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Beamline I22 at Diamond Light Source is dedicated to the study of soft matter systems from both biological and materials science. The beamline can operate in the range 3.7 keV to 22 keV for transmission SAXS and 14 keV to 20 keV for microfocus SAXS with beamsizes 240 x 60 {\mu}m$^{2}$ spot [Full width half maximum (FWHM) Horizontal (H) x Vertical (V)] at sample for the main beamline, and approximately 10 x 10 {\mu}m$^{2}$ for the dedicated microfocussing platform. There is a versatile sample platform for accommodating a range of facility, and user developed, sample environments. The high brilliance of the insertion device source on I22 allows structural investigation of materials under extreme environments (for example fluid flow at high pressures and temperatures). I22 provides reliable access to millisecond timescales, essential to understanding kinetic processes such as early folding events in proteins or structural evolution in polymers and colloids., Comment: Preprint. 27 pages, 5 figures. Supplementary Info. 8 pages, 7 figures

Echelle spectra of HD 183143 [B7Iae, E(B-V) = 1.27] were obtained on three nights, at a resolving power R = 38,000 and with a signal-to-noise ratio ~1000 at 6400 A in the final, combined spectrum. A catalog is presented of 414 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in this spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. Among the 414 bands, 135 (or 33%) were not reported in four previous, modern surveys of the DIBs in the spectra of various stars, including HD 183143. The principal result of this study is that the great majority of the bands in the catalog are very weak and fairly narrow. Typical equivalent widths amount to a few mA, and the bandwidths (FWHM) are most often near 0.7 A. No preferred wavenumber spacings among the 414 bands are identified which could provide clues to the identities of the large molecules thought to cause the DIBs. At generally comparable detection limits in both spectra, the population of DIBs observed toward HD 183143 is systematically redder, broader, and stronger than that seen toward HD 204827 (Paper II). In addition, interstellar lines of C2 molecules have not been detected toward HD 183143, while a very high value of N(C2)/E(B-V) is observed toward HD 204827. Therefore, either the abundances of the large molecules presumed to give rise to the DIBs, or the physical conditions in the absorbing clouds, or both, must differ significantly between the two cases., Comment: Additional data and figures available at http://dibdata.org. To appear as Astrophysical Journal, 705, 32-45 (Nov. 1, 2009)

The abundances of gas and dust (solids and complex molecules) in the interstellar medium (ISM) as well as their composition and structures impact practically all of astrophysics. Fundamental processes from star formation to stellar winds to galaxy formation all scale with the number of metals. However, significant uncertainties remain in both absolute and relative abundances, as well as how these vary with environment, e.g., stellar photospheres versus the interstellar medium (ISM). While UV, optical, IR, and radio studies have considerably advanced our understanding of ISM gas and dust, they cannot provide uniform results over the entire range of column densities needed. In contrast, X-rays will penetrate gas and dust in the cold (3K) to hot (100,000,000K) Universe over a wide range of column densities (log NH=20-24 cm^-2), imprinting spectral signatures that reflect the individual atoms which make up the gas, molecule or solid. *X-rays therefore are a powerful and viable resource for delving into a relatively unexplored regime for determining gas abundances and dust properties such as composition, charge state, structure, and quantity via absorption studies, and distribution via scattering halos.*, Comment: 8 pages, 6 figures. White paper submitted to the Astro2010 Decadal survey for Astronomy and Astrophysics

Echelle spectra of the double-lined spectroscopic binary HD 204827 were obtained on five nights, at a resolving power R = 38,000 and with a S/N ratio = 750 near 6000 A in the final, combined spectrum. The stars show E(B-V) = 1.11 and spectral types near O9.5V and B0.5III. A catalog is presented of 380 diffuse interstellar bands (DIBs) measured between 3900 and 8100 A in the stars' spectrum. The central wavelengths, the widths (FWHM), and the equivalent widths of nearly all of the bands are tabulated, along with the minimum uncertainties in the latter. The reliable removal of very weak stellar lines from the catalog, and of some stellar lines from the less severe blends with DIBs, is made generally easy by the highly variable radial velocities of both stars. The principal result of this investigation is that the great majority of the bands in the catalog are very weak and relatively narrow. Typical equivalent widths amount to a few mA, and the band widths (FWHM) are most often near 0.55 A. Therefore, most of these DIBs can be detected only in spectra obtained at a resolving power and a S/N ratio at least comparable to those used here. In addition, the anomalous interstellar reddening and the very high value of the ratio N(C2)/E(B-V) seen toward HD 204827 indicate that the physical conditions in one or more of the several interstellar clouds seen in this direction differ significantly from those found toward the prototypical DIB target HD 183143, for example. Probably primarily for these reasons, 113 of the 380 bands, or 30%, were not detected in four previous, modern surveys of the DIBs seen in the spectra of stars other than HD 204827. Both the tabulated data for the DIBs and a plot of our spectrum of HD 204827 are available online at http://dibdata.org, Comment: 85 pages (17 of text, 14 of tables, 54 of figures). To appear in the Astrophysical Journal

Are the organic molecules crucial for life on Earth abundant in early-epoch galaxies? To address this, we searched for organic molecules in extragalactic sources via their absorption features, known as diffuse interstellar bands (DIBs). There is strong evidence that DIBs are associated with polycyclic aromatic hydrocarbons (PAHs) and carbon chains. Galaxies with a preponderance of DIBs may be the most likely places in which to expect life. We use the method of quasar absorption lines to probe intervening early-epoch galaxies for the DIBs. We present the equivalent width measurements of DIBs in one neutral hydrogen (HI) abundant galaxy and limits for five DIB bands in six other HI-rich galaxies (damped Lyman-alpha systems--DLAs). Our results reveal that HI-rich galaxies are dust poor and have significantly lower reddening than known DIB-rich Milky Way environments. We find that DIBs in HI-rich galaxies do not show the same correlation with hydrogen abundance as observed in the Milky Way; the extragalactic DIBs are underabundant by as much as 10 times. The lower limit gas-to-dust ratios of four of the HI-rich early epoch galaxies are much higher than the gas-to-dust ratios found in the Milky Way. Our results suggest that the organic molecules responsible for the DIBs are underabundant in HI-rich early epoch galaxies relative to the Milky Way., Comment: 6 pages, 2 figures

The composite grain is made up of a host silicate spheroid and graphite inclusions. The extinction efficiencies of the composite spheroidal grains for three axial ratios are computed using the discrete dipole approximation (DDA). The interstellar extinction curve is evaluated in the spectral region 3.40--0.10$\mu m$ using the extinction efficiencies of the composite spheroidal grains. The model extinction curves are then compared with the average observed interstellar extinction curve. We also calculate the linear polarization for the spheroidal composite grains at three orientation angles and find the wavelength of maximum polarization. Further, we estimate the volume extinction factor, an important parameter from the point of view of cosmic abundance, for the composite grain models that reproduce the average observed interstellar extinction. The estimated abundances derived from the composite grain models for both carbon and silicon are found to be lower than that are predicted by the bare silicate/graphite grain models but these values are still higher than that are implied from the recent ISM values., Comment: 11 pages, 12 figures, 5 tables To appear in 2007 MNRAS

We present extinction curves that include data down to far ultraviolet wavelengths (FUV; 1050 - 1200 A) for nine Galactic sight lines. The FUV extinction was measured using data from the Far Ultraviolet Spectroscopic Explorer. The sight lines were chosen for their unusual extinction properties in the infrared through the ultraviolet; that they probe a wide range of dust environments is evidenced by the large spread in their measured ratios of total-to-selective extinction, R_V = 2.43 - 3.81. We find that extrapolation of the Fitzpatrick & Massa relationship from the ultraviolet appears to be a good predictor of the FUV extinction behavior. We find that predictions of the FUV extinction based upon the Cardelli, Clayton & Mathis (CCM) dependence on R_V give mixed results. For the seven extinction curves well represented by CCM in the infrared through ultraviolet, the FUV extinction is well predicted in three sight lines, over-predicted in two sight lines, and under-predicted in 2 sight lines. A Maximum Entropy Method analysis using a simple three component grain model shows that seven of the nine sight lines in the study require a larger fraction of grain materials to be in dust when FUV extinction is included in the models. Most of the added grain material is in the form of small (radii < 200 A) grains., Comment: Accepted for publication in the Astrophysical Journal. 31 pages with 7 figures

We have obtained new STIS/HST spectra to search for structure in the ultraviolet interstellar extinction curve, with particular emphasis on a search for absorption features produced by polycyclic aromatic hydrocarbons (PAHs). The presence of these molecules in the interstellar medium has been postulated to explain the infrared emission features seen in the 3-13 $\mu$m spectra of numerous sources. UV spectra are uniquely capable of identifying specific PAH molecules. We obtained high S/N UV spectra of stars which are significantly more reddened than those observed in previous studies. These data put limits on the role of small (30-50 carbon atoms) PAHs in UV extinction and call for further observations to probe the role of larger PAHs. PAHs are of importance because of their ubiquity and high abundance inferred from the infrared data and also because they may link the molecular and dust phases of the interstellar medium. A presence or absence of ultraviolet absorption bands due to PAHs could be a definitive test of this hypothesis. We should be able to detect a 20 \AA wide feature down to a 3$\sigma$ limit of $\sim$0.02 A$_V$. No such absorption features are seen other than the well-known 2175 \AA bump., Comment: 16 pages, 3 figure, ApJ in press

We present a study of the abundances and physical conditions in the interstellar gas toward the heavily reddened star HD 192639 [E_(B-V) = 0.64], based on analysis of FUSE and HST/STIS spectra covering the range from 912 to 1361 A. This work constitutes a survey of the analyses that can be performed to study the interstellar gas when combining data from different instruments. Low-velocity (-18 to -8 km/s) components are seen primarily for various neutral and singly ionized species such as C I, O I, S I, Mg II, Cl I, Cl II, Mn II, Fe II and Cu II. Numerous lines of H2 are present in the FUSE spectra, with a kinetic temperature for the lowest rotational levels T_(01) = (90 +/- 10) K. Analysis of the C I fine-structure excitation implies an average local density of hydrogen n_H = (16 +/- 3) cm^-3. The average electron density, derived from five neutral/first ion pairs under the assumption of photoionization equilibrium, is n_e = (0.11 +/- 0.02) cm^-3. The relatively complex component structure seen in high-resolution spectra of K I and Na I, the relatively low average density, and the measured depletions all suggest that the line of sight contains a number of diffuse clouds, rather than a single dense, translucent cloud. Comparisons of the fractions of Cl in Cl I and of hydrogen in molecular form suggest a higher molecular fraction, in the region(s) where H2 is present, than that derived considering the average line of sight. In general, such comparisons may allow the identification and characterization of translucent portions of such complex lines of sight. The combined data also show high-velocity components near -80 km/s for various species which appear to be predominantly ionized, and may be due to a radiative shock. A brief overview of the conditions in this gas will be given., Comment: 37 pages, accepted for publication in ApJ

Space Telescope Imaging Spectrograph (STIS) and archival International Ultraviolet Explorer (IUE) data were used to search for structure in the ultraviolet interstellar extinction curve. Between 1250 and 3200 A, in addition to the well-known 2175 A bump, there is only one fairly small (10%) absorption feature at 2700 A. The feature is very broad (>400 A). It coincides extremely well in position and shape with laboratory measurements of presolar diamond grains found in meteorites. As this feature appears in both the new STIS and archival IUE data, it is unlikely to be an instrumental effect. This feature appears to be ubiquitous in the ISM as it is seen along sightlines toward various clouds with reddenings in the range of E(B-V) = 0.35 to 1.73 mag. The identification with diamonds remains tentative since it is based on a single, weak feature. If the feature is due to interstellar diamonds then they require an order of magnitude more absorption strength per gram/cm^2 than the presolar meteoritic diamonds measured in the lab., Comment: Paper withdrawn after reanalysis of data. Paper no longer available for download

As part of an extensive survey of diffuse interstellar bands (DIBs), we have obtained optical spectra of the moderately reddened B5V star HD 62542, which is known to have an unusual UV extinction curve of the type usually identified with dark clouds. The typically strongest of the commonly catalogued DIBs covered by the spectra -- those at 5780, 5797, 6270, 6284, and 6614 A -- are essentially absent in this line of sight, in marked contrast with other lines of sight of similar reddening. We compare the HD 62542 line of sight with others exhibiting a range of extinction properties and molecular abundances and interpret the weakness of the DIBs as an extreme case of deficient DIB formation in a dense cloud whose more diffuse outer layers have been stripped away. We comment on the challenges these observations pose for identifying the carriers of the diffuse bands., Comment: 20 pages, 4 figures; aastex; accepted by ApJ

The Lyman and Werner band systems of deuterated molecular hydrogen (HD) occur in the far UV range below 1200 A. The high sensitivity of the FUSE mission can give access, at moderate resolution, to hot stars shining through translucent clouds, in the hope of observing molecular cores in which deuterium is essentially in the form of HD. Thus, the measurement of the HD/H2 ratio may become a new powerful tool to evaluate the deuterium abundance, D/H, in the interstellar medium. We report here on the detection of HD toward the high extinction star HD 73882 [E(B-V)=0.72]. A preliminary analysis is presented., Comment: 4 pages + 4 .ps figures. This paper will appear in a special issue of Astrophysical Journal Letters devoted to the first scientific results from the FUSE mission

We present Far Ultraviolet Explorer (FUSE) spectra for three Magellanic Cloud O stars (Sk 80, Sk -67 05 and Sk -67 111) with repeated observations. The data demonstrate the capabilities of FUSE to perform time-resolved spectroscopy on extragalactic stars. The wavelength coverage of FUSE provides access to resonance lines due to less abundant species, such as sulfur, which are unsaturated in O supergiants. This allows us to examine wind variability at all velocities in resonance lines for stars with higher mass loss rates than can be studied at longer (lambda > 1150 A) wavelengths. The FUSE wavelength range also includes resonance lines from ions which bracket the expected dominant ionization stage of the wind. Our observations span 1-4 months with several densely sampled intervals of 10 hours or more. These observations reveal wind variability in all of the program stars and distinctive differences in the ionization structure and time scales of the variability. Sk -67 111 demonstrates significant wind variability on a time scale less than 10 hours and the coolest O star (Sk -67 05) exhibits the largest variations in O VI., Comment: 3 pages of text and 3 JPG figures. To be included in the FUSE ApJ Letters special issue

We report the results of initial FUSE observations of molecular hydrogen (H2) in translucent clouds. These clouds have greater optical depth than any of the diffuse clouds previously observed for far-UV H2 absorption, and provide new insights into the physics and chemistry of such regions. Our initial results involve observations of HD 73882, a well-studied southern hemisphere star lying behind substantial interstellar material (E(B-V) = 0.72; A_V = 2.44). We find a total H2 column density, N(H2) = 1.2 x 10^{21} cm^{-2}, about three times larger than the values for diffuse clouds previously measured in the far-UV. The gas kinetic temperature indicated by the ratio N(J=1)/N(J=0) is 58 +/- 10 K. With the aid of ground-based data to calculate an appropriate multi-component curve of growth, we have determined column densities for all rotational levels up to J = 7. The J >= 2 states can be reasonably fitted with a rotational excitation temperature of 307 +/- 23 K. Both the kinetic and rotational temperatures are similar to those found in previous investigations of diffuse clouds. The ratios of carbonaceous molecules to hydrogen molecules are also similar to ratios in diffuse clouds, suggesting a similar chemistry for this line of sight., Comment: 7 pages, 3 figures, to appear in ApJ Letters (FUSE first-results issue)

We compare the stellar wind features in far-UV spectra of Sk -67 111, an O7 Ib(f) star in the LMC, with Sk 80, an O7 Iaf+ star in the SMC. The most striking differences are that Sk 80 has a substantially lower terminal velocity, much weaker O VI absorption, and stronger S IV emission. We have used line-blanketed, hydrodynamic, non-LTE atmospheric models to explore the origin of these differences. The far-UV spectra require systematically lower stellar temperatures than previous determinations for O7 supergiants derived from plane-parallel, hydrostatic models of photospheric line profiles. At these temperatures, the O VI in Sk -67 111 must be due primarily to shocks in the wind., Comment: 10 pages, 2 figures. AASTeX preprint format. This paper will appear in a special issue of Astrophysical Journal Letters devoted to the first scientific results from the FUSE mission

We describe a moderate-resolution FUSE mini-survey of H2 in the Milky Way and Magellanic Clouds, using four hot stars and four AGN as background sources. FUSE spectra of nearly every stellar and extragalactic source exhibit numerous absorption lines from the H2 Lyman and Werner bands between 912 and 1120 A. One extragalactic sightline, PKS 2155-304, with low N(HI) shows no detectable H2 and could be the "Lockman Hole" of molecular gas, of importance for QSO absorption-line studies. We measure H2 column densities in low rotational states (J = 0 and 1) to derive rotational and/or kinetic temperatures of diffuse interstellar gas. The higher-J abundances can constrain models of the UV radiation fields and gas densities. In three optically thick clouds toward extragalactic sources, we find n(H) ~ 30-50 cm(-3) and cloud thicknesses of 2-3 pc. The rotational temperatures for H2 at high Galactic latitude, = 107 +/- 17 K (seven sightlines) and 120 +/- 13 K (three optically thick clouds), are higher than those in the Copernicus sample composed primarily of targets in the disk. We find no evidence for great differences in the abundance or state of excitation of H2 between sight lines in the Galaxy and those in the SMC and LMC. In the future, we will probe the distribution and physical parameters of diffuse molecular gas in the disk and halo and in the lower-metallicity environs of the LMC and SMC., Comment: To appear in ApJL (FUSE first-results issue), 4 pages + 2 figures (.ps)

The H II region W40 harbors a small group of young, hot stars behind roughly 9 magnitudes of visual extinction. We have detected gaseous carbon monoxide (CO) and diatomic carbon (C_2) in absorption toward the star W40 IRS 1a. The 2-0 R0, R1, and R2 lines of 12CO at 2.3 micron were measured using the CSHELL on the NASA IR Telescope Facility (with upper limits placed on R3, R4, and R5) yielding an N_CO of (1.1 +/- 0.2) x 10^18 cm^-2. Excitation analysis indicates T_kin > 7 K. The Phillips system of C_2 transitions near 8775 Ang. was measured using the Kitt Peak 4-m telescope and echelle spectrometer. Radiative pumping models indicate a total C_2 column density of (7.0 +/- 0.4) x 10^14 cm^-2, two excitation temperatures (39 and 126 K), and a total gas density of n ~ 250 cm^-3. The CO ice band at 4.7 micron was not detected, placing an upper limit on the CO depletion of delta < 1 %. We postulate that the sightline has multiple translucent components and is associated with the W40 molecular cloud. Our data for W40 IRS 1a, coupled with other sightlines, shows that the ratio of CO/C_2 increases from diffuse through translucent environs. Finally, we show that the hydrogen to dust ratio seems to remain constant from diffuse to dense environments, while the CO to dust ratio apparently does not., Comment: To appear in The Astrophysical Journal 17 pages total, 5 figures Also available at http://casa.colorado.edu/~shuping/research/w40/w40.html

Due to recent interest in molecular anions as possible interstellar species, we have carried out several laboratory studies of anion chemistry. The reactions of the series C(sub n)(sup -); and C(sub n)H(sup -) with H and H2 were studied to address the viability of such species in the diffuse interstellar medium and to address their ability to be carriers of the diffuse interstellar bands (DIBs). These same molecules were also reacted with N and O to show possible heteroatomic products. C(sub m)N(sup - was a particularly stable product from the reaction of C(sub n)(sup -) + N. C3N(sup -) was further reacted with H to study chemistry that could produce HC3N, a known interstellar species. The reactions were done in a flowing afterglow selected ion flow tube apparatus (FA-SIFT). The anions were generated in an electron impact or cold cathode discharge source and the anion of interest was then selected by a quadrupole mass filter. The selected ion was then reacted with the atomic or molecular species in the flow tube and products were detected by another quadrupole. While the C(sub n)(sup -) species do not appear to be viable DIB carriers, their possible presence could provide a mechanism for the formation of known heteroatomic neutral molecules detected in the interstellar medium (ISM).

Infrared spectral properties of silicate grains in interplanetary dust particles (IDPs) were compared with those of astronomical silicates. The approximately 10-micrometer silicon-oxygen stretch bands of IDPs containing enstatite (MgSiO3), forsterite (Mg2SiO4), and glass with embedded metal and sulfides (GEMS) exhibit fine structure and bandwidths similar to those of solar system comets and some pre-main sequence Herbig Ae/Be stars. Some GEMS exhibit a broad, featureless silicon-oxygen stretch band similar to those observed in interstellar molecular clouds and young stellar objects. These GEMS provide a spectral match to astronomical "amorphous" silicates, one of the fundamental building blocks from which the solar system is presumed to have formed.