1. Revisiting iron oxidation chemistry in synthesis flames: Insights from a shock-tube study with intracavity laser absorption spectroscopy tracking of FeO
- Author
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Matthieu R. Lalanne, Sheikh Ahmed Mujaddadi, Peter Fjodorow, Sergey Cheskis, Holger Somnitz, Irenaeus Wlokas, Jürgen Herzler, Mustapha Fikri, Christof Schulz, and Igor Rahinov
- Subjects
Shock tube ,Intracavity absorption spectroscopy ,Iron oxidation ,Flame synthesis ,Fuel ,TP315-360 ,Energy industries. Energy policy. Fuel trade ,HD9502-9502.5 - Abstract
The reaction between Fe atoms and O2 in a mixture of iron-pentacarbonyl (IPC, 2 ppm) and oxygen (100 ppm), diluted in argon, has been studied in a shock tube behind reflected shock waves over the temperature and pressure ranges of 1050–3400 K and 0.7–2.0 bar. Time-resolved measurements of Fe and FeO have been performed simultaneously using a combination of atomic resonance absorption spectroscopy (ARAS) and intracavity laser absorption spectroscopy (ICAS) with a custom-made broadband dye laser, respectively. For ICAS, absorption features in the spectral range from 16,316 to 16,353 cm−1 have been evaluated, and the oscillator strengths for all 41 assigned ro-vibronic transitions have been expressed. For most of the experimental cases, the measured Fe and FeO traces agreed well with the mechanism reported in this work. The quantitative and highly-sensitive measurements revealed the presence of FeO at temperatures below 1400 K, leading to a reconsideration of rate coefficients for different Fe oxidation channels.
- Published
- 2023
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