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In current land surface models or satellite remote sensing retrievals, clear‐sky surface albedo (α) is usually assumed to be symmetrical and relies only on the solar elevation angle (SEA). Based on 1‐min high‐resolution measurements of surface radiation fluxes, this study demonstrated that the diurnal variations of clear‐sky surface albedo exhibited a significant asymmetrical pattern in both summer and winter seasons over a semi‐arid grassland of the China's Loess Plateau. The results indicated that α values in the morning were generally larger than those in the afternoon at the same SEA, and diurnal asymmetry of surface albedo was distinctly prominent with SEA <40° in summer (before 9:30 a.m.) or SEA <20° in winter (before 10:00 am), and tended to diminish at midday. The averaged morning/afternoon albedo differences under sunny days were 0.05 (30.4%) and 0.09 (37.8%) in summer and winter seasons, respectively. Air relative humidity was positively correlated with the diurnal asymmetry of surface albedo, ascribed to probable formation of dew in the morning. Depression of the dew point was negatively linked to the morning/afternoon albedo differences, which was attributed to the strong scattering of incident sunlight by dewdrops could enhance the morning surface albedo. Such diurnal asymmetry of surface albedo should be included in the parameterization scheme of mesoscale and region‐scale climate models in the semi‐arid areas of China's Loess Plateau. [ABSTRACT FROM AUTHOR]

A Cimel Sun‐sky‐lunar photometer (CE318‐T) is designed to perform daytime and nighttime photometric measurements and calculate diurnal cycle of aerosol optical depth (AOD). Nevertheless, the determination of nocturnal AOD from CE318‐T requires a precise knowledge of extraterrestrial lunar irradiance, which significantly changes with moon's phase angle (MPA) and lunar libration in a single night. This study evaluated the 1‐year nocturnal AODs at Lanzhou by using three different methods, which were validated by collocated measurements of DIAL Lidar (as a reference) and Cimel software (as a proxy). The results indicated that three independent approaches could implement a similar performance to compute nocturnal AOD near full moon phase (i.e., MPA = 0°) under moderate aerosol loading. The spectral AOD values at nighttime calculated by ROLO Lunar Langley (Robotic Lunar Observatory model) and Sun‐moon Gain Factor (SMGF) methods are significantly underestimated under low moon's illumination or high MPA (MPA < −47° or MPA > 47°) and distinctly dependent on MPA. The RIMO correction factor (RCF) (ROLO Implementation for Moon photometry Observation correction factor) method could compensate the underestimated extraterrestrial lunar irradiances of ROLO model for about 6.76%–9.78%, and thus greatly improve the calculation accuracy of nighttime AOD. The day/night coherence transition test has demonstrated that we would obtain a good diurnal variation of AODs at Lanzhou after RCF correction. The overall averages of nocturnal AOD440nm differences between Cimel software and ROLO model and SMGF method are 0.064 ± 0.024 and 0.052 ± 0.022, respectively, while the corresponding difference of RCF is less than 0.021 ± 0.014 for all wavelengths, falling within uncertainty range of AERONET AOD products (∼±0.02). The diurnal variations of AODs determined from RCF method agree well with synchronous results of DIAL Lidar, with total mean AOD532nm differences of 0.038 ± 0.024 and 0.023 ± 0.017 in daytime and nighttime, respectively. The spectral AODs computed from RCF method are well consistent with Cimel software, although there are some discrepancies under low AOD cases (AOD440nm < 0.30), and the overall average of AOD440nm differences are less than −0.0053 ± 0.002 and −0.0185 ± 0.013 in daytime and nighttime, respectively. Our results confirmed that the CE318‐T photometer can be reasonably calculated nighttime AOD and Ångström exponent (AE440–870nm) at urban Lanzhou by using three independent methods, although the former two need to be greatly improved under low moon's illumination. The RCF method was proved to reliably calculate nocturnal AOD from moonlight irradiance, which didn't rely on MPA. A more accurate lunar irradiance model needs to be developed to improve the underestimation of current ROLO model. Long‐term climatological information of nocturnal AOD is crucial for comprehensively characterizing the diurnal variations of aerosol optical properties and atmospheric boundary layer structure during the winter at typical northern city of China, which deserves to be further investigated in the future. Plain Language Summary: Aerosol optical depth (AOD) is an essential physical quantity for characterizing total aerosol concentration and investigating its environmental and climatic effects. Newer photometer technology is increasing our ability to passively observe AODs at nighttime, using the moon as the light source. In this study, we determined the moon calibration coefficients of CE318‐T photometer at Lanzhou and compared the nocturnal AOD with collocated active Lidar observations. The three independent methods could implement a similar performance to compute nocturnal AOD near full moon phase under moderate aerosol loading. Although the RIMO correction factor (Robotic Lunar Observatory [ROLO] Implementation for Moon photometry Observation correction factor) method could compensate the underestimated extraterrestrial lunar irradiances of ROLO model for about 6.76%–9.78%, and greatly improve the calculation accuracy of nighttime AOD, with an accuracy of 0.021 ± 0.014, a more accurate lunar irradiance model needs to be developed to improve the underestimation of current ROLO model. Key Points: The nocturnal aerosol optical depths (AODs) calculated by Robotic Lunar Observatory and Sun‐moon Gain Factor methods are significantly underestimated under low moon's illumination and dependent on moon's phase angle (MPA)The RIMO correction factor (RCF) method can be reliably calculated nocturnal AOD from moonlight irradiance at urban Lanzhou, which didn't rely on MPABoth daytime and nighttime AODs computed from RCF method are well consistent with Cimel software and synchronous measurement of DIAL Lidar [ABSTRACT FROM AUTHOR]

The physicochemical properties and origins of atmospheric aerosols in the Tibetan Plateau (TP) region are a research topic of great interest, but an in‐depth understanding of this topic is challenging, partially due to a lack of intensive in situ observations. Thus, a field campaign was conducted over Yadong, a remote area on the south slope of the TP from June 11 to 31 August 2021. The aerosol loading was low, with a black carbon mass concentration of 147.4 ± 98.4 ng·m−3. Aerosol single‐scattering albedo was low (0.73 ± 0.11 at 550 nm) and increased from 450 to 700 nm wavelength. Organic matter (OM) accounting for 69.6% of the total aerosol mass and relatively high secondary organic carbon ratios, highlighting the importance of secondary formation. An interesting phenomenon observed was that the evolution of aerosols was mainly characterized by diurnal variation, which could not be explained by large‐scale atmospheric processes such as Indian summer monsoon. Instead, it was found that regional mountain‐valley winds between the Himalayas and South Asia transported polluted air masses toward the TP, especially in the afternoon when regional valley wind are expected to be the strongest and the boundary layer in South Asia is deepest. Additionally, daytime local valley wind further elevated these aerosols to higher altitudes on the TP. This paper provides insights into the transport mechanisms of aerosols from South Asia to the TP. These findings are of great importance since aerosols exhibit significant diurnal variations in the TP region. Plain Language Summary: Previous studies focused on the analysis of the physical or chemical properties of aerosols on the Tibetan Plateau, but this study provides a comprehensive examination of both. The findings reveal that aerosols on the southern slope of the Tibetan Plateau exhibit strong absorption efficiency. Aerosol single‐scattering albedo was low (0.73 ± 0.11 at 550 nm), which may be attributed to aerosol secondary generation and coating. Finally, the mechanism of pollutant transport from South Asia to the Tibetan Plateau was analyzed relies on site observations, satellite, and reanalysis data to highlight the link between diurnal variations of pollutants and transport mechanism. The specific transport mechanism be understood uniformly across different scales, including Indian summer monsoon, regional mountain‐valley winds between the Himalayas and South Asia, and local mountain‐valley winds circulation. Key Points: Aerosol single‐scattering albedo was low (0.73 ± 0.11 at 550 nm) and secondary organic matter was the major aerosol componentThe evolution of aerosols was mainly characterized by diurnal variation that was related to transport mechanism over YadongThe Himalayas‐South Asia regional mountain‐valley winds combined with local mountain‐valley winds transport aerosols to the Tibetan Plateau [ABSTRACT FROM AUTHOR]