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Aims. The aim of this work is to compare the detailed chemical composition of the field N-rich dwarf stars to the second generation stars of globular clusters (GC) in order to investigate the hypothesis that they originated in GCs. Methods. We have measured the abundance of 23 elements (from Li to Eu) in a sample of six metal-poor N-rich stars (three of them pointed out for the first time) and we have compared their chemical composition to, (i) the chemical composition observed in a sample of classical metal-poor stars, and (ii) the abundances observed in the second generation stars of GCs. Results. In metal-poor N-rich stars C and O are slightly deficient but the scatter of [(C+N+O)/Fe] is very small, a strong indication that the N enrichment is the result of a pollution by CNO processed material. The N-rich stars of our sample, like the second generation stars in the GCs, show an excess of Na and sometimes of Al, as expected if the material from which these stars were formed, has been polluted by the ejecta of massive AGB stars. For the first time we have been able to establish an anti-correlation Na-O in field stars like the one observed in NGC6752. The N-rich star HD 74000 has a rather low [Eu/Ba] ratio for its metallicity. Such an anomaly is also observed in several second generation stars of M15. Conclusions. This analysis supports the hypothesis that the N-rich stars today observed in the field, were born as second generation stars in GCs., Comment: Astronomy and Astrophysics, EDP Sciences, 2022

The 'First Stars' programme revealed the metal-poor halo star CS 31082-001 to be r-process and actinide rich, including the first measurement of a uranium abundance for an old star. To better characterise and understand such rare objects, we present the first abundance estimates of three elements (Be, V, Cu) for CS 31082-001 from analysis of its near-ultraviolet spectrum. Beryllium is rarely measured in giant stars, and we confirm that its abundance in this star is low due to the rather cool effective temperature that causes destruction of both Be and Li in its atmosphere. Vanadium and copper are iron-peak elements that are starting to be used as chemical-tagging indicators to investigate the origin of stellar populations. We find V and Cu abundances for CS 31082-001 that are comparable to other metal-poor stars, and present new chemical evolution models to investigate our results. In the case of V, extra nucleosynthesis due to interaction of neutrinos with matter is included in the models to be able to reproduce the measured abundance. Given the availability of high-quality spectroscopy of CS 31082-001, we also explore other atomic lines in the near-ultraviolet as a template for future studies of metal-poor stars with the planned CUBES instrument in development for the Very Large Telescope.

Context. The study of old, metal-poor stars deepens our knowledge on the early stages of the universe. In particular, the study of these stars gives us a valuable insight into the masses of the first massive stars and their emission of ionising photons. Aims. We present a detailed chemical analysis and determination of the kinematic and orbital properties of a sample of 11 dwarf stars. These are metal-poor stars, and a few of them present a low lithium content. We inspected whether the other elements also present anomalies. Methods. We analysed the high-resolution UVES spectra of a few metal-poor stars using the Turbospectrum code to synthesise spectral lines profiles. This allowed us to derive a detailed chemical analysis of Fe

The isotope abundances provide powerful diagnostics of the chemical enrichment in our Galaxy. The star HD 140283 is one of the best-studied very metal-poor dwarf stars. It is very old, and the chemical abundance in this star is a good witness of the chemical composition of the matter in the early Galaxy. The aim of this work is to measure the precise abundances of carbon, nitrogen, oxygen, and mainly the 12C/13C isotopic ratio in this very old metal-poor star in order to have a good reference for the computations of the chemical evolution of the Galaxy. We used very high spectral resolution data, with extremely high signal-to-noise ratios obtained with the spectrographs ESPaDOnS at the CFHT, ESPRESSO at the VLT, and HARPS at the ESO 3.6m telescope. For the first time, we were able to measure the 12C/13C ratio in a very old metal-poor dwarf that was born at the very beginning of the Galaxy: 27 < 12C/13C < 45. We also obtained a precise determination of the abundance of the CNO elements in this star. These abundances suggest that the effect of super-asymptotic giant branch stars or fast-rotating massive stars was significant in the early Galaxy., Comment: Accepted for Publication in A&A, 6 pages, 3 figures

Context. The TOPoS project has the goal to find and analyse Turn-Off (TO) stars of extremely low metallicity. To select the targets for spectroscopic follow-up at high spectral resolution, we have relied on low-resolution spectra from the Sloan Digital Sky Survey. Aims. In this paper we use the metallicity estimates we have obtained from our analysis of the SDSS spectra to construct the metallicity distribution function (MDF) of the Milky Way, with special emphasis on its metal-weak tail. The goal is to provide the underlying distribution out of which the TOPoS sample was extracted. Methods. We make use of SDSS photometry, Gaia photometry and distance estimates derived from the Gaia parallaxes to derive a metallicity estimate for a large sample of over 24 million TO stars. This sample is used to derive the metallicity bias of the sample for which SDSS spectra are available. Results. We determined that the spectroscopic sample is strongly biased in favour of metal-poor stars, as intended. A comparison with the unbiased photometric sample allows to correct for the selection bias. We select a sub-sample of stars with reliable parallaxes for which we combine the SDSS radial velocities with Gaia proper motions and parallaxes to compute actions and orbital parameters in the Galactic potential. This allows us to characterize the stars dynamically, and in particular to select a sub-sample that belongs to the Gaia-Sausage-Enceladus (GSE) accretion event. We are thus able to provide also the MDF of GSE. Conclusions. The metal-weak tail derived in our study is very similar to that derived in the H3 survey and in the Hamburg/ESO Survey. This allows us to average the three MDFs and provide an error bar for each metallicity bin. Inasmuch the GSE structure is representative of the progenitor galaxy that collided with the Milky Way, that galaxy appears to be strongly deficient in metal-poor stars compared to the Milky Way, suggesting that the metal-weak tail of the latter has been largely formed by accretion of low mass galaxies rather than massive galaxies, such as the GSE progenitor., Comment: Astronomy and Astrophysics - A\&A, EDP Sciences, in press

Unevolved metal poor stars are the witness of the early evolution of the Galaxy. The determination of their detailed chemical composition is an important tool to understand the chemical history of our Galaxy. The study of their chemical composition can also be used to constrain the nucleosynthesis of the first generation of supernovae that enriched the interstellar medium. The aim is to observe a sample of extremely metal poor stars (EMP stars) candidates selected from SDSS DR12 release and determine their chemical composition. We obtained high resolution spectra of a sample of five stars using HDS on Subaru telescope and used standard 1D models to compute the abundances. The stars we analysed have a metallicity [Fe/H] between -3.50 dex and -4.25 dex . We confirm that the five metal poor candidates selected from low resolution spectra are very metal poor. We present, the discovery of a new ultra metal-poor star (UMP star) with a metallicity of [Fe/H]= -4.25 dex (SDSS~J1050032.34$-$241009.7). We measured in this star an upper limit of lithium ( log(Li/H) <= 2.0. We found that the 4 most metal poor stars of our sample have a lower lithium abundance than the Spite plateau lithium value. We obtain upper limits for carbon in the sample of stars. None of them belong to the high carbon band. We measured abundances of Mg and Ca in most of the stars and found three new alpha-poor stars., Comment: Accepted for Publication in A&A, 10 pages, 8 figures

We analyse a set of very metal-poor stars for which accurate chemical abundances have been obtained as part of the ESO Large Program "First stars" in the light of the Gaia DR2 data. The kinematics and orbital properties of the stars in the sample show they probably belong to the thick disc, partially heated to halo kinematics, and to the accreted Nissen & Schuster-Gaia Sausage-Enceladus satellite. The continuity of these properties with stars at both higher ($\rm [Fe/H]>-2$) and lower metallicities ($\rm [Fe/H]<-4.$) suggests that the Galaxy at $\rm [Fe/H] \lesssim -0.5$ and down to at least $\rm [Fe/H]\sim-6$ is dominated by these two populations. In particular, we show that the disc extends continuously from $\rm [Fe/H] \le -4$ (where stars with disc-like kinematics have been recently discovered) up to $\rm [Fe/H] \ge -2$, the metallicity regime of the Galactic thick disc. There exists indeed an "ultra-metal poor thick disc", which constitutes the extremely metal-poor tail of the canonical Galactic thick disc, and which extends this latter from $\rm [Fe/H] \sim -0.5$ up to the most metal-poor stars discovered in the Galaxy up to date. These results suggest that the disc may be the main, and possibly the only stellar population that has formed in the Galaxy at these metallicities. This requires that the dissipative collapse that led to the formation of the old Galactic disc must have been extremely fast. We also discuss these results in the light of recent simulation efforts made to reproduce the first stages of Milky Way-type galaxies., Comment: 30 pages, 18 figures, A&A, in press

Measurable amounts of Be could have been synthesised primordially if the Universe were non-homogeneous or in the presence of late decaying relic particles. We investigate the Be abundance in the extremely metal-poor star 2MASS J1808-5104 ([Fe/H]=--3.84) with the aim of constraining inhomogeneities or the presence of late decaying particles. High resolution, high signal-to-noise ratio UV spectra were acquired at ESO with the Kueyen 8.2 m telescope and the UVES spectrograph. Abundances were derived using several model atmospheres and spectral synthesis code. We measured log(Be/H) = -14.3 from a spectrum synthesis of the region of the Be line. Using a conservative approach, however we adopted an upper limit two times higher, i.e. log(Be/H) < -14.0. We measured the O abundance from UV OH lines and find [O/H]=--3.46 after a 3D correction. Our observation reinforces the existing upper limit on primordial Be. There is no observational indication for a primordial production of Be. This places strong constraints on the properties of putative relic particles. This result also supports the hypothesis of a homogeneous Universe, at the time of nucleosynthesis. Surprisingly, our upper limit of the Be abundance is well below the Be measurements in stars of similar [O/H]. This may be evidence that the Be-O relation breaks down in the early Galaxy, perhaps due to the escape of spallation products from the gas clouds in which stars such as 2MASS J1808-5104 have formed., Comment: 9 pages, 9 Figures

Extremely metal-poor stars are keys to understand the early evolution of our Galaxy. The ESO large programme TOPoS has been tailored to analyse a new set of metal-poor turn-off stars, whereas most of the previously known extremely metal-poor stars are giant stars. Sixty five turn-off stars (preselected from SDSS spectra) have been observed with the X-Shooter spectrograph at the ESO VLT Unit Telescope 2, to derive accurate and detailed abundances of magnesium, silicon, calcium, iron, strontium and barium. We analysed medium-resolution spectra (R ~ 10 000) obtained with the ESO X-Shooter spectrograph and computed the abundances of several alpha and neutron-capture elements using standard one-dimensional local thermodynamic equilibrium (1D LTE) model atmospheres. Our results confirms the super-solar [Mg/Fe] and [Ca/Fe] ratios in metal-poor turn-off stars as observed in metal-poor giant stars. We found a significant spread of the [alpha/Fe] ratios with several stars showing sub-solar [Ca/Fe] ratios. We could measure the abundance of strontium in 12 stars of the sample, leading to abundance ratios [Sr/Fe] around the Solar value. We detected barium in two stars of the sample. One of the stars (SDSS J114424-004658) shows both very high [Ba/Fe] and [Sr/Fe] abundance ratios (>1 dex)., Comment: Accepted for publication in A&A : 17 pages, 6 figures

The most metal-poor stars are the relics of the early chemical evolution of the Galaxy. Their chemical composition is an important tool to constrain the nucleosynthesis in the first generation of stars. The aim is to observe a sample of extremely metal-poor star (EMP stars) candidates selected from the Sloan Digital Sky Survey Data Release 12 (SDSS DR12) and determine their chemical composition. We obtain medium resolution spectra of a sample of six stars using the X-Shooter spectrograph at the Very Large Telescope (VLT) and we used ATLAS models to compute the abundances. Five stars of the sample have a metallicity [Fe/H] between -2.5 dex and -3.2 dex. We confirm the recent discovery of SDSS J002314.00+030758.0. As a star with an extremely low [Fe/H] ratio. Assuming the alpha-enhancement [Ca/Fe]=+0.4 dex, we obtain [Fe/H]=-6.1 dex. We could also determine its magnesium abundance and found that this star exhibits a very high ratio [Mg/Fe] >= +3.60~dex assuming [Fe/H] = -6.13 dex. We determined the carbon abundance and found A(C)=6.4 dex. From this carbon abundance, this stars belongs to the lower band of the A(C)-[Fe/H] diagram., Comment: Accepted to A&A - 8 pages, 5 figures

The Gaia Data Release 2 provides a parallax of 0.734+/-0.073 mas for SDSS J102915+172927, currently the most metal-poor known object. This parallax implies that it is dwarf star, ruling out the scenario that it is a subgiant. The subgiant scenario had as a corollary that the star had been formed in a medium highly enriched in C, thus making line cooling efficient during the collapse, that was also highly enriched in Fe by Type Ia SNe. This scenario can also now be ruled out for this star, reinforcing the need of dust cooling and fragmentation to explain its formation., Comment: Accepted for publication in Research Notes of the AAS

Carbon-enhanced metal-poor (CEMP) stars represent a sizeable fraction of all known metal-poor stars in the Galaxy. Their formation and composition remains a significant topic of investigation within the stellar astrophysics community. We analysed a sample of low-resolution spectra of 30 dwarf stars, obtained using the the visual and near UV FOcal Reducer and low dispersion Spectrograph for the Very Large Telescope (FORS/VLT) of the European Southern Observatory (ESO) and the Gemini Multi-Object Spectrographs (GMOS) at the GEMINI telescope, to derive their metallicity and carbon abundance. We derived C and Ca from all spectra, and Fe and Ba from the majority of the stars. We have extended the population statistics of CEMP stars and have confirmed that in general, stars with a high C abundance belonging to the high C band show a high Ba-content (CEMP-s or -r/s), while stars with a normal C-abundance or that are C-rich, but belong to the low C band, are normal in Ba (CEMP-no)., Comment: A&A in press

Extremely metal-poor stars provide us with indirect information on the first generations of massive stars. The TOPoS survey has been designed to increase the census of these stars and to provide a chemical inventory that is as detailed as possible. Seven of the most iron-poor stars have been observed with the UVES spectrograph at the ESO VLT Kueyen 8.2m telescope to refine their chemical composition. We analysed the spectra based on 1D LTE model atmospheres, but also used 3D hydrodynamical simulations of stellar atmospheres. We measured carbon in six of the seven stars: all are carbon-enhanced and belong to the low-carbon band, defined in the TOPoS II paper. We measured lithium (A(Li)=1.9) in the most iron-poor star (SDSS J1035+0641, [Fe/H] < -5.2 ). We were also able to measure Li in three stars at [Fe/H]~ -4.0, two of which lie on the Spite plateau. We confirm that SDSS J1349+1407 is extremely rich in Mg, but not in Ca. It is also very rich in Na. Several of our stars are characterised by low alpha-to-iron ratios. The lack of high-carbon band stars at low metallicity can be understood in terms of evolutionary timescales of binary systems. The detection of Li in SDSS J1035+0641 places a strong constraint on theories that aim at solving the cosmological lithium problem. The Li abundance of the two warmer stars at [Fe/H]~ -4.0 places them on the Spite plateau, while the third, cooler star, lies below. We argue that this suggests that the temperature at which Li depletion begins increases with decreasing [Fe/H]. SDSS J1349+1407 may belong to a class of Mg-rich EMP stars. We cannot assess if there is a scatter in alpha-to-iron ratios among the EMP stars or if there are several discrete populations. However, the existence of stars with low alpha-to-iron ratios is supported by our observations., Comment: A&A, in press

We have developed a model atom for Cu with which we perform statistical equilibrium computations that allow us to compute the line formation of Cu I lines in stellar atmospheres without assuming Local Thermodynamic Equilibrium (LTE). We validate this model atom by reproducing the observed line profiles of the Sun, Procyon and eleven metal-poor stars. Our sample of stars includes both dwarfs and giants. Over a wide range of stellar parameters we obtain excellent agreement among different Cu I lines. The eleven metal-poor stars have iron abundances in the range -4.2 <= [Fe/H] <= -1.4, the weighted mean of the [Cu/Fe] ratios is -0.22 dex, with a scatter of -0.15 dex. This is very different from the results from LTE analysis (the difference between NLTE and LTE abundances reaches 1 dex) and in spite of the small size of our sample it prompts for a revision of the Galactic evolution of Cu., Comment: To be published in MNRAS

In order to provide a better basis for the study of mechanisms of nucleosynthesis of the light elements beyond hydrogen and helium in the oldest stars, the abundances of C, O, Mg, Si, P, S, K, and Ca have been derived from UV-HST and visible-ESO high resolution spectra in the old, very metal-poor star HD 84937, at a metallicity that is 1/200 that of the Sun's. For this halo main-sequence turnoff star, the abundance determination of P and S are the first published determinations. The LTE profiles of the lines were fitted to the observed spectra. Wherever possible, we corrected the derived abundances for non-LTE effects. Three-dimensional (3D) CO5BOLD model atmospheres have been used to determine the abundances of C and O from molecular CH and OH bands. The abundances of these light elements in HD 84937 are found to agree well with the abundances in classical metal-poor stars. Our HD 84937 carbon abundance determination points toward a solar (or mildly enhanced) value of [C/Fe]. The modest overabundance of the alpha elements of even atomic number Z, typical of halo turnoff stars, is confirmed in this example. The odd-Z element P is found to be somewhat deficient in HD 84937, at [P/Fe]=-0.32, which is again consistent with the handful of existing determinations for turnoff stars of such low metallicity. We show that the abundance of oxygen, deduced from the OH band from 3D computations, is not compatible with the abundance deduced from the red oxygen triplet. This incompatibility is explained by the existence of a chromosphere heating the shallow layers of the atmosphere where the OH band, in 3D computations, is mainly formed. The abundance ratios are compared to the predictions of models of galactic nucleosynthesis and evolution, Comment: 8 pages, 9 figures

One of the primary objectives of the TOPoS survey is to search for the most metal-poor stars. Our search has led to the discovery of one of the most iron-poor objects known, SDSS\,J092912.32+023817.0. This object is a multiple system, in which two components are clearly detected in the spectrum. We have analysed 16 high-resolution spectra obtained using the UVES spectrograph at the ESO 8.2m VLT telescope to measure radial velocities and determine the chemical composition of the system. Cross correlation of the spectra with a synthetic template yields a double-peaked cross-correlation function (CCF) for eight spectra, and in one case there is evidence for the presence of a third peak. Chemical analysis of the spectrum obtained by averaging all the spectra for which the CCF showed a single peak found that the iron abundance is [Fe/H]=-4.97. The system is also carbon enhanced with [C/Fe]=+3.91 (A(C)=7.44). From the permitted oxygen triplet we determined an upper limit for oxygen of [O/Fe]<+3.52 such that C/O>1.3. We are also able to provide more stringent upper limits on the Sr and Ba abundances ([Sr/Fe]<+0.70, and [Ba/Fe]<+1.46, respectively)., Comment: Accepted for publication in A&A Letter

We aim at deriving accurate atmospheric parameters and chemical abundances of 19 barium (Ba) stars, including both strong and mild Ba stars, based on the high signal-to-noise ratio and high resolution Echelle spectra obtained from the 2.16 m telescope at Xinglong station of National Astronomical Observatories, Chinese Academy of Sciences. The chemical abundances of the sample stars were obtained from an LTE, plane-parallel and line-blanketed atmospheric model by inputting the atmospheric parameters (effective temperatures, surface gravities, metallicity and microturbulent velocity) and equivalent widths of stellar absorption lines. These samples of Ba stars are giants indicated by atmospheric parameters, metallicities and kinematic analysis about UVW velocity. Chemical abundances of 17 elements were obtained for these Ba stars. Their light elements (O, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Mn and Ni) are similar to the solar abundances. Our samples of Ba stars show obvious overabundances of neutron-capture (n-capture) process elements relative to the Sun. Their median abundances of [Ba/Fe], [La/Fe] and [Eu/Fe] are 0.54, 0.65 and 0.40, respectively. The YI and ZrI abundances are lower than Ba, La and Eu, but higher than the light elements for the strong Ba stars and similar to the iron-peak elements for the mild stars. There exists a positive correlation between Ba intensity and [Ba/Fe]. For the n-capture elements (Y, Zr, Ba, La), there is an anti-correlation between their [X/Fe] and [Fe/H]. We identify nine of our sample stars as strong Ba stars with [Ba/Fe]>0.6 where seven of them have Ba intensity Ba=2-5, one has Ba=1.5 and another one has Ba=1.0. The remaining ten stars are classified as mild Ba stars with 0.17<[Ba/Fe]<0.54.

HD 140283 is a reference subgiant that is metal poor and confirmed to be a very old star. The abundances of this type of old star can constrain the nature and nucleosynthesis processes that occurred in its (even older) progenitors. The present study may shed light on nucleosynthesis processes yielding heavy elements early in the Galaxy. A detailed abundance analysis of a high-quality spectrum is carried out, with the intent of providing a reference on stellar lines and abundances of a very old, metal-poor subgiant. We aim to derive abundances from most available and measurable spectral lines. The analysis is carried out using high-resolution (R = 81 000) and high signal-to-noise ratio (800 < S/N/pixel < 3400) spectrum, in the wavelength range 3700 - 10475, obtained with a seven-hour exposure time, using the ESPaDOnS at the CFHT. The calculations in LTE were performed with the OSMARCS 1D atmospheric model and the spectrum synthesis code Turbospectrum, while the analysis in NLTE is based on the MULTI code. We present LTE abundances for 26 elements, and NLTE calculations for the species C I, O I, Na I, Mg I, Al I, K I, Ca I, Sr II, and Ba II lines. The abundance analysis provided an extensive line list suitable for metal-poor subgiant stars. The results for Li, CNO, alpha-, and iron peak elements are in good agreement with literature. The newly NLTE Ba abundance, along with a NLTE Eu correction and a 3D Ba correction from literature, leads to [Eu/Ba] = +0.59 +/- 0.18. This result confirms a dominant r-process contribution, possibly together with a very small contribution from the main s-process, to the neutron-capture elements in HD 140283. Overabundances of the lighter heavy elements and the high abundances derived for Ba, La, and Ce favour the operation of the weak r-process in HD 140283., Comment: 34 pages, 27 figures

We present a grid of computed non-local thermodynamic equilibrium (NLTE) equivalent widths (EW) and NLTE abundance corrections for four Ba II lines: 4554, 5853, 6141, and 6496 A. The grid can be useful in deriving the NLTE barium abundance in stars having parameters in the following ranges: effective temperature from 4000 K to 6500 K, surface gravity log g from 0 to 5, microturbulent velocity 0 km s^-1 to 3 km s^-1, metallicity [Fe/H] from -2 to +0.5, and [Ba/Fe] from -0.4 to +0.6. The NLTE abundance can be either derived by EW interpolation (using the observed Ba II line EW) or by using the NLTE correction applied to a previously determined LTE abundance. Ba II line equivalent widths and the NLTE corrections were calculated using the updated MULTI code and the Ba II atomic model that was previously applied to determine the NLTE barium abundance in different types of stars. The grid is available on-line through the web, and we find that the grid Ba NLTE corrections are almost as accurate as direct NLTE profile fitting (to within 0.05-0.08 dex). For the weakest Ba II line (5853 A) the LTE abundances almost agree with the NLTE abundances, whereas the other three Ba II lines, 4554, 6141, and 6496 A, need NLTE corrections even at the highest metallicities tested here. The 4554 A line is extremely strong and should not be used for abundance analysis above [Fe/H]= -1. Furthermore, we tested the impact of different model atmospheres and spectrum synthesis codes and found average differences of 0.06 dex and 0.09 dex, respectively, for all four lines. At these metallicities we find an average Delta NLTE of +/-0.1 dex for the three useful Ba lines for subsolar cool dwarfs., Comment: 9 pages 8 figures submitted to A&A

In the course of the TOPoS (Turn Off Primordial Stars) survey, aimed at discovering the lowest metallicity stars, we have found several carbon-enhanced metal-poor (CEMP) stars. We here present our analysis of six CEMP stars. Calcium and carbon are the only elements that can be measured in all six stars. The range is -5.0<=[Ca/H]< -2.1 and 7.12<=A(C)<=8.65. For star SDSS J1742+2531 we were able to detect three FeI lines from which we deduced [Fe/H]=-4.80, from four CaII lines we derived [Ca/H]=-4.56, and from synthesis of the G-band we derived A(C)=7.26. For SDSS J1035+0641 we were not able to detect any iron lines, yet we could place a robust (3sigma) upper limit of [Fe/H]< -5.0 and measure the Ca abundance, with [Ca/H]=-5.0, and carbon, A(C)=6.90. No lithium is detected in the spectrum of SDSS J1742+2531 or SDSS J1035+0641, which implies a robust upper limit of A(Li)<1.8 for both stars. Our measured carbon abundances confirm the bimodal distribution of carbon in CEMP stars, identifying a high-carbon band and a low-carbon band. We propose an interpretation of this bimodality according to which the stars on the high-carbon band are the result of mass transfer from an AGB companion, while the stars on the low-carbon band are genuine fossil records of a gas cloud that has also been enriched by a faint supernova (SN) providing carbon and the lighter elements. (Abridged), Comment: to be published on A&A

It has been noted that, in classical extremely metal-poor (EMP) stars, the abundance ratio of Sr and Ba, is always higher than [Sr/Ba] = -0.5, the value of the solar r-only process; however, a handful of EMP stars have recently been found with a very low Sr/Ba ratio. We try to understand the origin of this anomaly by comparing the abundance pattern of the elements in these stars and in the classical EMP stars. Four stars with very low Sr/Ba ratios were observed and analyzed within LTE approximation through 1D (hydrostatic) model atmosphere, providing homogeneous abundances of nine neutron-capture elements. In CS 22950-173, the only turnoff star of the sample, the Sr/Ba ratio is, in fact, found to be higher than the r-only solar ratio, so the star is discarded. The remaining stars (CS 29493-090, CS 30322-023, HE 305-4520) are cool evolved giants. They do not present a clear carbon enrichment. The abundance patterns of the neutron-capture elements in the three stars are strikingly similar to a theoretical s-process pattern. This pattern could at first be attributed to pollution by a nearby AGB, but none of the stars presents a clear variation in the radial velocity indicating the presence of a companion. The stellar parameters seem to exclude any internal pollution in a TP-AGB phase for at least two of these stars. The possibility that the stars are early-AGB stars polluted during the core He flash does not seem compatible with the theory., Comment: Accepted for publication in Astronomy and Astrophysics

Moderately r-process-enriched stars (r-I) are at least four times as common as those that are greatly enriched in r-process elements (r-II), and the abundances in their atmospheres are important tools for obtaining a better understanding of the nucleosynthesis processes responsible for the origin of the elements beyond the iron peak. The main aim of this work is to derive abundances for a sample of seven metal-poor stars with classified as r-I stars, to understand the role of these stars for constraining the astrophysical nucleosynthesis event(s) that is(are) responsible for the production of the r-process, and to investigate whether they differ, in any significant way, from the r-II stars. We carried out a detailed abundance analysis based on high-resolution spectra obtained with the VLT/UVES spectrograph. The OSMARCS LTE 1D model atmosphere grid was employed, along with the spectrum synthesis code Turbospectrum. We have derived abundances of light elements Li, C, and N, alpha-elements, odd-Z elements, iron-peak elements, and the trans-iron elements from the first peak, the second peak, the third peak, and the actinides regions. The results are compared with values for these elements for r-II and normal very and extremely metal-poor stars reported in the literature, ages based on radioactive chronometry are explored using different models, and a number of conclusions about the r-process and the r-I stars are presented. Hydrodynamical models were used for some elements, and general behaviors for the 3D corrections were presented., Comment: 24 pages, 31 figures, accepted by A&A

The metal-weak tail of the metallicity distribution function (MDF) of the Galactic Halo stars contains crucial information on the formation mode of the first generation of stars. To determine this observationally, it is necessary to observe large numbers of extremely metal-poor stars. We present here the Turn-Off Primordial Stars survey (TOPoS) that is conducted as an ESO Large Programme at the VLT. This project has {four} main goals: (i) to understand the formation of low-mass stars in a low-metallicity gas: determine the metal-weak tail of the halo MDF below [M/H]=-3.5. In particular, we aim at determining the critical metallicity, that is the lowest metallicity sufficient for the formation of low-mass stars; (ii) to determine the relative abundance of the elements in extremely metal-poor stars, which are the signature of the massive first stars; (iii) to determine the trend of the lithium abundance at the time when the Galaxy formed; and (iv) to derive the fraction of C-enhanced extremely metal-poor stars with respect to normal extremely metal-poor stars. The large number of stars observed in the SDSS provides a good sample of candidates of stars at extremely low metallicity. Candidates with turn-off colours down to magnitude g=20 were selected from the low-resolution spectra of SDSS by means of an automated procedure. X-Shooter has the potential of performing the necessary follow-up spectroscopy, providing accurate metallicities and abundance ratios for several key elements for these stars. We here present the stellar parameters of the first set of stars. The nineteen stars range in iron abundance between -4.1 and -2.9 dex relative to the Sun. Two stars have a high radial velocity and, according to our estimate of their kinematics, appear to be marginally bound to the Galaxy and are possibly accreted from another galaxy., Comment: A&A accepted for publication

The extremely metal-poor stars are the direct descendants of the first generation stars. They carry the chemical signature of the pristine Universe at the time they formed, shortly after the Big Bang. We aim to derive information about extremely metal-poor stars from their observed spectra. Four extremely metal-poor stars were selected from the Sloan Digital Sky Survey (SDSS) and observed during the guaranteed observing time of X-Shooter. The X-Shooter spectra were analysed using an automatic code, MyGIsFOS, which is based on a traditional analysis method. It makes use of a synthetic grid computed from one-dimensional, plane-parallel, hydrostatic model atmospheres. The low metallicity derived from the SDSS spectra is confirmed here. Two kinds of stars are found. Two stars are confirmed to be extremely metal-poor, with no evidence of any enhancement in carbon. The two other stars are strongly enhanced in carbon. We could not derive iron abundance for one of them, while [Ca/H] is below -4.5. Two of the stars are members of the rare population of extremely metal-poor stars low in alpha elements., Comment: A&A in press

Detailed abundances of the elements produced by r-process nucleosynthesis in various circumstances are our best observational clues to their origin, since the site(s) of r-element production is(are) still not known with certainty. A small fraction of extremely metal-poor (EMP) stars exhibit excesses of heavy neutron-capture elements produced in the r-process, and CS 31082-001 is among the 4 well-known r-process-enhanced EMP stars. Observations with HST/STIS provide abundances for elements observable only from the UV region. Here we aim to supplement the optical data with abundances from near-UV spectroscopy of the first and second peak of the r-elements, which are crucial to giving insight into the nucleosynthesis of the elements beyond iron. The UVES spectrum provided additional measurements, thereby improving the previous results. The spectra were analyzed with the OSMARCS LTE model atmosphere and with a consistent approach based on the spectrum synthesis code Turbospectrum to derive abundances of heavy elements in CS 31082-001, using updated oscillator strengths from the recent literature. We computed synthetic spectra for all lines of the elements of interest, checking for proper intensities and possible blends. We combined the abundances of heavy elements derived in previous works with the derivation of abundances from all reliable new list of lines, for the first and second peaks of r-elements. We were able to derive new abundances for 23 n-elements, 6 of them - Ge, Mo, Lu, Ta, W, and Re - were not available in previous works, making this star the most complete r-II object studied, with a total of 37 detections of n-capture elements. We also present the first NLTE+3D lead abundance in this star. The results provide improved constraints on the nature of the r-process., Comment: 20 pages, 21 figures, 3 tables. Accepted for publication in Astronomy and Astrophysics

HD 140283 is a nearby (V=7.7) subgiant metal-poor star, extensively analysed in the literature. Although many spectra have been obtained for this star, none showed a signal-to-noise (S/N) ratio high enough to enable a very accurate derivation of abundances from weak lines. The detection of europium proves that the neutron-capture elements in this star originate in the r-process, and not in the s-process, as recently claimed in the literature. Based on the OSMARCS 1D LTE atmospheric model and with a consistent approach based on the spectrum synthesis code Turbospectrum, we measured the europium lines at 4129 {\AA} and 4205 {\AA}, taking into account the hyperfine structure of the transitions. The spectrum, obtained with a long exposure time of seven hours at the Canada-France-Hawaii Telescope (CFHT), has a resolving power of 81000 and a S/N ratio of 800 at 4100 {\AA}. We were able to determine the abundance A(Eu)=-2.35 dex, compatible with the value predicted for the europium from the r-process. The abundance ratio [Eu/Ba]=+0.58 dex agrees with the trend observed in metal-poor stars and is also compatible with a strong r-process contribution to the origin of the neutron-capture elements in HD 140283., Comment: 10 pages, 7 figures. To be published in A\&A

Using the cosmological constants derived from WMAP, the standard big bang nucleosynthesis (SBBN) predicts the light elements primordial abundances for 4He, 3He, D, 6Li and 7Li. These predictions are in satisfactory agreement with the observations, except for lithium which displays in old warm dwarfs an abundance depleted by a factor of about 3. Depletions of this fragile element may be produced by several physical processes, in different stellar evolutionary phases, they will be briefly reviewed here, none of them seeming yet to reproduce the observed depletion pattern in a fully convincing way., Comment: Invited review at the conference Lithium in the cosmos, Paris 27-29 Feb 2012, one reference added

(Abridged) Extremely metal-poor stars contain the fossil records of the chemical composition of the early Galaxy. The NLTE profiles of the calcium lines were computed in a sample of 53 extremely metal-poor stars with a modified version of the program MULTI. With our new model atom we are able to reconcile the abundance of Ca deduced from the Ca I and Ca II lines in Procyon. -We find that [Ca/Fe] = 0.50 $\pm$ 0.09 in the early Galaxy, a value slightly higher than the previous LTE estimations. -The scatter of the ratios [X/Ca] is generally smaller than the scatter of the ratio [X/Mg] where X is a "light metal" (O, Na, Mg, Al, S, and K) with the exception of Al. These scatters cannot be explained by error of measurements, except for oxygen. Surprisingly, the scatter of [X/Fe] is always equal to, or even smaller than, the scatter around the mean value of [X/Ca]. -We note that at low metallicity, the wavelength of the Ca I resonance line is shifted relative to the (weaker) subordinate lines, a signature of the effect of convection. -The Ca abundance deduced from the Ca I resonance line (422.7 nm) is found to be systematically smaller at very low metallicity, than the abundance deduced from the subordinate lines., Comment: Accepted in Astronomy and Astrophysics

The early Universe had a chemical composition consisting of hydrogen, helium and traces of lithium1, almost all other elements were created in stars and supernovae. The mass fraction, Z, of elements more massive than helium, is called "metallicity". A number of very metal poor stars have been found some of which, while having a low iron abundance, are rich in carbon, nitrogen and oxygen. For theoretical reasons and because of an observed absence of stars with metallicities lower than Z=1.5E-5, it has been suggested that low mass stars (M<0.8M\odot, the ones that survive to the present day) cannot form until the interstellar medium has been enriched above a critical value, estimated to lie in the range 1.5E-8\leqZ\leq1.5E-6, although competing theories claiming the contrary do exist. Here we report the chemical composition of a star with a very low Z\leq6.9E-7 (4.5E-5 of that of the Sun) and a chemical pattern typical of classical extremely metal poor stars, meaning without the enrichment of carbon, nitrogen and oxygen. This shows that low mass stars can be formed at very low metallicity. Lithium is not detected, suggesting a low metallicity extension of the previously observed trend in lithium depletion. Lithium depletion implies that the stellar material must have experienced temperatures above two million K in its history, which points to rather particular formation condition or internal mixing process, for low Z stars., Comment: Published on Nature, 2011 Volume 477, Issue 7362, pp. 67-69

Context: The discovery and chemical analysis of extremely metal-poor stars permit a better understanding of the star formation of the first generation of stars and of the Universe emerging from the Big Bang. aims: We report the study of a primordial star situated in the centre of the constellation Leo (SDSS J102915+172027). method: The star, selected from the low resolution-spectrum of the Sloan Digital Sky Survey, was observed at intermediate (with X-Shooter at VLT) and at high spectral resolution (with UVES at VLT). The stellar parameters were derived from the photometry. The standard spectroscopic analysis based on 1D ATLAS models was completed by applying 3D and non-LTE corrections. results: An iron abundance of [Fe/H]=--4.89 makes SDSS J102915+172927 one of the lowest [Fe/H] stars known. However, the absence of measurable C and N enhancements indicates that it has the lowest metallicity, Z<= 7.40x10^{-7} (metal-mass fraction), ever detected. No oxygen measurement was possible. conclusions: The discovery of SDSS J102915+172927 highlights that low-mass star formation occurred at metallicities lower than previously assumed. Even lower metallicity stars may yet be discovered, with a chemical composition closer to the composition of the primordial gas and of the first supernovae., Comment: To be published in A&A

Context: Extremely metal-poor stars (EMP) are very rare objects that hold in their atmospheres the fossil record of the chemical composition of the early phases of Galactic evolution. Finding these objects and determining their chemical composition provides important constraints on these early phases. Aims: Using a carefully designed selection method, we chose a sample of candidate EMP stars from the low resolution spectra of the Sloan Digital Sky Survey and observed them with X-Shooter at the VLT to confirm their metallicities and determine abundances for as many elements as possible. Method: The X-Shooter spectra are analysed by means of one-dimensional, plane-parallel, hydrostatic model atmospheres. Corrections for the granulation effects are computed using CO5BOLD hydrodynamical simulations. Results: All the candidates are confirmed to be EMP stars, proving the efficiency of our selection method within about 0.5 dex. The chemical composition of this sample is compatible with those of brighter samples, suggesting that the stars in the Galactic halo are well mixed. Conclusions These observations show that it is feasible to observe, in a limited amount of time, a large sample of about one hundred stars among EMP candidates selected from the SDSS. Such a size of sample will allow us, in particular, to confirm or refute the existence of a vertical drop in the Galactic Halo metallicity distribution function around [Fe/H] ~ -3.5., Comment: To be published on A&A

Heavy element abundances in extremely metal-poor stars provide strong constraints on the processes of forming these elements in the first stars. We attempt to determine precise abundances of strontium in a homogeneous sample of extremely metal-poor stars. The abundances of strontium in 54 very or extremely metal-poor stars, was redetermined by abandoning the local thermodynamic equilibrium (LTE) hypothesis, and fitting non-LTE (NLTE) profiles to the observed spectral lines. The corrected Sr abundances and previously obtained NLTE Ba abundances are compared to the predictions of several hypothetical formation processes for the lighter neutron-capture elements. Our NLTE abundances confirm the previously determined huge scatter of the strontium abundance in low metallicity stars. This scatter is also found (and is even larger) at very low metallicities (i. e. early in the chemical evolution). The Sr abundance in the extremely metal-poor (EMP) stars is compatible with the main r-process involved in other processes (or by variations of the r-process), as we briefly discuss.

The chemical composition of extremely metal-poor stars (EMP stars; [Fe/H]<~ -3) is a unique tracer of early nucleosynthesis in the Galaxy. As such stars are rare, we wish to find classes of luminous stars which can be studied at high resolution. We aim to determine the detailed chemical composition of the two EMP stars CS30317-056 and CS22881-039, originally thought to be red horizontal-branch (RHB) stars, and compare it to earlier results for EMP stars as well as to nucleosynthesis yields from various supernova (SN) models. In the analysis, we discovered that our targets are in fact the two most metal-poor RR Lyrae stars known. Our detailed abundance analysis, taking into account the variability of the stars, is based on VLT/UVES spectra (R~ 43000) and 1D LTE OSMARCS model atmospheres and synthetic spectra. For comparison with SN models we also estimate NLTE corrections for a number of elements. We derive LTE abundances for the 16 elements O, Na, Mg, Al, Si, S, Ca, Sc, Ti, Cr, Mn, Fe, Co, Ni, Sr and Ba, in good agreement with earlier values for EMP dwarf, giant and RHB stars. Li and C are not detected in either star. NLTE abundance corrections are newly calculated for O and Mg and taken from the literature for other elements. The resulting abundance pattern is best matched by model yields for supernova explosions with high energy and/or significant asphericity effects. Our results indicate that, except for Li and C, the surface composition of EMP RR Lyr stars is not significantly affected by mass loss, mixing or diffusion processes; hence, EMP RR Lyr stars should also be useful tracers of the chemical evolution of the early Galactic halo. The observed abundance ratios indicate that these stars were born from an ISM polluted by energetic, massive (25 - 40M*) and/or aspherical supernovae, but the NLTE corrections for Sc and certain other elements do play a role in the choice of model., Comment: Pages: 11 (+ 6 online material), Figures: 14, Tables: 4 (+ 2 online material)

Sulfur is important: the site of its formation is uncertain, and at very low metallicity the trend of [S/Fe] against [Fe/H] is controversial. Below [Fe/H]=-2.0, [S/Fe] remains constant or it decreases with [Fe/H], depending on the author and the multiplet used in the analysis. Moreover, although sulfur is not significantly bound in dust grains in the ISM, it seems to behave differently in DLAs and in old metal-poor stars. We aim to determine precise S abundance in a sample of extremely metal-poor stars taking into account NLTE and 3D effects. NLTE profiles of the lines of the multiplet 1 of SI have been computed using a new model atom for S. We find sulfur in EMP stars to behave like the other alpha-elements, with [S/Fe] remaining approximately constant for [Fe/H]<-3. However, [S/Mg] seems to decrease slightly as a function of [Mg/H]. The overall abundance patterns of O, Na, Mg, Al, S, and K are best matched by the SN model yields by Heger & Woosley. The [S/Zn] ratio in EMP stars is solar, as found also in DLAs. We obtain an upper limit on the abundance of sulfur, [S/Fe] < +0.5, for the ultra metal-poor star CS 22949-037. This, along with a previous reported measurement of zinc, argues against the conjecture that the light-element abundances pattern in this star, and, by analogy, the hyper metal-poor stars HE 0107-5240 and HE 1327-2326, are due to dust depletion., Comment: 10 pages, accepted for publication in A&A

We present VLT-UVES Li abundances for 28 halo dwarf stars between [Fe/H]=-2.5 and -3.5, 10 of which have [Fe/H]<-3. Four different T_eff scales have been used. Direct Infrared Flux Method (IRFM) has been used on the basis of 2MASS infrared photometry. H_alpha wings have been fitted against synthetic grids computed by means of 1D LTE atmosphere models, assuming different self-broadening theories. Finally, a grid of H_alpha profiles has been computed by means of 3D hydrodynamical atmosphere models. The Li I doublet at 670.8 nm has been used to measure A(Li) by means of 3D hydrodynamical NLTE spectral syntheses. An analytical fit of A(Li)(3D, NLTE) as a function of equivalent width, T_eff, log g, and [Fe/H] has been derived and is made available. A(Li) does not exhibit a plateau below [Fe/H]=-3. A strong positive correlation with [Fe/H] appears, not influenced by the choice of the T_eff estimator. From a linear fit, we obtain a strong slope of about 0.30 dex in A(Li) per dex in [Fe/H], significant to 2-3 sigma, and consistent among all the four T_eff estimators. A significant slope is also detected in the A(Li)--T_eff plane, driven mainly by the coolest stars in the sample which appear Li-poor. Removing such stars does not alter the behavior in the A(Li)-[Fe/H] plane. The scatter in A(Li) increases by a factor of 2 towards lower metallicities, while the plateau appears very thin above [Fe/H]=-2.8. The meltdown of the Spite plateau below [Fe/H]\sim-3 is established, but its cause is unclear. If the primordial A(Li) is the one derived from WMAP, it appears difficult to envision a single depletion phenomenon producing a thin, metallicity independent plateau above [Fe/H]=-2.8, and a highly scattered, metallicity dependent distribution below. The fact that no star below [Fe/H]=-3 lies above the plateau suggests that they formed at plateau level and underwent subsequent depletion., Comment: 22 pages, 15 figures, accepted for publication in Astronomy and Astrophysics, replaced with version with final format for table 3, typos corrected in table 4 and in equation B.1

LTE abundances of light elements in extremely metal-poor (EMP) stars have been previously derived from high quality spectra. New derivations, free from the NLTE effects, will better constrain the models of the Galactic chemical evolution and the yields of the very first supernovae. The NLTE profiles of the magnesium and potassium lines have been computed in a sample of 53 extremely metal-poor stars with a modified version of the program MULTI and adjusted to the observed lines in order to derive the abundances of these elements. The NLTE corrections for magnesium and potassium are in good agreement with the works found in the literature. The abundances are slightly changed, reaching a better precision: the scatter around the mean of the abundance ratios has decreased. Magnesium may be used with confidence as reference element. Together with previously determined NLTE abundances of sodium and aluminum, the new ratios are displayed, for comparison, along the theoretical trends proposed by some models of the chemical evolution of the Galaxy, using different models of supernovae.

CONTEXT:The detailed chemical abundances of extremely metal-poor (EMP) stars are key guides to understanding the early chemical evolution of the Galaxy. Most existing data are, however, for giant stars which may have experienced internal mixing later. AIMS: We aim to compare the results for giants with new, accurate abundances for all observable elements in 18 EMP turnoff stars. METHODS:VLT/UVES spectra at R ~45,000 and S/N~ 130 per pixel (330-1000 nm) are analysed with OSMARCS model atmospheres and the TURBOSPECTRUM code to derive abundances for C, Mg, Si, Ca, Sc, Ti, Cr, Mn, Co, Ni, Zn, Sr, and Ba. RESULTS: For Ca, Ni, Sr, and Ba, we find excellent consistency with our earlier sample of EMP giants, at all metallicities. However, our abundances of C, Sc, Ti, Cr, Mn and Co are ~0.2 dex larger than in giants of similar metallicity. Mg and Si abundances are ~0.2 dex lower (the giant [Mg/Fe] values are slightly revised), while Zn is again ~0.4 dex higher than in giants of similar [Fe/H] (6 stars only). CONCLUSIONS:For C, the dwarf/giant discrepancy could possibly have an astrophysical cause, but for the other elements it must arise from shortcomings in the analysis. Approximate computations of granulation (3D) effects yield smaller corrections for giants than for dwarfs, but suggest that this is an unlikely explanation, except perhaps for C, Cr, and Mn. NLTE computations for Na and Al provide consistent abundances between dwarfs and giants, unlike the LTE results, and would be highly desirable for the other discrepant elements as well. Meanwhile, we recommend using the giant abundances as reference data for Galactic chemical evolution models., Comment: A&A, Received 16 July 2008/ Accepted 15 March 2009

Barium is a key element in constraining the evolution of the (not well understood) r-process in the first galactic stars and currently the Ba abundances in these very metal-poor stars were mostly measured under the Local Thermodynamical Equilibrium (LTE) assumption, which may lead in general to an underestimation of Ba. We present here determinations of the barium abundance taking into account the non-LTE (NLTE) effects in a sample of extremely metal-poor stars (EMP stars): 6 turnoff stars and 35 giants. The NLTE profiles of the three unblended Ba II lines (455.4, 585.3, 649.6nm) have been computed. The computations were made with a modified version of the MULTI code, applied to an atomic model of the Ba atom with 31 levels of Ba I, 101 levels of Ba II, and compared to the observations. The ratios of the NLTE abundances of barium relative to Fe are slightly shifted towards the solar ratio. In the plot of [Ba/Fe] versus [Fe/H], the slope of the regression line is slightly reduced as is the scatter. In the interval -3.3 <[Fe/H] < -2.6, [Ba/Fe] decreases with a slope of about 1.4 and a scatter close to 0.44. For [Fe/H] <-3.3 the number of stars is not sufficient to decide whether [Ba/Fe] keeps decreasing (and then CD-38:245 should be considered as a peculiar "barium-rich star") or if a plateau is reached as soon as [Ba/Fe] ~ -1. In both cases the scatter remains quite large, larger than what can be accounted for by the measurement and determination errors, suggesting the influence of a complex process of Ba production, and/or inefficient mixing in the early Galaxy., Comment: Accepted in A&A

Aims: Aluminium is a key element to constrain the models of the chemical enrichment and the yields of the first supernovae. But obtaining precise Al abundances in extremely metal-poor (EMP) stars requires that the non-LTE effects be carefully taken into account. Methods: The NLTE profiles of the blue resonance aluminium lines have been computed in a sample of 53 extremely metal-poor stars with a modified version of the program MULTI applied to an atomic model of the Al atom with 78 levels of Al I and 13 levels of Al II, and compared to the observations. Results: With these new determinations, all the stars of the sample show a ratio Al/Fe close to the solar value: [Al/Fe] =-0.06 +- 0.10 with a very small scatter. These results are compared to the models of the chemical evolution of the halo using different models of SN II and are compatible with recent computations. The sodium-rich giants are not found to be also aluminium-rich and thus, as expected, the convection in these giants only brings to the surface the products of the Ne-Na cycle., Comment: To be published on A&A

In ESO period 65 (April-September 2000) the large programme 165.N-0276, led by Roger Cayrel, began making use of UVES at the Kueyen VLT telescope. Known within the Team and outside as ``First Stars'', it was aimed at obtaining high resolution, high signal-to-noise ratio spectra in the range 320 nm -- 1000 nm for a large sample of extremely metal-poor (EMP) stars identified from the HK objective prism survey.In this contribution we highlight the main results of the large programme., Comment: to be published in the proceedings of the Workshop "Science with VLT in the ELT era" 8-12 October 2007, Garching, ed. A. Moorwood

We have used high-resolution, high-S/N ratio spectra from the UVES spectrograph at the ESO VLT telescope. Long-term radial-velocity measurements and broad-band photometry allow us to determine improved orbital elements and stellar parameters for both components. We use OSMARCS 1D models and the {{\scshape turbospectrum}} spectral synthesis code to determine the abundances of Li, O, Na, Mg, Al, Si, Ca, Sc, Ti, Cr, Mn, Fe, Co and Ni. We also use the CO$^5$BOLD model atmosphere code to compute the 3D abundance corrections, especially for Li and O. We find a metallicity of [Fe/H]$\sim -3.6$ for both stars, using 1D models with 3D corrections of $\sim -0.1$ dex from averaged 3D models. We determine the oxygen abundance from the near-UV OH bands; the 3D corrections are large, -1 and -1.5 dex for the secondary and primary respectively, and yield [O/Fe] $\sim 0.8$, close to the high-quality results obtained from the [OI] 630 nm line in metal-poor giants. Other [$\alpha$/Fe] ratios are consistent with those measured in other dwarfs and giants with similar [Fe/H], although Ca and Si are somewhat low ([X/Fe]$\la 0$). Other element ratios follow those of other halo stars. The Li abundance of the primary star is consistent with the Spite plateau, but the secondary shows a lower abundance; 3D corrections are small. The Li abundance in the primary star supports the extension of the {{\em Spite Plateau}} value at the lowest metallicities, without any decrease. The low abundance in the secondary star could be explained by endogenic Li depletion, due to its cooler temperature. If this is not the case, another, yet unknown mechanism may be causing increased scatter in A(Li) at the lowest metallicities., Comment: Accepted for publication in Astronomy & Astrophysics

Our aim is to measure accurate, homogeneous neutron-capture element abundances for the sample of 32 EMP giant stars studied earlier in this series, including 22 stars with [Fe/H] $< -$3.0. Based on high-resolution, high S/N spectra from the ESO VLT/UVES, 1D, LTE model atmospheres, and synthetic spectrum fits, we determine abundances or upper limits for the 16 elements Sr, Y, Zr, Ba, La, Ce, Pr, Nd, Sm, Eu, Gd, Dy, Ho, Er, Tm, and Yb in all stars. As found earlier, [Sr/Fe], [Y/Fe], [Zr/Fe] and [Ba/Fe] are below Solar in the EMP stars, with very large scatter. However, we find a tight anti-correlation of [Sr/Ba], [Y/Ba], and [Zr/Ba] with [Ba/H] for $-4.5 <$ [Ba/H] $< -2.5$, also when subtracting the contribution of the main $r$-process as measured by [Ba/H]. The huge, well-characterised scatter of the [n-capture/Fe] ratios in our EMP stars is in stark contrast to the negligible dispersion in the [$\alpha$/Fe] and [Fe-peak/Fe] ratios for the same stars found in Paper V. These results demonstrate that a second (``weak'' or LEPP) $r$-process dominates the production of the lighter neutron-capture elements for [Ba/H] $< -2.5$. The combination of very consistent [$\alpha$/Fe] and erratic [n-capture/Fe] ratios indicates that inhomogeneous models for the early evolution of the halo are needed. Our accurate data provide strong constraints on future models of the production and mixing of the heavy elements in the early Galaxy., Comment: 19 pages, 16 figures, A&A accepted

Abundance ratios in extremely metal-poor (EMP) stars are a good indication of the chemical composition of the gas in the earliest phases of the Galaxy evolution. It had been found from an LTE analysis that at low metallicity, and in contrast with most of the other elements, the scatter of [Na/Fe] versus [Fe/H] was surprisingly large and that, in giants, [Na/Fe] decreased with metallicity. Since it is well known that the formation of sodium lines is very sensitive to non-LTE effects, to firmly establish the behaviour of the sodium abundance in the early Galaxy, we have used high quality observations of a sample of EMP stars obtained with UVES at the VLT, and we have taken into account the non-LTE line formation of sodium. The profiles of the two resonant sodium D lines (only these sodium lines are detectable in the spectra of EMP stars) have been computed in a sample of 54 EMP giants and turn-off stars (33 of them with [Fe/H]< -3.0) with a modified version of the code MULTI, and compared to the observed spectra. With these new determinations in the range -4 <[Fe/H]< -2.5, both [Na/Fe] and [Na/Mg] are almost constant with a low scatter. In the turn-off stars and "unmixed" giants (located in the low RGB): [Na/Fe] = -0.21 +/- 0.13 or [Na/Mg] = -0.45 +/- 0.16. These values are in good agreement with the recent determinations of [Na/Fe] and [Na/Mg] in nearby metal-poor stars. Moreover we confirm that all the sodium-rich stars are "mixed" stars (i.e., giants located after the bump, which have undergone an extra mixing). None of the turn-off stars is sodium-rich. As a consequence it is probable that the sodium enhancement observed in some mixed giants is the result of a deep mixing., Comment: 8 pages, 9 figures; accepted for publication in A&A

Aims. This study aims to determine the level and constancy of the Spite plateau as definitively as possible from homogeneous high-quality VLT-UVES spectra of 19 of the most metal-poor dwarf stars known. Methods. Our high-resolution (R ~ 43000), high S/N spectra are analysed with OSMARCS 1D LTE model atmospheres and turbospectrum synthetic spectra to determine effective temperatures, surface gravities, and metallicities, as well as Li abundances for our stars. Results. Eliminating a cool subgiant and a spectroscopic binary, we find 8 stars to have -3.5 < [Fe/H] < -3.0 and 9 stars with -3.0 < [Fe/H] < -2.5. Our best value for the mean level of the plateau is A(Li) =2.10 +- 0.09. The scatter around the mean is entirely explained by our estimate of the observational error and does not allow for any intrinsic scatter in the Li abundances. In addition, we conclude that a systematic error of the order of 200 K in any of the current temperature scales remains possible. The iron excitation equilibria in our stars support our adopted temperature scale, which is based on a fit to wings of the Halpha line, and disfavour hotter scales, which would lead to a higher Li abundance, but fail to achieve excitation equilibrium for iron. Conclusions. We confirm the previously noted discrepancy between the Li abundance measured in extremely metal-poor turnoff stars and the primordial Li abundance predicted by standard Big-Bang nucleosynthesis models adopting the baryonic density inferred from WMAP. We discuss recent work explaining the discrepancy in terms of diffusion and find that uncertain temperature scales remain a major question. (abridged), Comment: Figure 3 replaced, it was wrong in version 1. Minor corrections to the text following indications of A&A Language Editor

From high-resolution VLT/UVES spectra (R~43,000), we determine abundances or upper limits for Li, C, N, O, and other important elements, as well as 12C/13C isotopic ratio for three Carbon enhanced metal poor stars. All three stars have -3.30 <= [Fe/H] <= -2.85 and moderate to high CNO abundances. CS 22958-042 is one of the most carbon-rich CEMP stars known ([C/Fe] = +3.2), while CS 29528-041 (one of the few N-enhanced metal-poor stars known) is one of the most nitrogen rich ([N/Fe] = +3.0). Oxygen is very high in CS 31080-095 ([O/Fe] = +2.35) and in CS 22958-042 ([O/Fe] = +1.35). All three stars exhibit [Sr/Fe] < 0; Ba is not detected in CS 22958-042 ([Ba/Fe] < -0.53), but it is moderately enhanced ([Ba/Fe] ~ 1) in the other two stars. CS 22958-042 displays one of the largest sodium overabundances yet found in CEMP stars ([Na/Fe] = +2.8). CS 22958-042 has 12C/13C = 9, similar to most other CEMP stars without enhanced neutron-capture elements, while 12C/13C <= 40 in CS 31080-095. CS 31080-095 and CS 29528-041 have A(Li) ~ 1.7, below the Spite Plateau, while Li is not detected in CS 22958-042. CS 22958-042 is a CEMP-no star, but the other two stars are in no known class of CEMP star and thus either constitute a new class or are a link between the CEMP-no and CEMP-s classes, adding complexity to the abundance patterns for CEMP stars. We interpret the abundance patterns in our stars to imply that current models for the presumed AGB binary progenitors lack an extra-mixing process, similar to those apparently operating in RGB stars., Comment: A&A accepted 08/07/2006

Extremely metal-poor (EMP) stars preserve a fossil record of the composition of the ISM when the Galaxy formed. It is crucial, however, to verify whether internal mixing has modified their surface. We aim to understand the CNO abundance variations found in some, but not all EMP field giants analysed earlier. Mixing beyond the first dredge-up of standard models is required, and its origin needs clarification.The 12C/13C ratio is the most robust diagnostic of deep mixing, because it is insensitive to the adopted stellar parameters and should be uniformly high in near-primordial gas. We have measured 12C and 13C abundances in 35 EMP giants from high-quality VLT/UVES spectra. Correlations with other abundance data are used to study the depth of mixing.The 12C/13C ratio is found to correlate with [C/Fe] (and Li/H), and clearly anti-correlate with [N/Fe]. Evidence for such deep mixing is observed in giants above log L/Lsolar = 2.6, brighter than in less metal-poor stars, but matching the bump in the luminosity function in both cases. Three of the mixed stars are also Na-and Al-rich, another signature of deep mixing, but signatures of the ON cycle are not clearly seen in these stars. Extra mixing processes clearly occur in luminous RGB stars. The Na-and Al-rich giants could be AGB stars themselves, but an inhomogeneous early ISM or pollution from a binary companion remain possible alternatives (abridged)., Comment: (1) GEPI, Observatoire de Paris-Meudon, (2) GRAAL, Univ. Montpellier II, (3) European Southern Observatory (ESO), (4) Osservatorio Astr. Trieste, INAF, (5) IAG, Univ. Sao Paulo, (6) Dept of Physics & Astronomy, CSCE, and JINA Michigan State Univ., (7) The Niels Bohr Institute, Astronomy, (8) Nordic Optical Telescope Scientific Association, (9) Lund Observatory, (10) European Southern Observatory. Accepted for publication in A&A

Li abundances for 9 Turnoff (TO) stars of the intermediate metallicity cluster ([Fe/H]=-1.4) NGC6752 are presented. The cluster is known to show abundance anomalies and anticorrelations observed in both evolved and main sequence stars. We find that Li abundance anticorrelates with Na (and N) and correlates with O in these Turn-Off stars. For the first time we observe Pop II hot dwarfs systematically departing from the Spite plateau. The observed anticorrelations are in qualitative agreement with what is expected if the original gas were contaminated by Intermediate Mass AGB - processed material. However, a quantitative comparison shows that none of the existing models can reproduce all the observations at once. The very large amount of processed gas present in the cluster does not imply a 'pollution', but rather that the whole protocluster cloud was enriched by a previous generation of stars. We finally note that the different abundance patterns in NGC 6397 and NGC 6752 imply different ejecta of the preenrichment composition for the two clusters., Comment: Accepted for publication on A&A

We have investigated the poorly-understood origin of nitrogen in the early Galaxy by determining N abundances in 35 extremely metal-poor halo giants (22 stars have [Fe/H]<-3.0) using the C and O abundances determined in Paper V. Because any dredge-up of CNO processed material to the surface may complicate the interpretation of CNO abundances in giants, we have also measured the surface abundance of lithium. Our sample shows a clear dichotomy between two groups of stars. The first group shows evidence of C to N conversion through CN cycling and strong Li dilution, a signature of mixing. The second group shows no evidence for C to N conversion, and Li is only moderately diluted, and we conclude that their C and N abundances are very close to those of the gas from which they formed in the early Galaxy. These "unmixed" stars reflect the abundances in the early Galaxy: the [C/Fe] ratio is constant (about +0.2 dex) and the [C/Mg] ratio is close to solar at low metallicity, favouring a high C production by massive zero-metal supernovae. The [N/Fe] and [N/Mg] ratios scatter widely. The larger values of these ratios define a flat upper plateau ([N/Mg]= 0.0, [N/Fe]= +0.1), which could reflect higher values within a wide range of yields of zero-metal Sne II. Alternatively, by analogy with the DLA's, the lower abundances ([N/Mg]= -1.1, [N/Fe]= -0.7) could reflect generally low yields from the first Sne II, the other stars being N enhanced by winds of massive Asymptotic Giant Branch (AGB) stars. At present it cannot be decided whether primary N is produced primarily in SNe II or in massive AGB stars, or in both. The stellar N abundances and [N/O] ratios are compatible with those found in Damped Lyman-alpha (DLA) systems., Comment: 15 pages,18 figures, difference of N abundance from NH and CN slightly reduced

We have carried out a new determination of abundances in the very metal-poor CH/CN strong stars CS 29497-34 and CS 22948-27, using high-resolution spectra obtained with the HARPS spectrograph at the 3.6m telescope of ESO, La Silla, that covers the range 400 - 690 nm at a resolution of R = 100,000. Both stars are found to be long period binaries. It is confirmed that the abundance patterns show an enhancement of all the alpha-elements (like Mg, Ca), of the proton capture elements (like Na and Al) and a strong enrichment in "r" and "s" process elements, where the s-enrichment is probably due to a mass transfer episode from a companion in its AGB phase. The possible origins of the abundance pattern and especially of the strong enhancement of both "s" and "r" elements are discussed., Comment: 12 pages, 11 Postscript figures, accepted for publication in A&A

High resolution (R > 40 000) and high S/N spectra have been acquired with UVES on the VLT-Kueyen (Paranal Observatory, ESO Chile) for several main sequence turnoff stars (V ~ 17 mag) and subgiants at the base of the Red Giant Branch (V ~ 16 mag) in three globular clusters (NGC 6397, NGC 6752 and 47 Tuc/NGC 104) at different metallicities (respectively [Fe/H] = -2.0; -1.5; -0.7$). Spectra for a sample of 25 field halo subdwarves have also been taken with equal resolution, but higher S/N. These data have been used to determine the abundances of several neutron-capture elements in these three clusters: strontium, yttrium, barium and europium. This is the first abundance determination of these heavy elements for such unevolved stars in these three globular clusters. These values, together with the [Ba/Eu] and [Sr/Ba] abundance ratios, have been used to test the self-enrichment scenario. A comparison is done with field halo stars and other well known Galactic globular clusters in which heavy elements have already been measured in the past, at least in bright giants (V > 11-12 mag). Our results show clearly that globular clusters have been uniformly enriched by r- and s-process syntheses, and that most of them seem to follow exactly the same abundance patterns as field halo stars, which discards the ``classical'' self-enrichment scenario for the origin of metallicities and heavy elements in globular clusters., Comment: 15 pages, 4 figures, to be published in A&A