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Silicic magmatism is a feature of all continental LIP events, and where volumetrically significant, occurs as high‐frequency (~1,000–10,000 yr recurrence intervals), large‐magnitude (>M8) explosive supereruptions producing vast ignimbrite sheets. Silicic supereruptions inherently have the eruptive mechanism to deliver aerosols and ash to the stratosphere for global dispersal, and thus overcome eruptive barriers that exist for flood basalts built up by long‐lived, low effusion and low vigor fountains that lack height and persistent stratospheric penetration. The historical record demonstrates the climate forcing capabilities of silicic supereruptions, which during LIP events, were likely associated with large CO2, SO2, halogen, and Hg emissions, and through tephra deposition, could cause iron fertilization in the world's oceans, thereby kick‐starting phytoplanktonic biological pumps to significantly draw down atmospheric CO2. What may be important, therefore, for LIP events to cause the most environmental impact and trigger a mass extinction, is the combined effect of closely spaced basaltic and silicic, or effusive and explosive, eruptions that work in tandem to overload the troposphere and stratosphere with volcanic aerosols producing rapid decadal‐scale, extreme fluctuations in pH driven by acid rain, S‐, or iron fertilization‐driven temperature chills, and toxic UV radiation bursts. These effects could be repeated within as little as a few hundred years of each other particularly during hyperactive LIP pulses.

Determining the oxidation state of Fe through parameterization of X-ray absorption near-edge structure (XANES) spectral features is highly dependent on accurate and repeatable energy calibration between spectra. Small errors in energy calibration can lead to vastly different interpretations. While simultaneous measurement of a reference foil is often undertaken on X-ray spectroscopy beamlines, other beamlines measure XANES spectra without a reference foil and therefore lack a method for correcting energy drift. Here a method is proposed that combines two measures of Fe oxidation state taken from different parts of the spectrum to iteratively correct for an unknown energy offset between spectra, showing successful iterative self-calibration not only during individual beam time but also across different beamlines.

Coral reef ecosystems are under increasing pressure from local and regional stressors and a changing climate. Current management focuses on reducing stressors to allow for natural recovery, but in many areas where coral reefs are damaged, natural recovery can be restricted, delayed or interrupted because of unstable, unconsolidated coral fragments, or rubble. Rubble fields are a natural component of coral reefs, but repeated or high-magnitude disturbances can prevent natural cementation and consolidation processes, so that coral recruits fail to survive. A suite of interventions have been used to target this issue globally, such as using mesh to stabilise rubble, removing the rubble to reveal hard substrate and deploying rocks or other hard substrates over the rubble to facilitate recruit survival. Small, modular structures can be used at multiple scales, with or without attached coral fragments, to create structural complexity and settlement surfaces. However, these can introduce foreign materials to the reef, and a limited understanding of natural recovery processes exists for the potential of this type of active intervention to successfully restore local coral reef structure. This review synthesises available knowledge about the ecological role of coral rubble, natural coral recolonisation and recovery rates and the potential benefits and risks associated with active interventions in this rapidly evolving field. Fundamental knowledge gaps include baseline levels of rubble, the structural complexity of reef habitats in space and time, natural rubble consolidation processes and the risks associated with each intervention method. Any restoration intervention needs to be underpinned by risk assessment, and the decision to repair rubble fields must arise from an understanding of when and where unconsolidated substrate and lack of structure impair natural reef recovery and ecological function. Monitoring is necessary to ascertain the success or failure of the intervention and impacts of potential risks, but there is a strong need to specify desired outcomes, the spatial and temporal context and indicators to be measured. With a focus on the Great Barrier Reef, we synthesise the techniques, successes and failures associated with rubble stabilisation and the use of small structures, review monitoring methods and indicators, and provide recommendations to ensure that we learn from past projects.

The generation of continental crust, its bulk composition and temporal evolution provide important records of plate tectonics and associated magma-generating processes. However, the long-term integrated effects of repeated magmatic events on crustal growth, composition and differentiation and, therefore, on crustal evolution are rarely considered. Here, we examine long-term (∼350 Myr) temporal compositional trends of granitic magmatism within a limited (∼200 km × 100 km) area in the Northern New England Orogen of Queensland, Australia to avoid lateral crustal variations in order to understand how temporal–compositional variations of silicic igneous rocks record crustal evolution. Long-term temporal compositional variations are tracked using whole-rock chemistry, zircon chronochemistry and zircon Hf isotopic compositions. We particularly focus on whole-rock U, Th and K abundances and calculated heat-production values as proxies for crustal evolution, and tracking crustal sources involved in granitic magmatism. We identified two major compositional groupings within the study area that were repeatedly produced over time: compositional Group 1 comprises voluminous I-type igneous rocks emplaced during the Permo-Carboniferous and Early Cretaceous; Group 2 represents mainly lower volume A-type igneous rocks of Triassic, Middle Cretaceous and Tertiary age. Importantly, these compositional groupings alternate over the 350 Myr history of granitic magmatism within the study area. Heat-production values over time exhibit a zigzag pattern and mirror zircon Hf isotopic signatures where rocks with elevated heat-production values exhibit unradiogenic (crustal) Hf isotopic compositions. We identify the composition of crustal sources, level of the crust undergoing partial melting, scale of magmatism and source crustal volume as important factors in understanding the compositional diversity of silicic igneous rocks. We interpret the two chemical groupings to reflect the following magma-generating conditions: Group 1 igneous rocks record large-scale magmatic systems triggered by extensive crustal melting of multiple lower to middle crustal sources, which produce more compositionally and isotopically uniform magma compositions that approach bulk crustal compositions. In contrast, Group 2 igneous rocks reflect smaller-scale magmatic systems generated from smaller-scale partial melting events of the middle to upper crust that produced A-type magmas. Over the long term, the successive large-scale magmatic events (recorded by Group 1 igneous rocks) through their concomitant basaltic underplating make the Hf composition of the lower crust more radiogenic, and tend to homogenize the isotopic composition of the continental crust. We consider three important coupled controls: (1) promotion of extensive crustal melting by large-scale magmatic systems, potentially blending multiple crustal sources that can also include a significant juvenile source contribution; (2) melt depletion, whereby older, and potentially more unradiogenic crustal materials become more refractory; (3) ‘crustal jacking’, where mantle-derived magmas are added as underplate to the crust (i.e. basification) and can shift older crustal materials to more shallow levels (potentially in concert with erosion and exhumation) and away from zones of crustal melting. Our findings highlight the importance of integrating the geological and intrusive history with whole-rock geochemical data and isotopic information, and have direct implications for continental regions that exhibit protracted igneous histories and where isotopic compositions may trend towards more juvenile compositions such as circum-Pacific or retreating accretionary orogens.

The 2012 Havre eruption evacuated a crystal-poor rhyolite (∼3–7% crystals) producing a volumetrically dominant (∼1.4 km3) pumice raft, as well as seafloor giant pumice (5–8%) and lavas (12–14%) at the vent (∼0.1 km3), both of which have subtly higher phenocryst contents. For crystal-poor rhyolites like the Havre pumice, it can often remain ambiguous as to whether the few phenocrysts present, in this case, plagioclase, orthopyroxene, clinopyroxene, Fe-Ti oxides ± quartz, are: (a) autocrysts crystallizing from the surrounding melt, (b) antecrysts being sourced from mush and the magma plumbing system, or (c) xenocrysts derived from source materials or chamber walls, or (d) possibly a combination of all of the above. In crystal-poor magmas, the few crystals present are strongly relied upon to constrain pre-eruptive conditions such as magmatic temperatures, pressures, water content and fO2. A detailed textural and compositional analysis combined with a range of equilibrium tests and rhyolite-MELTS modeling provide the basis for distinguishing autocrystic vs inherited crystal populations in the Havre eruption. An autocrystic mineral assemblage of andesine plagioclase, enstatite and Fe-Ti oxides constrains the pre-eruptive conditions of the Havre rhyolite magma: magmatic temperatures of 890 ± 27°C, crystallization pressures at 2–4 kbars, oxygen fugacity of NNO + 0.4 and water concentrations (5.6 ± 1.1 wt.%). Inherited phases not in equilibrium with the host melt composition are clinopyroxene, An-rich plagioclase (> An53) and quartz. Rhyolite-MELTs modeling indicates the clinopyroxene and quartz have most likely been sourced from cooler, silicic mush zones in the Havre magmatic system. This study demonstrates that even in crystal-poor rhyolites it cannot be assumed that all crystals are autocrystic and can be used to constrain pre-eruptive magmatic conditions.

The Drummond Basin of central Queensland preserves a large-volume succession of little studied, predominantly fluviatile, coarse-grained sedimentary rocks of mid-Mississippian age. The stratigraphy of the basin has been subdivided into three sedimentary cycles. The Cycle 1/Cycle 2 boundary records a distinct, but poorly understood change in provenance from a volcanic-dominated succession related to initial basin rifting (Cycle 1) to a quartz-rich, craton-derived succession (Cycle 2). Cycle 3 has been thought to mark a resumption of intrabasinal volcanism and related sedimentation. The purpose of this study was to enhance the understanding of the basin-wide siliciclastic sedimentation of Cycles 2 and 3, and causes for the changes in sediment provenance. This objective was achieved by constraining large-scale spatial and temporal depositional trends and investigating sediment transport pathways into and through the basin. Petrographic, QFL, paleocurrent and conglomerate clast analyses were undertaken. The observations presented here have several implications relevant to understanding the stratigraphy of the Drummond Basin and regional tectonic events at this time. Cycle 3 is revised here primarily to be a continuation of Cycle 2-style basement-derived sedimentation, rather than recording a resumption of volcanism in the area, as per prevailing models. Quartz-rich sedimentation in the Drummond Basin was, therefore, more long-lived than previously envisaged, and once established, was not significantly disrupted by volcanism. Cycle 2 formation thicknesses appear highly variable across the basin. This is unlikely to be a result of pre-existing rift-related topography as suggested in previous models. The thickness variations are more likely related to sediment bypassing and post-depositional deformation in the area. The distinctive coarse-grained, relatively quartz-rich sedimentation of Cycles 2 and 3 is unusual in its volume and extent. The sediment was transported into the basin from its southern/southwestern margin, implying long-distance transport and extrabasinal sediment supply. While the specific source terrain(s) remain unknown, one plausible tectonic driver was far-field influence of the intraplate Alice Springs Orogeny.

The Devonian subsurface Adavale Basin occupies a central position in the Paleozoic central Thomson Orogen of eastern Australia and records its tectonic setting during this time interval. Here, we have focussed on the basal volcanics of the Gumbardo Formation to clarify the tectonic setting of the basin. The approach has been to undertake stratigraphic logging, LA-ICP-MS U–Pb zircon geochronology and whole-rock geochemical analysis. The data indicate that basin initiation was rapid occurring at ca 401 Ma. The volcanic rocks are dominated by K-feldspar phyric rhyodacitic ignimbrites. The whole-rock geochemical data indicate little evidence for extensive fractional crystallisation, with the volcanic suite resembling the composition of the upper continental crust and exhibiting transitional I- to A-type tectonomagmatic affinities. One new U–Pb zircon age revealed an Early Ordovician emplacement age for a volcanic rock previously interpreted to be part of the Early Devonian Gumbardo Formation, and older basement age is consistent with seismic interpretations of uplifted basement in this region of the western Adavale Basin. Five ignimbrites dated from different stratigraphic levels within the formation yield similar emplacement ages with a pooled weighted age of 398.2 ± 1.9 Ma (mean square weighted deviation = 0.94, n = 93). Significant zircon inheritance in the volcanic rocks records reworking of Ordovician and Silurian silicic igneous basement from the Thomson Orogen and provides insight into the crustal make-up of the Thomson Orogen. Collectively, the new data presented here suggest the Adavale Basin is a cover-type basin that developed on a stabilised Thomson Orogen after the major Bindian deformation event in the late Silurian.

Emerging over the past decade has been a new view on the genesis of, and links between, the Sierra Madre Occidental silicic large igneous province, the Comondu Group of Baja California and the Gulf of California rift. Underpinning this has been a wealth of new data from both margins of the Gulf of California including offshore sampling, and marine geophysical data, in part seeded by the NSF Margins program where the Gulf of California was a principal focus site. Previously, the Sierra Madre Occidental silicic large igneous province and Comondu Group had been widely regarded as supra - subduction volcanism with the Comondu Group in particular, defining the location of the early to mid - Miocene supra - subduction zone volcanic arc, and therefore acting as both a spatial and temporal barrier to when rifting of the Gulf of California could begin. More broadly, this continental magmatism occurring during the last phase of subduction of the Farallon Plate between the Late Eocene and the Middle Miocene, shows little to n o petrogenetic connection to the active plate boundary and is more strongly linked to the progressive thinning of the upper plate and establishment of a shallow asthenospheric mantle beneath western Mexico. A database developed for this study of 4255 ages and chemical analyses for igneous rocks from 100 to 5 Ma from across western Mexico, reveals a significant transition period between 50 and 40 Ma where relatively low - volume magmatism was established across a broad area up to 800 km wide and extended up to 1000 km in board of the paleotrench. Since 40 Ma, magma fluxes greatly increased across this broad belt and compositions were initially silicic - dominated but quickly became bimodal by ~30 Ma. The space - time pattern of crustal extension is constrained in 39 areas, for which the approximate age of extension can be established on the basis of geologic relations or thermochronology. The onset of continental extension is constrained to the Eocene when extensional basins developed across the Central Plateau and the easternmost part of the Sierra Madre Occidental, approximately 500 km in board of the paleo - plate boundary. By the end of Oligocene, crustal extension had affected a wide region (250 km width) from the eastern Sierra Madre Occidental to the site of the future Gulf of California (wide rift mode). Concomitant with this extension was: 1) a widespread invasion of the mid to upper crust by mafic magmas with lithospheric signatures (the southern cordillera orogenic basaltic andesite suite or SCORBA), and lesser erupted volumes of uncontaminated asthenosphere - derived within - plate lavas, and; 2) crustal melting producing voluminous pulses of silicic ignimbrite eruptions (the SMO SLIP) with a ferroan (dry) and transitional within - plate signature. At ~19 Ma, ortho gonal extension became focused between the western side of the SMO and eastern Baja California in a ~80 - 100 km wide belt.

The origin of elevated geothermal gradients in the subsurface Thomson Orogen and the nature of the crustal basement beneath it, whether oceanic or continental, remain enigmatic. Previous studies have demonstrated that a higher crustal radiogenic input is required to explain these anomalous thermal gradients. In this study, we have investigated the nature and age of this crustal input by undertaking geochemical, geochronological and Hf and O isotope analyses of buried granitic rocks as well as evaluating the heat-producing potential of metasedimentary rocks. The mineralogy, composition and Neoproterozoic/Cambrian to Devonian age of the low to moderate heat-producing I- and S-type granitic rocks strongly contrast with the Carboniferous A-type high-heat-producing granites of the Big Lake Suite, which have been suggested to be an important contributor to the elevated geothermal gradients, near the southwest corner of the Thomson Orogen. These differences suggest the Big Lake Suite rocks do not extend into the Queensland part of the temperature anomaly. Heat production of the metasedimentary rocks is also low to moderate. Based on Hf isotope compositions of zircons characterised by mantle-like oxygen signature ( ϵ Hf(t) = –12 to +2), we propose the temperature anomaly results from the occurrence of Mesoproterozoic and/or Paleoproterozoic high-heat-producing rocks beneath the Thomson Orogen. Precambrian crust, therefore, lies well east of the Tasman line. The results do not support a Neoproterozoic to Cambrian oceanic crust, as previously suggested, but instead point to a continental substrate for the Thomson Orogen. Hf isotopes indicate an overall trend towards more isotopically juvenile compositions with a progressive reduction in the contribution of older crustal sources to granitic magmas towards the present time. Different Hf isotopic signatures for the Lachlan (ϵHf(t) = –13 to +15), Thomson (ϵHf(t) = –14 to +5) and Delamerian (ϵHf(t) = –7 to +4) orogens highlight lateral variations in the age structures of crustal basement beneath these orogens.

Zircon- and bulk-rock Zr-based thermometric parameters have become fundamental to petrogenetic models of magmatism, from which broader geochronological and tectonic implications are being made. In particular, petrogenetic models have become increasingly reliant on Ti concentration in zircon geothermometry (T ZircTi ) and zircon saturation temperature (T Zircsat ). A feature of many of these studies is an implicit assumption that all zircons present in the host igneous rock are autocrystic, that is, crystallised from the surrounding melt. However, it has long been recognised that zircons present in an igneous rock can be inherited either from the surrounding country rock or source region (xenocrysts), or from earlier phases of magmatism or the magmatic plumbing system (antecrysts). Distinguishing these different origins for zircon crystals or domains within crystals is not straightforward. Here, we first review the utility and reliability of zircon-based thermometers for petrogenetic studies and show that T Zircsat is a theoretical temperature and cannot be used to constrain magmatic or partial melting temperatures. It is a dynamic variable that changes during magma crystallisation, and essentially increases as fractional crystallisation proceeds, whereas true magmatic temperatures (T Magma ) decrease. Generally, in Temperature-SiO2 space, the cross-over point of these two temperatures is magmatic system dependent, and also affected by the type of calibration used for the T Zircsat calculations. Consequently, each magmatic system needs to be evaluated independently to assess the validity and usefulness of T Zircsat . A fundamental conclusion of T Zircsat and T Magma relationships assessed here is that new zircon generally only crystallises in silicic (granitic/rhyolitic) melt compositions, and thus autocrystic zircons should not be assumed to be present in igneous rocks with bulk compositions Zircsat and T Magma ) to estimate whether the magma was zircon-saturated or undersaturated. To test this new protocol, we use as examples, several Phanerozoic granitic rocks intersected by drilling in Queensland where contextual information is limited, and show how antecrystic and xenocrystic zircons and monazites can be distinguished. In contrast, where zircons are metamict (for example, high U and Th-rich zircons), much of the ability to discriminate is impacted because such zircons have suffered Pb loss and have modified compositions (e.g., higher T ZircTi ). We recommend an integrated approach incorporating whole-rock chemistry, independent geothermometric constraints, zircon composition, textures and ages obtained by routine cathodoluminescence and LA-ICP-MS or ion microprobe analysis to provide increased confidence for the discrimination of inherited zircons from autocrystic zircons and determination of the emplacement age.

U–Pb dating of zircons from thin middle Permian tuffs in the Canning Basin of Western Australia by chemical abrasion-isotope dilution thermal ionisation mass spectrometry reveals a conflict with the established spore-pollen zonation. Normally, the first appearance datum of Dulhuntyispora granulata across the continent lies stratigraphically above assemblages assigned to the Microbaculispora villosa Zone. However, the youngest tuffs within non-marine facies from the M. villosa Zone in Pittston SD-1, drilled in the southwest of the Canning Basin, yielded an age of 267.04 ± 0.14 Ma, which is 1.7 million years younger than tuffs associated with the D. granulata Zone in marginal-marine facies from core holes 350–400 km to the northeast. The apparent conflict in ages is possibly due to the non-marine depositional environment having wielded a strong local influence on the palynoflora along the edge of this basin. Although the present information indicates an age 2.5 million years younger than the 266.6 Ma age previously suggested for the top of the M. villosa Zone, revisions to the ages of Roadian–Wordian spore-pollen zones are not considered justifiable without further supporting evidence. Furthermore, considerable care is needed when comparing palynological assemblages from significantly differing facies. Two basaltic sills (43.5 m and 20 m thick) immediately below the tuffaceous beds in Pittston SD-1 are coincidental, as Ar–Ar dating indicates a Late Triassic age for the intrusions.

A correction is made to the paper by Jones et al. (2020). [J. Synchrotron Rad. (2020), 27, 207–211].

Large igneous provinces (LIPs) form in both oceanic and continental settings by the emplacement and eruption of voluminous magmas ranging from basalt to rhyolite in composition. Continental flood basalt provinces are the best studied LIPs and consist of crustal intrusive systems, extensive flood lavas and ignimbrites, and mafic volcaniclastic deposits in varying proportions. Intrusive rocks are inferred to represent the solidified remnants of a plumbing system that fed eruptions at the surface, as well as themselves representing substantial accumulations of magma in the subsurface. The vast majority of intrusive rock within the upper crust is in widespread sills, the emplacement of which may structurally isolate and dismember upper crustal strata from underlying basement, as well as spawning dyke assemblages of complex geometry. Interaction of dykes and shoaling sills with near-surface aquifers is implicated in development of mafic volcaniclastic deposits which, in better-studied provinces, comprise large vent complexes and substantial primary volcaniclastic deposits. Flood lavas generally postdate and overlie mafic volcaniclastic deposits, and are emplaced as pahoehoe flows at a grand scale (up to 104 km2) from eruptions lasting years to decades. As with modern Hawaiian analogues, pahoehoe flood lavas have erupted from fissure vents that sometimes show evidence of high lava fountains at times during eruption. In contrast to basaltic provinces, in which volcaniclastic deposits are significant but not dominant, silicic LIPs are dominated by deposits of explosive volcanism, although they also contain variably significant contributions from widespread lavas. Few vent sites have been identified for silicic eruptive units in LIPs, but it has been recognized that some ignimbrites have also been erupted from fissure-like vents. Although silicic LIPs are an important, albeit less common, expression of LIP events along continental margins, the large volumes of easily erodible primary volcaniclastic deposits result in these provinces also having a significant sedimentary signature in the geologic record. The inter-relationships between flood basalt lavas and volcaniclastic deposits during LIP formation can provide important constraints on the relative timings between LIP magmatism, extension, kilometre-scale uplift and palaeoenvironmental changes. Copyright IAVCEI 2009

The theory of island biogeography predicts that area and age explain species richness patterns (or alpha diversity) in insular habitats. Using a unique natural phenomenon, pumice rafting, we measured the influence of area, age, and oceanic climate on patterns of species richness. Pumice rafts are formed simultaneously when submarine volcanoes erupt, the pumice clasts breakup irregularly, forming irregularly shaped pumice stones which while floating through the ocean are colonized by marine biota. We analyze two eruption events and more than 5,000 pumice clasts collected from 29 sites and three climatic zones. Overall, the older and larger pumice clasts held more species. Pumice clasts arriving in tropical and subtropical climates showed this same trend, where in temperate locations species richness (alpha diversity) increased with area but decreased with age. Beta diversity analysis of the communities forming on pumice clasts that arrived in different climatic zones showed that tropical and subtropical clasts transported similar communities, while species composition on temperate clasts differed significantly from both tropical and subtropical arrivals. Using these thousands of insular habitats, we find strong evidence that area and age but also climatic conditions predict the fundamental dynamics of species richness colonizing pumice clasts.

Granitic magmas extracted from crustal sources can form over a wide variety of P, T and aH 2O conditions. Both fluid-present and effectively fluid-absent conditions can yield granitic magmas, though the majority are formed through high-T, fluid-absent reactions because, in the deep crust, most available H 2O within rock bodies is contained within minerals rather than in free fluids. Fluid-present partial melting generally results in the formation of migmatites (and sometimes diatexites) under upper amphibolite-facies conditions. By definition, aqueous fluid-present melting begins at temperatures very close to the relevant ‘wet’ solidus. Consequently, studying mid-crustal migmatites, and the poorly mobile and mainly small intrusions that may result from such melting, provides no guide to the temperatures and fluid conditions that are involved in the genesis of highly mobile granitic magmas that facilitate crustal differentiation. Although zircon-saturation temperatures are commonly used to infer magma temperatures, and even melting temperatures, they seldom resemble actual magmatic temperatures. Recent notions about the persistence of granite-forming melts at conditions well below the experimentally determined H 2O-saturated (‘wet’) solidi for granites (i.e., generally

The Gulf of California is a young example of crustal stretching and transtensional shearing leading to the birth of a new oceanic basin at a formerly convergent margin. Previous studies focused along the southwestern rifted margin in Baja California indicated rifting was initiated after subduction and related magmatism ceased at ca. 14–12.5 Ma. However, the geologic record on the Mexico mainland (Sinaloa and Nayarit States) indicates crustal stretching in the region began as early as late Oligocene. The timing of cooling and exhumation of pre- and synrift plutonic rocks can provide constraints on the timing and rate of rifting. Here, we present results of a regional study on intrusive rocks in the southern Gulf of California sampled along the conjugate Baja California and Nayarit-Sinaloa rift margins, as well as plutonic rocks now exposed on submerged rifted blocks inside the gulf. Forty-one samples were dated via U/Pb zircon and 40Ar/39Ar mineral ages, providing emplacement age and thermochronological constraints on timing and rate of cooling. We found an extensive suite of early and middle Miocene plutons emplaced at shallow depths within the basement Cretaceous–Paleocene Peninsular Range and Sinaloa-Jalisco Batholiths. Early Miocene granitoids occur in an elongated WNW-ESE belt crossing the entire southern gulf from southern Baja California to Nayarit and Sinaloa. Most have an intermediate composition ( 75 SiO2 wt%) was emplaced 20.1–18.3 Ma, near the end of the early Miocene. Age span and chemical composition of the early Miocene silicic plutons essentially overlap ignimbrites and domes exposed in the southern Sierra Madre Occidental and in southern Baja California, suggesting that eruptive sources for the early Miocene ignimbrite flare-up may also have been located within the southern Gulf of California. Early Miocene plutons cooled below the 40Ar-39Ar biotite closure temperature (350–400 °C) in less than 2.5 m.y., which we interpret as evidence of a regional extensional event leading to the opening of the Gulf of California. A less widely distributed suite of intermediate-composition, middle Miocene granitoids (15–13 Ma) was sampled from the central-western part of the gulf, west of the Pescadero Basin, and these correspond to an episode of scarce volcanism recorded by the middle and upper members of the onshore Comondu Group in Baja California. Our widely spaced sampling of the generally sediment-covered igneous crust suggests that middle Miocene primary volcanic rocks are much less abundant than implied by previous models in which the gulf was the site of a robust Comondu arc. Thermobarometry data also indicate a very shallow depth (

A large subsurface, elevated temperature anomaly is well documented in Central Australia. High heat producing granites (HHPGs) intersected by drilling at Innamincka are often assumed to be the dominant cause of the elevated subsurface temperatures, although their presence in other parts of the temperature anomaly has not been confirmed. Geological controls on the temperature anomaly remain poorly understood. Additionally, methods previously used to predict temperature at 5. km depth in this area are simplistic and possibly do not give an accurate representation of the true distribution and magnitude of the temperature anomaly. Here we re-evaluate the geological controls on geothermal potential in the Queensland part of the temperature anomaly using a stochastic thermal model. The results illustrate that the temperature distribution is most sensitive to the thermal conductivity structure of the top 5. km. Furthermore, the results indicate the presence of silicic crust enriched in heat producing elements between 5 and 40. km.

The Warburton-Cooper basins, central Australia, include a multitude of reactivated fracture-fault networks related to a complex, and poorly understood, tectonic evolution. We investigated authigenic illites from a granitic intrusion and sedimentary rocks associated with prominent structural features (Gidgealpa-Merrimelia-Innamincka Ridge and the Nappamerri Trough). These were analysed by 40Ar-39Ar, 87Rb-87Sr and 147Sm-143Nd geochronology to explore the thermal and tectonic histories of central Australian basins. The combined age data provide evidence for three major periods of fault reactivation throughout the Phanerozoic. While Carboniferous (323.3 ± 9.4 Ma) and Late Triassic ages (201.7 ± 9.3 Ma) derive from basin-wide hydrothermal circulation, Cretaceous ages (~128 to ~86 Ma) reflect episodic fluid flow events restricted to the synclinal Nappamerri Trough. Such events result from regional extensional tectonism derived from the transferral of far-field stresses to mechanically and thermally weakened regions of the Australian continent. Specifically, Cretaceous ages reflect continent-wide transmission of tensional stress from a > 2500 km long rifting event on the Eastern (and southern) Australian margin associated with break-up of Gondwana and opening of the Tasman Sea. By integrating 40Ar-39Ar, 87Rb-87Sr and 147Sm-143Nd dating, this study highlights the use of authigenic illite in temporally constraining the tectonic evolution of intracontinental basins that would otherwise remain unknown. Furthermore, combining Sr- and Ar-isotopic systems enables more accurate dating of authigenesis whilst significantly reducing geochemical pitfalls commonly associated with these radioisotopic dating methods.

Multiple phases of extension and contraction in orogens can produce relatively complicated thermal histories for sedimentary basins as recorded by thermochronological datasets. This makes it difficult to determine which tectonic events had the most impact on the thermal state, and were drivers of exhumation, of the upper crust. In this study, apatite and zircon (U[sbnd]Th)/He data obtained from five drill core samples (Campaspe DDH-1) from the Drummond Basin are used to construct a continuous, post-depositional thermal history of this Late Devonian-Early Carboniferous rift basin. Detrital zircon U/Pb ages indicate a maximum depositional age of ~340 Ma for the sampled formations, however, most apatite (U[sbnd]Th)/He (AHe) analyses yielded apparent ages of 30–100 Ma (n = 35) and zircon (U[sbnd]Th)/He (ZHe) analyses gave ages of 200–340 Ma (n = 67). Zircon (U[sbnd]Th)/(He[sbnd]Pb) double dating yielded no correlation between U/Pb and ZHe ages, with all the ZHe ages younger than depositional age. These data indicate disturbance of the ZHe and AHe systems after deposition. Inverse thermal history modeling using the QTQt and HeFTy codes suggests the samples experienced two post-depositional heating-cooling cycles: (1) rapid heating to ~150–195 °C at ~300 Ma was followed by rapid cooling to near-surface temperatures of ~50 +50/−30 °C between 270 and 240 Ma, and (2) gradual heating until the Early Cretaceous, when temperatures increased to ~105 +15/−10 °C followed by rapid cooling beginning ~90 Ma. We relate the ~300 Ma heating to the Kennedy-Connors-Auburn silicic large igneous province, revealing that major regional igneous events can significantly perturb a basin thermal history. In contrast, the slow temperature increase between ~270 and 100 Ma is related to progressive burial by overlying sediments of the Galilee and Great Australian basins. Finally, rapid cooling beginning ~90 Ma was synchronous with rift margin exhumation.

The composition of the lithosphere can be fundamentally altered by long-lived subduction processes such that subduction-modified lithosphere can survive for 100's Myrs. Incorrect petrotectonic interpretations result when spatial-temporal-compositional trends of, and source contributions to, magmatism are not properly considered. Western Mexico has had protracted Cenozoic magmatism developed mostly in-board of active oceanic plate subduction beneath western North America. A broad range of igneous compositions from basalt to high-silica rhyolite were erupted with intermediate to silicic compositions in particular, showing calc-alkaline and other typical subduction-related geochemical signatures. A major Oligocene rhyolitic ignimbrite “flare-up” (>300,000 km3) switched to a bimodal volcanic phase in the Early Miocene (~100,000 km3), associated with distributed extension and opening of numerous grabens. Extension became more focussed ~18 Ma resulting in localised volcanic activity along the future site of the Gulf of California. This localised volcanism (known as the Comondu “arc”) was dominantly effusive and andesite-dacite in composition. Past tectonic interpretations of Comondu-age volcanism may have been incorrect as these regional temporal-compositional changes are alternatively interpreted as a result of increased mixing of mantle-derived basaltic and crust-derived rhyolitic magmas in an active rift environment rather than fluid flux melting of the mantle wedge above the subducting Guadalupe Plate.

Large Igneous Provinces are exceptional intraplate igneous events throughout Earth’s history. Their significance and potential global impact is related to the total volume of magma intruded and released during these geologically brief events (peak eruptions are often within 1-5 Myrs duration) where millions to tens of millions of cubic kilometers of magma are produced. In some cases, at least 1% of the Earth’s surface has been directly covered in volcanic rock, being equivalent to the size of small continents with comparable crustal thicknesses. Large Igneous Provinces are thus important, albeit episodic episodes of new crust addition. However, most magmatism is basaltic so that contributions to crustal growth will not always be picked up in zircon geochronology studies that better trace major episodes of extension-related silicic magmatism and the silicic Large Igneous Provinces. Much headway has been made on our understanding of these anomalous igneous events over the last 25 years, driving many new ideas and models. This includes their: 1) global spatial and temporal distribution, with a long-term average of one event approximately every 20 Myrs, but a clear clustering of events at times of supercontinent break-up – Large Igneous Provinces are thus an integral part of the Wilson cycle and are becoming an increasingly important tool in reconnecting dispersed continental fragments; 2) compositional diversity that in part reflects their crustal setting of ocean basins, and continental interiors and margins where in the latter setting, LIP magmatism can be silicicdominant; 3) mineral and energy resources with major PGE and precious metal resources being hosted in these provinces, as well as magmatism impacting on the hydrocarbon potential of volcanic basins and rifted margins through enhancing source rock maturation, providing fluid migration pathways, and trap formation; 4) biospheric, hydrospheric and atmospheric impacts, with Large Igneous Provinces now widely regarded as a key trigger mechanism for mass extinctions, although the exact kill mechanism(s) are still being resolved; 5) role in mantle geodynamics and thermal evolution of the Earth, by potentially recording the transport of material from the lower mantle or core-mantle boundary to the Earth's surface and being a fundamental component in whole mantle convection models; and 6) recognition on the inner planets where the lack of plate tectonics and erosional processes and planetary antiquity means that the very earliest record of LIP events during planetary evolution may be better preserved than on Earth.

We present a new interpretation on the genesis of, and links between, the Sierra Madre Occidental silicic large igneous province (SMO), the Comondu Group of Baja California (CG) and the Gulf of California (GoC) rift. Previously, the SMO and CG had been regarded as suprasubduction arcs, predating the opening of the GoC. In contrast, we conclude that this continental magmatism, occurring during the last phase of subduction of the Farallon Plate between ~40 and 13 Ma, shows little to no petrogenetic connection to the active plate boundary and is more strongly linked to the progressive thinning of the upper plate and the establishment of a shallow asthenospheric mantle beneath western Mexico induced by the piecemeal removal of the subducted slab. A database of 4255 ages and chemical analyses for igneous rocks from 100 to 5 Ma reveals a significant transition period between 50 and 40 Ma where relatively low volume magmatism spreads in an 800 km wide belt, up to 1000 km from the paleotrench. Since 40 Ma, magma fluxes greatly increased and compositions were initially silicic dominated but became bimodal by ~30 Ma. Since the Eocene extensional basins developed in the easternmost part of the SMO, ~500 km in board of the paleoplate boundary. By the end of Oligocene, crustal extension had affected a 250 km wide region from the eastern SMO to the the future GoC. Concomitant with this extension was: 1) a widespread invasion of the crust by mafic magmas associated with melting of the lithospheric mantle (SCORBA suite), and more limited erupted volumes of asthenosphere-derived within-plate lavas, and 2) crustal melting producing voluminous pulses of silicic ignimbrites (the SMO SLIP) with a ferroan (dry) and a transitional within-plate signature. At ~19 Ma, orthogonal extension focused between the western side of the SMO and eastern Baja California in a narrow ~80-100 km wide belt. Volcanism became more effusive and intermediate in composition (the CG), and concentrated within rapidly extending, tectonic depressions along the future site of the GoC. By ~12 Ma, the crust had thinned to half of its original thickness along the axis of the Gulf. Since Late Miocene right-lateral transtensional deformation associated with the dragging of Baja California by the Pacific Plate was then able to quickly finish the lithosphere rupture to form the modern GoC.

Confusion exists as to the age of the Abor Volcanics of NE India. Some consider the unit to have been emplaced in the Early Permian, others the Early Eocene, a difference of ∼230 million years. The divergence in opinion is significant because fundamentally different models explaining the geotectonic evolution of India depend on the age designation of the unit. Paleomagnetic data reported here from several exposures in the type locality of the formation in the lower Siang Valley indicate that steep dipping primary magnetizations (mean = 72.7 ± 6.2°, equating to a paleo-latitude of 58.1°) are recorded in the formation. These are only consistent with the unit being of Permian age, possibly Artinskian based on a magnetostratigraphic argument. Plate tectonic models for this time consistently show the NE corner of the sub-continent >50°S; in the Early Eocene it was just north of the equator, which would have resulted in the unit recording shallow directions. The mean declination is counter-clockwise rotated by ∼94°, around half of which can be related to the motion of the Indian block; the remainder is likely due local Himalayan-age thrusting in the Eastern Syntaxis. Several workers have correlated the Abor Volcanics with broadly coeval mafic volcanic suites in Oman, NE Pakistan–NW India and southern Tibet–Nepal, which developed in response to the Cimmerian block peeling-off eastern Gondwana in the Early-Middle Permian, but we believe there are problems with this model. Instead, we suggest that the Abor basalts relate to India–Antarctica/India–Australia extension that was happening at about the same time. Such an explanation best accommodates the relevant stratigraphical and structural data (present-day position within the Himalayan thrust stack), as well as the plate tectonic model for Permian eastern Gondwana.

The Early–mid Cretaceous marks the confluence of three major continental-scale events in eastern Gondwana: (1) the emplacement of a Silicic Large Igneous Province (LIP) near the continental margin; (2) the volcaniclastic fill, transgression and regression of a major epicontinental seaway developed over at least a quarter of the Australian continent; and (3) epeirogenic uplift, exhumation and continental rupturing culminating in the opening of the Tasman Basin c. 84 Ma. The Whitsunday Silicic LIP event had widespread impact, producing both substantial extrusive volumes of dominantly silicic pyroclastic material and coeval first-cycle volcanogenic sediment that accumulated within many eastern Australian sedimentary basins, and principally in the Great Australian Basin system (>2 Mkm3 combined volume). The final pulse of volcanism and volcanogenic sedimentation at c. 105–95 Ma coincided with epicontinental seaway regression, which shows a lack of correspondence with the global sea-level curve, and alternatively records a wider, continental-scale effect of volcanism and rift tectonism. Widespread igneous underplating related to this LIP event is evident from high paleogeothermal gradients and regional hydrothermal fluid flow detectable in the shallow crust and over a broad region. Enhanced CO2 fluxing through sedimentary basins also records indirectly, large-scale, LIP-related mafic underplating. A discrete episode of rapid crustal cooling and exhumation began c. 100–90 Ma along the length of the eastern Australian margin, related to an enhanced phase of continental rifting that was largely amagmatic, and probably a switch from wide–more narrow rift modes. Along-margin variations in detachment fault architecture produced narrow (SE Australia) and wide continental margins with marginal, submerged continental plateaux (NE Australia). Long-lived NE-trending cross-orogen lineaments controlled the switch from narrow to wide continental margin geometries.

Large igneous provinces (LIPs) are sites of the most frequently recurring, largest volume basaltic and silicic eruptions in Earth history. These large-volume (N1000 km3 dense rock equivalent) and large-magnitude (NM8) eruptions produce areally extensive (104–105 km2) basaltic lava flow fields and silicic ignimbrites that are the main building blocks of LIPs. Available information on the largest eruptive units are primarily from the Columbia River and Deccan provinces for the dimensions of flood basalt eruptions, and the Parana–Etendeka and Afro-Arabian provinces for the silicic ignimbrite eruptions. In addition, three large-volume (675– 2000 km3) silicic lava flows have also been mapped out in the Proterozoic Gawler Range province (Australia), an interpreted LIP remnant. Magma volumes of N1000 km3 have also been emplaced as high-level basaltic and rhyolitic sills in LIPs. The data sets indicate comparable eruption magnitudes between the basaltic and silicic eruptions, but due to considerable volumes residing as co-ignimbrite ash deposits, the current volume constraints for the silicic ignimbrite eruptions may be considerably underestimated. Magma composition thus appears to be no barrier to the volume of magma emitted during an individual eruption. Despite this general similarity in magnitude, flood basaltic and silicic eruptions are very different in terms of eruption style, duration, intensity, vent configuration, and emplacement style. Flood basaltic eruptions are dominantly effusive and Hawaiian–Strombolian in style, with magma discharge rates of ~106–108 kg s−1 and eruption durations estimated at years to tens of years that emplace dominantly compound pahoehoe lava flow fields. Effusive and fissural eruptions have also emplaced some large-volume silicic lavas, but discharge rates are unknown, and may be up to an order of magnitude greater than those of flood basalt lava eruptions for emplacement to be on realistic time scales (b10 years). Most silicic eruptions, however, are moderately to highly explosive, producing co-current pyroclastic fountains (rarely Plinian) with discharge rates of 109– 1011 kg s−1 that emplace welded to rheomorphic ignimbrites. At present, durations for the large-magnitude silicic eruptions are unconstrained; at discharge rates of 109 kg s−1, equivalent to the peak of the 1991 Mt Pinatubo eruption, the largest silicic eruptions would take many months to evacuate N5000 km3 of magma. The generally simple deposit structure is more suggestive of short-duration (hours to days) and high intensity (~1011 kg s−1) eruptions, perhaps with hiatuses in some cases. These extreme discharge rates would be facilitated by multiple point, fissure and/or ring fracture venting of magma. Eruption frequencies are much elevated for large-magnitude eruptions of both magma types during LIP-forming episodes. However, in basaltdominated provinces (continental and ocean basin flood basalt provinces, oceanic plateaus, volcanic rifted margins), large magnitude (NM8) basaltic eruptions have much shorter recurrence intervals of 103–104 years, whereas similar magnitude silicic eruptions may have recurrence intervals of up to 105 years. The Parana– Etendeka province was the site of at least nine NM8 silicic eruptions over an ~1 Myr period at ~132 Ma; a similar eruption frequency, although with a fewer number of silicic eruptions is also observed for the Afro- Arabian Province. The huge volumes of basaltic and silicic magma erupted in quick succession during LIP events raises several unresolved issues in terms of locus of magma generation and storage (if any) in the crust prior to eruption, and paths and rates of ascent from magma reservoirs to the surface.

Numerical and fluid dynamic modelling predicts that mantle plumes should generate a broad domal uplift (>1,000 km wide, 500 to ⩾1,000 m high) preceding volcanism in large igneous provinces. The Emeishan large igneous province (southwest China) has been offered as the best example of plume-induced uplift, where kilometre-scale pre- and syn-volcanic relief was interpreted to develop in response to the impingement of a plume head. Here, we document voluminous mafic hydromagmatic deposits and submarine extrusions that formed during the initiation and early stages of the Emeishan large igneous province: these deposits were previously interpreted to be alluvial fan sediments shed from a pre-volcanic domal high. The abundance of such deposits—consisting of variable proportions of marine limestone and basaltic fragments—strongly suggests that the bulk of this province was emplaced at sea level. Evidence for dynamic pre-volcanic uplift as predicted by plume models is lacking, and such a lack may be the more general case. Any positive relief that developed was more likely the result of the formation of a volcanic edifice and rapid accumulation of the volcanic pile. Thick alluvial fan sediments from the core of the Emeishan Large Igneous Province have been considered as critical field evidence in support of plume-induced pre-volcanic doming and uplift. These sediments are now reinterpreted as mafic hydromagmatic deposits emplaced at sea level, precluding dynamic pre-volcanic uplift as predicted by mantle plume models.

Much has been learned about Large Igneous Provinces (LIPs) and their database greatly expanded since their first formal categorization in the early 1990s. This progress provides an opportunity to review the key characteristics that distinguish LIP events from other melting events of the upper mantle, and to reassess and revise how we define LIPs. A precise definition is important to correctly recognize those LIP events with regional to global effects, and to aid in refining petrogenetic models of the origin of LIPs. We revise the definition of LIPs as follows: “Large Igneous Provinces are magmatic provinces with areal extents > 0.1 Mkm 2 , igneous volumes > 0.1 Mkm 3 and maximum lifespans of ∼ 50 Myr that have intraplate tectonic settings or geochemical affinities, and are characterised by igneous pulse(s) of short duration (∼ 1–5 Myr), during which a large proportion (> 75%) of the total igneous volume has been emplaced.” They are dominantly mafic, but also can have significant ultramafic and silicic components, and some are dominated by silicic magmatism. In this revision, seamounts, seamount groups, submarine ridges and anomalous seafloor crust are no longer considered as LIPs. Although many of these are spatially-related features post-dating a LIP event, they are constructed by long-lived melting anomalies in the mantle at lower emplacement rates, and contrast with the more transient, high magma emplacement rate characteristics of the LIP event. Many LIPs emplaced in both continental and oceanic realms, are split and rifted apart by new ridge spreading centres, which reinforce the link with mid-ocean ridges as a post-LIP event. Three new types of igneous provinces are now included in the LIP inventory, to accommodate the recognition of a greater diversity of igneous compositions, and preserved expressions of LIP events since the Archean: 1) giant diabase/dolerite continental dyke swarm, sill and mafic–ultramafic intrusion-dominated provinces; 2) Silicic LIPs; and 3) tholeiite–komatiite associations, which may be Archean examples of LIPs. A revised global distribution of LIPs for the Phanerozoic is presented. Establishing the full extent of LIPs requires well-constrained plate reconstructions, and at present, plate reconstructions for the Precambrian are poorly known. However, the possibility of reconstructing the LIP record back to and into the Archean and using this expanded LIP record to better constrain the origins and effects of LIPs is an exciting frontier, and our revised definition is a contribution to that effort.

Voluminous (≥3·9 × 105 km3), prolonged (∼18 Myr) explosive silicic volcanism makes the mid-Tertiary Sierra Madre Occidental province of Mexico one of the largest intact silicic volcanic provinces known. Previous models have proposed an assimilation–fractional crystallization origin for the rhyolites involving closed-system fractional crystallization from crustally contaminated andesitic parental magmas, with 33 to ∼100% of the dated population; most antecrysts range in age between ∼20 and 32 Ma. A sub-population of the antecrystic zircons is chemically distinct in terms of their high U (>1000 ppm to 1·3 wt %) and heavy REE contents; these are not present in the Oligocene ignimbrites in the northeastern sector of the Sierra Madre Occidental. The combination of antecryst zircon U–Pb ages and chemistry suggests that much of the zircon in the youngest rhyolites was derived by remelting of partially molten to solidified igneous rocks formed during preceding phases of Sierra Madre Occidental volcanism. Strong Zr undersaturation, and estimations for very rapid dissolution rates of entrained zircons, preclude coeval mafic magmas being parental to the rhyolite magmas by a process of lower crustal assimilation followed by closed-system crystal fractionation as interpreted in previous studies of the Sierra Madre Occidental rhyolites. Mafic magmas were more probably important in providing a long-lived heat and material flux into the crust, resulting in the remelting and recycling of older crust and newly formed igneous materials related to Sierra Madre Occidental magmatism.

Large Igneous Provinces (LIPs) are the end-product of huge additions of magma to the continental crust both at the surface and at depth. Since the first categorisation of LIPs by Coffin & Eldholm (1994), it has been recognised that LIPs are more varied in form, age and character, and this includes the recognition of Silicic LIPs. Silicic LIPs are the largest accumulations of primary volcaniclastic rocks at the Earth's surface with areal extents >0.1 Mkm2 and extrusive and subvolcanic intrusive volumes >0.25 Mkm3. The Late Palaeozoic to Cenozoic Silicic LIP events are the best recognised and are similar in terms of their dimension, crustal setting, volcanic architecture and geochemistry. The Silicic LIPs typically form linear (>2000 km long) volcanic–plutonic belts along volcanic rifted margins or as failed continental rifts. Igneous compositions are volumetrically silicic-dominant (>65 wt% SiO2), but generally show a range of igneous compositions from basalt through to high-silica rhyolite. The rhyolites show transitional within-plate to calc-alkaline or convergent margin geochemical signatures, whereas both low- and high-Ti (>2 wt% TiO2) magma types are present in the coeval mafic igneous rocks as commonly observed in continental flood basalt provinces. Several Silicic LIPs form a pre-rift magmatic event along volcanic rifted margins that develop through a consistent temporal pattern of LIP magmatism followed by rifting, uplift and seafloorspreading. The difference between the Silicic LIPs and other continental mafic-dominated LIPs is largely due to different crustal settings. Phanerozoic Silicic LIPs are restricted to continental margins that comprise fertile, hydrous lower crustal materials built up by Phanerozoic subduction. The role of hydrous crustal additions and underplate formed during previous episodes of subduction seem crucial in triggering widespread crustal partial melting, and preventing a dominantly mafic surface expression to LIP events along these palaeo- and active continental margins. Silicic LIPs represent important targets for precious metal mineralisation and host extensive epithermal Au–Ag fields. They have been the sites of many large volume (>1000 km3 dense rock equivalent) silicic explosive eruptions and important sources of ash and aerosol contributions to the stratosphere. Future studies need to integrate their environmental effects with those from similarly large volume flood basalt eruptions.

The Granadilla eruption at 600 ka was one of the largest phonolitic explosive eruptions from the Las Canadas volcano on Tenerife, producing a classical plinian eruptive sequence of a widespread pumice fall deposit overlain by an ignimbrite. The eruption resulted in a major phase of caldera collapse that probably destroyed the shallow-level magma chamber system. Granadilla pumices contain a diverse phenocryst assemblage of alkali feldspar + biotite + sodian diopside to aegirine–augite + titanomagnetite + ilmenite + nosean/hauyne + titanite + apatite; alkali feldspar is the dominant phenocryst and biotite is the main ferromagnesian phase. Kaersutite and partially resorbed plagioclase (oligoclase to sodic andesine) are present in some eruptive units, particularly in pumice erupted during the early plinian phase, and in the Granadilla ignimbrite at the top of the sequence. Associated with the kaersutite and plagioclase are small clots of microlitic plagioclase and kaersutite interpreted as quenched blebs of tephriphonolitic magma within the phonolite pumice. The Granadilla Member has previously been recognized as an example of reverse-then-normal compositional zonation, where the zonation is primarily expressed in terms of substantial variations in trace element abundances with limited major element variation (cryptic zonation). Evidence for cryptic zonation is also provided by the chemistry of the phenocryst phases, and corresponding changes in intensive parameters (e.g. T, f O2, f H2O). Geothermometry estimates indicate that the main body of phonolite magma had a temperature gradient from 860 °C to ∼790 °C, with hotter magma (≥900 °C) tapped at the onset and terminal phases of the eruption. The reverse-then-normal chemical and thermal zonation reflects the initial tapping of a partially hybridized magma (mixing of phonolite and tephriphonolite), followed by the more sequential tapping of a zoned and relatively large body of highly evolved phonolite at a new vent and during the main plinian phase. This suggests that the different magma types within the main holding chamber could have been laterally juxtaposed, as well as in a density-stratified arrangement. Correlations between the presence of mixed phenocryst populations (i.e. presence of plagioclase and kaersutite) and coarser pumice fall layers suggest that increased eruption vigour led to the tapping of hybridized and/or less evolved magma probably from greater depths in the chamber. New oxygen isotope data for glass and mineral separates preclude syn-eruptive interaction between the vesiculating magma and hydrothermal fluids as the cause of the Sr isotope disequilibrium identified previously for the deposit. Enrichment in radiogenic Sr in the pumice glass has more likely been due to low-temperature exchange with meteoric water that was enriched in 87Sr by sea spray, which may be a common process affecting porous and glassy pyroclastic deposits on oceanic islands.

The late Miocene Farallon Negro volcanics, comprising basaltic to rhyodacitic volcano-sedimentary rocks, host the Bajo de la Alumbrera porphyry copper-gold deposit in northwest Argentina. Early studies of the geology of the district have underpinned the general model for porphyry ore deposits where hydrothermal alteration and mineralization develop in and around porphyritic intrusions emplaced at shallow depths (2.5-3.5 km) into stratovolcanic assemblages. The Farallon Negro succession is dominated by thick sequences of volcanosedimentary breccias, with lavas forming a minor component volumetrically. These volcaniclastic rocks conformably overlie crystalline basement-derived sedimentary rocks deposited in a developing foreland basin southeast of the Puna-Altiplano plateau. Within the FarallAƒÂ³n Negro volcanics, volcanogenic accumulations evolved from early mafic to intermediate and silicic compositions. The younger and more silicic rocks are demonstrably coeval and comagmatic with the earliest group of mineralized porphyritic intrusions at Bajo de la Alumbrera. Our analysis of the volcanic stratigraphy and facies architecture of the Farallon Negro volcanics indicates that volcanic eruptions evolved from effusive to mixed effusive and explosive styles, as magma compositions changed to more intermediate and silicic compositions. An early phase of mafic to intermediate volcanism was characterized by small synsedimentary intrusions with peperitic contacts, and lesser lava units scattered widely throughout the district, and interbedded with thick and extensive successions of coarse-grained sedimentary breccias. These sedimentary breccias formed from numerous debris- and hyperconcentrated flow events. A later phase of silicic volcanism included both effusive eruptions, forming several areally restricted lavas, and explosive eruptions, producing more widely dispersed (up to 5 km) tuff units, some up to 30-m thickness in proximal sections. Four key features of the volcanic stratigraphy suggest that the Farallon Negro volcanics need not simply record the construction of a large steep-sided polygenetic stratovolcano: (1) sheetlike, laterally continuous debris-flow and other coarse-grained sedimentary deposits are dominant, particularly in the lower sections; (2) mafic-intermediate composition lavas are volumetrically minor; (3) peperites are present throughout the sequence; and (4) fine-grained lacustrine sandstone-siltstone sequences occur in areas previously thought to be proximal to the summit region of the stratovolcano. Instead, the nature, distribution, and geometry of volcanic and volcaniclastic facies suggest that volcanism occurred as a relatively low relief, multiple-vent volcanic complex at the eastern edge of a broad, >200-km-wide late Miocene volcanic belt and on an active foreland sedimentary basin to the Puna-Altiplano. Volcanism that occurred synchronously with the earliest stages of porphyry- related mineralization at Bajo de la Alumbrera apparently developed in an alluvial to ring plain setting that was distal to larger volcanic edifices.

La Sierra Madre Occidental (SMO) es el resultado de diferentes episodios magmaticos y tectonicos durante el Cretacico- Cenozoico, asociados a la subduccion de la placa Farallon debajo de la placa de Norteamerica y a la apertura del Golfo de California. La estratigrafia de la SMO consta de cinco conjuntos igneos principales: (1) rocas plutonicas y volcanicas del Cretacico Superior-Paleoceno y (2) rocas volcanicas andesiticas y, en menor medida, dacitico-rioliticas del Eoceno, tradicionalmente agrupadas en el denominado “Complejo Volcanico Inferior” (CVI); 3) ignimbritas silicicas emplazadas en su mayoria en dos pulsos, en el Oligoceno temprano (32-28 Ma) y el Mioceno temprano (24-20 Ma), y agrupadas en el Supergrupo Volcanico Superior; 4) coladas basaltico-andesiticas transicionales extravasadas despues de cada pulso ignimbritico, correlacionadas con las “Andesita-Basalticas del Sur de la Cordillera” (SCORBA por sus siglas en ingles); 5) volcanismo postsubduccion constituido por coladas de basaltos alcalinos e ignimbritas emplazados en diferentes episo- dios del Mioceno tardio, Plioceno y Cuaternario, y que se relacionan con la separacion de Baja California del continente. Los productos de todos estos episodios magmaticos, parcialmente superpuestos entre si, cubren a su vez un basamento heterogeneo pobremente expuesto con edades del Precambrico y Paleozoico en la parte norte (Sonora y Chihuahua) y del Mesozoico en el resto de la SMO. La deformacion Laramide afecto moderadamente a las rocas mas antiguas del CVI (~101 a ~89 Ma) en Sinaloa y a rocas volcanicas del Maastrichtiano en Chihuahua central. En su fase fi nal, durante el Paleoceno y Eoceno temprano, se desarrollaron fracturas de tension ~E-W a ENE-WSW que hospedan los principales depositos de por fi dos cupriferos de la SMO. La tectonica extensional inicio por lo menos en el Oligoceno en toda la mitad oriental d

Laser ablation‐inductively coupled plasma‐mass spectrometry (LA‐ICP‐MS) analysis of zircons confirm a Late Devonian to Early Carboniferous age (ca 360–350 Ma) for silicic volcanic rocks of the Campwyn Volcanics and Yarrol terrane of the northern New England Fold Belt (Queensland). These rocks are coeval with silicic volcanism recorded elsewhere in the fold belt at this time (Connors Arch, Drummond Basin). The new U–Pb zircon ages, in combination with those from previous studies, show that silicic magmatism was both widespread across the northern New England Fold Belt (>250 000 km2 and ≥500 km inboard of plate margin) and protracted, occurring over a period of ∼15 million years. Zircon inheritance is commonplace in the Late Devonian – Early Carboniferous volcanics, reflecting anatectic melting and considerable reworking of continental crust. Inherited zircon components range from ca 370 to ca 2050 Ma, with Middle Devonian (385–370 Ma) zircons being common to almost all dated units. Precambrian zircon components record either Precambrian crystalline crust or sedimentary accumulations that were present above or within the zone of magma formation. This contrasts with a lack of significant zircon inheritance in younger Permo‐Carboniferous igneous rocks intruded through, and emplaced on top of, the Devonian–Carboniferous successions. The inheritance data and location of these volcanic rocks at the eastern margins of the northern New England Fold Belt, coupled with Sr–Nd, Pb isotopic data and depleted mantle model ages for Late Palaeozoic and Mesozoic magmatism, imply that Precambrian mafic and felsic crustal materials (potentially as old as 2050 Ma), or at the very least Lower Palaeozoic rocks derived from the reworking of Precambrian rocks, comprise basement to the eastern parts of the fold belt. This crustal basement architecture may be a relict from the Late Proterozoic breakup of the Rodinian supercontinent.

A new influx of sea-rafted pumice reached the eastern coast of Australia in October 2002, approximately 1 year after a felsic, shallow-marine explosive eruption at a previously unknown volcano (0403-091) along the Tofua volcanic arc (Tonga). The eruption produced floating pumice rafts that first became stranded in Fiji in November 2001, approximately I month after the eruption. Strandings of sea-rafted pumice along shorelines have been the only record of products from this submarine explosive eruption at the remote, submerged volcano. Computed drift trajectories of the sea-rafted pumice using numerical models of southwest Pacific surface wind fields and ocean currents indicate two cyclonic systems disturbed the drift of pumice to eastern Australia, as well as the importance of the combined wave and direct wind effect on pumice trajectory. Pumice became stranded along at least two-thirds (>2000 km) of the coastline of eastern Australia, being deposited on beaches during a sustained period of fresh onshore winds. Typical amounts of pumice initially stranded on beaches were 500-4000 individual clasts per in, and a minimum volume estimate of pumice that arrived to eastern Australia is 1.25 x 10(5) m(3). Pumice was beached below maximum tidal/storm surge levels and was quickly reworked back into the ocean, such that the concentration of beached pumice rapidly dissipated within weeks of the initial stranding, and little record of this stranding event now exists. Most stranded pumice clasts ranged in size from 2 to 5 cm in diameter; the largest measured clasts were 10 cm in Australia and 20 cm in Fiji. The pumice has a low phenocryst content ( 3500 km) and period of pumice floatation (greater than or equal to1 year), confirm the importance of sea-rafted pumice as a long-distance dispersal mechanism for marine organisms including marine pests and harmful invasive species. Billions of individual rafting pumice clasts can be generated in a single small-volume eruption, such as observed here, and the geological implications for the transport of sessile taxa over large distances are significant. An avenue for future research is to examine whether speciation events and volcanicity are linked; the periodic development of globalism for some taxa (e.g., corals, gastropods, bryozoa) may correlate in time and/or space with voluminous silicic igneous events capable of producing >10(6) km(3) of silicic pumice-rich pyroclastic material and emplaced into ocean basins. (C) 2004 Elsevier B.V. All rights reserved.

ELA-ICP-MS U–Pb zircon geochronology has been used to show that the porphyritic intrusions related to the formation of the Bajo de la Alumbrera porphyry Cu–Au deposit, NW Argentina, are cogenetic with stratigraphically well-constrained volcanic and volcaniclastic rocks of the Late Miocene Farallon Negro Volcanic Complex. Zircon geochronology for intrusions in this deposit and the host volcanic sequence show that multiple mineralized porphyries were emplaced in a volcanic complex that developed over 1.5 million years. Volcanism occurred in a multi-vent volcanic complex in a siliciclastic intermontane basin. The complex evolved from early mafic-intermediate effusive phases to a later silicic explosive phase associated with mafic intrusions. Zircons from the basal mafic-intermediate lavas have ages that range from 8.46±0.14 to 7.94±0.27 Ma. Regionally extensive silicic explosive volcanism occurred at ~8.0 Ma (8.05±0.13 and 7.96±0.11 Ma), which is co-temporal with intrusion of the earliest mineralized porphyries at Bajo de la Alumbrera (8.02±0.14 and 7.98±0.14 Ma). Regional uplift and erosion followed during which the magmatic-hydrothermal system was probably unroofed. Shortly thereafter, dacitic lava domes were extruded (7.95±0.17 Ma) and rhyolitic diatremes (7.79±0.13 Ma) deposited thick tuff blankets across the region. Emplacement of large intermediate composition stocks occurred at 7.37±0.22 Ma, shortly before renewed magmatism occurred at Bajo de la Alumbrera (7.10±0.07 Ma). The latest porphyry intrusive event is temporally associated with new ore-bearing magmatic-hydrothermal fluids. Other dacitic intrusions are associated with subeconomic deposits that formed synchronously with the mineralized porphyries at Bajo de la Alumbrera. However, their emplacement continued (from 7.10± 0.06 to 6.93±0.07 Ma) after the final intrusion at Bajo de al Alumbrera. Regional volcanism had ceased by 6.8 Ma (6.92±0.07 Ma).

Upper Devonian to Lower Carboniferous strata of the Campwyn Volcanics of east central Queensland preserve a substantial sequence of first-cycle volcaniclastic sedimentary and coeval volcanic rocks that record prolonged volcanic activity along the northern New England Fold Belt. The style and scale of volcanism varied with time, producing an Upper Devonian sequence of mafic volcano-sedimentary rocks overlain by a rhyolitic ignimbrite-dominated sequence that passes upward into a Lower Carboniferous limestone-bearing sedimentary sequence. We define two facies associations for the Campwyn Volcanics. A lower facies association is dominated by mafic volcanic-derived sedimentary breccias with subordinate primary mafic volcanic rocks comprising predominantly hyaloclastite and peperite. Sedimentary breccias record episodic and high energy, subaqueous depositional events with clastic material sourced from a mafic lava-dominated terrain. Some breccias contain a high proportion of attenuated dense, glassy mafic juvenile clasts, suggesting a syn-eruptive origin. The lower facies association coarsens upwards from a lithic sand-dominated sequence through a thick interval of pebble- to boulder-grade polymict volcaniclastic breccias, culminating in facies that demonstrate subaerial exposure. The silicic upper facies association marks a significant change in eruptive style, magma composition and the nature of eruptive sources, as well as the widespread development of subaerial depositional conditions. Crystal-rich, high-grade, low- to high-silica rhyolite ignimbrites dominate the base of this facies association. Biostratigraphic age controls indicate that the ignimbrite-bearing sequences are Famennian to lower-mid Tournaisian in age. The ignimbrites represent extra-caldera facies with individual units up to 40 m thick and mostly lacking coarse lithic breccias. Thick deposits of pyroclastic material interbedded with fine-grained siliceous sandstone and mudstone (locally radiolarian-bearing) were deposited from pyroclastic flows that crossed palaeoshorelines or represent syn-eruptive, resedimented pyroclastic material. Some block-bearing lithic-pumice-crystal breccias may also reflect more proximal subaqueous silicic explosive eruptions. Crystal-lithic sandstones interbedded with, and overlying the ignimbrites, contain abundant detrital volcanic quartz and feldspar derived from the pyroclastic deposits. Limestone is common in the upper part of the upper facies association, and several beds are oolitic (cf. Rockhampton Group of the Yarrol terrane). Overall, the upper facies association fines upward and is transgressive, recording a return to shallow-marine conditions. Palaeocurrent data from all stratigraphic levels in the Campwyn Volcanics indicate that the regional sediment-dispersal direction was to the northwest, and opposed to the generally accepted notion of easterly sediment dispersal from a volcanic arc source. The silicic upper facies association correlates in age and lithology to Early Carboniferous silicic volcanism in the Drummond (Cycle 1) and Burdekin Basins, Connors Arch, and in the Yarrol terranes of eastern Queensland. The widespread development of silicic volcanism in the Early Carboniferous indicates that silicic (rift-related) magmatism was not restricted to the Drummond Basin, but was part of a more substantial silicic igneous province.

A much-revised Quaternary stratigraphy is presented for ignimbrites and pumice fall deposits of the Bandas del Sur, in southern Tenerife. New 40Ar/39Ar data obtained for the Arico, Granadilla, Fasnia, Poris, La Caleta and Abrigo formations are presented, allowing correlation with previously dated offshore marine ashfall layers and volcaniclastic sediments. We also provide a minimum age of 287±7 ka for a major sector collapse event at the Güimar valley. The Bandas del Sur succession includes more than seven widespread ignimbrite sheets that have similar characteristics, including widespread basal Plinian layers, predominantly phonolite composition, ignimbrites with similar extensive geographic distributions, thin condensed veneers with abundant diffuse bedding and complex lateral and vertical grading patterns, lateral gradations into localized massive facies within palaeo-wadis, and widespread lithic breccia layers that probably record caldera-forming eruptions. Each ignimbrite sheet records substantial bypassing of pyroclastic material into the ocean. The succession indicates that Las Cañadas volcano underwent a series of major explosive eruptions, each starting with a Plinian phase followed by emplacement of ignimbrites and thin ash layers, some of co-ignimbrite origin. Several of the ignimbrite sheets are compositionally zoned and contain subordinate mafic pumices and banded pumices indicative of magma mingling immediately prior to eruption. Because passage of each pyroclastic density current was characterized by phases of non-deposition and erosion, the entire course of each eruption is incompletely recorded at any one location, accounting for some previously perceived differences between the units. Because each current passed into the ocean, estimating eruption volumes is virtually impossible. Nevertheless, the consistent widespread distributions and the presence of lithic breccias within most of the ignimbrite sheets suggest that at least seven caldera collapse eruptions are recorded in the Bandas del Sur succession and probably formed a complex, nested collapse structure. Detailed field relationships show that extensive ignimbrite sheets (e.g. the Arico, Poris and La Caleta formations) relate to previously unrecognized caldera collapse events. We envisage that the evolution of the nested Las Cañadas caldera is more complex than previously thought and involved a protracted history of successive ignimbrite-related caldera collapse events, and large sector collapse events, interspersed with edifice-building phases.

We have come a long way from simple straw and balloon models of magma plumbing systems to a more detailed picture of shallow level intrusive complexes. In this chapter, the sub-volcanic plumbing systems is considered in terms of how we can define the types and styles of magma networks from the deep to the shallow subsurface. We look at the plumbing system from large igneous provinces, through rifted systems to polygenetic volcanoes, with a view to characterising some of the key conceptual models. There is a focus on how ancient magmatic centres can help us better understand magmatic plumbing. New innovative ways to consider and quantify magma plumbing are also highlighted including 3D seismic, and using the crystal cargo to help fingerprint key magma plumbing events. Conclusions are drawn to our understanding of the 3D plumbing system and how these recent advances can be helpful when exploring the other chapters of this contribution.

The Las Canadas caldera is a nested collapse caldera formed by the successive migration and collapse of shallow magmatic chambers. Among the pyroclastic products of this caldera are phonolitic fallout deposits that crop out in the caldera wall and on the extracaldera slopes. These deposits exhibit an uninterrupted facies gradation from nonwelded to lava-like and record continuous volcanic deposition. Densely welded and lava-like facies result from the extreme attenuation and complete homogenization of juvenile clasts that destroy original clast outlines and any evidence of fallout deposition. Agglutination contributes significantly to the final degree of flattening observed in the welded facies. After deposition, rheomorphic flowage occurs. Emplacement temperatures for one of the welding sequences are calculated from magmatic temperatures and a model of tephra cooling during fallout. Results are 486 °C for the nonwelded facies and 740 °C for the moderately welded facies. For the same welding sequence, a cooling time between 25 and 54 days is estimated from published experimental and computational data as the possible duration of welding and rheomorphism. Following deposition and agglutination, the lava-like pyroclastic facies had the rheological properties of viscous lavas and flowed down the outer slopes away from the caldera. Some lava-like masses detached from proximal areas to more distal regions. During deposition, the eruptive style evolved from Plinian fallout to fountain-fed spatter deposition. This evolution was accompanied by a decrease in explosive power and a lower height of the eruptive column, which produce higher emplacement temperatures and more effective heat retention of pyroclasts.

a Department of Geoscience, 121 Trowbridge Hall, University of Iowa, Iowa City IA 52242, USA b Biogeoscience, Queensland University of Technology, Brisbane, Queensland 4001, Australia c Department of Earth and Environment, University of Leeds, Leeds LS2 9JT, UK d DougalEARTH Ltd., 12 Nevilles Cross Villas, Durham DH1 4JR, UK e Department of Earth Sciences, University of Hong Kong, Pokfulam Road, Hong Kong, China

The Upper Devonian to Lower Carboniferous volcanosedimentary rocks of the Yarrol terrane of the northern New England Fold Belt have previously been ascribed to a forearc basin setting. New data presented here, however, suggest that the Yarrol terrane developed as a backarc basin during the Middle to early Late Devonian. Based on field studies, we recognise four regionally applicable strati graphic units: (i) a basal, ?Middle to Upper Devonian submarine mafic volcanic suite (Monal volcanic facies association); (ii) the lower Frasnian Lochenbar beds that locally unconformably overlie the Monal volcanic facies association: (iii) the Three Moon Conglomerate (Upper Devonian - Lower Carboniferous): and (iv) the Lower Carboniferous Rockhampton Group characterised by the presence of oolitic limestone. Stratigraphic and compositional differences suggest the Monal volcanic facies association post-dates Middle Devonian silicic-dominated magmatism that was coeval with gold-copper mineralisation at Mt Morgan. The Lochenbar beds, Three Moon Conglomerate and Rockhampton Group represent a near-continuous sedimentary record of volcanism that changed in composition and style from mafic effusive (Late Devonian) to silicic explosive volcanism (Early Carboniferous). Palaeocurrent data from the Three Moon Conglomerate and Rockhampton Group indicate dispersal of sediment to the west and northwest, and are inconsistent with derivation from a volcanic-are source situated to the west (Connors-Auburn Arch). Geochemical data show that the Monal volcanic facies association ranges from tholeiitic subalkaline basalts to calc-alkaline basaltic andesite. Trace and rare-earth element abundances are distinctly MORE-like (e.g, light rare earth element depletion), with only moderate enrichment of the large-ion lithophile elements in some units, and negative Nb anomalies, suggesting a subduction-related signature. Basalts of the Monal volcanic facies association are best described as transitional between calc-alkali basalts and N-MORB. The elevated high field strength element contents (e.g. Zr, Y, Ti) are higher than modern island-are basalts, but comparable to basalts that floor modern backarc basins. This geochemical study, coupled with stratigraphic relationships, suggest that the eruption of backarc basin basalts followed widespread Middle Devonian, extension-related silicic magmatism (e.g. Retreat Batholith, Mt Morgan), and floored the Yarrol terrane. The Monal volcanic facies association thus shows similarities in its tectonic environment to the Lower Permian successions (e.g. Rookwood Volcanics) of the northern New England Fold Belt. These mafic volcanic sequences are interpreted to record two backarc basin-forming periods (Middle - Late Devonian and Late Carboniferous - Early Permian) during the Late Palaeozoic history of the New England Orogen. Silicic-dominated explosive volcanism, occurring extensively across the northern New England Fold Belt in the Early Carboniferous (Varrol terrane, Campwyn Volcanics, Drummond and Burdekin Basins), reflects another period of crustal melting and extension, most likely related to the opening of the Drummond Basin.

The Granadilla Member is one of the most widely dispersed and largest volume pyroclastic units at Tenerife (Canary Islands) and represents the culminating eruption to a second cycle of explosive volcanism of the Las Canadas edifice. The member, dared at 0.57 Ma, comprises a plinian fall deposit. the Granadilla pumice, which is overlain by ignimbrite up to 30 m thick. The Granadilla pumice is up to 9 m thick approximately 10 km from sourer (Pyle b(t) value is 5.35 km), and is subdivided into four Fail units. Unit 1 is up to 1.2 m thick and is further divisible into another four pumice fall subunits, based on bedding and grainsize differences. Unit 2 is a thin but distinctive ash layer (similar to2 cm thick), and its wide dispersal (>550 km(2)), constant thickness. planar laminations and ash aggregate textures collectively indicate a phreatoplinian fall origin. The lithic-rich nature and abundance of unaltered lithic fragments reflect magma interaction with aquifer-derived water at depth. Unit 3 (less than or equal to1.8 m thick), records a reversal to dry plinian eruptive activity. Unit 4, the thickest of the fall units (up to 6.3 m thick), records the maximum dispersal and intensity of the eruption (Pyle b(t) and b(c) values are 5.7 and 6.3 km, respectively), best illustrated by the presence of large pumice bombs up to 30 cm diameter (at distances up to 20 km from vent). and reverse grading of lithic and pumice clasts. The widespread (>500 km(2)), nonwelded and pumice-rich Granadilla ignimbrite (unit 5) records the collapse of the plinian eruption column. The ignimbrite has a simple sheet-like geometry. but exhibits a complex internal stratigraphy. The base of the ignimbrite locally cuts down through the underlying Granadilla pumice removing it entirely, indicating up to 9 m of erosion by the pyroclastic flows. A coarse, vent-derived lithic breccia horizon towards the top of the ignimbrite is interpreted to record the onset of caldera collapse late in the eruption. Minimum volume estimates for the Granadilla pumice and ignimbrite are 5.2 and 5 km(3), respectively. The dispersal area, deposit characteristics. and exponential thickness and clast size decay relationships with (isopach area)(1/2) are consistent with dispersal and fallout from the umbrella region of a moderately high (similar to 17 to greater than or equal to 25 km) plinian column. We propose that the eruption involved two vents, probably aligned along a NE-SW fissure within the Las Canadas caldera. (C) 2000 Elsevier Science B.V. All rights reserved.

Contrary to general belief, not all large igneous provinces (LIPs) are characterised by rocks of basaltic composition. Silicic-dominated LIPs, such as the Whitsunday Volcanic Province of NE Australia, are being increasingly recognised in the rock record. These silicic LIPs are consistent in being: (1) volumetrically dominated by ignimbrite; (2) active over prolonged periods (40-50 m.y.), based on available age data; and (3) spatially and temporally associated with plate break-up. This silicic dominated LIP, related to the break-up of eastern continental Gondwana, is also significant for being the source of > 1.4 x 10(6) km(3) of coeval volcanogenic sediment preserved in adjacent sedimentary basins of eastern Australia. The Whitsunday Volcanic Province is volumetrically dominated by medium- to high-grade, dacitic to rhyolitic lithic ignimbrites. Individual ignimbrite units are commonly between 10 and 100 m thick, and the ignimbrite-dominated sequences exceed 1 km in thickness. Coarse lithic lag breccias containing clasts up to 6 m diameter are associated with the ignimbrites in proximal sections. Pyroclastic surge and fallout deposits, subordinate basaltic to rhyolitic lavas, phreatomagmatic deposits, and locally significant thicknesses of coarse-grained volcanogenic conglomerate and sandstone are interbedded with the ignimbrites. The volcanic sequences are intruded by gabbro/dolerite to rhyolite dykes (up to 50 m in width), sills and comagmatic granite. Dyke orientations are primarily from NW to NNE. The volcanic sequences are characterised by the interstratification of proximal/near-vent lithofacies such as rhyolite domes and lavas, and basaltic agglomerate, with medial to distal facies of ignimbrite. The burial of these near-vent lithofacies by ignimbrites, coupled with the paucity of mass wastage products such as debris-flow deposits indicates a low-relief depositional environment. Furthermore, the volcanic succession records a temporal change in: (1) eruptive styles; (2) the nature of source vents; and (3) erupted compositions. An early explosive dacitic pyroclastic phase was succeeded by a later mixed pyroclastic-effusive phase producing an essentially bimodal suite of lavas and rhyolitic ignimbrite. From the nature and distribution of volcanic lithofacies. the volcanic sequences are interpreted to record the evolution of a multiple vent, low-relief volcanic region, dominated by several large caldera centres. (C) 2000 Elsevier Science B.V. All rights reserved.