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Methods that allow the self-assembly of colloidal nano/micro-particles into controllable structures are highly important in many applications, such as photonics, biosensors and electronic chemicals. However, the complicated procedures, low assembly efficiency and multiscale integration of self-assembly of colloidal particles have become great challenges. Here, we first develop a hydrophobic-force-induced self-assembly (HFSA) method to fabricate homogeneous and binary colloidal microdroplets by the feed of volatile fluorocarbon oil. Specially, both mono-color and dual-color colloidal photonic crystals (CPCs) can be architected via HFSA in an efficient (within 200 s), coffee-ring free and visualized fashion. Additionally, such effective HFSA process is further confirmed by dissipative particle dynamics (DPD) simulations. Moreover, a variety of multi-structural colored CPCs are available by using hydrophobic reagents, combining with the visualized HFSA process. This work presents an easy-to-perform platform for designing orderly structural materials, which will significantly highlight the development of colloidal assembly methodology.

Molecular dynamics (MD) simulations were conducted for a CL-20/DNB (2, 4, 6, 8, 10, 12-hexanitro-2, 4, 6, 8, 10, 12-hexaazaisowurtzitane/1, 3-dinitrobenzene) co-crystal based PBX (Polymer-bonded explosive) with HTPB (hydroxyl-terminated polybutadiene). The binding energies, pair correlation functions and mechanical properties of the PBX were reported. From the calculated binding energy (E bind), it was found that the order of the binding energies between the crystalline surfaces (1 0 0), (0 1 0) and (0 0 1) and HTPB is (1 0 0) > (0 0 1) > (0 1 0). And it was also shown that the interactions between the crystalline surfaces and HTPB originate mainly from vdW energies. The pair correlation function revealed that H···O hydrogen bonds exist on the interfaces between the crystalline surfaces and HTPB. From the calculated mechanical data, the co-crystal/HTPB was inferred that the PBX has a higher buffer for external stimuli and reduces the formation probability of hot spots.

Frequent occurring of haze pollution events and high fine particulate matter (PM(2.5)) concentration in China have attracted more and more attention in the world. Satellite remote sensing can be used to characterize the air pollution. However, haze is usually misidentified as fog, thin cloud or bright surface in NASA’s Moderate Resolution Imaging Spectrometer (MODIS) cloud and clear days’ aerosol products, and the retrieval of its optical properties is not included in MODIS cloud detection and dark target algorithm. This approach first studies the spectral characters of cloud, fog, haze, and land cover pixels. Second, following the previous cloud detection and aerosol retrieval literatures, a threshold algorithm is developed to distinguish haze from other pixels based on MODIS multi-band apparent reflectance and brightness temperature. This algorithm is used to detect the haze distribution over North China Plain in 2008 spring and summer. Our result shows a good agreement with the true-color satellite images, which enhances MODIS’s ability to monitor the severe air pollution episodes. In addition, the high AOD data from Beijing and Xiang Aerosol Robotic NETwork (AERONET) sites indicate nearly 80% haze days are detected by our approach. Finally, we analyze the errors and uncertainties in haze detection algorithm, and put forward the potential improvements.

Recently, Magnesium hydride MgH2is one of the attractive hydrogen storage materials because it reaches a high hydrogen capacity. However, the reaction kinetics is too slow and needs high temperature for progressing hydrogen absorption and desorption reactions, which hinders the process of practical applications and it is necessary to improve the hydrogen storage propesties. In this paper, most used or under research methods (Doping with metal and compound) of improving on the hydrogen storage of magnesium hydride are reviewed, in particular to elements substitution, addition of transition metal oxides or fluorine and so on. The advantages and disadvantages of vaious methods of improving on the hydrogen storage of magnesium hydride are compared. The trend of the methods of improving is also introduced.

The indoor and outdoor concentrations of carbonyl compounds (aldehydes and ketones), aromatic hydrocarbons (i.e. benzene, toluene, ethylbenzene, o,m,p-xylenes, and styrene), and total volatile organic compounds (TVOC) were monitored in a Beijing-based large furniture mall between January and July 2010. The furniture mall was heavily polluted with these organic air pollutants, with indoor concentrations much higher than outdoors. Formaldehyde was the most abundant carbonyl compound, followed by acetone, acetaldehyde, C4 carbonyls (2-butanone and butyraldehyde) and hexaldehyde, while propionaldehyde, benzaldehyde and valeraldehyde occurred at lower level. The abundance of aromatic hydrocarbons decreases in the following order: o,m,p-xylenes, toluene, ethylbenzene, styrene and benzene. The carbonyl compounds had significantly higher indoor concentrations in summer than in winter and spring, with total concentrations of 621.7 ± 218.2, 106.8 ± 63.9 and 115.8 ± 23.7 μg m−3, respectively, due to seasonal differences in environmental factors, i.e. temperature and relative humidity. In contrast, no significant seasonal difference was observed for indoor aromatic hydrocarbon and TVOC concentrations, although the average concentrations were higher in summer than in the other two seasons. No significant correlation was observed between carbonyl compounds and aromatic hydrocarbons. This lack of correlation is further evidenced by their different distribution in specific sections of the furniture mall.

Molecular dynamics (MD) simulations were carried out to study the polymer-bonded explosives (PBXs) where the explosive base was the well-known high energy co-crystal compound, 2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexazaisowurtzitane/2,4,6-trinitrotoluene (CL-20/TNT), and the polymer binders were fluorine rubber (F[Formula: see text], fluorine resin (F[Formula: see text], polyvinyl acetate (PVAc) and polystyrene (PS), respectively. The binding energies, pair correlation functions (PCFs) and mechanical properties of the PBXs were reported. According to our theoretical results of binding energies, the compatibility of the PBXs is predicted to be in the following order: CL-20/TNT/PVAc[Formula: see text] CL-20/TNT/F[Formula: see text] [Formula: see text] CL-20/TNT/PS [Formula: see text] CL-20/TNT/F[Formula: see text]. The binding energies of the PBXs on three crystalline surfaces, (100), (001), (010), of the CL-20/TNT co-crystal were also compared: CL-20/TNT(100)[Formula: see text]CL-20/TNT(001)[Formula: see text]CL-20/TNT(010) for F[Formula: see text], F[Formula: see text], and PS; CL-20/TNT(001)[Formula: see text]CL-20/TNT(100)[Formula: see text]CL-20/TNT(010) for PVAc. The PCF analysis reveals that there exist H-bonds between H and O, F, and N atoms on all three interfaces and among all H-bonds, N H-bond has the fewest number. For the CL-20/TNT co-crystal, the moduli can be reduced by adding a small amount of the polymer binders but the ductility can be prolonged only by F[Formula: see text] and F[Formula: see text].

Biomass burning makes up an important part of both trace gases and particulate matter emissions, which can efficiently degrade air quality and reduce visibility, destabilize the global climate system at regional to global scales. Burned area is one of the primary parameters necessary to estimate emissions, and considered to be the largest source of error in the emission inventory. Satellite-based fire observations can offer a reliable source of fire occurrence data on regional and global scales, a variety of sensors have been used to detect and map fires in two general approaches: burn scar mapping and active fire detection. However, both of the two approaches have limitations. In this article, we explore the relationship between hotspot data and burned area for the Southeastern United States, where a significant amount of biomass burnings from both prescribed and wild fire took place. MODIS (Moderate resolution imaging spectrometer) data, which has high temporal-resolution, can be used to monitor ground biomass. burning in time and provided hot spot data in this study. However, pixel size of MODIS hot spot can't stand for the real ground burned area. Through analysis of the variation of vegetation band reflectance between pre- and post-burn, we extracted the burned area from Landsat-5 TM (Thematic Mapper) images by using the differential normalized burn ratio (dNBR) which is based on TM band4 (0.84 μm) and TM band 7(2.22 μm) data. We combined MODIS fire hot spot data and Landsat-5 TM burned scars data to build the burned area estimation model, results showed that the linear correlation coefficient is 0.63 and the relationships vary as a function of vegetation cover. Based on the National Land Cover Database (NLCD), we built burned area estimation model over different vegetation cover, and got effective burned area per fire pixel, values for forest, grassland, shrub, cropland and wetland are 0.69, 1.27, 0.86, 0.72 and 0.94 km2 respectively. We validated the burned area estimates by using the ground survey data from National interagency Fire Center (NIFC), our results are more close to the ground survey data than burned area from Global Fire Emissions Database (GFED) and MODIS burned area product (MCD45), which omitted many small prescribed fires. We concluded that our model can provide more accurate burned area parameters for developing fire emission inventory, and be better for estimating emissions from biomass burning.

In the present, for the characteristic of HJ-1 CCD camera, after receiving aerosol optical depth (AOD) from deep blue algorithm which was developed by Hsu et al. assisted by MODerate-resolution imaging spectroradiometer (MODIS) surface reflectance database, bidirectional reflectance distribution function (BRDF) correction with Kernel-Driven Model, and the calculation of viewing geometry with auxiliary data, a new atmospheric correction method of HJ-1 CCD was developed which can be used over vegetation, soil and so on. And, when the CCD data is processed to correct atmospheric influence, with look up table (LUT) and bilinear interpolation, atmospheric correction of HJ-1 CCD is completed quickly by grid calculation of atmospheric parameters and matrix operations of interface define language (IDL). The experiment over China North Plain on July 3rd, 2012 shows that by our method, the atmospheric influence was corrected well and quickly (one CCD image of 1 GB can be corrected in eight minutes), and the reflectance after correction over vegetation and soil was close to the spectrum of vegetation and soil. The comparison with MODIS reflectance product shows that for the advantage of high resolution, the corrected reflectance image of HJ-1 is finer than that of MODIS, and the correlation coefficient of the reflectance over typical surface is greater than 0.9. Error analysis shows that the recognition error of aerosol type leads to 0. 05 absolute error of surface reflectance in near infrared band, which is larger than that in visual bands, and the 0. 02 error of reflectance database leads to 0.01 absolute error of surface reflectance of atmospheric correction in green and red bands.

With the urbanizing in China, haze days occur frequently, which have largely impacted air quality. In the present paper, based on haze physical properties, haze optical properties were calculated by Mie theory and apparent reflectance of haze in Environment Satellite 1 (HJ-1) channels was simulated by Radiative Transfer (RT) 3. Simulated results show that it is reasonable to extract the haze from apparent reflectance in the first and second channels. By Deep Blue algorithm, Haze Optical Depth (HOD) was retrieved from HJ-1 data supported by reflectance database from MODIS product. From HJ-1 data in 2009 over Beijing area, the haze days were monitored and validated by AERONET/PHOTONS Beijing site. The validation shows that the correlation coefficient of HOD is greater than 0.9, but HOD from HJ-1 is greater than that from ground-based measurements. The discussions show that the error from reflectance database is less than 0.1 and radiance resolution of HJ-1 needs to advance for haze monitoring.

Generally, aerosols over land are composed of fine and coarse aerosols, which have different optical properties. How to derive the fine mode and coarse mode aerosols from satellite observations is an important issue in the aerosol retrieving. In the present paper, information of aerosol models (including refractive index and size distribution function) was retrieved from the ground-based measurement of the AERONET/PHOTONS site in Beijing. The retrievals indicate that, aerosols over Beijing have a bi-model distribution, and the optical properties of fine and coarse aerosols are distinct. Based on the dark dense vegetation (DDV) method, optical depth of the fine, coarse and total aerosols were derived from MODIS data over Beijing area in 2007. The validation of these satellite retrievals shows that from MODIS data, the optical depth of fine and total aerosols can be retrieved well (with correlation coefficients greater than 0.8), and so can the Angstrom exponent (having a correlation coefficient of 0.517). However, relatively poor results were obtained when retrieving the optical depth of coarse aerosols.

The potentiality of the retrieval of surface reflectance using CCD camera aboard HJ-1A/B satellite was studied. It is very difficult to use dark targets in atmospheric correction due to the lack of near infrared band. The alternative normalized difference vegetation index (NDVI) and the red/blue reflectance ratio are detected from the spectral experiment in Beijing and the Pearl River Delta. Ground-based spectral data including grass, dense vegetation, water body, soil, residential roof and bright building etc. were used to validate the surface reflectance in Beijing, and the relative error in red, blue band is under 38.7% and 37.2% respectively. Uncertainties of the surface reflectance retrievals were analyzed. The comparison of MODIS surface reflectance product showed that there is a good agreement in the dense targets, and the correlation coefficient (R2) in red, blue band is as high as 0.809 4 and 0.723 9 respectively. HJ-1-CCD data can effectively reduce pixel-mixed impact on the cement roof and bright buildings, and the inversion accuracy is higher than MODIS products.

Concentrations of BTX (benzene, toluene and xylene), total volatile organic compounds (TVOC), formaldehyde and other carbonyl compounds were measured in different sections of a furniture mall in Beijing. The overall indoor concentrations (mean +/- standard deviation) of formaldehyde, benzene, toluene, xylene, and TVOC were (0.37 +/- 0.08), (0.04 +/- 0.03), (0.19 +/- 0.16), (0.47 +/- 0.57), and (2.76 +/- 2.18) mg/m3, respectively. Indoor concentrations of formaldehyde, xylene and TVOC were 22, 46 and 34 times higher than the corresponding outdoor concentrations respectively. Concentrations of formaldehyde, xylene and TVOC were much higher than the standard limits regulated in the national "indoor air quality standard" (GB/T 18883-2002), and the highest concentrations of formaldehyde and TVOC exceeded the standard limit 5.1 and 14.8 times respectively. Total concentration of carbonyl compounds was (689.3 +/- 94.8) microg/m3, which was 5 times higher than that outdoors. Of the carbonyls, formaldehyde and acetaldehyde were found to be the most abundant, together accounting for over 75% of the total carbonyl concentrations. Acetone, C4 carbonyls (methacrolein, methyl ethyl ketone, butanal), and hexanal also occurred at relatively high concentrations. In conclusion, indoor air pollution is serious in the furniture mall.

To investigate the usability of laboratory test report from the angle of patients and understand to what degree the patients master the knowledge of lipid-lowering.A total of 508 outpatients, selected from a Grade III-A general hospital, were queried by a questionnaire, their medical records and test reports were reviewed and their heights and weights were measured. In the study, 431 of them fulfilled the inclusion criteria and their information about lipid lowering treatment and treatment compliance were collected.Of the 508 subjects, 90.2% (458/508) read the report seriously; however, only 47.4% (240/508) took drugs according to the doctor's prescription even if the tests were "normal". Of the 431 lipid-lowering therapy related patients, only 26.4% (112/431) chose right in their cardiovascular risk classification, and less than 37.1% (160/431) agreed that "different people had different lipid lowering target". Of the 381 patients who needed the lipid-lowering treatment, 71.7% (273/381) recognized the need for treatment, but 98.7% (376/381) answered a wrong target for treatment; 60.9% (232/381) recognized that the reference values given in the laboratory test reports should be the target for treatment. Of the 246 patients under the lipid-lowering treatment, 35.4% (87/246)had reached their treatment goals, and only 52.0% (128/246) had a good compliance.Most patients read and trusted the laboratory test reports. However, dyslipidemia patients scarcely knew their lipid lowering treatment goals and their cardiovascular risk levels. The compliance of patients was poor, and the goal attainment was low. The laboratory medicine department should find out a simple and intuitional way to change the current situation.

The Ring effect is a significant limitation to the accuracy of the retrieval of trace gas constituents in atmosphere, while using satellite data with differential optical absorption spectroscopy technique. The Ring effect refers to the filling in of Fraunhofer lines, known as solar absorption lines, caused almost entirely by rotational Raman scattering. The inelastic component of the molecular scattering results in a net increase in radiance in the line because more radiation is shifted to the wavelength of an absorption line than shifted from this wavelength to other wavelengths. The rotational Raman scattering by N2 and Oz in the atmosphere is the main factor that leads to Ring effect. Basically, the Ring effect is considered as a pseudo-absorption process in retrieval of trace gas constituents in atmosphere. The solar spectrum measured by OMI/AURA is convolved with rotational Raman cross sections of N2 and O2, divided by the original solar spectrum, with a cubic polynomial subtracted off, to create differential Ring spectrum. This method has been suggested in order to obtain an effective differential Ring cross-section for the DOAS fitting process. The differential Ring spectrum could be used to improve the accuracy of the retrieval of the trace gases concentration. The results in this paper have been in basic agreement with the corresponding results calculated with RTM, and the R2 Statistic is 0. 966 3.