3,889 results on '"Smith, Alex"'
Search Results
2. Removal of Chromium and Arsenic from Water Using Polyol-Functionalized Porous Aromatic Frameworks
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Uliana, Adam A, Pezoulas, Ethan R, Zakaria, N Isaac, Johnson, Arun S, Smith, Alex, Lu, Yubing, Shaidu, Yusuf, Velasquez, Ever O, Jackson, Megan N, Blum, Monika, Neaton, Jeffrey B, Yano, Junko, and Long, Jeffrey R
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Engineering ,Chemical Sciences ,General Chemistry ,Chemical sciences - Abstract
Chromium and arsenic are two of the most problematic water pollutants due to their high toxicity and prevalence in various water streams. While adsorption and ion-exchange processes have been applied for the efficient removal of numerous toxic contaminants, including heavy metals, from water, these technologies display relatively low overall performances and stabilities for the remediation of chromium and arsenic oxyanions. This work presents the use of polyol-functionalized porous aromatic framework (PAF) adsorbent materials that use chelation, ion-exchange, redox activity, and hydrogen-bonding interactions for the highly selective capture of chromium and arsenic from water. The chromium and arsenic binding mechanisms within these materials are probed using an array of characterization techniques, including X-ray absorption and X-ray photoelectron spectroscopies. Adsorption studies reveal that the functionalized porous aromatic frameworks (PAFs) achieve selective, near-instantaneous (reaching equilibrium capacity within 10 s), and high-capacity (2.5 mmol/g) binding performances owing to their targeted chemistries, high porosities, and high functional group loadings. Cycling tests further demonstrate that the top-performing PAF material can be recycled using mild acid and base washes without any measurable performance loss over at least ten adsorption-desorption cycles. Finally, we establish chemical design principles enabling the selective removal of chromium, arsenic, and boron from water. To achieve this, we show that PAFs appended with analogous binding groups exhibit differences in adsorption behavior, revealing the importance of binding group length and chemical identity.
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- 2024
3. Measuring Implicit Bias in ICU Notes Using Word-Embedding Neural Network Models.
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Cobert, Julien, Mills, Hunter, Lee, Albert, Gologorskaya, Oksana, Espejo, Edie, Jeon, Sun, Boscardin, W, Heintz, Timothy, Kennedy, Christopher, Ashana, Deepshikha, Chapman, Allyson, Raghunathan, Karthik, Smith, Alex, and Lee, Sei
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critical care ,inequity ,linguistics ,machine learning ,natural language processing ,Humans ,Natural Language Processing ,Intensive Care Units ,Neural Networks ,Computer ,Algorithms ,Critical Illness ,Bias ,Electronic Health Records ,Male ,Female - Abstract
BACKGROUND: Language in nonmedical data sets is known to transmit human-like biases when used in natural language processing (NLP) algorithms that can reinforce disparities. It is unclear if NLP algorithms of medical notes could lead to similar transmissions of biases. RESEARCH QUESTION: Can we identify implicit bias in clinical notes, and are biases stable across time and geography? STUDY DESIGN AND METHODS: To determine whether different racial and ethnic descriptors are similar contextually to stigmatizing language in ICU notes and whether these relationships are stable across time and geography, we identified notes on critically ill adults admitted to the University of California, San Francisco (UCSF), from 2012 through 2022 and to Beth Israel Deaconess Hospital (BIDMC) from 2001 through 2012. Because word meaning is derived largely from context, we trained unsupervised word-embedding algorithms to measure the similarity (cosine similarity) quantitatively of the context between a racial or ethnic descriptor (eg, African-American) and a stigmatizing target word (eg, nonco-operative) or group of words (violence, passivity, noncompliance, nonadherence). RESULTS: In UCSF notes, Black descriptors were less likely to be similar contextually to violent words compared with White descriptors. Contrastingly, in BIDMC notes, Black descriptors were more likely to be similar contextually to violent words compared with White descriptors. The UCSF data set also showed that Black descriptors were more similar contextually to passivity and noncompliance words compared with Latinx descriptors. INTERPRETATION: Implicit bias is identifiable in ICU notes. Racial and ethnic group descriptors carry different contextual relationships to stigmatizing words, depending on when and where notes were written. Because NLP models seem able to transmit implicit bias from training data, use of NLP algorithms in clinical prediction could reinforce disparities. Active debiasing strategies may be necessary to achieve algorithmic fairness when using language models in clinical research.
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- 2024
4. High-Capacity, Cooperative CO2 Capture in a Diamine-Appended Metal–Organic Framework through a Combined Chemisorptive and Physisorptive Mechanism
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Zhu, Ziting, Tsai, Hsinhan, Parker, Surya T, Lee, Jung-Hoon, Yabuuchi, Yuto, Jiang, Henry ZH, Wang, Yang, Xiong, Shuoyan, Forse, Alexander C, Dinakar, Bhavish, Huang, Adrian, Dun, Chaochao, Milner, Phillip J, Smith, Alex, Martins, Pedro Guimarães, Meihaus, Katie R, Urban, Jeffrey J, Reimer, Jeffrey A, Neaton, Jeffrey B, and Long, Jeffrey R
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Inorganic Chemistry ,Chemical Sciences ,Climate Action ,General Chemistry ,Chemical sciences ,Engineering - Abstract
Diamine-appended Mg2(dobpdc) (dobpdc4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) metal-organic frameworks are promising candidates for carbon capture that exhibit exceptional selectivities and high capacities for CO2. To date, CO2 uptake in these materials has been shown to occur predominantly via a chemisorption mechanism involving CO2 insertion at the amine-appended metal sites, a mechanism that limits the capacity of the material to ∼1 equiv of CO2 per diamine. Herein, we report a new framework, pip2-Mg2(dobpdc) (pip2 = 1-(2-aminoethyl)piperidine), that exhibits two-step CO2 uptake and achieves an unusually high CO2 capacity approaching 1.5 CO2 per diamine at saturation. Analysis of variable-pressure CO2 uptake in the material using solid-state nuclear magnetic resonance (NMR) spectroscopy and in situ diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) reveals that pip2-Mg2(dobpdc) captures CO2 via an unprecedented mechanism involving the initial insertion of CO2 to form ammonium carbamate chains at half of the sites in the material, followed by tandem cooperative chemisorption and physisorption. Powder X-ray diffraction analysis, supported by van der Waals-corrected density functional theory, reveals that physisorbed CO2 occupies a pocket formed by adjacent ammonium carbamate chains and the linker. Based on breakthrough and extended cycling experiments, pip2-Mg2(dobpdc) exhibits exceptional performance for CO2 capture under conditions relevant to the separation of CO2 from landfill gas. More broadly, these results highlight new opportunities for the fundamental design of diamine-Mg2(dobpdc) materials with even higher capacities than those predicted based on CO2 chemisorption alone.
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- 2024
5. The Role of Culture in Reading Comprehension Interventions for Students with Learning Disabilities: A Systematic Review
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Kelly, Jerae, Kunkel, Amy K., Smith, Alex, Gerzel-Short, Lydia, Park, Soyoung, and Moore, Alexcia
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Culture is ubiquitous and plays a significant role in student knowledge development and reading comprehension. Therefore, the purpose of this review was to investigate how culture is considered within reading comprehension interventions for students with learning disabilities (LD) from culturally and linguistically diverse backgrounds. Through a search of five prominent academic journals focusing on LD, we identified 41 studies related to reading comprehension interventions. We coded studies for evidence of culturally responsive pedagogy (CRP) as well as discussion of culture within the manuscript. Findings revealed that while many studies featured evidence-based instructional strategies, researchers often did not explicitly reference culture within their interventions or discuss culture when reporting results. An analysis of studies reporting the use of CRP revealed strategies that value students' linguistic backgrounds and lived experiences. Limitations and implications are discussed, and a call to action in future research is presented.
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- 2023
6. The Uchuu-GLAM BOSS and eBOSS LRG lightcones: Exploring clustering and covariance errors
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Ereza, Julia, Prada, Francisco, Klypin, Anatoly, Ishiyama, Tomoaki, Smith, Alex, Baugh, Carlton M., Li, Baojiu, Hernández-Aguayo, César, and Ruedas, José
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
This study investigates the clustering and bias of Luminous Red Galaxies (LRG) in the BOSS-LOWZ, -CMASS, -COMB, and eBOSS samples, using two types of simulated lightcones: (i) high-fidelity lightcones from Uchuu $N$-body simulation, employing SHAM technique to assign LRG to (sub)halos, and (ii) 16000 covariance lightcones from GLAM-Uchuu $N$-body simulations, including LRG using HOD data from Uchuu. Our results indicate that Uchuu and GLAM lightcones closely replicate BOSS/eBOSS data, reproducing correlation function and power spectrum across scales from redshifts $0.2$ to $1.0$, from $2$ to $150\,h^{-1}\mathrm{Mpc}$ in configuration space, from $0.005$ to $0.7\,h\mathrm{Mpc}^{-1}$ in Fourier space, and across different LRG stellar masses. Furthermore, comparing with existing MD-Patchy and EZmock BOSS/eBOSS lightcones based on approximate methods, our GLAM-Uchuu lightcones provide more precise clustering estimates. We identify significant deviations from observations within $20\,h^{-1}\mathrm{Mpc}$ scales in MD-Patchy and EZmock, with our covariance matrices indicating that these methods underestimate errors by between $10\%$ and $60\%$. Lastly, we explore the impact of cosmology on galaxy clustering. Our findings suggest that, given the current level of uncertainties in BOSS/eBOSS data, distinguishing models with and without massive neutrino effects on LSS is challenging. This paper highlights the Uchuu and GLAM-Uchuu simulations' robustness in verifying the accuracy of Planck cosmological parameters, providing a strong foundation for enhancing lightcone construction in future LSS surveys. We also demonstrate that generating thousands of galaxy lightcones is feasible using $N$-body simulations with adequate mass and force resolution.
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- 2023
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7. Long time away for 'Te Mana'
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Smith, Alex
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- 2019
8. ANTITRUST VIOLATIONS.
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Meyer, Luke, Smith, Alex, Wickham, Douglas, and Zhang, Emil
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Antitrust law -- Evaluation ,Double jeopardy -- Laws, regulations and rules ,Restraint of trade -- Remedies -- Laws, regulations and rules ,Limitation of actions -- Evaluation ,Comity of nations -- Laws, regulations and rules ,Respondeat superior -- Laws, regulations and rules ,Reasonable man doctrine -- Analysis ,Conspiracy -- Remedies -- Laws, regulations and rules ,Government regulation ,Antitrust issue ,Sherman Act - Abstract
I. INTRODUCTION 395 II. ELEMENTS OF THE OFFENSE 397 A. Agreement to Concerted Action 397 B. Restraint of Trade 398 1. Per Se Unreasonable 400 2. Rule of Reason 403 [...]
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- 2024
9. Redox Reorganization: Aluminium Promoted 1,5-Hydride Shifts Allow the Controlled Synthesis of Multisubstituted Cyclohexenes.
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Smith, Alex, Duarte, Fernanda, Donohoe, Timothy, Smith, Lewis, Armstrong, Roly, Hou, Jingyan, Smith, Edward, Sze, Ming, and Sterling, Alistair
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1 ,5-Hydride Shift ,Aluminium ,Cyclohexene ,Ring Formation ,Selective - Abstract
An efficient synthesis of cyclohexenes has been achieved from easily accessible tetrahydropyrans via a tandem 1,5-hydride shift-aldol condensation. We discovered that readily available aluminium reagents, e.g. Al2 O3 or Al(Ot Bu)3 are essential for this process, promoting the 1,5-hydride shift with complete regio- and enantiospecificity (in stark contrast to results obtained under basic conditions). The mild conditions, coupled with multiple methods available to access the tetrahydropyran starting materials makes this a versatile method with exceptional functional group tolerance. A wide range of cyclohexenes (>40 examples) have been prepared, many in enantiopure form, showing our ability to selectively install a substituent at each position around the newly forged cyclohexene ring. Experimental and computational studies revealed that aluminium serves a dual role in facilitating the hydride shift, activating both the alkoxide nucleophile and the electrophilic carbonyl group.
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- 2023
10. Large molecules from the cerebrospinal fluid enter the optic nerve but not the retina of mice
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Tong, Xiao J., Akdemir, Gokhan, Wadhwa, Meetu, Verkman, Alan S., and Smith, Alex J.
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- 2024
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11. Haptic Teleoperation goes Wireless: Evaluation and Benchmarking of a High-Performance Low-Power Wireless Control Technology
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Bolarinwa, Joseph, Smith, Alex, Aijaz, Adnan, Stanoev, Aleksandar, Sooriyabandara, Mahesh, and Giuliani, Manuel
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Computer Science - Networking and Internet Architecture - Abstract
Communication delays and packet losses are commonly investigated issues in the area of robotic teleoperation. This paper investigates application of a novel low-power wireless control technology (GALLOP) in a haptic teleoperation scenario developed to aid in nuclear decommissioning. The new wireless control protocol, which is based on an off-the-shelf Bluetooth chipset, is compared against standard implementations of wired and wireless TCP/IP data transport. Results, through objective and subjective data, show that GALLOP can be a reasonable substitute for a wired TCP/IP connection, and performs better than a standard wireless TCP/IP method based on Wi-Fi connectivity., Comment: Accepted for publication in IEEE International Symposium on Safety, Security, and Rescue Robotics (SSRR) 2022
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- 2022
12. DESI Bright Galaxy Survey: Final Target Selection, Design, and Validation
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Hahn, ChangHoon, Wilson, Michael J., Ruiz-Macias, Omar, Cole, Shaun, Weinberg, David H., Moustakas, John, Kremin, Anthony, Tinker, Jeremy L., Smith, Alex, Wechsler, Risa H., Ahlen, Steven, Alam, Shadab, Bailey, Stephen, Brooks, David, Cooper, Andrew P., Davis, Tamara M., Dawson, Kyle, Dey, Arjun, Dey, Biprateep, Eftekharzadeh, Sarah, Eisenstein, Daniel J., Fanning, Kevin, Forero-Romero, Jaime E., Frenk, Carlos S., Gaztañaga, Enrique, Gontcho, Satya Gontcho A, Guy, Julien, Honscheid, Klaus, Ishak, Mustapha, Juneau, Stéphanie, Kehoe, Robert, Kisner, Theodore, Lan, Ting-Wen, Landriau, Martin, Guillou, Laurent Le, Levi, Michael E., Magneville, Christophe, Martini, Paul, Meisner, Aaron, Myers, Adam D., Nie, Jundan, Norberg, Peder, Palanque-Delabrouille, Nathalie, Percival, Will J., Poppett, Claire, Prada, Francisco, Raichoor, Anand, Ross, Ashley J., Safonova, Sasha, Saulder, Christoph, Schlafly, Eddie, Schlegel, David, Sierra-Porta, David, Tarle, Gregory, Weaver, Benjamin A., Yèche, Christophe, Zarrouk, Pauline, Zhou, Rongpu, Zhou, Zhimin, and Zou, Hu
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
Over the next five years, the Dark Energy Spectroscopic Instrument (DESI) will use 10 spectrographs with 5000 fibers on the 4m Mayall Telescope at Kitt Peak National Observatory to conduct the first Stage-IV dark energy galaxy survey. At $z < 0.6$, the DESI Bright Galaxy Survey (BGS) will produce the most detailed map of the Universe during the dark energy dominated epoch with redshifts of >10 million galaxies over 14,000 deg$^2$. In this work, we present and validate the final BGS target selection and survey design. From the Legacy Surveys, BGS will target a $r < 19.5$ magnitude-limited sample (BGS Bright); a fainter $19.5 < r < 20.175$ sample, color-selected to have high redshift efficiency (BGS Faint); and a smaller low-z quasar sample. BGS will observe these targets using exposure times, scaled to achieve uniform completeness, and visit each point on the footprint three times. We use observations from the Survey Validation programs conducted prior to the main survey along with realistic simulations to show that BGS can complete its strategy and make optimal use of `bright' time. We demonstrate that BGS targets have stellar contamination <1% and that their densities do not depend strongly on imaging properties. We also confirm that BGS Bright will achieve >80% fiber assignment efficiency. Finally, we show that BGS Bright and Faint will achieve >95% redshift success rates with no significant dependence on observing conditions. BGS meets the requirements for an extensive range of scientific applications. BGS will yield the most precise Baryon Acoustic Oscillations and Redshift-Space Distortions measurements at $z < 0.4$. It also presents opportunities to exploit new methods that require highly complete and dense galaxy samples (e.g. N-point statistics, multi-tracers). BGS further provides a powerful tool to study galaxy populations and the relations between galaxies and dark matter., Comment: AJ, submitted, 34 pages, 22 figures, one of a suite of 8 papers detailing targeting for DESI
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- 2022
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13. A lightcone catalogue from the Millennium-XXL simulation: improved spatial interpolation and colour distributions for the DESI BGS
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Smith, Alex, Cole, Shaun, Grove, Cameron, Norberg, Peder, and Zarrouk, Pauline
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
The use of realistic mock galaxy catalogues is essential in the preparation of large galaxy surveys, in order to test and validate theoretical models and to assess systematics. We present an updated version of the mock catalogue constructed from the Millennium-XXL simulation, which uses a halo occupation distribution (HOD) method to assign galaxies r-band magnitudes and g-r colours. We have made several modifications to the mock to improve the agreement with measurements from the SDSS and GAMA surveys. We find that cubic interpolation, which was used to build the original halo lightcone, produces extreme velocities between snapshots. Using linear interpolation improves the correlation function quadrupole measurements on small scales. We also update the g-r colour distributions so that the observed colours better agree with measurements from GAMA data, particularly for faint galaxies. As an example of the science that can be done with the mock, we investigate how the luminosity function depends on environment and colour, and find good agreement with measurements from the GAMA survey. This full-sky mock catalogue is designed for the ongoing Dark Energy Spectroscopic Instrument (DESI) Bright Galaxy Survey (BGS), and is complete to a magnitude limit r=20.2., Comment: 15 pages, 11 figures. Accepted for publication in MNRAS
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- 2022
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14. Demo: Untethered Haptic Teleoperation for Nuclear Decommissioning using a Low-Power Wireless Control Technology
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Bolarinwa, Joseph, Smith, Alex, Aijaz, Adnan, Stanoev, Aleksandar, and Giuliani, Manuel
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Computer Science - Networking and Internet Architecture ,Computer Science - Robotics - Abstract
Haptic teleoperation is typically realized through wired networking technologies (e.g., Ethernet) which guarantee performance of control loops closed over the communication medium, particularly in terms of latency, jitter, and reliability. This demonstration shows the capability of conducting haptic teleoperation over a novel low-power wireless control technology, called GALLOP, in a nuclear decommissioning use-case. It shows the viability of GALLOP for meeting latency, timeliness, and safety requirements of haptic teleoperation. Evaluation conducted as part of the demonstration reveals that GALLOP, which has been implemented over an off-the-shelf Bluetooth 5.0 chipset, can be a replacement for conventional wired TCP/IP connection, and outperforms WiFi-based wireless solution in same use-case., Comment: Accepted for publication in IEEE INFOCOM 2022
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- 2022
15. Solving small-scale clustering problems in approximate lightcone mocks
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Smith, Alex, Cole, Shaun, Grove, Cameron, Norberg, Peder, and Zarrouk, Pauline
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
Realistic lightcone mocks are important in the clustering analyses of large galaxy surveys. For simulations where only the snapshots are available, it is common to create approximate lightcones by joining together the snapshots in spherical shells. We assess the two-point clustering measurements of central galaxies in approximate lightcones built from the Millennium-XXL simulation, which are constructed using different numbers of snapshots. The monopole and quadrupole of the real-space correlation function is strongly boosted on small scales below 1 Mpc/h, due to some galaxies being duplicated at the boundaries between snapshots in the lightcone. When more snapshots are used, the total number of duplicated galaxies is approximately constant, but they are pushed to smaller separations. The effect of this in redshift space is small, as long as the snapshots are cut into shells in real space. Randomly removing duplicated galaxies is able to reduce the excess clustering signal. Including satellite galaxies will reduce the impact of the duplicates, since many small-scale pairs come from satellites in the same halo. Galaxies that are missing from the lightcone at the boundaries can be added to the lightcone by having a small overlap between each shell. This effect will impact analyses that use very small-scale clustering measurements, and when using mocks to test the impact of fibre collisions., Comment: 10 pages, 7 figures, 1 table. Accepted for publication in MNRAS
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- 2022
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16. Evaluation of the Stability of Diamine-Appended Mg2(dobpdc) Frameworks to Sulfur Dioxide
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Parker, Surya T, Smith, Alex, Forse, Alexander C, Liao, Wei-Chih, Brown-Altvater, Florian, Siegelman, Rebecca L, Kim, Eugene J, Zill, Nicholas A, Zhang, Wenjun, Neaton, Jeffrey B, Reimer, Jeffrey A, and Long, Jeffrey R
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Climate Action ,Sulfur Dioxide ,Diamines ,Carbon Dioxide ,Amines ,Carbon ,Chemical Sciences ,General Chemistry - Abstract
Diamine-appended Mg2(dobpdc) (dobpdc4- = 4,4'-dioxidobiphenyl-3,3'-dicarboxylate) metal-organic frameworks are a promising class of CO2 adsorbents, although their stability to SO2─a trace component of industrially relevant exhaust streams─remains largely untested. Here, we investigate the impact of SO2 on the stability and CO2 capture performance of dmpn-Mg2(dobpdc) (dmpn = 2,2-dimethyl-1,3-propanediamine), a candidate material for carbon capture from coal flue gas. Using SO2 breakthrough experiments and CO2 isobar measurements, we find that the material retains 91% of its CO2 capacity after saturation with a wet simulated flue gas containing representative levels of CO2 and SO2, highlighting the robustness of this framework to SO2 under realistic CO2 capture conditions. Initial SO2 cycling experiments suggest dmpn-Mg2(dobpdc) may achieve a stable operating capacity in the presence of SO2 after initial passivation. Evaluation of several other diamine-Mg2(dobpdc) variants reveals that those with primary,primary (1°,1°) diamines, including dmpn-Mg2(dobpdc), are more robust to humid SO2 than those featuring primary,secondary (1°,2°) or primary,tertiary (1°,3°) diamines. Based on the solid-state 15N NMR spectra and density functional theory calculations, we find that under humid conditions, SO2 reacts with the metal-bound primary amine in 1°,2° and 1°,3° diamine-appended Mg2(dobpdc) to form a metal-bound bisulfite species that is charge balanced by a primary ammonium cation, thereby facilitating material degradation. In contrast, humid SO2 reacts with the free end of 1°,1° diamines to form ammonium bisulfite, leaving the metal-diamine bond intact. This structure-property relationship can be used to guide further optimization of these materials for CO2 capture applications.
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- 2022
17. Metal-organic frameworks as O2-selective adsorbents for air separations
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Jaramillo, David E, Jaffe, Adam, Snyder, Benjamin ER, Smith, Alex, Taw, Eric, Rohde, Rachel C, Dods, Matthew N, DeSnoo, William, Meihaus, Katie R, Harris, T David, Neaton, Jeffrey B, and Long, Jeffrey R
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Chemical Sciences ,Affordable and Clean Energy ,Climate Action ,Ferrari ,Lamborghini ,Aston Martin ,Chemical sciences - Abstract
Oxygen is a critical gas in numerous industries and is produced globally on a gigatonne scale, primarily through energy-intensive cryogenic distillation of air. The realization of large-scale adsorption-based air separations could enable a significant reduction in associated worldwide energy consumption and would constitute an important component of broader efforts to combat climate change. Certain small-scale air separations are carried out using N2-selective adsorbents, although the low capacities, poor selectivities, and high regeneration energies associated with these materials limit the extent of their usage. In contrast, the realization of O2-selective adsorbents may facilitate more widespread adoption of adsorptive air separations, which could enable the decentralization of O2 production and utilization and advance new uses for O2. Here, we present a detailed evaluation of the potential of metal-organic frameworks (MOFs) to serve as O2-selective adsorbents for air separations. Drawing insights from biological and molecular systems that selectively bind O2, we survey the field of O2-selective MOFs, highlighting progress and identifying promising areas for future exploration. As a guide for further research, the importance of moving beyond the traditional evaluation of O2 adsorption enthalpy, ΔH, is emphasized, and the free energy of O2 adsorption, ΔG, is discussed as the key metric for understanding and predicting MOF performance under practical conditions. Based on a proof-of-concept assessment of O2 binding carried out for eight different MOFs using experimentally derived capacities and thermodynamic parameters, we identify two existing materials and one proposed framework with nearly optimal ΔG values for operation under user-defined conditions. While enhancements are still needed in other material properties, the insights from the assessments herein serve as a guide for future materials design and evaluation. Computational approaches based on density functional theory with periodic boundary conditions are also discussed as complementary to experimental efforts, and new predictions enable identification of additional promising MOF systems for investigation.
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- 2022
18. “My Mom Is a Fighter”: A Qualitative Analysis of the Use of Combat Metaphors in ICU Clinician Notes
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Kim, Shannen, Mills, Hunter, Brender, Teva, McGowan, Samuel, Widera, Eric, Chapman, Allyson C., Harrison, Krista L., Lee, Sei, Smith, Alex K., Bamman, David, Gologorskaya, Oksana, and Cobert, Julien
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- 2024
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19. SpaceEdit: Learning a Unified Editing Space for Open-Domain Image Editing
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Shi, Jing, Xu, Ning, Zheng, Haitian, Smith, Alex, Luo, Jiebo, and Xu, Chenliang
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Computer Science - Computer Vision and Pattern Recognition ,Computer Science - Graphics - Abstract
Recently, large pretrained models (e.g., BERT, StyleGAN, CLIP) have shown great knowledge transfer and generalization capability on various downstream tasks within their domains. Inspired by these efforts, in this paper we propose a unified model for open-domain image editing focusing on color and tone adjustment of open-domain images while keeping their original content and structure. Our model learns a unified editing space that is more semantic, intuitive, and easy to manipulate than the operation space (e.g., contrast, brightness, color curve) used in many existing photo editing softwares. Our model belongs to the image-to-image translation framework which consists of an image encoder and decoder, and is trained on pairs of before- and after-images to produce multimodal outputs. We show that by inverting image pairs into latent codes of the learned editing space, our model can be leveraged for various downstream editing tasks such as language-guided image editing, personalized editing, editing-style clustering, retrieval, etc. We extensively study the unique properties of the editing space in experiments and demonstrate superior performance on the aforementioned tasks.
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- 2021
20. Revisión minimalista de Mesochorus Gravenhorst, 1829 (Hymenoptera: Ichneumonidae: Mesochorinae) del Área de Conservación Guanacaste, Costa Rica, con 158 especies nuevas y registros de hospedantes para 129 especies
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Sharkey, Michael J., Baker, Austin, McCluskey, Kathryn, Smith, Alex, Naik, Suresh, Ratnasingham, Sujeevan, Manjunath, Ramya, Perez, Kate, Sones, Jayme, D'Souza, Michelle, St. Jacques, Brianne, Hajibabaei, Mehrdad, Whitfield, Jim, Arias, Diana, Solis, Alma, Metz, Mark, Burns, John, Zuñiga, Ronald, Phillips-Rodriguez, Eugenie, Espinoza, Bernardo, Chacon, Isidro, Hebert, Paul, Hallwachs, Winnie, and Janzen, Daniel
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- 2023
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21. Unbiased Signal Equation for Quantitative Magnetization Transfer Mapping in Balanced Steady-State Free Precession MRI
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Bayer, Fritz M., Jezzard, Peter, Bock, Michael, and Smith, Alex K.
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Physics - Medical Physics - Abstract
Purpose: Quantitative magnetization transfer (qMT) imaging can be used to quantify the proportion of protons in a voxel attached to macromolecules. Here, we show that the original qMT balanced steady-state free precession (bSSFP) model is biased due to over-simplistic assumptions made in its derivation. Theory and Methods: We present an improved model for qMT bSSFP, which incorporates finite radio-frequency (RF) pulse effects as well as simultaneous exchange and relaxation. Further, a correction to finite RF pulse effects for sinc-shaped excitations is derived. The new model is compared to the original one in numerical simulations of the Bloch-McConnell equations and in previously acquired in-vivo data. Results: Our numerical simulations show that the original signal equation is significantly biased in typical brain tissue structures (by 7-20 %) whereas the new signal equation outperforms the original one with minimal bias (< 1%). It is further shown that the bias of the original model strongly affects the acquired qMT parameters in human brain structures, with differences in the clinically relevant parameter of pool-size-ratio of up to 31 %. Particularly high biases of the original signal equation are expected in an MS lesion within diseased brain tissue (due to a low T2/T1-ratio), demanding a more accurate model for clinical applications. Conclusion: The improved model for qMT bSSFP is recommended for accurate qMT parameter mapping in healthy and diseased brain tissue structures.
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- 2021
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22. Patient-Level Pooled Analysis of Endovascular Ultrasound Renal Denervation or a Sham Procedure 6 Months After Medication Escalation: The RADIANCE Clinical Trial Program
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Azizi, Michel, Sharp, Andrew S.P., Fisher, Naomi D.L., Weber, Michael A., Lobo, Melvin D., Daemen, Joost, Lurz, Philipp, Mahfoud, Felix, Schmieder, Roland E., Basile, Jan, Bloch, Michael J., Saxena, Manish, Wang, Yale, Sanghvi, Kintur, Jenkins, J. Stephen, Devireddy, Chandan, Rader, Florian, Gosse, Philippe, Claude, Lisa, Augustin, Dimitri A., McClure, Candace K., Kirtane, Ajay J., Wang, Yale, Skeik, Nedaa, Bae, Richard, McMeans, Amy, Goldman, JoAnne, Peterson, Rose, Stephen Jenkins, James, Tutor, Isabelle, Harrison, Michael, Penning, Angel, Devireddy, Chandan, Lea, Janice, Fiebach, Amanda, Merlin, Claudia, Rader, Florian, Dohad, Suhail, Tran, Anne, Bhatia, Kirin, Fisher, Naomi D.L., Sobieszczyk, Piotr, Halliday, Ian, Munson, Tay, Lindsey, Jason, Laster, Steven, Bunte, Mathew, Hart, Anthony, King, Dana, Hall, Jamie, Sanghvi, Kintur, Krathen, Courtney, Lewis, Luot, Willitts, Ashley, Todoran, Thomas, Basile, Jan, Awkar, Anthony, Palmer, Casey, Tecklenburg, Anna, Schindler, John, Pacella, John, Muldoon, Matthew, Albright, MaryJo, Nicholson, Tracy, Flack, John, Chami, Youseff, Hafiz, Abdul Moiz, Starkey, Emily, Adams, Kristal, Bernardo, Nelson, Veis, Judith, Hashim, Hayder, Singh, Suman, Whitman, Donna, Stouffer, Rick, Hinderliter, Alan, Allen, Meghan, Scholl, Tatum, Fong, Pete, Gainer, James, Crook, Sherron, Hatchcock, Ellen, Cohen, Debbie, Giri, Jay, Kobayashi, Taisei, Neubauer, Robin, Naidu, Suveeksha, Kirtane, Ajay J., Radhakrishnan, Jai, Batres, Candido, Edwards, Suzanne, Khuddus, Matheen, Zentko, Suzanne, Touchton, Abby, Roberson, Marti, Bloch, Michael J., Akinapelli, Abhilash, English, Lisa, Neumann, Bridget, Mendelsohn, Farrel, Brantley, Hutton, Cawthon, Thomas, DeRamus, Susan, Wade, Wesley, Fishman, Robert, Tuohy, Edward, LeBlanc, Jessica, McCurry, Tina, Krishnaswamy, Amar, Laffin, Luke, Bajzer, Christopher, Boros, Marilyn, Branche, Monica, Abraham, Josephine, Abraham, Anu, Stijleman, Inge, Hsi, David, Martin, Scott, Portnay, Edward, Fiebach, Maryann, Garavito, Carolina, Adams, Todd, Teklinski, Andrew, Leech, Adam, Drilling, Patrick, Tulik, Lynda, Benzuly, Keith, Paparello, James, Fintel, Dan, Ramirez, Haydee, Kats, Lauren, Huang, Paul, Biswas, Santanu, Risher, Serena, Pratt, Kristina, Ibebuogu, Uzoma, Johnson, Karen, Cushman, William, Jones, Lisa, Jackson, Leigh, Landers, David, Pasala, Tilak, Salazer, Thomas, Canino, Peter, Arakelian, Patricia, Yang, Yi-Ming, Khaliq, Asma, Weinberg, Mitchell, Abetu, Yihenew, Gulliver, Alana, Reilly, J.P., Garasic, Joseph, Chugh, Atul, Bertolet, Barry, Go, Brian, Gallapudi, Raghava, Cohn, Joel, Rogers, Kevin, Saxena, Manish, Mathur, Anthony, Jain, Ajay, Balawon, Armida, Zongo, Oliver, Topham, Christine, Sharp, Andrew, Anderson, Richard, Thompson, Elizabeth, Spiro, Nikki, Hodges, Elizabeth, Holder, Jaqueline, Ellam, Timothy, Bagnall, Alan, Jackson, Ralph, Bridgett, Victoria, Wilson, Peter, Das, Neelanjan, Doulton, Timothy, Loader, David, Hector, Gemma, Levy, Terry, Bent, Clare, Kodoth, Vivek, Horler, Stephanie, Nix, Sara, Robinson, Nicholas, Al-Janabi, Firas, Sayer, Jeremy, Ganesh Iyer, Sudha, Redman, Emily, Ramirez, Jonaifah, Padmanabhan, Sandosh, Sharif, Faisal, Alhmoudi, Aishah, Lunardi, Mattia, Coen, Eileen, Glynn, Nicola, Mahfoud, Felix, Lauder, Lucas, Kulenthiran, Saarraaken, Koch, Christina, Wachter, Angelika, Schmieder, Roland, Schmid, Axel, Kannenkeril, Dennis, Heinritz, Ulrike, Endres-Frohlich, Kerstin, Lurz, Philipp, Rommel, Karl, Fengler, Petzold, Martin, Büttner, Margit, Weil, Joachim, Agdirlioglu, Tolga, Köllner, Tanja, Stephan, Jeannine, Dagkonakis, Nikolaos, Hamann, Frank, Ettl, Ute, Petzsche, Ulrike, Reimer, Peter, Hausberg, Martin, Hinrichs, Ralf, Di Ponio-Voit, Isabella, Lutz, Matthias, Gosse, Philippe, Cremer, Antoine, Papadopoulos, Panteleimon, Gaudissard, Julie, Maire, Florent, Azizi, Michel, Sapoval, Marc, Livrozet, Marine, Regrag, Asma, Paquet, Valerie, Delsart, Pascal, Hennicaux, Justin, Sommeville, Coralie, Bertrand, Fabien, Daemen, Joost, Lafeber, Melvin, Zeijen, Victor, Ruiter, Amo, Huijskens, Elisabeth, van Ramshorst, Jan, Xaplanteris, Panagiotis, Briki, Rachid, de Hemptinne, Quentin, Pascal, Severine, Renard, Katty, Ferdinande, Bert, Iglesias, Juan F., Ehert, Georg, Gallego, Laetitia, Dobretz, Kevin, Bottone, Sylviane, Sanghvi, Kintur, Costello, Josh, Krathan, Courtney, Lewis, Luot, McElvarr, Andrew, Reilly, John, Jenkins, Stephen, Cash, Michael, Williams, Shannon, Jarvis, Maria, Fong, Pete, Laffer, Cheryl, Gainer, James, Robbins, Mark, Crook, Sherron, Maddel, Sarita, Hsi, David, Martin, Scott, Portnay, Edward, Ducey, Maryanne, Rose, Suzanne, DelMastro, Elizabeth, Bangalore, Sripal, Williams, Stephen, Cabos, Stanley, Rodriguez Alvarez, Carolina, Todoran, Thomas, Basile, Jan, Powers, Eric, Hodskins, Emily, Paladugu, Vijay, Tecklenburg, Anna, Devireddy, Chandan, Lea, Janice, Wells, Bryan, Fiebach, Amanda, Merlin, Claudia, Rader, Florian, Dohad, Suhail, Kim, Hyun-Min, Rashid, Mohammad, Abraham, Josephine, Owan, Theophilus, Abraham, Anu, Lavasani, Iran, Neilson, Hailey, Calhoun, David, McElderry, Thomas, Maddox, William, Oparil, Suzanne, Kinder, Sheila, Kirtane, Ajay J., Radhakrishnan, Jai, Batres, Candido, Edwards, Suzanne, Garasic, Joseph, Drachman, Doug, Zusman, Randy, Rosenfield, Kenneth, Do, Danny, Khuddus, Matheen, Zentko, Suzanne, O’Meara, James, Barb, Ilie, Foster, Abby, Boyette, Alice, Wang, Yale, Jay, Desmond, Skeik, Nedaa, Schwartz, Robert, Peterson, Rose, Goldman, Jo Anne, Goldman, Jessie, Ledley, Gary, Katof, Nancy, Potluri, Srinivasa, Biedermann, Scott, Ward, Jacquelyn, White, Megan, Fisher, Naomi D.L., Mauri, Laura, Sobieszczky, Piotr, Smith, Alex, Aseltine, Laura, Stouffer, Rick, Hinderliter, Alan, Pauley, Eric, Wade, Tyrone, Zidar, David, Shishehbor, Mehdi, Effron, Barry, Costa, Marco, Semenec, Terence, Bloch, Michael J., Roongsritong, Chanwit, Nelson, Priscilla, Neumann, Bridget, Cohen, Debbie, Giri, Jay, Neubauer, Robin, Vo, Thu, Chugh, Atul R., Huang, Pei-Hsiu, Jose, Powell, Flack, John, Fishman, Robert, Jones, Michael, Adams, Todd, Bajzer, Christopher, Saxena, Manish, Lobo, Melvin D., Mathur, Anthony, Jain, Ajay, Balawon, Armida, Zongo, Olivier, Levy, Terry, Bent, Clare, Beckett, David, Lakeman, Nicki, Kennard, Sarah, Sharp, Andrew, D’Souza, Richard J., Statton, Sarah, Wilkes, Lindsay, Anning, Christine, Sayer, Jeremy, Ganesh Iyer, Sudha, Robinson, Nicholas, Sevillano, Annaliza, Ocampo, Madelaine, Gerber, Robert, Faris, Mohamad, John Marshall, Andrew, Sinclair, Janet, Pepper, Hayley, Davies, Justin, Chapman, Neil, Burak, Paula, Carvelli, Paula, Jadhav, Sachin, Quinn, Jane, Christian Rump, Lars, Stegbauer, Johannes, Schimmöller, Lars, Potthoff, Sebastian, Schmid, Claudia, Roeder, Sylvia, Weil, Joachim, Hafer, Lukas, Agdirlioglu, Tolga, Köllner, Tanja, Mahfoud, Felix, Böhm, Michael, Ewen, Sebastian, Kulenthiran, Saarraaken, Wachter, Angelika, Koch, Christina, Lurz, Philipp, Fengler, Karl, Rommel, Karl-Philipp, Trautmann, Kai, Petzold, Martin, Schmieder, Roland E., Ott, Christian, Schmid, Axel, Uder, Michael, Heinritz, Ulrike, Fröhlich-Endres, Kerstin, Genth-Zotz, Sabine, Kämpfner, Denise, Grawe, Armin, Höhne, Johannes, Kaesberger, Bärbel, von zur Mühlen, Constantin, Wolf, Dennis, Welzel, Markus, Gosse, Philippe, Cremer, Antoine, Trillaud, Hervé, Papadopoulos, Panteleimon, Maire, Florent, Gaudissard, Julie, Azizi, Michel, Sapoval, Marc, Cornu, Erika, Fouassier, David, Livrozet, Marine, Lorthioir, Aurélien, Paquet, Valérie, Pathak, Atul, Honton, Benjamin, Cottin, Marianne, Petit, Frédéric, Lantelme, Pierre, Berge, Constance, Courand, Pierre-Yves, Langevin, Fatou, Delsart, Pascal, Longere, Benjamin, Ledieu, Guillaume, Pontana, François, Sommeville, Coralie, Bertrand, Fabien, Daemen, Joost, Feyz, Lida, Zeijen, Victor, Ruiter, Arno, Huyskens, Elisabeth, Blankestijn, Peter, Voskuil, Michiel, Rittersma, Zwaantina, Dolmans, Helma, Kroon, A.A., van Zwam, W.H., Vranken, Jeannique, de Haan, Claudia, Persu, Alexandre, Renkin, Jean, Maes, Frédéric, Beauloye, Christophe, Lengelé, Jean-Philippe, Huyberechts, Dominique, Bouvier, Anne, Witkowski, Adam, Januszewicz, Andrzej, Kądziela, Jacek, Prejbisj, Aleksander, Hering, Dagmara, Ciecwierz, Dariusz, Jaguszewski, Milosz J., Owczuk, Radoslaw, Ciecwierz, Dariusz, Jaguszewski, Milosz J., Wang, Yale, Jay, Desmond, Skeik, Nedaa, Schwartz, Robert, Rader, Florian, Dohad, Suhail, Victor, Ronald, Sanghvi, Kintur, Costello, Josh, Walsh, Courtney, Abraham, Josephine, Owan, Theophilus, Abraham, Anu, Fisher, Naomi D.L., Mauri, Laura, Sobieszczky, Piotr, Williams, Jonathan, Bloch, Michael J., Roongsritong, Chanwit, Todoran, Thomas, Basile, Jan, Powers, Eric, Hodskins, Emily, Fong, Pete, Laffer, Cheryl, Gainer, James, Robbins, Mark, Reilly, John, Cash, Michael, Goldman, Jessie, Aggarwal, Sandeep, Ledley, Gary, Hsi, David, Martin, Scott, Portnay, Edward, Calhoun, David, McElderry, Thomas, Maddox, William, Oparil, Suzanne, Huang, Pei-Hsiu, Jose, Powell, Khuddus, Matheen, Zentko, Suzanne, O’Meara, James, Barb, Ilie, Garasic, Joseph, Drachman, Doug, Zusman, Randy, Rosenfield, Kenneth, Devireddy, Chandan, Lea, Janice, Wells, Bryan, Stouffer, Rick, Hinderliter, Alan, Pauley, Eric, Potluri, Srinivasa, Biedermann, Scott, Bangalore, Sripal, Williams, Stephen, Zidar, David, Shishehbor, Mehdi, Effron, Barry, Costa, Marco, Kirtane, Ajay J., Radhakrishnan, Jai, Lobo, Melvin D., Mathur, Anthony, Jain, Ajay, Sayer, Jeremy, Ganesh Iyer, Sudha, Robinson, Nicholas, Ali Edroos, Sadat, Levy, Terry, Patel, Amit, Beckett, David, Bent, Clare, Davies, Justin, Chapman, Neil, Shun Shin, Matthew, Howard, James, Sharp, Andrew S.P., Joseph, Anil, D’Souza, Richard, Gerber, Robert, Faris, Mohamad, John Marshall, Andrew, Elorz, Cristina, Lurz, Philipp, Höllriegel, Robert, Fengler, Karl, Rommel, Karl-Philipp, Mahfoud, Felix, Böhm, Michael, Ewen, Sebastian, Lucic, Jelena, Schmieder, Roland E., Ott, Christian, Schmid, Axel, Uder, Michael, Rump, Christian, Stegbauer, Johannes, Kröpil, Patric, Azizi, Michel, Sapoval, Marc, Cornu, Erika, Fouassier, David, Gosse, Philippe, Cremer, Antoine, Trillaud, Hervé, Papadopoulos, Panteleimon, Pathak, Atul, Honton, Benjamin, Lantelme, Pierre, Berge, Constance, Courand, Pierre-Yves, Daemen, Joost, Feyz, Lida, Blankestijn, Peter, Voskuil, Michiel, Rittersma, Zwaantina, Kroon, A.A., van Zwam, W.H., Persu, Alexandre, and Renkin, Jean
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- 2024
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23. Mixed Reality Applications for Manipulating Robots and Rovers: ARSIS 6.0
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Teogalbo, Digno J. R., Auner, David, Ayala, Natalie, Burnell, Charles, Dayrit, Trice, Gamel, Gamma, Lotspeich, Nick, Smith, Alex, Swanson, Steve, Willerup, Elias, Williamson, Brady, Villanueva, Ben, Goos, Gerhard, Founding Editor, Hartmanis, Juris, Founding Editor, Bertino, Elisa, Editorial Board Member, Gao, Wen, Editorial Board Member, Steffen, Bernhard, Editorial Board Member, Yung, Moti, Editorial Board Member, Chen, Jessie Y. C., editor, and Fragomeni, Gino, editor
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- 2023
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24. Incidental Gallbladder Cancer: The Role of Routine Versus Selective Histopathological Examination of Gallbladder Specimens After Cholecystectomy
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Di Mauro, Davide, Saunders, Sarah, Orabi, Amira, Myintmo, Aye, Reece-Smith, Alex, Wajed, Shahjehan, Manzelli, Antonio, Kumar Shukla, Vijay, editor, Pandey, Manoj, editor, and Dixit, Ruhi, editor
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- 2023
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25. Exploration of New Complexity Metrics for Curriculum-Based Measures of Writing
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Wagner, Kyle, Smith, Alex, Allen, Abigail, McMaster, Kristen, Poch, Apryl, and Lembke, Erica
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Researchers and practitioners have questioned whether scoring procedures used with curriculum-based measures of writing (CBM-W) capture growth in complexity of writing. We analyzed data from six independent samples to examine two potential scoring metrics for picture word CBM-W (PW), a sentence-level CBM task. Correct word sequences per response (CWSR) and words written per response (WWR) were compared with the current standard metric of correct word sequences (CWS). Linear regression analyses indicated that CWSR predicted scores on standardized norm-referenced criterion measures in more samples than did WWR or CWS. Future studies should explore the capacity of CWSR and WWR to show growth over time, stability, diagnostic accuracy, and utility for instructional decision making.
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- 2019
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26. Predicting cytopenias, progression, and survival in patients with clonal cytopenia of undetermined significance: a prospective cohort study
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Cargo, Catherine, Bernard, Elsa, Beinortas, Tumas, Bolton, Kelly L, Glover, Paul, Warren, Helen, Payne, Daniel, Ali, Rukhsaar, Khan, Alesia, Short, Mike, Van Hoppe, Suzan, Smith, Alex, Taylor, Jan, Evans, Paul, Papaemmanuil, Elli, and Crouch, Simon
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- 2024
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27. Reducing the Variance of Redshift Space Distortion Measurements from Mock Galaxy Catalogues with Different Lines of Sight
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Smith, Alex, de Mattia, Arnaud, Burtin, Etienne, Chuang, Chia-Hsun, and Zhao, Cheng
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
Accurate mock catalogues are essential for assessing systematics in the cosmological analysis of large galaxy surveys. Anisotropic two-point clustering measurements from the same simulation show some scatter for different lines of sight (LOS), but are on average equal, due to cosmic variance. This results in scatter in the measured cosmological parameters. We use the OuterRim N-body simulation halo catalogue to investigate this, considering the 3 simulation axes as LOS. The quadrupole of the 2-point statistics is particularly sensitive to changes in the LOS, with sub-percent level differences in the velocity distributions resulting in ~1.5$\sigma$ shifts on large scales. Averaging over multiple LOS can reduce the impact of cosmic variance. We derive an expression for the Gaussian cross-covariance between the power spectrum multipole measurements, for any two LOS, including shot noise, and the corresponding reduction in variance in the average measurement. Quadrupole measurements are anti-correlated, and for three orthogonal LOS, the variance on the average measurement is reduced by more than 1/3. We perform a Fisher analysis to predict the corresponding gain in precision on the cosmological parameter measurements, which we compare against a set of 300 extended Baryon Oscillation Spectroscopic Survey (eBOSS) emission line galaxy (ELG) EZmocks. The gain in $f\sigma_8$, which measures the growth of structure, is also better than 1/3. Averaging over multiple LOS in future mock challenges will allow the RSD models to be constrained with the same systematic error, with less than 3 times the CPU time., Comment: 14 pages, 10 figures, 1 table, updated to match the version accepted for publication in MNRAS
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- 2020
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28. The Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: BAO and RSD measurements from anisotropic clustering analysis of the Quasar Sample in configuration space between redshift 0.8 and 2.2
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Hou, Jiamin, Sánchez, Ariel G., Ross, Ashley J., Smith, Alex, Neveux, Richard, Bautista, Julian, Burtin, Etienne, Zhao, Cheng, Scoccimarro, Román, Dawson, Kyle S., de Mattia, Arnaud, de la Macorra, Axel, Bourboux, Hélion du Mas des, Eisenstein, Daniel J., Gil-Marín, Héctor, Lyke, Brad W., Mohammad, Faizan G., Mueller, Eva-Maria, Percival, Will J., Magaña, Mariana Vargas, Rossi, Graziano, Zarrouk, Pauline, Zhao, Gong-Bo, Brinkmann, Jonathan, Brownstein, Joel R., Chuang, Chia-Hsun, Myers, Adam D., Newman, Jeffrey A., Schneider, Donald P., and Vivek, M.
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We measure the anisotropic clustering of the quasar sample from Data Release 16 (DR16) of the Sloan Digital Sky Survey IV extended Baryon Oscillation Spectroscopic Survey (eBOSS). A sample of $343,708$ spectroscopically confirmed quasars between redshift $0.8
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- 2020
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29. The Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: BAO and RSD measurements from the anisotropic power spectrum of the Quasar sample between redshift 0.8 and 2.2
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Neveux, Richard, Burtin, Etienne, de Mattia, Arnaud, Smith, Alex, Ross, Ashley J., Hou, Jiamin, Bautista, Julian, Brinkmann, Jonathan, Chuang, Chia-Hsun, Dawson, Kyle S., Gil-Marín, Héctor, Lyke, Brad W., de la Macorra, Axel, Bourboux, Hélion du Mas des, Mohammad, Faizan G., Müller, Eva-Maria, Myers, Adam D., Newman, Jeffrey A., Percival, Will J., Rossi, Graziano, Schneider, Donald, Vivek, M., Zarrouk, Pauline, Zhao, Cheng, and Zhao, Gong-Bo
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We measure the clustering of quasars of the final data release (DR16) of eBOSS. The sample contains $343\,708$ quasars between redshifts $0.8\leq z\leq2.2$ over $4699\,\mathrm{deg}^2$. We calculate the Legendre multipoles (0,2,4) of the anisotropic power spectrum and perform a BAO and a Full-Shape (FS) analysis at the effective redshift $z{\rm eff}=1.480$. The errors include systematic errors that amount to 1/3 of the statistical error. The systematic errors comprise a modelling part studied using a blind N-Body mock challenge and observational effects studied with approximate mocks to account for various types of redshift smearing and fibre collisions. For the BAO analysis, we measure the transverse comoving distance $D_{\rm M}(z_{\rm eff})/r_{\rm drag}=30.60\pm{0.90}$ and the Hubble distance $D_{\rm H}(z_{\rm eff})/r_{\rm drag}=13.34\pm{0.60}$. This agrees with the configuration space analysis, and the consensus yields: $D_{\rm M}(z_{\rm eff})/r_{\rm drag}=30.69\pm{0.80}$ and $D_{\rm H}(z_{\rm eff})/r_{\rm drag}=13.26\pm{0.55}$. In the FS analysis, we fit the power spectrum using a model based on Regularised Perturbation Theory, which includes Redshift Space Distortions and the Alcock-Paczynski effect. The results are $D_{\rm M}(z_{\rm eff})/r_{\rm drag}=30.68\pm{0.90}$ and $D_{\rm H}(z_{\rm eff})/r_{\rm drag}=13.52\pm{0.51}$ and we constrain the linear growth rate of structure $f(z_{\rm eff})\sigma_8(z_{\rm eff})=0.476\pm{0.047}$. Our results agree with the configuration space analysis. The consensus analysis of the eBOSS quasar sample yields: $D_{\rm M}(z_{\rm eff})/r_{\rm drag}=30.21\pm{0.79}$, $D_{\rm H}(z_{\rm eff})/r_{\rm drag}=3.23\pm{0.47}$ and $f(z_{\rm eff})\sigma_8(z_{\rm eff})=0.462\pm{0.045}$ and is consistent with a flat $\Lambda {\rm CDM}$ cosmological model using Planck results., Comment: 22 pages, 16 figures, 12 tables A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found here: https://sdss.org/science/final-bao-and-rsd-measurements/ . The full cosmological interpretation of these measurements can be found here: https://sdss.org/science/cosmology-results-from-eboss/
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- 2020
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30. The Completed SDSS-IV Extended Baryon Oscillation Spectroscopic Survey: Growth rate of structure measurement from cosmic voids
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Aubert, Marie, Cousinou, Marie-Claude, Escoffier, Stéphanie, Hawken, Adam J., Nadathur, Seshadri, Alam, Shadab, Bautista, Julian, Burtin, Etienne, Chuang, Chia-Hsun, de la Macorra, Axel, de Mattia, Arnaud, Gil-Marín, Héctor, Hou, Jiamin, Jullo, Eric, Kneib, Jean-Paul, Neveux, Richard, Rossi, Graziano, Schneider, Donald, Smith, Alex, Tamone, Amélie, Magaña, Mariana Vargas, and Zhao, Cheng
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We present a void clustering analysis in configuration-space using the completed Sloan Digital Sky Survey IV (SDSS-IV) extended Baryon Oscillation Spectroscopic Survey (eBOSS) DR16 samples. These samples consist of Luminous Red Galaxies (LRG) combined with the high redshift tail of the SDSS-III Baryon Oscillation Spectroscopic Survey (BOSS) DR12 CMASS galaxies (called as LRG+CMASS sample), Emission Line Galaxies (ELG) and quasars (QSO). We build void catalogues from the three eBOSS DR16 samples using a ZOBOV-based algorithm, providing 2,814 voids, 1,801 voids and 4,347 voids in the LRG+CMASS, ELG and QSO samples, respectively, spanning the redshift range $0.6
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- 2020
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31. The Completed SDSS-IV Extended Baryon Oscillation Spectroscopic Survey: GLAM-QPM mock galaxy catalogs for the Emission Line Galaxy Sample
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Lin, Sicheng, Tinker, Jeremy L., Klypin, Anatoly, Prada, Francisco, Blanton, Michael R., Comparat, Johan, Dawson, Kyle S., de Mattia, Arnaud, Bourboux, Hélion du Mas des, Percival, Will J., Raichoor, Anand, Rossi, Graziano, Smith, Alex, and Zhao, Cheng
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Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We present 2000 mock galaxy catalogs for the analysis of baryon acoustic oscillations in the Emission Line Galaxy (ELG) sample of the Extended Baryon Oscillation Spectroscopic Survey Data Release 16 (eBOSS DR16). Each mock catalog has a number density of $6.7 \times 10^{-4} h^3 \rm Mpc^{-3}$, covering a redshift range from 0.6 to 1.1. The mocks are calibrated to small-scale eBOSS ELG clustering measurements at scales of around 10 $h^{-1}$Mpc. The mock catalogs are generated using a combination of GaLAxy Mocks (GLAM) simulations and the Quick Particle-Mesh (QPM) method. GLAM simulations are used to generate the density field, which is then assigned dark matter halos using the QPM method. Halos are populated with galaxies using a halo occupation distribution (HOD). The resulting mocks match the survey geometry and selection function of the data, and have slightly higher number density which allows room for systematic analysis. The large-scale clustering of mocks at the baryon acoustic oscillation (BAO) scale is consistent with data and we present the correlation matrix of the mocks., Comment: 12 pages, 11 figures, submitted to MNRAS
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- 2020
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32. The Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: N-body Mock Challenge for the eBOSS Emission Line Galaxy Sample
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Alam, Shadab, de Mattia, Arnaud, Tamone, Amélie, Ávila, S., Peacock, John A., Gonzalez-Perez, V., Smith, Alex, Raichoor, Anand, Ross, Ashley J., Bautista, Julian E., Burtin, Etienne, Comparat, Johan, Dawson, Kyle S., Bourboux, Hélion du Mas des, Escoffier, Stéphanie, Gil-Marín, Héctor, Habib, Salman, Heitmann, Katrin, Hou, Jiamin, Mohammad, Faizan G., Mueller, Eva-Maria, Neveux, Richard, Paviot, Romain, Percival, Will J., Rossi, Graziano, Ruhlmann-Kleider, Vanina, Tojeiro, Rita, Magaña, Mariana Vargas, Zhao, Cheng, and Zhao, Gong-Bo
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Astrophysics - Cosmology and Nongalactic Astrophysics ,Astrophysics - Astrophysics of Galaxies - Abstract
Cosmological growth can be measured in the redshift space clustering of galaxies targeted by spectroscopic surveys. Accurate prediction of clustering of galaxies will require understanding galaxy physics which is a very hard and highly non-linear problem. Approximate models of redshift space distortion (RSD) take a perturbative approach to solve the evolution of dark matter and galaxies in the universe. In this paper we focus on eBOSS emission line galaxies (ELGs) which live in intermediate mass haloes. We create a series of mock catalogues using haloes from the Multidark and {\sc Outer Rim} dark matter only N-body simulations. Our mock catalogues include various effects inspired by baryonic physics such as assembly bias and the characteristics of satellite galaxies kinematics, dynamics and statistics deviating from dark matter particles. We analyse these mocks using the TNS RSD model in Fourier space and the CLPT in configuration space. We conclude that these two RSD models provide an unbiased measurement of redshift space distortion within the statistical error of our mocks. We obtain the conservative theoretical systematic uncertainty of $3.3\%$, $1.8\%$ and $1.5\%$ in $f\sigma_8$, $\alpha_{\parallel}$ and $\alpha_{\bot}$ respectively for the TNS and CLPT models. We note that the estimated theoretical systematic error is an order of magnitude smaller than the statistical error of the eBOSS ELG sample and hence are negligible for the purpose of the current eBOSS ELG analysis., Comment: 21 pages, 7 figures and 9 tables, A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found at https://www.sdss.org/science/final-bao-and-rsd-measurements/ . The full cosmological interpretation of these measurements can be found at https://www.sdss.org/science/cosmology-results-from-eboss/ . Final published version
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- 2020
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33. The Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: Cosmological Implications from two Decades of Spectroscopic Surveys at the Apache Point observatory
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eBOSS Collaboration, Alam, Shadab, Aubert, Marie, Avila, Santiago, Balland, Christophe, Bautista, Julian E., Bershady, Matthew A., Bizyaev, Dmitry, Blanton, Michael R., Bolton, Adam S., Bovy, Jo, Brinkmann, Jonathan, Brownstein, Joel R., Burtin, Etienne, Chabanier, Solene, Chapman, Michael J., Choi, Peter Doohyun, Chuang, Chia-Hsun, Comparat, Johan, Cuceu, Andrei, Dawson, Kyle S., de la Macorra, Axel, de la Torre, Sylvain, de Mattia, Arnaud, Agathe, Victoria de Sainte, Bourboux, Hélion du Mas des, Escoffier, Stephanie, Etourneau, Thomas, Farr, James, Font-Ribera, Andreu, Frinchaboy, Peter M., Fromenteau, Sebastien, Gil-Marín, Héctor, Gonzalez-Morales, Alma X., Gonzalez-Perez, Violeta, Grabowski, Kathleen, Guy, Julien, Hawken, Adam J., Hou, Jiamin, Kong, Hui, Klaene, Mark, Kneib, Jean-Paul, Goff, Jean-Marc Le, Lin, Sicheng, Long, Daniel, Lyke, Brad W., Cousinou, Marie-Claude, Martini, Paul, Masters, Karen, Mohammad, Faizan G., Moon, Jeongin, Mueller, Eva-Maria, Munõz-Gutieŕrez, Andrea, Myers, Adam D., Nadathur, Seshadri, Neveux, Richard, Newman, Jeffrey A., Noterdaeme, Pasquier, Oravetz, Audrey, Oravetz, Daniel, Palanque-Delabrouille, Nathalie, Pan, Kaike, Parker III, James, Paviot, Romain, Percival, Will J., Peŕez-Rafols, Ignasi, Petitjean, Patrick, Pieri, Matthew M., Prakash, Abhishek, Raichoor, Anand, Ravoux, Corentin, Rezaie, Mehdi, Rich, James, Ross, Ashley J., Rossi, Graziano, Ruggeri, Rossana, Ruhlmann-Kleider, Vanina, Sańchez, Ariel G., Sańchez, F. Javier, Sańchez-Gallego, José R., Sayres, Conor, Schneider, Donald P., Seo, Hee-Jong, Shafieloo, Arman, Slosar, Anže, Smith, Alex, Stermer, Julianna, Tamone, Amelie, Tinker, Jeremy L., Tojeiro, Rita, Vargas-Magaña, Mariana, Variu, Andrei, Wang, Yuting, Weaver, Benjamin A., Weijmans, Anne-Marie, Yeche, Christophe, Zarrouk, Pauline, Zhao, Cheng, Zhao, Gong-Bo, and Zheng, Zheng
- Subjects
Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We present the cosmological implications from final measurements of clustering using galaxies, quasars, and Ly$\alpha$ forests from the completed Sloan Digital Sky Survey (SDSS) lineage of experiments in large-scale structure. These experiments, composed of data from SDSS, SDSS-II, BOSS, and eBOSS, offer independent measurements of baryon acoustic oscillation (BAO) measurements of angular-diameter distances and Hubble distances relative to the sound horizon, $r_d$, from eight different samples and six measurements of the growth rate parameter, $f\sigma_8$, from redshift-space distortions (RSD). This composite sample is the most constraining of its kind and allows us to perform a comprehensive assessment of the cosmological model after two decades of dedicated spectroscopic observation. We show that the BAO data alone are able to rule out dark-energy-free models at more than eight standard deviations in an extension to the flat, $\Lambda$CDM model that allows for curvature. When combined with Planck Cosmic Microwave Background (CMB) measurements of temperature and polarization the BAO data provide nearly an order of magnitude improvement on curvature constraints. The RSD measurements indicate a growth rate that is consistent with predictions from Planck primary data and with General Relativity. When combining the results of SDSS BAO and RSD with external data, all multiple-parameter extensions remain consistent with a $\Lambda$CDM model. Regardless of cosmological model, the precision on $\Omega_\Lambda$, $H_0$, and $\sigma_8$, remains at roughly 1\%, showing changes of less than 0.6\% in the central values between models. The inverse distance ladder measurement under a o$w_0w_a$CDM yields $H_0= 68.20 \pm 0.81 \, \rm km\, s^{-1} Mpc^{-1}$, remaining in tension with several direct determination methods. (abridged), Comment: A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found here: https://www.sdss.org/science/final-bao-and-rsd-measurements/ . The full cosmological interpretation of these measurements can be found here: https://www.sdss.org/science/cosmology-results-from-eboss/
- Published
- 2020
- Full Text
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34. The Completed SDSS-IV Extended Baryon Oscillation Spectroscopic Survey: N-body Mock Challenge for Galaxy Clustering Measurements
- Author
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Rossi, Graziano, Choi, Peter D., Moon, Jeongin, Bautista, Julian E., Gil-Marin, Hector, Paviot, Romain, Vargas-Magana, Mariana, de la Torre, Sylvain, Fromenteau, Sebastien, Ross, Ashley J., Avila, Santiago, Burtin, Etienne, Dawson, Kyle S., Escoffier, Stephanie, Habib, Salman, Heitmann, Katrin, Hou, Jiamin, Mueller, Eva-Maria, Percival, Will J., Smith, Alex, Zhao, Cheng, and Zhao, Gong-Bo
- Subjects
Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We develop a series of N-body data challenges, functional to the final analysis of the extended Baryon Oscillation Spectroscopic Survey (eBOSS) Data Release 16 (DR16) galaxy sample. The challenges are primarily based on high-fidelity catalogs constructed from the Outer Rim simulation - a large box size realization (3 Gpc/h) characterized by an unprecedented combination of volume and mass resolution, down to 1.85x10^9 M_sun/h. We generate synthetic galaxy mocks by populating Outer Rim halos with a variety of halo occupation distribution (HOD) schemes of increasing complexity, spanning different redshift intervals. We then assess the performance of three complementary redshift space distortion (RSD) models in configuration and Fourier space, adopted for the analysis of the complete DR16 eBOSS sample of Luminous Red Galaxies (LRGs). We find all the methods mutually consistent, with comparable systematic errors on the Alcock-Paczynski parameters and the growth of structure, and robust to different HOD prescriptions - thus validating the robustness of the models and the pipelines used for the baryon acoustic oscillation (BAO) and full shape clustering analysis. In particular, all the techniques are able to recover a_par and a_perp to within 0.9%, and fsig8 to within 1.5%. As a by-product of our work, we are also able to gain interesting insights on the galaxy-halo connection. Our study is relevant for the final eBOSS DR16 `consensus cosmology', as the systematic error budget is informed by testing the results of analyses against these high-resolution mocks. In addition, it is also useful for future large-volume surveys, since similar mock-making techniques and systematic corrections can be readily extended to model for instance the Dark Energy Spectroscopic Instrument (DESI) galaxy sample., Comment: 34 pages, 14 figures, 13 tables. Updated to match the version accepted for publication in MNRAS. A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found here: https://sdss.org/science/final-bao-and-rsd-measurements/ . The full cosmological interpretation of these measurements can be found here: https://sdss.org/science/cosmology-results-from-eboss/
- Published
- 2020
- Full Text
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35. The Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: Large-scale Structure Catalogs for Cosmological Analysis
- Author
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Ross, Ashley J., Bautista, Julian, Tojeiro, Rita, Alam, Shadab, Bailey, Stephen, Burtin, Etienne, Comparat, Johan, Dawson, Kyle S., de Mattia, Arnaud, Bourboux, Hélion du Mas des, Gil-Marín, Héctor, Hou, Jiamin, Kong, Hui, Lyke, Brad W., Mohammad, Faizan G., Moustakas, John, Mueller, Eva-Maria, Myers, Adam D., Percival, Will J., Raichoor, Anand, Rezaie, Mehdi, Seo, Hee-Jong, Smith, Alex, Tinker, Jeremy L., Zarrouk, Pauline, Zhao, Cheng, Zhao, Gong-Bo, Bizyaev, Dmitry, Brinkmann, Jonathan, Brownstein, Joel R., Rosell, Aurelio Carnero, Chabanier, Solène, Choi, Peter D., Chuang, Chia-Hsun, Cruz-Gonzalez, Irene, de la Macorra, Axel, de la Torre, Sylvain, Escoffier, Stephanie, Fromenteau, Sebastien, Higley, Alexandra, Jullo, Eric, Kneib, Jean-Paul, McLane, Jacob N., Muñoz-Gutiérrez, Andrea, Neveux, Richard, Newman, Jeffrey A., Nitschelm, Christian, Palanque-Delabrouille, Nathalie, Paviot, Romain, Pullen, Anthony R., Rossi, Graziano, Ruhlmann-Kleider, Vanina, Schneider, Donald P., Magaña, Mariana Vargas, Vivek, M., and Zhang, Yucheng
- Subjects
Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We present large-scale structure catalogs from the completed extended Baryon Oscillation Spectroscopic Survey (eBOSS). Derived from Sloan Digital Sky Survey (SDSS) -IV Data Release 16 (DR16), these catalogs provide the data samples, corrected for observational systematics, and random positions sampling the survey selection function. Combined, they allow large-scale clustering measurements suitable for testing cosmological models. We describe the methods used to create these catalogs for the eBOSS DR16 Luminous Red Galaxy (LRG) and Quasar samples. The quasar catalog contains 343,708 redshifts with $0.8 < z < 2.2$ over 4,808\,deg$^2$. We combine 174,816 eBOSS LRG redshifts over 4,242\,deg$^2$ in the redshift interval $0.6 < z < 1.0$ with SDSS-III BOSS LRGs in the same redshift range to produce a combined sample of 377,458 galaxy redshifts distributed over 9,493\,deg$^2$. Improved algorithms for estimating redshifts allow that 98 per cent of LRG observations result in a successful redshift, with less than one per cent catastrophic failures ($\Delta z > 1000$ ${\rm km~s}^{-1}$). For quasars, these rates are 95 and 2 per cent (with $\Delta z > 3000$ ${\rm km~s}^{-1}$). We apply corrections for trends between the number densities of our samples and the properties of the imaging and spectroscopic data. For example, the quasar catalog obtains a $\chi^2$/DoF$= 776/10$ for a null test against imaging depth before corrections and a $\chi^2$/DoF$=6/8$ after. The catalogs, combined with careful consideration of the details of their construction found here-in, allow companion papers to present cosmological results with negligible impact from observational systematic uncertainties., Comment: Matches version accepted by MNRAS, very minor changes. A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found here: https://www.sdss.org/science/final-bao-and-rsd-measurements/ . The full cosmological interpretation of these measurements can be found here: https://sdss.org/science/cosmology-results-from-eboss/
- Published
- 2020
- Full Text
- View/download PDF
36. The Completed SDSS-IV Extended Baryon Oscillation Spectroscopic Survey: N-body Mock Challenge for the Quasar Sample
- Author
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Smith, Alex, Burtin, Etienne, Hou, Jiamin, Neveux, Richard, Ross, Ashley J., Alam, Shadab, Brinkmann, Jonathan, Dawson, Kyle S., Habib, Salman, Heitmann, Katrin, Kneib, Jean-Paul, Lyke, Brad W., Bourboux, Hélion du Mas des, Mueller, Eva-Maria, Myers, Adam D., Percival, Will J., Rossi, Graziano, Schneider, Donald P., Zarrouk, Pauline, and Zhao, Gong-Bo
- Subjects
Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
The growth rate and expansion history of the Universe can be measured from large galaxy redshift surveys using the Alcock-Paczynski effect. We validate the Redshift Space Distortion models used in the final analysis of the Sloan Digital Sky Survey (SDSS) extended Baryon Oscillation Spectroscopic Survey (eBOSS) Data Release 16 quasar clustering sample, in configuration and Fourier space, using a series of HOD mock catalogues generated using the OuterRim N-body simulation. We test three models on a series of non-blind mocks, in the OuterRim cosmology, and blind mocks, which have been rescaled to new cosmologies, and investigate the effects of redshift smearing and catastrophic redshifts. We find that for the non-blind mocks, the models are able to recover $f\sigma_8$ to within 3% and $\alpha_\parallel$ and $\alpha_\bot$ to within 1%. The scatter in the measurements is larger for the blind mocks, due to the assumption of an incorrect fiducial cosmology. From this mock challenge, we find that all three models perform well, with similar systematic errors on $f\sigma_8$, $\alpha_\parallel$ and $\alpha_\bot$ at the level of $\sigma_{f\sigma_8}=0.013$, $\sigma_{\alpha_\parallel}=0.012$ and $\sigma_{\alpha_\bot}=0.008$. The systematic error on the combined consensus is $\sigma_{f\sigma_8}=0.011$, $\sigma_{\alpha_\parallel}=0.008$ and $\sigma_{\alpha_\bot}=0.005$, which is used in the final DR16 analysis. For BAO fits in configuration and Fourier space, we take conservative systematic errors of $\sigma_{\alpha_\parallel}=0.010$ and $\sigma_{\alpha_\bot}=0.007$., Comment: 25 pages, 17 figures, 8 tables, updated to match the version accepted for publication in MNRAS. A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found here: https://sdss.org/science/final-bao-and-rsd-measurements/. The full cosmological interpretation of these measurements can be found here: https://sdss.org/science/cosmology-results-from-eboss/
- Published
- 2020
- Full Text
- View/download PDF
37. The Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: measurement of the BAO and growth rate of structure of the luminous red galaxy sample from the anisotropic power spectrum between redshifts 0.6 and 1.0
- Author
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Gil-Marín, Héctor, Bautista, Julián E., Paviot, Romain, Vargas-Magaña, Mariana, de la Torre, Sylvain, Fromenteau, Sebastien, Alam, Shadab, Ávila, Santiago, Burtin, Etienne, Chuang, Chia-Hsun, Dawson, Kyle S., Hou, Jiamin, de Mattia, Arnaud, Mohammad, Faizan G., Müller, Eva-Maria, Nadathur, Seshadri, Neveux, Richard, Percival, Will J., Raichoor, Anand, Rezaie, Mehdi, Ross, Ashley J., Rossi, Graziano, Ruhlmann-Kleider, Vanina, Smith, Alex, Tamone, Amélie, Tinker, Jeremy L., Tojeiro, Rita, Wang, Yuting, Zhao, Gong-Bo, Zhao, Cheng, Brinkmann, Jonathan, Brownstein, Joel R., Choi, Peter D., Escoffier, Stephanie, de la Macorra, Axel, Moon, Jeongin, Newman, Jeffrey A., Schneider, Donald P., Seo, Hee-Jong, and Vivek, Mariappan
- Subjects
Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We analyse the clustering of the Sloan Digital Sky Survey IV extended Baryon Oscillation Spectroscopic Survey Data Release 16 luminous red galaxy sample (DR16 eBOSS LRG) in combination with the high redshift tail of the Sloan Digital Sky Survey III Baryon Oscillation Spectroscopic Survey Data Release 12 (DR12 BOSS CMASS). We measure the redshift space distortions (RSD) and also extract the longitudinal and transverse baryonic acoustic oscillation (BAO) scale from the anisotropic power spectrum signal inferred from 377,458 galaxies between redshifts 0.6 and 1.0, with effective redshift of $z_{\rm eff}=0.698$ and effective comoving volume of $2.72\,{\rm Gpc}^3$. After applying reconstruction we measure the BAO scale and infer $D_H(z_{\rm eff})/r_{\rm drag} = 19.30\pm 0.56$ and $D_M(z_{\rm eff})/r_{\rm drag} =17.86 \pm 0.37$. When we perform a redshift space distortions analysis on the pre-reconstructed catalogue on the monopole, quadrupole and hexadecapole we find, $D_H(z_{\rm eff})/r_{\rm drag} = 20.18\pm 0.78$, $D_M(z_{\rm eff})/r_{\rm drag} =17.49 \pm 0.52$ and $f\sigma_8(z_{\rm eff})=0.454\pm0.046$. We combine both sets of results along with the measurements in configuration space of \cite{LRG_corr} and report the following consensus values: $D_H(z_{\rm eff})/r_{\rm drag} = 19.77\pm 0.47$, $D_M(z_{\rm eff})/r_{\rm drag} = 17.65\pm 0.30$ and $f\sigma_8(z_{\rm eff})=0.473\pm 0.044$, which are in full agreement with the standard $\Lambda$CDM and GR predictions. These results represent the most precise measurements within the redshift range $0.6\leq z \leq 1.0$ and are the culmination of more than 8 years of SDSS observations., Comment: 41 pages, 20 figures; Minor updates to match the published version in MNRAS. A summary of all SDSS BAO and RSD measurements with accompanying legacy figures can be found here: https://www.sdss.org/science/final-bao-and-rsd-measurements/ . The full cosmological interpretation of these measurements can be found here: https://www.sdss.org/science/cosmology-results-from-eboss/
- Published
- 2020
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- View/download PDF
38. Influence of Water Vapor on the Interaction Between Dodecane Thiol Ligated Au Nanoparticles
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Martinez, Michael N., Smith, Alex G., Jin, Miaochen, Slater, Kevin B., Nowack, Linsey M., Lin, Binhua, and Rice, Stuart A.
- Subjects
Condensed Matter - Soft Condensed Matter ,Condensed Matter - Mesoscale and Nanoscale Physics - Abstract
It is well-known that the interaction between passivated nanoparticles can be tuned by their complete immersion in a chosen solvent, such as water. What remains unclear on a molecular level is how nanoparticle interactions may be altered in the presence of solvent vapor where complete immersion is not achieved. In this paper, we report an all-atom molecular dynamics simulation study of the change in pair potential of mean force between dodecane thiol ligated gold nanoparticles (AuNPs) when exposed to water vapor. With the equilibrium vapor pressure of water at 25 \degree C, there is very rapid condensation of water molecules onto the surface of the AuNPs in the form of mobile clusters of 100-2000 molecules that eventually coalesce into a few large clusters. When the distance between two AuNPs decreases, a water cluster bridging them provides an adhesive force that increases the depth and alters the shape of the pair-potential of mean force. That change of shape includes a decreased curvature near the minimum, consistent with experimental data showing that cyclic exposure to water vapor and its removal reversibly decreases and increases the Young's modulus of a freely suspended self-assembled monolayer of these AuNPs., Comment: 26 pages, 11 figures. Accepted for publication in JCP
- Published
- 2020
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39. On the Convergence of the Dynamic Inner PCA Algorithm
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Shin, Sungho, Smith, Alex D., Qin, S. Joe, and Zavala, Victor M.
- Subjects
Electrical Engineering and Systems Science - Systems and Control ,Computer Science - Machine Learning ,Statistics - Machine Learning - Abstract
Dynamic inner principal component analysis (DiPCA) is a powerful method for the analysis of time-dependent multivariate data. DiPCA extracts dynamic latent variables that capture the most dominant temporal trends by solving a large-scale, dense, and nonconvex nonlinear program (NLP). A scalable decomposition algorithm has been recently proposed in the literature to solve these challenging NLPs. The decomposition algorithm performs well in practice but its convergence properties are not well understood. In this work, we show that this algorithm is a specialized variant of a coordinate maximization algorithm. This observation allows us to explain why the decomposition algorithm might work (or not) in practice and can guide improvements. We compare the performance of the decomposition strategies with that of the off-the-shelf solver Ipopt. The results show that decomposition is more scalable and, surprisingly, delivers higher quality solutions.
- Published
- 2020
40. Application of fluorescent dextrans to the brain surface under constant pressure reveals AQP4-independent solute uptake
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Smith, Alex J, Akdemir, Gokhan, Wadhwa, Meetu, Song, Dan, and Verkman, Alan S
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Neurosciences ,Brain Disorders ,1.1 Normal biological development and functioning ,Underpinning research ,Neurological ,Animals ,Aquaporin 4 ,Biological Transport ,Brain ,Dextrans ,Extracellular Fluid ,Mice ,Physiology ,Medical Physiology - Abstract
Extracellular solutes in the central nervous system are exchanged between the interstitial fluid, the perivascular compartment, and the cerebrospinal fluid (CSF). The "glymphatic" mechanism proposes that the astrocyte water channel aquaporin-4 (AQP4) is a major determinant of solute transport between the CSF and the interstitial space; however, this is controversial in part because of wide variance in experimental data on interstitial uptake of cisternally injected solutes. Here, we investigated the determinants of solute uptake in brain parenchyma following cisternal injection and reexamined the role of AQP4 using a novel constant-pressure method. In mice, increased cisternal injection rate, which modestly increased intracranial pressure, remarkably increased solute dispersion in the subarachnoid space and uptake in the cortical perivascular compartment. To investigate the role of AQP4 in the absence of confounding variations in pressure and CSF solute concentration over time and space, solutes were applied directly onto the brain surface after durotomy under constant external pressure. Pressure elevation increased solute penetration into the perivascular compartment but had little effect on parenchymal solute uptake. Solute penetration and uptake did not differ significantly between wild-type and AQP4 knockout mice. Our results offer an explanation for the variability in cisternal injection studies and indicate AQP4-independent solute transfer from the CSF to the interstitial space in mouse brain.
- Published
- 2021
41. Measuring the BAO peak position with different galaxy selections
- Author
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Hernández-Aguayo, César, Cautun, Marius, Smith, Alex, Baugh, Carlton M., and Li, Baojiu
- Subjects
Astrophysics - Cosmology and Nongalactic Astrophysics - Abstract
We investigate if, for a fixed number density of targets and redshift, there is an optimal way to select a galaxy sample in order to measure the baryon acoustic oscillation (BAO) scale, which is used as a standard ruler to constrain the cosmic expansion. Using the mock galaxy catalogue built by Smith et al. in the Millennium-XXL N-body simulation with a technique to assign galaxies to dark matter haloes based on halo occupation distribution modelling, we consider the clustering of galaxies selected by luminosity, colour and local density. We assess how well the BAO scale can be extracted by fitting a template to the power spectrum measured for each sample. We find that the BAO peak position is recovered equally well for samples defined by luminosity or colour, while there is a bias in the BAO scale recovered for samples defined by density. The BAO position is contracted to smaller scales for the densest galaxy quartile and expanded to large scales for the two least dense galaxy quartiles. For fixed galaxy number density, density-selected samples have higher uncertainties in the recovered BAO scale than luminosity- or colour-selected samples., Comment: 11 pages, 8 figures, 1 table, submitted to MNRAS
- Published
- 2019
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42. First Principles Studies of Structural, Molecular Adsorption, and Spectroscopic Properties of Metal-Organic Frameworks
- Author
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Smith, Alex
- Subjects
Condensed matter physics ,Computational physics ,Physical chemistry ,Adsorption ,DFT ,GW/BSE ,MOFs ,Optical Properties - Abstract
Metal-organic frameworks (MOFs) are a class of crystalline materials with broad diversity in their chemical compositions and geometries which give rise to a high degree of tunability of their properties, and many possible applications. Because a broad range of synthetic modifications to MOFs are possible, computational methods are invaluable in guiding experimental studies to understand the relationship between a given structure and chemistry and its material properties. In this work, we use first principles electronic structure calculations to calculate low energy geometries, nuclear magnetic resonance (NMR) chemical shifts, and binding energetics of MOFs that adsorb CO$_2$ and O$_2$. Our calculations explain experiments indicating that the presence of SO$_2$ degrades the performance of diamine-appended Mg$_2$(dobpdc), a promising class of MOF for carbon capture, with some appended diamines but not others. Additionally, we show that we can capture trends in O$_2$ binding in a computationally challenging family of MOFs, the BTTri MOFs, that contain open-shell transition metal atoms. We predict that by modifying the halide in BTTri we can obtain binding energies that are ideal for industrial separations of O$_2$. In order to better understand the mechanism of cooperative CO$_2$ adsorption in diamine-appended Mg$_2$(dobpdc), we extend a statistical mechanics model to understand the role of defects, steric hindrance, and mixtures of diamines on CO$_2$ adsorption isotherms and isobars. This work shows that cooperative uptake is robust in the presence of defects as long as the cooperative interaction which promotes CO$_2$ binding at adjacent diamine sites is sufficiently strong. We also rationalize experimentally observed double stepped isotherms, and develop a way of understanding how the ratio of mixed diamine systems can be chosen to target a specific pressure at which CO$_2$ will be bound to the MOF.We benchmark the performance of van der Waals corrected density functionals in layered MOFs and layered perovskites, showing that recently developed functionals are able to accurately predict lattice constants for hybrid layered materials. Our calculations also highlight the impact of the lattice constants on calculated observables like the exfoliation energy and the fundamental gap, and demonstrate that care must be taken in including van der Waals corrections in these challenging systems.Finally, with ab initio many-body perturbation theory we predict the structure and spectroscopic properties of Zn-MFU-4l including electron-hole interactions and accounting for zero-point vibrational effects, and show how modifications to the anion in the framework can reduce both the fundamental gap and the optical gap, and we provide an explanation for previously seen trends in optical experiments on Zn-MFU-4l.
- Published
- 2024
43. Technical change in the greenhouse tomato producing industry
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Smith, Alex W
- Published
- 2001
44. Completed SDSS-IV extended Baryon Oscillation Spectroscopic Survey: Cosmological implications from two decades of spectroscopic surveys at the Apache Point Observatory
- Author
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Alam, Shadab, Aubert, Marie, Avila, Santiago, Balland, Christophe, Bautista, Julian E, Bershady, Matthew A, Bizyaev, Dmitry, Blanton, Michael R, Bolton, Adam S, Bovy, Jo, Brinkmann, Jonathan, Brownstein, Joel R, Burtin, Etienne, Chabanier, Solène, Chapman, Michael J, Choi, Peter Doohyun, Chuang, Chia-Hsun, Comparat, Johan, Cousinou, Marie-Claude, Cuceu, Andrei, Dawson, Kyle S, de la Torre, Sylvain, de Mattia, Arnaud, de Sainte Agathe, Victoria, du Mas des Bourboux, Hélion, Escoffier, Stephanie, Etourneau, Thomas, Farr, James, Font-Ribera, Andreu, Frinchaboy, Peter M, Fromenteau, Sebastien, Gil-Marín, Héctor, Le Goff, Jean-Marc, Gonzalez-Morales, Alma X, Gonzalez-Perez, Violeta, Grabowski, Kathleen, Guy, Julien, Hawken, Adam J, Hou, Jiamin, Kong, Hui, Parker, James, Klaene, Mark, Kneib, Jean-Paul, Lin, Sicheng, Long, Daniel, Lyke, Brad W, de la Macorra, Axel, Martini, Paul, Masters, Karen, Mohammad, Faizan G, Moon, Jeongin, Mueller, Eva-Maria, Muñoz-Gutiérrez, Andrea, Myers, Adam D, Nadathur, Seshadri, Neveux, Richard, Newman, Jeffrey A, Noterdaeme, Pasquier, Oravetz, Audrey, Oravetz, Daniel, Palanque-Delabrouille, Nathalie, Pan, Kaike, Paviot, Romain, Percival, Will J, Pérez-Ràfols, Ignasi, Petitjean, Patrick, Pieri, Matthew M, Prakash, Abhishek, Raichoor, Anand, Ravoux, Corentin, Rezaie, Mehdi, Rich, James, Ross, Ashley J, Rossi, Graziano, Ruggeri, Rossana, Ruhlmann-Kleider, Vanina, Sánchez, Ariel G, Sánchez, F Javier, Sánchez-Gallego, José R, Sayres, Conor, Schneider, Donald P, Seo, Hee-Jong, Shafieloo, Arman, Slosar, Anže, Smith, Alex, Stermer, Julianna, Tamone, Amelie, Tinker, Jeremy L, Tojeiro, Rita, Vargas-Magaña, Mariana, Variu, Andrei, Wang, Yuting, Weaver, Benjamin A, Weijmans, Anne-Marie, Yèche, Christophe, Zarrouk, Pauline, Zhao, Cheng, Zhao, Gong-Bo, and Zheng, Zheng
- Subjects
Particle and High Energy Physics ,Physical Sciences ,astro-ph.CO - Abstract
We present the cosmological implications from final measurements of clustering using galaxies, quasars, and Lyα forests from the completed Sloan Digital Sky Survey (SDSS) lineage of experiments in large-scale structure. These experiments, composed of data from SDSS, SDSS-II, BOSS, and eBOSS, offer independent measurements of baryon acoustic oscillation (BAO) measurements of angular-diameter distances and Hubble distances relative to the sound horizon, rd, from eight different samples and six measurements of the growth rate parameter, fσ8, from redshift-space distortions (RSD). This composite sample is the most constraining of its kind and allows us to perform a comprehensive assessment of the cosmological model after two decades of dedicated spectroscopic observation. We show that the BAO data alone are able to rule out dark-energy-free models at more than eight standard deviations in an extension to the flat, ΛCDM model that allows for curvature. When combined with Planck Cosmic Microwave Background (CMB) measurements of temperature and polarization, under the same model, the BAO data provide nearly an order of magnitude improvement on curvature constraints relative to primary CMB constraints alone. Independent of distance measurements, the SDSS RSD data complement weak lensing measurements from the Dark Energy Survey (DES) in demonstrating a preference for a flat ΛCDM cosmological model when combined with Planck measurements. The combined BAO and RSD measurements indicate σ8=0.85±0.03, implying a growth rate that is consistent with predictions from Planck temperature and polarization data and with General Relativity. When combining the results of SDSS BAO and RSD, Planck, Pantheon Type Ia supernovae (SNe Ia), and DES weak lensing and clustering measurements, all multiple-parameter extensions remain consistent with a ΛCDM model. Regardless of cosmological model, the precision on each of the three parameters, ωΛ, H0, and σ8, remains at roughly 1%, showing changes of less than 0.6% in the central values between models. In a model that allows for free curvature and a time-evolving equation of state for dark energy, the combined samples produce a constraint ωk=-0.0022±0.0022. The dark energy constraints lead to w0=-0.909±0.081 and wa=-0.49-0.30+0.35, corresponding to an equation of state of wp=-1.018±0.032 at a pivot redshift zp=0.29 and a Dark Energy Task Force Figure of Merit of 94. The inverse distance ladder measurement under this model yields H0=68.18±0.79 km s-1 Mpc-1, remaining in tension with several direct determination methods; the BAO data allow Hubble constant estimates that are robust against the assumption of the cosmological model. In addition, the BAO data allow estimates of H0 that are independent of the CMB data, with similar central values and precision under a ΛCDM model. Our most constraining combination of data gives the upper limit on the sum of neutrino masses at mν
- Published
- 2021
45. Offensive prowess proves insufficient as Princeton Football falls to Yale 42-28
- Author
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Beverton-Smith, Alex
- Subjects
Football teams ,News, opinion and commentary ,Sports and fitness - Abstract
Byline: Alex Beverton-Smith In a touchdown shootout match, the Tigers (2-7 overall, 1-5 Ivy League) ultimately fell short in the 146th contest against Yale (6-3, 3-3) 42-28. The Tigers came [...]
- Published
- 2024
46. Men's basketball overcomes Northeastern 79-76 in close-fought struggle
- Author
-
Beverton-Smith, Alex
- Subjects
News, opinion and commentary ,Sports and fitness - Abstract
Byline: Alex Beverton-Smith The Tigers (3--0 overall, 0--0 Ivy League) were back in action on Sunday afternoon against the Northeastern Huskies (1--1 overall, 0--0 Colonial), prevailing 79--76 in yet another [...]
- Published
- 2024
47. Football comes up short 26-17 against Dartmouth despite second half rally
- Author
-
Beverton-Smith, Alex
- Subjects
Football teams - Abstract
Byline: Alex Beverton-Smith A small but lively crowd saw the Tigers (2-6 overall, 1-4 Ivy League) narrowly lose to the Dartmouth Big Green (7-1, 4-1) on a cold Friday night [...]
- Published
- 2024
48. Defensive display gives Princeton football 29-17 victory against Brown
- Author
-
Beverton-Smith, Alex
- Subjects
Football ,News, opinion and commentary ,Sports and fitness - Abstract
Byline: Alex Beverton-Smith Princeton Football (2-3 overall, 1-1 Ivy League) put on a strong defensive display with five turnovers to secure victory against the Brown Bears (2-3, 1-1) over the [...]
- Published
- 2024
49. Men's soccer secures consecutive victory in close fought contest against Monmouth
- Author
-
Beverton-Smith, Alex
- Subjects
Soccer ,News, opinion and commentary ,Sports and fitness - Abstract
Byline: Alex Beverton-Smith On a cool Tuesday evening at Roberts Stadium, Princeton men's soccer (4--3 overall, 1--0 Ivy League) kept a consecutive clean sheet in a 1--0 victory against the [...]
- Published
- 2024
50. 'Not an accomplishment, but a responsibility': Princeton Football names captains
- Author
-
Beverton-Smith, Alex
- Subjects
Lehigh University - Abstract
Byline: Alex Beverton-Smith Following weeks of fall practice.Princeton Football announced their captains for the 2024 football season. With an opening game against Lehigh University less than one week away on [...]
- Published
- 2024
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