7 results on '"Stephen M. Long"'
Search Results
2. A feasibility study of disinfection by-product precursor removal from surface water by a membrane bioreactor acclimatized with wastewater organic matter
- Author
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Hao L. Tang and Stephen M. Long
- Subjects
Environmental Engineering ,Hydraulic retention time ,Microfiltration ,0208 environmental biotechnology ,Portable water purification ,02 engineering and technology ,Wastewater ,010501 environmental sciences ,Membrane bioreactor ,01 natural sciences ,Water Purification ,Bioreactors ,Bioreactor ,Organic matter ,0105 earth and related environmental sciences ,Water Science and Technology ,chemistry.chemical_classification ,Chemistry ,Water ,Disinfection by-product ,020801 environmental engineering ,Disinfection ,Environmental chemistry ,Feasibility Studies ,Water Pollutants, Chemical ,Trihalomethanes - Abstract
A membrane bioreactor (MBR) acclimatized with wastewater organic matter was employed for surface water treatment, and the feasibility of the MBR for the removal of disinfection by-product (DBP) precursors was studied. With a low pressure microfiltration hollow-fiber membrane module, a hydraulic retention time of 1.5 hours and a solids retention time of 180 days, the MBR was able to achieve 35% removal of trichloroacetic acid precursors and 21% removal of dichloroacetic acid precursors. The removal of trichloromethane (TCM) and brominated DBP precursors was unsatisfactory. The TCM yield and bromine substitution factors for trihalomethanes and dihaloacetic acids increased. The phenomena could be attributed to an extended treatment time for hydrophobic dissolved organic matter (DOM), production of soluble microbial products from biomass activities, and an increased Br/DOM ratio by the MBR. Since the MBR treatment would lead to the production of some new DBP precursors and a change of DOM composition, the toxic potency of the DBPs formed needs to be taken into consideration if this process is employed for surface water treatment.
- Published
- 2018
- Full Text
- View/download PDF
3. Novel ZnFe2O4/TiO2/flake graphite composite as particle electrodes for efficient photoelectrocatalytic degradation of rhodamine B in water
- Author
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Dan Jia, Hao L. Tang, Jian Yu, and Stephen M. Long
- Subjects
Environmental Engineering ,Materials science ,Composite number ,02 engineering and technology ,Electrolyte ,010402 general chemistry ,021001 nanoscience & nanotechnology ,Electrocatalyst ,01 natural sciences ,0104 chemical sciences ,chemistry.chemical_compound ,Reaction rate constant ,Chemical engineering ,chemistry ,Electrode ,Rhodamine B ,Photocatalysis ,Degradation (geology) ,0210 nano-technology ,Water Science and Technology - Abstract
A novel ZnFe2O4/TiO2/flake graphite composite material was synthesized and used as particle electrodes in a photoelectrocatalytic (PEC) system to investigate the degradation of rhodamine B as a model dye pollutant in water. Results showed that a PEC process with the new composite evidently led to enhanced degradation of rhodamine B due to a synergistic effect of photocatalysis and electrocatalysis. Operating variables including electrolyte concentration, applied cell voltage, air flow, composite dosage, solution pH, and dye concentration were also found to play important roles in rhodamine B removal. A 99.0% removal efficiency was observed within 30 min of treatment under optimum conditions of 0.01 mol/L Na2SO4, applied cell voltage of 15 V, air flow of 20 mL/min, composite dosage of 10 g/L, solution pH of 2, and rhodamine B concentration of 20 mg/L, with a pseudo-first-order rate constant of 0.278 min−1. These findings could provide new insights into the development of efficient PEC technologies on degradation of residual dyes in water.
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- 2018
- Full Text
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4. Novel ZnFe
- Author
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Dan, Jia, Jian, Yu, Stephen M, Long, and Hao L, Tang
- Subjects
Titanium ,Rhodamines ,Zinc Compounds ,Dielectric Spectroscopy ,Water ,Graphite ,Coloring Agents ,Electrodes ,Ferric Compounds ,Waste Disposal, Fluid ,Catalysis ,Water Pollutants, Chemical ,Water Purification - Abstract
A novel ZnFe
- Published
- 2018
5. Conformational searching using a population-based incremental learning algorithm
- Author
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Peter Adams, Mark L. Smythe, Stephen M. Long, Paul J. Darwen, and Tran Trung Tran
- Subjects
Models, Molecular ,Global energy ,Population-based incremental learning ,Small number ,Molecular Conformation ,General Chemistry ,Small molecule ,New population ,Force field (chemistry) ,Maxima and minima ,Computational Mathematics ,Low energy ,Pharmaceutical Preparations ,Alkanes ,Algorithm ,Algorithms ,Mathematics - Abstract
A new population-based incremental learning algorithm for conformational searching of molecules is presented. This algorithm is particularly effective at determining, by relatively small number of energy minimizations, global energy minima of large flexible molecules. The algorithm is also able to find a large set of low energy conformations of more rigid small molecules. The performance of the algorithm is relation to other algorithm is examined via the test molecules: C18H38, C39H80, cycloheptadecane and a set of five drug-like molecules. (C) 2011 Wiley Periodicals, Inc. J Comput Chem 32: 1541-1549, 2011
- Published
- 2011
- Full Text
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6. On the Efficacy of Turbulence Modelling for Sloshing
- Author
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Omar Ahmed Mahfoze, Wendi Liu, Stephen M. Longshaw, Alex Skillen, and David R. Emerson
- Subjects
slosh-induced damping ,turbulence modelling ,multiphase flow ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
As part of a wider project to understand the applicability of utilising slosh-based damping for wing-like structures, simulations of partially filled tanks subjected to harmonically oscillating and vertical motion are presented. The Volume of Fluid modelling approach is used to capture the air–water interface and different turbulence models based on the Reynolds Averaged Navier–Stokes equations employed. No-model simulations are also conducted to demonstrate the efficacy of using turbulence models in the simulation of sloshing flows. Accuracy of the models is assessed by comparing with recent well-validated experimental data in terms of the damping effect of the sloshing. A wide range of excitation amplitudes are considered in the study to demonstrate the effectiveness of different turbulence models in representing the flow feature of weak and very violent sloshing. The results show that standard turbulence models can produce an excessive dissipation, especially at the interface, leading to inaccuracies in the estimation of sloshing dynamics of the violent sloshing. This issue is absent in the no-model simulations, and better results are obtained for all tested sloshing conditions, suggesting approaches to mitigate this interfacial dissipation within RANS-based modelling is an important consideration for future direction.
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- 2022
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7. Simulating Slosh Induced Damping, with Application to Aircraft Wing-like Structures
- Author
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Wendi Liu, Omar Ahmed Mahfoze, Stephen M. Longshaw, Alex Skillen, and David R. Emerson
- Subjects
slosh damping ,fluid–structure interaction ,multiphase flow ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The added damping generated by liquid sloshing in a tank has been utilized in a number of civil applications, including aviation, to reduce the vibration of the system. As part of a wider EU H2020 project called SLOWD (Sloshing Wing Dynamics), the presented study performed numerical simulations on the slosh-induced damping of liquid in tanks that were under free decay oscillations and embedded in an aircraft wing-like structure. A new open-source partitioned fluid–structure interaction software framework is presented and employed for the numerical simulations. Periodic sloshing waves and violent vertical fluid motions are observed in the study. These demonstrate the effects of slosh-induced damping under different excitation amplitudes of the structure and a varying number of baffled regions within the tank. Various sloshing patterns caused by different combinations of the excitation amplitude and compartment numbers lead to different induced dampings of the free decay motion. We observed a distinctly non-monotonic function on the slosh damping when the initial excitation amplitude is small (i.e., 0.25), with a 59% reduction when we increase the number of baffled compartments from one to four, and a 153% increase when moving from one to eight compartments. This is due to the change in the sloshing wave frequency, resulting in a significant change in the impact of the fluid between the tank ceiling and the wave crests. When the initial excitation amplitude is large (i.e., 1.0), there is no significant change in the slosh-induced damping when changing the number of compartments in the tank, for the range of parameters considered, due to the highly turbulent fluid motion. This work is expected to form the basis of further, more detailed studies within the context of the SLOWD project and its ever-expanding experimental data output.
- Published
- 2022
- Full Text
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