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Electrochemical stability window (ESW) of an inorganic compound (solid‐state electrolyte (SSE) or coating) is an indispensable parameter to evaluate the interface compatibility between the electrode and electrolyte in ion batteries. The discovery of novel coatings and SSEs, driven by extensive ESW data, is expected to accelerate the design of high‐performance batteries. However, only a very small fraction of the ESW of inorganic compounds has been experimentally measured at present, which limits technological progress. Benefiting from the high‐accuracy ESW prediction with dynamically determined direct or indirect decomposition pathway proposed in the previous work, both the oxidation and reduction potentials align to the experimental data reasonably. Here, a database containing phase diagrams and electrochemical stability information is established for more than 1500 solid‐state inorganic compounds with Li+, Na+, K+, Mg2+, Ca2+, and Al3+ as the migrating ions, and this number is still growing. The database is reproducible and provides a unified picture of the structure–activity relationships associated with electrochemical stability of inorganic compounds. This study demonstrates the validity of the improved ESW prediction method and paves the way for accelerated screening of superior SSEs or coatings based on machine learning. [ABSTRACT FROM AUTHOR]

Lattice dynamics has been widely employed to study various properties of crystalline materials, by revealing the atomic vibration rules with phonon dispersion curves. Modulating lattice‐dynamics‐related factors is an emerging trend in the design of inorganic crystalline solid‐state electrolytes (ICSSEs) with promoted ionic conductivity. Nevertheless, due to complicated interplay of these enormous factors, fundamental understanding of lattice‐dynamics‐influenced ionic transport is still limited. In this review, all related factors are classified into lattice static and dynamic ones based on their variability in ionic transport process, facilitating a methodological evaluation of their individual and interrelated influences. The previous efforts are affirmed to design ICSSEs by constructing potential energy surfaces for ionic transport based on lattice static factors (e.g., ionic arrangement, time‐scale dependent ionic concentration, and lattice softening). As for lattice dynamic factors, the possibility to quantify ionic transport activation energy and to screen the type of migration ions by phonon frequency and amplitude, respectively is validated. Specifically, it is highlighted that the optimization of specific phonon mode and the coupling of both lattice static and dynamic factors are essential to achieve superior ionic transport in ICSSEs. Finally, challenges and opportunities are pointed out in this field, which can potentially guide the future development of ICSSEs. [ABSTRACT FROM AUTHOR]

Accurately predicting changes in the potential distribution of crops resulting from climate change has great significance for adapting to and mitigating the impacts of climate change and ensuring food security. After understanding the spatial and temporal suitability of wheat (Triticum aestivum), rice (Oryza sativa), and maize (Zea mays), as well as the main bioclimatic variables affecting crop growth, we used the MaxEnt model. The accuracy of the MaxEnt was extremely significant, with mean AUC (area under curve) values ranging from 0.876 to 0.916 for all models evaluated. The results showed that for wheat, annual mean temperature (Bio-1) and mean temperature of the coldest quarter (Bio-11) contributed 39.2% and 13.4%, respctively; for rice, precipitation of the warmest quarter (Bio-18) and elevation contributed 34.9% and 19.9%, respectively; and for maize, Bio-1 and precipitation of the driest quarter (Bio-17) contributed 36.3% and 14.3%, respectively. The map drawn indicates that the suitability of wheat, rice, and corn in South Asia may change in the future. Understanding the future distribution of crops can help develop transformative climate change adaptation strategies that consider future crop suitability. The study showed an average significant improvement in high-suitable areas of 8.7%, 30.9%, and 13.1%, for wheat, rice, and maize, respectively; moderate-suitable area increases of 3.9% and 8.6% for wheat and rice, respectively; and a decrease of −8.3% for maize as compared with the current values. The change in the unsuitable areas significantly decreases by −2.5%, −13.5%, and −1.7% for wheat, rice, and maize, respectively, compared to current land suitability. The results of this study are crucial for South Asia as they provide policy-makers with an opportunity to develop appropriate adaptation and mitigation strategies to sustain wheat, rice, and corn production in future climate scenarios. [ABSTRACT FROM AUTHOR]

LiNi0.5Mn1.5O4 (LNMO) with a spinel crystal structure presents a compelling avenue towards the development of economic cobalt-free and high voltage (∼ 5 V) lithium-ion batteries. Nevertheless, the elevated operational voltage of LNMO gives rise to pronounced interfacial interactions between the distorted surface lattices characterized by Jahn–Teller (J–T) distortions and the electrolyte constituents. Herein, a localized crystallized coherent LaNiO3 and surface passivated Li3PO4 layer is deposited on LNMO via a one-step calcination process. As evidenced by transmission electron microscopy (TEM), time-of-flight secondary ion mass spectrometry (ToF-SIMS) and density functional theory (DFT) calculation, the epitaxial growth of LaNiO3 along the LNMO lattice can effectively stabilize the structure and inhibit irreversible phase transitions, and the Li3PO4 surface coating can prevent the chemical reaction between HF and transition metals without sacrificing the electrochemical activity. In addition, the ionic conductive Li3PO4 and atomic wetting inter-layer enables fast charge transfer transport property. Consequently, the LNMO material enabled by the lattice bonding and surface passivating features, demonstrates high performance at high current densities and good capacity retention during long-term test. The rational design of interface coherent engineering and surface coating layers of the LNMO cathode material offers a new perspective for the practical application of high-voltage lithium-ion batteries. [ABSTRACT FROM AUTHOR]