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We report on a detailed analysis of the transport properties and superconducting critical temperatures of boron-doped diamond films grown along the {100} direction. The system presents a metal-insulator transition (MIT) for a boron concentration (nB) on the order of nc~4.5×1020 cm−3, in excellent agreement with numerical calculations. The temperature dependence of the conductivity and Hall effect can be well described by variable range hopping for nBnc) present a superconducting transition at low temperature. The zero-temperature conductivity 0 deduced from fits to the data above the critical temperature (Tc) using a classical quantum interference formula scales as 0(nB/nc−1) with ~1. Large Tc values (0.4 K) have been obtained for boron concentration down to nB/nc~1.1 and Tc surprisingly mimics a (nB/nc−1)1/2 law. Those high Tc values can be explained by a slow decrease of the electron-phonon coupling parameter and a corresponding drop of the Coulomb pseudopotential µ* as nBnc. Original Publication:T. Klein, P. Achatz, J. Kacmarcik, C. Marcenat, F. Gustafsson, J. Marcus, E. Bustarret, J. Pernot, F. Omnes, Bo Sernelius, C. Persson, A. Ferreira da Silva and C. Cytermann, Metal-insulator transition and superconductivity in boron-doped diamond, 2007, Physical Review B. Condensed Matter and Materials Physics, (75), 165313.http://dx.doi.org/10.1103/PhysRevB.75.165313Copyright: American Physical Societyhttp://www.aps.org/

International audience; U–Pb ages of zircons recovered from Pliocene pyroclastic deposits in northern part of the Cenozoic intra-Carpathian back-arc basin (Pannonian Basin) span the interval from Pliocene (2.2 Ma) to Paleoproterozoic (Orosirian–Rhyacian, 1850–2115 Ma). The scattered U–Pb ages reflect eruption ages of the host basaltic volcanic centres, two episodes of post-Eocene magmatic crustal growth, and the possible tectonic affiliation, provenance and age of the subjacent basement or the sedimentary basin detritus sampled by the basaltic magma. The youngest zircons define the maximum ages of phreatomagmatic eruptions during the Late Miocene–Pliocene extension. These zircons are distinguished from older zircons by Zr/Hf (40–90) and Th/U ratios (0.5–4.5) as well as super-chondritic εHf(t) values ranging from + 7 to + 14, indicating mantle-derived parental magmas. The locally increased Th/U ratios (up to 8) accompanied by Zr/Hf > 60 are diagnostic of evolved phonolite parental melt. Hence, the youngest zircons can be interpreted as antecrysts, originating from evolved melts cogenetic with the host alkali basalts. In contrast, older zircons represent xenocrysts scavenged by the uprising basalt from surrounding rocks. Subordinate Eocene–Early Oligocene (29–38 Ma) sub-group of zircon xenocrysts is coincidental with the magmatism and volcanism along the Periadriatic lineament and the middle-Hungarian zone. The Early Miocene (18 Ma) cluster is coeval with the deposition of the Bükk Mountains felsic ignimbrite correlated with the onset of the back-arc extension that triggered Miocene sedimentation within the Pannonian Basin. The Eocene–Early Oligocene zircons have been likely scavenged from pyroclastic and ash-fall deposits of the Palaeogene retroarc basin subjacent to the Miocene basin infilling. Sub-chondritic εHf(t) values between − 2.5 and − 8 in the Eocene–Early Miocene zircons attest their crystallization from subduction-related felsic-to-intermediate melts containing large amounts of recycled crustal material. Palaeozoic–Proterozoic zircons create a heterogeneous population with variable trace element abundances and εHf(t) values. The determined age clusters are reminiscent of some basement units cropping out recently in Central Western Carpathians. Zircon Hf isotope data indicate recycling of up to 3.4 Ga old mafic crust and also the presence of 2 Ga old juvenile mafic crust. These units had either underlain the northern part of the Pannonian Basin during Pliocene or had been exposed during the deposition of Miocene clastic sediments. The absence of Mesoproterozoic, Grenvillian zircons (0.9–1.8 Ga) in the pre-Cenozoic population of zircon xenocrysts is provisionally interpreted as indicating the evolution of the zircon source area within the west-African Craton.

International audience; Anorogenic granite xenoliths occur in alkali basalts coeval with the Pliocene–Pleistocene continental rifting of the Pannonian Basin. Observed granite varie - ties include peraluminous, calcic to peralkalic, magnesian to ferroan types. Quartz and feldspars are dominant rock-forming minerals, accompanied by minor early ilmenite and late magnetite–ulvöspinel. Zircon and Nb–U–REE minerals (oxycalciopyrochlore, fergusonite, columbite) are locally abundant accessory phases in calc-alkalic types. Absence of OH-bearing Fe, Mg-silicates and presence of single homogeneous feldspars (plagioclase in calcic types, anorthoclase in calc-alkalic types, ferrian Na-sanidine to anorthoclase in alkalic types) indicate water-deficient, hypersolvus crystallization conditions. Variable volumes of interstitial glass, absence of exsolutions, and lacking deu-teric hydrothermal alteration and/or metamorphic/meta -somatic overprint are diagnostic of rapid quenching from hypersolidus temperatures. U–Pb zircon ages determined in calcic and calc-alkalic granite xenoliths correspond to a time interval between 5.7 and 5.2 Ma. Positive εHf val -ues (14.2± 3.9) in zircons from a 5.2-Ma-old calc-alkalic granite xenolith indicate mantle-derived magmas largely unaffected by the assimilation of crustal material. This is in accordance with abundances of diagnostic trace elements (Rb, Y, Nb, Ta), indicating A1-type, OIB-like source mag-mas. Increased accumulations of Nb–U–REE minerals in these granites indicate higher degree of the magmatic dif-ferentiation reflected in Rb-enrichment, contrasting with Ba-enrichment in barren xenoliths. Incipient charnock-itization, i.e. orthopyroxene and ilmenite crystallization from interstitial silicate melt, was observed in many granite xenoliths. Thermodynamic modeling using pseudosections showed that the orthopyroxene growth may have been trig-gered by water exsolution from the melt during ascent of xenoliths in basaltic magma. Euhedral-to-skeletal orthopy-roxene growth probably reflects contrasting ascent rates of basaltic magma with xenoliths, intermitted by the stagna-tion in various crustal levels at a

Background The understanding of enzymatic polysaccharide degradation has progressed intensely in the past few years with the identification of a new class of fungal-secreted enzymes, the lytic polysaccharide monooxygenases (LPMOs) that enhance cellulose conversion. In the fungal kingdom, saprotrophic fungi display a high number of genes encoding LPMOs from family AA9 but the functional relevance of this redundancy is not fully understood. Results In this study, we investigated a set of AA9 LPMOs identified in the secretomes of the coprophilous ascomycete Podospora anserina, a biomass degrader of recalcitrant substrates. Their activity was assayed on cellulose in synergy with the cellobiose dehydrogenase from the same organism. We showed that the total release of oxidized oligosaccharides from cellulose was higher for PaLPMO9A, PaLPMO9E, and PaLPMO9H that harbored a carbohydrate-binding module from the family CBM1. Investigation of their regioselective mode of action revealed that PaLPMO9A and PaLPMO9H oxidatively cleaved at both C1 and C4 positions while PaLPMO9E released only C1-oxidized products. Rapid cleavage of cellulose was observed using PaLPMO9H that was the most versatile in terms of substrate specificity as it also displayed activity on cello-oligosaccharides and β-(1,4)-linked hemicellulose polysaccharides (e.g., xyloglucan, glucomannan). Conclusions This study provides insights into the mode of cleavage and substrate specificities of fungal AA9 LPMOs that will facilitate their application for the development of future biorefineries. Electronic supplementary material The online version of this article (doi:10.1186/s13068-015-0274-3) contains supplementary material, which is available to authorized users.

Brachiopod shells are the most widely used geological archive for the reconstruction of the temperature and the oxygen isotope composition of Phanerozoic seawater. However, it is not conclusive whether brachiopods precipitate their shells in thermodynamic equilibrium. In this study, we investigated the potential impact of kinetic controls on the isotope composition of modern brachiopods by measuring the oxygen and clumped isotope compositions of their shells. Our results show that clumped and oxygen isotope compositions depart from thermodynamic equilibrium due to growth rate-induced kinetic effects. These departures are in line with incomplete hydration and hydroxylation of dissolved CO2. These findings imply that the determination of taxon-specific growth rates alongside clumped and bulk oxygen isotope analyses is essential to ensure accurate estimates of past ocean temperatures and seawater oxygen isotope compositions from brachiopods.