112 results on '"Stanca C"'
Search Results
2. Endovascular treatment of transplanted renal artery stenosis with PTA/stenting
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Guzzardi, G., Fossaceca, R., Di Gesù, I., Cerini, P., Di Terlizzi, M., Stanca, C., Malatesta, E., Moniaci, D., Brustia, P., Stratta, P., and Carriero, A.
- Published
- 2013
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3. Endovascular treatment of popliteal artery aneurysms: preliminary results
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Guzzardi, G., Fossaceca, R., Cerini, P., Di Terlizzi, M., Stanca, C., Di Gesù, I., Martino, F., Brustia, P., and Carriero, A.
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- 2013
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4. Long-term efficacy of endovascular treatment of isolated iliac artery aneurysms
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Fossaceca, R., Guzzardi, G., Di Terlizzi, M., Divenuto, I., Cerini, P., Malatesta, E., Di Gesù, I., Stanca, C., Brustia, P., and Carriero, A.
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- 2013
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5. Natural history of small duct primary sclerosing cholangitis: a case series with review of the literature
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Singal, A. K., Stanca, C. M., Clark, V., Dixon, L., Levy, C., Odin, J. A., Fiel, M. I., Friedman, S. L., and Bach, N.
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- 2011
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6. Influence of Direct Coronal Restoration Materials on the Fracture Resistance of Endodontically Treated Premolars: An In Vitro Study
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Georgiana Florentina Gheorghe, Ana Maria Cristina Țâncu, Oana Elena Amza, Ioana Suciu, Laura Iosif, Stanca Cuc, Ioan Petean, Marioara Moldovan, and Bogdan Dimitriu
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root canal treatment ,restoration material ,endodontically treated tooth ,premolar ,fracture resistance ,stereomicroscope ,Dentistry ,RK1-715 - Abstract
(1) Background: The long-term survival of an endodontically treated tooth depends on a successful root canal treatment as well as an adequate definitive coronal restoration. This study aimed to evaluate the strength of endodontically treated premolars with mesial–occlusal–distal (MOD) cavity preparation restored with different direct coronal restoration materials but from the same manufacturer against fracture. (2) Methods: sixty intact premolars were selected and placed into five groups (n = 12): G1—intact teeth, G2—endodontic treatment and unrestored MOD cavities, G3—endodontic treatment and MOD cavities restored with Tetric PowerFlow and Tetric EvoCeram, G4—endodontic treatment and MOD cavities restored with Multicore Flow and Tetric EvoCeram, and G5—endodontic treatment and MOD cavities restored with Multicore Flow. The specimens were subjected to an axial compression load at a speed of 1.6 mm/min and optically inspected before and after with a stereomicroscope. For each premolars group, the following data were recorded: the compression resistance, the compressive strength, and the maximum force supported. The microstructure of the samples after the compression test was analyzed using scanning electron microscopy (SEM). (3) Results: statistical analysis (ANOVA and Tukey test) showed that there was a statistically significant difference between G1 and the other groups. Even though there was no statistically significant difference between the restored groups, a better mechanical behavior was registered within the G3. (4) Conclusions: this in vitro study indicated that none of the materials used can lead to a higher or at least similar fracture resistance as the intact teeth. The coronal restoration only with nano-hybrid composites may lead to a higher therapeutic benefit for the fracture-susceptible premolars.
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- 2024
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7. Conditioning Influence of Kaolinite Matrices on Flexural Strength of Raw Pressed Slurry Collected from Ceramic Tile Production Wastewater
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Simona Elena Avram, Lucian Barbu Tudoran, Stanca Cuc, Gheorghe Borodi, Bianca Violeta Birle, and Ioan Petean
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kaolinite matrix ,ceramic tile slurry ,flexural strength ,microstructural investigation ,Technology ,Science - Abstract
Kaolinite is able to assure the high binding affinity of the filler particles of raw ceramic bodies. It acts as a matrix that strongly holds the other constituents’ particles in a compact structure. The slurry samples were characterized by XRD, mineralogical microscopy and SEM coupled with an EDX elemental analysis. The slurry collected from the ceramic tile production wastewaters had a significant amount of kaolinite (36%), mostly fine particles of 3 µm, less surrounding quartz (37%) and mullite (19%) particles of 5–100 µm in diameter and traces of lepidocrocite (8%). It is a dense paste with a relative moisture of 25%. The square bar of the slurry as received, pressed at a load of 350 N, had a flexural strength of 0.61 MPa. Increasing the moisture to 33% using regular water, followed by mechanical attrition at 2000 rpm for 5 min, resulted in a porous bar with a flexural strength of 0.09 MPa; by increasing the attrition speed to 6000 rpm, the microstructural homogenization was improved and the flexural strength was about 0.68 MPa. It seems that regular water does not assure an optimal moisture for the kaolinite matrix conditioning. Therefore, we used technological water at pH = 10, a moisture of 33% and attrition at 6000 rpm for 5 min, and the bar pressed at a load of 350 N had a flexural strength of 1.17 MPa. The results demonstrate that the bar moistened with technological water and an attrition regime assured a proper conditioning for the kaolinite matrix, achieving the optimal binding of the quartz and mullite particles under the pressing load. Bars with the optimal mixture were pressed at several loads, including 70, 140, 210 and 350 N, and the flexural strength was progressively increased from 0.56 MPa to 1.17 MPa. SEM fractography coupled with atomic force microscopy (AFM) revealed that the optimal moisture facilitated a proper kaolinite particle disposal regarding the quartz and mullite filler particles, and the progressive load assured the strong binding of the finest kaolinite platelets onto their surface.
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- 2024
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8. Advanced Dentistry Biomaterials Containing Graphene Oxide
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Doina Prodan, Marioara Moldovan, Stanca Cuc, Codruţa Sarosi, Ioan Petean, Miuța Filip, Rahela Carpa, Rami Doukeh, and Ioana-Codruta Mirica
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posterior restoration ,cement ,graphene oxide ,hydroxyapatite ,antibacterial properties ,Organic chemistry ,QD241-441 - Abstract
The aim of this study was to obtain three experimental resin-based cements containing GO and HA-Ag for posterior restorations. The samples (S0, S1, and S2) shared the same polymer matrix (BisGMA, TEGDMA) and powder mixture (bioglass (La2O3 and Sr-Zr), quartz, GO, and HA-Ag), with different percentages of graphene oxide (0%, 0.1%, 0.2% GO) and silver-doped hydroxyapatite (10%, 9.9%, 9.8% HA-Ag). The physical–chemical properties (water absorption, degree of conversion), mechanical properties (DTS, CS, FS), structural properties (SEM, AFM), and antibacterial properties (Staphylococcus aureus, Enterococcus faecalis, Streptococcus mutans, Porphyromonas gingivalis, and Escherichia coli) were investigated. The results showed that the mechanical properties, except for the diametral tensile test, increased with the rise in the %GO. After 28 days, water absorption increased with the rise in the %GO. The surface structure of the samples did not show major changes after water absorption for 28 days. The antibacterial effects varied depending on the samples and bacterial strains tested. After increasing the %GO and decreasing the %HA-Ag, we observed a more pronounced antibacterial effect. The presence of GO, even in very small percentages, improved the properties of the tested experimental cements.
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- 2024
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9. Formulation and Characterization of New Experimental Dental Composites with Zirconium Filling in Different Forms
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Dipa Rani Mohajon, Doina Prodan, Marioara Moldovan, Ioan Petean, Stanca Cuc, Miuta Filip, Rahela Carpa, Georgiana Florentina Gheorghe, and Codruţa Liana Saroşi
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composites ,glass fibers ,zirconium ,degree of conversion ,AFM ,SEM ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
Short glass fibers are generally used in posterior dental restorations to enhance the mechanical properties and improve the material microstructure. Two resin-based composites (S0 and SF) were formulated and characterized to investigate the influence of zirconium in their characteristics and properties. The organic part of the investigated materials was the same (BisGMA, TEGDMA, and a photochemical polymerization system), and in the inorganic part, besides quart, glassA, and hydroxylapatite with Zn, sample S0 contained strontium glass with zirconium and sample SF contained fiber powder of chopped zirconium. The samples were characterized by the degree of conversion (DC), mechanical properties, water sorption (WS), scanning electron microscopy (SEM), atomic force microscopy (AFM) before and after the WS test, and antimicrobial properties. The results obtained were subjected to one-way ANOVA and Tukey’s statistical tests. Both samples had a high DC. Regarding the mechanical properties, both samples were very similar, except DTS, which was higher for the composite without fibers. After 14 days, the WS value of the SF sample was lower than that of the S0 sample. Water caused significant changes in the topography of the SF sample, but thanks to its antimicrobial properties and the diffusion phenomenon, SF had a more pronounced antimicrobial effect. This study shows that the addition of appropriate amounts of Sr-Zr-glass powder gives the material in which it is added similar properties to material containing chopped zirconium glass fiber powder. According to the antimicrobial test results, resin composites containing experimental zirconia fillings can be considered in future in vitro clinical studies for posterior reconstructions with significantly improved mechanical properties.
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- 2024
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10. The Influence of Lyophilization Pretreatment and Whey Content on Whey and Gelatin-Based Hydrogels
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Pompilia Mioara Lopes, Radu Fechete, Felicia Minteuan, Liviu Mare, Dumitrița Moldovan, Marioara Moldovan, Stanca Cuc, Codruța Liana Saroși, and Violeta Popescu
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whey and gelatin ,hydrogel ,crosslinking ,lyophilization ,mechanical properties ,Science ,Chemistry ,QD1-999 ,Inorganic chemistry ,QD146-197 ,General. Including alchemy ,QD1-65 - Abstract
Whey and gelatin, natural polymers within the protein category, find widespread use in hydrogel formulations applied across the food, medical, and pharmaceutical industries. This study presents new characteristics of hydrogels based on whey, gelatin, and copper sulfate as a consequence of the additional steps in the preparation method, specifically refrigeration and freezing storage followed by lyophilization. The water state in hydrogels prior to lyophilization impacts the morphological appearance, with refrigerated hydrogels exhibiting a more regular and dense pore distribution, as shown by the Scanning Electron Microscopy (SEM) images. This observation aligns with the higher mobility of polymer chains indicated by T2 distributions in 1H nuclear magnetic resonance (RMN) relaxometry measurements. Changes in the intensity and amide-specific wavenumbers of the FTIR spectra of whey and gelatin proteins are evident in the Fourier Transformed Infrared (FTIR) spectra of crosslinked and frozen hydrogels before lyophilization. Moreover, the reinforcing effect in the hydrogel matrix, noted in mechanical tests, is attributed to increased polymer chain content and copper sulfate crosslinking.
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- 2024
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11. Developing Bioactive Hydrogels with Peptides for Dental Application
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Alexandrina Muntean, Codruta Sarosi, Ioan Petean, Stanca Cuc, Rahela Carpa, Ioana Andreea Chis, Aranka Ilea, Ada Gabriela Delean, and Marioara Moldovan
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peptides ,hydrogels ,hydroxyapatite ,remineralisation ,cytotoxicity ,Biology (General) ,QH301-705.5 - Abstract
Dental caries is an avoidable and complex condition impacting billions of individuals worldwide, posing a specific concern among younger generations, despite the progress of oral hygiene products. This deterioration occurs due to the acid demineralization of tooth enamel, leading to the loss of minerals from the enamel subsurface. The remineralisation of early enamel carious lesions could prevent the cavitation of teeth. The enamel protein amelogenin constitutes 90% of the total enamel matrix protein and plays a key role in the bio mineralisation process. The aim of this study is to investigate the self-assembly microstructure and reticulation behaviour of a newly developed bioactive hydrogel with leucine-rich amelogenin peptide (LRAP) intended for enamel remineralisation. SEM, AFM, UV-VIS, and FTIR analyses emphasize the ability of peptides to promote cell adhesion and the treatment of early carious lesions. In conclusion, short-chain peptides can be used in hydrogels for individual or professional use.
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- 2024
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12. Damage stability analysis in particular flooding situations of a multipurpose cargo ship
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Andrei, C, primary, Stanca, C, additional, Acomi, N, additional, Dumitrache, C, additional, and Ancuta, C, additional
- Published
- 2018
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13. Calculation of naval collisions with general use finite element software
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Dumitrache, C L, primary, Dumitrache, R, additional, Stanca, C, additional, Andrei, C, additional, and Ancuta, C, additional
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- 2018
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14. Properties of Nanohybrid Dental Composites—A Comparative In Vitro Study
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Mihaela Păstrav, Ovidiu Păstrav, Andrea Maria Chisnoiu, Radu Marcel Chisnoiu, Stanca Cuc, Ioan Petean, Codruța Saroși, and Dana Feștilă
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nanohybrid composites ,filler ,color stability ,roughness ,dentistry ,restorative dentistry ,Biology (General) ,QH301-705.5 - Abstract
(1) Background: the current study investigated three nanohybrid composites: two commercial products ClearfilMajestyTM (CM) and HarmonizeTM (HU), compared with an experimental product PS2. (2) Methods: Two sample types were molded using Teflon dies. The first sample type was represented by standard discs (20 mm diameter and 2 mm thickness) (n = 60, 20/each material), used for surface conditioning investigation, specifically roughness monitoring and color stability analysis using AFM and the CIELab test, respectively. The second sample type was a standard cylindrical specimen (4 mm diameter and 6 mm height) for compression testing (n = 60, 20/each material). After complete polymerization, the samples were ground with sandpaper and further polished. The filler size and distribution in the polymer matrix were investigated with SEM. Data were statistically analyzed using the Anova Test followed by Tukey’s post hoc test on the Origin Lab 2019 software produced by OriginLab Corporation, Northampton, MA, USA. (3) Results: A mono-disperse system was identified in HU samples, while CM and PS2 revealed both nano- and microfiller particles. The samples’ observation after immersion in coffee and tea indicated that a lower roughness combined with optimal filler lamination within the polymer matrix assured the best color preservation. The compression strength was lower for the HU sample, while higher values were obtained for the complex filler systems within CM and PS2. (4) Conclusions: the behavior of the investigated nanohybrid composites strongly depends on the microstructural features.
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- 2024
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15. SEM Evaluation of Marginal Adaptation E-Max Crowns Manufactured by Printing-Pressed and Milling
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Ana Ispas, Marioara Moldovan, Stanca Cuc, Doina Prodan, Cecilia Bacali, Ioan Petean, Smaranda Buduru, Manuela Manziuc, and Laura Iosif
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E-Max crowns ,marginal adaptation ,SEM microscopy ,Medicine (General) ,R5-920 - Abstract
Dental crown marginal adaptation is a matter of the success of dental restoration treatment. Nowadays, there are many technological ways for crown manufacturing, such as tridimensional printing of an exactly desired shape through CAD-assisted systems and the appropriate shape milling of a predesigned bulk crown. Both methods are developed for patient benefits. The current research aims to investigate the marginal adaptation of E-Max crowns manufactured by printing-pressed and milling methods. The in vitro cementation procedures were effectuated on healthy teeth extracted for orthodontic purposes according to the standard procedures and the marginal adaptation was investigated with SEM microscopy. The restoration overview was inspected at a magnification of 100× and the microstructural details at 400×. The integrity of marginal adaptation was properly inspected in identical samples on segments of 2 mm from each buccal, palatal, distal and mesial side. The obtained results reveal a good marginal adaptation for all samples, with some particularities. The statistical analysis shows that the best values of the marginal adaptation were obtained for vestibular/buccal and palatal sides of the teeth being situated around 90–95%, while the values obtained for distal and mesial sides are slightly lower such as 80–90%. Furthermore, it was observed that the milled crowns presents better marginal adaptations than the printed-pressed ones, sustained by the statistical p < 0.05. This indicates that the milling process allows a better fit of the crown to the tooth surface and preserves the integrity of the bonding cement layer.
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- 2023
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16. Recycled PET Composites Reinforced with Stainless Steel Lattice Structures Made by AM
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Mircea Rusu, Nicolae Balc, Marioara Moldovan, Stanca Cuc, Ioan Petean, Cosmin Cosma, and Dan Leordean
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recycled PET ,316L stainless steel ,additive manufacturing ,metal reinforcement ,IPC ,interpenetrating phase composites ,Organic chemistry ,QD241-441 - Abstract
Polyethylene terephthalate (PET) recycling is one of the most important environmental issues, assuring a cleaner environment and reducing the carbon footprint of technological products, taking into account the quantities used year by year. The recycling possibilities depend on the quality of the collected material and on the targeted product. Current research aims to increase recycling quantities by putting together recycled PET in an innovative way as a filler for the additive manufactured metallic lattice structure. Starting from the structures mentioned above, a new range of composite materials was created: IPC (interpenetrating phase composites), materials with a complex architecture in which a solid phase, the reinforcement, is uniquely combined with the other phase, heated to the temperature of melting. The lattice structure was modeled by the intersection of two rings using Solid Works, which generates the lattice structure, which was further produced by an additive manufacturing technique from 316L stainless steel. The compressive strength shows low values for recycled PET, of about 26 MPa, while the stainless-steel lattice structure has about 47 MPa. Recycled PET molding into the lattice structure increases its compressive strength at 53 MPa. The Young’s moduli are influenced by the recycled PET reinforcement by an increase from about 1400 MPa for the bare lattice structure to about 1750 MPa for the reinforced structure. This sustains the idea that recycled PET improves the composite elastic behavior due to its superior Young’s modulus of about 1570 MPa, acting synergically with the stainless-steel lattice structure. The morphology was investigated with SEM microscopy, revealing the binding ability of recycled PET to the 316L surface, assuring a coherent composite. The failure was also investigated using SEM microscopy, revealing that the microstructural unevenness may act as a local tensor, which promotes the interfacial failure within local de-laminations that weakens the composite, which finally breaks.
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- 2023
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17. Behavior analysis of container ship in maritime accident in order to redefine the operating criteria
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Ancuţa, C, primary, Stanca, C, additional, Andrei, C, additional, and Acomi, N, additional
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- 2017
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18. Comparison of the Eggshell and the Porcine Pericardium Membranes for Guided Tissue Regeneration Applications
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Horia Opris, Mihaela Baciut, Marioara Moldovan, Stanca Cuc, Ioan Petean, Daiana Opris, Simion Bran, Florin Gligor Onisor, Gabriel Armenea, and Grigore Baciut
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eggshell membrane ,biocompatibility ,bone regeneration ,rat model ,Biology (General) ,QH301-705.5 - Abstract
Guided bone regeneration is frequently used to reconstruct the alveolar bone to rehabilitate the mastication using dental implants. The purpose of this article is to research the properties of eggshell membrane (ESM) and its potential application in tissue engineering. The study focuses on the structural, mechanical, and histological characteristics of ESM extracted from Gallus domesticus eggs and to compare them to a commercially available porcine pericardium membrane (Jason® membrane, botiss biomaterials GmbH, Zossen, Germany). Thus, histology was performed on the ESM, and a comparison of the microstructure through scanning electron microscopy and atomic force microscopy (AFM) was conducted. Also, mechanical tensile strength was evaluated. Samples of ESM were prepared and treated with alcohol for fixation and disinfection. Histological analysis revealed that the ESM architecture is constituted out of loose collagen fibers. However, due to the random arrangement of collagen fibers within the membrane, it might not be an effective barrier and occlusive barrier. Comparative analyses were performed between the ESM and the AFM examinations and demonstrated differences in the surface topography and mechanical properties between the two membranes. The ESM exhibited rougher surfaces and weaker mechanical cohesion attributed to its glycoprotein content. The study concludes that while the ESM displays favorable biocompatibility and resorb ability, its non-uniform collagen arrangement limits its suitability as a guided bone regeneration membrane in the current non-crosslinked native form. Crosslinking techniques may enhance its properties for such applications. Further research is needed to explore modifications and processing methods that could leverage the ESM’s unique properties for tissue engineering purposes.
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- 2023
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19. Polymer Mixtures for Experimental Self-Limited Dental Burs Development—A Preliminary Approach (Part 1)
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Radu Marcel Chisnoiu, Alexandrina Muntean, Ovidiu Păstrav, Andrea Maria Chisnoiu, Stanca Cuc, Laura Silaghi Dumitrescu, Mihaela Păstrav, Doina Prodan, and Ada Gabriela Delean
- Subjects
polymer mixture ,graphene ,mechanical properties ,dentistry ,dental materials ,Biotechnology ,TP248.13-248.65 ,Medicine (General) ,R5-920 - Abstract
Alternative techniques have been investigated for effectiveness in caries removal because conventional metallic dental burs can lead to an excessive loss of sound tissue. The aim of the present study is to realize a preliminary approach in obtaining effective polymer mixtures for polymeric bur development, capable of removing primary dental caries using combinations of polymers to ensure the requirements for such instruments, but also a greater compatibility with the teeth structure. This study assessed the main mechanical properties, water sorption, solubility and microscopic structure of four new polymer mixture recipes to provide essential features in obtaining experimental self-limited dental burs. Two mixtures have in their composition polymer mixtures of Bis-phenol A diglycidyl ether dimethacrylate/Triethylene glycol dimethacrylate/Urethane dimethacrylates (R1, R2), and two other mixtures have Bis-phenol A diglycidyl ether dimethacrylate/Polymethyl methacrylate/Methyl methacrylates (R3, R4). The incorporation of nanoparticles into the polymer matrix has become essential due to the need of polymer biocompatibility increasing along with teeth surface remineralization, so that the powder charge was added to four recipes, such as 5% glass with BaF2 and 0.5% graphene with silver particles. All data sets were analyzed using the One-Way ANOVA test. R3, R4 showed higher compressive strength and diametrical compression values; these values increased when glass and graphene were added. Moreover, the addition of glass particles lead to an increase in flexural strength. Regarding the sorption, sample R3 had the most significant differences between day 69 and the rest of the investigation days, while the solubility varied at different intervals. From the mechanical evaluation, we could conclude that the Bis-GMA/PMMA/MMA mixtures fit the mechanical characteristics supported by polymer burs, following future studies regarding their use on the affected dentin.
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- 2023
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20. Mechanical Properties and Liquid Absorption of Calcium Phosphate Composite Cements
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Ioana Lacan, Marioara Moldovan, Codruta Sarosi, Stanca Cuc, Mihaela Pastrav, Ioan Petean, and Razvan Ene
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calcium phosphate ,chitosan ,composite cements ,mechanical properties ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
Calcium phosphate cements present increased biocompatibility due to their chemical composition being similar to that of the hydroxyapatite in the hard tissues of the living body. It has certain limitations due to its poor mechanical properties, such as low tensile strength and increased brittleness. Thus, the optimal way to improve properties is through the design of novel composite cements. The purpose was fulfilled using a 25% hydroxyethyl methacrylate (HEMA) mixed with 3% urethane dimethacrzlate (UDMA) base matrix with various ratios of polyethylene glycol (PEG 400) and polycaprolactone (PCL). Mineral filler is based on tricalcium phosphate (TCP) with different chitosan ratio used as bio-response enhancer additive. Four mixtures were prepared: S0—unfilled polymer matrix; S1 with 50% TCP filler; S2 with 50% chitosan + TCP filler; and S3 with 17.5% chitosan + TCP mixed with 17.5% nano hydroxyapatite (HA). The mechanical properties testing revealed that the best compressive strength was obtained by S2, followed by S3, and the worst value was obtained for the unfilled matrix. The same tendency was observed for tensile and flexural strength. These results show that the novel filler system increases the mechanical resistance of the TCP composite cements. Liquid exposure investigation reveals a relative constant solubility of the used filler systems during 21 days of exposure: the most soluble fillers being S3 and S2 revealing that the additivated TCP is more soluble than without additives ones. Thus, the filler embedding mode into the polymer matrix plays a key role in the liquid absorption. It was observed that additive filler enhances the hydrophobicity of UDMA monomer, with the matrix resulting in the lowest liquid absorption values, while the non-additivated samples are more absorbent due to the prevalence of hydrolytic aliphatic groups within PEG 400. The higher liquid absorption was obtained on the first day of immersion, and it progressively decreased with exposure time due to the relative swelling of the surface microstructural features. The obtained results are confirmed by the microstructural changes monitored by SEM microscopy. S3 and S2 present a very uniform and compact filler distribution, while S1 presents local clustering of the TCP powder at the contact with the polymer matrix. The liquid exposure revealed significant pore formation in S0 and S1 samples, while S3 and S2 proved to be more resistant against superficial erosion, proving the best resistance against liquid penetration.
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- 2023
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21. Aspects regarding analysis of the work deck from a support vessel
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Axinte, T, primary, Nutu, C, additional, Stanca, C, additional, Cupsa, O, additional, and Carp, A, additional
- Published
- 2016
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22. Assessment of current criteria for dynamic stability of container vessels
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Stanca, C, primary, Ancuta, C, additional, Acomi, N, additional, and Andrei, C, additional
- Published
- 2016
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23. Advanced analysis of the transverse bulkhead of the a general cargo ship
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Axinte, T, primary, Nutu, C, additional, Stanca, C, additional, Cupsa, O, additional, and Carp, A, additional
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- 2016
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24. Comparative analysis of different loading conditions on large container ships from the perspective of the stability requirement
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Stanca, C, primary, Acomi, N, additional, Ancuta, C, additional, and Georgescu, S, additional
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- 2015
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25. The evaluation of the environmental impact and the external factors of urban transport in Constanta
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Stanca, C, primary, Stîngă, V G, additional, Georgescu, S, additional, and Cupşa, O S, additional
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- 2015
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26. The use of ECDIS equipment to achieve an optimum value for energy efficiency operation index
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Acomi, N, primary, Acomi, O C, additional, and Stanca, C, additional
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- 2015
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27. IMPLEMENTATION SOLUTION FOR AN ACTIVE SUSPENSION SYSTEM FOR VEHICLES USING LINEAR ELECTROMAGNETIC ACTUATORS.
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JIPA, C. G. and STANCA, C. A.
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DAMPERS (Mechanical devices) , *PERMANENT magnets , *VIBRATION (Mechanics) - Abstract
This paper presents a solution of the active suspension system for vehicles, using electromagnetic actuators. Compared to active hydraulic suspension systems, which have a greater reaction time and high energy consumption, the system presented has the advantage of better regulation dynamics as well as increasing energy efficiency with the possibility of energy recovery. In the paper is presented the concept but also its design and implementation on a demonstrator. [ABSTRACT FROM AUTHOR]
- Published
- 2018
28. Statistical Comparison of the Mechanical Properties of 3D-Printed Resin through Triple-Jetting Technology and Conventional PMMA in Orthodontic Occlusal Splint Manufacturing
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Ioan Barbur, Horia Opris, Bogdan Crisan, Stanca Cuc, Horatiu Alexandru Colosi, Mihaela Baciut, Daiana Opris, Doina Prodan, Marioara Moldovan, Liana Crisan, Cristian Dinu, and Grigore Baciut
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polymethylmethacrylate (PMMA) ,3D printing ,polyjet ,mechanical properties ,occlusal splint ,scanning electron microscopy (SEM) ,Biology (General) ,QH301-705.5 - Abstract
Dental 3D-printing technologies, including stereolithography (SLA), polyjet (triple-jetting technology), and fusion deposition modeling, have revolutionized the field of orthodontic occlusal splint manufacturing. Three-dimensional printing is now currently used in many dental fields, such as restorative dentistry, prosthodontics, implantology, and orthodontics. This study aimed to assess the mechanical properties of 3D-printed materials and compare them with the conventional polymethylmethacrylate (PMMA). Compression, flexural, and tensile properties were evaluated and compared between PMMA samples (n = 20) created using the “salt and pepper” technique and digitally designed 3D-printed samples (n = 20). The samples were subjected to scanning electron microscope analysis. Statistical analysis revealed that the control material (PMMA) exhibited a significantly higher Young’s modulus of compression and tensile strength (p < 0.05). In the flexural tests, the control samples demonstrated superior load at break results (p < 0.05). However, the 3D-printed samples exhibited significantly higher maximum bending stress at maximum load (MPa) (p < 0.05). Young’s modulus of tensile testing (MPa) was statistically significant higher for the control samples, while the 3D-printed samples demonstrated significantly higher values for elongation at break (p < 0.05). These findings indicate that 3D-printed materials are a promising alternative that can be effectively utilized in clinical practice, potentially replacing traditional heat-cured resin in various applications.
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- 2023
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29. Improving the Mechanical Properties of Orthodontic Occlusal Splints Using Nanoparticles: Silver and Zinc Oxide
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Ioan Barbur, Horia Opris, Horatiu Alexandru Colosi, Mihaela Baciut, Daiana Opris, Stanca Cuc, Ioan Petean, Marioara Moldovan, Cristian Mihail Dinu, and Grigore Baciut
- Subjects
methylmethacrylate ,graphene ,occlusal splint ,mechanical properties ,silver ,zinc oxide ,Biology (General) ,QH301-705.5 - Abstract
The goal of the current study was to determine the mechanical proprieties of polymethylmethacrylate (PMMA) and the improved compound, the graphene-based PMMA, with Zn and Ag and to compare the results. Scanning electron microscopy analysis of the samples before and after the mechanical test was conducted. The compression behavior, flexural properties, tensile strength, and shape of the samples were all investigated and compared between the variants of PMMA. Commercially available polymethylmethacrylate was used (Orthocryl®—Dentaurum, Ispringen, Germany) with the salt and pepper technique according to the manufacturer’s instructions to produce 20 samples for each mechanical trial with standard cylinders (4 mm diameter × 8 mm length) for compression, parallelepipedal prisms for flexing (2 mm × 2 mm × 25 mm) and flat samples for traction. There was no statistical difference in the mechanical proprieties of the samples evaluated, although there were values that could suggest significance. The graphene-based PMMA demonstrated good mechanical proprieties, like the commercially available PMMA, and appears promising for future clinical use based on its multiple advantages.
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- 2023
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30. Development and Characterization of Polylactic Acid (PLA)-Based Nanocomposites Used for Food Packaging
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Andrei Moldovan, Stanca Cuc, Doina Prodan, Mircea Rusu, Dorin Popa, Adrian Catalin Taut, Ioan Petean, Dorin Bomboş, Rami Doukeh, and Ovidiu Nemes
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polylactic acid ,plasticizer ,food packaging ,physical-mechanical properties ,Organic chemistry ,QD241-441 - Abstract
The present study is focused on polylactic acid (PLA) blending with bio nanoadditives, such as Tonsil® (clay) and Aerosil®, to obtain nanocomposites for a new generation of food packaging. The basic composition was enhanced using Sorbitan oleate (E494) and Proviplast as plasticizers, increasing the composite samples’ stability and their mechanical strength. Four mixtures were prepared: S1 with Tonsil®; S2 with Aerosil®; S3 with Aerosil® + Proviplast; and S4 with Sabosorb. They were complexly characterized by FT-IR spectroscopy, differential scanning calorimetry, mechanical tests on different temperatures, and absorption of the saline solution. FTIR shows a proper embedding of the filler component into the polymer matrix and DSC presents a good stability at the living body temperature for all prepared samples. Micro and nanostructural aspects were evidenced by SEM and AFM microscopy, revealing that S3 has the most compact and uniform filler distribution and S4 has the most irregular one. Thus, S3 evidenced the best diametral tensile strength and S4 evidenced the weakest values. All samples present the best bending strength at 18 °C and fair values at 4 °C, with the best values being obtained for the S1 sample and the worst for S4. The lack of mechanical strength of the S4 sample is compensated by its best resistance at liquid penetration, while S1 is more affected by the liquid infiltrations. Finally, results show that PLA composites are suitable for biodegradable and disposable food packages, and the desired properties could be achieved by proper adjustment of the filler proportions.
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- 2023
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31. Chemical and Structural Assessment of New Dental Composites with Graphene Exposed to Staining Agents
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Marioara Moldovan, Diana Dudea, Stanca Cuc, Codruta Sarosi, Doina Prodan, Ioan Petean, Gabriel Furtos, Andrei Ionescu, and Nicoleta Ilie
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graphene oxide ,SiO2 ,ZrO2 ,dental composites ,antibacterial test ,surface properties ,Biotechnology ,TP248.13-248.65 ,Medicine (General) ,R5-920 - Abstract
Among the newest trends in dental composites is the use of graphene oxide (GO) nanoparticles to assure better cohesion of the composite and superior properties. Our research used GO to enhance several hydroxyapatite (HA) nanofiller distribution and cohesion in three experimental composites CC, GS, GZ exposed to coffee and red wine staining environments. The presence of silane A-174 on the filler surface was evidenced by FT-IR spectroscopy. Experimental composites were characterized through color stability after 30 days of staining in red wine and coffee, sorption and solubility in distilled water and artificial saliva. Surface properties were measured by optical profilometry and scanning electron microscopy, respectively, and antibacterial properties wer e assessed against Staphylococcus aureus and Escherichia coli. A colour stability test revealed the best results for GS, followed by GZ, with less stability for CC. Topographical and morphological aspects revealed a synergism between GZ sample nanofiller components that conducted to the lower surface roughness, with less in the GS sample. However, surface roughness variation due to the stain was affected less than colour stability at the macroscopic level. Antibacterial testing revealed good effect against Staphylococcus aureus and a moderate effect against Escherichia coli.
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- 2023
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32. Antimicrobial Poly (Lactic Acid)/Copper Nanocomposites for Food Packaging Materials
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Violeta Popescu, Doina Prodan, Stanca Cuc, Codruţa Saroşi, Gabriel Furtos, Andrei Moldovan, Rahela Carpa, and Dorin Bomboş
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food packaging ,antimicrobial properties ,mechanical properties ,copper ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
Composites based on polylactic acid (PLA) and copper for food packaging applications were obtained. Copper clusters were synthesized in polyethylene glycols 400 and 600, respectively, using ascorbic acid as a reducing agent, by reactive milling. Copper clusters were characterized by Scanning Electron Microscopy (SEM), Fourier Transform Infrared (FT-IR), and Ultraviolet-Visible (UV-VIS) spectroscopy. Copper/PLA composites containing Proviplast as plasticizer were characterized by FT-IR spectroscopy, mechanical tests, Differential Scanning Calorimetry (DSC), Thermogravimetric Analysis (TGA), absorption of the saline solution, contact angle, and antibacterial properties. It was observed that the concentration of Copper/PEG influenced the investigated properties. The mechanical properties of the samples decreased with the increasing of Copper/PEG concentration. We recorded the phase transformation temperatures and identified the exothermic or endothermic processes. The lowest absorption values were recorded in the case of the sample containing 1% Cu. The contact angle decreases with the increase in the concentration of the PEG 600-Cu mixture in the recipes. The increase in the content of Cu clusters favors the decrease in the temperature, taking place 15% wt mass losses. The obtained composites showed antibacterial properties for all tested strains. These materials could be used as alternative materials for obtaining biodegradable food packaging.
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- 2023
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33. Aartzt PBC database: design, implementation and validation
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Tandon, N, Gutierrez, J, Stanca, C, Fernandez, J, Merati, S, Lopez, J, Jaffe, D, Leonard, J, Thung, Sn, Berk, P, Schwartz, M, Miller, C, Walewski, J, Friedman, Sl, Bach, N, Freni, Maria Ant. Tta, Branch, Ad, Bodenheimer, H, and Odin, Ja
- Published
- 2002
34. Physico-Antibacterial Feature and SEM Morphology of Bio-Hydraulic Lime Mortars Incorporating Nano-Graphene Oxide and Binary Combination of Nano-Graphene Oxide with Nano Silver, Fly Ash, Zinc, and Titanium Powders
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Mehmet Serkan Kırgız, Jahangir Mirza, Stanca Cuc, Doina Prodan, Codruţa Saroşi, Ioana Perhaiţă, Rahela Carpa, Marioara Moldovan, Dorin Popa, Simona Varvara, and Maria Popa
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graphene nanopowder ,hydraulic mortar ,porosity ,water absorption ,antibacterial property ,SEM morphology ,Building construction ,TH1-9745 - Abstract
The study evaluated the impact of graphene powders used as additives in the recipe of the experimental lime mortar to a mixture ratio of 1:2.5 of NHL3.5 hydraulic lime:fine sand. The content of binder, aggregate and water was kept constant, varying only the amount and the type of the added additives in relation to the amount of natural hydraulic lime NHL3.5. The following five types of experimental mortars were prepared as follows: reference mortar (without additive); mortars containing 1 wt.% GO and 5 wt.% GO powder; mortar with the following GO powders mixture: GO powder functionalized with silver nanoparticles and with fly ash (GO-Ag + GO-fly ash); mortar with the following GO powders mixture: GO with zinc oxide and with titanium oxide (GO-ZnO + GO-TiO2). The influence of the GO-based additive addition on the porosity, surface microstructure, and water sorption coefficient of the mortar samples was evaluated. The antibacterial effect of the mortar samples against three bacterial strains was also investigated. The best results were obtained for the experimental mortar containing GO-ZnO -TiO2, which showed improved experimental properties that potentially allow its use for the rehabilitation of heritage buildings.
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- 2023
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35. Effects of Acidic Environments on Dental Structures after Bracket Debonding
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Cristina Iosif, Stanca Cuc, Doina Prodan, Marioara Moldovan, Ioan Petean, Mîndra Eugenia Badea, Sorina Sava, Andrada Tonea, and Radu Chifor
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dental brackets ,enamel surface ,acid environment ,shared bond test ,surface roughness ,Biology (General) ,QH301-705.5 ,Chemistry ,QD1-999 - Abstract
Brackets are metallic dental devices that are very often associated with acidic soft drinks such as cola and energy drinks. Acid erosion may affect the bonding between brackets and the enamel surface. The purpose of this study was to investigate the characteristics of brackets’ adhesion, in the presence of two different commercially available drinks. Sixty human teeth were divided into six groups and bonded with either resin-modified glass ionomer (RMGIC) or resin composite (CR). A shared bond test (SBS) was evaluated by comparing two control groups with four other categories, in which teeth were immersed in either Coca-ColaTM or Red BullTM energy drink. The debonding between the bracket and enamel was evaluated by SEM. The morphological aspect correlated with SBS results showed the best results for the samples exposed to artificial saliva. The best adhesion resistance to the acid erosion environment was observed in the group of teeth immersed in Red BullTM and with brackets bonded with RMGIC. The debonded structures were also exposed to Coca-ColaTM and Red BullTM to assess, by atomic force microscopy investigation (AFM), the erosive effect on the enamel surface after debonding and after polishing restoration. The results showed a significant increase in surface roughness due to acid erosion. Polishing restoration of the enamel surface significantly reduced the surface roughness that resulted after debonding, and inhibited acid erosion. The roughness values obtained from polished samples after exposure to Coca-ColaTM and Red BullTM were significantly lower in that case than for the debonded structures. Statistical results evaluating roughness showed that Red BullTM has a more erosive effect than Coca-Cola™. This result is supported by the large contact surface that resulted after debonding. In conclusion, the prolonged exposure of the brackets to acidic drinks affected the bonding strength due to erosion propagation into both the enamel–adhesive interface and the bonding layer. The best resistance to acid erosion was obtained by RMGIC.
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- 2022
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36. Mechanical Properties of Orthodontic Cements and Their Behavior in Acidic Environments
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Cristina Iosif, Stanca Cuc, Doina Prodan, Marioara Moldovan, Ioan Petean, Anca Labunet, Lucian Barbu Tudoran, Iulia Clara Badea, Sorin Claudiu Man, Mîndra Eugenia Badea, and Radu Chifor
- Subjects
orthodontic cements ,acidic environment ,mechanical properties ,surface roughness ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
The present research is focused on three different classes of orthodontic cements: resin composites (e.g., BracePaste); resin-modified glass ionomer RMGIC (e.g., Fuji Ortho) and resin cement (e.g., Transbond). Their mechanical properties such as compressive strength, diametral tensile strength and flexural strength were correlated with the samples’ microstructures, liquid absorption, and solubility in liquid. The results show that the best compressive (100 MPa) and flexural strength (75 Mpa) was obtained by BracePaste and the best diametral tensile strength was obtained by Transbond (230 MPa). The lowestvalues were obtained by Fuji Ortho RMGIC. The elastic modulus is relatively high around 14 GPa for BracePaste, and Fuji Ortho and Transbond have only 7 GPa. The samples were also subjected to artificial saliva and tested in different acidic environments such as Coca-Cola and Red Bull. Their absorption and solubility were investigated at different times ranging from 1 day to 21 days. Fuji Ortho presents the highest liquid absorption followed by Transbond, the artificial saliva has the best absorption and Red Bull has the lowest absorption. The best resistance to the liquids was obtained by BracePaste in all environments. Coca-Cola presents values four times greater than the ones observed for artificial saliva. Solubility tests show that BracePaste is more soluble in artificial saliva, and Fuji Ortho and Transbond are more soluble in Red Bull and Coca-Cola. Scanning electron microscopy (SEM) images evidenced a compact structure for BracePaste in all environments sustaining the lower liquid absorption values. Fuji Ortho and Transbond present a fissure network allowing the liquid to carry out in-depth penetration of materials. SEM observations are in good agreement with the atomic force microscopy (AFM) results. The surface roughness decreases with the acidity increasing for BracePaste meanwhile it increases with the acidity for Fuji Ortho and Transbond. In conclusion: BracePaste is recommended for long-term orthodontic treatment for patients who regularly consume acidic beverages, Fuji Ortho is recommended for short-term orthodontic treatment for patients who regularly consume acidic beverages and Transbond is recommended for orthodontic treatment over an average time period for patients who do not regularly consume acidic beverages.
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- 2022
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37. Comparative Evaluation of Two Bracket Systems’ Bond Strength: Conventional and Self-Ligating
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Aurel-Claudiu Vartolomei, Dana-Valentina Ghiga, Dan-Cosmin Serbanoiu, Marioara Moldovan, Stanca Cuc, Mariana Pacurar, and Maria Cristina Figueiredo Pollmann
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shear bond strength ,adhesion ,active self-ligating brackets ,passive self-ligating brackets ,conventional brackets ,tensile strength ,Dentistry ,RK1-715 - Abstract
Adhesion remains a key element in dentistry, whether approached in prosthetics, odontology, or orthodontics. It is a continuously researched aspect, as improved materials and adhesive methods keep emerging in the market. No orthodontic treatment can be effective without the proper adhesion strength of the bonded elements on the teeth. The objective of this research, in the broad context of self-ligating versus conventional brackets, was to compare active and passive self-ligating systems with a conventional one by conducting an in vitro study on human-extracted premolars. Shear bond strength tests were executed by means of an advanced materials-testing machine that generated maximum load and tensile strength values. The data obtained underwent statistical analysis with a statistical threshold of p < 0.05. The results regarding the statistical significance were acquired when comparing the passive self-ligating system with the active self-ligating and conventional systems (load-at-maximum-load mean 204.9, SD 91.09, and p < 0.05). In this study, the passive self-ligating bracket system appears to present increased shear bond strength.
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- 2022
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38. Endovascular treatment of transplanted renal artery stenosis with PTA/stenting
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Guzzardi, G., primary, Fossaceca, R., additional, Di Gesù, I., additional, Cerini, P., additional, Di Terlizzi, M., additional, Stanca, C., additional, Malatesta, E., additional, Moniaci, D., additional, Brustia, P., additional, Stratta, P., additional, and Carriero, A., additional
- Published
- 2012
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39. Endovascular treatment of popliteal artery aneurysms: preliminary results
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Guzzardi, G., primary, Fossaceca, R., additional, Cerini, P., additional, Di Terlizzi, M., additional, Stanca, C., additional, Di Gesù, I., additional, Martino, F., additional, Brustia, P., additional, and Carriero, A., additional
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- 2012
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40. Long-term efficacy of endovascular treatment of isolated iliac artery aneurysms
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Fossaceca, R., primary, Guzzardi, G., additional, Di Terlizzi, M., additional, Divenuto, I., additional, Cerini, P., additional, Malatesta, E., additional, Di Gesù, I., additional, Stanca, C., additional, Brustia, P., additional, and Carriero, A., additional
- Published
- 2012
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41. Stress for stress tolerance: improving cell survival by sublethal stress treatment of eggs before vitrification – pilot study
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Pribenszky, C., primary, Mátyás, S., additional, Losonczi, E., additional, Stanca, C., additional, Bock, I., additional, and Vajta, G., additional
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- 2010
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42. Comparative Evaluation of Two Bracket Systems’ Kinetic Friction: Conventional and Self-Ligating
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Aurel-Claudiu Vartolomei, Dan-Cosmin Serbanoiu, Dana-Valentina Ghiga, Marioara Moldovan, Stanca Cuc, Maria Cristina Figueiredo Pollmann, and Mariana Pacurar
- Subjects
friction ,self-ligating brackets ,conventional brackets ,tensile strength ,maximum load ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
Friction is an intensely studied feature in orthodontics, as the sliding mechanics approach remains one of the most utilized techniques in current practice, and the question of whether self-ligating brackets produce less friction than conventional brackets still stands. The objective of this study was to compare a self-ligating system with different closing mechanisms and a conventional system with different ligating mechanisms regarding their frictional properties. Laboratory measurements were performed using an advanced materials testing machine generating tensile strength and load at maximum Load values, which were statistically analyzed and compared. These two parameters have been associated with the frictional resistance generated at the archwire–bracket slot interface. Statistically significant results were obtained when comparing the active self-ligating brackets with the passive self-ligating (tensile strength mean 1.953, SD 0.4231; load at maximum moad mean 6.000, SD 1.3000) and conventional brackets (tensile strength mean 1.953, SD 0.4231; load at maximum load mean 6.000, SD 1.3000), as well as when comparing the passive self-ligating brackets with the conventional brackets (tensile strength mean 1.708, SD 0.8628; load at maximum load mean 5.254, SD 2.645). The active self-ligating brackets tended to produce more friction when compared to the passive self-ligating brackets but were similar to conventional brackets with stainless steel ligatures.
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- 2022
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43. Restricted use of albumin for spontaneous bacterial peritonitis
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Sigal, S. H, primary, Stanca, C. M, additional, Fernandez, J., additional, Arroyo, V., additional, and Navasa, M., additional
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- 2007
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44. Photodynamic Therapy (PDT) in Prosthodontics: Disinfection of Human Teeth Exposed to Streptococcus mutans and the Effect on the Adhesion of Full Ceramic Veneers, Crowns, and Inlays: An In Vitro Study
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Corina Elena Tisler, Radu Chifor, Mindra Eugenia Badea, Marioara Moldovan, Doina Prodan, Rahela Carpa, Stanca Cuc, Ioana Chifor, and Alexandru Florin Badea
- Subjects
photodynamic therapy ,biofilm ,ceramic ,adhesion ,pull-out test ,SEM ,Biology (General) ,QH301-705.5 - Abstract
The use of PDT in prosthodontics as a disinfection protocol can eradicate bacteria from tooth surfaces by causing the death of the microorganisms to which the photosensitizer binds, absorbing the energy of laser light during irradiation. The aim of the study was to investigate the capacity of PDT to increase the bond strength of full ceramic restorations. In this study, 45 extracted human teeth were prepared for veneers, crowns, and inlays and contaminated with Streptococcus mutans. Tooth surfaces decontamination was performed using a diode laser and methylene blue as a photosensitizer. The disinfection effect and the impact on tensile bond strength were evaluated by scanning electron microscopy (SEM) and pull-out tests of the cemented ceramic prosthesis. Results show that the number of bacteria was reduced from colonized prepared tooth surfaces, and the bond strength was increased when PDT was used. In conclusion, the present study indicates that using PDT as a protocol before the final adhesive cementation of ceramic restorations could be a promising approach, with outstanding advantages over conventional methods.
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- 2022
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45. Development of New Experimental Dental Enamel Resin Infiltrants—Synthesis and Characterization
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Doina Prodan, Marioara Moldovan, Andrea Maria Chisnoiu, Codruța Saroși, Stanca Cuc, Miuța Filip, Georgiana Florentina Gheorghe, Radu Marcel Chisnoiu, Gabriel Furtos, Ileana Cojocaru, Ada Gabriela Delean, and Sanda Ileana Cimpean
- Subjects
dental resin infiltrants ,white spot ,degree of conversion ,fluoride release ,flexural strength ,Technology ,Electrical engineering. Electronics. Nuclear engineering ,TK1-9971 ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Microscopy ,QH201-278.5 ,Descriptive and experimental mechanics ,QC120-168.85 - Abstract
The aim of the present study was to obtain experimental infiltration materials, intended for the treatment of dental white spots, and to investigate them. Two series of infiltrants (P1–P6)/(P1F–P6F) were obtained, based on different monomer mixtures, without/with glass filler (with fluoride release ability). Each infiltrant from the second series contained the same amount of glass powder, and each infiltrant from the (P–PF) group contained the same resin composition. The characteristics of the experimental infiltrants were investigated by degree of conversion (DC), mechanical strength, water sorption (WS), and fluoride release, in addition to residual monomer for (P1F–P6F) infiltrants. The results were compared with those obtained for commercial Icon infiltrant. For the experimental infiltrants, without/with filler, the recorded DC was in the range of 58.27–89.70%/60.62–89.99%, compared with Icon (46.94%) 24 h after polymerization. The release of fluoride depends on the permeability of the polymer matrix, with respect to the water sorption, which may help to diffuse ions in the storage medium but which can also influence the release of residual monomers. The highest flexural strengths were recorded for the (TEGDMA/HEMA/Bis-GMA) infiltrants (133.94 ± 16.389 MPa/146.31 ± 7.032 MPa). The best experimental infiltrants were P2 and P2F (Bis-GMA/HEMA/TEGDMA).
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- 2022
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46. Structural Changes in Resin-Based Composites in Saliva of Patients with Leukemia before Starting Chemotherapeutic Regimen
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Alexandru Mester, Marioara Moldovan, Stanca Cuc, Ioan Petean, Ciprian Tomuleasa, Andra Piciu, Cristian Dinu, Simion Bran, and Florin Onisor
- Subjects
leukemia ,dental composite ,chemotherapy ,saliva ,oral health ,Organic chemistry ,QD241-441 - Abstract
Background: The aim of this in vitro study was to assess the morphological characteristics and stability of dental composites immersed in saliva collected from patients with leukemia. Material and Methods: A total number of five patients without systemic disease and 20 patients with leukemia (acute lymphoblastic leukemia (ALL), acute myeloid leukemia (AML), chronic lymphocytic leukemia (CLL), and chronic myeloid leukemia (CML)) were included for saliva sampling. Composite disks were immersed in the leukemia, control, and artificial environments for 7 days. At the end of the experiment, atomic force microscopy (AFM), color stability (ΔE), and saliva elements analysis were performed. Statistical significance was considered for a p-value under 0.05. Results: The most changed surface resulted for ALL with a roughness that was almost double that of the untreated sample and was significantly increased compared to the healthy saliva. The effect of CLL was not as intense as observed for acute leukemia, but was significantly over the control. ALL seemed to modify structural components of the saliva, which were able to deteriorate the surface of the composite. ALL saliva promoted a significant dissolution of the initial feature of the samples and promoted nano-particle clusterization. All dental composites showed clinically acceptable color change values (ΔE < 3.3) in all four-leukemia salivas; CLL and CML showed large color differences for all composites. The total concentrations of P, Na, and K showed wide ranges of variations, while the coefficient of variation in Fe, Cu, and Mg showed narrow variations between the salvias’ investigated. The salivary concentration of zinc decreased considerably in the CLL and CML environments compared to the ALL and AML environments. Fe and Cu were significantly increased in the CML environment. Conclusions: Control and artificial salivas have a mild erosive effect on the surface of dental composites. The acute stage of the disease seems to deteriorate the surface roughness rather than its morphology, however, in the chronic stage, it is the surface morphology that mostly deteriorates.
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- 2022
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47. Effects of Monomer Composition of Urethane Methacrylate Based Resins on the C=C Degree of Conversion, Residual Monomer Content and Mechanical Properties
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Codruta Sarosi, Marioara Moldovan, Andrada Soanca, Alexandra Roman, Timea Gherman, Ancuta Trifoi, Andrea Maria Chisnoiu, Stanca Cuc, Miuta Filip, Georgiana Florentina Gheorghe, and Radu Marcel Chisnoiu
- Subjects
dental resin ,dimethacrylates ,PEG ,residual monomer ,Organic chemistry ,QD241-441 - Abstract
(1) Background: This study investigated the influence of Bis-GMA, TEGDMA, UDMA, and two different polyethylene glycol (PEG)-containing, UDMO-based co-monomers on the Young’s modulus and flexural strength, degree of methacrylate C=C double bond conversion and residual monomer elution of experimental dental resins. (2) Methods: Urethane methacrylate-based monomer was synthesised via a radical chain growth polymerization mechanism using PEG in order to improve the mechanical properties. Dental resins were formulated using Bis-GMA, UDMA, or UDMO as base monomers combined with TEGDMA as a dilution monomer and DMAEM + CQ as the photo-initiator system. Degree of conversion (DC), mechanical properties, and residual monomer content of light-activated methacrylate resin formulations were evaluated and statistically analysed by ANOVA and a Tukey’s test. (3) Results: PEG-containing UDMO resins had lower Young’s modulus and elastic strength than UDMA-derived resin for all irradiation times. The highest DC (67,418%) was observed for the PEG-containing UDMO-based resin formulation when light cured for 40 s. For all samples, DC increased with the photo-polymerization time. The amount of residual monomer decreased after increasing the light-curing period from 20 to 40 s, resin with UDMO content 0.01 mol of PEG having the smallest amount of free eluted monomer. (4) Conclusions: A strong structure–property relationship exists in photo-cured dimethacrylate-based dental resins. The time and quantity of the photochemical initiation system can influence the physical–mechanical properties of the resins but also the monomers in their composition.
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- 2021
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48. Characteristics of Dental Resin-Based Composites in Leukemia Saliva: An In Vitro Analysis
- Author
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Alexandru Mester, Marioara Moldovan, Stanca Cuc, Ciprian Tomuleasa, Sergiu Pasca, Miuta Filip, Andra Piciu, and Florin Onisor
- Subjects
leukemia ,oral health ,saliva ,dental composite ,resin-based composite ,Biology (General) ,QH301-705.5 - Abstract
Background: The aim was to analyze, in vitro, four resin based composite systems (RBCs) immersed in saliva of leukemia patients before starting chemotherapy regiments. Material and methods: Saliva was collected from 20 patients (4 healthy patients, 16 leukemia patients). Resin disks were made for each RBC and were immersed in the acute leukemia (acute lymphocytic (ALL), acute myeloid (AML)), chronic leukemia (chronic lymphocytic (CLL), chronic myeloid (CML)), Artificial saliva and Control environment, and maintained for seven days. At the end of the experiment, the characteristics and the effective response of saliva from the studied salivas’ on RBCs was assessed using water sorption, water solubility, residual monomer and scanning electron microscopy (SEM). Data analysis was performed and a p-value under 0.05 was considered statistically significant. Results: The behaviour of RBCs in different immersion environments varies according to the characteristics of the RBCs. RBCs with a higher filler ratio have a lower water sorption. The solubility is also deteriorated by the types of organic matrix and filler; the results of solubility being inversely proportional on the scale of negative values compared to sorption values. Chromatograms of residual monomers showed the highest amount of unreacted monomers in ALL and AML, and the Control and artificial saliva environments had the smallest residual monomer peaks. Because of the low number of differences between the experimental conditions, we further considered that there were no important statistical differences between experimental conditions and analysed them as a single group. Conclusion: The influence of saliva on RBCs depends on the type of leukemia; acute leukemia influenced the most RBCs by changing their properties compared to chronic leukemia.
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- 2021
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49. Synthesis and Characterization of Some Graphene Oxide Powders Used as Additives in Hydraulic Mortars
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Doina Prodan, Marioara Moldovan, Gabriel Furtos, Codruța Saroși, Miuța Filip, Ioana Perhaița, Rahela Carpa, Maria Popa, Stanca Cuc, Simona Varvara, and Dorin Popa
- Subjects
building materials ,graphene oxide ,FT-IR ,TG ,UV-Vis ,SEM ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
Various powders of graphene oxide (GO), GO with silver (GO-Ag) and zinc oxide (GO-ZnO) were obtained. The powders were silanized with (3-aminopropyl) triethoxysilane (APTES) aiming to be used, in a future stage, as additives in the hydraulic lime mortars composition. The powders were characterized by Fourier Transform Infrared Spectrometry (FTIR) and Scanning Electron Microscopy (SEM) before and after the silanization process. GO, GO-Ag, GO-Ag-APTES, GO-ZnO and GO-ZnO-APTES powders were also investigated by Thermogravimetric Analysis (TG/DTA) and Ultraviolet–Visible Spectroscopy (UV-Vis). Likewise, the antibacterial effect of powders against five bacterial strains was evaluated. The peaks associated to the functional groups from GO, GO-APTES, GO-Ag, GO-Ag-APTES, GO-ZnO and GO-ZnO-APTES powders were identified by FTIR analysis. The mass losses of powders, analyzed by TG/DTA were lower than those recorded for GO. By UV-VIS analysis, maxima corresponding to the electronic π-π * and n-π * transitions were recorded. SEM images highlighted the lamellar and layered structure of GO, but also the presence of Ag and Zn nanoparticles on the surface of graphene sheets. All these results confirm the presence of Ag/ZnO/APTES on the GO. The antibacterial effect evaluated by recording the diameter of the inhibition zone ranged between 12–22 mm.
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- 2021
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50. An Evaluation of the Demineralizing Effects of Various Acidic Solutions
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Agnes Kolumban, Marioara Moldovan, Ioan Andrei Țig, Ioana Chifor, Stanca Cuc, Marius Bud, and Mindra Eugenia Badea
- Subjects
enamel demineralization ,hydroxyapatite ,acid solution ,artificial white spot lesion ,Technology ,Engineering (General). Civil engineering (General) ,TA1-2040 ,Biology (General) ,QH301-705.5 ,Physics ,QC1-999 ,Chemistry ,QD1-999 - Abstract
The purpose of this study was to evaluate which of the techniques and acids included in this in vitro research can induce artificial caries lesions in the most natural way. White spot lesions were created using six different demineralizing solutions in liquid form (lactic acid; orthophosphoric acid; formic acid; and an acid solution that contains calcium chloride, sodium phosphate and acetic acid) and gel form (hydrochloric acid and orthophosphoric acid). Radiographs, photographs and readings with a DIAGNODent™ pen, VITA Easyshade and a scanning electron microscope (SEM) were made in the initial situation, after 30 min, 1 h, 24 h and 96 h of demineralization. The total color change (ΔE) values in most cases presented statistically significant differences. SEM images showed different aspects of the enamel surface for each type of acid. Only in the case of exposed dentine did the DIAGNODent™ pen record significant differences. There was no noticeable radio-translucency of the teeth treated for a short period of time, but after 24 h, the absence of enamel and major demineralization of dentine were visible. Acids in the liquid state can penetrate and demineralize dental structures deeper than those that are more viscous. This study should be repeated with a protocol that includes remineralization. Using weaker acids would be another direction that could lead to more interesting findings.
- Published
- 2021
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