aboard the NASA DC-8 aircraft during the second SAGE III Ozone Loss and Validation Experiment (SOLVE II). GAMS acquired line-of-sight (LOS) direct solar irradiance spectra during the sunlit portions of ten science flights of the DC-8 between 12 January and 4 February 2003. Differential line-of-sight (DLOS) optical depth spectra are produced from the GAMS raw solar irradiance spectra. Then, DLOS ozone number densities are retrieved from the GAMS spectra using a multiple linear regression spectral fitting technique. Both the DLOS optical depth spectra and retrieved ozone data are compared with coincident measurements from two other solar instruments aboard the DC-8 platform to demonstrate the robustness and stability of the GAMS data. The GAMS ozone measurements are then utilized to evaluate the quality of the Wulf band ozone cross sections, a critical component of the SAGE III aerosol, water vapor, and temperature/pressure retrievals. Results suggest the ozone cross section compilation of Shettle and Anderson currently used operationally in SAGE III data processing may be in error by as much as 10-20% in theWulf bands, and their lack of reported temperature dependence is a significant deficiency. A second, more recent, cross section database compiled for the SCIAMACHY satellite mission appears to be of much better quality in the Wulf bands, but still may have errors as large as 5% near the Wulf band absorption peaks, which is slightly larger than their stated uncertainty. Additional laboratory measurements of the Wulf band cross sections should be pursued to further reduce their uncertainty and better quantify their temperature dependence.

The 14-channel NASA Ames Airborne Tracking Sunphotometer (AATS-14) measured solar-beam transmission on the NASA DC-8 during the Second SAGE III Ozone Loss and Validation Experiment (SOLVE II). This paper presents AATS-14 results for multiwavelength aerosol optical depth (AOD), including its spatial structure and comparisons to results from two satellite sensors and another DC-8 instrument. These are the Stratospheric Aerosol and Gas Experiment III (SAGE III), the Polar Ozone and Aerosol Measurement III (POAM III) and the Direct beam Irradiance Airborne Spectrometer (DIAS).

The Guara Campaign consisted of a series of sounding rockets that were launched from August to October, 1994 at a new launch facility at Alcantara, Brazil, which is within one degree of the Earth's magnetic equator. The campaign was based on focused scientific experiments designed to investigate the electrodynamics and irregularities in the ionosphere and mesosphere at the Earth's magnetic equator and to study their relationship with neutral upper atmosphere motions. In all, 13 large sounding rockets and 20 small meteorological rockets were launched as part of four different experiment groups designed to investigate: (1) the daytime equatorial electrojet, (2) very high altitude Spread-F processes, (3) sunset electrodynamics, and (4) middle atmosphere-thermosphere coupling at the equator. The instrumentation on the sounding rockets varied with each investigation, but primarily included experiments to measure electric fields, currents, plasma densities,- neutral winds, neutral densities and temperatures, and ionospheric instabilities. All of the experiments utilized ground-based scientific instruments including a VHF backscatter radar interferometer, magnetometers, ionosondes, and scintillation receivers. An overview of each investigation is provided, along with a description of the launch site and the ground-based experiments. Scientific highlights of the campaign are provided.

In August 1994, the Mesospheric and Lower Thermospheric Equatorial Dynamics (MALTED) Program was conducted from the Alcantara rocket site in northeastern Brazil as part of the International Guard Rocket Campaign to study equatorial dynamics, irregularities, and instabilities in the ionosphere. This site was selected because of its proximity to the geographic (2.3 deg S) and magnetic (approx. 0.5 deg S) equators. MALTED was concerned with planetary wave modulation of the diurnal tidal amplitude, which exhibits considerable amplitude variability at equatorial and subtropical latitudes. Our goals were to study this global modulation of the tidal motions where tidal influences on the thermal structure are maximum, to study the interaction of these tidal structures with gravity waves and turbulence at mesopause altitudes, and to gain a better understanding of dynamic influences and variability on the equatorial middle atmosphere. Four (two daytime and two nighttime) identical Nike-Orion payloads designed to investigate small-scale turbulence and irregularities were coordinated with 20 meteorological falling-sphere rockets designed to measure temperature and wind fields during a 10-day period. These in situ measurements were coordinated with observations of global-scale mesospheric motions that were provided by various ground based radars and the Upper Atmosphere Research Satellite (UARS) through the Coupling and Dynamics of Regions Equatorial (CADRE) campaign. The ground-based observatories included the Jicamarca radar observatory near Lima, Peru, and medium frequency (MF) radars in Hawaii, Christmas Island, and Adelaide. Since all four Nike-Orion flights penetrated and overflew the electrojet with apogees near 125 km, these flights provided additional information about the electrodynamics and irregularities in the equatorial ionospheric E region and may provide information on wave coupling between the mesosphere and the electrojet. Simultaneous with these flights, the CUPRI 50-MHz radar (Cornell University) provided local sounding of the electrojet region. A description of the campaign logistics and the measurements performed with the Nike-Orion instrumentation and their implications for turbulence due to gravity waves and tidal instability in the mesosphere and lower thermosphere (MLT) are presented here. From a study of electron density fluctuations measured by rocket probes, we have found evidence for equatorial mesospheric neutral-atmospheric turbulence between 85 and 90 km. Furthermore, falling-sphere data imply that gravity wave breaking was a source for this turbulence. Mean motions and the various planetary, tidal, and gravity wave structures and their coherence and variability are the subjects of a companion paper.

During the period July-August 1991, observations were made of Polar Mesospheric Summer Echoes (PMSE) at 46.9 MHz and 224 MHz by the CUPRI and EISCAT radars, respectively, at two sites in northern Scandinavia. Those observations are compared here with observations of noctilucent clouds, nergetic particle precipitation and magnetic disturbances. The appearance and morphology of PMSE are found to be closely correlated at the two frequencies and the two sites, 200 km apart. No correlation is found between PMSE and noctilucent clouds or magnetic disturbance. No correlation is found between energetic particle precipitation and the appearance of PMSE at 46.9 MHz for the whole time period. At 224 MHz, there is no evidence for a correlation before the beginning of August and only one event suggesting a possible correlation after the beginning of August. A minimum in occurrence for PMSE is found between 16 and 21 UT (17-22 LST) which may be related to an expected minimum in background wind strength in that time interval.

The mesospheric and lower thermospheric equatorial dynamics program (MALTED), conducted from the Alcantara, Brazil rocket site as part of the international Guara rocket campaign to study equatorial dynamics, irregularities, and instabilities, is reported. The MALTED program was concerned with the 16-day modulation of the diurnal tidal amplitude, which shows high extremes during August in the equatorial belt. The interaction of this global phenomenon with locally produced gravity waves and turbulence in the mesopause region is studied in order to gain a better understanding of the dynamic influences on the equatorial middle atmosphere. Four identical payloads designed to investigate small-scale turbulence and irregularities, were coordinated with 20 falling sphere rockets designed to measure meteorological parameters. The prediction and monitoring of global mesospheric effects were obtained through coordination with various ground-based radar observatories. The campaign logistics, the instrumentation, and the preliminary results are described.

At radar frequencies in the range 50 MHz to 250 MHz, at times even to over 1 GHz, strong enhancements of scattering cross section occur between approximately equal to 80 km and approximately 95 km altitude in summer at high latitudes. These echoes, termed 'Polar Mesosphere Summer Echoes' (PMSE) have attracted considerable experimental effort. Observations of this phenomenon are reviewed in the context of atmospheric dynamics and of scattering processes. Recent rocket and radar measurements indicate that a partial reflection from a multitude of ion layers and constructive interference causes at least some of the PMSE. It is discussed which further observations are necessary and some possible practical consequences of PMSE are pointed out.

VHF radar data from the Summer 1990 Equatorial Spread F campaign on Kwajalein are presented. The Cornell 50 MHz portable radar interferometer (CUPRI) operated concurrently with the Altair UHF incoherent scatter radar throughout July and August and supported two sounding rocket flights on July 30 and August 2. This experiment provided the first opportunity to simultaneously diagnose equatorial spread F using the three prime experimental techniques: VHF/UHF coherent scatter, incoherent scatter, and in situ probe measurements of electric field and density fluctuations. The intensity of the coherent echoes observed was consistent with typical Jicamarca spread F observations, but chains of periodic, large-scale plasma upwellings were observed more often and for much longer durations on Kwajalein than have been seen over Peru. CUPRI also measured Doppler frequencies in one upwelling corresponding to 1200-m/s plasma drift velocities. This measurement agrees with recent observations of supersonic drift rates at the magnetic equator by spacecraft. Near the most active localized plasma upwellings, interferometer data reveal that the zonal drift rate of plasma irregularities can vary sharply in space, as one would expect for two-dimensional incompressible flow. We introduce a semiempirical model of the three-dimensional spectrum of F region irregularities that is consistent with the one-dimensional spectra of density fluctuations observed by sounding rockets and with the axial ratio of irregularities determined recently. Normalized to data from one of the rocket flights on Kwajalein, the model predicts the 3-m scattering cross-section measured by CUPRI to within a few decibels.

Sounding rocket data from the 1990 Combined Release and Radiation Effects Satellite (CRRES)/EQUIS equatorial spread F campaign on Kwajalein Atoll are presented. Two Terrier Malamute sounding rockets were launched into active spread F conditions on July 30 and August 2, respectively, and achieved apogee slightly below 500 km, just above the F peak. Plasma frequency probes aboard both rockets showed that the unstable nighttime F region is characterized by propagating steepened structures. Power density spectra for the structures typically exhibit two regions that obey k(exp -n) scaling, where n is approximately equal to 2 at wavelengths greater than 80-100 m and approximately equal to 5 at shorter wavelengths. These spectral indices are quiet variable, and the long-wavelength spectral index in particular seems to decrease with increasing amplitude of density fluctuations. The rocket payloads also measured vector electric fields in the plane perpendicular to B over wavelengths ranging from over 60 km to less than 6 m. Both vector components of the perpendicular electric field are proportional to delta n/n at wavelengths longer than 300 m but assume a Boltzmann relationship (with square of the absolute value of delta E approximately equal to (k(exp2))(square of the absolute value of (delta n/n)) at smaller scales. The perturbed zonal electric field, delta E(sub x), dominates the vertical field, delta E(sub z), at long wavelenghts, but the situation is reversed at smaller scales.

In late July and early August of 1991, a major suborbital scientific campaign (NLC-91) involving scientists from eight countries was conducted as ESRANGE, Kiruna, Sweden and at Heiss Island, Russia. The purpose of the program was to investigate the chemical, dynamical, and electrodynamical properties of the polar summer mesosphere. Thirty one rocket flights were coordinated with two coherent radar facilities, EISCAT and CUPRI, and with other ground-based observatories and facilities. This permitted direct comparison between the in situ measurements and those obtained by remote sensing of the mesosphere via continuous ground-based monitoring. The primary objectives of the campaign were to study noctilucent clouds (NLCs) and polar mesospheric summer echoes (PMSEs), including their possible relationship to local aerosols and/or small scale turbulence. This overview describes the scientific program, discusses the geophysical conditions during launch activities, and reviews some of the preliminary results. More detailed results can be found in the papers which follow.

In the late winter of 1988 and 1989, three NASA sounding rockets were flown through the auroral electrojet from ESRANGE (Sweden) as part of the E-region Rocket-Radar Instability Study (ERRRIS). Many ground-based instruments supported these flights, including the EISCAT, STARE, and CUPRI radars, as well as all-sky cameras, riometers, and magnetometers. In this paper the observations of the Cornell University Portable Radar Interferometer (CUPRI), which detected coherent backscatter from 3-m irregularities in the auroral E-region are summarized. Twenty hours of power spectra and interferometry data are available, and, during the 1989 campaign, three weeks of nearly continuous Range-Time-Intensity (RTI) and first moment data were recorded.

The plasma instabilities in the low-attitude auroral ionosphere and the sources of free energy that drive these waves have been examined in detail in the framework of the ERRRIS project. Independent sets of experiments were carried out on board three NASA sounding rockets which were flown in conjunction with radar backscatter measurements from Esrange, Sweden, in 1988 and 1989. The backscatter measurements were taken by the 50 MHz CUPRI system for determining the launch conditions. The Eiscat incoherent scatter radar was used to take plasma drift, density, and temperature measurements on board two of the flown rockets. STARE observations of 1 m backscatter echoes were also made. The STARE velocity fields were in agreement with the Eiscat and in situ measured electric fields. Both CUPRI and STARE observed a very dynamic and changing auroral ionosphere over Esrange. It is concluded that the ERRRIS experiments provided valuable data on plasma instabilities in the auroral electrojet, including detailed in situ measurements of the two-stream wave spectrum and phase velocities.