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Dust grains in the planet forming regions around young stars are expected to be heavily processed due to coagulation, fragmentation and crystallization. This paper focuses on the crystalline silicate dust grains in protoplanetary disks. As part of the Cores to Disks Legacy Program, we obtained more than a hundred Spitzer/IRS spectra of TTauri stars. More than 3/4 of our objects show at least one crystalline silicate emission feature that can be essentially attributed to Mg-rich silicates. Observational properties of the crystalline features seen at lambda > 20 mu correlate with each other, while they are largely uncorrelated with the properties of the amorphous silicate 10 mu feature. This supports the idea that the IRS spectra essentially probe two independent disk regions: a warm zone (< 1 AU) emitting at lambda ~ 10 mu and a much colder region emitting at lambda > 20 mu (< 10 AU). We identify a crystallinity paradox, as the long-wavelength crystalline silicate features are 3.5 times more frequently detected (~55 % vs. ~15%) than the crystalline features arising from much warmer disk regions. This suggests that the disk has an inhomogeneous dust composition within ~10 AU. The abundant crystalline silicates found far from their presumed formation regions suggests efficient outward radial transport mechanisms in the disks. The analysis of the shape and strength of both the amorphous 10 mu feature and the crystalline feature around 23 mu provides evidence for the prevalence of micron-sized grains in upper layers of disks. Their presence in disk atmospheres suggests efficient vertical diffusion, likely accompanied by grain-grain fragmentation to balance the efficient growth expected. Finally, the depletion of submicron-sized grains points toward removal mechanisms such as stellar winds or radiation pressure.

We present a panchromatic study, involving a multiple technique approach, of the circumstellar disc surrounding the T Tauri star IM Lupi (Sz 82). We have undertaken a comprehensive observational study of IM Lupi using photometry, spectroscopy, millimetre interferometry and multi-wavelength imaging. For the first time, the disc is resolved from optical and near-infrared wavelengths in scattered light, to the millimetre regime in thermal emission. Our data-set, in conjunction with existing photometric data, provides an extensive coverage of the spectral energy distribution, including a detailed spectrum of the silicate emission bands. We have performed a simultaneous modelling of the various observations, using the radiative transfer code MCFOST, and analysed a grid of models over a large fraction of the parameter space via Bayesian inference. We have constructed a model that can reproduce all of the observations of the disc. Our analysis illustrates the importance of combining a wide range of observations in order to fully constrain the disc model, with each observation providing a strong constraint only on some aspects of the disc structure and dust content. Quantitative evidence of dust evolution in the disc is obtained: grain growth up to millimetre-sized particles, vertical stratification of dust grains with micrometric grains close to the disc surface and larger grains which have settled towards the disc midplane, and possibly the formation of fluffy aggregates and/or ice mantles around grains., Comment: 20 pages, 13 figures. Accepted for publication in A&A

With the goal to study the physical and chemical evolution of ices in solar-mass systems, a spectral survey is conducted of a sample of 41 low luminosity YSOs using 3-38 um Spitzer and ground-based spectra. The long-known 6.0 and 6.85 um bands are detected toward all sources, with the Class 0-type YSOs showing the deepest bands ever observed. In almost all sources the 6.0 um band is deeper than expected from the bending mode of pure solid H2O. The depth and shape variations of the remaining 5-7 um absorption indicate that it consists of 5 independent components, which, by comparison to laboratory studies, must be from at least 8 different carriers. Simple species are responsible for much of the absorption in the 5-7 um region, at abundances of 1-30% for CH3OH, 3-8% for NH3, 1-5% for HCOOH, ~6% for H2CO, and ~0.3% for HCOO- with respect to solid H2O. The 6.85 um band likely consists of one or two carriers, of which one is less volatile than H2O because its abundance relative to H2O is enhanced at lower H2O/tau_9.7 ratios. It does not survive in the diffuse interstellar medium (ISM), however. The similarity of the 6.85 um bands for YSOs and background stars indicates that its carrier(s) must be formed early in the molecular cloud evolution. If an NH4+ salt is the carrier its abundance with respect to solid H2O is typically 7%, and low temperature acid-base chemistry or cosmic ray induced reactions must have been involved in its formation. Possible origins are discussed for the carrier of an enigmatic, very broad absorption between 5 and 8 um. Finally, all the phenomena observed for ices toward massive YSOs are also observed toward low mass YSOs, indicating that processing of the ices by internal ultraviolet radiation fields is a minor factor in the early chemical evolution of the ices. [abridged], Comment: Accepted for publication in ApJ. 22 pages, 18 b&w figures

We have identified four circumstellar disks with a deficit of dust emission from their inner 15-50 AU. All four stars have F-G spectral type, and were uncovered as part of the Spitzer Space Telescope ``Cores to Disks'' Legacy Program Infrared Spectrograph (IRS) first look survey of ~100 pre-main sequence stars. Modeling of the spectral energy distributions indicates a reduction in dust density by factors of 100-1000 from disk radii between ~0.4 and 15-50 AU, but with massive gas-rich disks at larger radii. This large contrast between the inner and outer disk has led us to use the term `cold disks' to distinguish these unusual systems. However, hot dust [0.02-0.2 Mmoon] is still present close to the central star (R ~0.8 AU). We introduce the 30/13 micron, flux density ratio as a new diagnostic for identifying cold disks. The mechanisms for dust clearing over such large gaps are discussed. Though rare, cold disks are likely in transition from an optically thick to an optically thin state, and so offer excellent laboratories for the study of planet formation., Comment: 13 pages, 3 figures, accepted to ApJL

We present a survey of mid-infrared gas-phase lines toward a sample of 76 circumstellar disks around low mass pre-main sequence stars from the Spitzer "Cores to Disks" legacy program. We report the first detections of [Ne II] and [Fe I] toward classical T Tauri stars in ~20% respectively ~9% of our sources. The observed [Ne II] line fluxes and upper limits are consistent with [Ne II] excitation in an X-ray irradiated disk around stars with X-ray luminosities L_X=10^{29}-10^{31} erg s^{-1}. [Fe I] is detected at ~10^-5-10^-4 L_Sun, but no [S I] or [Fe II] is detected down to ~10^{-6} L_Sun. The [Fe I] detections indicate the presence of gas-rich disks with masses of >~0.1 M_J. No H_2 0-0 S(0) and S(1) disk emission is detected, except for S(1) toward one source. These data give upper limits on the warm (T~100-200K) gas mass of a few Jovian masses, consistent with recent T Tauri disk models which include gas heating by stellar radiation. Compact disk emission of hot (T>~500K) gas is observed through the H_2 0-0 S(2) and/or S(3) lines toward ~8% of our sources. The line fluxes are, however, higher by more than an order of magnitude than those predicted by recent disk models, even when X-ray and excess UV radiation are included. Similarly the [Ne II]/H_2 0-0 S(2) ratios for these sources are lower than predicted, consistent with the presence of an additional hot molecular gas component not included in current disk models. Oblique shocks of stellar winds interacting with the disk can explain many aspects of the hot gas emission, but are inconsistent with the non-detection of [S I] and [Fe II] lines., Comment: Accepted for publication in ApJ. 19 pages, 11 figures, and 4 tables, f7,f10a, f11a, and f11b replaced with slightly modified versions

We present Spitzer observations and McDonald Observatory Smith Telescope and Anglo-Australian Telescope high spectral resolution optical observations of 4 nearby stars with variable or anomalous optical absorption, likely caused by circumstellar material. The optical observations of CaII and NaI cover a 2.8 year baseline, and extend the long term monitoring of these systems by previous researchers. In addition, mini-surveys of the local interstellar medium (LISM) around our primary targets provide a reconstruction of the intervening LISM along the line of sight. We confirm that the anomalous absorption detected toward alpha Oph is not due to circumstellar material, but to a small filamentary cloud <14.3 pc from the Sun. The three other primary targets, beta Car, HD85905, and HR10 show both short and long term variability, and little of the observed absorption can be attributed to the LISM along the line of sight. The Spitzer observations did not detect infrared excesses. We are able to place upper limits on any possible fractional infrared luminosity, which range from L_IR/L_star < 2-5 10^-6, for our three disk stars. No stable gas absorption component centered at the radial velocity of the star is detected for any of our targets. Based on simple assumptions of the variable gas absorption component, we estimate limits on the circumstellar gas mass causing the variable absorption, which range from 0.4-20 10^-8 M_Earth. These multiwavelength observations place strong limits on any possible circumstellar dust, while confirming variable circumstellar gas absorption, and therefore are interesting targets to explore the origins and evolution of variable circumstellar gas. (abridged), Comment: 65 pages, 16 figures; Accepted for publication in ApJ

We announce the discovery of SST-Lup3-1, a very low mass star close to the brown dwarf boundary in Lupus III with a circum(sub)stellar disk, discovered by the `Cores to Disks' Spitzer Legacy Program from mid-, near-infrared and optical data, with very conspicuous crystalline silicate features in its spectrum. It is the first of such objects with a full 5 to 35 micron spectrum taken with the IRS and it shows strong 10 and 20 micron silicate features with high feature to continuum ratios and clear crystalline features out to 33 micron. The dust in the disk upper layer has a crystalline silicate grain fraction between 15% and 33%, depending on the assumed dust continuum. The availability of the full Spitzer infrared spectrum allows an analysis of the dust composition as a function of temperature and position in the disk. The hot (~ 300 K) dust responsible for the 10 micron feature consists of a roughly equal mix of small (~ 0.1 micron) and large (~ 1.5 micron) grains, whereas the cold (~ 70 K) dust responsible for the longer wavelength silicate features contains primarily large grains (> 1 micron). Since the cold dust emission arises from deeper layers in the inner (< 3 AU) disk as well as from the surface layers of the outer (3-5 AU) disk, this provides direct evidence for combined grain growth and settling in the disk. The inferred crystalline mass fractions in the two components are comparable. Since only the inner 0.02 AU of the disk is warm enough to anneal the amorphous silicate grains, even the lowest fraction of 15% of crystalline material requires either very efficient mixing or other formation mechanisms., Comment: Accepted for publication in ApJ. 19 pages and 4 figures. V2 with correct references

Recent results indicate that the grain size and crystallinity inferred from observations of silicate features may be correlated with spectral type of the central star and/or disk geometry. In this paper, we show that grain size, as probed by the 10 um silicate feature peak-to-continuum and 11.3-to-9.8 um flux ratios, is inversely proportional to log L_star. These trends can be understood using a simple two-layer disk model for passive irradiated flaring disks, CGPLUS. We find that the radius, R_10, of the 10 um silicate emission zone in the disk goes as (L_star/L_sun)^0.56, with slight variations depending on disk geometry (flaring angle, inner disk radius). The observed correlations, combined with simulated emission spectra of olivine and pyroxene mixtures, imply a grain size dependence on luminosity. Combined with the fact that R_10 is smaller for less luminous stars, this implies that the apparent grain size of the emitting dust is larger for low-luminositysources. In contrast, our models suggest that the crystallinity is only marginally affected, because for increasing luminosity, the zone for thermal annealing (assumed to be at T>800 K) is enlarged by roughly the same factor as the silicate emission zone. The observed crystallinity is affected by disk geometry, however, with increased crystallinity in flat disks. The apparent crystallinity may also increase with grain growth due to a corresponding increase in contrast between crystalline and amorphous silicate emission bands., Comment: 6 pages, 3 figures, scheduled to appear in ApJ, vol 658 (April 1, 2007)

We present mid-infrared Spitzer-IRS spectra of the well-known UX Orionis star VV Ser. We combine the Spitzer data with interferometric and spectroscopic data from the literature covering UV to submillimeter wavelengths. The full set of data are modeled by a two-dimensional axisymmetric Monte Carlo radiative transfer code. The model is used to test the prediction of (Dullemond et al. 2003) that disks around UX Orionis stars must have a self-shadowed shape, and that these disks are seen nearly edge-on, looking just over the edge of a puffed-up inner rim, formed roughly at the dust sublimation radius. We find that a single, relatively simple model is consistent with all the available observational constraints spanning 4 orders of magnitude in wavelength and spatial scales, providing strong support for this interpretation of UX Orionis stars. The grains in the upper layers of the puffed-up inner rim must be small (0.01-0.4 micron) to reproduce the colors (R_V ~ 3.6) of the extinction events, while the shape and strength of the mid-infrared silicate emission features indicate that grains in the outer disk (> 1-2 AU) are somewhat larger (0.3-3.0 micron). From the model fit, the location of the puffed-up inner rim is estimated to be at a dust temperature of 1500 K or at 0.7-0.8 AU for small grains. This is almost twice the rim radius estimated from near-infrared interferometry. A best fitting model for the inner rim in which large grains in the disk mid-plane reach to within 0.25 AU of the star, while small grains in the disk surface create a puffed-up inner rim at ~0.7-0.8 AU, is able to reproduce all the data, including the near-infrared visibilities. [Abstract abridged], Comment: 12 pages, accepted for publication in ApJ

Aims: We search for PAH features towards T Tauri stars and compare them with surveys of Herbig Ae/Be stars. The presence and strength of the PAH features are interpreted with disk radiative transfer models exploring the PAH feature dependence on the incident UV radiation, PAH abundance and disk parameters. Methods: Spitzer Space Telescope 5-35 micron spectra of 54 pre-main sequence stars with disks were obtained, consisting of 38 T Tauri, 7 Herbig Ae/Be and 9 stars with unknown spectral type. Results: Compact PAH emission is detected towards at least 8 sources of which 5 are Herbig Ae/Be stars. The 11.2 micron PAH feature is detected in all of these sources, as is the 6.2 micron PAH feature where short wavelength data are available. However, the 7.7 and 8.6 micron features appear strongly in only 1 of these 4 sources. PAH emission is observed towards at least 3 T Tauri stars (8% detection rate). The lowest mass source with PAHs in our sample is T Cha (G8). All 4 sources in our sample with evidence for dust holes in their inner disk show PAH emission, increasing the feature/continuum ratio. Typical 11.2 micron line intensities are an order of magnitude lower than those observed for the more massive Herbig Ae/Be stars. Measured line fluxes indicate PAH abundances that are factors of 10-100 lower than standard interstellar values. Conversely, PAH features from disks exposed to stars with Teff<=4200K without enhanced UV are predicted to be below the current detection limit, even for high PAH abundances. Disk modeling shows that the 6.2 and 11.2 micron features are the best PAH tracers for T Tauri stars, whereas the 7.7 and 8.6 micron bands have low feature over continuum ratios due to the strongly rising silicate emission., Comment: 20 pages, 15 figures, accepted for publication in A&A

We present a compositional analysis of 8-13um spectra of 32 young stellar objects (YSOs). Our sample consists of 5 intermediate-mass stars and 27 low-mass stars. While the spectra and first scientific results have already been published by Przygodda et al. (2003) and Kessler-Silacci et al. (2004) we perform a more detailed analysis of the 10um silicate feature. In our analysis we assume that this emission feature can be represented by a linear superposition of the wavelength-dependent opacity $\kappa_{\rm abs}(\lambda)$ describing the optical properties of silicate grains with different chemical composition, structure, and grain size. The determination of an adequate fitting equation is another goal of this study. Using a restricted number of fitting parameters we investigate which silicate species are necessary for the compositional fitting. Particles with radii of 0.1um- and 1.5um consisting of amorphous olivine and pyroxene, forsterite, enstatite, and quartz have been considered. Only compact, homogeneous dust grains have been used in the presented fitting procedures. In this context we show that acceptable fitting results can also be achieved if emission properties of porous silicate grains are considered instead. Although some previous studies give reasons for the similarity between the dust in circumstellar disks of TTauri stars and Herbig Ae/Be stars, a quantitative comparison has been missing, so far. Therefore, we conclude with a discussion of the results of a 10um spectroscopic survey of van Boekel et al. (2005) who focus on Herbig Ae/Be stars, the higher mass counterparts of T Tauri stars and draw comparisons to this and other studies. We find that the results of our study of T Tauri systems partly agree with previous studies of Herbig Ae/Be stars., Comment: 17 pages, 6 figures

We have combined new I, J, H, and Ks imaging of portions of the Chamaeleon II, Lupus I, and Ophiuchus star-forming clouds with 3.6 to 24 micron imaging from the Spitzer Legacy Program, "From Molecular Clouds to Planet Forming Disks", to identify a sample of 19 young stars, brown dwarfs and sub-brown dwarfs showing mid-infrared excess emission. The resulting sample includes sources with luminosities of 0.5>log(L/Lsun)>-3.1. Six of the more luminous sources in our sample have been previously identified by other surveys for young stars and brown dwarfs. Five of the sources in our sample have nominal masses at or below the deuterium burning limit (~12 M_J). Over three decades in luminosity, our sources have an approximately constant ratio of excess to stellar luminosity. We compare our observed SEDs to theoretical models of a central source with a passive irradiated circumstellar disk and test the effects of disk inclination, disk flaring, and the size of the inner disk hole on the strength/shape of the excess. The observed SEDs of all but one of our sources are well fit by models of flared and/or flat disks., Comment: 35 pages, ApJ accepted

Spitzer Space Telescope spectra of the low mass young stellar object (YSO) IRS 46 (L_bol ~ 0.6 L_sun) in Ophiuchus reveal strong vibration-rotation absorption bands of gaseous C2H2, HCN, and CO2. This is the only source out of a sample of ~100 YSO's that shows these features and the first time they are seen in the spectrum of a solar-mass YSO. Analysis of the Spitzer data combined with Keck L- and M-band spectra gives excitation temperatures of > 350 K and abundances of 10(-6)-10(-5) with respect to H2, orders of magnitude higher than those found in cold clouds. In spite of this high abundance, the HCN J=4-3 line is barely detected with the James Clerk Maxwell Telescope, indicating a source diameter less than 13 AU. The (sub)millimeter continuum emission and the absence of scattered light in near-infrared images limits the mass and temperature of any remnant collapse envelope to less than 0.01 M_sun and 100 K, respectively. This excludes a hot-core type region as found in high-mass YSO's. The most plausible origin of this hot gas rich in organic molecules is in the inner (<6 AU radius) region of the disk around IRS 46, either the disk itself or a disk wind. A nearly edge-on 2-D disk model fits the spectral energy distribution (SED) and gives a column of dense warm gas along the line of sight that is consistent with the absorption data. These data illustrate the unique potential of high-resolution infrared spectroscopy to probe organic chemistry, gas temperatures and kinematics in the planet-forming zones close to a young star., Comment: 4 pages, 4 figures; To appear in Astrophysical Journal Letters

A powerful way to observe directly the solid state inventory of dense molecular clouds is by infrared spectroscopy of background stars. We present Spitzer/IRS 5-20 micron spectra of ices toward stars behind the Serpens and Taurus molecular clouds, probing visual extinctions of 10-34 mag. These data provide the first complete inventory of solid-state material in dense clouds before star formation begins. The spectra show prominent 6.0 and 6.85 micron bands. In contrast to some young stellar objects (YSOs), most (~75%) of the 6.0 micron band is explained by the bending mode of pure water ice. In realistic mixtures this number increases to 85%, because the peak strength of the water bending mode is very sensitive to the molecular environment. The strength of the 6.85 micron band is comparable to what is observed toward YSOs. Thus, the production of the carrier of this band does not depend on the energetic input of a nearby source. The spectra show large abundances of carbon monoxide and carbon dioxide (20-40% with respect to water ice). Compared to YSOs, the band profile of the 15 micron carbon dioxide bending mode lacks the signatures of crystallization, confirming the cold, pristine nature of these lines of sight. After the dominant species are removed, there are residuals that suggest the presence of minor species such as formic acid and possibly ammonia. Clearly, models of star formation should begin with dust models already coated with a fairly complex mixture of ices., Comment: 4 pages, 5 figures; To appear in Astrophysical Journal Letters

Infrared ~5--35 um spectra for 40 solar-mass T Tauri stars and 7 intermediate-mass Herbig Ae stars with circumstellar disks were obtained using the Spitzer Space Telescope as part of the c2d IRS survey. This work complements prior spectroscopic studies of silicate infrared emission from disks, which were focused on intermediate-mass stars, with observations of solar-mass stars limited primarily to the 10 um region. The observed 10 and 20 um silicate feature strengths/shapes are consistent with source-to-source variations in grain size. A large fraction of the features are weak and flat, consistent with um-sized grains indicating fast grain growth (from 0.1--1.0 um in radius). In addition, approximately half of the T Tauri star spectra show crystalline silicate features near 28 and 33 um indicating significant processing when compared to interstellar grains. A few sources show large 10-to-20 um ratios and require even larger grains emitting at 20 um than at 10 um. This size difference may arise from the difference in the depth into the disk probed by the two silicate emission bands in disks where dust settling has occurred. The 10 um feature strength vs. shape trend is not correlated with age or Halpha equivalent width, suggesting that some amount of turbulent mixing and regeneration of small grains is occurring. The strength vs. shape trend is related to spectral type, however, with M stars showing significantly flatter 10 um features (larger grain sizes) than A/B stars. The connection between spectral type and grain size is interpreted in terms of the variation in the silicate emission radius as a function of stellar luminosity, but could also be indicative of other spectral-type dependent factors (e.g, X-rays, UV radiation, stellar/disk winds, etc.)., Comment: 17 pages, 13 figures, accepted for publication by ApJ, formatted with emulateapj using revtex4 v4.0

We argue that classical T Tauri stars (cTTs) possess significant non- photospheric excess in the J and H bands. We first show that normalizing the spectral energy distributions (SEDs) of cTTs to the J-band leads to a poor fit of the optical fluxes, while normalizing the SEDs to the Ic-band produces a better fit to the optical bands and in many cases reveals the presence of a considerable excess at J and H. NIR spectroscopic veiling measurements from the literature support this result. We find that J and H-band excesses correlate well with the K-band excess, and that the J-K and H-K colors of the excess emission are consistent with that of a black body at the dust sublimation temperature (~ 1500-2000 K). We propose that this near-IR excess originates at a hot inner rim, analogous to those suggested to explain the near-IR bump in the SEDs of Herbig Ae/Be stars. To test our hypothesis, we use the model presented by Dullemond et al. (2001) to fit the photometry data between 0.5 um and 24 um of 10 cTTs associated with the Chamaeleon II molecular cloud. The models that best fit the data are those where the inner radius of the disk is larger than expected for a rim in thermal equilibrium with the photospheric radiation field alone. In particular, we find that large inner rims are necessary to account for the mid infrared fluxes (3.6-8.0 um) obtained by the Spitzer Space Telescope. Finally, we argue that deriving the stellar luminosities of cTTs by making bolometric corrections to the J-band fluxes systematically overestimates these luminosities. The overestimated luminosities translate into underestimated ages when the stars are placed in the H-R diagram. Thus, the results presented herein have important implications for the dissipation timescale of inner accretion disks., Comment: 45 pages, 13 figures

Mid-infrared (23-35 micron) emission from the deeply embedded "Class 0" protostar IRAS16293-2422 is detected with the Spitzer Space Telescope infrared spectrograph. A detailed radiative transfer model reproducing the full spectral energy distribution (SED) from 23 micron to 1.3 mm requires a large inner cavity of radius 600 AU in the envelope to avoid quenching the emission from the central sources. This is consistent with a previous suggestion based on high angular resolution millimeter interferometric data. An alternative interpretation using a 2D model of the envelope with an outflow cavity can reproduce the SED but not the interferometer visibilities. The cavity size is comparable to the centrifugal radius of the envelope and therefore appears to be a natural consequence of the rotation of the protostellar core, which has also caused the fragmentation leading to the central protostellar binary. With a large cavity such as required by the data, the average temperature at a given radius does not increase above 60-80 K and although hot spots with higher temperatures may be present close to each protostar, these constitute a small fraction of the material in the inner envelope. The proposed cavity will also have consequences for the interpretation of molecular line data, especially of complex species probing high temperatures in the inner regions of the envelope., Comment: Accepted for publication in ApJ Letters

In order to investigate possible connections between dust processing and disk properties, 8--13 um spectra of 34 young stars, with a range of circumstellar environments and spectral types A to M, were obtained using the Long Wavelength Spectrometer at the W. M. Keck Observatory. The broad 9.7 um amorphous silicate feature which dominates this wavelength regime evolves from absorption in young, embedded sources, to emission in optically revealed stars, and to complete absence in older debris disk systems for both low- and intermediate-mass stars. The peak wavelength and FWHM are centered about 9.7 and ~2.3 um, corresponding to amorphous olivine, with a larger spread in FWHM for embedded sources and in peak wavelength for disks. In a few of our objects that have been previously identified as class I low-mass YSOs, the observed silicate feature is complex, with absorption near 9.5 um and emission peaking around 10 um. Although most of the emission spectra show broad classical features attributed to amorphous silicates, variations in the shape/strength may be linked to dust processing, including grain growth and/or silicate crystallization. We study quantitatively the evidence for evolutionary trends in the 8--13 um spectra through a variety of spectral shape diagnostics. Based on the lack of correlation between these diagnostics and broad-band infrared luminosity characteristics for silicate emission sources, we conclude that although spectral signatures of dust processing are present, they can not be connected clearly to disk evolutionary stage (for optically thick disks) or optical depth (for optically thin disks). The diagnostics of silicate absorption features (other than the central wavelength of the feature), however, are tightly correlated with optical depth., Comment: 27 pages, 13 figures, accepted for publication by ApJ, formatted with emulateapj using revtex4 v4.0

We present 5.2-37.2 micron spectroscopy of the edge-on circumstellar disk CRBR 2422.8-3423 obtained using the InfraRed Spectrograph (IRS) of the Spitzer Space Telescope. The IRS spectrum is combined with ground-based 3-5 micron spectroscopy to obtain a complete inventory of solid state material present along the line of sight toward the source. We model the object with a 2D axisymmetric (effectively 3D) Monte Carlo radiative transfer code. It is found that the model disk, assuming a standard flaring structure, is too warm to contain the very large observed column density of pure CO ice, but is possibly responsible for up to 50% of the water, CO2 and minor ice species. In particular the 6.85 micron band, tentatively due to NH4+, exhibits a prominent red wing, indicating a significant contribution from warm ice in the disk. It is argued that the pure CO ice is located in the dense core Oph-F in front of the source seen in the submillimeter imaging, with the CO gas in the core highly depleted. The model is used to predict which circumstances are most favourable for direct observations of ices in edge-on circumstellar disks. Ice bands will in general be deepest for inclinations similar to the disk opening angle, i.e. ~70 degrees. Due to the high optical depths of typical disk mid-planes, ice absorption bands will often probe warmer ice located in the upper layers of nearly edge-on disks. The ratios between different ice bands are found to vary by up to an order of magnitude depending on disk inclination due to radiative transfer effects caused by the 2D structure of the disk. Ratios between ice bands of the same species can therefore be used to constrain the location of the ices in a circumstellar disk. [Abstract abridged], Comment: 49 pages, accepted for publication in ApJ

Sensitive 5-38 um Spitzer Space Telescope (SST) and ground based 3-5 um spectra of the embedded low mass protostars B5 IRS1 and HH46 IRS show deep ice absorption bands superposed on steeply rising mid-infrared continua. The ices likely originate in the circumstellar envelopes. The CO2 bending mode at 15 um is a particularly powerful tracer of the ice composition and processing history. Toward these protostars, this band shows little evidence for thermal processing at temperatures above 50 K. Signatures of lower temperature processing are present in the CO and OCN- bands, however. The observed CO2 profile indicates an intimate mixture with H2O, but not necessarily with CH3OH, in contrast to some high mass protostars. This is consistent with the low CH3OH abundance derived from the ground based L band spectra. The CO2/H2O column density ratios are high in both B5 IRS1 and HH46 IRS (~35%). Clearly, the SST spectra are essential to study ice evolution in low mass protostellar environments, and to eventually determine the relation between interstellar and solar system ices., Comment: Scheduled for publication in ApJS Sept. 2004, v154 [Spitzer Special issue]. 5 pages, 1 b&w figure, 1 color figure