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1. Constraints on the martian crust away from the InSight landing site

Author

Jiaqi Li, Caroline Beghein, Scott M. McLennan, Anna C. Horleston, Constantinos Charalambous, Quancheng Huang, Géraldine Zenhäusern, Ebru Bozdağ, W. T. Pike, Matthew Golombek, Vedran Lekić, Philippe Lognonné, and W. Bruce Banerdt

Subjects
Science
Abstract

The authors show that the Martian crust, ~4300 km from the InSight landing site, has a subsurface interface similar to that beneath the lander, suggesting it is a regional or global feature that may be related to the closure of pore spaces at depth.

Published
2022
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2. Crustal Structure Constraints From the Detection of the SsPp Phase on Mars

Author

Jiaqi Li, Caroline Beghein, Paul Davis, Mark. A. Wieczorek, Scott M. McLennan, Doyeon Kim, Ved Lekić, Matthew Golombek, Martin Schimmel, Eleonore Stutzmann, Philippe Lognonné, and William Bruce Banerdt

Subjects
Martian crust, porosity, marsquake, P‐wave speed, Astronomy, QB1-991, Geology, QE1-996.5
Abstract

Abstract The shallowest intracrustal layer (extending to 8 ± 2 km depth) beneath the Mars InSight Lander site exhibits low seismic wave velocity, which is likely related to a combination of high porosity and other lithological factors. The SsPp phase, an SV‐ to P‐wave reflection on the receiver side, is naturally suited for constraining the seismic structure of this top crustal layer since its prominent signal makes it observable with a single station without the need for stacking. We have analyzed six broadband and low‐frequency seismic events recorded on Mars and made the first coherent detection of the SsPp phase on the red planet. The timing and amplitude of SsPp confirm the existence of the ∼8 km interface in the crust and the large wave speed (or impedance) contrast across it. With our new constraints from the SsPp phase, we determined that the average P‐wave speed in the top crustal layer is between 2.5 and 3.2 km/s, which is a more precise and robust estimate than the previous range of 2.0–3.5 km/s obtained by receiver function analysis. The low velocity of Layer 1 likely results from the presence of relatively low‐density lithified sedimentary rocks and/or aqueously altered igneous rocks that also have a significant amount of porosity, possibly as much as 22%–30% by volume (assuming an aspect ratio of 0.1 for the pore space). These porosities and average P‐wave speeds are compatible with our current understanding of the upper crustal stratigraphy beneath the InSight Lander site.

Published
2023
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3. Different Martian Crustal Seismic Velocities Across the Dichotomy Boundary From Multi‐Orbiting Surface Waves

Author

Jiaqi Li, Caroline Beghein, Philippe Lognonné, Scott M. McLennan, Mark A. Wieczorek, Mark P. Panning, Brigitte Knapmeyer‐Endrun, Paul Davis, and W. Bruce Banerdt

Subjects
surface wave, marsquake, Rayleigh wave, porosity, Mars, dichotomy, Geophysics. Cosmic physics, QC801-809
Abstract

Abstract We have observed both minor‐arc (R1) and major‐arc (R2) Rayleigh waves for the largest marsquake (magnitude of 4.7 ± 0.2) ever recorded. Along the R1 path (in the lowlands), inversion results show that a simple, two‐layer model with an interface located at 21–29 km and an upper crustal shear‐wave velocity of 3.05–3.17 km/s can fit the group velocity measurements. Along the R2 path, observations can be explained by upper crustal thickness models constrained from gravity data and upper crustal shear‐wave velocities of 2.61–3.27 and 3.28–3.52 km/s in the lowlands and highlands, respectively. The shear‐wave velocity being faster in the highlands than in the lowlands indicates the possible existence of sedimentary rocks, and relatively higher porosity in the lowlands.

Published
2023
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4. Post-Landing Major Element Quantification Using SuperCam Laser Induced Breakdown Spectroscopy

Author

Ryan B Anderson, Olivier Forni, Agnes Cousin, Roger C Wiens, Samuel M Clegg, Jens Frydenvang, Travis S J Gabriel, Ann M Ollila, Susanne Schroder, Olivier Beyssac, Erin Gibbons, David S Vogt, Elise Clave, Jose-Antonio Manrique, Carey Legett IV, Paolo Pilleri, Raymond T Newell, Joseph Sarao, Sylvestre Maurice, Gorka Arana, Karim Benzerara, Pernelle Bernardi, Sylvian Bernard, Bruno Bousquet, Adrian J Brown, Cesar-Alvarez Llamas, Baptiste Chide, Edward Cloutis, Jade Comellas, Stephanie Connell, Erwin Dehouck, Dorothea M Delapp, Ari Essunfeld, Cecile Fabre, Thierry C Fouchet, Cristina Garcia-Florentino, Laura Garcia-Gomez, Patrick Gasda, Olivier Gasnault, Elisabeth Hausrath, Nina L Lanza, Javier Laserna, Jeremie Lasue, Guillermo Lopez, Juan Manuel Madariaga, Lucia Mandon, Nicolas Mangold, Pierre-Yves Meslin, Anthony E Nelson, Horton Newsom, Adriana L Reyes-Newell, Scott Robinson, Fernando Rull, Shiv Sharma, Justin I Simon, Pablo Sobron, Imanol Torre Fernandez, Arya Udry, Dawn Venhaus, Scott M McLennan, Richard V Morris, and Bethany Ehlmann

Subjects
Geosciences (General)
Abstract

The SuperCam instrument on the PerseveranceMars 2020 rover uses a pulsed 1064 nm laser to ablate targets at a distance and conduct laser induced breakdown spectroscopy (LIBS) by analyzing the light from the resulting plasma. SuperCam LIBS spectra are preprocessed to remove ambient light, noise, and the continuum signal present in LIBS observations. Prior to quantification, spectra are masked to remove noisier spectrometer regions andspectra are normalized to minimize signal fluctuations and effectsof target distance.In some cases, the spectra are also standardized or binned prior to quantification. To determine quantitative elemental compositionsof diverse geologic materials at Jezero crater, Mars, we use a suite of 1198 laboratory spectra of 334 well-characterized reference samples. The samples were selected to span a wide range of compositions and include typical silicate rocks, pure minerals (e.g.,silicates, sulfates, carbonates, oxides),more unusual compositions (e.g.,Mn oreand sodalite), andreplicates of the sintered SuperCam calibration targets (SCCTs) onboardthe rover. For each major element (SiO2, TiO2, Al2O3, FeOT, MgO, CaO, Na2O, K2O), the database was subdivided into five“folds” with similar distributions of the element of interest. One fold was held out as an independent test set, and the remaining fourfolds were used to optimize multivariate regression models relating the spectrum to the composition. We considered a variety of models, and selected several for further investigation for each element, based primarily on the root mean squared error of prediction (RMSEP) on the test set, when analyzed at 3m. In cases with several models of comparable performance at 3 m, we incorporated the SCCT performance at different distances to choose the preferred model. Shortly after landing on Mars and collecting initial spectra of geologic targets, we selected one model per element. Subsequently, with additional data from geologic targets, some models were revised to ensure results that are more consistent with geochemical constraints. The calibration discussed here is a snapshot of an ongoing effort to deliver the most accurate chemical compositions with SuperCam LIBS.

Published
2021
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5. The SuperCam Instrument Suite on the NASA Mars 2020 Rover: Body Unit and Combined System Tests

Author

Roger C. Wiens, Sylvestre Maurice, Scott H. Robinson, Anthony E. Nelson, Philippe Cais, Pernelle Bernardi, Raymond T. Newell, Sam Clegg, Shiv K. Sharma, Steven Storms, Jonathan Deming, Darrel Beckman, Ann M. Ollila, Olivier Gasnault, Ryan B. Anderson, Yves André, S. Michael Angel, Gorka Arana, Elizabeth Auden, Pierre Beck, Joseph Becker, Karim Benzerara, Sylvain Bernard, Olivier Beyssac, Louis Borges, Bruno Bousquet, Kerry Boyd, Michael Caffrey, Jeffrey Carlson, Kepa Castro, Jorden Celis, Baptiste Chide, Kevin Clark, Edward Cloutis, Elizabeth C. Cordoba, Agnes Cousin, Magdalena Dale, Lauren Deflores, Dorothea Delapp, Muriel Deleuze, Matthew Dirmyer, Christophe Donny, Gilles Dromart, M. George Duran, Miles Egan, Joan Ervin, Cecile Fabre, Amaury Fau, Woodward Fischer, Olivier Forni, Thierry Fouchet, Reuben Fresquez, Jens Frydenvang, Denine Gasway, Ivair Gontijo, John Grotzinger, Xavier Jacob, Sophie Jacquinod, Jeffrey R. Johnson, Roberta A. Klisiewicz, James Lake, Nina Lanza, Javier Laserna, Jeremie Lasue, Stéphane Le Mouélic, Carey Legett, Richard Leveille, Eric Lewin, Guillermo Lopez-Reyes, Ralph Lorenz, Eric Lorigny, Steven P. Love, Briana Lucero, Juan Manuel Madariaga, Morten Madsen, Soren Madsen, Nicolas Mangold, Jose Antonio Manrique, J. P. Martinez, Jesus Martinez-Frias, Kevin P. McCabe, Timothy H. McConnochie, Justin M. McGlown, Scott M. McLennan, Noureddine Melikechi, Pierre-Yves Meslin, John M. Michel, David Mimoun, Anupam Misra, Gilles Montagnac, Franck Montmessin, Valerie Mousset, Naomi Murdoch, Horton Newsom, Logan A. Ott, Zachary R. Ousnamer, Laurent Pares, Yann Parot, Rafal Pawluczyk, C. Glen Peterson, Paolo Pilleri, Patrick Pinet, Gabriel Pont, Francois Poulet, Cheryl Provost, Benjamin Quertier, Heather Quinn, William Rapin, Jean-Michel Reess, Amy H. Regan, Adriana L. Reyes-Newell, Philip J. Romano, Clement Royer, Fernando Rull, Benigno Sandoval, Joseph H. Sarrao, Violaine Sautter, Marcel J. Schoppers, Susanne Schröder, Daniel Seitz, Terra Shepherd, Pablo Sobron, Bruno Dubois, Vishnu Sridhar, Michael J. Toplis, Imanol Torre-Fdez, Ian A. Trettel, Mark Underwood, Andres Valdez, Jacob Valdez, Dawn Venhaus, and Peter Willis

Published
2020
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7. Global crustal thickness revealed by surface waves orbiting Mars

Author

Doyeon Kim, Cecilia Duran, Domenico Giardini, Ana-Catalina Plesa, Simon C. Stähler, Christian Boehm, Vedran Lekic, Scott M. McLennan, Savas Ceylan, John Clinton, Paul McEwan Davis, Amir Khan, Brigitte Knapmeyer-Endrun, Mark Paul Panning, Mark A. Wieczorek, and Philippe Lognonné

Abstract

We report observations of Rayleigh waves that orbit around Mars up to three times following the S1222a marsquake. Averaging these signals, we find the largest amplitude signals at 30 s and 85 s central period, propagating with distinctly different group velocities of 2.9 km/s and 3.8 km/s, respectively. The group velocities constraining the average crustal thickness beneath the great circle path rule out the majority of previous crustal models of Mars that have a >200 kg/m3 density contrast across the dichotomy. We find that the thickness of the martian crust is 42-56 km on average, and thus thicker than the crusts of the Earth and Moon. Together with thermal evolution models, a thick martian crust suggests that the crust must contain 50-70% of the total heat production to explain present-day local melt zones in the interior of Mars.

Published
2023

10. Crustal Structure Constraints from the Detection of the SsPp Phase on Mars

Author

Jiaqi Li, Caroline Beghein, Paul Davis, Mark. A. Wieczorek, Scott M. McLennan, Doyeon Kim, Ved Lekić, Matthew Golombek, Martin Schimmel, Eleonore Stutzmann, Philippe Lognonné, and William Bruce Banerdt

Subjects
porosity, marsquake, Martian crust, General Earth and Planetary Sciences, P-wave speed, Environmental Science (miscellaneous)
Abstract

The shallowest intracrustal layer (extending to 8 +/- 2 km depth) beneath the Mars InSight Lander site exhibits low seismic wave velocity, which is likely related to a combination of high porosity and other lithological factors. The SsPp phase, an SV- to P-wave reflection on the receiver side, is naturally suited for constraining the seismic structure of this top crustal layer since its prominent signal makes it observable with a single station without the need for stacking. We have analyzed six broadband and low-frequency seismic events recorded on Mars and made the first coherent detection of the SsPp phase on the red planet. The timing and amplitude of SsPp confirm the existence of the similar to 8 km interface in the crust and the large wave speed (or impedance) contrast across it. With our new constraints from the SsPp phase, we determined that the average P-wave speed in the top crustal layer is between 2.5 and 3.2 km/s, which is a more precise and robust estimate than the previous range of 2.0-3.5 km/s obtained by receiver function analysis. The low velocity of Layer 1 likely results from the presence of relatively low-density lithified sedimentary rocks and/or aqueously altered igneous rocks that also have a significant amount of porosity, possibly as much as 22%-30% by volume (assuming an aspect ratio of 0.1 for the pore space). These porosities and average P-wave speeds are compatible with our current understanding of the upper crustal stratigraphy beneath the InSight Lander site., Earth and Space Science, 10 (3), ISSN:2333-5084

Published
2022

12. Perseverance rover reveals an ancient delta-lake system and flood deposits at Jezero crater, Mars

Author

C. Quantin-Nataf, Keyron Hickman-Lewis, Adrian J. Brown, Tanja Bosak, Scott M. McLennan, David L. Shuster, Kenneth H. Williford, R. A. Yingst, Kenneth A. Farley, Benjamin P. Weiss, James F. Bell, Sylvestre Maurice, Amy J. Williams, Linda C. Kah, S. F. Sholes, Gilles Dromart, Vivian Z. Sun, Justin I. Simon, S. Holm-Alwmark, Jorge I. Nunez, Olivier Gasnault, Sunetra Gupta, Ann Ollila, Melissa S. Rice, Allan H. Treiman, K. M. Stack, John P. Grotzinger, N. Mangold, J. Martinez-Frias, Bethany L. Ehlmann, Roger C. Wiens, J. W. Rice, Olivier Beyssac, P. Pilleri, Fred Calef, Briony Horgan, J. D. Tarnas, Nathan R. Williams, S. Le Mouélic, Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut de recherche en astrophysique et planétologie (IRAP), Institut national des sciences de l'Univers (INSU - CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), and Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)

Subjects
Delta, Hydrology Geomorphology fluvial 1625, 010504 meteorology & atmospheric sciences, Geochemistry, [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], Mars, 01 natural sciences, Jezero crater, [SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology, Impact crater, Margin (machine learning), 0103 physical sciences, 010303 astronomy & astrophysics, CORINTH, 0105 earth and related environmental sciences, ARCHITECTURE, Multidisciplinary, Flood myth, ORIGIN, Mars Exploration Program, SCIENCE, Sedimentology, 13. Climate action, RIFT, Sedimentary rock, Geology
Abstract

Perseverance images of a delta on Mars The Perseverance rover landed in Jezero crater, Mars, in February 2021. Earlier orbital images showed that the crater contains an ancient river delta that was deposited by water flowing into a lake billions of years ago. Mangold et al . analyzed rover images taken shortly after landing that show distant cliff faces at the edge of the delta. The exposed stratigraphy and sizes of boulders allowed them to determine the past lake level and water discharge rates. An initially steady flow transitioned into intermittent floods as the planet dried out. This history of the delta’s geology provides context for the rest of the mission and improves our understanding of Mars’ ancient climate. —KTS

Published
2021

13. Seismic Velocity Variations in a 3D Martian Mantle: Implications for the InSight Measurements

Author

M. van Driel, Scott M. McLennan, Simon Stähler, Amir Khan, Martin Knapmeyer, Tilman Spohn, Mark A. Wieczorek, Attilio Rivoldini, Ebru Bozdag, Nicola Tosi, Daniel Peter, Sebastiano Padovan, Doris Breuer, Ana-Catalina Plesa, and Université Côte d'Azur, Observatoire de la Côte d'Azur, CNRS, Laboratoire Lagrange, Nice, France

Subjects
010504 meteorology & atmospheric sciences, Mars, Heat producing elements distribution, engineering.material, 01 natural sciences, Mantle (geology), [SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology, Geochemistry and Petrology, Lithosphere, Thermal, Earth and Planetary Sciences (miscellaneous), Seismic velocities, Petrology, ComputingMilieux_MISCELLANEOUS, InSight, 0105 earth and related environmental sciences, Martian, Olivine, Lithospheric thermal structure, Crust, Mars Exploration Program, Wadsleyite, Geophysics, 13. Climate action, Space and Planetary Science, engineering, Geology, Thermal evolution
Abstract

We use a large data set of 3D thermal evolution models to predict the distribution of present-day seismic velocities in the Martian interior. Our models show a difference between maximum and minimum S-wave velocity of up to 10% either below the crust, where thermal variations are largest, or at the depth of the olivine to wadsleyite phase transition, located at around 1000 – 1200 km depth. Models with thick lithospheres on average have weak low-velocity zones that extend deeper than 400 km, and seismic velocity variations in the uppermost 400 – 600 km that closely follow the crustal thickness pattern. For these cases the crust contains more than half of the total amount of heat producing elements. Models with limited crustal heat production have thinner lithospheres and shallower but prominent low-velocity zones that are incompatible with InSight observations. Seismic events suggested to originate in Cerberus Fossae indicate the absence of S-wave shadow zones in 25° - 30° epicentral distance. This result is compatible with previous best-fit models that require a large average lithospheric thickness and a crust containing more than half of the bulk amount of heat producing elements to be compatible with geological and geophysical constraints. Ongoing and future InSight measurements that will determine the existence of a weak low-velocity zone will directly bear on the crustal heat production. ISSN:0148-0227 ISSN:2169-9097 ISSN:2169-9100

Published
2021

14. The SuperCam Instrument Suite on the Mars 2020 Rover: Science Objectives and Mast-Unit Description

Author

I. Torre-Fdez, V. Gharakanian, E. Cordoba, Jérôme Parisot, R. Perez, Amaury Fau, Peter Willis, Ruth A. Anderson, Pablo Sobron, K. W. Wong, A. Debus, Julien Mekki, Noureddine Melikechi, K. Mathieu, S. Gauffre, M. Toplis, Jesús Martínez-Frías, Alexandre Cadu, Francois Poulet, B. Quertier, Horton E. Newsom, H. Seran, C. Quantin-Nataf, W. D’anna, Jens Frydenvang, Frédéric Chapron, Pierre Beck, Jean-François Mariscal, B. Chide, Y. André, Y. Michel, G. Orttner, N. Toulemont, A. Dufour, Briana Lucero, Olivier Gilard, Marion Bonafous, D. Pheav, Q.-M. Lee, D. Standarovsky, Franck Montmessin, R. Gonzalez, S. Le Mouélic, Cedric Virmontois, L. Roucayrol, I. Gontijo, M. Deleuze, L. Parès, L. Oudda, Y. Micheau, F. Manni, Bruno Dubois, Bruno Bousquet, G. de los Santos, D. M. Delapp, Guillermo Lopez-Reyes, L. Picot, Clément Royer, E. Clave, Richard Leveille, Erwin Dehouck, Gaetan Lacombe, J. Javier Laserna, Olivier Beyssac, P. Romano, Y. Daydou, Scott M. McLennan, John Michel, V. Sridhar, Driss Kouach, Gabriel Pont, M. Dupieux, Michel Gauthier, Jean-Michel Reess, J. Moros, J.-C. Dameury, T. Fouchet, Ann Ollila, Sophie Jacquinod, P. Y. Meslin, M. Egan, Juan Manuel Madariaga, Karim Benzerara, G. Hervet, Gilles Montagnac, Woodward W. Fischer, Olivier Gasnault, T. Nelson, Stanley M. Angel, Lauren DeFlores, Violaine Sautter, Marco Veneranda, C. Leyrat, Olivier Humeau, Y. Morizet, Jose Antonio Manrique, M. Sodki, P. Pilleri, C. Velasco, Naomi Murdoch, M. J. Schoppers, S. A. Storms, Sylvestre Maurice, Benigno Sandoval, Cedric Pilorget, N. Striebig, S. Robinson, V. Mousset, David Mimoun, Morten Madsen, M. Heim, A. Doressoundiram, Christophe Montaron, Eric Lewin, Patrick Pinet, C. Donny, Susanne Schröder, Agnès Cousin, Sadok Abbaki, John P. Grotzinger, Claude Collin, Xavier Jacob, Jeffrey R. Johnson, Cécile Fabre, K. McCabe, C. Legett, J. P. Berthias, Shiv K. Sharma, Timothy H. McConnochie, A. Sournac, Ralph D. Lorenz, M. Viso, Yann Parot, N. Mangold, W. Rapin, Jérémie Lasue, Gorka Arana, Joan Ervin, E. Le Comte, N. Nguyen Tuong, P. Cais, Olivier Forni, D. Rambaud, T. Battault, D. Venhaus, Anupam K. Misra, K. Clark, M. Tatat, Laurent Lapauw, P. Bernardi, Roger C. Wiens, Samuel M. Clegg, Nina Lanza, Sylvain Bernard, Soren N. Madsen, Kepa Castro, M. Boutillier, Raymond Newell, D. Granena, Y. Hello, Fernando Rull, M. Ruellan, R. Mathon, Edward A. Cloutis, Gilles Dromart, L. Le Deit, Rafik Hassen-Khodja, Institut de recherche en astrophysique et planétologie (IRAP), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Los Alamos National Laboratory (LANL), Laboratoire d'études spatiales et d'instrumentation en astrophysique = Laboratory of Space Studies and Instrumentation in Astrophysics (LESIA), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), Laboratoire d'Astrophysique de Bordeaux [Pessac] (LAB), Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Centre National d'Études Spatiales [Toulouse] (CNES), Universidad de Valladolid [Valladolid] (UVa), Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), US Geological Survey [Flagstaff], United States Geological Survey [Reston] (USGS), University of South Carolina [Columbia], Universidad del Pais Vasco / Euskal Herriko Unibertsitatea [Espagne] (UPV/EHU), Institut de Planétologie et d'Astrophysique de Grenoble (IPAG), Centre National d'Études Spatiales [Toulouse] (CNES)-Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Météo-France -Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Météo-France, Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Centre d'Etudes Lasers Intenses et Applications (CELIA), Université de Bordeaux (UB)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Institut Supérieur de l'Aéronautique et de l'Espace (ISAE-SUPAERO), Jet Propulsion Laboratory (JPL), NASA-California Institute of Technology (CALTECH), University of Winnipeg, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France, University of Hawai‘i [Mānoa] (UHM), GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), California Institute of Technology (CALTECH), University of Copenhagen = Københavns Universitet (UCPH), Institut de mécanique des fluides de Toulouse (IMFT), Université de Toulouse (UT)-Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT), Johns Hopkins University Applied Physics Laboratory [Laurel, MD] (APL), PLANETO - LATMOS, Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Universidad de Málaga [Málaga] = University of Málaga [Málaga], Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), McGill University = Université McGill [Montréal, Canada], Institut des Sciences de la Terre (ISTerre), Institut national des sciences de l'Univers (INSU - CNRS)-Institut de recherche pour le développement [IRD] : UR219-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Université Gustave Eiffel-Université Grenoble Alpes (UGA), Consejo Superior de Investigaciones Científicas [Madrid] (CSIC), University of Maryland [College Park], University of Maryland System, Stony Brook University [SUNY] (SBU), State University of New York (SUNY), University of Massachusetts [Lowell] (UMass Lowell), University of Massachusetts System (UMASS), Laboratoire de Planétologie et Géodynamique - Angers (LPG-ANGERS), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), The University of New Mexico [Albuquerque], Institut d'astrophysique spatiale (IAS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales [Paris] (CNES), In­sti­tut für Op­ti­sche Sen­sor­sys­te­me, Deutsches Zentrum für Luft- und Raumfahrt [Berlin] (DLR), SETI Institute, Institut national des sciences de l'Univers (INSU - CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'études spatiales et d'instrumentation en astrophysique (LESIA (UMR_8109)), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP), Sorbonne Université (SU)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA), Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Bordeaux (UB), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD), Centre National de la Recherche Scientifique (CNRS)-Université de Lorraine (UL)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Institut national des sciences de l'Univers (INSU - CNRS), University of Copenhagen = Københavns Universitet (KU), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées, Sorbonne Université (SU)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Université Fédérale Toulouse Midi-Pyrénées-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Centre National de la Recherche Scientifique (CNRS), and Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Université Fédérale Toulouse Midi-Pyrénées

Subjects
Rocks, 010504 meteorology & atmospheric sciences, Computer science, [SDU.STU.GP]Sciences of the Universe [physics]/Earth Sciences/Geophysics [physics.geo-ph], Mars, Context (language use), Perseverance, Imaging on Mars, Mars 2020 Perseverance rover, 01 natural sciences, SuperCam Instrument, Unit (housing), Mast (sailing), Jezero crater, [SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology, imaging on Mars, Microphone on Mars, 0103 physical sciences, Calibration, Rover, [PHYS.COND]Physics [physics]/Condensed Matter [cond-mat], infrared spectroscopy, Raman, 010303 astronomy & astrophysics, Infrared spectroscopy, 0105 earth and related environmental sciences, [SPI.ACOU]Engineering Sciences [physics]/Acoustics [physics.class-ph], M2020, LIBS, Payload, Suite, Mars2020, Astronomy and Astrophysics, Laser-Induced Breakdown Spectroscopy, Mars Exploration Program, microphone on Mars, Planetary science, SuperCam, Space and Planetary Science, Raman spectroscopy, Systems engineering, [PHYS.COND.CM-MS]Physics [physics]/Condensed Matter [cond-mat]/Materials Science [cond-mat.mtrl-sci], Mars 2020 PERSEVERANCE rover
Abstract

On the NASA 2020 rover mission to Jezero crater, the remote determination of the texture, mineralogy and chemistry of rocks is essential to quickly and thoroughly characterize an area and to optimize the selection of samples for return to Earth. As part of the Perseverance payload, SuperCam is a suite of five techniques that provide critical and complementary observations via Laser-Induced Breakdown Spectroscopy (LIBS), Time-Resolved Raman and Luminescence (TRR/L), visible and near-infrared spectroscopy (VISIR), high-resolution color imaging (RMI), and acoustic recording (MIC). SuperCam operates at remote distances, primarily 2-7 m, while providing data at sub-mm to mm scales. We report on SuperCam's science objectives in the context of the Mars 2020 mission goals and ways the different techniques can address these questions. The instrument is made up of three separate subsystems: the Mast Unit is designed and built in France; the Body Unit is provided by the United States; the calibration target holder is contributed by Spain, and the targets themselves by the entire science team. This publication focuses on the design, development, and tests of the Mast Unit; companion papers describe the other units. The goal of this work is to provide an understanding of the technical choices made, the constraints that were imposed, and ultimately the validated performance of the flight model as it leaves Earth, and it will serve as the foundation for Mars operations and future processing of the data. In France was provided by the Centre National d'Etudes Spatiales (CNES). Human resources were provided in part by the Centre National de la Recherche Scientifique (CNRS) and universities. Funding was provided in the US by NASA's Mars Exploration Program. Some funding of data analyses at Los Alamos National Laboratory (LANL) was provided by laboratory-directed research and development funds.

Published
2021

15. The CanMars Mars Sample Return analogue mission

Author

Derek King, T. Haltigin, A. Bina, C. L. Marion, Jackie Goordial, Racel Sopoco, E. A. Lymer, Tom Dzamba, Anna Grau Galofre, E. M. Harrington, Martin Picard, R. Francis, K. Balachandran, C. M. Caudill, Liam Robert John Innis, P. A. Christoffersen, S. Duff, Elizabeth A. Silber, Alexandra Pontefract, Joshua Laughton, Rebecca Wilks, M. C. Kerrigan, Yaozhu Li, Edward A. Cloutis, Dylan Hickson, Daniel Bednar, Kristen Cote, C. H. Ryan, Tanya N. Harrison, Omar Draz, M. Bourassa, Tianqi Xie, Paul Fulford, Melissa Battler, Ian Pritchard, J. W. O’Callaghan, E. Godin, Eric A. Pilles, Matthew Svensson, Matthew Maloney, Sarah Mcfadden, Matthew Cross, P. Patel, David Beaty, J. D. Newman, John Maris, Scott M. McLennan, Kenneth H. Williford, Pierre Allard, Fenge Cao, Haley M. Sapers, Alexis David P. Pascual, Bryce Dudley, Diego Uribe, V. Hipkin, Z. R. Morse, Anna Mittelholz, Taylor Haid, W. Zylberman, Bianca D'Aoust, Catherine Maggiori, J. T. Poitras, Byung-Hun Choe, Gordon R. Osinski, Livio L. Tornabene, J. Hawkswell, P. J. A. Hill, Jonathan Kissi, G. D. Tolometti, S. L. Simpson, and Joseph Nsasi Bakambu

Subjects
Operations architecture, Mission control center, 010504 meteorology & atmospheric sciences, Payload, Astronomy and Astrophysics, Sample (statistics), Mars Exploration Program, Exploration of Mars, 01 natural sciences, Space exploration, Outreach, Space and Planetary Science, 0103 physical sciences, Systems engineering, 010303 astronomy & astrophysics, 0105 earth and related environmental sciences
Abstract

The return of samples from known locations on Mars is among the highest priority goals of the international planetary science community. A possible scenario for Mars Sample Return (MSR) is a series of 3 missions: sample cache, fetch, and retrieval. The NASA Mars 2020 mission represents the first cache mission and was the focus of the CanMars analogue mission described in this paper. The major objectives for CanMars included comparing the accuracy of selecting samples remotely using rover data versus a traditional human field party, testing the efficiency of remote science operations with periodic pre-planned strategic observations (Strategic Traverse Days), assessing the utility of realistic autonomous science capabilities to the remote science team, and investigating the factors that affect the quality of sample selection decision-making in light of returned sample analysis. CanMars was conducted over two weeks in November 2015 and continued over three weeks in October and November 2016 at an analogue site near Hanksville, Utah, USA, that was unknown to the Mission Control Team located at the University of Western Ontario (Western) in London, Ontario, Canada. This operations architecture for CanMars was based on the Phoenix and Mars Exploration Rover missions together with previous analogue missions led by Western with the Mission Control Team being divided into Planning and Science sub-teams. In advance of the 2015 operations, the Science Team used satellite data, chosen to mimic datasets available from Mars-orbiting instruments, to produce a predictive geological map for the landing ellipse and a set of hypotheses for the geology and astrobiological potential of the landing site. The site was proposed to consist of a series of weakly cemented multi-coloured sedimentary rocks comprising carbonates, sulfates, and clays, and sinuous ridges with a resistant capping unit, interpreted as inverted paleochannels. Both the 2015 CanMars mission, which achieved 11 sols of operations, and the first part of the 2016 mission (sols 12–21), were conducted with the Mars Exploration Science Rover (MESR) and a series of integrated and hand-held instruments designed to mimic the payload of the Mars 2020 rover. Part 2 of the 2016 campaign (sols 22–39) was implemented without the MESR rover and was conducted exclusively by the field team as a Fast Motion Field Test (FMFT) with hand-carried instruments and with the equivalent of three sols of operations being executed in a single actual day. A total of 8 samples were cached during the 39 sols from which the Science Team prioritized 3 for “return to Earth”. Various science autonomy capabilities, based on flight-proven or near-future techniques intended for actual rover missions, were tested throughout the 2016 CanMars activities, with autonomous geological classification and targeting and autonomous pointing refinement being used extensively during the FMFT. Blind targeting, contingency sequencing, and conditional sequencing were also employed. Validation of the CanMars cache mission was achieved through various methods and approaches. The use of dedicated documentarians in mission control provided a detailed record of how and why decisions were made. Multiple separate field validation exercises employing humans using traditional geological techniques were carried out. All 8 of the selected samples plus a range of samples from the landing site region, collected out-of-simulation, have been analysed using a range of laboratory analytical techniques. A variety of lessons learned for both future analogue missions and planetary exploration missions are provided, including: dynamic collaboration between the science and planning teams as being key for mission success; the more frequent use of spectrometers and micro-imagers having remote capabilities rather than contact instruments; the utility of strategic traverse days to provide additional time for scientific discussion and meaningful interpretation of the data; the benefit of walkabout traverse strategies along with multi-sol plans with complex decisions trees to acquire a large amount of contextual data; and the availability of autonomous geological targeting, which enabled complex multi-sol plans gathering large suites of geological and geochemical survey data. Finally, the CanMars MSR activity demonstrated the utility of analogue missions in providing opportunities to engage and educate children and the public, by providing tangible hands-on linkages between current robotic missions and future human space missions. Public education and outreach was a priority for CanMars and a dedicated lead coordinated a strong presence on social media (primarily Twitter and Facebook), articles in local, regional, and national news networks, and interaction with the local community in London, Ontario. A further core objective of CanMars was to provide valuable learning opportunities to students and post-doctoral fellows in preparation for future planetary exploration missions. A learning goals survey conducted at the end of the 2016 activities had 90% of participants “somewhat agreeing” or “strongly agreeing” that participation in the mission has helped them to increase their understanding of the four learning outcomes.

Published
2019

16. Exploring new models for improving planetary rover operations efficiency through the 2016 CanMars Mars Sample Return (MSR) analogue deployment

Author

Scott M. McLennan, J. D. Newman, M. C. Kerrigan, Kenneth H. Williford, R. Francis, Melissa Battler, M. Bourassa, T. Haltigin, C. M. Caudill, Elizabeth A. Silber, Eric A. Pilles, Matthew Cross, V. Hipkin, and Gordon R. Osinski

Subjects
Mars sample return, Mission operations, 010504 meteorology & atmospheric sciences, Computer science, Astronomy and Astrophysics, Sample (statistics), Plan (drawing), Mars Exploration Program, 01 natural sciences, Planetary rover, Space and Planetary Science, Software deployment, 0103 physical sciences, Key (cryptography), Systems engineering, 010303 astronomy & astrophysics, 0105 earth and related environmental sciences
Abstract

Approaches to rover mission operations were investigated in the framework of the CanMars Mars Sample Return (MSR) analogue mission deployments. Improving the efficiency of operations is a necessity for future planetary missions, including Mars 2020, which seek to combine sample targeting with in situ investigations in the fixed amount of time available in primary science operations and with increasingly high public and science community expectations for results. Analogue missions provide an important opportunity to experiment with mission operation strategies and learn lessons that can be incorporated in future missions. Improving the efficiency of operations was a key objective of the 2015 and 2016 CanMars mission deployment. The mission overall operations organisation for CanMars is described with comparison to current implementation of Mars Exploration Rover and Mars Science Laboratory missions. Approaches being tested included 3-sol plan sequences with increased use of waypoints for teach and return as part of a global Walkabout approach, use of Strategic Observation days to focus the Science Team's efforts, and consideration to improvements in how information is exchanged tactically and strategically in operations.

Published
2019

17. Correction to: PIXL: Planetary Instrument for X-Ray Lithochemistry

Author

Payam Zamani, Thomas S. Luchik, Juan Villalvazo, Peter Nemere, Cathleen M. Harris, James L. Lambert, Sterling Conaby, Mandy Wang, Napat Pootrakul, Matthew A. Jadusingh, David A. K. Pedersen, Violet Torossian, Robert Hodyss, Eric Hertzberg, David R. Thompson, Jonathan H. Kawamura, Peter R. Lawson, Allan H. Treiman, David P. Randall, Luca Cinquini, Abigail C. Allwood, Soren N. Madsen, Benton C. Clark, Richard E. Muller, Robert F. Sharrow, W. T. Elam, T. J. Parker, Shana C. Worel, Timothy P. Setterfield, Amarit Kitiyakara, Kyle Uckert, Robert W. Denise, Christopher Hummel, Kenneth Arnett, Carl Christian Liebe, Raul A. Romero, Mike Zappe, Marc C. Foote, Yang Liu, Mary Soria, Jenna Delaney, Yejun He, Scott Davidoff, B. J. Naylor, Joel A. Hurowitz, Troelz Denver, Nicholas Tallarida, Christopher M. Heirwegh, Steven Battel, Michael E. Schein, R. T. Schaefer, Fang Zhong, Matthew E. King, David Flannery, Kris Kozaczek, Martin S. Gilbert, Michael E. Sondheim, Mitchell H. Au, Christophe Basset, Igor Ponomarev, Richard Zimmerman, Ning Gao, Lars Timmermann, John P. Grotzinger, Shihchuan Tsai, John Leif Jørgensen, Patrick Meras, Michael M. Tice, Eric M. Ek, Lawrence A. Wade, Jamie Napoli, Vritika Singh, Robert J. Calvet, George Allen, Douglas Dawson, James R. Holden, David F. Braun, Joan Ervin, Eugenie Song, Ernesto Diaz, Daniel W. Wilson, Rogelio Rosas, Brett Hannah, Michael Evans, Henry A. Conley, Patrick J. McNally, John C. Bousman, Jackson T. Harris, Kristen M. Macneal, P. C. Stek, Johannes Gross, Jared Sachs, Mathias Benn, Raul M. Perez, Scott M. McLennan, Gary Doran, and Christina Hernandez

Subjects
Physics, Planetary science, Space and Planetary Science, X-ray, Astronomy and Astrophysics, Astrophysics
Published
2021

18. X-ray amorphous components in sedimentary rocks of Gale crater, Mars: Evidence for ancient formation and long-lived aqueous activity

Author

E. B. Rampe, Cherie N. Achilles, Briony Horgan, Erwin Dehouck, Mark R. Salvatore, R. J. Smith, Vivian Z. Sun, N. Mangold, Kirsten L. Siebach, Scott M. McLennan, State University of New York, Stonybrook, State University of New York (SUNY), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), and Université de Nantes (UN)-Université de Nantes (UN)-Université d'Angers (UA)

Subjects
geography, geography.geographical_feature_category, Noachian, Geochemistry, Mars, Context (language use), Diagenesis, Geophysics, [SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology, Volcano, Impact crater, Space and Planetary Science, Geochemistry and Petrology, [SDU]Sciences of the Universe [physics], X ray amorphous, aqueous alteration, Earth and Planetary Sciences (miscellaneous), Hesperian, curiosity rover, Sedimentary rock, gale crater, Lithification, diagenesis
Abstract

International audience; The CheMin instrument on the Mars Science Laboratory rover Curiosity detected ubiquitous high abundances (∼15-70 wt%) of X ray amorphous components (AmCs) in ancient sedimentary rocks of Gale crater. Mechanisms and timing of formation for the AmCs are poorly constrained, and could include volcanic, impact, or aqueous processes. We explore trends in AmC composition and abundance, and look for systematic compositional variation between sites within Gale crater. AmC compositions were estimated indirectly based on bulk chemistry and the nature and abundance of the crystalline phases for 19 sedimentary rock samples. AmC abundances positively correlate with AmC SiO2 contents, and a mixing relationship appears to exist between SiO2 rich and FeOT rich AmC endmembers. Endmember compositions are inconsistent with volcanic or impact glass alone, and so we conclude that the SiO2 and FeOT contents formed largely through aqueous processes. Cross cutting relationships and geologic context provide evidence that the most SiO2 rich AmCs observed in Gale crater thus far may result from interactions with localized fluids during late diagenesis. AmCs with moderate to low SiO2 contents likely formed earlier (before or soon after sediment deposition). Thus, the AmC SiO2 and FeOT contents in Gale crater rocks represent mixtures of sedimentary materials formed over most of the sedimentary history of Gale crater, starting before the first sediments were deposited in the crater (late Noachian), and ending well after the youngest sediments were lithified (at least mid Hesperian). However, it remains unclear how these metastable minerals have persisted through billions of years of diagenesis in Gale crater sediments.

Published
2021

19. The SuperCam Instrument Suite on the NASA Mars 2020 Rover: Body Unit and Combined System Tests

Author

Francois Poulet, Nina Lanza, John Michel, Kerry Boyd, Valerie Mousset, Fernando Rull, Anupam K. Misra, Horton E. Newsom, Magdalena Dale, Richard Leveille, Sylvain Bernard, Karim Benzerara, Logan Ott, Timothy H. McConnochie, M. George Duran, Jonathan Deming, C. Glen Peterson, Jorden Celis, Juan Manuel Madariaga, Anthony Nelson, Elizabeth C. Auden, Violaine Sautter, Paolo Pilleri, Naomi Murdoch, Susanne Schröder, Joseph H. Sarrao, Miles Egan, Bruno Dubois, Ann Ollila, Roberta A. Klisiewicz, M. Deleuze, K. McCabe, Ryan B. Anderson, Kevin Clark, Noureddine Melikechi, Jens Frydenvang, Matthew R. Dirmyer, A. Regan, Pierre Beck, Olivier Forni, A. Reyes-Newell, David Mimoun, Lauren DeFlores, Stéphane Le Mouélic, Nicolas Mangold, Eric Lorigny, Denine Gasway, John P. Grotzinger, M. Caffrey, Shiv K. Sharma, J. Javier Laserna, Olivier Gasnault, Steven P. Love, Eric Lewin, Sophie Jacquinod, Jeffrey R. Johnson, Dorothea Delapp, Soren N. Madsen, James Lake, Kepa Castro, Joan Ervin, Olivier Beyssac, C. Donny, Yann Parot, J. P. Martinez, Pierre-Yves Meslin, Gabriel Pont, Jean-Michel Reess, L. Parès, P. Bernardi, D. Venhaus, Guillermo Lopez-Reyes, Benjamin Quertier, Gorka Arana, Morten Madsen, Ivair Gontijo, Ralph D. Lorenz, Philip J. Romano, Ian A. Trettel, S. Michael Angel, Gilles Montagnac, Joseph Becker, Vishnu Sridhar, Rafal Pawluczyk, Jérémie Lasue, P. Cais, William Rapin, Jose Antonio Manrique, Xavier Jacob, Clement Royer, Jacob Valdez, I. Torre-Fdez, Amaury Fau, Peter Willis, Louis Borges, Cheryl Provost, Elizabeth C. Cordoba, M. L. Underwood, Justin McGlown, Daniel Seitz, S. A. Storms, Briana Lucero, Heather Quinn, Thierry Fouchet, Raymond Newell, Cécile Fabre, B. Chide, Y. André, Jeffrey Carlson, Roger C. Wiens, Scott M. McLennan, Woodward W. Fischer, Benigno Sandoval, S. Robinson, Patrick Pinet, Samuel M. Clegg, Agnes Cousin, Sylvestre Maurice, Edward A. Cloutis, Gilles Dromart, Franck Montmessin, C. Legett, Andres Valdez, Bruno Bousquet, Reuben Fresquez, Terra Shepherd, Zachary R. Ousnamer, Pablo Sobron, M. Toplis, Marcel J. Schoppers, Jesús Martínez-Frías, D. T. Beckman, Los Alamos National Laboratory (LANL), Institut de recherche en astrophysique et planétologie (IRAP), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Laboratoire d'Astrophysique de Bordeaux [Pessac] (LAB), Université de Bordeaux (UB)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'études spatiales et d'instrumentation en astrophysique = Laboratory of Space Studies and Instrumentation in Astrophysics (LESIA), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), University of Hawai‘i [Mānoa] (UHM), Astrogeology Science Center [Flagstaff], United States Geological Survey [Reston] (USGS), Centre National d'Études Spatiales [Toulouse] (CNES), University of South Carolina [Columbia], Universidad del Pais Vasco / Euskal Herriko Unibertsitatea [Espagne] (UPV/EHU), Institut de Planétologie et d'Astrophysique de Grenoble (IPAG), Centre National d'Études Spatiales [Toulouse] (CNES)-Observatoire des Sciences de l'Univers de Grenoble (OSUG ), Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Météo-France -Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Météo-France, Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Centre d'Etudes Lasers Intenses et Applications (CELIA), Université de Bordeaux (UB)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Jet Propulsion Laboratory (JPL), NASA-California Institute of Technology (CALTECH), Institut Supérieur de l'Aéronautique et de l'Espace (ISAE-SUPAERO), University of Winnipeg, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), California Institute of Technology (CALTECH), University of Copenhagen = Københavns Universitet (UCPH), Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut de mécanique des fluides de Toulouse (IMFT), Université de Toulouse (UT)-Université de Toulouse (UT)-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université de Toulouse (UT), Johns Hopkins University Applied Physics Laboratory [Laurel, MD] (APL), Universidad de Valladolid [Valladolid] (UVa), Universidad de Málaga [Málaga] = University of Málaga [Málaga], McGill University = Université McGill [Montréal, Canada], Consejo Superior de Investigaciones Científicas [Madrid] (CSIC), University of Maryland [College Park], University of Maryland System, State University of New York (SUNY), University of Massachusetts [Lowell] (UMass Lowell), University of Massachusetts System (UMASS), PLANETO - LATMOS, Laboratoire Atmosphères, Milieux, Observations Spatiales (LATMOS), Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), The University of New Mexico [Albuquerque], Institut d'astrophysique spatiale (IAS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS)-Centre National d’Études Spatiales [Paris] (CNES), FiberTech Optica (FTO), In­sti­tut für Op­ti­sche Sen­sor­sys­te­me, Deutsches Zentrum für Luft- und Raumfahrt [Berlin] (DLR), SETI Institute, Observatoire Midi-Pyrénées (OMP), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France, Institut national des sciences de l'Univers (INSU - CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Laboratoire d'études spatiales et d'instrumentation en astrophysique (LESIA (UMR_8109)), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université de Paris (UP), Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Savoie Mont Blanc (USMB [Université de Savoie] [Université de Chambéry])-Centre National de la Recherche Scientifique (CNRS)-Institut National de Recherche pour l’Agriculture, l’Alimentation et l’Environnement (INRAE)-Université Grenoble Alpes (UGA), Centre National de la Recherche Scientifique (CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université de Bordeaux (UB), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Centre National de la Recherche Scientifique (CNRS)-Université de Lorraine (UL)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Institut national des sciences de l'Univers (INSU - CNRS), University of Copenhagen = Københavns Universitet (KU), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut National Polytechnique (Toulouse) (Toulouse INP), Université Fédérale Toulouse Midi-Pyrénées, Laboratoire de Planétologie et Géodynamique - Angers (LPG-ANGERS), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Sorbonne Université (SU)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Sorbonne Université (SU)-Université de Versailles Saint-Quentin-en-Yvelines (UVSQ)-Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris-Saclay-Centre National de la Recherche Scientifique (CNRS), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD), Institut Supérieur de l'Aéronautique et de l'Espace - ISAE-SUPAERO (FRANCE), and Centre National de la Recherche Scientifique (CNRS)

Subjects
010504 meteorology & atmospheric sciences, [SDU.STU]Sciences of the Universe [physics]/Earth Sciences, Mars, 01 natural sciences, 7. Clean energy, Article, law.invention, Telescope, symbols.namesake, Jezero crater, Optics, ChemCam instrument, law, Microphone on Mars, 0103 physical sciences, SuperCam, planetary exploration, luminescence, Traitement du signal et de l'image, Perseverance rover, Spectroscopy, 010303 astronomy & astrophysics, Infrared spectroscopy, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, Physics, laboratory curiosity rover, remote Raman system, LIBS, Spectrometer, business.industry, Detector, Astronomy and Astrophysics, Mars Exploration Program, Gale crater, Laser, induced breakdown spectroscopy, Wavelength, in-situ, mission, 13. Climate action, Space and Planetary Science, [SDU]Sciences of the Universe [physics], Raman spectroscopy, symbols, business
Abstract

The SuperCam instrument suite provides the Mars 2020 rover, Perseverance, with a number of versatile remote-sensing techniques that can be used at long distance as well as within the robotic-arm workspace. These include laser-induced breakdown spectroscopy (LIBS), remote time-resolved Raman and luminescence spectroscopies, and visible and infrared (VISIR; separately referred to as VIS and IR) reflectance spectroscopy. A remote micro-imager (RMI) provides high-resolution color context imaging, and a microphone can be used as a stand-alone tool for environmental studies or to determine physical properties of rocks and soils from shock waves of laser-produced plasmas. SuperCam is built in three parts: The mast unit (MU), consisting of the laser, telescope, RMI, IR spectrometer, and associated electronics, is described in a companion paper. The on-board calibration targets are described in another companion paper. Here we describe SuperCam's body unit (BU) and testing of the integrated instrument. The BU, mounted inside the rover body, receives light from the MU via a 5.8 m optical fiber. The light is split into three wavelength bands by a demultiplexer, and is routed via fiber bundles to three optical spectrometers, two of which (UV and violet; 245-340 and 385-465 nm) are crossed Czerny-Turner reflection spectrometers, nearly identical to their counterparts on ChemCam. The third is a high-efficiency transmission spectrometer containing an optical intensifier capable of gating exposures to 100 ns or longer, with variable delay times relative to the laser pulse. This spectrometer covers 535-853 nm ( 105 - 7070 cm − 1 Raman shift relative to the 532 nm green laser beam) with 12 cm − 1 full-width at half-maximum peak resolution in the Raman fingerprint region. The BU electronics boards interface with the rover and control the instrument, returning data to the rover. Thermal systems maintain a warm temperature during cruise to Mars to avoid contamination on the optics, and cool the detectors during operations on Mars. Results obtained with the integrated instrument demonstrate its capabilities for LIBS, for which a library of 332 standards was developed. Examples of Raman and VISIR spectroscopy are shown, demonstrating clear mineral identification with both techniques. Luminescence spectra demonstrate the utility of having both spectral and temporal dimensions. Finally, RMI and microphone tests on the rover demonstrate the capabilities of these subsystems as well., Proyecto MINECO Retos de la Sociedad. Ref. ESP2017-87690-C3-1-R

Published
2021

21. Curation and Analysis of Global Sedimentary Geochemical Data to Inform Earth History

Author

Austin J. Miller, Christina R. Woltz, Tianran Zhang, Romain Guilbaud, Donald E. Canfield, Chao Li, Justin V. Strauss, Nicholas J. Tosca, Geoffrey J. Gilleaudeau, Tais W. Dahl, Pavel Kabanov, David K. Loydell, Úna C. Farrell, N. Mills, Xinze Lu, Marcus Kunzmann, Devon B. Cole, Timothy M. Gibson, Scott M. McLennan, Jochen J. Brocks, Huan Cui, Simon W. Poulton, Erik A. Sperling, Joseph F. Emmings, C. B. Keller, Peter W. Crockford, Akshay Mehra, Malcolm Hodgkiss, Amber J. M. Jarrett, Keith Dewing, Brennan O'Connell, Robert R. Gaines, Philip R. Wilby, Lucas D. Mouro, Emmy Smith, Samantha R. Ritzer, Shanan E. Peters, Géosciences Environnement Toulouse (GET), Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), and Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS)

Subjects
Earth history, Process (engineering), Geology, Data science, Metadata, Workflow, 13. Climate action, [SDU]Sciences of the Universe [physics], Resampling, [SDE]Environmental Sciences, Earth Sciences, Data and Information, Sedimentary rock, ComputingMilieux_MISCELLANEOUS
Abstract

Large datasets increasingly provide critical insights into crustal and surface processes on Earth. These data come in the form of published and contributed observations, which often include associated metadata. Even in the best-case scenario of a carefully curated dataset, it may be non-trivial to extract meaningful analyses from such compilations, and choices made with respect to filtering, resampling, and averaging can affect the resulting trends and any interpretation(s) thereof. As a result, a thorough understanding of how to digest, process, and analyze large data compilations is required. Here, we present a generalizable workflow developed using the Sedimentary Geochemistry and Paleoenvironments Project database. We demonstrate the effects of filtering and weighted resampling on Al2O3 and U contents, two representative geochemical components of interest in sedi-mentary geochemistry (one major and one trace element, respectively). Through our analyses, we highlight several methodological challenges in a "bigger data" approach to Earth science. We suggest that, with slight modifications to our workflow, researchers can confidently use large collections of observations to gain new insights into processes that have shaped Earth's crustal and surface environments.

Published
2021

22. Amorphization of S, Cl‐Salts Induced by Martian Dust Activities

Author

Darby Dyar, Erbin Shi, Scott M. McLennan, William M. Farrell, Hongkun Qu, Yuanchao Yan, Alian Wang, Bradley L. Jolliff, and Jen L. Houghton

Subjects
Martian, symbols.namesake, Geophysics, Materials science, Space and Planetary Science, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), symbols, Mars Exploration Program, Raman spectroscopy, Astrobiology
Published
2020

24. PIXL: Planetary Instrument for X-Ray Lithochemistry

Author

James R. Holden, David F. Braun, Joan Ervin, Eugenie Song, John C. Bousman, Lars Timmermann, John P. Grotzinger, Shihchuan Tsai, Jonathan H. Kawamura, Jamie Napoli, Matthew A. Jadusingh, Christina Hernandez, Violet Torossian, David A. K. Pedersen, Scott M. McLennan, Gary Doran, Peter Nemere, Yang Liu, Allan H. Treiman, Christophe Basset, Ning Gao, Timothy P. Setterfield, Matthew E. King, Mandy Wang, Vritika Singh, Robert Hodyss, David P. Randall, Christopher Hummel, Kenneth Arnett, Abigail C. Allwood, B. J. Naylor, Carl Christian Liebe, Daniel W. Wilson, Rogelio Rosas, Eric M. Ek, Troelz Denver, Peter R. Lawson, Cathleen M. Harris, David O. Flannery, Mike Zappe, Benton C. Clark, Joel A. Hurowitz, Kyle Uckert, Robert W. Denise, Richard Zimmerman, Nicholas Tallarida, Richard E. Muller, Martin S. Gilbert, W. T. Elam, Fang Zhong, Christopher M. Heirwegh, Napat Pootrakul, Michael E. Sondheim, Steven Battel, Robert F. Sharrow, Shana C. Worel, Luca Cinquini, Mathias Benn, Henry A. Conley, Payam Zamani, Soren N. Madsen, Thomas S. Luchik, Eric Hertzberg, Michael M. Tice, Michael E. Schein, Patrick J. McNally, Kris Kozaczek, Mitchell H. Au, T. J. Parker, George Allen, Raul M. Perez, Marc C. Foote, Amarit Kitiyakara, P. C. Stek, James L. Lambert, Douglas Dawson, Kristen M. Macneal, Lawrence A. Wade, Juan Villalvazo, Igor Ponomarev, Yejun He, John Leif Jørgensen, Patrick Meras, David R. Thompson, Jenna Delaney, Robert J. Calvet, R. T. Schaefer, Johannes Gross, Jackson T. Harris, Mary Soria, Scott Davidoff, Ernesto Diaz, Brett Hannah, Michael Evans, Jared Sachs, Raul A. Romero, and Sterling Conaby

Subjects
010504 meteorology & atmospheric sciences, Hyperspectral imaging, Astronomy and Astrophysics, Mars Exploration Program, 01 natural sciences, Texture (geology), law.invention, Lens (optics), Planetary science, Space and Planetary Science, law, 0103 physical sciences, High spatial resolution, Scale (map), 010303 astronomy & astrophysics, Robotic arm, 0105 earth and related environmental sciences, Remote sensing
Abstract

Planetary Instrument for X-ray Lithochemistry (PIXL) is a micro-focus X-ray fluorescence spectrometer mounted on the robotic arm of NASA’s Perseverance rover. PIXL will acquire high spatial resolution observations of rock and soil chemistry, rapidly analyzing the elemental chemistry of a target surface. In 10 seconds, PIXL can use its powerful 120 μm-diameter X-ray beam to analyze a single, sand-sized grain with enough sensitivity to detect major and minor rock-forming elements, as well as many trace elements. Over a period of several hours, PIXL can autonomously raster-scan an area of the rock surface and acquire a hyperspectral map comprised of several thousand individual measured points. When correlated to a visual image acquired by PIXL’s camera, these maps reveal the distribution and abundance variations of chemical elements making up the rock, tied accurately to the physical texture and structure of the rock, at a scale comparable to a 10X magnifying geological hand lens. The many thousands of spectra in these postage stamp-sized elemental maps may be analyzed individually or summed together to create a bulk rock analysis, or subsets of spectra may be summed, quantified, analyzed, and compared using PIXLISE data analysis software. This hand lens-scale view of the petrology and geochemistry of materials at the Perseverance landing site will provide a valuable link between the larger, centimeter- to meter-scale observations by Mastcam-Z, RIMFAX and Supercam, and the much smaller (micron-scale) measurements that would be made on returned samples in terrestrial laboratories.

Published
2020

25. Post-landing major element quantification using SuperCam laser induced breakdown spectroscopy

Author

Ryan B. Anderson, Olivier Forni, Agnes Cousin, Roger C. Wiens, Samuel M. Clegg, Jens Frydenvang, Travis S.J. Gabriel, Ann Ollila, Susanne Schröder, Olivier Beyssac, Erin Gibbons, David S. Vogt, Elise Clavé, Jose-Antonio Manrique, Carey Legett, Paolo Pilleri, Raymond T. Newell, Joseph Sarrao, Sylvestre Maurice, Gorka Arana, Karim Benzerara, Pernelle Bernardi, Sylvain Bernard, Bruno Bousquet, Adrian J. Brown, César Alvarez-Llamas, Baptiste Chide, Edward Cloutis, Jade Comellas, Stephanie Connell, Erwin Dehouck, Dorothea M. Delapp, Ari Essunfeld, Cecile Fabre, Thierry Fouchet, Cristina Garcia-Florentino, Laura García-Gómez, Patrick Gasda, Olivier Gasnault, Elisabeth M. Hausrath, Nina L. Lanza, Javier Laserna, Jeremie Lasue, Guillermo Lopez, Juan Manuel Madariaga, Lucia Mandon, Nicolas Mangold, Pierre-Yves Meslin, Anthony E. Nelson, Horton Newsom, Adriana L. Reyes-Newell, Scott Robinson, Fernando Rull, Shiv Sharma, Justin I. Simon, Pablo Sobron, Imanol Torre Fernandez, Arya Udry, Dawn Venhaus, Scott M. McLennan, Richard V. Morris, Bethany Ehlmann, US Geological Survey [Flagstaff], United States Geological Survey [Reston] (USGS), Institut de recherche en astrophysique et planétologie (IRAP), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Los Alamos National Laboratory (LANL), Globe Institute, Faculty of Health and Medical Sciences, University of Copenhagen = Københavns Universitet (UCPH)-University of Copenhagen = Københavns Universitet (UCPH), DLR Institute of Optical Sensor Systems, Deutsches Zentrum für Luft- und Raumfahrt [Berlin] (DLR), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), McGill University = Université McGill [Montréal, Canada], Centre d'Etudes Lasers Intenses et Applications (CELIA), Université de Bordeaux (UB)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Centre National de la Recherche Scientifique (CNRS), Universidad de Valladolid [Valladolid] (UVa), University of the Basque Country/Euskal Herriko Unibertsitatea (UPV/EHU), Laboratoire d'études spatiales et d'instrumentation en astrophysique = Laboratory of Space Studies and Instrumentation in Astrophysics (LESIA), Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire de Paris, Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS)-Université Paris Cité (UPCité), Plancius Research LLC, Universidad de Málaga [Málaga] = University of Málaga [Málaga], University of Manitoba [Winnipeg], Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), GeoRessources, Institut national des sciences de l'Univers (INSU - CNRS)-Centre de recherches sur la géologie des matières premières minérales et énergétiques (CREGU)-Université de Lorraine (UL)-Centre National de la Recherche Scientifique (CNRS), University of Nevada [Las Vegas] (WGU Nevada), Laboratoire de Planétologie et Géosciences [UMR_C 6112] (LPG), Université d'Angers (UA)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)-Nantes université - UFR des Sciences et des Techniques (Nantes univ - UFR ST), Nantes Université - pôle Sciences et technologie, Nantes Université (Nantes Univ)-Nantes Université (Nantes Univ)-Nantes Université - pôle Sciences et technologie, Nantes Université (Nantes Univ)-Nantes Université (Nantes Univ), The University of New Mexico [Albuquerque], University of Hawai‘i [Mānoa] (UHM), NASA Johnson Space Center (JSC), NASA, Search for Extraterrestrial Intelligence Institute (SETI), State University of New York at Stony Brook, Stony Brook University [SUNY] (SBU), State University of New York (SUNY)-State University of New York (SUNY), Division of Geological and Planetary Sciences [Pasadena], and California Institute of Technology (CALTECH)

Subjects
LIBS, Mars, Multivariate regression, Laser induced breakdown spectroscopy, Regression, Atomic and Molecular Physics, and Optics, Analytical Chemistry, [SDU]Sciences of the Universe [physics], Calibration, Chemometrics, Laser induced breakdown spectroscopy LIBS Mars Multivariate regression Regression Chemometrics Calibration, Instrumentation, Spectroscopy
Abstract

International audience; The SuperCam instrument on the Perseverance Mars 2020 rover uses a pulsed 1064 nm laser to ablate targets at a distance and conduct laser induced breakdown spectroscopy (LIBS) by analyzing the light from the resulting plasma. SuperCam LIBS spectra are preprocessed to remove ambient light, noise, and the continuum signal present in LIBS observations. Prior to quantification, spectra are masked to remove noisier spectrometer regions and spectra are normalized to minimize signal fluctuations and effects of target distance. In some cases, the spectra are also standardized or binned prior to quantification. To determine quantitative elemental compositions of diverse geologic materials at Jezero crater, Mars, we use a suite of 1198 laboratory spectra of 334 well-characterized reference samples. The samples were selected to span a wide range of compositions and include typical silicate rocks, pure minerals (e.g., silicates, sulfates, carbonates, oxides), more unusual compositions (e.g., Mn ore and sodalite), and replicates of the sintered SuperCam calibration targets (SCCTs) onboard the rover. For each major element (SiO2, TiO2, Al2O3, FeOT, MgO, CaO, Na2O, K2O), the database was subdivided into five "folds" with similar distributions of the element of interest. One fold was held out as an independent test set, and the remaining four folds were used to optimize multivariate regression models relating the spectrum to the composition. We considered a variety of models, and selected several for further investigation for each element, based primarily on the root mean squared error of prediction (RMSEP) on the test set, when analyzed at 3 m. In cases with several models of comparable performance at 3 m, we incorporated the SCCT performance at different distances to choose the preferred model. Shortly after landing on Mars and collecting initial spectra of geologic targets, we selected one model per element. Subsequently, with additional data from geologic targets, some models were revised to ensure results that are more consistent with geochemical constraints. The calibration discussed here is a snapshot of an ongoing effort to deliver the most accurate chemical compositions with SuperCam LIBS.

Published
2022

26. Chlorine Release From Common Chlorides by Martian Dust Activity

Author

Scott M. McLennan, William M. Farrell, Alian Wang, Kun Wang, Yuanchao Yan, Bradley L. Jolliff, and Erbin Shi

Subjects
Martian, Geophysics, chemistry, Space and Planetary Science, Geochemistry and Petrology, Earth and Planetary Sciences (miscellaneous), Chlorine, chemistry.chemical_element, Mars Exploration Program, Electrochemistry, Astrobiology
Published
2020

27. Reevaluation of Perchlorate in Gale Crater Rocks Suggests Geologically Recent Perchlorate Addition

Author

P. Douglas Archer, Kirsten L. Siebach, John P. Grotzinger, Kenneth A. Farley, P. Martin, Scott M. McLennan, and J. V. Hogancamp

Subjects
Martian, geography, geography.geographical_feature_category, 010504 meteorology & atmospheric sciences, Bedrock, Amazonian, Geochemistry, Martian soil, Mars Exploration Program, 01 natural sciences, Diagenesis, Perchlorate, chemistry.chemical_compound, Geophysics, chemistry, Space and Planetary Science, Geochemistry and Petrology, Sample Analysis at Mars, Earth and Planetary Sciences (miscellaneous), 0105 earth and related environmental sciences
Abstract

Perchlorate (ClO₄⁻) was discovered in Martian soil by the Phoenix lander, with important implications for potential Martian biology, photochemistry, aqueous chemistry, and the chlorine cycle on Mars. Perchlorate was subsequently reported in both loose sediment and bedrock samples analyzed by the Sample Analysis at Mars instrument onboard the Curiosity rover in Gale crater based on a release of O₂ at 200–500°C. However, the continually wet paleoenvironment recorded by the sedimentary rocks in Gale crater was not conducive to the deposition of highly soluble salts. Furthermore, the preservation of ancient perchlorate to the modern day is unexpected due to its low thermodynamic stability and radiolytic decomposition associated with its long exposure to radioactivity and cosmic radiation. We therefore investigate alternative sources of O₂ in Sample Analysis at Mars analyses including superoxides, sulfates, nitrate, and nanophase iron and manganese oxides. Geochemical evidence and oxygen release patterns observed by Curiosity are inconsistent with each of these alternatives. We conclude that perchlorate is indeed the most likely source of the detected O2 release at 200–500°C, but contend that it is unlikely to be ancient. Rather than being associated with the lacustrine or early diagenetic environment, the most likely origin of perchlorate in the bedrock is late stage addition by downward percolation of water through rock pore space during transient wetting events in the Amazonian. The conclusion that the observed perchlorate in Gale crater is most likely Amazonian suggests the presence of recent liquid water at the modern surface.

Published
2020

28. Extraformational sediment recycling on Mars

Author

Kristen A. Bennett, Scott M. McLennan, Marie J. Henderson, Rebecca M. E. Williams, Scott K. Rowland, Steven G. Banham, John P. Grotzinger, Christopher S. Edwards, Deirdra M. Fey, R. Aileen Yingst, Lucy M. Thompson, Christopher H. House, Roger C. Wiens, Sanjeev Gupta, Alberto G. Fairén, Kirsten L. Siebach, Lauren A. Edgar, Horton E. Newsom, James B. Garvin, Kenneth S. Edgett, Nicolas Mangold, Christopher M. Fedo, Scott VanBommel, Yingst, R. A., Banham, S. [0000-0003-1206-1639], Gupta, S. [0000-0001-6415-1332], Edgett, K. [0000-0001-7197-5751], Project 'MarsFirstWater, Science and Technology Facilities Council (STFC), UK Space Agency, Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737, European Research Council (ERC), Malin Space Science Systems (MSSS), Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), and Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS)

Subjects
Geochemistry & Geophysics, 010504 meteorology & atmospheric sciences, Stratigraphy, [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], Geochemistry, Mars, 0404 Geophysics, Geologic record, Sediment recycling, 01 natural sciences, Unconformity, Article, Conglomerate, Impact crater, 0103 physical sciences, 0402 Geochemistry, 14. Life underwater, 010303 astronomy & astrophysics, Lithification, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, Sediment, Geology, Gale crater, Mineralogy, 0403 Geology, 13. Climate action, Hesperian, Sedimentary rock
Abstract

Extraformational sediment recycling (old sedimentary rock to new sedimentary rock) is a fundamental aspect of Earth's geological record; tectonism exposes sedimentary rock, whereupon it is weathered and eroded to form new sediment that later becomes lithified. On Mars, tectonism has been minor, but two decades of orbiter instrument-based studies show that some sedimentary rocks previously buried to depths of kilometers have been exposed, by erosion, at the surface. Four locations in Gale crater, explored using the National Aeronautics and Space Administration's Curiosity rover, exhibit sedimentary lithoclasts in sedimentary rock: At Marias Pass, they are mudstone fragments in sandstone derived from strata below an erosional unconformity; at Bimbe, they are pebble-sized sandstone and, possibly, laminated, intraclast-bearing, chemical (calcium sulfate) sediment fragments in conglomerates; at Cooperstown, they are pebble-sized fragments of sandstone within coarse sandstone; at Dingo Gap, they are cobble-sized, stratified sandstone fragments in conglomerate derived from an immediately underlying sandstone. Mars orbiter images show lithified sediment fans at the termini of canyons that incise sedimentary rock in Gale crater; these, too, consist of recycled, extraformational sediment. The recycled sediments in Gale crater are compositionally immature, indicating the dominance of physical weathering processes during the second known cycle. The observations at Marias Pass indicate that sediment eroded and removed from craters such as Gale crater during the Martian Hesperian Period could have been recycled to form new rock elsewhere. Our results permit prediction that lithified deltaic sediments at the Perseverance (landing in 2021) and Rosalind Franklin (landing in 2023) rover field sites could contain extraformational recycled sediment., With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)

Published
2020

29. Seismic Velocities Distribution in a 3D Mantle: Implications for InSight Measurements

Author

Daniel Peter, Caio Ciardelli, Scott M. McLennan, Scott D. King, Nicola Tosi, Ana-Catalina Plesa, Sebastiano Padovan, Doris Breuer, Tilman Spohn, Ebru Bozdag, Amir Khan, Martin Knapmeyer, Martin van Driel, Attilio Rivoldini, Mark A. Wieczorek, and S. C. Staehler

Subjects
Seismometer, Observatory, seismic velocities, Tectonophysics, Mars, Geophysics, Mars Exploration Program, Geology, Mantle (geology), Elysium, InSight
Abstract

The InSight mission [1] landed in November 2018 in the Elysium Planitia region [2] bringing the first geophysical observatory to Mars. Since February 2019 the seismometer SEIS [3] has continuously ...

Published
2020

30. Initial results from the InSight mission on Mars

Author

Sharon Kedar, Don Banfield, Scott M. McLennan, Nicholas Schmerr, Justin N. Maki, Gareth S. Collins, John Clinton, Anna Mittelholz, Paul Morgan, Mélanie Drilleau, Sabine Stanley, Chloé Michaut, Nicholas A Teanby, Daniele Antonangeli, Jeroen Tromp, W. Bruce Banerdt, James B. Garvin, Mark A. Wieczorek, Jerzy Grygorczuk, Suzanne E. Smrekar, Catherine L. Johnson, Aymeric Spiga, Peter Chi, Brigitte Knapmeyer-Endrun, Raphaël F. Garcia, Claire E. Newman, Seiichi Nagihara, Matthias Grott, W. Thomas Pike, Philippe Lognonné, Véronique Dehant, Ana-Catalina Plesa, Matthew Fillingim, Domenico Giardini, Taichi Kawamura, Mark T. Lemmon, Antoine Mocquet, Naomi Murdoch, Ebru Bozdag, David Mimoun, Ludovic Margerin, Matthew P. Golombek, Jessica C. E. Irving, Troy L. Hudson, Sami W. Asmar, Günter Kargl, Martin Knapmeyer, Mark P. Panning, Francis Nimmo, Scott D. King, John A. Grant, Sebastien Rodriguez, Martin van Driel, Nicholas H. Warner, Nils Mueller, José Antonio Rodríguez-Manfredi, Christopher T. Russell, Caroline Beghein, Clément Perrin, Ulrich R. Christensen, William M. Folkner, Renee Weber, Neil Bowles, Ingrid Daubar, Simon Stähler, Tilman Spohn, Eléanore Stutzmann, Ralph D. Lorenz, Matthew A. Siegler, Institut Supérieur de l'Aéronautique et de l'Espace - ISAE-SUPAERO (FRANCE), Jet Propulsion Laboratory (JPL), California Institute of Technology (CALTECH)-NASA, Cornell Center for Astrophysics and Planetary Science (CCAPS), Cornell University, Institute of Geophysics [ETH Zürich], Department of Earth Sciences [ETH Zürich] (D-ERDW), Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology in Zürich [Zürich] (ETH Zürich)-Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology in Zürich [Zürich] (ETH Zürich), Department of Earth, Ocean and Atmospheric Sciences [Vancouver] (EOAS), University of British Columbia (UBC), Département de géophysique spatiale et planétaire (DGSP (UMR_7096)), Université Paris Diderot - Paris 7 (UPD7)-IPG PARIS-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Météorologie Dynamique (UMR 8539) (LMD), Département des Géosciences - ENS Paris, École normale supérieure - Paris (ENS Paris)-École normale supérieure - Paris (ENS Paris)-Centre National de la Recherche Scientifique (CNRS)-École des Ponts ParisTech (ENPC)-École polytechnique (X)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), DLR Institut für Planetenforschung, Deutsches Zentrum für Luft- und Raumfahrt [Berlin] (DLR), Institut de Physique du Globe de Paris (IPGP), Institut national des sciences de l'Univers (INSU - CNRS)-IPG PARIS-Université Paris Diderot - Paris 7 (UPD7)-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS), Institut de minéralogie, de physique des matériaux et de cosmochimie (IMPMC), Muséum national d'Histoire naturelle (MNHN)-Institut de recherche pour le développement [IRD] : UR206-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Department of Atmospheric, Oceanic and Planetary Physics [Oxford] (AOPP), University of Oxford [Oxford], Department of Geosciences [Princeton], Princeton University, Max Planck Institute for Solar System Research (MPS), Max-Planck-Gesellschaft, Swiss Seismological Service [ETH Zurich] (SED), Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology in Zürich [Zürich] (ETH Zürich)-Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology in Zürich [Zürich] (ETH Zürich)-Department of Earth Sciences [ETH Zürich] (D-ERDW), Department of Earth Science and Engineering [Imperial College London], Imperial College London, Department of Earth, Environmental and Planetary Sciences [Providence], Brown University, Royal Observatory of Belgium [Brussels], Space Sciences Laboratory [Berkeley] (SSL), University of California [Berkeley], University of California-University of California, Département Electronique, Optronique et Signal (DEOS), Institut Supérieur de l'Aéronautique et de l'Espace (ISAE-SUPAERO), Institute of Remote Sensing and Geographic Information System (IRSGIS), School of Earth and Space Sciences [Beijing], Peking University [Beijing]-Peking University [Beijing], Austrian Academy of Sciences (OeAW), Graphics and Vision Research Laboratory (Graphics Lab), University of Otago [Dunedin, Nouvelle-Zélande], Deutsches Zentrum für Luft- und Raumfahrt (DLR), Space Science Institute [Boulder] (SSI), Johns Hopkins University Applied Physics Laboratory [Laurel, MD] (APL), Department of Geosciences, Stony Brook University [SUNY] (SBU), State University of New York (SUNY)-State University of New York (SUNY), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Nantes - Faculté des Sciences et des Techniques, Université de Nantes (UN)-Université de Nantes (UN)-Université d'Angers (UA), AstraZeneca, Aeolis Research, Department of Earth and Planetary Sciences [Santa Cruz], University of California [Santa Cruz] (UCSC), Department of Geological Sciences, University of Florida [Gainesville], Centro de Astrobiologia [Madrid] (CAB), Instituto Nacional de Técnica Aeroespacial (INTA)-Consejo Superior de Investigaciones Científicas [Spain] (CSIC), Department of Earth, Planetary and Space Sciences [Los Angeles] (EPSS), University of California [Los Angeles] (UCLA), The Open University [Milton Keynes] (OU), Morton K. Blaustein Department of Earth and Planetary Sciences [Baltimore], Johns Hopkins University (JHU), School of Earth Sciences [Bristol], University of Bristol [Bristol], Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology in Zürich [Zürich] (ETH Zürich), University of Southern California (USC), Joseph Louis LAGRANGE (LAGRANGE), Université Nice Sophia Antipolis (... - 2019) (UNS), COMUE Université Côte d'Azur (2015 - 2019) (COMUE UCA)-COMUE Université Côte d'Azur (2015 - 2019) (COMUE UCA)-Observatoire de la Côte d'Azur, COMUE Université Côte d'Azur (2015 - 2019) (COMUE UCA)-Centre National de la Recherche Scientifique (CNRS), Cornell University [New York], Department of Earth Sciences [Swiss Federal Institute of Technology - ETH Zürich] (D-ERDW), Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology [Zürich] (ETH Zürich)- Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology [Zürich] (ETH Zürich), Department of Earth, Ocean and Atmospheric Sciences [Vancouver] (UBC EOAS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-IPG PARIS-Université Paris Diderot - Paris 7 (UPD7)-Université de La Réunion (UR)-Centre National de la Recherche Scientifique (CNRS), École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS Paris), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-Centre National de la Recherche Scientifique (CNRS)-École des Ponts ParisTech (ENPC)-École polytechnique (X)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Pierre et Marie Curie - Paris 6 (UPMC), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Muséum national d'Histoire naturelle (MNHN)-Centre National de la Recherche Scientifique (CNRS), Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology [Zürich] (ETH Zürich)- Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology [Zürich] (ETH Zürich)-Department of Earth Sciences [Swiss Federal Institute of Technology - ETH Zürich] (D-ERDW), Royal Observatory of Belgium [Brussels] (ROB), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Southwest Research Institute [Boulder] (SwRI), Astrophysique Interprétation Modélisation (AIM (UMR_7158 / UMR_E_9005 / UM_112)), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Université Paris Diderot - Paris 7 (UPD7), Instituto Nacional de Técnica Aeroespacial (INTA)-Consejo Superior de Investigaciones Científicas [Madrid] (CSIC), University of California, Eidgenössische Technische Hochschule - Swiss Federal Institute of Technology [Zürich] (ETH Zürich), NASA-California Institute of Technology (CALTECH), Institut de recherche pour le développement [IRD] : UR206-Muséum national d'Histoire naturelle (MNHN)-Sorbonne Université (SU)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Université de La Réunion (UR)-Institut de Physique du Globe de Paris (IPG Paris)-Centre National de la Recherche Scientifique (CNRS), Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut national des sciences de l'Univers (INSU - CNRS)-École polytechnique (X)-École des Ponts ParisTech (ENPC)-Centre National de la Recherche Scientifique (CNRS)-Département des Géosciences - ENS Paris, École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL)-École normale supérieure - Paris (ENS-PSL), Université Paris sciences et lettres (PSL)-Université Paris sciences et lettres (PSL), Muséum national d'Histoire naturelle (MNHN)-Université Pierre et Marie Curie - Paris 6 (UPMC)-Institut de recherche pour le développement [IRD] : UR206-Centre National de la Recherche Scientifique (CNRS), University of Oxford, Max-Planck-Institut für Sonnensystemforschung = Max Planck Institute for Solar System Research (MPS), University of California [Berkeley] (UC Berkeley), University of California (UC)-University of California (UC), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), University of California [Santa Cruz] (UC Santa Cruz), Astrophysique Interprétation Modélisation (AIM (UMR7158 / UMR_E_9005 / UM_112)), Commissariat à l'énergie atomique et aux énergies alternatives (CEA)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Paris Diderot - Paris 7 (UPD7)-Centre National de la Recherche Scientifique (CNRS), University of California (UC), Unidad de Excelencia Científica María de Maeztu Centro de Astrobiología del Instituto Nacional de Técnica Aeroespacial y CSIC, MDM-2017-0737, Tromp, J. [0000-0002-2742-8299], Rodríguez, S. [0000-0003-1219-0641], Lognonné, P. [0000-0002-1014-920X], Perrin, C. [0000-0002-7200-5682], Murdoch, N. [0000-0002-9701-4075], Knapmeyer, M. [0000-0003-0319-2514], Rodríguez Manfredi, J. A. [0000-0003-0461-9815], Spiga, A. [0000-0002-6776-6268], Panning, M. P. [0000-0002-2041-3190], García, R. [0000-0003-1460-6663], Johnson, C. [0000-0001-6084-0149], Stutzmann, E. [0000-0002-4348-7475], Knapmeyer-Endrun, B. [0000-0003-3309-6785], Schmerr, N. [0000-0002-3256-1262], Irving, J. C. E. [0000-0002-0866-8246], Morgan, P. [0000-0001-8714-4178], Mueller, N. [0000-0001-9229-8921], Pike, W. [0000-0002-7660-6231], Kawamura, T. [0000-0001-5246-5561], Clinton, J. [0000-0001-8626-2703], Agence Nationale de la Recherche (ANR), Swiss National Science Foundation (SNSF), Agence Nationale de la Recherche (ANR), ANR-10LABX-0023 ANR-11-IDEX-0005-0, Swiss National Science Foundation (SNSF- ANR project), 157133, ETH Research grant, ETH-06 17-02, Lunar and Planetary Institute, 2250, UCL - SST/ELI/ELIC - Earth & Climate, Science and Technology Facilities Council (STFC), and Science & Technology Facilities Council

Subjects
Seismometer, 010504 meteorology & atmospheric sciences, [PHYS.ASTR.EP]Physics [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], [SDU.ASTR.EP]Sciences of the Universe [physics]/Astrophysics [astro-ph]/Earth and Planetary Astrophysics [astro-ph.EP], Mars, 010502 geochemistry & geophysics, 01 natural sciences, Atmosphere, [SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology, Impact crater, Autre, Planet, Inner planets, InSight Mars Geophysik, Meteorology & Atmospheric Sciences, Seismology, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences, Atmospheric dynamics, Geomorphology, Moment magnitude scale, Mars InSight, Geomagnetism, Mars Exploration Program, Geophysics, [SDU]Sciences of the Universe [physics], 13. Climate action, Intraplate earthquake, General Earth and Planetary Sciences, Timekeeping on Mars, [SDU.OTHER]Sciences of the Universe [physics]/Other, InSight mission, Geology
Abstract

Banerdt, William B. et al., NASA’s InSight (Interior exploration using Seismic Investigations, Geodesy and Heat Transport) mission landed in Elysium Planitia on Mars on 26 November 2018. It aims to determine the interior structure, composition and thermal state of Mars, as well as constrain present-day seismicity and impact cratering rates. Such information is key to understanding the differentiation and subsequent thermal evolution of Mars, and thus the forces that shape the planet’s surface geology and volatile processes. Here we report an overview of the first ten months of geophysical observations by InSight. As of 30 September 2019, 174 seismic events have been recorded by the lander’s seismometer, including over 20 events of moment magnitude M = 3–4. The detections thus far are consistent with tectonic origins, with no impact-induced seismicity yet observed, and indicate a seismically active planet. An assessment of these detections suggests that the frequency of global seismic events below approximately M = 3 is similar to that of terrestrial intraplate seismic activity, but there are fewer larger quakes; no quakes exceeding M = 4 have been observed. The lander’s other instruments—two cameras, atmospheric pressure, temperature and wind sensors, a magnetometer and a radiometer—have yielded much more than the intended supporting data for seismometer noise characterization: magnetic field measurements indicate a local magnetic field that is ten-times stronger than orbital estimates and meteorological measurements reveal a more dynamic atmosphere than expected, hosting baroclinic and gravity waves and convective vortices. With the mission due to last for an entire Martian year or longer, these results will be built on by further measurements by the InSight lander., With funding from the Spanish government through the "María de Maeztu Unit of Excellence" accreditation (MDM-2017-0737)

Published
2020

32. Photochemical controls on chlorine and bromine geochemistry at the Martian surface

Author

Suniti Karunatillake, W. Andrew Jackson, Yu-Yan Sara Zhao, and Scott M. McLennan

Subjects
Bromine, 010504 meteorology & atmospheric sciences, Chlorate, chemistry.chemical_element, Photochemistry, Bromate, 01 natural sciences, Chloride, chemistry.chemical_compound, Perchlorate, Geophysics, chemistry, Space and Planetary Science, Geochemistry and Petrology, Bromide, 0103 physical sciences, Halogen, Earth and Planetary Sciences (miscellaneous), medicine, Chlorine, 010303 astronomy & astrophysics, Geology, 0105 earth and related environmental sciences, medicine.drug
Abstract

Widely distributed perchlorate on the Martian surface and over three orders of magnitude variation in bromine abundances in surface samples are difficult to explain solely by chloride and bromide aqueous geochemistry. New experiments show that photochemical oxidation (ultraviolet wavelength 254 nm) of chloride- and bromide-bearing evaporative brines in the presence of silica beads produces substantial perchlorate (ClO − 4 ), chlorate (ClO − 3 ), and bromate (BrO − 3 ) under conditions relevant to Mars. Neutral to alkaline aqueous environments result in the dominance of chlorate over perchlorate. Preferential atmospheric recycling of Br over Cl causes variable Br/Cl ratios, consistent with numerous in-situ measurements of Cl and Br abundances on Mars. Bromate reacts with organics more readily than chlorate or perchlorate, and its presence in subsurface brines could challenge habitability in the Martian subsurface.

Published
2018

33. Improved accuracy in quantitative laser-induced breakdown spectroscopy using sub-models

Author

Scott M. McLennan, Ryan B. Anderson, Bethany L. Ehlmann, M. Darby Dyar, Richard V. Morris, Roger C. Wiens, Samuel M. Clegg, and Jens Frydenvang

Subjects
Multivariate statistics, 010504 meteorology & atmospheric sciences, Mean squared error, 010401 analytical chemistry, Regression analysis, Mars Exploration Program, 01 natural sciences, Atomic and Molecular Physics, and Optics, 0104 chemical sciences, Analytical Chemistry, Test set, Partial least squares regression, Calibration, Environmental science, Laser-induced breakdown spectroscopy, Instrumentation, Spectroscopy, 0105 earth and related environmental sciences, Remote sensing
Abstract

Accurate quantitative analysis of diverse geologic materials is one of the primary challenges faced by the laser-induced breakdown spectroscopy (LIBS)-based ChemCam instrument on the Mars Science Laboratory (MSL) rover. The SuperCam instrument on the Mars 2020 rover, as well as other LIBS instruments developed for geochemical analysis on Earth or other planets, will face the same challenge. Consequently, part of the ChemCam science team has focused on the development of improved multivariate analysis calibrations methods. Developing a single regression model capable of accurately determining the composition of very different target materials is difficult because the response of an element's emission lines in LIBS spectra can vary with the concentration of other elements. We demonstrate a conceptually simple “sub-model” method for improving the accuracy of quantitative LIBS analysis of diverse target materials. The method is based on training several regression models on sets of targets with limited composition ranges and then “blending” these “sub-models” into a single final result. Tests of the sub-model method show improvement in test set root mean squared error of prediction (RMSEP) for almost all cases. The sub-model method, using partial least squares (PLS) regression, is being used as part of the current ChemCam quantitative calibration, but the sub-model method is applicable to any multivariate regression method and may yield similar improvements.

Published
2017

34. Geochemical constraints on the presence of clay minerals in the Burns formation, Meridiani Planum, Mars

Author

C. D. Cino, Erwin Dehouck, and Scott M. McLennan

Subjects
Meridiani Planum, Mineral, 010504 meteorology & atmospheric sciences, Chemistry, Geochemistry, Astronomy and Astrophysics, Nontronite, engineering.material, 010502 geochemistry & geophysics, 01 natural sciences, Space and Planetary Science, Illite, engineering, Kaolinite, Sulfate minerals, Clay minerals, 0105 earth and related environmental sciences, Geochemical modeling
Abstract

Burns formation sandstones, deposited by aeolian processes and preserved at Meridiani Planum, Mars, contain abundant sulfate minerals. These sedimentary rocks are thought to be representative of a sulfate-rich geological epoch during late Noachian – early Hesperian time that followed an earlier clay-rich epoch. Twenty Burns formation targets, abraded by the Rock Abrasion Tool (RAT) and for which alpha-particle X-ray spectrometry (APXS) and Mossbauer spectroscopy data are available, were selected for geochemical modeling. A linear unmixing modeling approach was employed. Mineralogical constituents quantitatively constrained by Mossbauer and Mini-TES spectroscopy and interpreted to be chemically precipitated from aqueous fluids during deposition and/or early diagenesis were subtracted from the bulk chemistry. Resulting residual chemical compositions, interpreted to be dominated by detrital siliciclastic components and representing ∼21–35% of the rocks, were then geochemically evaluated to constrain the potential for the presence of clay minerals or their poorly-crystalline or non-crystalline precursors/chemical equivalents. Calculations incorporated a robust estimate of the uncertainties in mineral abundances. On Al2O3 – (CaO+Na2O) – K2O (A-CN-K) and Al2O3 – (CaO+Na2O+K2O) – (FeOtotal+MgO) (A-CNK-FM) molar ternary diagrams, removal of chemical constituents resulted in a shift from igneous–like compositions to compositions consistent with secondary mineral assemblages containing significant aluminous clay mineral components. All of the residual compositions are corundum-normative, further supportive of the presence of highly aluminous phases. On the A-CNK-FM diagram, clay minerals plotting closest to the residual field are natural montmorillonites but could also represent mixtures of various Mg/Fe-rich phyllosilicates, such as nontronite or saponite, and other more Al-rich minerals such as Al-montmorillonite, kaolinite or illite. Depending on the age of clay mineral formation, occurrence of clay minerals or their poorly crystalline precursors/chemical equivalents in the Burns formation could suggest that any global transition from clay-rich to sulfate-rich environments on early Mars was more complex than previously recognized. Results are also consistent with models for the Burns formation aqueous history in which acidic conditions were more restricted in time and/or space than previously thought and thus may also be consistent with growing evidence that changing redox conditions, rather than global pH variations, was an important factor in the environmental evolution of early Mars.

Published
2017

35. Discordant K-Ar and young exposure dates for the Windjana sandstone, Kimberley, Gale Crater, Mars

Author

Kenneth A. Farley, Paulo M. Vasconcelos, Melissa S. Rice, Charles Malespin, Scott M. McLennan, D. W. Ming, Paul Mahaffy, and Joel A. Hurowitz

Subjects
010504 meteorology & atmospheric sciences, Outcrop, Gale crater, Mineralogy, Cosmic ray, Fractionation, Mars Exploration Program, Sanidine, 01 natural sciences, Geophysics, Space and Planetary Science, Geochemistry and Petrology, 0103 physical sciences, Geochronology, Sample Analysis at Mars, Earth and Planetary Sciences (miscellaneous), 010303 astronomy & astrophysics, Geology, 0105 earth and related environmental sciences
Abstract

K-Ar and noble gas surface exposure age measurements were carried out on the Windjana sandstone, Kimberley region, Gale Crater, Mars, by using the Sample Analysis at Mars instrument on the Curiosity rover. The sandstone is unusually rich in sanidine, as determined by CheMin X-ray diffraction, contributing to the high K_2O concentration of 3.09 ± 0.20 wt % measured by Alpha-Particle X-ray Spectrometer analysis. A sandstone aliquot heated to ~915°C yielded a K-Ar age of 627 ± 50 Ma. Reheating this aliquot yielded no additional Ar. A second aliquot heated in the same way yielded a much higher K-Ar age of 1710 ± 110 Ma. These data suggest incomplete Ar extraction from a rock with a K-Ar age older than 1710 Ma. Incomplete extraction at ~900°C is not surprising for a rock with a large fraction of K carried by Ar-retentive K-feldspar. Likely, variability in the exact temperature achieved by the sample from run to run, uncertainties in sample mass estimation, and possible mineral fractionation during transport and storage prior to analysis may contribute to these discrepant data. Cosmic ray exposure ages from ^3He and ^(21)Ne in the two aliquots are minimum values given the possibility of incomplete extraction. However, the general similarity between the ^3He (57 ± 49 and 18 ± 32 Ma, mean 30 Ma) and ^(21)Ne (2 ± 32 and 83 ± 24 Ma, mean 54 Ma) exposure ages provides no evidence for underextraction. The implied erosion rate at the Kimberley location is similar to that reported at the nearby Yellowknife Bay outcrop.

Published
2016

36. Chemical alteration of fine-grained sedimentary rocks at Gale crater

Author

Roger C. Wiens, Thomas F. Bristow, C. Fedo, Erwin Dehouck, Frances Rivera-Hernandez, Horton E. Newsom, Mark R. Salvatore, Cherie N. Achilles, Olivier Gasnault, Scott M. McLennan, Jonas L'Haridon, Olivier Forni, W. Rapin, P. Y. Meslin, Jens Frydenvang, Robert T. Downs, N. Mangold, L. Le Deit, Shaunna M. Morrison, Sylvestre Maurice, E. B. Rampe, Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement [Lyon] (LGL-TPE), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-École normale supérieure - Lyon (ENS Lyon), Laboratoire de Planétologie et Géodynamique [UMR 6112] (LPG), Université d'Angers (UA)-Université de Nantes - UFR des Sciences et des Techniques (UN UFR ST), Université de Nantes (UN)-Université de Nantes (UN)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Géologie de Lyon - Terre, Planètes, Environnement (LGL-TPE), École normale supérieure de Lyon (ENS de Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Université Jean Monnet - Saint-Étienne (UJM)-Centre National de la Recherche Scientifique (CNRS), Institut de recherche en astrophysique et planétologie (IRAP), Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Observatoire Midi-Pyrénées (OMP), Institut de Recherche pour le Développement (IRD)-Université Toulouse III - Paul Sabatier (UT3), Université de Toulouse (UT)-Université de Toulouse (UT)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Institut de Recherche pour le Développement (IRD)-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Météo-France -Centre National de la Recherche Scientifique (CNRS), Exobiology Branch [Moffett Field], NASA Ames Research Center (ARC), Stony Brook University [SUNY] (SBU), State University of New York (SUNY), Institute of Meteoritics [Albuquerque] (IOM), The University of New Mexico [Albuquerque], NASA Johnson Space Center (JSC), NASA, ANR-16-CE31-0012,MARS-PRIME,Environnement Primitif de Mars(2016), École normale supérieure - Lyon (ENS Lyon)-Université Claude Bernard Lyon 1 (UCBL), Université de Lyon-Université de Lyon-Institut national des sciences de l'Univers (INSU - CNRS)-Centre National de la Recherche Scientifique (CNRS), Institut national des sciences de l'Univers (INSU - CNRS)-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Observatoire Midi-Pyrénées (OMP), Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Université Fédérale Toulouse Midi-Pyrénées-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Météo France-Centre National d'Études Spatiales [Toulouse] (CNES)-Centre National de la Recherche Scientifique (CNRS)-Institut de Recherche pour le Développement (IRD)-Centre National de la Recherche Scientifique (CNRS), Laboratoire de Planétologie et Géodynamique UMR6112 (LPG), Centre National de la Recherche Scientifique (CNRS)-Institut national des sciences de l'Univers (INSU - CNRS)-Université de Nantes - Faculté des Sciences et des Techniques, Université de Nantes (UN)-Université de Nantes (UN)-Université d'Angers (UA), Centre National de la Recherche Scientifique (CNRS)-Observatoire Midi-Pyrénées (OMP), Université Fédérale Toulouse Midi-Pyrénées-Université Fédérale Toulouse Midi-Pyrénées-Université Toulouse III - Paul Sabatier (UT3), Université Fédérale Toulouse Midi-Pyrénées-Institut national des sciences de l'Univers (INSU - CNRS), University of Copenhagen = Københavns Universitet (KU), and Los Alamos National Laboratory (LANL)

Subjects
010504 meteorology & atmospheric sciences, Geochemistry, Gale crater, Astronomy and Astrophysics, Weathering, engineering.material, Curiosity rover, 01 natural sciences, [SDU.STU.PL]Sciences of the Universe [physics]/Earth Sciences/Planetology, 13. Climate action, Space and Planetary Science, [SDU]Sciences of the Universe [physics], 0103 physical sciences, engineering, Plagioclase, Sedimentary rock, Mafic, 010303 astronomy & astrophysics, Bay, Dissolution, Geology, ComputingMilieux_MISCELLANEOUS, 0105 earth and related environmental sciences
Abstract

From Sol 750 to 1550, the Curiosity rover documented>100 m thick stack of fine-grained sedimentary rocks making up part of the Murray formation, at the base of Mt Sharp, Gale crater. Here, we use data collected by the ChemCam instrument to estimate the level of chemical weathering in these sedimentary rocks. Both the Chemical Index of Alteration (CIA) and the Weathering Index Scale (WIS) indicate a progressive increase in alteration up section, reaching values of CIA of 63 and WIS of 25%. The increase in CIA and WIS values is coupled with a decrease in calcium abundance, suggesting partial dissolution of Ca-bearing minerals (clinopyroxene and plagioclase). Mineralogy from the CheMin X-ray diffraction instrument indicates a decrease in mafic minerals compared with previously analyzed strata and a significant proportion of phyllosilicates consistent with this interpretation. These observations suggest that the sediments were predominantly altered in an open system, before or during their emplacement, contrasting with the rock-dominated conditions inferred in sedimentary deposits analyzed at Yellowknife Bay.

Published
2019

37. Mars Exploration Rover Opportunity

Author

Ralf Gellert, Scott M. McLennan, William H. Farrand, David W. Mittlefehldt, Andrew H. Knoll, and Bradley L. Jolliff

Subjects
Meridiani Planum, Martian surface, visual_art, Noachian, visual_art.visual_art_medium, Geochemistry, Hesperian, Sedimentary rock, Mars Exploration Program, Hematite, Geology, Diagenesis
Abstract

The Opportunity rover has explored the surface of Mars in the area of southwestern Meridiani Planum since 2004. This site was specifically chosen because of orbital evidence for a watery past, evidenced by the occurrence of abundant hematite. Opportunity demonstrated that the primary source of hematite inferred from orbit is 1–6-mm concretions, observed both within regionally exposed sandstones and as residual erosional products distributed across the plains. Sandstones of the Late Noachian to Early Hesperian Burns formation also contain high concentrations of sulfate minerals, some of which are hydrated, including jarosite. The mineralogy and chemical compositions of ancient Meridiani sandstones bear witness to the alteration of basaltic protoliths, regional precipitation of evaporites, sedimentary reworking, diagenetic alteration involving groundwater interactions, oxidation, and perhaps more recent formation of alteration rinds and veneers on exposed rock surfaces. Traverses of the interiors and ejecta of successively larger impact craters have permitted Opportunity to investigate materials from different stratigraphic levels and thus different times. In particular, exploration of materials along the rim of the 22-km-diameter Endeavour Crater has revealed older Noachian rocks that bear evidence of phyllosilicate alteration. Aqueous alteration and cation/anion mobilization along fractures related to the Endeavour impact reflect ancient aqueous processes. Its fortuitous landing site and its longevity have allowed Opportunity to explore terrain and rocks spanning the Late Noachian to Early Hesperian transition on Mars, a time when an early, relatively wet Martian surface was essentially drying out.

Published
2019

38. List of Contributors

Author

John C. Bridges, Frances E.G. Butcher, Stephen M. Clifford, Susan J. Conway, William H. Farrand, Justin Filiberto, Heather B. Franz, Fabrice Gaillard, Ralf Gellert, Leon J. Hicks, Bradley L. Jolliff, Penelope L. King, Andrew H. Knoll, Samuel P. Kounaves, Jérémie Lasue, Paul R. Mahaffy, Nicolas Mangold, Amy C. McAdam, Francis M. McCubbin, Scott M. McLennan, Douglas W. Ming, David W. Mittlefehldt, John F. Mustard, Elizabeth A. Oberlin, Karen Olsson-Francis, Ulrich Ott, Susanne P. Schwenzer, Brad Sutter, Timothy D. Swindle, G. Jeffrey Taylor, Allan H. Treiman, Tomohiro Usui, and Albert S. Yen

Published
2019

39. The sedimentary cycle on early Mars

Author

Joel A. Hurowitz, Scott M. McLennan, John P. Grotzinger, and Nicholas J. Tosca

Subjects
Stratigraphy, Space and Planetary Science, Earth and Planetary Sciences (miscellaneous), Geochemistry, Astronomy and Astrophysics, Sedimentary rock, Mars Exploration Program, Sedimentology, Geology, Diagenesis
Abstract

Two decades of intensive research have demonstrated that early Mars ([Formula: see text]2 Gyr) had an active sedimentary cycle, including well-preserved stratigraphic records, understandable within a source-to-sink framework with remarkable fidelity. This early cycle exhibits first-order similarities to (e.g., facies relationships, groundwater diagenesis, recycling) and first-order differences from (e.g., greater aeolian versus subaqueous processes, basaltic versus granitic provenance, absence of plate tectonics) Earth's record. Mars’ sedimentary record preserves evidence for progressive desiccation and oxidation of the surface over time, but simple models for the nature and evolution of paleoenvironments (e.g., acid Mars, early warm and wet versus late cold and dry) have given way to the view that, similar to Earth, different climate regimes on Mars coexisted on regional scales and evolved on variable timescales, and redox chemistry played a pivotal role. A major accomplishment of Mars exploration has been to demonstrate that surface and subsurface sedimentary environments were both habitable and capable of preserving any biological record. ▪ Mars has an ancient sedimentary rock record with many similarities to but also many differences from Earth's sedimentary rock record. ▪ Mars’ ancient sedimentary cycle shows a general evolution toward more desiccated and oxidized surficial conditions. ▪ Climatic regimes of early Mars were relatively clement but with regional variations leading to different sedimentary mineral assemblages. ▪ Surface and subsurface sedimentary environments on early Mars were habitable and capable of preserving any biological record that may have existed.

Published
2018

40. Oxidation of manganese in an ancient aquifer, Kimberley formation, Gale crater, Mars

Author

John P. Grotzinger, David T. Vaniman, Javier Martin-Torres, Fred Calef, Jeffrey R. Johnson, Kenneth S. Edgett, Cécile Fabre, Stéphane Le Mouélic, Jérémie Lasue, Susanne Schröder, Raymond E. Arvidson, Violaine Sautter, Ann Ollila, John L. Campbell, Jens Frydenvang, Jeff A. Berger, Nicolas Mangold, Allan H. Treiman, Craig Hardgrove, María Paz Zorzano, James F. Bell, Douglas W. Ming, Scott VanBommel, Agnes Cousin, Horton E. Newsom, Woodward W. Fischer, Nathan T. Bridges, Marie J. McBride, Olivier Forni, Michael C. Malin, Roger C. Wiens, Samuel M. Clegg, Richard V. Morris, Martin R. Fisk, Sylvestre Maurice, Scott M. McLennan, Ralf Gellert, Nina Lanza, Benton C. Clark, Diana L. Blaney, Melissa S. Rice, Lucy M. Thompson, Joel A. Hurowitz, and Keian R. Hardy

Subjects
010504 meteorology & atmospheric sciences, Evaporite, Mineralogy, chemistry.chemical_element, Manganese, Mars Exploration Program, 01 natural sciences, Atmosphere, Geophysics, Planetary science, Deposition (aerosol physics), chemistry, 13. Climate action, 0103 physical sciences, General Earth and Planetary Sciences, Trace metal, 010303 astronomy & astrophysics, Earth (classical element), Geology, 0105 earth and related environmental sciences
Abstract

The Curiosity rover observed high Mn abundances (>25 wt % MnO) in fracture-filling materials that crosscut sandstones in the Kimberley region of Gale crater, Mars. The correlation between Mn and trace metal abundances plus the lack of correlation between Mn and elements such as S, Cl, and C, reveals that these deposits are Mn oxides rather than evaporites or other salts. On Earth, environments that concentrate Mn and deposit Mn minerals require water and highly oxidizing conditions; hence, these findings suggest that similar processes occurred on Mars. Based on the strong association between Mn-oxide deposition and evolving atmospheric dioxygen levels on Earth, the presence of these Mn phases on Mars suggests that there was more abundant molecular oxygen within the atmosphere and some groundwaters of ancient Mars than in the present day.

Published
2016

41. The association of hydrogen with sulfur on Mars across latitudes, longitudes, and compositional extremes

Author

William V. Boynton, Olivier Gasnault, Scott M. McLennan, Steven W. Squyres, Suniti Karunatillake, Lujendra Ojha, N. E. Button, James J. Wray, A. Deanne Rogers, and J. R. Skok

Subjects
ComputerSystemsOrganization_COMPUTERSYSTEMIMPLEMENTATION, 010504 meteorology & atmospheric sciences, Hydrogen, Earth science, chemistry.chemical_element, ComputerApplications_COMPUTERSINOTHERSYSTEMS, Mars Exploration Program, 010502 geochemistry & geophysics, 01 natural sciences, Jet propulsion, Sulfur, Astrobiology, Latitude, Geophysics, chemistry, Space and Planetary Science, Geochemistry and Petrology, ComputingMilieux_COMPUTERSANDEDUCATION, Earth and Planetary Sciences (miscellaneous), Geology, ComputingMethodologies_COMPUTERGRAPHICS, 0105 earth and related environmental sciences
Abstract

NASA/Jet Propulsion Lab; NASA Mars Data Analysis Program [NNX07AN96G, NNX10AQ23G]; MDAP grants [NNX12AG89G, NNX13AI98G]; LSU's College of Science and Geology and Geophysics

Published
2016

42. High concentrations of manganese and sulfur in deposits on Murray Ridge, Endeavour Crater, Mars

Author

Margaret A.G. Hinkle, James F. Bell, Edward A. Guinness, Steven W. Squyres, Kenneth E. Herkenhoff, William H. Farrand, Raymond E. Arvidson, Nathan Stein, Valerie Fox, Richard V. Morris, Scott VanBommel, Ralf Gellert, Paulo de Souza, Benton C. Clark, David W. Mittlefehldt, Jeffrey R. Johnson, Wendy M. Calvin, Andrew H. Knoll, John P. Grotzinger, Scott M. McLennan, B. L. Jolliff, Matthew P. Golombek, and Jeffrey G. Catalano

Subjects
Basalt, 010504 meteorology & atmospheric sciences, Fracture (mineralogy), Geochemistry, Noachian, Mineralogy, Fracture zone, Mars Exploration Program, 010502 geochemistry & geophysics, 01 natural sciences, Geophysics, Impact crater, Geochemistry and Petrology, Breccia, Sulfate minerals, Geology, 0105 earth and related environmental sciences
Abstract

Mars Reconnaissance Orbiter HiRISE images and Opportunity rover observations of the ~22 km wide Noachian age Endeavour Crater on Mars show that the rim and surrounding terrains were densely fractured during the impact crater-forming event. Fractures have also propagated upward into the overlying Burns formation sandstones. Opportunity’s observations show that the western crater rim segment, called Murray Ridge, is composed of impact breccias with basaltic compositions, as well as occasional fracture-filling calcium sulfate veins. Cook Haven, a gentle depression on Murray Ridge, and the site where Opportunity spent its sixth winter, exposes highly fractured, recessive outcrops that have relatively high concentrations of S and Cl, consistent with modest aqueous alteration. Opportunity’s rover wheels serendipitously excavated and overturned several small rocks from a Cook Haven fracture zone. Extensive measurement campaigns were conducted on two of them: Pinnacle Island and Stuart Island. These rocks have the highest concentrations of Mn and S measured to date by Opportunity and occur as a relatively bright sulfate-rich coating on basaltic rock, capped by a thin deposit of one or more dark Mn oxide phases intermixed with sulfate minerals. We infer from these unique Pinnacle Island and Stuart Island rock measurements that subsurface precipitation of sulfate-dominated coatings was followed by an interval of partial dissolution and reaction with one or more strong oxidants (e.g., O_2) to produce the Mn oxide mineral(s) intermixed with sulfate-rich salt coatings. In contrast to arid regions on Earth, where Mn oxides are widely incorporated into coatings on surface rocks, our results demonstrate that on Mars the most likely place to deposit and preserve Mn oxides was in fracture zones where migrating fluids intersected surface oxidants, forming precipitates shielded from subsequent physical erosion.

Published
2016

43. Smectite deposits in Marathon Valley, Endeavour Crater, Mars, identified using CRISM hyperspectral reflectance data

Author

K. E. Powell, Scott L. Murchie, Scott M. McLennan, Valerie Fox, Jeffrey G. Catalano, Raymond E. Arvidson, and Edward A. Guinness

Subjects
Spectral signature, 010504 meteorology & atmospheric sciences, Mineralogy, Mars Exploration Program, Albedo, 010502 geochemistry & geophysics, 01 natural sciences, CRISM, Hyperspectral reflectance, Geophysics, Impact crater, Breccia, General Earth and Planetary Sciences, Clay minerals, Geomorphology, Geology, 0105 earth and related environmental sciences
Abstract

The ~100 m wide Marathon Valley crosscuts the Cape Tribulation rim segment of the 22 km diameter, Noachian-age Endeavour impact crater on Mars. Single-scattering albedo spectra retrieved from three Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) Full-Resolution Targeted (FRT, regularized to 18 m/pixel) and two Along Track Oversampled (ATO, regularized to 12 m/pixel) observations indicate the presence of Fe3+-Mg2+ smectite exposures located in Marathon Valley with combination vibration metal-OH absorption strength comparable to smectite spectral signatures in Mawrth Vallis. The Opportunity rover was directed to the exposures and documented the presence of Shoemaker formation impact breccias that have been isochemically altered, likely by fracture-controlled aqueous fluids.

Published
2016

44. The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam on boardCuriosity

Author

Horton E. Newsom, Jérémie Lasue, K. M. Stack, Diana L. Blaney, Dawn Y. Sumner, Martin R. Fisk, William Rapin, S. Le Mouélic, Valerie Payre, Gilles Dromart, Scott M. McLennan, P. Y. Meslin, Allan H. Treiman, Olivier Gasnault, Ryan B. Anderson, Nina Lanza, Cécile Fabre, N. Mangold, Olivier Forni, Melissa S. Rice, S. Maurice, John P. Grotzinger, Susanne Schröder, Sanjeev Gupta, Violaine Sautter, Agnès Cousin, Roger C. Wiens, Samuel M. Clegg, L. Le Deit, and Marion Nachon

Subjects
Basalt, Martian, Olivine, 010504 meteorology & atmospheric sciences, Outcrop, Geochemistry, Crust, Mars Exploration Program, engineering.material, 01 natural sciences, On board, Geophysics, Space and Planetary Science, Geochemistry and Petrology, 0103 physical sciences, Earth and Planetary Sciences (miscellaneous), engineering, Sedimentary rock, 010303 astronomy & astrophysics, Geology, 0105 earth and related environmental sciences
Abstract

Key Points: • Mean K2O abundance in sedimentary rocks >5 times higher than that of the average Martian crust • Presence of alkali feldspars and K-phyllosilicates in basaltic sedimentary rocks along the traverse • The K-bearing minerals likely have a detrital origin

Published
2016

45. Dysprosium

Author

Scott M. McLennan

Published
2018

46. Holmium

Author

Scott M. McLennan

Published
2018

47. Gadolinium

Author

Scott M. McLennan

Published
2018

48. Thulium

Author

Scott M. McLennan

Published
2018

49. Erbium

Author

Scott M. McLennan

Published
2018

50. Lutetium

Author

Scott M. McLennan

Published
2018

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