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Copyright of Chemical & Biochemical Engineering Quarterly is the property of Croatian Society of Chemical Engineers and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The anthropogenic change of the nitrogen (N) cycle is strongly triggered by urban demand (such as food and meat consumption, energy demand and transport). As a consequence of high population density, impacts on human health through water and air pollution also concentrate on a city environment. Thus, an urban perspective on a predominantly rural pollution becomes relevant. Urban N budgets may be considered less intrinsically connected, so that separation of an agri-food chain and an industry-combustion chain is warranted. Results have been obtained for Zielona Góra, Poland, a city of 140,000 inhabitants characterized by domestic and transport sources and forest-dominated surroundings. In addition to food imports in Zielona Gora amounting to about 30 %, in the suburban area a significant share of N amounting to 41 % is related to fertilizer imports. The remaining imports are in fuel, electronics, textiles, plastics and paper. Most of the agri-food N (45 %) is denitrified in wastewater treatment. N associated with combustion (mainly NOx emissions from vehicles) represents a much smaller share than N entering via the agri-food system, amounting to 22 % of the total N imports. This overall picture is maintained also when specifically addressing the city center, with the exception of mineral fertilizer that plays a much smaller role, with just 7 % of N imports to the city., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Authors. Published by Elsevier B.V. All rights reserved.)

Reactive nitrogen (Nr) released to the environment is a cause of multiple environmental threats. While Nr flows are often only analyzed in an agricultural context, consumption and emission takes place in the urban environment, and opportunities for Nr recycling and effective policy implementation for mitigation often appear in cities. Since little information is available on the bigger picture of Nr flows through the urban environment, these opportunities often remain unexploited. Here we developed a framework to model Nr pathways through urban and surrounding areas, which we applied to four test areas (Beijing and Shijiazhuang (China), Vienna (Austria), and Zielona Góra (Poland)). Using indicators such as recycling rates and Nr surplus, we estimated environmental risks and recycling potentials based on Nr flows and their entry and exit points. Our findings show marked differences between the core and surrounding areas of each city, with the former being a site of Nr consumption with largest flows associated with households, and the latter a site of (agricultural) production with largest flows associated with industry (fertilizers) and urban plants. As a result, Nr transgresses the core areas in a rather linear manner with only 0-5 % being re-used, with inputs from Nr contained in food and fuels and outputs most commonly as non-reactive N 2 emissions to the atmosphere from wastewater treatment and combustion processes. While the peri-urban areas show a higher Nr recycling rate (6-14 %), Nr accumulation and emissions from cultivated land pose significant environmental challenges, indicating the need for mitigation measures. We found potential to increase nitrogen use efficiency through improved Nr management on cultivated areas and to increase Nr recycling using urine and sewage sludge as synthetic fertilizer substitutes. Hence our framework for urban nitrogen budgets not only allows for consistent budgeting but helps identify common patterns, potentially harmful flows and Nr recycling potential., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier B.V. All rights reserved.)

During heavy precipitation, chemical and biological pollutants from urban and agricultural areas enter the waters from storm overflows as a result of infiltration and inflow, as well as via uncontrolled outflows from water treatment plants. Infiltration and inflow of rainwater into sewers is an especially popular and major worldwide problem. Climate forecasts indicate changes in climatic conditions towards an increase in the intensity and frequency of torrential rainfalls. It may therefore be assumed that the negative impact of rainwater on water quality will increase. This article attempts to address the question of the impact of pollution from wastewater introduced into water during rainy weather to the receiver. The assessment of the impact of rainfalls on a receiver was carried out on the basis of a simulation of pollution loads from sewage introduced into a river by storm overflows based on data from monitoring the amount of rainfall and simulating the operation of storm overflows using Environmental Protection Agency Storm Water Management Model (EPA SWMM). The obtained results were compared with the pollutant loads discharged at the same time from the sewage treatment plant (STP). In addition, the article assesses possible improvement solutions to reduce the negative impact of storm overflows on water., (© 2021. The Author(s).)

To ensure high fermentation efficiency, it is necessary to assess the biodegradability of a substrate. These parameters are most often determined on the basis of the amount of loss on ignition and total organic carbon. We are more and more often using chemical indices. However, these indices do not provide information on how much an organic substance is susceptible to biodegradation. The actual assessment of the content of easily biodegradable matter in substrates that are used for fermentation should be performed on the basis of aerobic (AT4) and anaerobic tests (BMP), which require specialised equipment and are time consuming. The AT4 index is being more and more frequently adopted for the analysis of substrates that are used in the fermentation process, because AT4 takes a much shorter time than BMP and provides information on the biodegradability of substrates. The aim of the article is to answer the question of whether the AT4 parameter can be used to assess the suitability of the substrate from the agricultural sector for the fermentation process. The results show that the AT4 index could be used instead of the BMP parameter.

Achieving high efficiency of biological waste treatment in mechanical⁻biological treatment (MBT) plants requires reliable methods for measuring the degree of biodegradation of organic substances. For this purpose, several physical, chemical, and biological indices are used. This paper presents respirometric activity (AT4), biogas potential (GB21), total and dissolved organic carbon (TOC and DOC, respectively), and loss on ignition (LOI) values, as well as the correlations between the indices selected for stabilized waste produced in 18 MBT plants in Poland, which use various technologies for biological processing of the organic fraction of municipal solid waste. The study confirms that there is a linear relationship between AT4 and GB21 for stabilized waste produced in MBT plants, regardless of the waste treatment technology used. It has also been found that there is a linear relationship between AT4 and the concentration of dissolved carbon in water extract from stabilized waste. This indicates that DOC can be used for monitoring the organic matter stabilization process in mechanical⁻biological waste treatment plants. Its advantage is a shorter time needed for measurements in comparison to AT4 and GB21 tests.