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Several theoretical studies have predicted that refrigerant mixtures with glides of more than 20 K can yield COP improvements in heat pumps for operating conditions where the temperature difference between the heat source and heat sink is large, but experimental validations and quantifications are scarce. The application of high-glide mixtures (>20 K) in industrial heat pumps in the field is, therefore, still hampered by concerns about the behavior and handling of the mixtures. This study experimentally investigates hydrocarbon (HC) mixtures R-290/600 (propane/butane) and R-290/601 (propane/pentane) and compares them to previously tested mixtures of synthetic refrigerants. Comprehensive evaluations are presented regarding COP, compressor performance, pressure drop, heat transfer, and the possibility of inline composition determination. The mixtures were tested over a range of compositions at a source inlet temperature of 60 °C and a sink outlet temperature of 100 °C, with the heat sink and heat source temperature differences controlled to 35 K. R-290/601 at a mass composition of 70%/30% was found as the best mixture with a COP improvement of 19% over R-600 as the best pure fluid. The overall isentropic compressor efficiency was similar for HC and synthetic refrigerants, given equal suction and discharge pressures. Pressure drops in heat exchangers and connecting lines were equal for synthetic and HC mixtures at equal mass flow rates. This allows higher heating capacities of HC mixtures at a given pressure drop (mass flow rate) due to their wider vapor dome. A previously developed evaporator heat transfer correlation for synthetic refrigerant mixtures was applicable to the HC mixtures. A condenser heat transfer correlation previously fitted for synthetic refrigerants performed significantly worse for HC mixtures. Composition determination during operation and without sampling was possible with a deviation of at most 0.05 mass fraction using simple temperature and pressure measurements and REFPROP for thermodynamic property calculations. Overall, high-glide HC mixtures, just like mixtures of synthetic refrigerants, showed significant COP improvements for specific operating conditions despite a decreased heat transfer coefficient. Potential problems like composition shift or poor compressor performance were not encountered. As a next step, testing high-glide mixtures in pilot-plant installations is recommended.

Several theoretical studies have predicted that refrigerant mixtures with glides of more than 20 K can yield COP improvements in heat pumps for operating conditions where the temperature difference between the heat source and heat sink is large, but experimental validations and quantifications are scarce. The application of high-glide mixtures (>20 K) in industrial heat pumps in the field is, therefore, still hampered by concerns about the behavior and handling of the mixtures. This study experimentally investigates hydrocarbon (HC) mixtures R-290/600 (propane/butane) and R-290/601 (propane/pentane) and compares them to previously tested mixtures of synthetic refrigerants. Comprehensive evaluations are presented regarding COP, compressor performance, pressure drop, heat transfer, and the possibility of inline composition determination. The mixtures were tested over a range of compositions at a source inlet temperature of 60 °C and a sink outlet temperature of 100 °C, with the heat sink and heat source temperature differences controlled to 35 K. R-290/601 at a mass composition of 70%/30% was found as the best mixture with a COP improvement of 19% over R-600 as the best pure fluid. The overall isentropic compressor efficiency was similar for HC and synthetic refrigerants, given equal suction and discharge pressures. Pressure drops in heat exchangers and connecting lines were equal for synthetic and HC mixtures at equal mass flow rates. This allows higher heating capacities of HC mixtures at a given pressure drop (mass flow rate) due to their wider vapor dome. A previously developed evaporator heat transfer correlation for synthetic refrigerant mixtures was applicable to the HC mixtures. A condenser heat transfer correlation previously fitted for synthetic refrigerants performed significantly worse for HC mixtures. Composition determination during operation and without sampling was possible with a deviation of at most 0.05 mass fraction using simple temperature and pressure measurements and REFPROP for thermodynamic property calculations. Overall, high-glide HC mixtures, just like mixtures of synthetic refrigerants, showed significant COP improvements for specific operating conditions despite a decreased heat transfer coefficient. Potential problems like composition shift or poor compressor performance were not encountered. As a next step, testing high-glide mixtures in pilot-plant installations is recommended. [ABSTRACT FROM AUTHOR]

White horticultural peat is a microbiologically active growing medium which binds significant quantities of nutrients and water due to its favourable cation exchange capacity and porosity. Unfortunately, horticultural peat is only very slowly renewable, and good quality horticultural peat is not common even in peatland-rich countries. Therefore, good-quality and simultaneously renewable alternative growing media are needed. A new growing medium based on Sphagnum moss biomass is introduced in this study. According to our results, harvesting of Sphagnum biomass to a depth of no more than 30 cm will have a relatively short-term effect on Sphagnum carpet coverage and carbon sequestration, allowing a harvesting cycle of ~30 years to be achieved. Therefore, the average harvesting depth will be 30 cm. Only half of the mire surface on each harvesting area will be utilised, the other half being kept intact for transportation routes. This will also secure a reserve of Sphagnum mosses for reseeding and recovery. The end product - Sphagnum biomass based growing medium - will be truly renewable, and environmental effects will be negligible compared with conventional extraction of white horticultural peat. Therefore, Sphagnum biomass harvesting is more comparable with sustainable forestry management than with the production of white peat, which causes drastic and long-term alterations of the mire ecosystem. [ABSTRACT FROM AUTHOR]

After drainage for forestry and agriculture, peat extraction is one of the most important causes of peatland degradation. When peat extraction is ceased, multiple after-use options exist, including abandonment, restoration, and replacement (e.g., forestry and agricultural use). However, there is a lack of a global synthesis of after-use research. Through a systematic review of 356 peer-reviewed scientific articles, we address this research gap and examine (1) what after-use options have been studied, (2) what the studied and recognized impacts of the after-use options are, and (3) what one can learn in terms of best practices and research gaps. The research has concentrated on the impacts of restoration (N = 162), abandonment (N = 72), and replacement (N = 94), the latter of which consists of afforestation (N = 46), cultivation (N = 34) and creation of water bodies (N = 14). The studies on abandonment, restoration, and creation of water bodies have focused mostly on analyzing vegetation and greenhouse gas (GHG) fluxes, while the studies assessing afforestation and cultivation sites mostly evaluate the provisioning ecosystem services. The studies show that active restoration measures speed-up vegetation recolonization on bare peat areas, reduce GHG emissions and decrease negative impacts on water systems. The most notable research gap is the lack of studies comparing the environmental and social impacts of the after-use options. Additionally, there is a lack of studies focusing on social impacts and downstream hydrology, as well as long-term monitoring of GHG fluxes. Based on the reviewed studies, a comparison of the impacts of the after-use options is not straightforward. We emphasize a need for comparative empirical research in the extracted sites with a broad socio-ecological and geographical context., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023 The Authors. Published by Elsevier B.V. All rights reserved.)

Drosera rotundifolia L. is a carnivorous plant used in traditional medicine for its therapeutic properties. Because of its small size, its collection in nature is laborious and different cultivation methods have been studied to ensure availability. However, only a few studies exist where the lab-grown sundew tissue and field-grown sundew would have been compared in their functionality or metabolic profiles. In this study, the antioxidant and antiviral activities of lab-grown and field-grown sundew extracts and their metabolic profiles are examined. The effect of drying methods on the chromatographic profile of the extracts is also shown. Antioxidant activity was significantly higher (5-6 times) in field-grown sundew but antiviral activity against enterovirus strains coxsackievirus A9 and B3 was similar in higher extract concentrations (cell viability ca. 90%). Metabolic profiles showed that the majority of the identified compounds were the same but field-grown sundew contained higher numbers and amounts of secondary metabolites. Freeze-drying, herbal dryer, and oven or room temperature drying of the extract significantly decreased the metabolite content from -72% up to -100%. Freezing was the best option to preserve the metabolic composition of the sundew extract. In conclusion, when accurately handled, the lab-grown sundew possesses promising antiviral properties, but the secondary metabolite content needs to be higher for it to be considered as a good alternative for the field-grown sundew.