1. Novel recycling of incinerated sewage sludge ash (ISSA) and waste bentonite as ceramsite for Pb-containing wastewater treatment: Performance and mechanism
- Author
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Shengya Gao, Jing Nie, Yaoyu Zhou, Qiming Wang, Jiang-Shan Li, and Chi Sun Poon
- Subjects
Environmental Engineering ,0208 environmental biotechnology ,02 engineering and technology ,010501 environmental sciences ,Management, Monitoring, Policy and Law ,Complex Mixtures ,Wastewater ,01 natural sciences ,Adsorption ,Waste Management and Disposal ,0105 earth and related environmental sciences ,Aqueous solution ,Sewage ,Precipitation (chemistry) ,Chemistry ,General Medicine ,Pulp and paper industry ,020801 environmental engineering ,Incineration ,Kinetics ,Lead ,Ionic strength ,Bentonite ,Sewage treatment ,Sludge ,Water Pollutants, Chemical - Abstract
With rapid economic growth and urbanisation, the reuse and recycling of solid wastes has become a high priority for the sustainable development of modern cities. In this study, two typical solid wastes, incinerated sewage sludge ash (ISSA) and waste bentonite, were co-valorised to produce granular adsorbents through a simple and energy-saving pelletisation/sintering process. A mixture of ISSA and bentonite at a weight ratio of 3:1 was pelletised and sintered at 700 °C. The resultant ceramsite, with good mechanical strength, could effectively remove Pb(Ⅱ) from aqueous solutions. The adsorption kinetics can be described by the pseudo-first-order (PFO) model. The results indicated that the Pb(Ⅱ) adsorption process was dominated by electrostatic attraction, precipitation, and complexation. The isothermal data exhibited a good correlation with the Freundlich model, indicating that the adsorption process was non-ideal and spontaneous. The maximum adsorption capacity was approximately 21.6 ± 0.35 mg/g at 318 K. After 5 cycles of regeneration, the adsorbent maintained good adsorption performance. Moreover, the removal rate was not greatly affected by ionic strength. These findings demonstrate that the granular adsorbent prepared with ISSA and waste bentonite can be recognised as a promising adsorbent for Pb-containing wastewater treatment.
- Published
- 2020