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In the last decades, the use of Raman spectroscopy on dispersed carbonaceous material in rocks has become a promising tool for geothermometry and thermal maturity assessment. In diagenesis the main problem is linked to organofacies composition and the need of time-consuming optical classification (Henry et al., 2019, Sanders et al., 2022). In this work, three different methods of clustering analysis on Raman spectra were tested as a potential approach to recognize the three main organofacies (amorphous organic matter, translucid and opaque phytoclasts) that characterize a set of 27 organic-rich samples from the Lower Toarcian source rock interval (Schistes Carton) of the Paris Basin (France).Raman analyses were performed on concentrated organic matter obtained by acid attacks, with around 60 counts for each sample. Principal Component Analysis (PCA) was applied to reduce the dimensionality of each dataset on a 2-D score-plot. Unsupervised clustering was then performed by using three different clustering algorithms: k-means, Gaussian Mixture Models (GMM), and Density-Based Spatial Clustering for Applications with Noise (DBSCAN). The main task of these algorithms is to correctly assign the number of clusters, their size, orientation, and distribution in the score-plot that related to the heterogeneities in organofacies composition.Results show the best performances are achieved through the application of GMM clustering that can successfully determine cluster’s geometry and optimal numbers with an accuracy mostly higher than 80% for the translucid phytoclasts group, that is the target for thermal maturity assessment. This is a preliminary attempt showing promising application for unsupervised learning techniques coupled with Raman spectroscopy that could be applied in industrial routinely organic matter characterization or in the analysis of big dataset in both Earth and planetary sciences. Henry, D. G., Jarvis, I., Gillmore, G., & Stephenson, M., 2019. Raman spectroscopy as a tool to determine the thermal maturity of organic matter: Application to sedimentary, metamorphic and structural geology. Earth-Science Reviews 198, 102936.Sanders, M. M., Jubb, A. M., Hackley, P. C., & Peters, K. E., 2022. Molecular mechanisms of solid bitumen and vitrinite reflectance suppression explored using hydrous pyrolysis of artificial source rock. Organic Geochemistry 165, 104371.

The Rif belt (Northern Morocco) represents the western termination of the Maghrebides system. It is subdivided into three tectono-stratigraphic domains known as: Internal domain (i.e., Alboran domain), the Maghrebian flysch domain (i.e., the sedimentary cover of the Maghrebian Tethys) and the external domain (i.e., north African passive paleo-margin and its sedimentary infill. The Rif fold-and-thrust belt derives from the deformation of the North African passive Paleo-margin and its sedimentary infill since the onset of Africa-Eurasia convergence. The compressional setting led to the progressive closure of the Maghrebian Tethys and westward translation of the Alboran Domain and its docking onto the Northwest African rifted margin during the Late Burdigalian. However, field structural survey revealed the presence of an important Paleogene unconformity in the External domain, attesting for a deformation older than the Miocene Alpine compression.Thus, to unravel the Cenozoic history of the Rif fold-and-thrust belt and its burial paths, a regional transect NE-SW-oriented crossing the Rif fold-and-thrust belt is studied. The methodological approach consists in combining organic petrography, micro-Raman spectroscopy on organic matter, clay mineralogy and 1D thermal modelling, together with field structural data.A new paleo-thermal data set of vitrinite reflectance (Ro%), Raman micro-spectroscopy and %I in I/S mixed layers has been provided. The obtained results show a thermal jump between the Miocene deposits in the Mesorif (External Domain) and their Eocene substratum. In order to fit the paleo-thermal data, the thermal modelling indicates the erosion of about 1300-1900 m of sedimentary and/or tectonic pile before the deposition of Lower Miocene siliciclastic. The obtained results have been used to highlight a disregarded tectonic event affecting the north African paleo-margin and how it is influencing the Miocene orogenic processes.

The geological collections, hosted in the Liceo Classico Statale “E. Q. Visconti” in Rome, from the "wonders" of Jesuit Father Athanasius Kircher to the nineteenth-century collections and the present-day “Wunder Musaeum”, will be presented in this presentation. These collections represent a rich and "hidden" geological jewel preserved in the heart of Rome, made up of thousands of minerals, rocks, fossils and teaching tools, aquired through a long and fascinating story. A historical-scientific heritage that the "Geomuseum" project, developed between the geologists of the University of Roma Tre and teachers of the higher School, has made possible in order to enhance it and make it accessible to the general public and the students, for outreach and teaching purposes.

In recent decades, reconstructing the geometric and kinematic evolution of fold-and-thrust belts around the Mediterranean region has been one of the priority goals of the scientific community, also with the aim of energy resource retrieval. However, the frequent poor quality of subsurface constraints has sometimes led to the production of even very different geometric-kinematic evolutionary models, characterized by different amounts of shortening and deformation timing, with important implications on the kinematic reconstructions of the Africa-Europe convergence process. In this talk, I intend to propose a journey through a series of fold-and thrust belts around this region, that in recent years have been studied by the team of the Academic Lab of Basin Analysis or Roma Tre, in collaboration with many colleagues around the Mediterranean, through the integration of classical stratigraphic and structural data with the reconstruction of the paleo-thermal evolution of these structures. Particular attention will be paid to thermal modeling, constrained through different parameters of thermal and thermo-chronological evolution of both pre-orogenic and syn-orogenic sedimentary successions.

[The manuscript presents the first attempt to define the diagenetic conditions (burial and related paleo‐temperatures) for sulfur formation in relationship with the deposits generated by the Messinian salinit crisis. ​, Abstract Recent studies on the genesis of sedimentary native sulfur deposits indicate diagenetic mid‐low temperature Bacterial Sulfate Reduction (BSR) as the main process, involving organic compounds (kerogen/hydrocarbons), bacterial colonies and gypsiferous rocks. In the peri‐Mediterranean area (Southern Spain, Sicily, Northern Apennines, Israel), the main sulfur accumulations are always associated with late Miocene sulfates and organic‐rich successions encompassing the Messinian salinity crisis (MSC). In particular, the Messinian successions of the Apennine‐Adriatic foreland basin system, due to a large amount of high‐resolution stratigraphic data, represent a perfect case study for understanding the diagenetic conditions controlling the development of the BSR process during sedimentary basin evolution. In this work, thermal models performed in three sub‐basins in a sector of the Northern Apennines comprised of the Sillaro and Marecchia rivers (Italy), calibrated by means of organic and inorganic geothermometers, indicate a general thermal immaturity of the studied successions attained as a result of a constant heat flow similar to the present day one (ca. 40 mW/m2) since Late Tortonian and lithostatic loads between 615 and 1,710 m depending on different sub‐basins. These results suggest that the MSC deposits experienced maximum temperatures between about 39°C and 65°C. Temperatures derived from thermal models have been used to constraint occurrence of the diagenetic BSR associated with evaporitic deposits providing thermal constraints in sulfur genesis as well as new useful thermal‐constraints for basin analysis studies.]

Located in Northern Morocco, the Rif fold and-thrust belt is mainly made by the remnant of the north African paleo-passive margin and its sedimentary infill. We present in this contribution new field observations combined with paleo-thermal analysis to investigate the formation of the Rif orogenic wedge. Three structural domains are recognized from north to south, namely, the Alboran domain assigned to a meso-Mediterranean continental terrane, the Maghrebian flysch domain that corresponds to the sedimentary cover of the Maghrebian Tethys and the External domain (namely Intrarif, Mesorif and Prerif) that belongs to the former north African margin. The Rif fold and-thrust belt suffered an important Cenozoic Alpine compressional deformation starting from the Late Oligocene-Early Miocene, as a consequence of the closure of the Maghrebian Tethys and the westward translation and docking of the Alboran Domain onto the African margin.To define the evolution and geometry of thrust sheet stacking and their burial-exhumation paths, a NE-SW regional transect crossing the Maghrebian flysch and the External domains is presented and discussed. A set of 32 samples have been collected for paleo-thermal analysis. The methodological approach consists in combining petrography and Raman micro-spectroscopy on dispersed organic matter, X-ray diffraction of clay minerals and 1D thermal modelling with viable cross section reconstruction and field structural survey.The highest thermal maturity values along the section (1.00 and 1.15 Ro%) are concentrated in the Cretaceous Intrarif sub-domain (Loukkos and Tangier Intrarifain sub-units) that are structurally squeezed between the Maghrebian flysch domain and the Mesorifain sub-domain. The relationship between organic and inorganic paleo-thermal indicators plotted on Hillier diagram show a thermal signature for the Intrarifain sub-domain typical of continental rift thermal regime. The thermal evolution of the Tangier sub-unit, tectonically overlain by the Numidian-like sandstones has been modelled. The model shows a thermal jump between the two juxtaposed rock units indicating an allochthonous origin of the Numidian-like sandstones, probably detached from the Maghrebian Flysch domain. In the Mesorif sub-domain, data plots on Hillier diagram indicate a continental rift heating regime except for the Lower Miocene Zoumi siliciclastics at the top of it, cropping out between Intrarif and Mesorif sub-domains that falls in a very cold thermal regime, typical of synorogenic basins. The structural relationships between the Cenozoic Zoumi basin and its substratum (Upper Jurassic-Lower Eocene) shows an unconformity where the Paleocene-Eocene is missing, probably indicating a pre-Oligocene compressive phase.These evidences constrain the geological timing of the Rif belt structuration. According to new models, the whole external Rif deformed between the Early Langhian and Late Tortonian with the front of the chain placed at the boundary between Intrarif and Mesorif, where the Zoumi basin developed during the Late Serravallian-Early Tortonian times.

The integration of low-temperature thermochronological and thermal maturity analyses constrains the maximum temperatures experienced during burial by the sedimentary fill of the central sector of the Greater Caucasus basin and the timing of its structural inversion. Raman spectroscopy, illite percentage and stacking order in illite-smectite mixed layers, illite crystallinity index, and Rock-Eval Pyrolysis analyses indicate that the maximum paleotemperatures experienced by the Greater Caucasus basin fill increase progressively from about 100 °C in the southern foothills of the central Greater Caucasus to close to 400 °C approaching the axial zone of the orogen. Apatite fission-track and apatite and zircon (U-Th)/He analyses along the same transect yielded ZHe ages between about 137 and 5 Ma, AFT central ages between about 37 and 4 Ma, and AHe ages between about 10 and 2 Ma, with progressively younger ages approaching the axial zone of the Greater Caucasus. Statistical inverse modelling of thermochronological data, integrating thermal maturity results and all other geological and geochronological constraints available, points to episodic exhumation during structural inversion of the central Greater Caucasus basin. Such basin was first partially inverted in Late Cretaceous/Paleocene times following Northern Neotethys closure along the Sevan-Akera suture zone; renewed basin inversion occurred since Middle-Late Miocene times as a consequence of far-field compressional stress transmission from the Arabia-Eurasia hard collision along the Bitlis-Zagros suture zone. It should be emphasised that this sequence of events applies only to the central portion of the Greater Caucasus and by no means should be extended to the other parts of such a large and complex orogenic system.

The 350 km-long Adjara-Trialeti fold-and-thrust belt of southwestern Georgia is the result of the structural inversion of a continental back-arc basin developed in the Paleogene on the upper (Eurasian) plate of the northward subducting northern branch of the Neotethys. Low-temperature thermochronological data [fission-track and (U-Th)/He analyses on apatite] from sedimentary and plutonic rocks provide robust constraints on the tectonic evolution of the Adjara-Trialeti orogenic belt. Fission-track central ages range from the Middle Eocene to the Middle Miocene (46–15 Ma); helium ages are clustered in the Late Miocene-Pliocene (10–3 Ma). Time-temperature paths obtained integrating thermochronologic, stratigraphic, and radiometric data show that the volcanosedimentary basin fill of the Adjara-Trialeti back-arc basin underwent progressive burial heating prior to final cooling/exhumation in the late Middle Miocene-Pliocene. These new data show that the Adjara-Trialeti back-arc basin was inverted and developed as a fold-and-thrust belt starting at 14–10 Ma, in tune with widespread Middle-to-Late Miocene shortening and exhumation across wide areas of the Middle East, from the eastern Pontides of NE Turkey to the Lesser Caucasus in northern Armenia and NW Azerbaijan, and the Talysh and Alborz ranges in northern Iran. Such a supraregional tectonism is interpreted as a far-field effect of the Arabia-Eurasia collision along the Bitlis suture ca. 400 km to the south of the study area.

Young back-arc rift basins, because of the not yet dissipated extensional thermal signature, are prone to positive inversion following changes in the local geodynamic regime and/or far-Xeld stress transmission. Structural inversion of such basins tends to exploit and reactivate the former normal faults, particularly if the latter are favourably oriented with respect to the direction of stress transfer. The Adjara-Trialeti fold-and-thrust belt (ATFTB) of SW Georgia perfectly exempliXes this mechanism: it results from the structural inversion of a continental back-arc rift basin developed on the upper plate of the northern Neotethys slab in Paleogene times, behind the long-lived Pontides-Lesser Caucasus magmatic arc. Integration of (i) thermal maturity analyses on the former sedimentary Xll of the Adjara- Trialeti back-arc basin and (ii) low-temperature thermochronological [apatite Xssion-track (AFT) and (U-Th)/He (AHe)] analyses on both the former sedimentary Xll and syn-rift plutons provides constraints on the burial-exhumation history of the ATFTB. Maximum paleotemperatures reached by the oldest (Paleocene) rocks within the former Adjara- Trialeti basin are in the order of about 110-115°C. AFT central ages range between 46 and 15 Ma, while AHe ages cluster mainly between 10 and 3 Ma. The reconstructed maximum paleotemperatures indicate that AFT ages are only partially reset, whereas AHe ages are totally reset. Thermal modelling, integrating AFT and AHe data with independent geological constraints, clearly indicates that the Adjara-Trialeti back-arc basin was inverted starting from the Middle Miocene. This result is corroborated by several independent geological evidence, available for example in the adjacent Rioni, Kartli and Kura foreland basins and in the eastern Black Sea offshore, which all suggest a Middle-Late Miocene phase of deformation linked with the ATFTB building. Adjara-Trialeti structural inversion can be correlated with the widespread Middle-to-Late Miocene phase of shortening and exhumation registered from the eastern Pontides to the Lesser Caucasus, the Talysh and the Alborz ranges. This tectonic phase can in turn be interpreted as a far-Xeld effect of the Arabia-Eurasia collision, developed coevally along the Bitlis-Zagros suture hundreds of kilometres to the south.

We present a brand new multi-proxy dataset of thermal maturity indicators, which derive from the application of several analytical techniques on surface and subsurface sedimentary successions. The study area spans from the Greater Caucasus to the Adjara-Trialeti fold-and-thrust belt (FTB), comprising the intervening western Kura Basin, in Georgia, and represents a region of continental deformation in the hinterland of the Arabia-Eurasia collision zone. Original and published clay mineralogy, Raman spectroscopy and petrography on dispersed organic matter, and pyrolysis data are integrated for the first time in a coherent tectono-sedimentary scenario. Thermal maturity spans from the low diagenetic realm (60-80°C) in the Upper Miocene section of the Kura sedimentary fill, to the oil window in the Cretaceous to Lower Miocene successions of Adjara-Trialeti FTB, Kakheti ridge and Kura Basin (70-120°C), up to about 400°C in the Greater Caucasus core. Integration of different indicators, besides allowing the estimation of maximum burial temperatures acquired through time, enabled to draw the tectonic evolution of the area. Different maturity trends and thermal histories, coupled with structural and stratigraphic data, highlight that the study area comprises two domains derived from positive tectonic inversion: the E-W Adjara-Trialeti doubly-verging FTB from an Eocene back-arc rift basin and the SSW-verging Georgian Greater Caucasus from a Mesozoic rift basin. Between the two, thin-skinned south-verging thrusts deform the Kura Basin and the Kakheti ridge successions, originally deposited on an extensional structural high which was later flexured during compression. The similar thermal maturity degree in the Adjara-Trialeti FTB and the Kakheti ridge/Kura Basin areas has been acquired in different time spans: during Paleogene extension and during Miocene thin-skinned shortening, respectively. The results indicate that thermal maturation of the sedimentary successions in the Adjara-Trialeti FTB can be ascribed to burial during rift evolution. The same conclusion can be drawn for the axial zone of the Greater Caucasus, whereas tectonic overburden may have contributed to the thermal maturity of the rocks in the southern foothills of the Greater Caucasus: this area needs further work to assess its tectonic evolution.

Raman spectral shifts of carbonaceous materials arising from faulted rocks produce varied and complex results. By analyzing faulted and adjacent non-faulted samples from three discrete localities in France, Italy, and Morocco, we assess changes in specific Raman parameters, including G-peak width, G-peak position, and peak intensity ratios. We consistently observe a shift in Raman parameters between faulted and non-faulted samples; however, the direction and magnitude of this shift varies. Raman peak intensity ratios are shown to both increase and decrease on fault planes. The majority of samples exhibit decreasing peak width and peak position in the faulted samples, but this is not consistent; in two samples an increase is observed, but the shift tends to be small. These data are compared to published Raman spectral shifts from experimental fault data. Our results suggest that fault zone deformation processes may measurably change the carbon nanostructure in faulted rocks. The inconsistent nature of Raman spectral shifts in the fault rock samples analyzed, and those published suggest that a complex set of factors control carbon nanostructure changes in fault rocks. These factors, although not discriminated here, likely include, background temperature, frictional heating, strain, carbonaceous material type, amongst others. We have shown that Raman Spectral shifts occur in faulted rocks with implications for how Raman data are used to predict maximum temperatures in faulted sedimentary rocks. We recognize the potential for a range of fault zone processes to modify Raman spectral shifts, however, systematic sampling across individual fault zones is critical.

A compilation of new and previously published vitrinite reflectance (R0) data from Carboniferous coals constitutes the most comprehensive map of reflectance across Great Britain. Values of R0 range from 0.38 to 3.29%, recording an ambient thermal maturity in the early oil window (standard reference point for reflectance studies), modified by elevated heat flow in northern England and along the Variscan orogenic front. The map provides a context for other geological datasets. Supplementary material: A statistical summary of vitrinite reflectance data is available at https://doi.org/10.6084/m9.figshare.c.4529969

International audience; Thirteen seismic reflection profiles and field observations have been used to build a three-dimensional watertight geological model of the sub-surface architecture of the Trapanese carbonate platform unit of the Apennine-Maghrebian chain in the Mt. Kumeta and Mt. Rocca Busambra (NW Sicily, Italy). Either a single step or a two-step thrust-fault deformation model is acceptable on the basis of seismic interpretation but the integration of 3D model reconstruction and 3D geomechanical restoration, validates only the scenario with a single stage of deformation.The 3D model highlights along strike variations of the structural style for the Trapanese unit where pre-existing discontinuities (e.g. inherited Mesozoic normal faults) played an important role in the preferential occurrence of hinterland verging structures. In detail, backthrusts (N-verging) are dissected by tear faults along the Mt. Kumeta structure whereas an imbricate backthrust system evolves into thrust along the Mt. Rocca Busambra structure. Shortening estimate indicates low amount of internal deformation affecting the carbonate platform unit (

Belonging to the Maghrebides system, the Rif belt (Northern Morocco) suffered an important Cenozoic Alpine compressional deformation as a consequence of the closure of the Maghrebian Tethys and the westward translation and docking of the Alboran Domain onto the African margin during the Late Burdigalian. The Mesozoic North African Margin is still partially preserved in the Eastern Rif (e.g., Senhadja Jurassic-Cretaceous unit) and inverted in its Central portion (North of the Nekor Fault Zone) due to the high shortening in this area. It is in agreement with sub-surface data suggesting that the thickest crust along the chain is located in the central Rif (Izzaren Area, External Rif), and can be interpreted as a deep-rooted crustal imbrication.This contribution aims to characterize the role of the structural inheritance of the rifted North African margin in the development and the propagation of the Rif belt by the combination of paleothermal and structural data collected along a NE-SW regional transect (between Chefchaouen and Ouezzane provinces), focusing mainly on the external zones (namely, Intrarif, Mesorif and Prerif) sampling the deformed domains originally developed along the North African paleo-passive margin. A new paleo-thermal dataset of vitrinite reflectance (Ro%), micro-Raman spectroscopy on organic matter and XRD on clayey fraction of sediments displays levels of thermal maturity between early and deep diagenetic conditions (Ro% from 0.49% to 1.15%). The highest thermal maturity values along the section are concentrated in the Lower to middle Cretaceous Loukkos Intrarifain sub-unit that is structurally squeezed between Tangier Intrarif Upper Cretaceous sub-unit and the Mesorif “Izzaren Duplex”. It attests for an important amount of shortening leading to the development of an imbricate fan of thrusts.The geometry of the “Izzaren Duplex”, limited at surface by two first-order thrust faults, is controlled by pre-existing tectonic structures, probably inherited by the former architecture of the North African paleomargin. Moreover, the Chattian-Middle Miocene siliciclastic succession filling the Zoumi basin is in a stratigraphic continuity with the Izzaren Upper Jurassic-Upper Cretaceous substratum, sheding new light on its geodynamic meaning. This observation is supported by the homogeneity of deformation and the absence of thermal jump between the Mesozoic and Cenozoic successions, attesting for an active compressive deformation in the area between the Late Serravalian and Late Tortonian.In conclusion, the combination of paleo-thermal and structural analysis allowed to reconstruct robust tectono-thermal model in order to propose an accurate reconstruction of the structural evolution and a new geological restoration of the Rif belt with respect to the geometry of the rifted paleo-margin.

The correct assessment of maximum temperatures experienced by rocks is an essential tool to unravel the evolution of the thermal structure of the crust during the main phases of an orogenesis. Given to broad P-T stability field of classical metamorphic mineralogical indicators, maximum temperatures derived from the analyses of carbonaceous material dispersed in rocks by means of Raman spectroscopy has shown to be a suitable alternative to classical geothermometer. Initially developed for high metamorphic rocks the use of this tools has recently been extended also at lower metamorphic degree and diagenesis. This allowed us to extend the analyses of paleotemperatures experienced by rocks from Ghomarides and Sebtides from the Internal Rif in North Morocco with respect to previous works. Ghomaride and Sebtides in this portion of the Rif-Betic-Tell chain, represent respectively the upper and lower plates of a metamorphic core complex and are composed, the first, by Paleozoic rocks with a partially preserved Mesozoic-Cenozoic cover and the second by lower Paleozoic to Triassic deep-crustal mica-schists, migmatites and granulites associated with peridotites (Beni Bousera complex).Our data suggest that the uppermost Tiszgarine Unit of the Upper Sebtides experienced warmer condition than previously observed. Moreover, we calculate the maximum temperatures experienced by the Ghomarides during both the Eo and Late Variscan cycles showing that differences in temperature exist among the vary units that compose the complex. Finally, in the southern area our data suggest a less severe alpine heating related to the emplacement of the Beni Bousera peridotite, than previously calculated.

Young back-arc rift basins, because of the not yet dissipated extensional thermal signature, can be easily inverted following changes in the geodynamic regime and/or far-field stress transmission. Structural inversion of such basins mainly develops through reactivation of normal faults, particularly if the latter are favourably oriented with respect to the direction of stress transfer. The Adjara-Trialeti fold-and-thrust belt of SW Georgia is an example of this mechanism, resulting from the structural inversion of a continental back-arc rift basin developed on the upper plate of the northern Neotethys slab in Paleogene times, behind the Pontides-Lesser Caucasus magmatic arc. New low-temperature thermochronological data [apatite fission-track (AFT) and (U-Th)/He (AHe) analyses] were obtained from a number of samples, collected across the Adjara-Trialeti belt from the former sedimentary fill of the basin and from syn-rift plutons. AFT central ages range between 46 and 15 Ma, while AHe ages cluster mainly between 10 and 3 Ma. Thermal modelling, integrating AFT and AHe data with independent geological constraints (e.g. depositional/intrusion age, other geochronological data, thermal maturity indicators and stratigraphic relationships), clearly indicates that the Adjara-Trialeti back-arc basin was inverted starting from the late Middle Miocene, at 14-10 Ma. This result is corroborated by many independent geological evidences, found for example in the adjacent Rioni, Kartli and Kura foreland basins and in the eastern Black Sea offshore, which all suggest a Middle-Late Miocene phase of deformation linked with the Adjara-Trialeti FTB building. Adjara-Trialeti structural inversion can be associated with the widespread Middle-to-Late Miocene phase of shortening and exhumation that is recognised from the eastern Pontides to the Lesser Caucasus, the Talysh and the Alborz ranges. This tectonic phase can in turn be interpreted as a far-field effect of the Arabia-Eurasia collision, developed along the Bitlis suture hundreds of kilometres to the south.

This study focuses on the thermal maturity of Permian deposits from the Zagros Basin, Southwest Iran, employing both optical methods (Thermal Alteration Index, Palynomorph Darkness Index, Vitrinite Reflectance, UV Fluorescence) and geochemical analyses of organic matter (Rock Eval Pyrolysis and MicroRaman spectroscopy) applied to the Faraghan Formation along two investigated Darreh Yas and Kuh e Faraghan surface sections. Furthermore, an integrated palynofacies and lithofacies analysis was carried out in order to integrate the few studies on the depositional environment. The Faraghan Formation, which is widely distributed in the Zagros area, generally consists of shale intercalated with sandstones and pebble conglomerates in the lower part, followed by a succession of sandstone, siltstone and shaly intercalations and with carbonate levels at the top. The integrated palynofacies and lithofacies data confirm a coastal depositional setting evolving upwards to a shallow marine carbonate environment upwards. Rock Eval Pyrolysis and Vitrinite Reflectance analysis showed that the organic matter from samples of the Darreh Yas and Kuh e Faraghan sections fall in the mature to postmature range with respect to the oil to gas generation window, restricting the thermal maturity range proposed by previous authors. Similar results were obtained with MicroRaman spectroscopy and optical analysis such as Thermal Alteration Index and UV Fluorescence. Palynomorph Darkness Index values were compared with Rock Eval Pyrolysis and vitrinite reflectance values and discussed for the first time in the late stage of oil generation. This research was funded by PRIN (2017RX9XXXY-CIRILLI), by Fondo Ricerca di Base Department of Physics and Geology, University of Perugia (SPIRICBAS2018-SPINA), by the project “Paleontological Studies and Biozonation of Paleozoic Sediments in Central Iran and Zagros Basins” (coordinator R. Rettori) and MIUR grants-SORCI to PhD School of Science and Technology for Physics and Geology (XXXIV Cycle), University of Perugia; Project “Paleontological Studies and Biozonation of Paleozoic Sediments in Central Iran and Zagros Basins” (RETTORI). info:eu-repo/semantics/publishedVersion

Between 2017 and 2019, a prototype of a geological garden for the dissemination of Geological Sciences to the general public was created in the open-air spaces of the Department of Sciences of the Roma Tre University. This first nucleus is the result of a Citizen Science activity carried out by students of the High Schools of Rome and its province, conceived and guided by a group of University researchers and high school teachers, in collaboration with local institutions and some mining companies operating in the surroundings of Rome. Currently the prototype consists of six large rock samples representative of lithotypes cropping out in the Roman Campaign and in the nearby Central Apennines that allow to tell the evolution of the territory surrounding the city of Rome since about 15 Ma ago, with particular reference to the history of the Roman countryside in the Quaternary period. Guided tours for schools and a general public and events popularizing scientific culture at various scales have represented the main dissemination activities carried out so far. Currently the garden is being expanded and integrated with numerous plant species representative of the botanical heritage of the Lazio region.

Located in northern Morocco, the Rif belt represents the western edge of the Maghrebides system. This domain underwent a significant Cenozoic alpine compressional deformation, due to the collision between the North African margin and the south-western margin of the exotic Alboran Domain. This collision led to the development of a nappe stack during the Miocene.This contribution aims to characterize the main tectonic mechanisms driving the evolution of the Rifain wedge, its burial-exhumation paths and to understand the former architecture of the North African paleo-margin. The work focuses mainly on the Flysch domain, originated from the Maghrebian branch of the Tethys and on the External domain (namely Intrarif, Mesorif and Prerif) that belong to the former north African margin. To define the thrust sheet stacking pattern and their burial-exhumation paths, a regional transect from Chefchaouen and Ouezzane towns (Central Rif), crossing the orogenic wedge from the Flysch to the Prerif Units is constructed.The methodological approach consists in combining petrography and Raman micro-spectroscopy on organic matter and 1D thermal modelling, together with field structural data.A new paleo-thermal data set of vitrinite reflectance (Ro%) and Raman micro-spectroscopy displays levels of thermal maturity between early and deep diagenetic conditions (Ro% ranges from 0.50% to 1.15%).Preliminary results show an abrupt change in the thermal maturity and the rate of shortening in the Loukkos sub-unit (Intrarif Domain) that is structurally squeezed between Tangier sub-unit (Intrarif Domain) and the “Izzaren Duplex” (Mesorif).Furthermore, previous studies show that the thickest crust below the Rif fold-and-thrust belt is located below the Izzaren area, suggesting a deep crustal imbrication at the transition between the Intrarif and the Mesorif. These observations joined with the thermal maturity data and 1D thermal modelling allow revisiting the structural evolution of the central part of the Rif belt, by defining the rate of shortening and proposing a new geological restoration with respect to the Mesozoic North African margin structural original setting.

A realistic reconstruction of the time-temperature history of sedimentary basins is critical to understand basin evolution and to predict oil maturation as well to assess reservoir quality. Carbonate rocks undergo diagenetic processes that modify their mineralogical and petrophysical properties. Understanding the temperature at which those processes occur and determining the geochemistry of the driving fluids is critical to constrain their occurrence and evolution in space and time.Here, we put to the test the joint application of two independent techniques: the traditional fluid inclusion microthermometry (FIM) and the more recent clumped isotopes thermometer (∆47). We compare thermal information acquired by Δ47 thermometer and FIM on diagenetic carbonates having precipitated at temperatures between 60°C and 130°C in Upper Triassic reservoirs (depths of 1820-2450 m) from the well-known Paris Basin, and having suffered 120°C during maximum burial for about 20 Ma. A conventional diagenesis study (petrography, O-C isotope geochemistry) has been accomplished in samples from three different cores drilled in carbonate-cemented siliciclastic reservoir units of Norian age (Grés de Chaunoy Formation) and located in the northern part of the basin depocenter. A complete cement paragenesis was reconstructed highlighting three different burial cements: two non-ferroan blocky calcite phases (Cal1 and Cal2) and one non-ferroan dolomite phase of saddle type (Dol1). The progressively more negative δ18Ocarb suggests a possible increase in temperature, going from Cal1 to Dol1, whereas the consistently negative δ13C could indicate the involvement of continental fluids.FIM indicates homogenization temperatures (Th) spanning from 60°C to 95°C (mode 67.5°C) for Cal1, 70°C to 110°C (mode 84°C) for Cal2, and 100°C to 130°C (mode 115°C) for Dol1. Δ47 measurements overall reveals lower temperatures for calcite cements, indicating probable thermal re-equilibration of the fluid inclusions, and a fairly similar temperature for the saddle dolomite cement. Uncertainties in the temperatures obtained through FIM and ∆47 thermometry and in the successively calculated δ18Ofluid, may lead to an erroneous assessment of the time of precipitation of the different diagenetic phases and to an erroneous thermal history and fluid-flow reconstruction. This work emphasizes the necessity of better understanding the limitations and applicability fields of these thermometric tools, especially when applied to burial diagenetic phases precipitated at temperatures above 100°C and/or in reservoirs having experienced temperatures in the gas window.

Temperature evaluation of PDCs has been recently performed using optical analysis of charred wood (Reflectance analysis - Ro%) embedded within the pyroclastic deposits.The validity of this proxy for the emplacement temperature assessment, has been established in different case studies (Fogo Volcano, Laacher See volcano, Merapi Volcano, Colima Volcano, Doña Juana Volcano, Ercolano-Vesuvius Volcano), resulting comparable with the already well know paleomagnetic analysis (pTRM).Due to its not retrograde nature, the process of carbonification records over time the maximum temperatures experienced by the wood fragment/tree trunk/furniture. This peculiarity has great importance in terms of timing of charring events, as the charred wood can record the possible temperature fluctuations in case of multiple pulse events. This allows us to reconstruct the thermal and dynamic of PDCs history at different steps.Reflectance analysis (Ro%) results display samples with homogeneous charring temperature (same Ro% values) from rim to core and others with different charring temperatures throughout the sample. Ro% of the latter usually infer higher temperature on the edge of the fragment/tree trunk than in the inner part. This bimodal reflectance distribution can be attributable to multiple temperature exposure, occurred during diachronous events of flow and deposition. Therefore, within the same fragment/tree trunk we can extrapolate PDCs temperature information related not only to equilibrium (emplacement) condition but, more importantly, to dynamic (flow) regime.This study constitutes a pioneering attempt for the indirect estimation of the temperature of the PDCs not only for volcanic hazard estimation, but also in the archaeological field. In fact, the numerous remains of charred wooden artefacts found in the archaeological sites of Pompeii, Herculaneum and in the Meurin quarry (Eiffel-Germany), allowed the reconstruction of temperature variation based on the vent distance and the presence of buildings which may have interacted with the depositional processes of pyroclastic flows. This study opens a promising new frontier to evaluate the maximum temperature of the PDCs, based on the degree of carbonization of the organic matter incorporated during volcanic events. Estimating the temperature of the dynamic temperature of the PDC has important implications in terms of volcanic risk assessment.

Continent Ocean Transitions (COTs) record the processes leading to continental breakup and localized oceanic accretion initiation. The recent IODP Expeditions 367-368 and 368X at the SE China margins combined with high quality multi-channel seismic profiles provide a unique dataset to explore the tectono-magmatic and thermal evolution from final rifting to early seafloor spreading. To investigate these issues, we developed a multi-disciplinary approach combining reflection seismic interpretations with geophysical quantitative analysis calibrated thanks to drilling results, from which we measured and modelled the thermal maturity in pre-/syn- to post-rift sediments.Drilling results show that the transition from the most thinned continental crust to new, largely igneous crust is narrow (~20 km). During final rifting, decompression melting forming Mid-Ocean Ridge type magmatism emplaced within thinned continental crust as deep intrusions and shallow extrusive rocks concomitant with continued deformation by extensional faults. The initial igneous crust of the conjugate margins is asymmetric in width and morphology. The wider and faulted newly accreted domain on the SE China side indicates that magmatic accretion was associated with tectonic faulting during the formation of initial oceanic lithosphere, a feature not observed on the conjugate Palawan side. We suggest that deformation and magmatism were not symmetrically distributed between the conjugate margins during the initiation of seafloor spreading but evolved asymmetrically prior to the spreading ridge stabilising.Organic matter from post-rift sediments has low thermal maturities due to limited burial and the absence of late post-rift magmatism. In contrast, pre to syn-rift sediments show significant variability in thermal maturities across the COT. Localised high thermal maturities for the pre- to syn-rift sediments requires that significant additional heat be imparted at shallow depths during breakup, likely related to magmatic intrusion or subsurface expressions of volcanism. The heterogeneous variation in thermal maturity observed across the COT reflects localised thermal perturbations caused by magmatic additions.

The upper Triassic Streppenosa and Noto Formations are considered the main source rocks of the Hyblean Plateau in south-eastern Sicily, that represents the present-day deformed foreland of the Sicilian fold-and-thrust belt. This work focusses on the Upper Triassic Streppenosa and Noto Formations, penetrated by the Eureka 1 onshore well (south-eastern Sicily, Italy) in order to constrain the burial-thermal history of this basin of the western Tethys. According to previous paleogeographic reconstructions, starting from Norian, the palaeogeographic scenario consisted, moving from north to south, of a wide carbonate platform (Sciacca Fm.), adjacent to two different domains: the euxinic lagoon/basin of the Noto Formation, and, to the south, the basin of the Streppenosa Formation. Eureka 1 well is located in the inner portion of the platform-basin system and its Triassic succession consists of alternation of black shales and micritic, microbial dolomitic laminated limestones. A detailed description of the sedimentological facies from cores samples has been performed together with detailed organic petrography/Raman spectroscopy and clay mineralogy on fine grained sediments to assess thermal maturity of the Streppenosa and Noto Fms. The main facies consist of light-grey limestones (wackestone-mudstone) with scattered sub-angular intraclast, light grey finely laminated limestones, dark grey-black laminated mudstones, brownish undulated algal laminae saturated with bitumen. The cores are often bitumen saturated and interrupted by different sets of open microfractures, veins filled with calcite, and stylolites (parallel and vertical with respect to lamination) that may enhance and/or inhibit at places the fluid flow. Concerning thermal maturity, the studied interval falls in the lower-mid portion of the oil window, with robust agreement among the geothermometers derived from the three adopted techniques.

Thermal history reconstructions can help to better characterise the geological history of areas that experienced a polyphase tectonic evolution. The integration of published stratigraphic/structural data with new and pre-existing data on thermal maturity (clay mineralogy, Raman spectroscopy, vitrinite reflectance, and pyrolysis) of both surface and subsurface sedimentary successions of a wide region of Georgia including -north to south- the southern Greater Caucasus, the western Kura Basin, and the Adjara-Trialeti fold-and-thrust belt (FTB) provides cogent constraints on its late Mesozoic-Cenozoic tectono-sedimentary evolution. Overall, thermal maturity spans from the low diagenesis (60–80 °C) in the Upper Miocene section of the Kura Basin to anchizone-epizone (about 400 °C) in the central Greater Caucasus axial zone. In more detail, different maturity trends and thermal histories point to the existence of two domains formed by positive tectonic inversion: (i) the Adjara-Trialeti FTB from an Eocene rift basin and (ii) the Greater Caucasus from a Mesozoic rift basin. Multiple thermal indicators, along with stratigraphic/structural evidence, show that the Paleocene section of the Adjara-Trialeti basin fill reached the upper oil window (ca. 115 °C) during maximum sedimentary burial and that the whole basin was then exhumed starting from the late Middle Miocene. A positive correlation between thermal maturity and stratigraphic age points to a limited thermal effect of tectonic loading. In the southern Greater Caucasus, thermal maturity increases progressively with stratigraphic age, from ca. 100 °C (Upper Eocene) to 400 °C (Lower Jurassic), in broad agreement with the reconstructed thickness of the basin-fill succession, thus indicating that most of the thermal maturity was again induced by sedimentary burial. As to the flexural western Kura Basin, its Maikopian (Oligocene-Early Miocene) section reached the oil window (up to ca. 110 °C) whereas the Middle-Late Miocene one is immature. The Kakheti ridge -a highly tectonised portion of the Kura Basin- reached immature to early mature conditions.

Temperature-dependent clay minerals and vitrinite reflectance data, surface and subsurface geological constraints were used to unravel the burial evolution of the Ordovician-Quaternary sedimentary successions from the inner to the outer zones of the Zagros fold-and-thrust belt in the Fars province (Iran). These sedimentary successions were buried to their thermal maxima during early to late diagenesis, achieving temperatures corresponding to the immature to early mature stages of hydrocarbon generation. They experienced low levels of thermal maturity in the Interior Fars, corresponding to vitrinite reflectance values between 0.38 and 0.66%, to mixed layers illite-smectite (I-S) with an illite content between 30 and 75% and to KI values between 0.97 and 1.18°Δ2θ. In the Central and Coastal Fars, vitrinite reflectance ranges between 0.35 and 0.51%, the illite content in I-S displays values between 20 and 85% and KI data are between 0.71 and 1.30°Δ2θ. In individual anticlines, mixed layers I-S show an increase of the illite content as a function of stratigraphic age (depth), suggesting that levels of thermal maturity are controlled by sedimentary burial. One dimensional thermal history models allowed us: (i) to estimate the maximum burial experienced by the sedimentary successions and the amount of the sedimentary pile currently removed by erosion, (ii) to determine the thickness of the ophiolite units obducted during Late Cretaceous time in the High Zagros, and (iii) to define the onset of oil generation for the Albian source rocks throughout the Zagros belt. Paoleothermal data were used to constrain the geometry of eroded structures in a 253 km long cross-section extending from the High Zagros to the Coastal Fars. Along the cross-section, lithostatic load slightly decreases towards the foreland (e.g., from 3.65 km to 3.2 km for the Bangestan Group) and the amount of the eroded material varies between ∼6 km (above anticlines in the Central and Interior Fars) and ∼200 m (above synclines in the external part of the belt).

The recent 10th–11th of July 2015 Volcan de Colima eruption involved the collapse of the summit dome that breached to the south generating pyroclastic density currents (PDCs) along the Montegrande ravine on the southern flank of the volcano. Trees within the valley were buried, uprooted and variably transported by the PDCs, while the trees on the edges of the valley and on the overbanks, were mainly burned and folded. The emplacement temperature of valley confined and overbank PDC deposits were reconstructed using Partial Thermal Remanent Magnetization (pTRM) analysis of lithic clasts and Charcoal Reflectance analysis (Ro %) applied to the charred wood. A total of 13 sites were sampled for the pTRM study and 39 charcoaled wood fragments were collected for the charcoal optical analysis along the entire deposit length in order to detect temperature variation from proximal to distal zone. The result overlap from both data sets display a T max from ≃345°–385 °C in valley-confined area (from 3.5 to 8.5 km from the vent) and ≃170°–220 °C (from 8.0 to 10.5 km from the vent) in unconfined distal area. The emplacement temperature pattern along the 10.5 km long deposit appears related to the degree of topography confinement: valley confined and unconfined. In particular the valley confined setting is very conservative in terms of temperature, while the major drop occurs in a very narrow space where the PDC expanded over unconfined flat topography just at the exit of the main valley. This study represents the first attempt in determining the relationship between PDCs flow dynamics variation and topographic confining using deposit emplacement temperature as key proxy.

The study of the structural order of charcoals embedded in pyroclastic density currents provides information on their emplacement temperature during volcanic eruptions. In the present work, a set of charcoals from three distinct pyroclastic density currents deposits whose temperatures have been previously estimated by charcoal reflectance analyses to lie between 250 °C and 550 °C, was studied by means of Raman spectroscopy. The analyses reveal a very disordered structural ordering of the charcoals, similar to kerogen matured under diagenetic conditions. Changes in Raman spectra at increasing temperatures reflect depolymerization and an increase of aromaticity and can be expressed by parameters derived from a simplified fitting method. Based on this approach, a second order polynomial regression with a high degree of correlation and a minimum error was derived to predict paleotemperatures of pyroclastic deposits. Our results show that Raman spectroscopy can provide a reliable and powerful tool for volcanological studies and volcanic hazard assessment given its advantage of minimum samples preparation, rapid acquisition processes and high precision.

The Argentinean Andean region hosts a vast geothermal resource clustered by active magmatic and tectonic activity. One of the most studied geothermal areas is the Tuzgle-Tocomar geothermal system in Central Puna (NW Argentina). However, despite the existence of several studies since the 1970′s highlighting the geothermal potential of the area, only highly schematic and dissimilar conceptual models have been proposed for the Tocomar Geothermal System. This study presents new detailed geological-structural and hydrogeochemical data, together with in-situ permeability analysis of fault zones and Raman spectroscopic characterization of hydrothermal-alteration minerals. The electrical generating capacity has also been evaluated using the volumetric method and a stochastic approach. A new comprehensive conceptual model of the studied area was constructed highlighting the role of the Calama-Olacapato-El Toro (COT) fault-system in the circulation of hydrothermal fluids. The reservoir of the Tocomar geothermal system has a Na+-Clˉ(HCO3)ˉ composition and an estimated temperature of ∼235 °C. Such a reservoir is hosted in fractured Ordovician rocks and controlled by the COT-like Chorrillos transpressive fault at 1000–1500 m depth b.g.l. The water isotopic data and hydrological features indicate a regional recharge beyond the Tocomar sub-basin boundaries (>5000 m a.s.l.). Additionally, the main hydrothermal reservoir receives inputs of magmatic fluids from the degassing of the intra-crustal rhyolitic magma chamber of the Tocomar volcanic center. The Monte Carlo simulations suggest that the Tocomar geothermal system has a probable power production capacity above 1.23 MWe (P90), 6.18 MWe (P50) and 11.67 MWe (P10) at different confidence levels. All calculations were biased towards minimum values, thus a tighter definition of the resource size and fracture porosity would significantly impact on the predictions. Notwithstanding, the strategic position of the Tocomar geothermal field encourages move forward towards more in-depth exploration phases.

In this paper we reply to the criticisms advanced by Narkiewicz (2017) on the paper by Schito et al. (2017). We clarify the issues related to the stratigraphic and thermal maturity constraints used for reconstructing burial and thermal models of the two blocks of the Holy Cross Mountains. We also show how geological evidences brought by Narkiewicz (2017) as a proof of elevated Variscan heat flow are not conclusive or at least suggest the occurence of a localized thermal anomaly only along the area of the Holy Cross Fault. In the end, we performed new burial and thermal models in the Kielce region demonstrating that stratigraphic thickness variations between Schito et al. (2017) and Narkiewicz et al. (2010) produce only negligible differences in levels of thermal maturity of Paleozoic rocks. In addition, we outline that levels of thermal maturity for Silurian rocks can be matched only by using constant heat flow values through the Paleozoic and point to a decisive role for the absence of regional high Variscan heat flow in the area.

The stretching of continental lithosphere results in asthenospheric upwelling, raising of isotherms, melting during decompression and eventually seafloor spreading. The thermal maturity of overlying sedimentary organic matter from these settings would be expected to be distinctly altered by these processes, however this is still poorly constrained and quantitatively unexplored. International Ocean Discovery Program (IODP) Expeditions 367–368 cored sediments at the Continent Ocean Transition (COT) on the Northern Margin of the South China Sea (SCS). From two settings at the South East China COT we measured and modelled thermal maturity in pre-/syn- to post-rift sediments making use of a range of thermal maturity parameters. Various heat-flow evolutionary scenarios were investigated, with notable jumps in thermal maturity for sediments corresponding to different depositional packages. In order to match observations of thermal maturity, it was found that the deeper and likely pre-rift sediments were heated to temperatures as high as 200 °C during initial breakup. Achieving this temperature for the deeper sediments requires that significant additional heat be imparted at shallow depths (e.g. exposure to at least the far-field effects of a magmatic intrusion or subsurface expressions of volcanism). The post-rift sediments have lower thermal maturities which are likely due to limited burial and the absence of late post-rift magmatism. The comparison of the SE China COT with other margin examples highlights some parameters controlling the thermal evolution and its record.

Thrusting at shallow depths often precludes analysis by means of structural indicators effective in other geological contexts (e.g., mylonites, sheath folds, shear bands). In this paper, a combination of techniques (including structural analysis, magnetic methods, as anisotropy of magnetic susceptibility and paleomagnetism, and paleothermometry) is used to define thrusting conditions, deformation, and transport directions in the Cameros–Demanda thrust (North Spain). Three outcrops were analyzed along this intraplate, large-scale major structure having 150 km of outcropping length, 30 km of maximum horizontal displacement, and 5 km of vertical throw. Results obtained by means of the different techniques are compared with data derived from cross sections and stratigraphic analysis. Mixed-layer illite–smectite and vitrinite reflectance indicating deep diagenetic conditions and mature stage of hydrocarbon generation suggests shallow depths during deformation, thus confirming that the protolith for most of the fault rocks is the footwall of the main thrust. Kinematic indicators (foliation, S/C structures, and slickenside striations) indicate altogether a dominant NNW movement of the hanging wall in the western zone and NE in the eastern zone of the thrust, thus implying strain partitioning between different branches of the main thrust. The study of AMS in fault rocks (nearly 400 samples of fault gouge, breccia, and microbreccia) indicates that the strike of magnetic foliation is oblique to the transport direction and that the magnetic lineation parallelizes the projection of the transport direction onto the k max/k int plane in sites with strong shear deformation. Paleomagnetism applied to fault rocks indicates the existence of remagnetizations linked to thrusting, in spite of the shallow depth for deformation, and a strong deformation or scattering of the magnetic remanence vectors in the fault zone. The application of the described techniques and consistency of results indicate that the proposed multidisciplinary approach is useful when dealing with thrusts at shallow crustal levels.

Paleo-thermometers in sedimentary basins often drive to misleading thermal modelling when applied alone or only on potentially productive Paleozoic source rocks. Different paleo-thermal and thermo-chronological data have been used as constraints to model the Silurian to Cenozoic succession of a recently drilled well in the onshore portion of the Baltic Basin, in northern Poland. This dataset provides an integrated platform for thermal maturity assessment contributing to the highly debated reconstruction of the thermal history of the Baltic Basin in the last decade. The well stratigraphy consists of a Lower Paleozoic marine clayey and arenaceous/calcareous succession, about 1000 m thick that is unconformably overlain by a 2000 m thick Permian to Cenozoic sequence, developed in a continental to shallow marine environment. Optical microscopy, FT-IR and Raman spectroscopy analysis of organic matter have been coupled with (U–Th)/He data to produce a robust vitrinite reflectance profile and constrain the 1D thermal modelling of the well. In addition, such a thermal maturity profile was validated by an independent thermal modelling calibrated by the smectite illitization kinetics. Both models identify high heat flow conditions (up to 1.7 HFU) at the end of Mesozoic. The Lower Paleozoic succession entered the late oil window of HC generation during this last heating event.

Thermal maturity of six organic rich samples from Jurassic continental successions cropping out in the Holy Cross Mountains in Central Poland, has been characterized by classic thermal maturity indicators, micro-Raman spectroscopy and Palynomorph Darkness Index, in order to create a multi-method workflow for complex palynofacies thermal maturity assessment. Transmitted light observations on dispersed organic matter define a Hettangian lacustrine depositional environment, characterized by periods of reducing/oxidizing conditions and variable sedimentation rates. Thermal maturity detected by classical maturity indicators and PDI indicates an early maturation stage of hydrocarbon generation and is in agreement with spectroscopic analyses performed on phytoclast groups. Moreover, Raman parameters in the sporomorph group indicate a systematic shift toward a lower degree of aromatization compared to the phytoclast group. Finally, the multivariate statistical analysis performed on Raman spectra is found to be a promising tool to define and predict the heterogeneity of dispersed organic matter in sediments.

Temperature-dependent clay mineral assemblages, vitrinite reflectance, and one-dimensional (1-D) thermal and three-dimensional (3-D) geological modeling of a Neogene wedge-top basin in the Sicilian fold-and-thrust belt and its pre-orogenic substratum allowed us to: (1) define the burial history of the sedimentary succession filling the wedge-top basin and its substratum, (2) reconstruct the wedge-top basin geometry, depocenter migration, and sediment provenance through time in the framework of a source-to-sink system, and (3) shed new light into the kinematic evolution of the Apennine-Maghrebian fold-and-thrust belt.The pre-orogenic substratum of the Scillato basin shows an increase in levels of thermal maturity as a function of stratigraphic age that is consistent with maximum burial to 3.5 km in deep diagenetic conditions. In detail, Ro% values range from 0.40% to 0.94%, and random ordered illite-smectite (I-S) first converts to short-range ordered structures and then evolves to long-range ordered structures at the base of the Imerese unit. The wedge-top basin fill experienced shallow burial (∼2 km) and levels of thermal maturity in the immature stage of hydrocarbon generation and early diagenesis. Vitrinite reflectance and mixed-layer I-S values show two populations of authigenic and inherited phases. The indigenous population corresponds to macerals with Ro% values of 0.33%–0.45% and I-S with no preferred sequence in stacking of layers, whereas the reworked group corresponds to macerals with Ro% values of 0.42%–0.47% and short-range ordered I-S with no correlation as a function of depth.Authigenic and reworked components of the Scillato basin fill allowed us to unravel sediment provenance during the Neogene, identifying two main source areas feeding the wedge-top basin (crystalline units of the European domain and sedimentary units of the African domain), and to detect an early phase of exhumation driven by low-angle extensional faults that predated Neogene compression.

Reconstructing the paleofluid evolution in mature fault zones, which typically have complex structural architectures, is a challenging task because reactivation of pre-existing deformation structures and dissolution-reprecipitation processes are very abundant. Understanding why specific structural elements are preferentially mineralized and what are the factors leading to rapid fluid migration and accumulation, bears geological and economic implications, especially in seismically active fault zones. We studied the Compione Fault on the Tyrrhenian Sea side of the Northern Apennines orogenic wedge, Italy, which is a segment of the 30-km-long Northern Lunigiana high-angle extensional fault system still active today. The Compione Fault propagated from the metamorphic basement and accumulated about 1.5 km of displacement. We used structural, petrographic, isotopic, microthermometric, compositional, and organic matter analyses to constrain fluid and host rock properties during fault zone evolution. This approach allowed us to quantify the thermal anomaly in the fault zone and to infer the processes responsible for such a disequilibrium. Specifically, we show that in the fault process zone ahead of the upper fault tip, which is twice as wide as the damage zone, seismic pumping caused suprahydrostatic fluid pressures and that local dilation promoted the nucleation of a highly permeable mesh of conjugate extensional shear fractures hosting calc-silicate mineralization. The thermal difference between hydrothermal minerals in the conjugate fracture mesh and the host rock is 60-90 degrees C. The mineralizing fluids were deeply sourced from metamorphic reactions. Propagation of the upper fault tip caused process zone folding and incorporation into the fault damage zones. As the upper fault tip breached through shallower structural levels, it favored mixing between deep and meteoric fluids.

Pyroclastic density currents (PDCs) can have devastating impacts on urban settlements, due to their dynamic pressure and high temperatures. Our degree of understanding of the interplay between these hot currents and the affected infrastructures is thus fundamental not only to implement our strategies for risk reduction, but also to better understand PDC dynamics. We studied the temperature of emplacement of PDC deposits that destroyed and buried the Villa dei Papiri, an aristocratic Roman edifice located just outside the Herculaneum city, during the AD79 plinian eruption of Mt Vesuvius (Italy) by using the thermal remanent magnetization of embedded lithic clasts. The PDC deposits around and inside the Villa show substantial internal thermal disequilibrium. In areas affected by convective mixing with surface water or with collapsed walls, temperatures average at around 270 °C (min 190 °C, max 300 °C). Where the deposits show no evidence of mixing with external material, the temperature is much higher, averaging at 350 °C (min 300 °C; max 440 °C). Numerical simulations and comparison with temperatures retrieved at the very same sites from the reflectance of charcoal fragments indicate that such thermal disequilibrium can be maintained inside the PDC deposit for time-scales well over 24 hours, i.e. the acquisition time of deposit temperatures for common proxies. We reconstructed in detail the history of the progressive destruction and burial of Villa dei Papiri and infer that the rather homogeneous highest deposit temperatures (average 350 °C) were carried by the ash-sized fraction in thermal equilibrium with the fluid phase of the incoming PDCs. These temperatures can be lowered on short time- (less than hours) and length-scales (meters to tens of meters) only where convective mixing with external materials or fluids occurs. By contrast, where the Villa walls remained standing the thermal exchange was only conductive and very slow, i.e. negligible at 50 cm distance from contact after 24 hours. We then argue that the state of conservation of materials buried by PDC deposits largely depends on the style of the thermal interactions. Here we also suggest that PDC deposit temperatures are excellent proxies for the temperatures of basal parts of PDCs close to their depositional boundary layer. This general conclusion stresses the importance of mapping of deposit temperatures for the understanding of thermal processes associated with PDC flow dynamics and during their interaction with the affected environment.

The Podolia region is located along the western border of the Eastern European Craton, which is also known as Ukrainian Shield. From the Ordovician to the Miocene, this area formed part of an epicontinental basin system. In order to investigate the effects of orogenic cycles occurring along the plate margin, a multi-disciplinary approach was used in this study. Paleotemperature analysis and low-temperature thermochronometry were combined with stratigraphic data to obtain a burial model for the Paleozoic succession exposed in the study area. Maximum burial for Silurian and Devonian rocks occurred during the Devonian and Early Carboniferous at depths of 4-5 km, as constrained by vitrinite reflectance and illite content in mixed illite-smectite layers. Thermochronometric data indicate that exhumation through the 45-120 °C temperature range took place between the Late Triassic and the Early Jurassic, and that no significant burial occurred afterwards (temperatures characterising the stratigraphically lowermost units remaining below ca. 60 °C). These results point to a major exhumation event coeval with the Cimmerian orogenesis, which took place a few hundreds of kilometres away from the study area. On the other hand, no significant effect of the Alpine orogenesis was recorded, although the collisional front was located

Understanding the thermal behavior of pyroclastic density currents (PDCs) is crucial for forecasting impact scenarios for exposed populations as it affects their lethality and destructiveness. Here we report the emplacement temperatures of PDC deposits produced during the paroxysmal explosive eruption of Merapi (Central Java) on 5 November 2010 based on the reflectance of entombed charcoal fragments. This event was anomalously explosive for Merapi, and destroyed the summit dome that had been rapidly growing, with partial collapses and associated PDCs, since October 26. Results show mean reflectance values mainly between 0.17 and 0.41. These new data provide a minimum temperature of the flow of 240–320 °C, consistent with previous estimations determined from independent field, engineering, and medical observations published in the literature for this eruption. A few charcoal fragments recorded higher values, suggestive of temperatures up to 450 °C, and we suggest that this is due to the thermal disequilibrium of the deposits, with larger block-size clasts being much hotter than the surrounding ash matrix. Charring temperatures show no major differences between proximal and distal PDC deposits and are significantly lower than those that may be associated with a fast growing dome dominated by dense and vitric non-vesicular rocks. We therefore infer that the decrease in temperature from that at fragmentation (>900 °C) occurred in the very initial part of the current

Anisotropy of magnetic susceptibility (AMS) has been applied to the study of shallow fault zones, although interpretation of the results requires establishing clear relationships between petrofabric and magnetic features, magnetic behaviour of fault rocks, and an extensive knowledge of P-T conditions. In this work, we demonstrate that magnetic methods can be applied to the study of heterogeneous fault zones, provided that a series of requisites are met. A major fault zone within the Iberian plate (Daroca thrust), showing transpressional movements during Cenozoic time was chosen for this purpose, because of the exceptional outcrops of fault gouge and microbreccia and its relevance within the context of the northeastern Iberian Plate. Magnetic fabrics were analysed and the results were compared with foliation and S-C structures measured within the fault zone. Clay mineral assemblages suggest maximum burial depths shallower than 2 km (

Mixed layer clay minerals, vitrinite reflectance and geochemical data from Rock-Eval pyrolysis were used to constrain the burial evolution of the Mesozoic–Cenozoic successions exposed at the Kuh-e-Asmari (Dezful Embayment) and Sim anticlines (Fars province) in the Zagros fold-and-thrust belt. In both areas, Late Cretaceous to Pliocene rocks, show low levels of thermal maturity in the immature stages of hydrocarbon generation and early diagenetic conditions (R0 I–S and Ro% values < 0.5). At depths of 2–4 km, Tmax values (435–450 °C) from organic-rich layers of the Sargelu, Garau and Kazhdumi source rocks in the Kuh-e-Asmari anticline indicate mid to late mature stages of hydrocarbon generation. One dimensional thermal models allowed us to define the onset of oil generation for the Middle Jurassic to Eocene source rocks and pointed out that sedimentary burial is the main factor responsible for measured levels of thermal maturity. Specifically, the Sargelu and Garau Formations entered the oil window prior to Zagros folding in Late Cretaceous times, the Kazhdumi Formation during middle Miocene (syn-folding stage), and the Pabdeh Formation in the Late Miocene–Pliocene after the Zagros folding. In the end, the present-day distribution of oil fields in the Dezful Embayment and gas fields in the Fars region is primarily controlled by lithofacies changes and organic matter preservation at the time of source rock sedimentation. Burial conditions during Zagros folding had minor to negligible influence.