Search

To select drought-resistant and dust-tolerant native species suitable for use in the rehabilitation of major coal bases in northwest China, nine tree species were identified for growth rates, biomass, harm index, and physiological indices under drought and high dust stress conditions. The results showed that, in the dust resistance index system, the order was Caragana korshinskii > Amorpha fruticosa > Sabina vulgaris > Hedysarum scoparium > Tamarix chinensis > Ammopiptanthus mongolicus > Ulmus pumila > Caryopteris mongholica > Elaeagnus angustifolia. In a comprehensive drought and dust resistance index system, 14 indices (such as shoot length, stomatal conductance, and peroxidase) had the larger weight indices. The drought and dust resistance order of the tree species was Caragana korshinskii > Ulmus pumila > Amorpha fruticosa > Sabina vulgaris > Caryopteris mongholica > Ammopiptanthus mongolicus > Hedysarum scoparium > Tamarix chinensis > Elaeagnus angustifolia. This study provides effective strategies and references for selecting suitable tree species for arid mining sites in China, and also for the revegetation of coal mining sites worldwide.

To tailor the properties and enhance the applicability of starch, various ways of starch modification have been practiced. Among them, physical modification methods (micronization, nonthermal plasma, high-pressure, ultrasonication, pulsed electric field, and γ-irradiation) are highly potential for starch modification considering its safety, environmentally friendliness, and cost-effectiveness, without generating chemical wastes. Thus, this article provides an overview of the recent advances in nonthermal physical modification of starch and summarizes the resulting changes in the multi-level structures and physicochemical properties. While the effect of these techniques highly depends on starch type and treatment condition, they generally lead to the destruction of starch granules, the degradation of molecules, decreases in crystallinity, gelatinization temperatures, and viscosity, increases in solubility and swelling power, and an increase or decrease in digestibility, to different extents. The advantages and shortcomings of these techniques in starch processing are compared, and the knowledge gap in this area is commented on.

The development of high-efficiency and durable bifunctional electrocatalysts for both the oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) is critical for the widespread application of rechargeable zinc-air (Zn-air) batteries. This calls for rational screening of targeted ORR/OER components and precise control of their atomic and electronic structures to produce synergistic effects. Here, we report a Mn-doped RuO

Ultralong carbon nanotubes (CNTs) are in huge demand in many cutting-edge fields due to their macroscale lengths, perfect structures, and extraordinary properties, while their practical application is limited by the difficulties in their mass production. Herein, we report the synthesis of ultralong CNTs with a dramatically increased yield by a simple but efficient substrate interception and direction strategy (SIDS), which couples the advantages of floating-catalyst chemical vapor deposition with the flying-kite-like growth mechanism of ultralong CNTs. The SIDS-assisted approach prominently improves the catalyst utilization and significantly increases the yield. The areal density of the ultralong CNT arrays with length of over 1 cm reached a record-breaking value of ∼6700 CNTs mm

Designing high-performance trifunctional electrocatalysts for ORR/OER/HER with outstanding activity and stability for each reaction is quite significant yet challenging for renewable energy technologies. Herein, a highly efficient and durable trifunctional electrocatalyst RuCoOx is prepared by a unique one-pot glucose-blowing approach. Remarkably, RuCoOx catalyst exhibits a small potential difference (ΔE) of 0.65 V and low HER overpotential of 37 mV (10 mA cm-2), as well as a negligible decay of overpotential after 200 000/10 000/10 000 CV cycles for ORR/OER/HER, all of which show overwhelming superiorities among the advanced trifunctional electrocatalysts. When used in liquid rechargeable Zn-air batteries and water splitting electrolyzer, RuCoOx exhibits high efficiency and outstanding durability even at quite large current density. Such excellent performance can be attributed to the rational combination of targeted ORR/OER/HER active sites into one electrocatalyst based on the double-phase coupling strategy, which induces sufficient electronic structure modulation and synergistic effect for enhanced trifunctional properties.

Background Starches and proteins are two major types of biopolymer components, especially in many flour (starch)-based foods consumed worldwide, which provide energy and nutrition needed by the human body. In many such starch-based matrices (the main structural component of such foods), proteins and their interactions with starches greatly influence the matrix structure and properties. Studying the different roles played by proteins (endogenous and exogenous) in various starch-based food systems can provide a frame of reference for the design and production of improved starch-based food products with tailored properties and desirable nutritional functions. Scope and approach Significant efforts have recently been made to tailor the morphology, structure, and properties of many starch-based food systems, and thus to design various starch-based food products with satisfactory attributes. This review surveys the latest literature on starch-based matrices containing proteins. Discussed are the influences of proteins and their interactions with starches on the morphologies and structures (e.g. short- and long-range orders) of starch-based matrices, as well as on their pasting, thermal, rheological, textural, sensory, and digestive properties. Also, current understandings of structure–property links are presented, along with their implications on the production of various starchy foods (e.g. pastas, breads, cakes, and biscuits), including gluten-free versions. Key findings and conclusions Proteins in many starchy food matrices can encapsulate the starch phase (or be adsorbed on its surfaces) on a micron scale, and thereby interact with starch chains via both non-covalent (e.g. hydrogen bonding, hydrophobic, and electrostatic) and covalent bonds (e.g. via Maillard reactions). These facts and protein features (e.g. hydration and gelation abilities) can play major roles in inhibiting starch retrogradation (the reassembly of cooked starch chains into ordered structures) and in regulating various other properties of such starch-based matrices, including viscosity, transition temperatures, moduli, hardness, sensory, digestibility, and shelf-life. Despite the fact that the current literature presents considerable information on the structure–property relationships of many different starch-based matrices and their applications in the processing of various starchy foods (e.g. pastas, noodles, and biscuits), it is still highly necessary to define more comprehensive correlations among starch–protein interactions, starch–protein matrix structures, and the resulting properties of such food products.

Expression Quantitative Trait Loci (eQTLs), provide valuable information on the effects of genetic variants. Many methods have been developed to leverage eQTLs to nominate candidate genes of complex traits, including colocalization analysis, transcriptome-wide association studies (TWAS), and Mendelian Randomization (MR)-based methods. All these methods, however, suffer from a key problem: when using the eQTLs of a gene to assess its role in a trait, nearby variants and nearby genetic components of expression of other genes can be correlated with the eQTLs of the test gene, while affecting the trait directly. These “genetic confounders” often lead to false discoveries. We introduced a novel statistical framework to address this challenge. Our method, causal-TWAS (cTWAS), borrowed ideas from statistical fine-mapping, and allowed us to adjust all genetic confounders. In our simulations, we found that existing methods based on TWAS, colocalization or MR all suffered from high false positive rates, often greater than 50%. In contrast, cTWAS showed calibrated false positive rates while maintaining power. Application of cTWAS on several common traits highlighted the weakness of existing methods and discovered novel candidate genes. In conclusion, cTWAS is a novel statistical framework to integrate eQTL and GWAS data, enabling reliable gene discoveries.

Radiative cooling (RC) is a promising sustainable human body cooling technology. However, there still lacks a RC material that can simultaneously enable efficient human body cooling in both outdoor and indoor hot scenarios. Here, we propose a selective emission-transmission (SET) RC model, which is featured with selective high emission in the atmospheric window waveband (8-13 μm) and high transmission in the remaining mid-infrared wavebands, to guide the design of multi-scenario RC materials. Assisted with designs at molecular and nano-scale, we demonstrated a polyoxymethylene (POM) nano-textile, which selectively exhibits high emittance of 75.7% in the 8-13 μm waveband, high human radiation transmittance of 48.5% (4-25 μm), and also a high solar reflectance of 94.7% (0.3-2.5 μm). As a result, the POM nano-textile exhibits superior human body cooling performance in various scenarios including sunny outdoor (2.6-8.8 ℃ cooling), cloudy outdoor (0.7-3.6 ℃ cooling) and indoor (0.5-1.2 ℃ cooling), compared to existing RC materials and commercial cotton. In addition, the POM nano-textile also possesses good wearability. When the POM nano-textile is tailored onto a protective clothing, it provides better cooling performance than its commercial counterpart. This work provides an alternative pathway towards multi-scenario personal thermal management.

This work concerns how starch-protein interplay affects the multi-scale structures (e.g., short- and long-range orders, nanoscale structure and morphology) of starch undergoing thermal processing (pasting) involving heating and cooling at high water content. An indica rice starch (IRS) and three proteins (whey protein isolate, WPI; soy protein isolate, SPI; casein, CS) were used. By inspecting rheological profiles of mixed systems before and after adding chemicals, IRS-WPI and IRS-CS showed mainly hydrophobic molecular interaction; and IRS-SPI exhibited hydrophobic, hydrogen bonding and electrostatic interactions. The RVA results revealed that, with starch and proteins as controls, starch-globular protein (WPI or SPI) interplay accelerated the swelling of starch granules (faster viscosity increase at initial pasting stage), and reduced the paste stability during heating (higher breakdown) and during cooling (higher setback); however, the starch-casein interactions resulted in opposed effects. Moreover, starch-protein interactions varied the multi-scale chain reassembly of starch into different structures during cooling. Observed could be fewer short- and long-range starch orders, and larger nonperiod structure (or colloidal clusters) on the nanoscale. On even larger scale to micron, IRS-globular protein molecules generated larger grids (with reduced number) in the gel network, and IRS-casein formed a more continuous gel network with less prominent tunnel-like features.

Separation of antioxidant peptides from complex food matrix is labor-intensive and time-consuming. The combination of peptidomics and bioinformatics may shorten this process. In this work, the gast...

Carbon nanotubes (CNTs) are promising candidates for numerous cutting-edge fields because of their excellent properties. However, the inherent black color of CNTs cannot satisfy the aesthetic/fashion requirement, and the flammability of CNTs severely restricts their application in high-temperature environments with oxygen. Here, we realized a structural coloration of CNTs by coating them with amorphous TiO 2 layers. By tuning the TiO 2 coating thickness, both CNT fibers and membranes exhibited controllable and brilliant colors, which exhibited remarkable superdurability that could endure 2000 cycles of laundering tests and more than 10 months of high-intensity ultraviolet irradiation. The TiO 2 -coated CNTs exhibited a notable fire-retardant performance and could endure 8 hours of fire burning. The structural coloration of CNTs with excellent fire retardance substantially improves their performance and broadens their applications.

Nowadays, resulting from disordered glucose and lipid metabolism, metabolic diseases (e.g., hyperglycemia, type 2 diabetes, and obesity) are among the most serious health issues facing humans worldwide. Increasing evidence has confirmed that dietary intervention (with healthy foods) is effective at regulating the metabolic syndrome. Whole grain rice (WGR) rich in dietary fiber and many bioactive compounds (e.g., γ-amino butyric acid, γ-oryzanol, and polyphenols) can not only inhibit starch digestion and prevent rapid increase in the blood glucose level, but also reduce oxidative stress and damage to the liver, thereby regulating glucose and lipid metabolism. The rate of starch digestion is directly related to the blood glucose level in the organism after WGR intake. Therefore, the effects of different factors (e.g., additives, cooking, germination, and physical treatments) on WGR starch digestibility are examined in this review. In addition, the mechanisms from human and animal experiments regarding the correlation between the intake of WGR or its products and the lowered blood glucose and lipid levels and the reduced incidence of diabetes and obesity are discussed. Moreover, information on developing WGR products with the health benefits is provided.

Colored brown rice shows better health benefits than polished rice, and there is great interest in the design of demanded cooking manners for brown rice. This investigation concerns how the change of cooking mode can slow starch digestion of colored brown rice by inspecting mainly starch structural changes during cooking. Compared to cooking Mode 1, the soaking of Mode 2, at higher temperature, probably enhanced water diffusion into rice matrices, thus strengthening starch lamellae without apparently altering rice morphology and ordered structures such as starch polymorphs and helices. The followed heating of Mode 2, with reduced time, more sufficiently disrupted rice structures, causing less prominent nonperiodic molecular organizations. At the final cooking stage, the braising of Mode 2, having faster temperature reduction for prolonged time, leading to similar rice morphology, reduced molecular orders (e.g., helices) and probably denser amorphous regions of nonperiodic organizations. Such features tended to increase packing density of molecular chains (mainly starch) in rice matrices, thus slowing the enzyme diffusion in rice matrices and associated binding and catalysis events. In this way, a reduced starch digestion rate and increased resistant starch (RS) and slowly digestible starch (SDS) were seen for the rice following Mode 2 cooking.

Developing cheap and highly efficient catalysts for the selective oxidation of glycerol to value-added carboxylic acids still remains a challenge. Here, non-noble-metal Ni–Co oxide catalysts with lattice distortions are reported for the first time as highly efficient and stable catalysts for the oxidation of glycerol to glyceric acid. The Ni1Co1Ox catalyst, prepared by a modified hard template method, exhibits superior activity (1.5 × 10−3 s−1), excellent glyceric acid selectivity (66.5%), and good stability under mild conditions (80 °C, 1 MPa O2). Multiple characterizations demonstrated that the nanosized Ni1Co1Ox catalyst (2.3 nm) contains lattice distortion Ni–Co structures with nickel-rich surfaces. This morphology induces electron transfer from Co cations (mainly Co3+) to Ni cations (mainly Ni3+), resulting in the generation of surface oxygen vacancies. Density functional theory calculations and catalytic kinetics demonstrated that oxygen vacancies on Co species could improve glyceric acid selectivity by preventing the cleavage of C C bond, and oxygen vacancies on the Ni species could promote the activation of C H bonds, which results in the exceptional catalytic performance of Ni1Co1Ox. The novel Ni–Co oxide catalyst with lattice distortions synthesized here may provide some guidance for the rational design of inexpensive and highly efficient catalysts for the catalytic oxidation of biopolyols.

Smartphones sind seit der Präsentation in ihrer heutigen Form durch Steve Jobs in 2007 im Wesentlichen unverändert und haben sich als universelles Werkzeug der Digitalisierung im Alltag durchgesetzt. Wenn man auf die Präsentation des iPhones als eines der ersten echten Smartphones in 2007 schaut, stellt sich die Frage, wie sich diese Geräteklasse weiter entwickeln wird. Diese Frage ist für die Digitalisierung vieler Prozesse von großer Bedeutung, den das Smartphone ist derzeit das persönliche Ein- und Ausgabegerät fast aller an der Digitalisierung beteiligten Personen. In diesem Arbeitspapier wird versucht mit ausgewählten Metohden des Innovationsmanagements die Frage nach dem Smartphone der Zukunft zu beantworten und zu prüfen, ob die genutzten Methoden zur Beantwortung der Frage geeignet sind.

Achieving efficient catalytic conversion over a heterogeneous catalyst with excellent resistance against leaching is still a grand challenge for sustainable chemical synthesis in aqueous solution. Herein, we devised a single-atom Pt

Designing high-performance trifunctional electrocatalysts for ORR/OER/HER with outstanding activity and stability for each reaction is quite significant yet challenging for renewable energy technologies. Herein, a highly efficient and durable trifunctional electrocatalyst RuCoO