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Combining Deep-UV second harmonic generation spectroscopy with molecular simulations, we confirm and quantify the specific adsorption of guanidinium cations to the air-water interface. Using a Langmuir analysis and measurements at multiple concentrations, we extract the Gibbs free energy of adsorption, finding it larger than typical thermal energies. Molecular simulations clarify the role of polarizability in tuning the thermodynamics of adsorption, and establish the preferential parallel alignment of guanidinium at the air-water interface. Guanidinium is the first polyatomic cation proven to exhibit a propensity for the air-water interface. As such, these results expand on the growing body of work on specific ion adsorption., Comment: 9 pages, 4 figures. Supporting information included at the end of main text

We present spot properties on 32 periodic young stellar objects in IC 5070. Long term, $\sim$5 yr, light curves in the $V$, $R$, and $I$-bands are obtained through the HOYS (Hunting Outbursting Young Stars) citizen science project. These are dissected into six months long slices, with 3 months oversampling, to measure 234 sets of amplitudes in all filters. We fit 180 of these with reliable spot solutions. Two thirds of spot solutions are cold spots, the lowest is 2150 K below the stellar temperature. One third are warm spots that are above the stellar temperature by less than $\sim$2000 K. Cold and warm spots have maximum surface coverage values of 40 percent, although only 16 percent of warm spots are above 20 percent surface coverage as opposed to 60 percent of the cold spots. Warm spots are most likely caused by a combination of plages and low density accretion columns, most common on objects without inner disc excess emission in $K-W2$. Five small hot spot solutions have $<3$ percent coverage and are 3000 - 5000 K above the stellar temperature. These are attributed to accretion, and four of them occur on the same object. The majority of our objects are likely to be accreting. However, we observe very few accretion hot spots as either the accretion is not stable on our timescale or the photometry is dominated by other features. We do not identify cyclical spot behaviour on the targets. We additionally identify and discuss a number of objects that have interesting amplitudes, phase changes, or spot properties., Comment: Accepted for publication by MNRAS. 17 + 7 pages, 7 + 23 figures, 1 table

The Hunting Outbursting Young Stars (HOYS) project performs long-term, optical, multi-filter, high cadence monitoring of 25 nearby young clusters and star forming regions. Utilising Gaia DR3 data we have identified about 17000 potential young stellar members in 45 coherent astrometric groups in these fields. Twenty one of them are clear young groups or clusters of stars within one kiloparsec and they contain 9143 Gaia selected potential members. The cluster distances, proper motions and membership numbers are determined. We analyse long term (about 7yr) V, R, and I-band light curves from HOYS for 1687 of the potential cluster members. One quarter of the stars are variable in all three optical filters, and two thirds of these have light curves that are symmetric around the mean. Light curves affected by obscuration from circumstellar materials are more common than those affected by accretion bursts, by a factor of 2-4. The variability fraction in the clusters ranges from 10 to almost 100 percent, and correlates positively with the fraction of stars with detectable inner disks, indicating that a lot of variability is driven by the disk. About one in six variables shows detectable periodicity, mostly caused by magnetic spots. Two thirds of the periodic variables with disk excess emission are slow rotators, and amongst the stars without disk excess two thirds are fast rotators - in agreement with rotation being slowed down by the presence of a disk., Comment: accepted for publication in MNRAS, 1 table, 9 figures

Lightcurves of many classical novae deviate from the canonical "fast rise - smooth decline" pattern and display complex variability behavior. We present the first TESS-space-photometry-based investigation of this phenomenon. We use TESS Sector 41 full-frame images to extract a lightcurve of the slow Galactic nova V606 Vul that erupted nine days prior to the start of the TESS observations. The lightcurve covers the first of two major peaks of V606 Vul that was reached 19 days after the start of the eruption. The nova reached its brightest visual magnitude V=9.9 in its second peak 64 days after the eruption onset, following the completion of Sector 41 observations. To increase the confidence level of the extracted lightcurve, we performed the analysis using four different codes implementing the aperture photometry (Lightkurve, VaST) and image subtraction (TESSreduce, tequila_shots) and find good agreement between them. We performed ground-based photometric and spectroscopic monitoring to complement the TESS data. The TESS lightcurve reveals two features: periodic variations (0.12771d, 0.01mag average peak-to-peak amplitude) that disappeared when the source was within 1mag of peak optical brightness and a series of isolated mini-flares (with peak-to-peak amplitudes of up to 0.5mag) appearing at seemingly random times. We interpret the periodic variations as the result of azimuthal asymmetry of the photosphere engulfing the nova-hosting binary that was distorted by and rotating with the binary. Whereas we use spectra to associate the two major peaks in the nova lightcurve with distinct episodes of mass ejection, the origin of mini-flares remains elusive., Comment: 31 pages, 10 figures, submitted to ApJ; comments welcome

Photovoltaics (PVs) are a critical technology for curbing growing levels of anthropogenic greenhouse gas emissions, and meeting increases in future demand for low-carbon electricity. In order to fulfil ambitions for net-zero carbon dioxide equivalent (CO2eq) emissions worldwide, the global cumulative capacity of solar PVs must increase by an order of magnitude from 0.9 TWp in 2021 to 8.5 TWp by 2050 according to the International Renewable Energy Agency, which is considered to be a highly conservative estimate. In 2020, the Henry Royce Institute brought together the UK PV community to discuss the critical technological and infrastructure challenges that need to be overcome to address the vast challenges in accelerating PV deployment. Herein, we examine the key developments in the global community, especially the progress made in the field since this earlier roadmap, bringing together experts primarily from the UK across the breadth of the photovoltaics community. The focus is both on the challenges in improving the efficiency, stability and levelized cost of electricity of current technologies for utility-scale PVs, as well as the fundamental questions in novel technologies that can have a significant impact on emerging markets, such as indoor PVs, space PVs, and agrivoltaics. We discuss challenges in advanced metrology and computational tools, as well as the growing synergies between PVs and solar fuels, and offer a perspective on the environmental sustainability of the PV industry. Through this roadmap, we emphasize promising pathways forward in both the short- and long-term, and for communities working on technologies across a range of maturity levels to learn from each other., Comment: 160 pages, 21 figures

This paper is one in a series reporting results from small telescope observations of variable young stars. Here, we study the repeating outbursts of three likely Be stars based on long-term optical, near-infrared, and mid-infrared photometry for all three objects, along with follow-up spectra for two of the three. The sources are characterised as rare, truly regularly outbursting Be stars. We interpret the photometric data within a framework for modelling light curve morphology, and find that the models correctly predict the burst shapes, including their larger amplitudes and later peaks towards longer wavelengths. We are thus able to infer the start and end times of mass loading into the circumstellar disks of these stars. The disk sizes are typically 3-6 times the areas of the central star. The disk temperatures are ~40%, and the disk luminosities are ~10% of those of the central Be star, respectively. The available spectroscopy is consistent with inside-out evolution of the disk. Higher excitation lines have larger velocity widths in their double-horned shaped emission profiles. Our observations and analysis support the decretion disk model for outbursting Be stars., Comment: Accepted for publication by MNRAS. 20 pages, 11 figures, 2 tables

The post-common envelope binary V471 Tauri has been an object of interest for decades. V471 Tau shows various phenomena due to its evolutionary state and unique properties, e.g. its magnetic accretion and eclipse timing variation (ETV). Previous authors explained the ETVs by different, sometimes contradictory theories. In this paper, we present and analyse the variability of the eclipse timing of this star. We observed V471 Tauri over the last ten years and covered the second cycle of its period variation. Based on our analysis of the presented data, we assess the possible existence of a brown dwarf in this system and derive its orbital parameters. We compare the results of our dynamical modelling to the solution predicted by Applegate-mechanism theories, which have been developed in recent studies. We found that the observed ETV cannot be explained only by the presence of additional components to the binary., Comment: 10 pages, 4 figures, to be published in MNRAS

The fluctuation-dissipation theorem describes the intimate connection between the Brownian diffusion of thermal particles and their drag coefficients. In the simple case of spherical particles, it takes the form of the Stokes-Einstein relationship that links the particle geometry, fluid viscosity, and diffusive behavior. However, studying the fundamental properties of microscopic asymmetric particles, such as the helical-shaped propeller used by $\textit{E. coli}$, has remained out of reach for experimental approaches due to the need to quantify correlated translation and rotation simultaneously with sufficient spatial and temporal resolution. To solve this outstanding problem, we generated volumetric movies of fluorophore-labeled, freely diffusing, isolated $\textit{E. Coli}$ flagella using oblique plane microscopy. From these movies, we extracted trajectories and determined the hydrodynamic propulsion matrix directly from the diffusion of flagella via a generalized Einstein relation. Our results validate prior proposals, based on macroscopic wire helices and low Reynolds number scaling laws, that the average flagellum is a highly inefficient propeller. Specifically, we found the maximum propulsion efficiency of flagella is less than 5%. Beyond extending Brownian motion analysis to asymmetric 3D particles, our approach opens new avenues to study the propulsion matrix of particles in complex environments where direct hydrodynamic approaches are not feasible., Comment: 6 pages, 4 figures, 9 supplemental sections, 7 supplemental figures, 3 supplemental movies *authors contributed equally and reserve the right to change order for first authorship

The development and the use of quantum technologies are hindered by a fundamental challenge: Quantum materials exhibit macroscopic quantum properties at extremely low temperatures due to the loss of quantum coherence at elevated temperatures. Here, based on our recent discovery of room temperature superfluorescence in perovskites, we present the Quantum Analog of Vibration Isolation, 'QAVI', model and explain how it protects the quantum phase against dephasing at high temperatures. We then postulate the requirements for observation of macroscopic quantum phenomena at practical temperatures and propose a unified model for all macroscopic quantum phase transitions. We further present the general features of the temperature and density phase diagram of macroscopic quantum phase transitions that are mediated by the QAVI process and identify the similarities observed in the phase diagram of high Tc superconductors. Understanding this fundamental quantum coherence protection mechanism is imperative to accelerate the discovery of high temperature macroscopic quantum phenomena, and offers significant potential for developing quantum technologies functioning under practical conditions., Comment: 21 pages, 4 figures

Studying rotational variability of young stars is enabling us to investigate a multitude of properties of young star-disk systems. We utilise high cadence, multi-wavelength optical time series data from the Hunting Outbursting Young Stars citizen science project to identify periodic variables in the Pelican Nebula (IC5070). A double blind study using nine different period-finding algorithms was conducted and a sample of 59 periodic variables was identified. We find that a combination of four period finding algorithms can achieve a completeness of 85% and a contamination of 30% in identifying periods in inhomogeneous data sets. The best performing methods are periodograms that rely on fitting a sine curve. Utilising GaiaEDR3 data, we have identified an unbiased sample of 40 periodic YSOs, without using any colour or magnitude selections. With a 98.9% probability we can exclude a homogeneous YSO period distribution. Instead we find a bi-modal distribution with peaks at three and eight days. The sample has a disk fraction of 50%, and its statistical properties are in agreement with other similarly aged YSOs populations. In particular, we confirm that the presence of the disk is linked to predominantly slow rotation and find a probability of 4.8$\times$10$^{-3}$ that the observed relation between period and presence of a disk has occurred by chance. In our sample of periodic variables, we also find pulsating giants, an eclipsing binary, and potential YSOs in the foreground of IC5070., Comment: 25 pages, 14 figures, 5 tables, accepted for publication in MNRAS

As radar sensors are being miniaturized, there is a growing interest for using them in indoor sensing applications such as indoor drone obstacle avoidance. In those novel scenarios, radars must perform well in dense scenes with a large number of neighboring scatterers. Central to radar performance is the detection algorithm used to separate targets from the background noise and clutter. Traditionally, most radar systems use conventional CFAR detectors but their performance degrades in indoor scenarios with many reflectors. Inspired by the advances in non-linear target detection, we propose a novel high-performance, yet low-complexity target detector and we experimentally validate our algorithm on a dataset acquired using a radar mounted on a drone. We experimentally show that our proposed algorithm drastically outperforms OS-CFAR (standard detector used in automotive systems) for our specific task of indoor drone navigation with more than 19% higher probability of detection for a given probability of false alarm. We also benchmark our proposed detector against a number of recently proposed multi-target CFAR detectors and show an improvement of 16% in probability of detection compared to CHA-CFAR, with even larger improvements compared to both OR-CFAR and TS-LNCFAR in our particular indoor scenario. To the best of our knowledge, this work improves the state of the art for high-performance yet low-complexity radar detection in critical indoor sensing applications.

K2 observations of the weak-lined T Tauri binary V928 Tau A+B show the detection of a single, asymmetric eclipse which may be due to a previously unknown substellar companion eclipsing one component of the binary with an orbital period $>$ 66 days. Over an interval of about 9 hours, one component of the binary dims by around 60%, returning to its normal brightness about 5 hours later. From modeling of the eclipse shape we find evidence that the eclipsing companion may be surrounded by a disk or a vast ring system. The modeled disk has a radius of $0.9923\,\pm\,0.0005\,R_*$, with an inclination of $56.78\,\pm\, 0.03^\circ$, a tilt of $41.22\,\pm\,0.05^\circ$, an impact parameter of $-0.2506\,\pm\,0.0002\,R_*$ and an opacity of 1.00. The occulting disk must also move at a transverse velocity of $6.637\,\pm\,0.002\,R_*\,\mathrm{day}^{-1}$, which depending on whether it orbits V928 Tau A or B, corresponds to approximately 73.53 or 69.26 $\mathrm{km s}^{-1}$. A search in ground based archival data reveals additional dimming events, some of which suggest periodicity, but no unambiguous period associated with the eclipse observed by K2. We present a new epoch of astrometry which is used to further refine the orbit of the binary, presenting a new lower bound of 67 years, and constraints on the possible orbital periods of the eclipsing companion. The binary is also separated by 18" ($\sim$2250 au) from the lower mass CFHT-BD-Tau 7, which is likely associated with V928 Tau A+B. We also present new high dispersion optical spectroscopy that we use to characterize the unresolved stellar binary., Comment: 30 pages, 9 tables, 10 figures, accepted for publication in ApJ, GitHub repository for scripts and figures on https://github.com/dmvandam/v928tau