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This study reports the synthesis of five novel Schiff base heterobinuclear nickel(II) and tin(II) complexes. The heterobinuclear complexes were synthesized by the interaction of N,N′-ethylenebis(2-hydroxyacetophenoniminato) nickel(II) with tin(II) salts of 2,4,6-trinitrophenol, 1-nitroso-2-naphthol, o-nitrophenol, 8-hydroxyquinoline and 2,4-dinitrophenol. Characterization of these complexes was carried by physico-chemical techniques such as elemental analyses, conductivity measurements, magnetic measurements, infrared spectra and electronic spectral studies. The molar conductance data reveals that the complexes are non-electrolytic in nature. The magnetic susceptibility data and the spectral studies propose square planar geometry of the complexes around nickel(II) and coordination to the metal centre via azomethine nitrogen and deprotonated phenolic oxygen atoms.

Copper(II) ion can form complexes with varied ligands. The present study describes the synthesis of a series of new hetero binuclear Schiff base complexes of copper(II) and organic chelates of silver(I). The Schiff base ligand was derived from salicylaldehyde and ophenylenediamine. For the characterization of the hetero binuclear complexes, various physicoanalytical and spectral studies viz. elemental analysis, magnetic moment measurements, molar conductance, FTIR and electronic spectral recordings were applied. Evidences from these analyses reveal square geometry for the complexes.

This paper describes the synthesis of six novel Schiff base heterobimetallic complexes of nickel(II) and silver(I) and their spectral characteristics. The Schiff base was synthesized via condensation of o-Hydroxyacetophenone and 1,2- Diaminopropane in molar ratio 2:1. The characterization of the synthesized complexes was done with the aid of molar conductance, elemental analysis, FTIR, electronic spectral analysis and magnetic moment studies. The complexes obtained are non-electrolytes, colored and stable. Spectral analyses of the hetero bimetallic complexes suggest square planar geometry with coordination number four for all the complexes.

A series of new hetero binuclear complexes of copper(II) and lead(II) using Schiff base have been synthesized. The Schiff base has been derived from the condensation reaction between Salicylaldehyde and 1,2-Ethylenediamine. The hetero binuclear complexes have been characterized by using elemental analysis, molar conductance measurement, magnetic susceptibility studies, UV-Vis and IR spectra. The studies revealed square planar geometry for the complexes with coordination number four.