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Advanced processes for peroxymonosulfate (PMS)-based oxidation are efficient in eliminating toxic and refractory organic pollutants from sewage. The activation of electron-withdrawing HSO5− releases reactive species, including sulfate radical (·SO4−), hydroxyl radical (·OH), superoxide radical (·O2−), and singlet oxygen (1O2), which can induce the degradation of organic contaminants. In this work, we synthesized a variety of M-OMS-2 nanorods (M = Co, Ni, Cu, Fe) by doping Co2+, Ni2+, Cu2+, or Fe3+ into manganese oxide octahedral molecular sieve (OMS-2) to efficiently remove sulfamethoxazole (SMX) via PMS activation. The catalytic performance of M-OMS-2 in SMX elimination via PMS activation was assessed. The nanorods obtained in decreasing order of SMX removal rate were Cu-OMS-2 (96.40%), Co-OMS-2 (88.00%), Ni-OMS-2 (87.20%), Fe-OMS-2 (35.00%), and OMS-2 (33.50%). Then, the kinetics and structure–activity relationship of the M-OMS-2 nanorods during the elimination of SMX were investigated. The feasible mechanism underlying SMX degradation by the Cu-OMS-2/PMS system was further investigated with a quenching experiment, high-resolution mass spectroscopy, and electron paramagnetic resonance. Results showed that SMX degradation efficiency was enhanced in seawater and tap water, demonstrating the potential application of Cu-OMS-2/PMS system in sewage treatment. [ABSTRACT FROM AUTHOR]

Biogas has improved due to technological advancements, environmental awareness, policy support, and research innovation, making it a more cost-effective and environmentally friendly renewable energy source. The Generalized Linear Model (GLM) was employed to examine the relationship between purchased and generated energy from 2007 to 2023. Metrics such as deviance, log likelihood, and dispersion phi were examined to assess model fit. The Mann–Kendall test was utilized to detect trends in energy datasets. Biochemical Oxygen Demand (BOD5) and Chemical Oxygen Demand (COD) reduction was significant, exceeding 97% from 2014 to 2023. However, treated sewage displayed limited susceptibility to biological degradation, with COD to BOD5 ratios increasing from 2.28 to 6.59 for raw sewage and from 2.33 to 7.05 for treated sewage by 2023. Additionally, the efficiency of sewage purification processes was calculated, and multivariate regression analysis was conducted on gas composition data. Principal Coordinate Ordination (PCO) and k-means clustering were used for dimensionality reduction and biogas component clustering, respectively. This research showed that biogas from the waste water treatment process can be used, particularly in methane production. Technological advancements have made biogas production more efficient, enhancing energy generation within a circular economy framework. [ABSTRACT FROM AUTHOR]

TiO2 photocatalyst has the advantages of high catalytic activity, suitable energy band potential, high chemical stability, high photoelectric conversion efficiency, high safety and non-toxicity, which exhibits excellent performances in photocatalytic degradation of organic wastewater. However, it is difficult to separate and recover TiO2 photocatalyst from the reactive system. Interestingly, magnetic TiO2 prepared by combining TiO2 with superparamagnetic ferromagnetic particles can overcome this shortcoming. In this review, the preparation method and the photocatalytic mechanism of magnetic TiO2 were summarized. Moreover, the catalytic mechanisms of the modified binary, ternary and multicomponent magnetic TiO2 composite photocatalysts were compared, and the effects of different magnetic substrates on the degradation activity were discussed. Besides the applications in the wastewater treatment, the development trend and application prospects were prospected. [ABSTRACT FROM AUTHOR]

Copyright of Bulletin of the Chinese Ceramic Society is the property of Bulletin of the Chinese Ceramic Society Editorial Office and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The present research aimed to explore the durability of MMO electrodes through electro-oxidation (EO) in purifying secondary treated actual sewage wastewater using batch and pilot-scale setups. The main aim is to inactivate bacteria in sewage treatment plants before they are released into the environment, thus contaminating water and soil. Process parameters such as current density (j), NaCl dose (n), and treatment time (t) were optimized using response surface methodology in a lab-scale EO reactor under batch conditions. The results showed that optimization of current density at 5.90 mA/cm2 and NaCl concentration at 1.31 g/L led to 93.90% of bacterial inactivation (Q1) within 8 min of treatment and 0.48 kWh/m3 energy consumption (Q2). Biological analysis was conducted to validate bacterial cell destruction and count coliform bacteria in the EO-treated sewage wastewater. XRD, cyclic voltammetry studies, and FE-SEM/EDS analysis were done to confirm the MMO anode's durability and stability after 100 recycles. The study prioritized bacterial inactivation along with organic matter degradation. Besides that, a small pilot-scale study on the actual sewage wastewater with a volume of 10–50 L was done in batch mode under previously optimized conditions to analyze the efficacy of the MMO anodes in terms of bacterial inactivation. [ABSTRACT FROM AUTHOR]

The aim of this study was to measure consequences of the arsenic pollution released from a sewage treatment plant into the seawater in Jazan province in the southwest of Saudi Arabia. The impact of the release of arsenic on the ecosystem is the adsorption of arsenic by sea plants. To do so, samples were collected alongside a distance of seven kilometers from the treatment plant. The algae samples: Sargassum sp., Cladophora sp., and seagrasses: Halodule uninervis and Cymodocea rotunda were digested in nitric acid, and the assays of arsenic levels were taken by ICP-AES according to EPA methods. The results showed that algae are more efficient than seagrass with absorbing arsenic. Also, the treatment plant was not the only source of arsenic contamination, as ships and boats were adding more arsenic to the ecosystem.

Aerobic granular sludge (AGS) is an emerging replacement for activated sludge for advanced and sustainable wastewater treatment. This study examined the beneficial effect of granular activated carbon (GAC) addition on AGS formation and sewage treatment in tropical climates. GAC shortened the start-up period for granulation by minimizing sludge washout. Ammonium was removed effectively through partial nitrification and denitritation. Enhanced biological phosphate removal was established with ~98% removal efficiencies. Improved granulation, enrichment of polyphosphateaccumulating organisms, and establishment of enhanced biological phosphate removal pathways in tropical climates recommend GAC addition as a simple and potential start-up strategy for AGS-based biological wastewater treatment. [ABSTRACT FROM AUTHOR]

The combination of photovoltaic system and electrochemical technology can not only improve the treatment efficiency, reduce energy consumption and operating costs, but also help promote the application of clean energy in environmental protection and water resources management, and has a good application prospect for achieving sustainable and efficient sewage treatment. The application of photovoltaic conversion of solar energy in wastewater treatment is described, and the research progress of photovoltaic conversion in electrooxidation system, reverse osmosis process, electrocoagulation process, aeration equipment, electroflocculation technology and fenton technology is reviewed. The future research direction of solar energy application in wastewater treatment is also proposed [ABSTRACT FROM AUTHOR]

Photocatalysis is a promising technology for efficient sewage treatment, and designing a reactor with a stable loading technique is crucial for achieving long-term stability. However, there is a need to improve the current state of the art in both reactor design and loading techniques to ensure reliable and efficient performance. In this study, we propose an innovative solution by employing polydimethylsiloxane as a bonding layer on a substrate of 3D-printed polyacrylic resin. By means of mechanical extrusion, the active layer interacts with the bonding layer, ensuring a stable loading of the active layer onto the substrate. Simultaneously, 3D printing technology is utilized to construct a photocatalytic reactor resembling a "Kongming Lantern", guaranteeing both high activity and durability. The reactor exhibited remarkable performance in degrading organic dyes and eliminating microbes and displayed a satisfactory purification effect on real water samples. Most significantly, it maintained its catalytic activity even after 50 weeks of cyclic degradation. This study contributes to the development of improved photocatalysis technologies for long-term sewage treatment applications. [ABSTRACT FROM AUTHOR]

The reutilization of municipal solid waste incineration (MSWI) fly ash is a prominent area of research. This study focused on creating fly ash porous plate filler (FAPPF) by using techniques, such as water extraction, milling, component adjustment, and sintering. The produced FAPPF was then used to cultivate a biofilm for wastewater treatment. The key parameters included a two‐stage water extraction process with a 5:1 liquid‐to‐solid ratio; milling for 1, 2, and 4 h; component adjustment using waste glass powder, milled fly ash, palygorskite powder, and peanut shell powder at a 7:1:1:1 mass ratio; and sintering temperatures ranging from 700 to 1000°C. For the biofilm cultivation and treatment, this study employed semisimulated sewage in a sequencing biofilm batch reactor system. The results revealed the FAPPF had no heavy metal leaching, with a porosity of 48.53%–54.68%. Approximately 90% of its composition was derived from waste materials. Furthermore, scanning electron microscopy microanalysis revealed an internally stable liquid‐phase sintering structure. Finally, a mature biofilm developed in 21 days, achieving maximum removal rates of 95.48% for chemical oxygen demand and 78.4% for ammonia nitrogen. This article confirms the sustainable recycling potential of MSWI fly ash. [ABSTRACT FROM AUTHOR]

Rainwater and sewage are important pollution sources for surface water bodies. Vertical greening systems (VGSs) are extensively employed for these wastewater treatments due to the green and sustainable characteristics, as well as their high-efficiency in pollutant (organic matter, nitrogen, and phosphorus) removal. At present, more and more VGSs are designed with green buildings, serving city ecosystems. This study provides an overview of different kinds of VGSs for rain and sewage treatment, emphasizing their types, design, mechanisms, selection of plants, and growth substrate. Plants play a crucial role in pollutant removal, and different plants usually obtain different efficiencies of water treatment. Climbing plants and ornamental plants with fast growth rates are priority selections for VGSs, including Canna lilies, Jasmine, Grape vine, Boston ivy, Pittosporum tobira, Pelargonium australe, Mentha aquatica, and Lythrum salicaria. The substrate is the most critical part of the VGS, which plays an important role in regulating water flow, supporting plant growth, promoting biofilm growth, filtering pollutants, and adsorbing nutrients. The single substrate either has a blockage problem or has a short holding time. Therefore, a number of studies have mixed the substrates and integrated the advantages of the substrates to form a complementary effect, thereby improving the overall purification efficiency and stability. Novel substrates (sand, spent coffee grounds, date seeds, coffee grinds, reed-based, etc.) are usually mixed with coco coir, light-weight expanded clay, growstone, or perlite at a certain ratio to obtain optimum treatment performance. Moreover, plants in clay show more significant growth advantages and health statuses than in zeolite or soil. Operating parameters are also significant influences on the treatment performance. This review provides theoretical and technical support for designing sustainable, environmentally friendly, and cost-effective VGSs in treating rainwater and sewage. [ABSTRACT FROM AUTHOR]

The widespread use of organophosphorus flame retardants (OPFRs) in industrial and household products increases the risk of their environmental exposure, posing a serious threat to ecosystems and human health. Photocatalytic technology has been widely used in wastewater treatment due to its high efficiency, mild reaction conditions, and robustness. This review summarizes the current status of research on photocatalytic degradation of OPFRs, focusing on the effect of different types of catalysts on the degradation efficiency, the effects of pH, and co-existing inorganic and organic ions. And pH and co-existing inorganic mainly affect the active oxygen and the active surface sites of the catalyst. In addition, toxicological calculations of the intermediates of the degradation pathway using T.E.S.T. and ECOSAR showed that photocatalysis could effectively reduce the toxicity of OPFRs. Development of new photocatalytic materials, in-depth study of the degradation mechanism of different catalysts and flame retardants, and attention to practical applications and toxicity issues can be the development direction of future research. [ABSTRACT FROM AUTHOR]

In addition to filtering some sediments, hydrophobic wood sponges can also absorb many organic solvents, particularly crude oil. The leakage of crude oil poses a serious threat to the marine ecosystem, and oil mixed with water also generates great danger for its use. From the perspective of low cost and high performance, wood sponges exhibit great potential for dealing with crude oil pollution. Wood sponge is a renewable material. With a highly oriented layered structure and a highly compressible three-dimensional porous frame, wood sponges are extremely hydrophobic, making them ideal for oil–water separation. Currently, the most common approach for creating wood sponge is to first destroy the wood cell wall to obtain a porous-oriented layered structure and then enhance the oil–water separation ability via superhydrophobic treatment. Wood sponge prepared using various experimental methods and different natural woods exhibits distinctive properties in regards to robustness, compressibility, fatigue resistance, and oil absorption ability. As an aerogel material, wood sponge offers multi-action (absorption, filtration) and reusable oil–water separation functions. This paper introduces the advantages of the use of wood sponge for oil–water separation. The physical and chemical properties of wood sponge and its mechanism of adsorbing crude oil are explained. The synthesis method and the properties are discussed. Finally, the use of wood sponge is summarized and prospected. [ABSTRACT FROM AUTHOR]

The issue of water pollution is one of the hot topics of global concern, which requires us to efficiently treat pollutants in water, especially printing and dyeing sewage. There are varieties of dyestuffs and intermediates, which are complex and difficult to degrade, and they even contain heavy metals. In this study, a bacterial strain named Q3-6 with potential for sewage treatment was isolated and its physiological, biochemical, and genomic characteristics, and potential application value, were further investigated. The genome sequence confirmed that it belongs to Bacillus thuringiensis. Strain Q3-6 has a significant decolorization effect on the dyes. The decolorization rate for Brilliant blue G-250 (0.1 g/L) and Congo Red (0.1 g/L) can reach 93.9% and 91.9%, respectively. In addition, strain Q3-6 is resistant to many kinds of antibiotics and heavy metals. Further, it has strong heat resistance, and heating at 80 °C can promote the biomass of the strain. Genomic analysis revealed the presence of genes related to heat shock proteins (GroES, GrpE, DnaJ, GroEL, DnaK, ClpB, and ClpA) in strain Q3-6. These results suggest the strain's exceptional resilience and adaptability to intricate environments with heavy metals, antibiotics, or high-temperature environments, suggesting its pivotal role in the bioremediation of complex contaminated effluents. [ABSTRACT FROM AUTHOR]

Relative efficacy of five common weeds—of the kind that are either rooted in soil or which freely float over water—was assessed in rapid, effective and sustainable treatment of sewage at pilot plant scale in the recently developed and patented SHEFROL® bioreactors. The plants were utilized in a unit of capacity 12,000 liters/day (LPD) which, after two years of use, was enlarged to handle 40,000 LPD of sewage. It was then further expanded after an year to treat 57,000 LPD. All the five weeds, of which none has previously been tested in a pilot-scale SHEFROL, were able to foster highly efficient primary treatment (in terms of suspended and total solids) and secondary treatment (in terms of BOD and COD) to levels exceeding 85% in most cases. Additionally, the weeds also helped in achieving significant tertiary treatment. At different hydraulic retention times, and at steady state, the five weeds achieved treatment of BOD, COD, suspended solids, nitrogen, phosphorous, copper, nickel, zinc, and manganese in the ranges, 80–95, 79–91, 82–95, 61–71, 51–73, 37–43, 30–38, 39–47, and 27–35%, respectively. It all occurred in a single process step and without the use of any machine or chemical. This made the system not only simple and inexpensive to install but also to maintain. Over continuous long-term operation for four years, the system was seen to be very robust as it was able to handle wide variations in the volumes and characteristics of sewage, as well as absorb shock loads without compromising the reactor performance. The sustainability of the system can be further enhanced by upgrading it to a circular biorefinery. Energy sources in the form of volatile fatty acids (VFAs) can be extracted from the weeds removed from SHEFROL and then the weeds can be converted into organic fertilizer using high-rate vermireactors recently developed by the authors. A novel and inexpensive, yet very efficient sewage treatment system is presented. The versatility and robustness of the system has been assessed at pilot plant scale for several years. The long-term continuous studies establish the efficacy of five common weeds—not hitherto explored at pilot plant level—which can serve as the main bioagent(s) in the sewage treatment system. The system has the potential of being transformed in to a closed-loop-no-waste biorefinery [ABSTRACT FROM AUTHOR]

Recently, membrane bioreactors (MBRs) have emerged as a promising approach for sewage treatment because of their high efficiency in removing contaminants. However, they are prone to membrane-fouling and computational loading. To resolve these issues, this research article presents an innovative control strategy combining both artificial bee colony optimization (ABC) and recurrent neural network (RNN) to regulate the performance of MBR in sewage treatment. Initially, the influent wastewater data were collected and pre-processed using the regression imputation approach. RNN architecture was designed and trained using the pre-processed data to forecast the performance of the MBN system. Further, the ABC algorithm was applied to optimize the function of MBR by adjusting the control variables. The developed model was validated with the publically available wastewater treatment plan dataset and the effectiveness of the developed model was validated by performing intensive performance and comparative assessment. The performance evaluation demonstrates that the proposed methodology attained greater results of 98.59% effluent quality, 98.70% of nutrient removal efficiency, less computational time of 2.87 s, and a low membrane-fouling index of 1.23%. The comparative analysis illustrates that the presented approach achieved improved performances than the existing methodologies. [ABSTRACT FROM AUTHOR]

During the production process of sulfide lead-zinc ore using the flotation method, a large amount of beneficiation wastewater is generated. The pH value, suspended solids, chemical oxygen demand, heavy metal ions, etc. in the beneficiation wastewater often exceed the water quality standard limits. Direct discharge of mineral processing wastewater will disturb the water environment in the mining and surrounding areas. Direct reuse will cause fluctuations and deterioration of mineral processing production indicators. Therefore, lead-zinc mining production enterprises must treat mineral processing wastewater and discharge it in compliance with standards or recycle it back to the mineral processing plant for production use. Taking Dongtangzi Lead Zinc Mine in Feng County, Shaanxi Province as an example, this paper elaborates on the method of fully recycling mineral processing wastewater and the achieved results. In order to reduce the impact of mineral processing wastewater on production and mineral processing indicators, the circulation volume and water quality of mineral processing wastewater were analyzed and monitored, and the reasons affecting mineral processing production were identified. Through research and investigation, a wastewater treatment process suitable for the company was designed. By continuously adjusting and optimizing the mineral processing agent system (including changing the lime dosing point and reducing the lime dosage, using Z-1 flotation agent, MB collector, and BK204 frother reducing, the dosage of copper sulfate and ethyl sulfide nitrogen, and discontinuing the use of Na2SO3 K2Cr2O6, Na2CO3, ZnSO4, xanthate, terpineol oil and other reagents, the total amount of mineral processing reagents hasbeen reduced from 13 295 g/t to 6 500 g/t, with a reduction by 6 795 g/t and a decrease of 51%. At the same time, the flocculation effect of lime and Z-1 flotation agent, as well as the inhibitory effect of Z-1 flotation agent on heavy metals and carbon-containing substances, purify the flotation operation environment, enabling wastewater treatment and mineral processing operations to be carried out simultaneously in the production process, eliminating the impact of fully recycled mineral processing wastewater on production. Mineral processing wastewater only needs to be naturally settled in the tailings pond and can be fully recycled for mineral processing production without the specific wastewater treatment, achieving full recycling of mineral processing wastewater. The dosage and cost of reagents are significantly reduced, and the mineral processing indicators are significantly improved. The results can provide a reference for the recycling of similar lead-zinc ore beneficiation wastewater. [ABSTRACT FROM AUTHOR]

The aim of this study was to measure consequences of the arsenic pollution released from a sewage treatment plant into the seawater in Jazan province in the southwest of Saudi Arabia. The impact of the release of arsenic on the ecosystem is the adsorption of arsenic by sea plants. To do so, samples were collected alongside a distance of seven kilometers from the treatment plant. The algae samples: Sargassum sp., Cladophora sp., and seagrasses: Halodule uninervis and Cymodocea rotunda were digested in nitric acid, and the assays of arsenic levels were taken by ICPAES according to EPA methods. The results showed that algae are more efficient than seagrass with absorbing arsenic. Also, the treatment plant was not the only source of arsenic contamination, as ships and boats were adding more arsenic to the ecosystem. [ABSTRACT FROM AUTHOR]

In this study, a dye-sensitizing graphene/TiO2(DTG) based photocatalytic composite film (TPU-DTG) was developed to address the challenging recovery of graphene photocatalyst powder from treated sewage. The composite film was created by incorporating self-made dye-sensitizing graphene/TiO2 onto an electrospun polyurethane film using electrostatic spraying technology. The structure and morphology of the composite film were analyzed using Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), and X-ray diffraction (XRD). Additionally, the tensile properties and thermal stability of the composite film were examined. X-ray diffraction (XRD) analysis indicated the presence of the diffraction peak of the DTG 101 crystal plane. SEM observation of TPU-4%DTG showed that the photocatalytic nanoparticles were evenly dispersed on the fiber membrane without visible agglomeration. TPU-4%DTG presented a maximum fracture stress of 17.2128 N and an elongation at a break of 335.43%. The photocatalytic performance study revealed that TPU-4%DTG was capable of eliminating over 99% of methylene blue (MB) within 10 h, and even after five cycles of photocatalytic experiments, the removal rate of MB remained above 90%. [ABSTRACT FROM AUTHOR]

The presence of nutrients and endocrine-disrupting chemical (EDC) hormones in the aquatic environment can affect wildlife and humans. Sewage treatment using biological processes followed by advanced oxidation processes can be a promising system for EDC removal, however, these have been little investigated in detail in the literature. This study evaluated the removal of nutrients, 17β-estradiol (E2), and 17α-ethynylestradiol (EE2) from sewage using an anaerobic/aerobic/anoxic sequential batch reactor (SBR). Furthermore, the treated sewage generated was subjected to post-treatment using a UV/H2O2 system. Hormones were added to the synthetic sewage only once, and it was submitted to treatment by SBR. The residues of E2 and EE2 were measured in the treated sewage generated by SBR for 13 consecutive cycles. The total removal rate of phosphorus and nitrogen by SBR was in average greater than 75% showing the simultaneous occurrence of nitrification, denitrification, and phosphorus biological removal. Seventeen percentage of the added E2 was detected in treated sewage, but 85% of EE2 was discharged into the same treated after 13 cycles of SBR. Although the literature has indicated the removal of EE2 by sorption and/or biodegradation in biological sewage treatment systems with nitrification, including full-scale ones, this study suggested that this removal has been apparent. The remaining residues of E2 and EE2 were completely degraded by the UV/H2O2 process. The removal of organic matter and nutrients by SBR facilitated the oxidative action of the UV/H2O2 system with lower consumption of peroxide. The integration of these two processes is very promising for EDC removal. [ABSTRACT FROM AUTHOR]

Copyright of Journal of Exact Sciences is the property of Master Editora and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

As a new pollutant treatment technology, microbial fuel cell (MFC) has a broad prospect. In this article, the devices assembled using walnut shells are named biochar-microbial fuel cell (B-MFC), and the devices assembled using graphene are named graphene-microbial fuel cell (G-MFC). Under the condition of an external resistance of 1,000 Ω, the B-MFC with biochar as the electrode plate can generate a voltage of up to 75.26 mV. The maximum power density is 76.61 mW/m2, and the total internal resistance is 3,117.09 Ω. The removal efficiency of B-MFC for ammonia nitrogen (NH3-N), chemical oxygen demand (COD), total nitrogen (TN), and total phosphorus (TP) was higher than that of G-MFC. The results of microbial analysis showed that there was more operational taxonomic unit (OTU) on the walnut shell biochar electrode plate. The final analysis of the two electrode materials using BET specific surface area testing method (BET) and scanning electron microscope (SEM) showed that the pore size of walnut shell biochar was smaller, the specific surface area was larger, and the pore distribution was smoother. The results show that using walnut shells to make electrode plates is an optional waste recycling method and an electrode plate with excellent development prospects. HIGHLIGHTS Preparation of electrode plates for microbial fuel cells using waste walnut shells.; The sewage treatment performance of the walnut shell biochar electrode plate has been improved.; Walnut shell biochar electrode plate is more suitable for microbial attachment and growth.;

Polyvinylidene fluoride (PVDF) is a kind of membrane material with excellent performance. However, the hydrophobicity of the membrane surface can easily lead to membrane fouling, which hinders its practical application in wastewater treatment. In order to improve the surface hydrophilicity of PVDF, three kinds of copolymer microspheres with different particle sizes were synthesized, and then polyethyleneimine was grafted on the surface of the membrane. The PVDF membrane modified by polyethyleneimine grafting/microsphere blending was tested by FTIR, XPS, SEM, Zeta potential and other analysis tests. The oil-water separation performance, protein contamination resistance, and dye adsorption and retention performance of the membrane were investigated. The results showed that the modified membrane was hydrophilic and oleophobic underwater, and the separation efficiency of oil-water emulsion was above 99%. The membrane was resistant to protein pollution, and the flux recovery rate of bovine serum albumin after filtration could reach 99.3%. It could adsorb and intercept anionic dyes, and the interception rate of Congo red dye was above 90%.

Abstract The public–private partnership (PPP) mode is one of the main ways to promote environmental governance through marketization in the sewage treatment industry. This mode is crucial for environmental protection and livelihood improvement. In order to investigate the impact of PPP mode on sewage treatment, the influence of financial development and the government–business relationship on the effectiveness of sewage treatment under PPP mode, and the role of government in this context, an empirical model is established. To achieve this, data from 284 prefecture-level and above cities in China from 2009 to 2017 has been selected as research samples. The total amount of regional sewage treatment PPP projects is used as the proxy variable for participation in the PPP mode. The findings reveal that the PPP mode of sewage treatment effectively reduces the intensity and amount of sewage discharge. Moreover, the results indicate that a higher level of financial development and a more perfect financial system are associated with better sewage treatment effects under the PPP mode. Similarly, a more harmonious government–business relationship and a higher health index of this relationship correspond to improved sewage treatment effects under the PPP mode. The government should actively enhance government transparency, formulate appropriate corporate taxes and fees, clarify the responsibilities and obligations of the government and enterprises, and optimize the business environment in order to optimize the sewage treatment effect of the PPP mode.

Through the study of 16S rDNA and physiological and biochemical characteristics of various strains, a heterotrophic nitrification and aerobic denitrification bacteria (HN-AD) strain with good heat resistance was found. The strain was inoculated into a nitrate nitrogen culture medium simulating sewage environment to study its denitrification efficiency and nitrate nitrogen removal rate under insufficient and sufficient carbon sources. The results showed that HN-AD strain that could make the pH of wastewater more suitable for its own denitrification was screened in hot springs, and the identified HN-AD strain was Pseudomonas stutzeri. The optimal pH for denitrification of this strain in a simulated wastewater environment was 8.0, with sufficient carbon source, its nitrate nitrogen removal rate could reach over 93%. The strain not only had a relatively efficient denitrification efficiency and a high nitrate nitrogen removal rate, but also had the ability to self regulate the environmental pH, which could be adjusted to the optimal pH for nitrogen degradation under sufficient carbon sources. [ABSTRACT FROM AUTHOR]

Wastewater Treatment Plants (WWTPs) play a crucial role in maintaining ecological balance, a cornerstone of environmental health for thriving biodiversity and undisturbed natural processes. This balance is crucial for the sustainability of ecosystems, directly influencing human health, biodiversity, and the overall quality of our natural environment. WWTPs contribute to this equilibrium by efficiently removing pollutants and harmful substances from wastewater, thus averting the degradation of water bodies that are essential for numerous ecological processes. WWTPs encompass multiple stages of wastewater and sludge treatment and are significant energy consumers globally, especially in secondary treatment, particularly the activated sludge method which is the most common method. With an upcoming directive from the European Union aiming to reduce energy consumption in WWTPs, this paper focuses on a literature review examining global practices implemented across all stages of WWTP treatment processes. It summarizes the key points of each study, focusing primarily on the outcomes of each application. This document concludes with an in-depth review of each study and provides general conclusions for each group of studies. The objective is to identify methods that have effectively reduced energy consumption and enhanced the overall energy efficiency of WWTPs. The main conclusions indicate that the studies encompass a wide range of applications that achieve significant reductions in energy consumption. However, additional testing of these applications in more diverse operating environments through trials could further enhance their reliability and increase acceptance among WWTP operators. [ABSTRACT FROM AUTHOR]

Copyright of Industrial Water Treatment is the property of CNOOC Tianjin Chemical Research & Design Institute and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)

The insight of the activity phase and reaction mechanism is vital for developing high-performance ammonia synthesis electrocatalysts. In this study, the origin of the electronic-dependent activity for the model Cu2O catalyst toward ammonia electrosynthesis with nitrate was probed. The modulation of the electronic state and oxygen vacancy content of Cu2O was realized by doping with halogen elements (Cl, Br, I). The electrocatalytic experiments showed that the activity of the ammonia production depends strongly on the electronic states in Cu2O. With increased electronic state defects in Cu2O, the ammonia synthesis performance increased first and then decreased. The Cu2O/Br with electronic defects in the middle showed the highest ammonia yield of 11.4 g h−1 g−1 at −1.0 V (vs. RHE), indicating that the pattern of change in optimal ammonia activity is consistent with the phenomenon of volcano curves in reaction chemistry. This work highlights a promising route for designing NO3−RR to NH3 catalysts. [ABSTRACT FROM AUTHOR]

In order to improve the efficiency of domestic wastewater treatment process design, a wastewater treatment process database was established to save data samples abstracted from real domestic wastewater treatment processes, and the process was selected by the support vector machine classification algorithm based on boundary points(BP-SVM). Support vector machine classification algorithm based on boundary points(BP-SVM)was used to select the process. Multiple BP-SVMs were set up to solve the multi-classification problem. Parameter optimization of BP-SVM parameters was performed using genetic algorithm(GA). The results of the study show that the process design algorithm gives a suitable solution, verifies an accuracy of 94%, and consumes less compared to other algorithms. The feasibility and effectiveness of the algorithm is proved. [ABSTRACT FROM AUTHOR]

Due to a large number of harmful chemicals flowing into the water source in production and life, the water quality deteriorates, and the use value of water is reduced or lost. Biochar has a strong physical adsorption effect, but it can only separate pollutants from water and cannot eliminate pollutants fundamentally. Photocatalytic degradation technology using photocatalysts uses chemical methods to degrade or mineralize organic pollutants, but it is difficult to recover and reuse. Woody biomass has the advantages of huge reserves, convenient access and a low price. Processing woody biomass into biochar and then combining it with photocatalysts has played a complementary role. In this paper, the shortcomings of a photocatalyst and biochar in water treatment are introduced, respectively, and the advantages of a woody biochar-based photocatalyst made by combining them are summarized. The preparation and assembly methods of the woody biochar-based photocatalyst starting from the preparation of biochar are listed, and the water treatment efficiency of the woody biochar-based photocatalyst using different photocatalysts is listed. Finally, the future development of the woody biochar-based photocatalyst is summarized and prospected. [ABSTRACT FROM AUTHOR]

The hazards of sludge, the status quo of treatment and disposal, and the preparation process of sludge ceramsites were summarized・ The application and mechanism of sludge ceramsites in the adsorption of nitrogen, phosphorus, heavy metals, organic matter and turbidity removal are systematically reviewed, so as to provide a reference for sludge ceramsites in the field of sewage treatment. The limitations of sludge ceramsites in water purification are analyzed, and its future development direction is prospected. [ABSTRACT FROM AUTHOR]

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Biogas has improved due to technological advancements, environmental awareness, policy support, and research innovation, making it a more cost-effective and environmentally friendly renewable energy source. The Generalized Linear Model (GLM) was employed to examine the relationship between purchased and generated energy from 2007 to 2023. Metrics such as deviance, log likelihood, and dispersion phi were examined to assess model fit. The Mann–Kendall test was utilized to detect trends in energy datasets. Biochemical Oxygen Demand (BOD5) and Chemical Oxygen Demand (COD) reduction was significant, exceeding 97% from 2014 to 2023. However, treated sewage displayed limited susceptibility to biological degradation, with COD to BOD5 ratios increasing from 2.28 to 6.59 for raw sewage and from 2.33 to 7.05 for treated sewage by 2023. Additionally, the efficiency of sewage purification processes was calculated, and multivariate regression analysis was conducted on gas composition data. Principal Coordinate Ordination (PCO) and k-means clustering were used for dimensionality reduction and biogas component clustering, respectively. This research showed that biogas from the waste water treatment process can be used, particularly in methane production. Technological advancements have made biogas production more efficient, enhancing energy generation within a circular economy framework.

The excessive discharge of phosphorus from rural domestic sewage is a problem that worthy of attention. If the phosphorus in the sewage were recovered, addressing this issue could significantly contribute to mitigating the global phosphorus crisis. In this study, corn straw, a common agricultural waste, was co‐pyrolytically modified with eggshells, a type of food waste from university cafeterias. The resulting product, referred to as corn straw eggshell biochar (EGBC) was characterized using SEM, XRD, XPS, XRF, and other methods. Batch adsorption experiments were conducted to determine the optimal preparation conditions of EGBC and to explore its adsorption characteristics. EGBC showed strong adsorption effectiveness within a pH range of 5–12. The adsorption isotherm closely followed the Sips model (R2 > 0.9011), and the adsorption kinetics were more consistent with the pseudo‐second‐order model (R2 > 0.9899). The process was found to be both spontaneous and endothermic. Under optimal conditions, the phosphorus adsorption capacity of EGBC was measured to be 288.83 mg/g. This demonstrates the high efficiency of EGBC for phosphorus removal and illustrates an effective method of utilizing food waste for environmental remediation. Practitioner Points: Biochar prepared from waste eggshell was used to removal and recovery phosphorus in wastewater treatment.EGBC has an impressive adsorption capacity that can reach up to 288.83 mg/g.EGBC has excellent adsorption and filtration capabilities, and there is a sudden increase in concentration at 900 min in the breakthrough curve of EGBC.EGBC has good regeneration performance, with an adsorption effect of 65% and an adsorption capacity of 121 mg/g after four desorption and regeneration cycles. [ABSTRACT FROM AUTHOR]

The low-temperature environment significantly inhibits the growth and metabolism of denitrifying bacteria, leading to an excessive concentration of ammonia nitrogen and total nitrogen in sewage treatment plants during the cold season. In this study, an efficient denitrifying strain of heterotrophic nitrification–aerobic denitrification (HN–AD) bacteria named HS2 was isolated and screened from industrial sewage of a chemical factory in Inner Mongolia at 8 °C. The strain was confirmed to be Achromobacter spiritinus, a colorless rod-shaped bacterium. When cultured with sodium succinate as the carbon source, a carbon-to-nitrogen ratio of 20–30, a shaking rate of 150–180 r/min, and an initial pH of 6–10, the strain HS2 exhibited excellent nitrogen removal at 8 °C. Through the results of whole-genome sequencing, gene amplification, and gas product detection, the strain HS2 was determined to possess key enzyme genes in both nitrification and denitrification pathways, suggesting a HN–AD pathway of NH4+-N → NH2OH → NO2−N → NO → N2O → N2. At 8 °C, the strain HS2 could completely remove ammonia nitrogen from industrial sewage with an initial concentration of 127.23 mg/L. Microbial species diversity analysis of the final sewage confirmed Achromobacter sp. as the dominant genus, which indicated that the low-temperature denitrifying strain HS2 plays an important role in nitrogen removal in actual low-temperature sewage. [ABSTRACT FROM AUTHOR]