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Partial lead service line replacement (PLSLR) results in the addition of a new galvanic connection and can increase lead concentrations at the tap. Focus has been given to minimizing lead release after PLSLR, but little information is available on the impact of lead remedial actions on copper concentrations, especially before passivation occurs. The impact of water quality (decreased chloride-to-sulfate mass ratio from 0.9 to 0.3; addition of orthoP; pH increase to 8.3) on lead and copper concentrations was investigated after stagnation (30 min–336 h) in a pipe rig comparing full lead service line (LSL), and two configurations of partial LSLs (Cu-Pb and Pb-Cu). Results show different trends for lead and copper: maximum lead concentrations were reached in 16 h while copper concentrations continued to increase over 336 h. Lead release rates were also the highest in the first 16 h of stagnation and were strongly impacted by water quality and the configuration of PLSLR (Cu-Pb vs Pb-Cu). Increasing the sampling flow rate from 5 to 15 LPM drastically increased the particulate lead release (78-fold) in Pb-Cu configurations; this effect was however not observed in 100% Pb or Cu-Pb configurations. High velocity flushing prior to 16 h stagnation decreased total Pb release by a factor of 12-fold for Cu-Pb, 1.6-fold for Pb-Cu and 2.0-fold for 100% Pb. Results support the definition of sampling protocols targeted for the detection of lead and copper sources and the proscription of flushing prior to sampling.

Long-term (155 weeks) Pb concentrations, following partial lead service lines replacements (PLSLR), were measured in a flow through pilot made of harvested lead service lines (LSL) from the distribution system of the City of Montreal. The present study also investigates how release of Pb from full and partial LSLs is influenced by: pipe diameter, decrease in chloride-to-sulfate mass ratio (CSMR) from 0.9 to 0.3, addition of orthophosphate (1 mg P/L), and increase in pH to 8.3. Pb concentrations were measured after 16 h of stagnation and under flow conditions. In this study, Pb concentrations did not decrease, in the long term, after partial LSL replacement. Moreover, the most effective corrosion control treatment in full LSLs was the addition of orthoP. In contrast, the decrease of the CSMR best reduced lead release from partial LSLs. The impact of pipe configuration therefore influenced the effectiveness of corrosion control treatments. It is noteworthy that the increase in Pb concentrations following PLSLR were attributed to particulate Pb release from the galvanic section of the pipe. The occurrence of galvanic corrosion, caused by the connection between Pb and copper pipes, adds a new source of Pb in the partial LSL. At least, this new source of lead has to be offset by the removal of a long enough section of LSL during PLSLR. Full LSL replacements may be warranted to minimize the exposure of consumers to elevated Pb levels caused by galvanic corrosion in LSLs.

Legacy lead and copper components are ubiquitous in plumbing of large buildings including schools that serve children most vulnerable to lead exposure. Lead and copper samples must be collected after varying stagnation times and interpreted in reference to different thresholds. A total of 130 outlets (fountains, bathroom and kitchen taps) were sampled for dissolved and particulate lead as well as copper. Sampling was conducted at 8 schools and 3 institutional (non-residential) buildings served by municipal water of varying corrosivity, with and without corrosion control (CC), and without a lead service line. Samples included first draw following overnight stagnation (8h), partial (30 s) and fully (5 min) flushed, and first draw after 30 min of stagnation. Total lead concentrations in first draw samples after overnight stagnation varied widely from 0.07 to 19.9 μg Pb/L (median: 1.7 μg Pb/L) for large buildings served with non-corrosive water. Higher concentrations were observed in schools with corrosive water without CC (0.9-201 μg Pb/L, median: 14.3 μg Pb/L), while levels in schools with CC ranged from 0.2 to 45.1 μg Pb/L (median: 2.1 μg Pb/L). Partial flushing (30 s) and full flushing (5 min) reduced concentrations by 88% and 92% respectively for corrosive waters without CC. Lead concentrations were10 μg Pb/L in all samples following 5 min of flushing. However, after only 30 min of stagnation, first draw concentrations increased back to45% than values in 1st draw samples collected after overnight stagnation. Concentrations of particulate Pb varied widely (≥0.02-846 μg Pb/L) and was found to be the cause of very high total Pb concentrations in the 2% of samples exceeding 50 μg Pb/L. Pb levels across outlets within the same building varied widely (up to 1000X) especially in corrosive water (0.85-851 μg Pb/L after 30MS) confirming the need to sample at each outlet to identify high risk taps. Based on the much higher concentrations observed in first draw samples, even after a short stagnation, the first 250mL should be discarded unless no sources of lead are present. Results question the cost-benefit of daily or weekly flushing as a remediation strategy. As such, current regulatory requirements may fail to protect children as they may not identify problematic taps and effective mitigation measures.

Thirty-three households were monitored in a full-scale water distribution system, to investigate the impact of recent (2 yr) or old partial lead service line replacements (PLSLRs). Total and particulate lead concentrations were measured using repeat sampling over a period of 1-20 months. Point-of-entry filters were installed to capture sporadic release of particulate lead from the lead service lines (LSLs). Mean concentrations increased immediately after PLSLRs and erratic particulate lead spikes were observed over the 18 month post-PLSLR monitoring period. The mass of lead released during this time frame indicates the occurrence of galvanic corrosion and scale destabilization. System-wide, lead concentrations were however lower in households with PLSLRs as compared to those with no replacement, especially for old PLSLRs. Nonetheless, 61% of PLSLR samples still exceeded 10 μg/L, reflecting the importance of implementing full LSL replacement and efficient risk communication. Acute concentrations measured immediately after PLSLRs demonstrate the need for appropriate flushing procedures to prevent lead poisoning.

Dwellings with/without a lead service line [LSL] were sampled for lead in tap water in Montreal, during different seasons. Short-term simulations using these results and the batchrun mode of the Integrated Exposure Uptake Biokinetic (IEUBK) model showed that children's exposure to lead at the tap in the presence of an LSL varies seasonally, and according to the type of dwelling. From July to March, for single-family homes, the estimated geometric mean [GM] blood lead level [BLL] decreased from 2.3-3.6 μg/dL to 1.5-2.5 μg/dL, depending on the children's age. The wide seasonal variations in lead exposure result in a minimal fraction (0-6%) of children with a predicted BLL >5 μg/dL in winter, as opposed to a significant proportion (5-25%) in summer. These estimations are in close agreement with the BLLs measured in Montreal children in fall and winter, and simulations using summer water lead levels illustrate the importance of measuring BLLs during the summer. Finally, simulations for wartime residences with long LSLs confirm the need to prioritize the control of this lead exposure from tap water.

Release of lead from 80% partially replaced service lines was compared to full lead service lines using harvested-stabilized lead pipes and field brass connectors. After more than a year of stabilization, lead release was consistent with field samples. Over the relatively short duration partial replacement of lead pipe by copper pipe (3 months), generated high lead release, attributed to galvanic corrosion, resulting in a final outcome for lead release that was even worse than for a full lead pipe. Increased lead release was especially evident at higher flow rates. Orthophosphate reduced lead release from full lead pipes by 64%. For partially replaced samples with copper, lead concentrations were unchanged by phosphate dosing at moderate flow (103 ± 265 vs 169 ± 349 μg/L) and were increased to very high levels when sampled at high flow rates (1001 ± 1808 vs 257 ± 224 μg/L). The increase lead release was in the form of particulate lead (>90%). In comparison to the condition without treatment, increased sulfate treatment had little impact on lead release from 100%-Pb rigs but reduced lead release from partially replaced lead pipes with copper. Our results also raise questions concerning protocols based on short 30 min stagnation (as those used in Canada) due to their incapacity to consider particulate lead release generated mostly after longer stagnation.

Lead is neurotoxic at very low dose and there is a need to better characterize the impact of domestic sources of lead on the biological exposure of young children. A cross-sectional survey evaluated the contribution of drinking water, house dust and paint to blood lead levels (BLLs) of young children living in old boroughs of Montréal (Canada). Three hundred and six children aged 1 to 5 years and currently drinking tap water participated in the study. For each participant, residential lead was measured in kitchen tap water, floor dust, windowsill dust and house paint and a venous blood sample was analyzed. Multivariate logistic regression was used to evaluate the association between elevated BLL in the children (≥ 75th percentile) and indoor lead contamination by means of odds ratios (OR) using 95% confidence intervals (CI). There was an association between BLL ≥75th percentile (1.78 μg/dL) and water lead when the mean water concentration was >3.3 μg/L: adjusted OR=4.7 (95% CI: 2.1–10.2). Windowsill dust loading >14.1 μg/ft2 was also associated with BLL ≥1.78 μg/dL: adjusted OR=3.2 (95% CI: 1.3–7.8). Despite relatively low BLLs, tap water and house dust lead contribute to an increase of BLLs in exposed young children.

A field study was performed in a building complex to investigate the extent and sources of lead (Pb) release in tap water and brass material was found to be the main contributor in the very first draw (250 mL). Based on these results, a pilot installation was built to study Pb leaching from old and new faucets in the presence and absence of a connection to Cu piping. Four water quality conditions were tested: i) no treatment; ii) addition of 0.8 mg P/L of orthophosphate; iii) pH adjustment to 8.4; and iv) adjustment to a higher chloride to sulfate mass ratio (CSMR; ratio from 0.3 to 2.9). Pb concentrations in samples taken from the faucets without treatment ranged from 1 to 52 μg/L, with a mean of 11 μg/L. The addition of orthophosphate @ 0.8 mg P/L (OrthoP) was the most effective treatment for all types of faucets tested. On average, OrthoP reduced mean Pb leaching by 41%, and was especially effective for new double faucets (70%). In the presence of orthophosphates, the relative proportion of particulate Pb (Pbpart) (>0.45 μm) increased from 31% to 54%. However, OrthoP was not efficient to reduce Zn release. The higher CSMR condition was associated with greater dezincification of yellow brass but not of red brass. Corrosion control treatment influenced Pb concentration equilibrium, directly impacting maximal exposure. Significantly higher Pb release (3 fold) was observed for 1 of the 8 faucets connected to Cu exposed to high CSMR water, suggesting the presence of galvanic corrosion.

Lead results from 78,971 water samples collected in four Canadian provinces from elementary schools, daycares, and other large buildings using regulatory and investigative sampling protocols were analyzed to provide lead concentration distributions. Maximum concentrations reached 13,200 and 3890 μg/L following long and short stagnation periods respectively. High lead levels were persistent in some large buildings, reflected by high median values considering all taps, or specific to a few taps in the building. Simulations using the Integrated Uptake Biokinetic (IEUBK) model and lead concentrations after 30 min of stagnation in the dataset showed that, for most buildings, exposure to lead at the tap does not increase children's blood lead levels (BLLs). However, buildings or taps with extreme concentrations represent a significant health risk to young children attending school or daycare, as the estimated BLL far exceeded the 5 μg/dL threshold. Ingestion of water from specific taps could lead to acute exposure. Finally, for a few taps, the total daily lead intake reached the former World Health Organization (WHO) tolerable level for adults, suggesting potential health risks.

Background and Aims: Lead sources in the general environment have reduced dramatically but the importance of domestic sources in Canada remains unknown. This study evaluated the contribution of res...

Lead samples were collected at the tap from homes with lead service lines (LSLs) in a full-scale utility using both random daytime (RDT) and particulate stimulation sampling (PSS) protocols. Analysis of the results revealed two sources and occurrences of particulate lead. A first source is due to corrosion of lead-bearing elements in the premise plumbing (PP) and occurs mostly at low to moderate concentrations < 3 microg/L, with some sporadic higher concentrations (4-12 microg/L). These spikes were consistently observed and considerably increased using PSS, showing that current sampling protocols may miss a significant portion of particulate lead. The second source results from the adsorption of dissolved lead onto iron deposits in LSL/PP, and is continuously present at low to moderate concentrations. Statistical analyses were validated by physical analyses of: (i) lead scales from LSLs; and (ii) lead particles from tap aerators.

Relatively limited information is available regarding the impacts of temperature on the adsorption kinetics and equilibrium capacities of granular ferric hydroxide (GFH) for arsenic (V) and arsenic (III) in an aqueous solution. In general, very little information is available on the kinetics and thermodynamic aspects of adsorption of arsenic compounds onto other iron oxide-based adsorbents as well. In order to gain an understanding of the adsorption process kinetics, a detailed study was conducted in a controlled batch system. The effects of temperature and pH on the adsorption rates of arsenic (V) and arsenic (III) were investigated. Reaction rate constants were calculated at pH levels of 6.5 and 7.5. Rate data are best described by a pseudo first-order kinetic model at each temperature and pH condition studied. At lower pH values, arsenic (V) exhibits greater removal rates than arsenic (III). An increase in temperature increases the overall adsorption reaction rate constant values for both arsenic (V) and arsenic (III). An examination of thermodynamic parameters shows that the adsorption of arsenic (V) as well as arsenic (III) by GFH is an endothermic process and is spontaneous at the specific temperatures investigated.