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United States (US) background ozone (O3) is the counterfactual O3 that would exist with zero US anthropogenic emissions. Estimates of US background O3 typically come from chemical transport models (CTMs), but different models vary in their estimates of both background and total O3. Here, a measurement–model data fusion approach is used to estimate CTM biases in US anthropogenic O3 and multiple US background O3 sources, including natural emissions, long-range international emissions, short-range international emissions from Canada and Mexico, and stratospheric O3. Spatially and temporally varying bias correction factors adjust each simulated O3 component so that the sum of the adjusted components evaluates better against observations compared to unadjusted estimates. The estimated correction factors suggest a seasonally consistent positive bias in US anthropogenic O3 in the eastern US, with the bias becoming higher with coarser model resolution and with higher simulated total O3, though the bias does not increase much with higher observed O3. Summer average US anthropogenic O3 in the eastern US was estimated to be biased high by 2, 7, and 11 ppb (11 %, 32 %, and 49 %) for one set of simulations at 12, 36, and 108 km resolutions and 1 and 6 ppb (10 % and 37 %) for another set of simulations at 12 and 108 km resolutions. Correlation among different US background O3 components can increase the uncertainty in the estimation of the source-specific adjustment factors. Despite this, results indicate a negative bias in modeled estimates of the impact of stratospheric O3 at the surface, with a western US spring average bias of - 3.5 ppb (- 25 %) estimated based on a stratospheric O3 tracer. This type of data fusion approach can be extended to include data from multiple models to leverage the strengths of different data sources while reducing uncertainty in the US background ozone estimates. [ABSTRACT FROM AUTHOR]

Formaldehyde (HCHO) is an important air pollutant with direct cancer risk and ozone-forming potential. HCHO sources are complex because HCHO is both directly emitted and produced from oxidation of most gas-phase reactive organic carbon. We update the secondary production of HCHO in the Community Regional Atmospheric Chemistry Multiphase Mechanism (CRACMM) in the Community Multiscale Air Quality (CMAQ) model. Production of HCHO from isoprene and monoterpenes is increased, correcting an underestimate in the current version. Simulated June–August surface HCHO during peak photochemical production (11:00–15:00 LT, local time) increased by 0.6 ppb (32 %) over the southeastern USA and by 0.2 ppb (13 %) over the contiguous USA. The increased HCHO compares more favorably with satellite-based observations from the TROPOspheric Monitoring Instrument (TROPOMI) and from aircraft-based observations. Evaluation against hourly surface observations indicates a missing nighttime sink that can be improved by increased nighttime deposition, which reduces June–August nocturnal (20:00–04:00 LT) surface HCHO by 1.1 ppb (36 %) over the southeastern USA and 0.5 ppb (29 %) over the contiguous USA. The ability of CRACMM to capture peak levels of HCHO at midday is improved, particularly at sites in the northeastern USA, while peak levels at sites in the southeastern USA are improved, although still lower than observed. Using established risk assessment methods, lifetime exposure of the population in the contiguous USA (∼ 320 million) to ambient HCHO levels predicted here may result in 6200 lifetime cancer cases, with 40 % from controllable anthropogenic emissions of nitrogen oxides and reactive organic compounds. Chemistry updates will be available in CRACMM version 2 (CRACMM2) in CMAQv5.5. [ABSTRACT FROM AUTHOR]

United States (US) background ozone (O3) is the counterfactual O3 that would exist with zero US anthropogenic emissions. Estimates of US background O3 typically come from chemical transport models (CTMs), but different models vary in their estimates of both background and total O3. Here, a measurement-model data fusion approach is used to estimate CTM biases in US anthropogenic O3 and multiple US background O3 sources, including natural emissions, long-range international emissions, short-range international emissions from Canada and Mexico, and stratospheric O3. Spatially and temporally varying bias correction factors adjust each simulated O3 component so that the sum of the adjusted components evaluates better against observations compared to unadjusted estimates. The estimated correction factors suggest a seasonally consistent positive bias in US anthropogenic O3 in the eastern US, with the bias becoming higher with coarser model resolution and with higher simulated total O3 though the bias does not increase much with higher observed O3. Correlation among different US background O3 components can increase the uncertainty in the estimation of the source-specific adjustment factors. Despite this, results indicate that there may be a negative bias in modeled estimates of the impact of stratospheric O3 at the surface. This type of data fusion approach can be extended to include data from multiple models to leverage the strengths of different data sources while reducing uncertainty in the US background ozone estimates. [ABSTRACT FROM AUTHOR]