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Context. Turbulence is a key component of molecular cloud structure. It is usually described by a cascade of energy down to the dissipation scale. The power spectrum for subsonic incompressible turbulence is $k^{-5/3}$, while for supersonic turbulence it is $k^{-2}$. Aims. We aim to determine the power spectrum in an actively star-forming molecular cloud, from parsec scales down to the expected magnetohydrodynamic (MHD) wave cutoff (dissipation scale). Methods. We analyze observations of the nearby NGC 1333 star-forming region in three different tracers to cover the different scales from $\sim$10 pc down to 20 mpc. The largest scales are covered with the low density gas tracer $^{13}$CO (1-0) obtained with single dish, the intermediate scales are covered with single-dish observations of the C$^{18}$O (3-2) line, while the smallest scales are covered in H$^{13}$CO$^+$ (1-0) and HNC (1-0) with a combination of NOEMA interferometer and IRAM 30m single dish observations. The complementarity of these observations enables us to generate a combined power spectrum covering more than two orders of magnitude in spatial scale. Results. We derive the power spectrum in an active star-forming region spanning more than 2 decades of spatial scales. The power spectrum of the intensity maps shows a single power-law behavior, with an exponent of 2.9$\pm$0.1 and no evidence of dissipation. Moreover, there is evidence for the power-spectrum of the ions to have more power at smaller scales than the neutrals, which is opposite from theoretical expectations. Conclusions. We show new possibilities of studying the dissipation of energy at small scales in star-forming regions provided by interferometric observations., Comment: 6 pages (+2 appendix), 5 figures. Accepted to A&A Letters. GitHub repo with code available at https://github.com/jpinedaf/NGC1333_NOEMA_turbulence

Submillimeter and millimeter wavelengths provide a unique view of the Universe, from the gas and dust that fills and surrounds galaxies to the chromosphere of our own Sun. Current single-dish facilities have presented a tantalising view of the brightest (sub-)mm sources, and interferometers have provided the exquisite resolution necessary to analyse the details in small fields, but there are still many open questions that cannot be answered with current facilities. In this report we summarise the science that is guiding the design of the Atacama Large Aperture Submillimeter Telescope (AtLAST). We demonstrate how tranformational advances in topics including star formation in high redshift galaxies, the diffuse circumgalactic medium, Galactic ecology, cometary compositions and solar flares motivate the need for a 50m, single-dish telescope with a 1-2 degree field of view and a new generation of highly multiplexed continuum and spectral cameras. AtLAST will have the resolution to drastically lower the confusion limit compared to current single-dish facilities, whilst also being able to rapidly map large areas of the sky and detect extended, diffuse structures. Its high sensitivity and large field of view will open up the field of submillimeter transient science by increasing the probability of serendipitous detections. Finally, the science cases listed here motivate the need for a highly flexible operations model capable of short observations of individual targets, large surveys, monitoring programmes, target of opportunity observations and coordinated observations with other observatories. AtLAST aims to be a sustainable, upgradeable, multipurpose facility that will deliver orders of magnitude increases in sensitivity and mapping speeds over current and planned submillimeter observatories., Comment: 47 pages, 12 figures. For further details on AtLAST see https://atlast.uio.no

The detection of narrow channels of accretion toward protostellar disks, known as streamers, have increased in number in the last few years. However, it is unclear if streamers are a common feature around protostars that were previously missed, or if they are a rare phenomenon. Our goals are to obtain the incidence of streamers toward a region of clustered star formation and to trace the origins of their gas, to determine if they originate within the filamentary structure of molecular clouds or from beyond. We used combined observations of the nearby NGC 1333 star-forming region, carried out with the NOEMA interferometer and the IRAM 30m single dish. Our observations cover the area between the IRAS 4 and SVS 13 systems. We traced the chemically fresh gas within NGC 1333 with HC3N molecular gas emission and the structure of the fibers in this region with N2H+ emission. We fit multiple velocity components in both maps and used clustering algorithms to recover velocity-coherent structures. We find streamer candidates toward 7 out of 16 young stellar objects within our field of view. This represents an incidence of approximately 40\% of young stellar objects with streamer candidates when looking at a clustered star forming region. The incidence increases to about 60\% when we considered only embedded protostars. All streamers are found in HC3N emission. Given the different velocities between HC3N and N2H+ emission, and the fact that, by construction, N2H+ traces the fiber structure, we suggest that the gas that forms the streamers comes from outside the fibers. This implies that streamers can connect cloud material that falls to the filaments with protostellar disk scales., Comment: 22 pages, 15 figures, accepted for publication in Astronomy and Astrophysics. GitHub repository with code available at https://github.com/tere-valdivia/propstar_gasflow

As we learn more about the multi-scale interstellar medium (ISM) of our Galaxy, we develop a greater understanding for the complex relationships between the large-scale diffuse gas and dust in Giant Molecular Clouds (GMCs), how it moves, how it is affected by the nearby massive stars, and which portions of those GMCs eventually collapse into star forming regions. The complex interactions of those gas, dust and stellar populations form what has come to be known as the ecology of our Galaxy. Because we are deeply embedded in the plane of our Galaxy, it takes up a significant fraction of the sky, with complex dust lanes scattered throughout the optically recognisable bands of the Milky Way. These bands become bright at (sub-)millimetre wavelengths, where we can study dust thermal emission and the chemical and kinematic signatures of the gas. To properly study such large-scale environments, requires deep, large area surveys that are not possible with current facilities. Moreover, where stars form, so too do planetary systems, growing from the dust and gas in circumstellar discs, to planets and planetesimal belts. Understanding the evolution of these belts requires deep imaging capable of studying belts around young stellar objects to Kuiper belt analogues around the nearest stars. Here we present a plan for observing the Galactic Plane and circumstellar environments to quantify the physical structure, the magnetic fields, the dynamics, chemistry, star formation, and planetary system evolution of the galaxy in which we live with AtLAST; a concept for a new, 50m single-dish sub-mm telescope with a large field of view which is the only type of facility that will allow us to observe our Galaxy deeply and widely enough to make a leap forward in our understanding of our local ecology., Comment: 27 pages, submitted to Open Research Europe as part of the AtLAST collection: https://open-research-europe.ec.europa.eu/collections/atlast/about

Electron fraction and cosmic-ray ionization rates (CRIR) in star-forming regions are important quantities in astrochemical modeling and are critical to the degree of coupling between neutrals, ions, and electrons, which regulates the dynamics of the magnetic field. However, these are difficult quantities to estimate. We aim to derive the electron fraction and CRIR maps of an active star-forming region. We combined observations of the nearby NGC 1333 star-forming region carried out with the NOEMA interferometer and IRAM 30-m single dish to generate high spatial dynamic range maps of different molecular transitions. We used the DCO$^+$ and H$^{13}$CO$^+$ ratio (in addition to complementary data) to estimate the electron fraction and produce cosmic-ray ionization rate maps. We derived the first large-area electron fraction and CRIR resolved maps in a star-forming region, with typical values of $10^{-6.5}$ and $10^{-16.5}$ s$^{-1}$, respectively. The maps present clear evidence of enhanced values around embedded young stellar objects (YSOs). This provides strong evidence for locally accelerated cosmic rays. We also found a strong enhancement toward the northwest region in the map that might be related either to an interaction with a bubble or to locally generated cosmic rays by YSOs. We used the typical electron fraction and derived a MHD turbulence dissipation scale of 0.054 pc, which could be tested with future observations. We found a higher cosmic-ray ionization rate compared to the canonical value for $N({\rm H_2})=10^{21}-10^{23}$ cm$^{-2}$ of $10^{-17}$ s$^{-1}$ in the region, and it is likely generated by the accreting YSOs. The high value of the electron fraction suggests that new disks will form from gas in the ideal-MHD limit. This indicates that local enhancements of $\zeta({\rm H_2})$, due to YSOs, should be taken into account in the analysis of clustered star formation., Comment: 13 pages, 13 Figures. Accepted to A&A. Abridged abstract. GitHub repo with code available at https://github.com/jpinedaf/NGC1333_NOEMA_Ions

W43-main is a massive molecular complex located at the interaction of the Scutum arm and the Galactic bar undergoing starburst activities. We aim to investigate the gas dynamics, in particular, the prevailing shock signatures from the cloud to clump scale and assess the impact of shocks on the formation of dense gas and early-stage cores. We have carried out NOEMA and IRAM-30m observations at 3 mm with an angular resolution of $\sim$0.1 pc towards five massive clumps in W43 main. We use CH$_{3}$CCH and H$_{2}$CS lines to trace the extended gas temperature and CH$_{3}$OH lines to probe the volume density of the dense gas ($\gtrsim$10$^{5}$ cm$^{-3}$). The emission of SiO (2-1) is extensive across the region ($\sim$4 pc) and is mostly contained within a low-velocity regime, hinting at a large-scale origin of the shocks. The position-velocity maps of multiple tracers show systematic spatio-kinematic offsets supporting the cloud-cloud collision/merging scenario. We identify an additional extended velocity component in CCH emission, which coincides with one of the velocity components of the larger scale $^{13}$CO (2-1) emission, likely representing an outer, less dense gas layer in the cloud merging process. We find that the V-shaped, asymmetric SiO wings are tightly correlated with localised gas density enhancements, which is direct evidence of dense gas formation and accumulation in shocks. We resolve two categories of NH$_{2}$D cores: ones exhibiting only subsonic to transonic velocity dispersion, and the others with an additional supersonic velocity dispersion. The centroid velocities of the latter cores are correlated with the shock front seen by SiO. The kinematics of the $\sim$0.1 pc NH$_{2}$D cores are heavily imprinted by shock activities, and may represent a population of early-stage cores forming around the shock interface., Comment: 35 pages, 34 figures (including appendices); Accepted in A&A

H2S is thought to be the main sulphur reservoir in the ice, being therefore a key molecule to understand sulphur chemistry in the star formation process and to solve the missing sulphur problem. The H2S deuterium fraction can be used to constrain its formation pathways. We investigate for the first time the H2S deuteration in a large sample of starless cores (SC). We use observations of the GEMS IRAM 30m Large Program and complementary IRAM 30m observations. We consider a sample of 19 SC in Taurus, Perseus, and Orion, detecting HDS in 10 and D2S in five. The H2S single and double deuterium fractions are analysed with regard to their relation with the cloud physical parameters, their comparison with other interstellar sources, and their comparison with deuterium fractions in early stage star-forming sources of c-C3H2, H2CS, H2O, H2CO, and CH3OH. We obtain a range of X(HDS)/X(H2S)~0.025-0.2 and X(D2S)/X(HDS)~0.05-0.3. H2S single deuteration shows an inverse relation with the cloud kinetic temperature. H2S deuteration values in SC are similar to those observed in Class 0. Comparison with other molecules in other sources reveals a general trend of decreasing deuteration with increasing temperature. In SC and Class 0 objects H2CS and H2CO present higher deuteration fractions than c-C3H2, H2S, H2O, and CH3OH. H2O shows single and double deuteration values one order of magnitude lower than those of H2S and CH3OH. Differences between c-C3H2, H2CS and H2CO deuterium fractions and those of H2S, H2O, and CH3OH are related to deuteration processes produced in gas or solid phases, respectively. We interpret the differences between H2S and CH3OH deuterations and that of H2O as a consequence of differences on the formation routes in the solid phase, particularly in terms of the different occurrence of the D-H and H-D substitution reactions in the ice, together with the chemical desorption processes., Comment: Accepted for publication in A&A

Pre-stellar cores represent a critical evolutionary phase in low-mass star formation. We aim to unveil the detailed thermal structure and density distribution of three early-stage cores, starless core L1517B, and prestellar core L694-2 and L429, with the high angular resolution observations of the NH$_{3}$ (1,1) and (2,2) inversion transitions obtained with VLA and GBT. In addition, we explore where/if NH$_{3}$ depletes in the central regions. Applying the mid-infrared extinction method to the $\textit{Spitzer}$ 8$~\mu$m map we obtain a high angular resolution hydrogen column density map, and derive the gas density profile to assess the variation of NH$_{3}$ abundance as a function of gas volume density. The measured temperature profiles of L429 and L1517B show a minor decrease towards the core center, dropping from $\sim$9\~K to below 8\~K, and $\sim$11 K to 10 K, while L694-2 has a rather uniform temperature distribution around $\sim$9 K. Among the three cores, L429 has the highest central gas density, close to sonic velocity line-width, and largest localised velocity gradient, all indicative of an advanced evolutionary stage. We resolve that the abundance of NH$_{3}$ becomes two times lower in the central region of L429, occurring around a gas density of 4.4$\times$10$^{4}$$~cm^{-3}$. Compared to Ophiuchus/H-MM1 which shows an even stronger drop of the NH$_{3}$ abundance at 2$\times$10$^{5}$$~cm^{-3}$, the abundance variations of the three cores plus Ophiuchus/H-MM1 suggest a progressive NH$_{3}$ depletion with increasing central density of the core., Comment: 23 pages, 23 figures incl. appendix; A&A accepted

We report a comprehensive study of the cyanopolyyne chemistry in the prototypical prestellar core L1544. Using the 100m Robert C. Byrd Green Bank Telescope (GBT) we observe 3 emission lines of HC$_3$N, 9 lines of HC$_5$N, 5 lines of HC$_7$N, and 9 lines of HC$_9$N. HC$_9$N is detected for the first time towards the source. The high spectral resolution ($\sim$ 0.05 km s$^{-1}$) reveals double-peak spectral line profiles with the redshifted peak a factor 3-5 brighter. Resolved maps of the core in other molecular tracers indicates that the southern region is redshifted. Therefore, the bulk of the cyanopolyyne emission is likely associated with the southern region of the core, where free carbon atoms are available to form long chains, thanks to the more efficient illumination of the interstellar field radiation. We perform a simultaneous modelling of the HC$_5$N, HC$_7$N, and HC$_9$N lines, to investigate the origin of the emission. To enable this analysis, we performed new calculation of the collisional coefficients. The simultaneous fitting indicates a gas kinetic temperature of 5--12 K, a source size of 80$\arcsec$, and a gas density larger than 100 cm$^{-3}$. The HC$_5$N:HC$_7$N:HC$_9$N abundance ratios measured in L1544 are about 1:6:4. We compare our observations with those towards the the well-studied starless core TMC-1 and with the available measurements in different star-forming regions. The comparison suggests that a complex carbon chain chemistry is active in other sources and it is related to the presence of free gaseous carbon. Finally, we discuss the possible formation and destruction routes in the light of the new observations., Comment: 16 pages, 7 figure, 3 tables

The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation of methanol, CH$_{3}$OH, towards two starless and two pre-stellar cores. We derive a D/H ratio of 0.8-1.9$\%$ with CH$_{2}$DOH in pre-stellar cores H-MM1 and L694-2, consistent with measurements in more evolved Class 0/I objects and comet 67P/Churyumov-Gerasimenko, suggesting a direct chemical link arising in the pre-stellar stage. Furthermore, the column density ratios of CHD$_{2}$OH/CH$_{2}$DOH are $\sim$50-80$\%$, consistently high as that towards Class 0/I objects, indicating an efficient formation mechanism of CHD$_{2}$OH, possibly through H atom additions to D$_{2}$CO. The CH$_{2}$DOH/CH$_{3}$OH and CHD$_{2}$OH/CH$_{3}$OH column density ratios in the two pre-stellar cores are larger than that in the two starless cores B68 and L1521E, representing an evolutionary trend of methanol deuteration in early-stage cores., Comment: accepted by A&A letter

Recent observations of the pre-stellar core L1544 and the younger starless core L1498 have revealed that complex organic molecules (COMs) are enhanced in the gas phase toward their outer and intermediate-density shells. Our goal is to determine the level of chemical complexity toward the starless core L1517B, which seems younger than L1498, and compare it with the other two previously studied cores to see if there is a chemical evolution within the cores. We have carried out 3 mm high-sensitivity observations toward two positions in the L1517B starless core: the core's centre and the position where the methanol emission peaks (at a distance of $\sim$5000 au from the core's centre). Our observations reveal that a lower number of COMs and COM precursors are detected in L1517B with respect to L1498 and L1544, and also show lower abundances. Besides methanol, we only detected CH$_3$O, H$_2$CCO, CH$_3$CHO, CH$_3$CN, CH$_3$NC, HCCCN, and HCCNC. Their measured abundances are $\sim$3 times larger toward the methanol peak than toward the core's centre, mimicking the behaviour found toward the more evolved cores L1544 and L1498. We propose that the differences in the chemical complexity observed between the three studied starless cores are a consequence of their evolution, with L1517B being the less evolved one, followed by L1498 and L1544. Chemical complexity in these cores seems to increase over time, with N-bearing molecules forming first and O-bearing COMs forming at a later stage as a result of the catastrophic depletion of CO., Comment: 18 pages, 13 figures

Isotopologue abundance ratios are important to understand the evolution of astrophysical objects and ultimately the origins of a planetary system like our own. Being nitrogen a fundamental ingredient of pre-biotic material, understanding its chemistry and inheritance is of fundamental importance to understand the formation of the building blocks of life. We present here single-dish observations of the ground state rotational transitions of the $^{13}$C and $^{15}$N isotopologues of HCN, HNC and CN with the IRAM 30m telescope. We analyse their column densities and compute the $^{14}$N/$^{15}$N ratio map for HCN. The $^{15}$N-fractionation of CN and HNC is computed towards different offsets across L1544. The $^{15}$N-fractionation map of HCN shows a clear decrease of the $^{14}$N/$^{15}$N ratio towards the southern edge of L1544, where carbon chain molecules present a peak, strongly suggesting that isotope-selective photodissociation has a strong effect on the fractionation of nitrogen across pre-stellar cores. The $^{14}$N/$^{15}$N ratio in CN measured towards four positions across the core also shows a decrease towards the South-East of the core, while HNC shows opposite behaviour. The uneven illumination of the pre-stellar core L1544 provides clear evidence that $^{15}$N-fractionation of HCN and CN is enhanced toward the region more exposed to the interstellar radiation field. Isotope-selective photodissociation of N$_2$ is then a crucial process to understand $^{15}$N fractionation, as already found in protoplanetary disks. Therefore, the $^{15}$N-fractionation in pre-stellar material is expected to change depending on the environment within which pre-stellar cores are embedded. The $^{12}$CN/$^{13}$CN ratio also varies across the core, but its variation does not affect our conclusions on the effect of the environment on the fractionation of nitrogen., Comment: Accepted for publication in A&A Letters

Pre-stellar cores are the basic unit for the formation of stars and stellar systems. The anatomy of the physical and chemical structures of pre-stellar cores is critical for understanding the star formation process. L1544 is a prototypical pre-stellar core, which shows significant chemical differentiation surrounding the dust peak. We aim to constrain the physical conditions at the different molecular emission peaks. This study allows us to compare the abundance profiles predicted from chemical models together with the classical density structure of Bonnor-Ebert (BE) sphere. We conducted multi-transition pointed observations of CH$_{3}$OH, c-C$_{3}$H$_{2}$ and HNCO with the IRAM 30m telescope, towards the dust peak and the respective molecular peaks of L1544. With non-LTE radiative transfer calculations and a 1-dimensional model, we revisit the physical structure of L1544, and benchmark with the abundance profiles from current chemical models. We find that the HNCO, c-C$_{3}$H$_{2}$ and CH$_{3}$OH lines in L1544 are tracing progressively higher density gas, from $\sim$10$^{4}$ to several times 10$^{5}$ cm$^{-3}$. Particularly, we find that to produce the observed intensities and ratios of the CH$_{3}$OH lines, a local gas density enhancement upon the BE sphere is required. This suggests that the physical structure of an early-stage core may not necessarily follow a smooth decrease of gas density profile locally, but can be intercepted by clumpy substructures surrounding the gravitational center. Multiple transitions of molecular lines from different molecular species can provide a tomographic view of the density structure of pre-stellar cores. The local gas density enhancement deviating from the BE sphere may reflect the impact of accretion flows that appear asymmetric and are enhanced at the meeting point of large-scale cloud structures., Comment: accepted by A&A; 22 pages, 22 figures incl. appendices

Pre-stellar cores represent the initial conditions in the process of star and planet formation. Their low temperatures ($<$10 K) allow the formation of thick icy dust mantles, which will be partially preserved in the future protoplanetary disks, ultimately affecting the chemical composition of planetary systems. Previous observations have shown that carbon- and oxygen-bearing species, in particular CO, are heavily depleted in pre-stellar cores due to the efficient molecular freeze-out onto the surface of cold dust grains. However, N-bearing species such as NH$_3$ and, in particular, its deuterated isotopologues, appear to maintain high abundances where CO molecules are mainly in solid phase. Thanks to ALMA, we present here the first clear observational evidence of NH$_2$D freeze-out toward the L1544 pre-stellar core, suggestive of the presence of a"complete-depletion zone" within a $\simeq$1800 au radius, in agreement with astrochemical pre-stellar core model predictions. Our state-of-the-art chemical model coupled with a non-LTE radiative transfer code demonstrates that NH$_2$D becomes mainly incorporated in icy mantles in the central 2000 au and starts freezing-out already at $\simeq$7000 au. Radiative transfer effects within the pre-stellar core cause the NH$_2$D(1$_{11}$-1$_{01}$) emission to appear centrally concentrated, with a flattened distribution within the central $\simeq$3000 au, unlike the 1.3 mm dust continuum emission which shows a clear peak within the central $\simeq$1800 au. This prevented NH$_2$D freeze-out to be detected in previous observations, where the central 1000 au cannot be spatially resolved., Comment: accepted for publication in The Astrophysical Journal

Chemical models predict that in cold cores gas-phase methanol is expected to be abundant at the outer edge of the CO depletion zone, where CO is actively adsorbed. CO adsorption correlates with volume density in cold cores, and, in nearby molecular clouds, the catastrophic CO freeze-out happens at volume densities above 10$^4$ cm$^{-3}$. The methanol production rate is maximized there and its freeze-out rate does not overcome its production rate, while the molecules are shielded from UV destruction by gas and dust. Thus, in cold cores, methanol abundance should generally correlate with visual extinction that depends both on volume and column density. In this work, we test the most basic model prediction that maximum methanol abundance is associated with a local $A_V\simeq$4 mag in dense cores and constrain the model parameters with the observational data. With the IRAM 30 m antenna, we mapped the CH$_3$OH (2-1) and (3-2) transitions toward seven dense cores in the L1495 filament in Taurus to measure the methanol abundance. We use the Herschel/SPIRE maps to estimate visual extinction, and the C$^{18}$O(2-1) maps from Tafalla & Hacar (2015) to estimate CO depletion. We explored the observed and modeled correlations between the methanol abundances, CO depletion, and visual extinction varying the key model parameters. The modeling results show that hydrogen surface diffusion via tunneling is crucial to reproduce the observed methanol abundances, and the needed reactive desorption efficiency matches the one deduced from laboratory experiments., Comment: Accepted for publication in ApJ

Observations carried out toward starless and pre-stellar cores have revealed that complex organic molecules are prevalent in these objects, but it is unclear what chemical processes are involved in their formation. Recently, it has been shown that complex organics are preferentially produced at an intermediate-density shell within the L1544 pre-stellar core at radial distances of ~4000 au with respect to the core center. However, the spatial distribution of complex organics has only been inferred toward this core and it remains unknown whether these species present a similar behaviour in other cores. We report high-sensitivity observations carried out toward two positions in the L1498 pre-stellar core, the dust peak and a position located at a distance of ~11000 au from the center of the core where the emission of CH$_3$OH peaks. Similarly to L1544, our observations reveal that small O-bearing molecules and N-bearing species are enhanced by factors ~4-14 toward the outer shell of L1498. However, unlike L1544, large O-bearing organics such as CH3CHO, CH3OCH3 or CH3OCHO are not detected within our sensitivity limits. For N-bearing organics, these species are more abundant toward the outer shell of the L1498 pre-stellar core than toward the one in L1544. We propose that the differences observed between O-bearing and N-bearing species in L1498 and L1544 are due to the different physical structure of these cores, which in turn is a consequence of their evolutionary stage, with L1498 being younger than L1544., Comment: Accepted for Astrophysical Journal

Context. The deuterium fraction in low-mass prestellar cores is a good diagnostic indicator of the initial phases of star formations, and it is also a fundamental quantity to infer the ionisation degree in these objects. Aims. With the analysis of multiple transitions of $\rm N_2H^+$, $\rm N_2D^+$, $\rm HC^{18}O^+$ and $\rm DCO^+$ we are able to determine the molecular column density maps and the deuterium fraction in $\rm N_2H^+$ and $\rm HCO^+$ toward the prototypical prestellar core L1544. This is the preliminary step to derive the ionisation degree in the source. Methods. We use a non-local thermodynamic equilibrium (non-LTE) radiative transfer code, combined with the molecular abundances derived from a chemical model, to infer the excitation conditions of all the observed transitions, which allows us to derive reliable maps of each molecule's column density. The ratio between the column density of a deuterated species and its non-deuterated counterpart gives the searched deuteration level. Results. The non-LTE analysis confirms that, for the analysed molecules, higher-J transitions are characterised by excitation temperatures $\approx 1-2\,$K lower than the lower-J ones. The chemical model that provides the best fit to the observational data predict the depletion of $\rm N_2H^+$ and to a lesser extent of $\rm N_2D^+$ in the innermost region. The peak values for the deuterium fraction that we find are $\mathrm{D/H_{N_2H^+}} = 0.26^{+0.15}_{-0.14}$ and $\mathrm{D/H_{HCO^+}} = 0.035^{+0.015}_{-0.012}$, in good agreement with previous estimates in the source., Comment: Accepted for publication on A&A on 18/7/19

We present ALMA maps of the starless molecular cloud core Ophiuchus/H-MM1 in the lines of deuterated ammonia (ortho-NH2D), methanol (CH3OH), and sulphur monoxide (SO). The dense core is seen in NH2D emission, whereas the CH3OH and SO distributions form a halo surrounding the core. Because methanol is formed on grain surfaces, its emission highlights regions where desorption from grains is particularly efficient. Methanol and sulphur monoxide are most abundant in a narrow zone that follows the eastern side of the core. This side is sheltered from the stronger external radiation field coming from the west. We show that photodissociation on the illuminated side can give rise to an asymmetric methanol distribution, but that the stark contrast observed in H-MM1 is hard to explain without assuming enhanced desorption on the shaded side. The region of the brightest emission has a wavy structure that rolls up at one end. This is the signature of Kelvin-Helmholtz instability occurring in sheared flows. We suggest that in this zone, methanol and sulphur are released as a result of grain-grain collisions induced by shear vorticity., Comment: Accepted for publication in the Astrophysical Journal

Protonated molecular species have been proven to be abundant in the interstellar gas. This class of molecules is also pivotal for the determination of important physical parameters for the ISM evolution (e.g. gas ionisation fraction) or as tracers of non-polar, hence not directly observable, species. The identification of these molecular species through radioastronomical observations is directly linked to a precise laboratory spectral characterisation. The goal of the present work is to extend the laboratory measurements of the pure rotational spectrum of the ground electronic state of protonated carbonyl sulfide (HSCO$^+$) and its deuterium substituted isotopomer (DSCO$^+$). At the same time, we show how implementing different laboratory techniques allows the determination of different spectroscopical properties of asymmetric-top protonated species. Three different high-resolution experiments were involved to detected for the first time the $b-$type rotational spectrum of HSCO$^+$, and to extend, well into the sub-millimeter region, the $a-$type spectrum of the same molecular species and DSCO$^+$. The electronic ground-state of both ions have been investigated in the 273-405 GHz frequency range, allowing the detection of 60 and 50 new rotational transitions for HSCO$^+$ and DSCO$^+$, respectively. The combination of our new measurements with the three rotational transitions previously observed in the microwave region permits the rest frequencies of the astronomically most relevant transitions to be predicted to better than 100 kHz for both HSCO$^+$ and DSCO$^+$ up to 500 GHz, equivalent to better than 60 m/s in terms of equivalent radial velocity. The present work illustrates the importance of using different laboratory techniques to spectroscopically characterise a protonated species at high frequency, and how a similar approach can be adopted when dealing with reactive species., Comment: 7 pages, 4 figures. Accepted for publication in Astronomy and Astrophysics

Towards the pre-stellar core L1544, the methanol (CH$_3$OH) emission forms an asymmetric ring around the core centre, where CH$_3$OH is mostly in solid form, with a clear peak 4000~au to the north-east of the dust continuum peak. As part of the NOEMA Large Project SOLIS (Seeds of Life in Space), the CH$_3$OH peak has been spatially resolved to study its kinematics and physical structure and to investigate the cause behind the local enhancement. We find that methanol emission is distributed in a ridge parallel to the main axis of the dense core. The centroid velocity increases by about 0.2~km~s$^{-1}$ and the velocity dispersion increases from subsonic to transonic towards the central zone of the core, where the velocity field also shows complex structure. This could be indication of gentle accretion of material onto the core or interaction of two filaments, producing a slow shock. We measure the rotational temperature and show that methanol is in local thermodynamic equilibrium (LTE) only close to the dust peak, where it is significantly depleted. The CH$_3$OH column density, $N_{tot}({\rm CH_3OH})$, profile has been derived with non-LTE radiative transfer modelling and compared with chemical models of a static core. The measured $N_{tot}({\rm CH_3OH})$ profile is consistent with model predictions, but the total column densities are one order of magnitude lower than those predicted by models, suggesting that the efficiency of reactive desorption or atomic hydrogen tunnelling adopted in the model may be overestimated; or that an evolutionary model is needed to better reproduce methanol abundance., Comment: 19 pages, 18 figures. Accepted by ApJ

HOCO$^+$ is a polar molecule that represents a useful proxy for its parent molecule CO$_2$, which is not directly observable in the cold interstellar medium. This cation has been detected towards several lines of sight, including massive star forming regions, protostars, and cold cores. Despite the obvious astrochemical relevance, protonated CO$_2$ and its deuterated variant, DOCO$^+$, still lack an accurate spectroscopic characterisation. The aim of this work is to extend the study of the ground-state pure rotational spectra of HOCO$^+$ and DOCO$^+$ well into the sub-millimetre region. Ground-state transitions have been recorded in the laboratory using a frequency-modulation absorption spectrometer equipped with a free-space glow-discharge cell. The ions were produced in a low-density, magnetically-confined plasma generated in a suitable gas mixture. The ground-state spectra of HOCO$^+$ and DOCO$^+$ have been investigated in the 213-967 GHz frequency range, with the detection of 94 new rotational transitions. Additionally, 46 line positions taken from the literature have been accurately remeasured. The newly-measured lines have significantly enlarged the available data sets for HOCO$^+$ and DOCO$^+$, thus enabling the determination of highly accurate rotational and centrifugal distortion parameters. Our analysis showed that all HOCO$^+$ lines with Ka $\geq$ 3 are perturbed by a ro-vibrational interaction that couples the ground state with the v$_ 5$ = 1 vibrationally-excited state. This resonance has been explicitly treated in the analysis in order to obtain molecular constants with clear physical meaning. The improved sets of spectroscopic parameters provide enhanced lists of very accurate, sub-millimetre rest-frequencies of HOCO$^+$ and DOCO$^+$ for astrophysical applications. These new data challenges a recent tentative identification of DOCO$^+$ toward a pre-stellar core., Comment: 7 pages, 1 figure, accepted for publication in A&A

The rotational spectra of thioisocyanic acid (HNCS), and its three energetic isomers (HSCN, HCNS, and HSNC) have been observed at high spectral resolution by a combination of chirped-pulse and Fabry-P\'{e}rot Fourier-transform microwave spectroscopy between 6 and 40~GHz in a pulsed-jet discharge expansion. Two isomers, thiofulminic acid (HCNS) and isothiofulminic acid (HSNC), calculated here to be 35-37~kcal/mol less stable than the ground state isomer HNCS, have been detected for the first time. Precise rotational, centrifugal distortion, and nitrogen hyperfine coupling constants have been determined for the normal and rare isotopic species of both molecules; all are in good agreement with theoretical predictions obtained at the coupled cluster level of theory. On the basis of isotopic spectroscopy, precise molecular structures have been derived for all four isomers by correcting experimental rotational constants for the effects of rotation-vibration calculated theoretically. Formation and isomerization pathways have also been investigated; the high abundance of HSCN relative to ground state HNCS, and the detection of strong lines of SH using CH$_3$CN and H$_2$S, suggest that HSCN is preferentially produced by the radical-radical reaction HS + CN. A radio astronomical search for HSCN and its isomers has been undertaken toward the high-mass star-forming region Sgr B2(N) in the Galactic Center with the 100 m Green Bank Telescope. While we find clear evidence for HSCN, only a tentative detection of HNCS is proposed, and there is no indication of HCNS or HSNC at the same rms noise level. HSCN, and tentatively HNCS, displays clear deviations from a single-excitation temperature model, suggesting weak masing may be occurring in some transitions in this source., Comment: Accepted in Physical Chemistry Chemical Physics

Dense cloud cores present chemical differentiation due to the different distribution of C-bearing and N-bearing molecules, the latter being less affected by freeze-out onto dust grains. In this letter we show that two C-bearing molecules, CH$_3$OH and $c$-C$_3$H$_2$, present a strikingly different (complementary) morphology while showing the same kinematics toward the prestellar core L1544. After comparing their distribution with large scale H$_2$ column density N(H$_2$) map from the Herschel satellite, we find that these two molecules trace different environmental conditions in the surrounding of L1544: the $c$-C$_3$H$_2$ distribution peaks close to the southern part of the core, where the surrounding molecular cloud has a N(H$_2$) sharp edge, while CH$_3$OH mainly traces the northern part of the core, where N(H$_2$) presents a shallower tail. We conclude that this is evidence of chemical differentiation driven by different amount of illumination from the interstellar radiation field: in the South, photochemistry maintains more C atoms in the gas phase allowing carbon chain (such as $c$-C$_3$H$_2$) production; in the North, C is mainly locked in CO and methanol traces the zone where CO starts to freeze out significantly. During the process of cloud contraction, different gas and ice compositions are thus expected to mix toward the central regions of the core, where a potential Solar-type system will form. An alternative view on carbon-chain chemistry in star-forming regions is also provided., Comment: Accepted for publication in A&A Letters

Using the IRAM 30m telescope, we mapped the methanol emission in the pre-stellar core L1544 and observed singly deuterated methanol (CH$_2$DOH and CH$_3$OD) towards the dust peak of L1544. Non-LTE radiative transfer modelling was performed on three CH$_3$OH emissions lines at 96.7 GHz, using a Bonnor-Ebert sphere as a model for the source. We have also assumed a centrally decreasing abundance profile to take the molecule freeze-out in the inner core into account. The column density of CH$_2$DOH was derived assuming LTE excitation and optically thin emission. The CH$_3$OH emission has a highly asymmetric morphology, resembling a non-uniform ring surrounding the dust peak, where CO is mainly frozen onto dust grains. The observations provide an accurate measure of methanol deuteration in the cold pre-stellar gas. The derived abundance ratio is [CH$_2$DOH]/[CH$_3$OH] $= 0.10\pm 0.03$, which is significantly smaller than the ones found in low-mass Class 0 protostars and smaller than the deuterium Fraction measured in other molecules towards L1544. The low deuterium fractionation observed in L1544 and the morphology of the CH$_3$OH emission suggest that we are mainly tracing the outer parts of the core, where CO just started to freeze-out onto dust grains., Comment: 8 pages, 9 figures. Accepted in A&A

The rotational spectrum of the higher-energy trans conformational isomer of methyl formate has been assigned for the first time using several pulsed-jet Fourier transform microwave spectrometers in the 6-60 GHz frequency range. This species has also been sought toward the Sagittarius B2(N) molecular cloud using the publicly available PRIMOS survey from the Green Bank Telescope. We detect seven absorption features in the survey that coincide with laboratory transitions of trans-methyl formate, from which we derive a column density of 3.1 (+2.6, -1.2) \times 10^13 cm-2 and a rotational temperature of 7.6 \pm 1.5 K. This excitation temperature is significantly lower than that of the more stable cis conformer in the same source but is consistent with that of other complex molecular species recently detected in Sgr B2(N). The difference in the rotational temperatures of the two conformers suggests that they have different spatial distributions in this source. As the abundance of trans-methyl formate is far higher than would be expected if the cis and trans conformers are in thermodynamic equilibrium, processes that could preferentially form trans-methyl formate in this region are discussed. We also discuss measurements that could be performed to make this detection more certain. This manuscript demonstrates how publicly available broadband radio astronomical surveys of chemically rich molecular clouds can be used in conjunction with laboratory rotational spectroscopy to search for new molecules in the interstellar medium., Comment: 40 pages, 7 figures, 4 tables; accepted for publication in ApJ