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Comets hold answers to mysteries of the Solar System by recording presolar history, the initial states of planet formation and prebiotic organics and volatiles to the early Earth. Analysis of returned samples from a comet nucleus will provide unparalleled knowledge about the Solar System starting materials and how they came together to form planets and give rise to life: 1. How did comets form? 2. Is comet material primordial, or has it undergone a complex alteration history? 3. Does aqueous alteration occur in comets? 4. What is the composition of cometary organics? 5. Did comets supply a substantial fraction of Earth's volatiles? 6. Did cometary organics contribute to the homochirality in life on Earth? 7. How do complex organic molecules form and evolve in interstellar, nebular, and planetary environments? 8. What can comets tell us about the mixing of materials in the protosolar nebula?, Comment: White Paper submitted to the Planetary Science Decadal Survey 2023-2032 reflecting the viewpoints of three New Frontiers comet sample return missions proposal teams, CAESAR, CONDOR, and CORSAIR

In the search for evidence of past aqueous activity by the Mars Exploration Rover Opportunity, fracture-filling veins and rock coatings are prime candidates for exploration. At one location within a segment of remaining rim material surrounding Endeavour Crater, a set of “boxwork” fractures in an outcrop called Esperance are filled by a bright, hydrated, and highly siliceous (SiO2 ~ 66 wt%) material, which has overall a montmorillonite-like chemical composition. This material is partially covered by patches of a thin, dark coating that is sulfate-rich (SO3 ~ 21 wt%) but also contains significant levels of Si, Fe, Ca, and Mg. The simultaneous presence of abundant S, Si, and Fe indicates significant mineralogical complexity within the coating. This combination of vein and coating compositions is unlike previous analyses on Mars. Both materials are heterogeneously eroded, presumably by eolian abrasion. The evidence indicates at least two separate episodes of solute precipitation from aqueous fluids at this location, possibly widely separated in time. In addition to the implications for multiple episodes of alteration at the surface of the planet, aqueous chemical environments such as these would have been habitable at the time of their formation and are also favorable for preservation of organic material.

NASA/Jet Propulsion Lab; NASA Mars Data Analysis Program [NNX07AN96G, NNX10AQ23G]; MDAP grants [NNX12AG89G, NNX13AI98G]; LSU's College of Science and Geology and Geophysics

Mars Reconnaissance Orbiter HiRISE images and Opportunity rover observations of the ~22 km wide Noachian age Endeavour Crater on Mars show that the rim and surrounding terrains were densely fractured during the impact crater-forming event. Fractures have also propagated upward into the overlying Burns formation sandstones. Opportunity’s observations show that the western crater rim segment, called Murray Ridge, is composed of impact breccias with basaltic compositions, as well as occasional fracture-filling calcium sulfate veins. Cook Haven, a gentle depression on Murray Ridge, and the site where Opportunity spent its sixth winter, exposes highly fractured, recessive outcrops that have relatively high concentrations of S and Cl, consistent with modest aqueous alteration. Opportunity’s rover wheels serendipitously excavated and overturned several small rocks from a Cook Haven fracture zone. Extensive measurement campaigns were conducted on two of them: Pinnacle Island and Stuart Island. These rocks have the highest concentrations of Mn and S measured to date by Opportunity and occur as a relatively bright sulfate-rich coating on basaltic rock, capped by a thin deposit of one or more dark Mn oxide phases intermixed with sulfate minerals. We infer from these unique Pinnacle Island and Stuart Island rock measurements that subsurface precipitation of sulfate-dominated coatings was followed by an interval of partial dissolution and reaction with one or more strong oxidants (e.g., O_2) to produce the Mn oxide mineral(s) intermixed with sulfate-rich salt coatings. In contrast to arid regions on Earth, where Mn oxides are widely incorporated into coatings on surface rocks, our results demonstrate that on Mars the most likely place to deposit and preserve Mn oxides was in fracture zones where migrating fluids intersected surface oxidants, forming precipitates shielded from subsequent physical erosion.

Gale crater is a ~154-km-diameter impact crater formed during the Late Noachian/Early Hesperian at the dichotomy boundary on Mars. Here we describe potential evidence for ancient glacial, periglacial and fluvial (including glacio-fluvial) activity within Gale crater, and the former presence of ground ice and lakes. Our interpretations are derived from morphological observations using high-resolution datasets, particularly HiRISE and HRSC. We highlight a potential ancient lobate rock–glacier complex in parts of the northern central mound, with further suggestions of glacial activity in the large valley systems towards the southeast central mound. Wide expanses of ancient ground ice may be indicated by evidence for very cohesive ancient river banks and for the polygonal patterned ground common on the crater floor west of the central mound. We extend the interpretation to fluvial and lacustrine activity to the west of the central mound, as recorded by a series of interconnected canyons, channels and a possible lake basin. The emerging picture from our regional landscape analyses is the hypothesis that rock glaciers may have formerly occupied the central mound. The glaciers would have provided the liquid water required for carving the canyons and channels. Associated glaciofluvial activity could have led to liquid water running over ground ice-rich areas on the basin floor, with resultant formation of partially and/or totally ice-covered lakes in parts of the western crater floor. All this hydrologic activity is Hesperian or younger. Following this, we envisage a time of drying, with the generation of polygonal patterned ground and dune development subsequent to the disappearance of the surface liquid and frozen water.

The Sample Analysis at Mars (SAM) instrument suite detected SO2, H2S, OCS, and CS2 from ~450 to 800°C during evolved gas analysis (EGA) of materials from the Rocknest aeolian deposit in Gale Crater, Mars. This was the first detection of evolved sulfur species from a Martian surface sample during in situ EGA. SO2 (~3–22 µmol) is consistent with the thermal decomposition of Fe sulfates or Ca sulfites, or evolution/desorption from sulfur-bearing amorphous phases. Reactions between reduced sulfur phases such as sulfides and evolved O2 or H2O in the SAM oven are another candidate SO2 source. H2S (~41–109 nmol) is consistent with interactions of H2O, H2 and/or HCl with reduced sulfur phases and/or SO2 in the SAM oven. OCS (~1–5 nmol) and CS2 (~0.2–1 nmol) are likely derived from reactions between carbon-bearing compounds and reduced sulfur. Sulfates and sulfites indicate some aqueous interactions, although not necessarily at the Rocknest site; Fe sulfates imply interaction with acid solutions whereas Ca sulfites can form from acidic to near-neutral solutions. Sulfides in the Rocknest materials suggest input from materials originally deposited in a reducing environment or from detrital sulfides from an igneous source. The presence of sulfides also suggests that the materials have not been extensively altered by oxidative aqueous weathering. The possibility of both reduced and oxidized sulfur compounds in the deposit indicates a nonequilibrium assemblage. Understanding the sulfur mineralogy in Rocknest materials, which exhibit chemical similarities to basaltic fines analyzed elsewhere on Mars, can provide insight in to the origin and alteration history of Martian surface materials.

The Sample Analysis at Mars (SAM) instrument on the Mars Science Laboratory (MSL) rover Curiosity detected evolved gases during thermal analysis of soil samples from the Rocknest aeolian deposit in Gale Crater. Major species detected (in order of decreasing molar abundance) were H₂O, SO₂, CO₂, and O₂, all at the µmol level, with HCl, H₂S, NH₃, NO, and HCN present at the tens to hundreds of nmol level. We compute weight % numbers for the major gases evolved by assuming a likely source and calculate abundances between 0.5 and 3 wt.%. The evolution of these gases implies the presence of both oxidized (perchlorates) and reduced (sulfides or H-bearing) species as well as minerals formed under alkaline (carbonates) and possibly acidic (sulfates) conditions. Possible source phases in the Rocknest material are hydrated amorphous material, minor clay minerals, and hydrated perchlorate salts (all potential H₂O sources), carbonates (CO₂), perchlorates (O₂ and HCl), and potential N-bearing materials (e.g., Martian nitrates, terrestrial or Martian nitrogenated organics, ammonium salts) that evolve NH₃, NO, and/or HCN. We conclude that Rocknest materials are a physical mixture in chemical disequilibrium, consistent with aeolian mixing, and that although weathering is not extensive, it may be ongoing even under current Martian surface conditions.

We synthesize multivariate correlation and regression methods to characterize unique relationships among compositional and physical properties of a planetary surface locally, regionally, and globally. Martian data including elemental mass fractions, areal fractions of mineral types, and thermal inertia constitute our case study. We incorporate techniques to address the effects of spatial autocorrelation and heteroscedasticity. We also utilize method and fit diagnostics. While the Mars Odyssey and Mars Global Surveyor missions provide the exploratory context in our discussion, our approach is applicable whenever the interrelationships of spatially binned data of continuous-valued planetary attributes are sought. For example, our regional-scale case study reinforces the strength of the spatial correlation among K, Th, and the dominant mineralogic type within northern low albedo regions (surface type 2) of Mars. Recent chemical and mineralogic data from the MESSENGER mission at Mercury and Dawn at Vesta may be analyzed effectively with these hierarchical regression methods to constrain geochemical processes. Likewise, our algorithm could be applied locally with the wide variety of compositional data expected from the MSL mission at Gale Crater in general, and the ChemCam sampling grids in particular.

Young gullies and gully deposits on walls of martian craters have been cited as evidence that liquid water flowed on the surface of Mars relatively recently. Effects of variable environmental conditions at the surface of Mars are modeled and applied to the case of groundwater emergence from shallow aquifers to investigate whether groundwater is a viable source to enable the erosion of these gullies. The model includes detailed treatment of ice growth in the aquifer. Model results indicate that groundwater discharge can be maintained under the current environmental conditions if the aquifer permeability is like that of terrestrial gravel or higher, if the aquifer is 350 K or warmer, or if the aquifer is a brine with a freezing point depressed to 250 K or below. Groundwater discharge cannot be maintained for the conservative case of a cold, pure water, semi-pervious aquifer. Cold (275 K) pure water pervious (gravel) aquifers, warm (350 K) pure water semi-pervious aquifers, and cold (275 K) CaCl2 brine semi-pervious aquifers all exhibit a dependence of discharge on season, latitude and slope orientation in our modeling. Seasonal, latitudinal and azimuthal discharge variations are strongest for cold CaCl2 brine semi-pervious aquifers, with discharges from this aquifer type favoring equator-facing slopes at mid and high southern latitudes. At all latitudes and slope azimuths under our nominal conditions, the cold pure water pervious aquifer, the cold pure water semi-pervious aquifer and the cold CaCl2 brine semi-pervious aquifer all freeze completely shortly after the simulations are started. Discharge restarts in the summer for the cold pure water pervious aquifer and the cold brine aquifer, but discharge does not restart for the cold pure water semi-pervious aquifer. The warm pure water semi-pervious aquifer maintains daily seeps throughout the year at all but high latitudes. In the case of the cold pure water pervious aquifer, approximately 500,000 m3 of water could be discharged from a mid-latitude, 150-m thick aquifer with a 20-m wide seepage face orientated towards the equator or the pole after a single undermining-induced event before ice growth seals the seepage face. For a brine semi-pervious aquifer with the same dimensions, 200–300 m3 of water could be released from a mid-latitude 20-m wide equator-facing seepage face before the fresh exposure is sealed for the fall and winter seasons. Our results do not rule out groundwater emergence as a means of creating some recent gullies, but they indicate that rather special and perhaps unusual conditions would be required.

We present observations and models that together explain many hallmarks of the structure and growth of small impact craters forming in targets with aligned fractures. Endurance Crater at Meridiani Planum on Mars (diameter ≈ 150 m) formed in horizontally-layered aeolian sandstones with a prominent set of wide, orthogonal joints. A structural model of Endurance Crater is assembled and used to estimate the transient crater planform. The model is based on observations from the Mars Exploration Rover Opportunity: (a) bedding plane orientations and layer thicknesses measured from stereo image pairs; (b) a digital elevation model of the whole crater at 0.3 m resolution; and (c) color image panoramas of the upper crater walls. This model implies that the crater’s current shape was mostly determined by highly asymmetric excavation rather than long-term wind-mediated erosion. We show that modal azimuths of conjugate fractures in the surrounding rocks are aligned with the square component of the present-day crater planform, suggesting excavation was carried farther in the direction of fracture alignments. This was previously observed at Barringer Crater in Arizona and we show the same relationship also holds for Tswaing Crater in South Africa. We present models of crater growth in which excavation creates a “stellate” transient cavity that is concave–cuspate in planform. These models reproduce the “lenticular-crescentic” layering pattern in the walls of some polygonal impact craters such as Endurance and Barringer Craters, and suggest a common origin for tear faults and some crater rays. We also demonstrate a method for detailed error analysis of stereogrammetric measurements of bedding plane orientations.

The region surrounding the Mawrth Vallis outflow channel on Mars hosts thick layered deposits containing diverse phyllosilicate minerals. Here we report detection of the Ca-sulfate bassanite on the outflow channel floor, requiring a more complex aqueous chemistry than previously inferred for this region. The sulfate-bearing materials underlie phyllosilicate-bearing strata, and provide an opportunity for testing proposed models of martian geochemical evolution with a future landed mission.

The Mars Odyssey Gamma Ray Spectrometer has yielded planetary data of global extent. Such remote-sensing missions usually assign the value of a continuous-valued geospatial attribute to a uniform latitude-longitude grid of bins. Typical attributes include elemental-mass fraction, areal fraction of a mineral type, areal fraction of rocks, thermal inertia, etc. The fineness of the grid is chosen according to the spatial resolution of the orbiter and concomitant data processing. We describe methods to maximize the information extracted from both bin and regional data. Rigorous use of statistical parameters and related methods for inter- and intra- regional comparisons are also discussed. While we discuss results from the Mars Odyssey mission, the techniques we describe are applicable whenever continuous-valued attributes of a planet's surface are characterized with bins and regions. Our goal is to distill the simplest statistical methods for regional comparisons that would be intuitively accessible to planetary scientists.

The High Resolution Imaging Science Experiment (HiRISE) on the Mars Reconnaissance Orbiter (MRO) acquired 8 terapixels of data in 9137 images of Mars between October 2006 and December 2008, covering ~0.55% of the surface. Images are typically 5–6 km wide with 3-color coverage over the central 20% of the swath, and their scales usually range from 25 to 60 cm/pixel. Nine hundred and sixty stereo pairs were acquired and more than 50 digital terrain models (DTMs) completed; these data have led to some of the most significant science results. New methods to measure and correct distortions due to pointing jitter facilitate topographic and change-detection studies at sub-meter scales. Recent results address Noachian bedrock stratigraphy, fluvially deposited fans in craters and in or near Valles Marineris, groundwater flow in fractures and porous media, quasi-periodic layering in polar and non-polar deposits, tectonic history of west Candor Chasma, geometry of clay-rich deposits near and within Mawrth Vallis, dynamics of flood lavas in the Cerberus Palus region, evidence for pyroclastic deposits, columnar jointing in lava flows, recent collapse pits, evidence for water in well-preserved impact craters, newly discovered large rayed craters, and glacial and periglacial processes. Of particular interest are ongoing processes such as those driven by the wind, impact cratering, avalanches of dust and/or frost, relatively bright deposits on steep gullied slopes, and the dynamic seasonal processes over polar regions. HiRISE has acquired hundreds of large images of past, present and potential future landing sites and has contributed to scientific and engineering studies of those sites. Warming the focal-plane electronics prior to imaging has mitigated an instrument anomaly that produces bad data under cold operating conditions.

High-resolution spectral images reveal many new exposures of hydrated minerals across the Noachian southern highlands of Mars. Several different phyllosilicates are observed, with inferred accompanying phases ranging from zeolites to sulfates to chlorides, each in distinct geologic settings. Hydrated sulfates are observed in several locations at mid-latitudes, and likely formed independently from the equatorial sulfates. These assemblages suggest a greater diversity of aqueous environments on ancient Mars than has previously been recognized, and their distribution implies that alteration was widespread during the Noachian Period, not restricted to a few locations.

This study investigates three bedrock exposures at Erebus crater, an ~ 300 m diameter crater approximately 4 km south of Endurance crater on Mars. These outcrops, called Olympia, Payson, and Yavapai, provide additional evidence in support of the dune–interdune model proposed for the formation of the deposits at the Opportunity landing site in Meridiani Planum. There is evidence for greater involvement of liquid water in the Olympia outcrop exposures than was observed in Eagle or Endurance craters. The Olympia outcrop likely formed in a wet interdune and sand sheet environment. The facies observed within the Payson outcrop, which is likely stratigraphically above the Olympia outcrop, indicate that it was deposited in a damp-wet interdune, sand sheet, and eolian dune environment. The Yavapai outcrop, which likely stratigraphically overlies the Payson outcrop, indicates that it was deposited in primarily a sand sheet environment and also potentially in an eolian dune environment. These three outcrop exposures may indicate an overall drying-upward trend spanning the stratigraphic section from its base at the Olympia outcrop to its top at the Yavapai outcrop. This contrasts with the wetting-upward trend seen in Endurance and Eagle craters. Thus, the series of outcrops seen at Meridiani by Opportunity may constitute a full climatic cycle, evolving from dry to wet to dry conditions.

Water has supposedly marked the surface of Mars and produced characteristic landforms. To understand the history of water on Mars, we take a close look at key locations with the High-Resolution Imaging Science Experiment on board the Mars Reconnaissance Orbiter, reaching fine spatial scales of 25 to 32 centimeters per pixel. Boulders ranging up to approximately 2 meters in diameter are ubiquitous in the middle to high latitudes, which include deposits previously interpreted as finegrained ocean sediments or dusty snow. Bright gully deposits identify six locations with very recent activity, but these lie on steep (20 degrees to 35 degrees) slopes where dry mass wasting could occur. Thus, we cannot confirm the reality of ancient oceans or water in active gullies but do see evidence of fluvial modification of geologically recent mid-latitude gullies and equatorial impact craters.

Home Plate is a layered plateau in Gusev crater on Mars. It is composed of clastic rocks of moderately altered alkali basalt composition, enriched in some highly volatile elements. A coarsegrained lower unit lies under a finer-grained upper unit. Textural observations indicate that the lower strata were emplaced in an explosive event, and geochemical considerations favor an explosive volcanic origin over an impact origin. The lower unit likely represents accumulation of pyroclastic materials, whereas the upper unit may represent eolian reworking of the same pyroclastic materials.

An edited version of this paper was published by AGU. Copyright (2015) American Geophysical Union, Lithium (Li), the lightest of the alkali elements, has geochemical properties that include high aqueous solubility (Li is the most fluid mobile element) and high relative abundance in basalt-forming minerals (values ranking between 0.2 and 12 ppm). Li isotopes are particularly subject to fractionation because the two stable isotopes of lithium - 7Li and 6Li - have a large relative mass difference (∼15%) that results in significant fractionation between water and solid phases. The extent of Li isotope fractionation during aqueous alteration of basalt depends on the dissolution rate of primary minerals - the source of Li - and on the precipitation kinetics, leading to formation of secondary phases. Consequently, a detailed analysis of Li isotopic ratios in both solution and secondary mineral lattices could provide clues about past Martian weathering conditions, including weathering extent, temperature, pH, supersaturation, and evaporation rate of the initial solutions in contact with basalt rocks. In this paper, we discuss ways in which Martian aqueous processes could have lead to Li isotope fractionation. We show that Li isotopic data obtained by future exploration of Mars could be relevant to highlighting different processes of Li isotopic fractionation in the past, and therefore to understanding basalt weathering and environmental conditions early in the planet's history, Data supporting our models and calculations are available as supporting information. The research leading to these results is a contribution from the Project ‘icyMARS’’, funded by the European Research Council, Starting Grant no 307496. This work was also partially supported by the European FEDER program and the Spanish Ministry of Science (MICINN) through the project CGL2011–30079. Comments by R. James and four anonymous reviewers helped us to clarify and strengthen our work

Compact Reconnaissance Imaging Spectrometer for Mars hyperspectral (1.0–2.65 µm) along-track oversampled observations covering Victoria, Santa Maria, Endeavour, and Ada craters were processed to 6 m/pixel and used in combination with Opportunity observations to detect and map hydrated Mg and Ca sulfate minerals in the Burns formation. The strongest spectral absorption features were found to be associated with outcrops that are relatively young and fresh (Ada) or preferentially scoured of dust, soil, and coatings by prevailing winds. At Victoria and Santa Maria, the scoured areas are on the southeastern rims and walls, opposite to the sides where wind-blown sands extend out of the craters. At Endeavour, the deepest absorptions are in Botany Bay, a subdued and buried rim segment that exhibits high thermal inertias, extensive outcrops, and is interpreted to be a region of enhanced wind scour extending up and out of the crater. Ada, Victoria, and Santa Maria outcrops expose the upper portion of the preserved Burns formation and show spectral evidence for the presence of kieserite. In contrast, gypsum is pervasive spectrally in the Botany Bay exposures. Gypsum, a relatively insoluble evaporative mineral, is interpreted to have formed close to the contact with the Noachian crust as rising groundwaters brought brines close to and onto the surface, either as a direct precipitate or during later diagenesis. The presence of kieserite at the top of the section is hypothesized to reflect precipitation from evaporatively concentrated brines or dehydration of polyhydrated sulfates, in both scenarios as the aqueous environment evolved to very arid conditions.

The Sample Analysis at Mars (SAM) instrument on board the Mars Science Laboratory Curiosity rover is designed to conduct inorganic and organic chemical analyses of the atmosphere and the surface regolith and rocks to help evaluate the past and present habitability potential of Mars at Gale Crater. Central to this task is the development of an inventory of any organic molecules present to elucidate processes associated with their origin, diagenesis, concentration, and long-term preservation. This will guide the future search for biosignatures. Here we report the definitive identification of chlorobenzene (150–300 parts per billion by weight (ppbw)) and C2 to C4 dichloroalkanes (up to 70 ppbw) with the SAM gas chromatograph mass spectrometer (GCMS) and detection of chlorobenzene in the direct evolved gas analysis (EGA) mode, in multiple portions of the fines from the Cumberland drill hole in the Sheepbed mudstone at Yellowknife Bay. When combined with GCMS and EGA data from multiple scooped and drilled samples, blank runs, and supporting laboratory analog studies, the elevated levels of chlorobenzene and the dichloroalkanes cannot be solely explained by instrument background sources known to be present in SAM. We conclude that these chlorinated hydrocarbons are the reaction products of Martian chlorine and organic carbon derived from Martian sources (e.g., igneous, hydrothermal, atmospheric, or biological) or exogenous sources such as meteorites, comets, or interplanetary dust particles. Key Points First in situ evidence of nonterrestrial organics in Martian surface sediments Chlorinated hydrocarbons identified in the Sheepbed mudstone by SAM Organics preserved in sample exposed to ionizing radiation and oxidative condition

The Mars Exploration Rover Opportunity has spent more than 2 years exploring Meridiani Planum, traveling ∼8 kilometers and detecting features that reveal ancient environmental conditions. These include well-developed festoon (trough) cross-lamination formed in flowing liquid water, strata with smaller and more abundant hematite-rich concretions than those seen previously, possible relict “hopper crystals” that might reflect the formation of halite, thick weathering rinds on rock surfaces, resistant fracture fills, and networks of polygonal fractures likely caused by dehydration of sulfate salts. Chemical variations with depth show that the siliciclastic fraction of outcrop rock has undergone substantial chemical alteration from a precursor basaltic composition. Observations from microscopic to orbital scales indicate that ancient Meridiani once had abundant acidic groundwater, arid and oxidizing surface conditions, and occasional liquid flow on the surface.

Impure reworked evaporitic sandstones, preserved on Meridiani Planum, Mars, are mixtures of roughly equal amounts of altered siliciclastic debris, of basaltic provenance (40 ± 10% by mass), and chemical constituents, dominated by evaporitic minerals (jarosite, Mg-, Ca-sulfates ± chlorides ± Fe-, Na-sulfates), hematite and possibly secondary silica (60 ± 10%). These chemical constituents and their relative abundances are not an equilibrium evaporite assemblage and to a substantial degree have been reworked by aeolian and subaqueous transport. Ultimately they formed by evaporation of acidic waters derived from interaction with olivine-bearing basalts and subsequent diagenetic alteration. The rocks experienced an extended diagenetic history, with at least two and up to four distinct episodes of cementation, including stratigraphically restricted zones of recrystallization and secondary porosity, non-randomly distributed, highly spherical millimeter-scale hematitic concretions, millimeter-scale crystal molds, interpreted to have resulted from dissolution of a highly soluble evaporite mineral, elongate to sheet-like vugs and evidence for minor synsedimentary deformation (convolute and contorted bedding, possible teepee structures or salt ridge features). Other features that may be diagenetic, but more likely are associated with relatively recent meteorite impact, are meter-scale fracture patterns, veins and polygonal fractures on rock surfaces that cut across bedding. Crystallization of minerals that originally filled the molds, early cement and sediment deformation occurred syndepositionally or during early diagenesis. All other diagenetic features are consistent with formation during later diagenesis in the phreatic (fluid saturated) zone or capillary fringe of a groundwater table under near isotropic hydrological conditions such as those expected during periodic groundwater recharge. Textural evidence suggests that rapidly formed hematitic concretions post-date the primary mineral now represented by crystal molds and early pore-filling cements but pre-date secondary moldic and vug porosity. The second generation of cements followed formation of secondary porosity. This paragenetic sequence is consistent with an extended history of syndepositional through post-depositional diagenesis in the presence of a slowly fluctuating, chemically evolving, but persistently high ionic strength groundwater system.

Outcrop exposures of sedimentary rocks at the Opportunity landing site (Meridiani Planum) form a set of genetically related strata defined here informally as the Burns formation. This formation can be subdivided into lower, middle, and upper units which, respectively, represent eolian dune, eolian sand sheet, and mixed eolian sand sheet and interdune facies associations. Collectively, these three units are at least 7 m thick and define a "wetting-upward" succession which records a progressive increase in the influence of groundwater and, ultimately, surface water in controlling primary depositional processes. The Burns lower unit is interpreted as a dry dune field (though grain composition indicates an evaporitic source), whose preserved record of large-scale cross-bedded sandstones indicates either superimposed bedforms of variable size or reactivation of lee-side slip faces by episodic (possibly seasonal) changes in wind direction. The boundary between the lower and middle units is a significant eolian deflation surface. This surface is interpreted to record eolian erosion down to the capillary fringe of the water table, where increased resistance to wind-induced erosion was promoted by increased sediment cohesiveness in the capillary fringe. The overlying Burns middle unit is characterized by fine-scale planar-laminated to low-angle-stratified sandstones. These sandstones accumulated during lateral migration of eolian impact ripples over the flat to gently undulating sand sheet surface. In terrestrial settings, sand sheets may form an intermediate environment between dune fields and interdune or playa surfaces. The contact between the middle and upper units of the Burns formation is interpreted as a diagenetic front, where recrystallization in the phreatic or capillary zones may have occurred. The upper unit of the Burns formation contains a mixture of sand sheet facies and interdune facies. Interdune facies include wavy bedding, irregular lamination with convolute bedding and possible small tepee or salt-ridge structures, and cm-scale festoon cross-lamination indicative of shallow subaqueous flows marked by current velocities of a few tens of cm/s. Most likely, these currents were gravity-driven, possibly unchannelized flows resulting from the flooding of interdune/ playa surfaces. However, evidence for lacustrine sedimentation, including mudstones or in situ bottom-growth evaporites, has not been observed so far at Eagle and Endurance craters. Mineralogical and elemental data indicate that the eolian sandstones of the lower and middle units, as well as the subaqueous and eolian deposits of the Burns upper unit, were derived from an evaporitic source. This indirectly points to a temporally equivalent playa where lacustrine evaporites or ground-water-generated efflorescent crusts were deflated to provide a source of sand-sized particles that were entrained to form eolian dunes and sand sheets. This process is responsible for the development of sulfate eolianites at White Sands, New Mexico, and could have provided a prolific flux of sulfate sediment at Meridiani. Though evidence for surface water in the Burns formation is mostly limited to the upper unit, the associated sulfate eolianites provide strong evidence for the critical role of groundwater in controlling sediment production and stratigraphic architecture throughout the formation. B) 2005 Elsevier B.V. All rights reserved.

Analyses of outcrops created by the impact craters Endurance, Fram and Eagle reveal the broad lateral continuity of chemical sediments at the Meridiani Planum exploration site on Mars. Approximately ten mineralogical components are implied in these salt-rich silicic sediments, from measurements by instruments on the Opportunity rover. Compositional trends in an apparently intact vertical stratigraphic sequence at the Karatepe West ingress point at Endurance crater are consistent with non-uniform deposition or with subsequent migration of mobile salt components, dominated by sulfates of magnesium. Striking variations in Cl and enrichments of Br, combined with diversity in sulfate species, provide further evidence of episodes during which temperatures, pH, and water to rock ratios underwent significant change. To first order, the sedimentary sequence examined to date is consistent with a uniform reference composition, modified by movement of major sulfates upward and of minor chlorides downward. This reference composition has similarities to martian soils, supplemented by sulfate anion and the alteration products of mafic igneous minerals. Lesser cementation in lower stratigraphic units is reflected in decreased energies for grinding with the Rock Abrasion Tool. Survival of soluble salts in exposed outcrop is most easily explained by absence of episodes of liquid H2O in this region since the time of crater formation.

The MER rover Opportunity has carried out the first outcrop-scale investigation of ancient sedimentary rocks on Mars. The rocks, exposed in craters and along fissures in Meridiani Planum, are sandstones formed via the erosion and re-deposition of fine grained siliciclastics and evaporites derived from the chemical weathering of olivine basalts by acidic waters. A stratigraphic section more than seven meters thick measured in Endurance crater is dominated by eolian dune and sand sheet facies; the uppermost half meter, however, exhibits festoon cross lamination at a length scale that indicates subaqueous deposition, likely in a playa-like interdune setting. Silicates and sulfate minerals dominate outcrop geochemistry, but hematite and Fe3D3 (another ferric iron phase) make up as much as 11% of the rocks by weight. Jarosite in the outcrop matrix indicates precipitation at low pH. Cements, hematitic concretions, and crystal molds attest to a complex history of early diagenesis, mediated by ambient ground waters. The depositional and early diagenetic paleoenvironment at Meridiani was arid, acidic, and oxidizing, a characterization that places strong constraints on astrobiologial inference.

New data returned from the Mars Exploration Rover (MER) mission have revealed abundant evaporites in the sedimentary record at Meridiani Planum. A working hypothesis for Meridiani evaporite formation involves the evaporation of fluids derived from the weathering of martian basalt and subsequent diagenesis. On Earth, evaporite formation in exclusively basaltic settings is rare. However, models of the evaporation of fluids derived from experimentally weathering synthetic martian basalt provide insight into possible formation mechanisms. The thermodynamic database assembled for this investigation includes both Fe2+ and Fe3+ in Pitzer's ion interaction equations to evaluate Fe redox disequilibrium at Meridiani Planum. Modeling results suggest that evaporation of acidic fluids derived from weathering olivine-bearing basalt should produce Mg, Ca, and Fe-sulfates such as jarosite and melanterite. Calculations that model diagenesis by fluid recharge predict the eventual breakdown of jarosite to goethite as well as the preservation of much of the initial soluble evaporite component at modeled porosity values appropriate for relevant depositional environments (< 0.30). While only one of several possible formation scenarios, this simple model is consistent with much of the chemical and mineralogical data obtained on Meridiani Planum outcrop. B) 2005 Elsevier B.V. All rights reserved.

This paper presents the initial results of lander and rover localization and topographic mapping of the MER 2003 mission (by Sol 225 for Spirit and Sol 206 for Opportunity). The Spirit rover has traversed a distance of 3.2 km (actual distance traveled instead of odometry) and Opportunity at 1.2 km. We localized the landers in the Gusev Crater and on the Meridiani Planum using two-way Doppler radio positioning technology and cartographic triangulations through landmarks visible in both orbital and ground images. Additional high-resolution orbital images were taken to verify the determined lander positions. Visual odometry and bundleadjustment technologies were applied to overcome wheel slippages, azimuthal angle drift and other navigation errors (as large as 21 percent). We generated timely topographic products including 68 orthophoto maps and 3D Digital Terrain Models, eight horizontal rover traverse maps, vertical traverse profiles up to Sol 214 for Spirit and Sol 62 for

The cover shows part of the Larry's Lookout panorama, seen from the Mars Exploration Rover (MER) Spirit during its drive up Husband Hill: the summit is about 200 metres from the rover. Six papers this week report in detail on the MER mission. An Analysis compares predictions used to select a landing site with the conditions actually encountered. This ‘ground truth’ will be invaluable for interpreting future remote-sensing data. Surface chemistry suggests that the upper layer of soil may contain 1% meteoritic material. MER provides a unique glimpse of solar transits of the moons Phobos and Deimos. Rover Opportunity examined wind-related processes, and spectroscopy indicates a dry origin for atmospheric dust. Features from within the Gusev crater give more information on the role of liquid water in Mars's past. An accompanying News and Views puts the MER data in context. Gusev crater was selected as the landing site for the Spirit rover because of the possibility that it once held a lake. Thus one of the rover's tasks was to search for evidence of lake sediments1. However, the plains at the landing site were found to be covered by a regolith composed of olivine-rich basaltic rock and windblown ‘global’ dust2. The analyses of three rock interiors exposed by the rock abrasion tool showed that they are similar to one another, consistent with having originated from a common lava flow3,4,5,6,7,8. Here we report the investigation of soils, rock coatings and rock interiors by the Spirit rover from sol (martian day) 1 to sol 156, from its landing site to the base of the Columbia hills. The physical and chemical characteristics of the materials analysed provide evidence for limited but unequivocal interaction between water and the volcanic rocks of the Gusev plains. This evidence includes the softness of rock interiors that contain anomalously high concentrations of sulphur, chlorine and bromine relative to terrestrial basalts and martian meteorites9; sulphur, chlorine and ferric iron enrichments in multilayer coatings on the light-toned rock Mazatzal; high bromine concentration in filled vugs and veins within the plains basalts; positive correlations between magnesium, sulphur and other salt components in trench soils; and decoupling of sulphur, chlorine and bromine concentrations in trench soils compared to Gusev surface soils, indicating chemical mobility and separation.

The Mars Exploration Rover Opportunity has investigated the landing site in Eagle crater and the nearby plains within Meridiani Planum. The soils consist of fine-grained basaltic sand and a surface lag of hematite-rich spherules, spherule fragments, and other granules. Wind ripples are common. Underlying the thin soil layer, and exposed within small impact craters and troughs, are flat-lying sedimentary rocks. These rocks are finely laminated, are rich in sulfur, and contain abundant sulfate salts. Small-scale cross-lamination in some locations provides evidence for deposition in flowing liquid water. We interpret the rocks to be a mixture of chemical and siliciclastic sediments formed by episodic inundation by shallow surface water, followed by evaporation, exposure, and desiccation. Hematite-rich spherules are embedded in the rock and eroding from them. We interpret these spherules to be concretions formed by postdepositional diagenesis, again involving liquid water.

The Spirit landing site in Gusev Crater on Mars contains dark, fine-grained, vesicular rocks interpreted as lavas. Pancam and Mini–Thermal Emission Spectrometer (Mini-TES) spectra suggest that all of these rocks are similar but have variable coatings and dust mantles. Magnified images of brushed and abraded rock surfaces show alteration rinds and veins. Rock interiors contain ≤25% megacrysts. Chemical analyses of rocks by the Alpha Particle X-ray Spectrometer are consistent with picritic basalts, containing normative olivine, pyroxenes, plagioclase, and accessory FeTi oxides. Mössbauer, Pancam, and Mini-TES spectra confirm the presence of olivine, magnetite, and probably pyroxene. These basalts extend the known range of rock compositions composing the martian crust.

A two-plus year process of identifying and evaluating landing sites for the NASA 2003 Mars Exploration Rovers began with definition of mission science objectives, preliminary engineering requirements, and identification of ∼155 potential sites in near-equator locations (these included multiple ellipses for locations accessible by both rovers). Four open workshops were used together with ongoing engineering evaluations to narrow the list of sites to four: Meridiani Planum and Gusev Crater were ranked highest for science, with southern Isidis Basin and a “wind safe” site in Elysium following in order. Based on exhaustive community assessment, these sites comprise the best-studied locales on Mars and should possess attributes enabling mission success.

The excitement of NASA, space exploration, and robotic missions provides a natural entry point to engage students in learning about math, science, and technology. Pairing them in a research partnership with scientists and engineers allows them to discover real world applications for that knowledge. Over three years, the LAPIS program has involved students in active, hands-on research with the prototype rover for the 2003–2004 Mars Exploration Rover mission and scientists associated with its Athena Science Investigation. The result has been an experience that positively impacts the scientists, teachers, and students involved, and provides additional information on using the rover to acquire scientific data. Using a participatory evaluation process, empowerment evaluation, the participants have helped improve the program and provided a model for an outreach program associated with the twin rovers of the 2003–2004 Mars mission, the Athena Student Interns Program.

With widespread evidence of both heat sources and water (either liquid or solid), hydrothermal systems are likely to have existed on Mars. We model hydrothermal systems in two sizes of fresh impact craters, one simple and one complex, and find that a hydrothermal system forms on the crater floor. In the larger complex craters with a substantial melt sheet, a lake can form, even under current martian atmospheric conditions. By comparing these hydrothermal systems to those that exist and have been studied extensively on the Earth, we make predictions as to the types of minerals that could be precipitated and the potential habitability of such systems by primitive organisms.

We report major element ratios determined for the S-class asteroid 433 Eros using remote- sensing x-ray fluorescence spectroscopy with the near-Earth asteroid rendezvous Shoemaker x-ray spectrometer (XRS). Data analysis techniques and systematic errors are described in detail. Data acquired during five solar flares and during two extended "quiet Sun" periods are presented; these results sample a representative portion of the asteroid's surface. Although systematic uncertainties are potentially large, the most internally consistent and plausible interpretation of the data is that Eros has primitive Mg/Si, Al/Si, Ca/Si and Fe/Si ratios, closely similar to H or R chondrites. Global differentiation of the asteroid is ruled out. The S/Si ratio is much lower than that of chondrites, probably reflecting impact-induced volatilization and/or photo- or ion-induced sputtering of sulfur at the surface of the asteroid. An alternative explanation for the low S/Si ratio is that it reflects a limited degree of melting with loss of an FeS-rich partial melt. Size-sorting processes could lead to segregation of Fe-Ni metal from silicates within the regolith of Eros; this could indicate that the Fe/Si ratios determined by the x-ray spectrometer are not representative of the bulk Eros composition.

Most small valleys in the ancient highlands of Mars are probably the result of erosion by groundwater sapping. This conclusion together with the fact that liquid water is thermodynamically unstable on the surface of Mars today is frequently used to argue that the planet was warmer in the past. The strength of these arguments is tested by examining the effectiveness of the sapping mechanism under various climatic and hydrologic conditions, including aquifer permeability, aquifer temperature, sediment grain size, wind speed at the surface, latitude, and obliquity. Numerical simulations of groundwater sapping under different conditions indicate that the link between the small valleys and a warmer early martian climate is not as strong as is often assumed. If water in the upper few hundred meters of the martian regolith had been kept above the freezing point through hydrothermal circulation or conduction of geothermal heat, then the small martian valleys could have formed by groundwater sapping under climatic conditions like those that prevail today, especially if the permeability of the martian regolith is like that of terrestrial gravels. Geothermal warming to temperatures well above the freezing point would have greatly facilitated sapping. The current low-pressure atmosphere is more conducive to the sapping process (though not necessarily to subsequent stream flow) than a high-pressure atmosphere that is only slightly warmer.

With plans for multiple sample return missions in the next decade, NASA requested guidance from the National Research Council's SSB on how to treat samples returned from solar system bodies such as planetary satellites, asteroids and comets. A special Task Group assessed the potential for a living entity to be included in return samples from various bodies as well as the potential for large scale effects if such an entity were inadvertently introduced into the Earth's biosphere. The Group also assessed differences among solar system bodies, identified investigations that could reduce uncertainty about the bodies, and considered risks of returned samples compared to natural influx of material to the Earth in the form of interplanetary dust particles, meteorites and other small impactors. The final report (NRC, 1998) provides a decision making framework for future missions and makes recommendations on how to handle samples from different planetary satellites and primitive solar system bodies.

Beta Regio is an area of rifting and volcanism on Venus, constituting a topographic rise. A shield volcano, Theia Mons, lies near the center of the region and is surrounded by several radially oriented rifts. We use Magellan altimetry, gravity, and synthetic aperture radar data of the area to constrain some subsurface parameters. First, we derive hoop strain. Using altimetry data and a fault dip angle derived from the split crater Somerville, we determine the extension in the rifts surrounding Beta Regio. We then derive the hoop strain accommodated by the rifts from the extension in these rifts. Except near Theia Mons, the hoop strain follows the shape expected from a mantle upwelling. The difference near the volcano, we believe, is due to volcanic infilling. We then model three observable quantities, the newly derived strain along with gravity and uplift, using two separate modeling techniques, one for the strain and uplift and another for the gravity. The model results show that the data are consistent with the view that a relatively low density contrast region now exists below Beta and has caused the uplift and rifting in the region.

Early examinations of Galileo images of Europa revealed features that look like low topographic domes. These small (5–10 km in radius) domes have been interpreted as surface manifestations of diapirs. As a way to probe the subsurface structure of Europa, we investigate the possibility that thermally-driven ice diapirism created these surface features. We use a previously developed analytic model for rising diapirs to estimate the initial radii of the diapirs, their initial depth, the temperature of the medium through which they rise and their formation timescales. We assume that the diapirs originate at the boundary layer between solid ice and whatever underlies it, whether it be liquid water or solid rock. Our results show that the diapirs originate at a depth of no more than a few tens of kilometers. Since the H2O layer on Europa is substantially thicker than this, our results support the view that liquid water recently existed beneath the ice on Europa at this location, at a depth of no more than a few tens of kilometers. Further, the ice must have been warm (250–270 K) and was therefore likely to have been convecting.

Rover observations and global satellite data show that the surface of Mars was wet and acidic early in its history, but rapidly became dry and oxidizing.

We develop a model of the combined thermal and mechanical evolution of diapirs in the mantle of Venus. The diapir is treated as an oblate spheroid rising through a viscous fluid and ultimately impinging on a rigid overlaying “lid”. Drag forces imposed by the lid cause the diapir to spread and flatten as it rises. We parameterize the heat loss from the rising diapir using a Nusselt number formulation and treat the resulting loss in buoyancy in our flow calculation. The model predicts the evolution timescale and degree of flattening of a diapir as it rises, as well as the stresses exerted on the underside of the lithosphere. In order to explore diapir behavior further, we check our analytical model against the predictions of the finite element code MANTLE. From the combined results of these models and observations of Venusian coronae, we are able to make a number of inferences about Venusian diapirism and mantle properties. We find that the diapirs responsible for formation of Venusian coronae have an initial size distribution extending from about 30 to 100 km in radius. Typical evolution timescales for these diapirs are 30–50 Myr. If Venus' global average resurfacing age is 300–500 Myr, then our results are consistent with a rate of diapirism that has been roughly constant over this period, and with an effective mantle viscosity of 1021 Pa s.

Conventional techniques for investigation of crater populations make use of size–frequency distributions, but typically disregard the statistical properties of the spatial distribution of craters. Cratering of a surface is generally a spatially random process, so the distributions of craters on lightly cratered surfaces can be expected to be random. As crater obliteration becomes important, however, the situation changes. Every random distribution has regions of sparseness and regions of clustering. Craters that form in areas of sparseness obliterate few older craters, so the sparseness is filled in. Craters that form in areas of clustering obliterate more older craters, relatively reducing the clustering. As sparseness is filled in and clustering is reduced, the spatial distribution should progress from one that is random to one that is more uniform than random. We show that the spatial distribution of craters on a lightly cratered lunar maria surface is consistent with randomness, but that the distributions on heavily cratered portions of Rhea and Callisto are markedly more uniform than random. We develop a simple model of crater formation and obliteration, and use it to investigate the statistical behavior of crater spatial distributions as crater “saturation” is approached. We find that the use of spatial distributions to investigate saturation is more robust to model uncertainties than is the use of crater density alone. Using a simple statistical parameter, the “ Z -statistic,” we find that ≳ 25% of the craters formed to date on our study areas on Rhea and Callisto have been obliterated by subsequent cratering. Adjusting the Z -statistic for crater floor area effects, we find evidence that crater saturation has been reached on Rhea.

Narrow-band 2.0–2.35 μm spectrophotometric observations of Jupiter at nine wavelengths were taken with the 5-m Hale Telescope at Palomar during the month following the impact of Comet P/Shoemaker–Levy 9. Spectra were obtained for the principal impact sites, and also for regions not affected by the comet impacts (the South Polar Region, North Equatorial Zone, South Equatorial Zone, and the Great Red Spot). A technique by which near-infrared reflection spectra can be inverted to yield vertical profiles of scatterer density is presented. For our wavelengths and bandwidths, the sensitivity of the inversions extends from pressure levels near 1 bar up to about 20 mbar. We find that all comet-induced aerosol clouds lie near or above the vertical limit of our sensitivity, i.e., 20 mbar. The lower limit of the clouds is around 50 mbar. The total scattering opacity of the clouds decreased by a factor of about 1.7 over the 35 days spanned by these observations, while the area covered by them increased by a factor of about 1.5. West et al. (West, R. A., E. Karkoschka, A. J. Friedson, M. Seymour, K. H. Baines, and H. B. Hammel 1995. Science 267, 1296–1301.) suggest particle coagulation during this time which fits with our observations, but particle fallout is also likely. All the aerosols comprise a volume the equivalent of a ∼ 0.6-km radius sphere assuming a particle size of 0.25 μm. We also measured the drift speeds of these clouds using two different techniques. One involved scaling down Voyager-measured cloud-top winds (Limaye, S. S. 1986. Icarus 65, 335–352.) and deforming early images to match later images, while the other involved directly cross-correlating longitudinally shifted images of spots from different times. Both techniques indicate wind speeds of order 5 m/sec, or ∼30% of the tropospheric wind speeds measured by Voyager in this region.

We present near-infrared observations from Palomar observatory of the impact of fragment R of comet Shoemaker-Levy 9 with Jupiter on 21 July 1994. Two instruments were used to image the event at 3.2 and 4.5 microns simultaneously. The lightcurves from these image sequences both show two faint precursor flashes, a bright main peak, and several oscillations over the following hour. We identify the precursor flashes with the entry of the bolide into Jupiter's upper atmosphere, and with the post-impact ejecta plume rising above the planet's limb. The main peak is due to the re-entry of the collapsing plume into Jupiter's atmosphere and the resultant shock heating.

Martian Veins After more than 7 years of traveling across the Meridiani Planum region of Mars, the Mars Exploration rover Opportunity reached the Endeavour Crater, a 22-km-impact crater made of materials older than those previously investigated by the rover. Squyres et al. (p. 570 ) present a comprehensive analysis of the rim of this crater. Localized zinc enrichments that provide evidence for hydrothermal alteration and gypsum-rich veins that were precipitated from liquid water at a relatively low temperature provide a compelling case for aqueous alteration processes in this area at ancient times.

International audience; The Sample Analysis at Mars (SAM) investigation of the Mars Science Laboratory (MSL) addresses the chemical and isotopic composition of the atmosphere and volatiles extracted from solid samples. The SAM investigation is designed to contribute substantially to the mission goal of quantitatively assessing the habitability of Mars as an essential step in the search for past or present life on Mars. SAM is a 40 kg instrument suite located in the interior of MSL's Curiosity rover. The SAM instruments are a quadrupole mass spectrometer, a tunable laser spectrometer, and a 6-column gas chromatograph all coupled through solid and gas processing systems to provide complementary information on the same samples. The SAM suite is able to measure a suite of light isotopes and to analyze volatiles directly from the atmosphere or thermally released from solid samples. In addition to measurements of simple inorganic compounds and noble gases SAM will conduct a sensitive search for organic compounds with either thermal or chemical extraction from sieved samples delivered by the sample processing system on the Curiosity rover's robotic arm.

Early in its history, Mars underwent fluvial erosion that has been interpreted as evidence for a warmer, wetter climate. However, no atmosphere composed of only CO2 and H2O appears capable of producing mean planetary temperatures even close to 0 degrees C. Rather than by precipitation, aquifer recharge and ground water seepage may have been enabled by hydrothermal convection driven by geothermal heat and heat associated with impacts. Some climatic warming was probably necessary to allow water to flow for long distances across the surface. Modest warming could be provided by even a low-pressure CO2 atmosphere if it was supplemented with small amounts of CH4, NH3, or SO2. Episodic excursions to high obliquities may also have raised temperatures over some portions of the planet's surface.