Search

Small organic compounds without any traditional fluorescent chromophores are generally non‐emissive, and only very few are reported to emit weak blue fluorescence. Here we synthesized a non‐traditional luminescent small organic compound N‐(2,2,2‐trifluoroethyl)acrylamide (TFAM) with dramatically enhanced and red‐shifted photoluminescence by introducing a strong electron‐withdrawing group into acrylamide (AM). Very impressively, TFAM emits cyan (472 nm) and yellow‐green (560 nm) fluorescence in solutions and solid state, respectively. TFAM also shows aggregation‐induced emission enhancement (AIEE) and excitation‐dependent fluorescence (EDF) characteristics, as well as temperature and metal cations‐responsive fluorescence. Theoretical calculations show that the introduction of electron‐withdrawing group leads to a lower energy gap between the HOMO–LUMO energy levels in TFAM than in AM. And strong cooperative hydrogen bonds are formed in TFAM molecules, resulting in rigidification of molecular conformations. The study provides a strategy for preparing non‐traditional luminescent compounds with enhanced and red‐shifted photoluminescence. [ABSTRACT FROM AUTHOR]

Herein, it is demonstrated that a small amount (0.05% in weight ratio) of polyethyleneimine (PEI) can effectively suppress the "burn‐in" degradation of both PTB7‐Th:PC61BM and P3HT:PC61BM cells, similar to the piperazine derivatives, suggesting that organic amines can serve as universal stabilizer in polymer:PC61BM solar cells. Light‐induced electron spin resonance (LESR) spectroscopy measurement shows a higher ESR signal intensity of PC61BM anions in 0.2% PEI‐doped film than in 1% piperazine‐doped film. Moreover, no piperazine is detected in a 10% (w/w) piperazine‐doped film by gas chromatography–mass spectrometry (GSMS). These results suggest that the residual piperazine in the blend film is very low, which can be understood by the high volatility of piperazine. Quantum calculations are performed on the intermolecular binding energy (EB) between polymer (using model repeating units), PC61BM, and piperazine molecules. Results reveal that piperazine prefers to localize at the polymer:fullerene interface by complexing with PC61BM (in P3HT:PC61BM) or PTB7‐Th (in PTB7‐Th:PC61BM system), which indicates that the photo dimerization of PC61BM which causes the "burn‐in" degradation of polymer:fullerene solar cells mainly happens at the donor/acceptor interface, and the organic amine serves as the targeting stabilizer at the interface. [ABSTRACT FROM AUTHOR]