Search

Stellar X-ray and UV radiation can significantly affect the survival, composition, and long-term evolution of the atmospheres of planets in or near their host star's habitable zone (HZ). Especially interesting are planetary systems in the solar neighborhood that may host temperate and potentially habitable surface conditions, which may be analyzed by future ground and space-based direct-imaging surveys for signatures of habitability and life. To advance our understanding of the radiation environment in these systems, we leverage $\sim$3 Msec of XMM-Newton and Chandra observations in order to measure three fundamental stellar properties at X-ray energies for 57 nearby FGKM stellar systems: the shape of the stellar X-ray spectrum, the luminosity, and the timescales over which the stars vary (e.g., due to flares). These systems possess HZs that will be directly imageable to next-generation telescopes such as the Habitable Worlds Observatory and ground-based Extremely Large Telescopes (ELTs). We identify 29 stellar systems with $L_X/L_{\rm bol}$ ratios similar to (or less than) that of the Sun; any potential planets in the habitable zones of these stars therefore reside in present day X-ray radiation environments similar to (or less hostile than) modern Earth, though a broader set of these targets could host habitable planets. An additional 19 stellar systems have been observed with the Swift X-ray Telescope; in total, only $\sim$30% of potential direct imaging target stars has been observed with XMM-Newton, Chandra, or Swift. The data products from this work (X-ray light curves and spectra) are available via a public Zenodo repository (doi: 10.5281/zenodo.11490574)., Comment: Accepted to ApJS. 38 pages, 15 figures, 10 tables

Atmospheric pollutants such as CFCs and NO$_{2}$ have been proposed as potential remotely detectable atmospheric technosignature gases. Here we investigate the potential for artificial greenhouse gases including CF$_{4}$, C$_{2}$F$_{6}$, C$_{3}$F$_{8}$, SF$_{6}$, and NF$_{3}$ to generate detectable atmospheric signatures. In contrast to passive incidental byproducts of industrial processes, artificial greenhouse gases would represent an intentional effort to change the climate of a planet with long-lived, low toxicity gases and would possess low false positive potential. An extraterrestrial civilization may be motivated to undertake such an effort to arrest a predicted snowball state on their home world or to terraform an otherwise uninhabitable terrestrial planet within their system. Because artificial greenhouse gases strongly absorb in the thermal mid-infrared window of temperate atmospheres, a terraformed planet will logically possess strong absorption features from these gases at mid-IR wavelengths ($\sim$8-12 $\mu$m), possibly accompanied by diagnostic features in the near-IR. As a proof of concept, we calculate the needed observation time to detect 1 [10](100) ppm of C$_{2}$F$_{6}$/C$_{3}$F$_{8}$/SF$_{6}$ on TRAPPIST-1f with JWST MIRI/LRS and NIRSpec. We find that a combination of 1[10](100) ppm each of C$_{2}$F$_{6}$, C$_{3}$F$_{8}$, and SF$_{6}$ can be detected with an S/N $\geq$ 5 in as few as 25[10](5) transits with MIRI/LRS. We further explore mid-infrared direct-imaging scenarios with the LIFE mission concept and find these gases are more detectable than standard biosignatures at these concentrations. Consequently, artificial greenhouse gases can be readily detected (or excluded) during normal planetary characterization observations with no additional overhead., Comment: 18 pages, 8 figures, 6 tables; ApJ, 969, 20

Systems hosting multiple giant planets are important laboratories for understanding planetary formation and migration processes. We present a nearly decade-long Doppler spectroscopy campaign from the Keck-I telescope to characterize the two transiting giant planets orbiting Kepler-511 on orbits of 27 days and 297 days. The radial velocity measurements yield precise masses for both planets, which we use to infer their bulk heavy element content. Both planets contain approximately 30 Earth masses of heavy elements, but their bulk metallicities (i.e., the ratio between metal mass and total mass) are drastically different ($0.86 \pm 0.04$ and $0.22 \pm 0.04$ respectively). Envelope mass loss cannot account for this difference due to the relatively large orbital distance and mass of the inner planet. We conclude that the outer planet underwent runaway gas accretion while the inner planet did not. This bifurcation in accretion histories is likely a result of the accretion of gas with very different metallicities by the two planets or the late formation of the inner planet from a merger of sub-Neptunes. Kepler-511 uniquely demonstrates how giant planet formation can produce strikingly different outcomes even for planets in the same system., Comment: submitted to AAS journals, comments welcome

This chapter reviews proposed exoplanet biosignatures, including their biological origins, observable features, atmospheric sinks, and potentially confounding abiotic sources. Emphasis is placed on material published since past comprehensive reviews while providing a foundational understanding of each named biosignature. Topics include possible gaseous biosignatures (e.g., O$_2$, O$_3$, CH$_4$, N$_2$O, DMS, CH$_3$Cl, C$_5$H$_8$, NH$_3$, PH$_3$), surface biosignatures (e.g., vegetation red edge, other pigment features, polarization signatures), and temporal biosignatures (e.g., atmospheric seasonality). Potential frameworks for assessing remote biosignatures are described. Text and table summaries provide references to relevant original research articles., Comment: Chapter 13 accepted for publication in the Reviews in Mineralogy and Geochemistry (RiMG) Volume 90 on "Exoplanets: Compositions, Mineralogy, and Evolution" edited by Natalie Hinkel, Keith Putirka, and Siyi Xu; 44 pages, 14 figures, and 4 tables

Theoretical predictions and observational data indicate a class of sub-Neptune exoplanets may have water-rich interiors covered by hydrogen-dominated atmospheres. Provided suitable climate conditions, such planets could host surface liquid oceans. Motivated by recent JWST observations of K2-18 b, we self-consistently model the photochemistry and potential detectability of biogenic sulfur gases in the atmospheres of temperate sub-Neptune waterworlds for the first time. On Earth today, organic sulfur compounds produced by marine biota are rapidly destroyed by photochemical processes before they can accumulate to significant levels. Domagal-Goldman et al. (2011) suggest that detectable biogenic sulfur signatures could emerge in Archean-like atmospheres with higher biological production or low UV flux. In this study, we explore biogenic sulfur across a wide range of biological fluxes and stellar UV environments. Critically, the main photochemical sinks are absent on the nightside of tidally locked planets. To address this, we further perform experiments with a 3D GCM and a 2D photochemical model (VULCAN 2D (Tsai et al. 2024)) to simulate the global distribution of biogenic gases to investigate their terminator concentrations as seen via transmission spectroscopy. Our models indicate that biogenic sulfur gases can rise to potentially detectable levels on hydrogen-rich waterworlds, but only for enhanced global biosulfur flux ($\gtrsim$20 times modern Earth's flux). We find that it is challenging to identify DMS at 3.4 $\mu m$ where it strongly overlaps with CH$_4$, whereas it is more plausible to detect DMS and companion byproducts, ethylene (C$_2$H$_4$) and ethane (C$_2$H$_6$), in the mid-infrared between 9 and 13 $\mu m$., Comment: 9 pages, 4 figures, accepted for publication in ApJL

Radiative transfer (RT) models are critical in the interpretation of exoplanetary spectra, in simulating exoplanet climates and when designing the specifications of future flagship observatories. However, most models differ in methodologies and input data, which can lead to significantly different spectra. In this paper, we present the experimental protocol of the MALBEC (Modeling Atmospheric Lines By the Exoplanet Community) project. MALBEC is an exoplanet model intercomparison project (exoMIP) that belongs to the CUISINES (Climates Using Interactive Suites of Intercomparisons Nested for Exoplanet Studies) framework which aims to provide the exoplanet community with a large and diverse set of comparison and validation of models. The proposed protocol tests include a large set of initial participating RT models, a broad range of atmospheres (from Hot Jupiters to temperate terrestrials) and several observation geometries, which would allow us to quantify and compare the differences between different RT models used by the exoplanetary community. Two types of tests are proposed: transit spectroscopy and direct imaging modeling, with results from the proposed tests to be published in dedicated follow-up papers. To encourage the community to join this comparison effort and as an example, we present simulation results for one specific transit case (GJ-1214 b), in which we find notable differences in how the various codes handle the discretization of the atmospheres (e.g., sub-layering), the treatment of molecular opacities (e.g., correlated-k, line-by-line) and the default spectroscopic repositories generally used by each model (e.g., HITRAN, HITEMP, ExoMol).

Discovering and characterizing exoplanets at the outer edge of the transit method's sensitivity has proven challenging owing to geometric biases and the practical difficulties associated with acquiring long observational baselines. Nonetheless, a sample of giant exoplanets on orbits longer than 100 days has been identified by transit hunting missions. We present long-term Doppler spectroscopy for 11 such systems with observation baselines spanning a few years to a decade. We model these radial velocity observations jointly with transit photometry to provide initial characterizations of these objects and the systems in which they exist. Specifically, we make new precise mass measurements for four long-period giant exoplanets (Kepler-111 c, Kepler-553 c, Kepler-849 b, and PH-2 b), we place new upper limits on mass for four others (Kepler-421 b, KOI-1431.01, Kepler-1513 b, and Kepler-952 b), and we show that several "confirmed" planets are in fact not planetary at all. We present these findings to complement similar efforts focused on closer-in short-period giant planets, and with the hope of inspiring future dedicated studies of cool giant exoplanets., Comment: 35 pages, 24 figures, 11 tables. Accepted for publication in ApJ Supplement

Chemical disequilibrium quantified via available free energy has previously been proposed as a potential biosignature. However, exoplanet biosignature remote sensing work has not yet investigated how observational uncertainties impact the ability to infer a life-generated available free energy. We pair an atmospheric retrieval tool to a thermodynamics model to assess the detectability of chemical disequilibrium signatures of Earth-like exoplanets, emphasizing the Proterozoic Eon where atmospheric abundances of oxygen-methane disequilibrium pairs may have been relatively high. Retrieval model studies applied across a range of gas abundances revealed that order-of-magnitude constraints on disequilibrium energy are achieved with simulated reflected-light observations at the high abundance scenario and signal-to-noise ratios (50) while weak constraints are found at moderate SNRs (20\,--\,30) for med\,--\,low abundance cases. Furthermore, the disequilibrium energy constraints are improved by modest thermal information encoded in water vapor opacities at optical and near-infrared wavelengths. These results highlight how remotely detecting chemical disequilibrium biosignatures can be a useful and metabolism-agnostic approach to biosignature detection., Comment: Nature Astronomy. Supplementary information see https://zenodo.org/records/10093798 For Source Data see https://zenodo.org/records/8335447

The atmospheric dynamics of tidally-locked hot Jupiters is characterized by strong equatorial winds. Understanding the interaction between global circulation and chemistry is crucial in atmospheric studies and interpreting observations. Two-dimensional (2D) photochemical transport models shed light on how the atmospheric composition depends on circulation. In this paper, we introduce the 2D photochemical (horizontal and vertical) transport model, VULCAN 2D, which improves on the pseudo-2D approaches by allowing for non-uniform zonal winds. We extensively validate our VULCAN 2D with analytical solutions and benchmark comparisons. Applications to HD 189733 b and HD 209458 b reveal a transition in mixing regimes: horizontal transport predominates below $\sim$0.1 mbar while vertical mixing is more important at higher altitudes above 0.1 mbar. Motivated by the previously inferred carbon-rich atmosphere, we find that HD 209458 b with super-solar carbon-to-oxygen ratio (C/O) exhibits pronounced C$_2$H$_4$ absorption on the morning limb but not on the evening limb, owing to horizontal transport from the nightside. We discuss when a pseudo-2D approach is a valid assumption and its inherent limitations. Finally, we demonstrate the effect of horizontal transport in transmission observations and its impact on the morning-evening limb asymmetry with synthetic spectra, highlighting the need to consider global transport when interpreting exoplanet atmospheres., Comment: 19 pages, 20 figures, published in ApJ

Ultra-cool dwarf stars are abundant, long-lived, and uniquely suited to enable the atmospheric study of transiting terrestrial companions with JWST. Amongst them, the most prominent is the M8.5V star TRAPPIST-1 and its seven planets. While JWST Cycle 1 observations have started to yield preliminary insights into the planets, they have also revealed that their atmospheric exploration requires a better understanding of their host star. Here, we propose a roadmap to characterize the TRAPPIST-1 system -- and others like it -- in an efficient and robust manner. We notably recommend that -- although more challenging to schedule -- multi-transit windows be prioritized to mitigate the effects of stellar activity and gather up to twice more transits per JWST hour spent. We conclude that, for such systems, planets cannot be studied in isolation by small programs, but rather need large-scale, jointly space- and ground-based initiatives to fully exploit the capabilities of JWST for the exploration of terrestrial planets.

Many past studies have predicted the steady-state production and maintenance of abiotic O$_2$ and O$_3$ in the atmospheres of CO$_2$-rich terrestrial planets orbiting M dwarf stars. However, the time-dependent responses of these planetary atmospheres to flare events - and the possible temporary production or enhancement of false positive biosignatures therein - has been comparatively less well studied. Most past works that have modeled the photochemical response to flares have assumed abundant free oxygen like that of the modern or Proterozoic Earth. Here we examine in detail the photochemical impact of the UV emitted by a single flare on abiotic O$_2$/O$_3$ production in prebiotic, CO$_2$-dominated atmospheres of M dwarf planets with CO$_2$ levels ranging from 10% to 90% of 1 bar. We find that a single flare generally destroys O$_2$ while modestly enhancing O$_3$ column densities. We simulate the spectral observables of both the steady-state atmosphere and time-dependent spectral response over the flare window for both emitted and transmitted light spectra. Over the course of the flare, the O$_3$ UV Hartley band is modestly enhanced by a maximum of 6 ppm while the CO$_2$ molecular transit depths modestly decline by 7 ppm. In both emitted and transmitted light spectra, the 9.65 $\mu$m O$_3$ band is hidden by the overlapping 9.4 $\mu$m CO$_2$ band for all scenarios considered. Overall, we find that the possible enhancements of abiotic O$_3$ due to a single flare are small compared to O$_3$'s sensitivity to other parameters such as CO$_2$ and H$_2$O abundances or the availability of reducing gases such as H$_2$., Comment: An error was discovered in the code use to obtain part of the results, thus compromising the article's conclusions. The authors have asked for the paper to be withdrawn from the journal until the problem can be corrected

Efforts to spectrally characterize the atmospheric compositions of temperate terrestrial exoplanets orbiting M-dwarf stars with the James Webb Space Telescope (JWST) are now underway. Key molecular targets of such searches include O$_2$ and CO, which are potential indicators of life. Recently, it was proposed that CO$_2$ photolysis generates abundant ($\gtrsim0.1$ bar) abiotic O$_2$ and CO in the atmospheres of habitable M-dwarf planets with CO$_2$-rich atmospheres, constituting a strong false positive for O$_2$ as a biosignature and further complicating efforts to use CO as a diagnostic of surface biology. Importantly, this implied that TRAPPIST-1e and TRAPPIST-1f, now under observation with JWST, would abiotically accumulate abundant O$_2$ and CO, if habitable. Here, we use a multi-model approach to re-examine photochemical O$_2$ and CO accumulation on planets orbiting M-dwarf stars. We show that photochemical O$_2$ remains a trace gas on habitable CO$_2$-rich M-dwarf planets, with earlier predictions of abundant O$_2$ and CO due to an atmospheric model top that was too low to accurately resolve the unusually-high CO$_2$ photolysis peak on such worlds. Our work strengthens the case for O$_2$ as a biosignature gas, and affirms the importance of CO as a diagnostic of photochemical O$_2$ production. However, observationally relevant false positive potential remains, especially for O$_2$'s photochemical product O$_3$, and further work is required to confidently understand O$_2$ and O$_3$ as biosignature gases on M-dwarf planets., Comment: Accepted to Astrophysical Journal Letters (in press). 3 Figures, 1 Table in main text; 4 Figures, 5 Tables in SI

Understanding the physical characteristics of Venus, including its atmosphere, interior, and its evolutionary pathway with respect to Earth, remains a vital component for terrestrial planet evolution models and the emergence and/or decline of planetary habitability. A statistical strategy for evaluating the evolutionary pathways of terrestrial planets lies in the atmospheric characterization of exoplanets, where the sample size provides sufficient means for determining required runaway greenhouse conditions. Observations of potential exoVenuses can help confirm hypotheses about Venus' past, as well as the occurrence rate of Venus-like planets in other systems. Additionally, the data from future Venus missions, such as DAVINCI, EnVision, and VERITAS, will provide valuable information regarding Venus, and the study of exoVenuses will be complimentary to these missions. To facilitate studies of exoVenus candidates, we provide a catalog of all confirmed terrestrial planets in the Venus Zone, including transiting and non-transiting cases, and quantify their potential for follow-up observations. We examine the demographics of the exoVenus population with relation to stellar and planetary properties, such as the planetary radius gap. We highlight specific high-priority exoVenus targets for follow-up observations including: TOI-2285 b, LTT 1445 A c, TOI-1266 c, LHS 1140 c, and L98-59 d. We also discuss follow-up observations that may yield further insight into the Venus/Earth divergence in atmospheric properties., Comment: 27 pages, 7 figures, accepted for publication in the Astronomical Journal

We assess the dependence of Earth's disk-integrated mid-infrared thermal emission spectrum on observation geometries and investigate which and how spectral features are impacted by seasonality on Earth. We compiled an exclusive dataset containing 2690 disk-integrated thermal emission spectra for four different full-disk observing geometries (North & South Pole centered and Africa & Pacific centred equatorial views) over four consecutive years. The spectra were derived from 2378 spectral channels in the wavelength range from 3.75 to 15.4 micron (nominal resolution $\approx$ 1200) and were recorded by the Atmospheric Infrared Sounder aboard the Aqua satellite. We learned that there is significant seasonal variability in Earth's thermal emission spectrum, and the strength of spectral features of bio-indicators, such as N2O, CH4, O3 and CO2 depends strongly on both season and viewing geometry. In addition, we found a strong spectral degeneracy with respect to the latter two indicating that multi-epoch measurements and time-dependent signals may be required in order to fully characterize planetary environments. Even for Earth and especially for equatorial views, the variations in flux and strength of absorption features in the disk-integrated data are small and typically $\le$ 10%. Disentangling these variations from the noise in future exoplanet observations will be a challenge. However, irrespectively of when the planet will be measured (i.e., day or night or season) the results from mid-infrared observations will remain the same to the zeroth order which is an advantage over reflected light observations., Comment: 21 pages, 15 Figures, 3 Tables

Nitrous oxide (N2O) -- a product of microbial nitrogen metabolism -- is a compelling exoplanet biosignature gas with distinctive spectral features in the near- and mid-infrared, and only minor abiotic sources on Earth. Previous investigations of N2O as a biosignature have examined scenarios using Earthlike N2O mixing ratios or surface fluxes, or those inferred from Earth's geologic record. However, biological fluxes of N2O could be substantially higher, due to a lack of metal catalysts or if the last step of the denitrification metabolism that yields N2 from N2O had never evolved. Here, we use a global biogeochemical model coupled with photochemical and spectral models to systematically quantify the limits of plausible N2O abundances and spectral detectability for Earth analogs orbiting main-sequence (FGKM) stars. We examine N2O buildup over a range of oxygen conditions (1%-100% present atmospheric level) and N2O fluxes (0.01-100 teramole per year; Tmol = 10^12 mole) that are compatible with Earth's history. We find that N2O fluxes of 10 [100] Tmol yr$^{-1}$ would lead to maximum N2O abundances of ~5 [50] ppm for Earth-Sun analogs, 90 [1600] ppm for Earths around late K dwarfs, and 30 [300] ppm for an Earthlike TRAPPIST-1e. We simulate emission and transmission spectra for intermediate and maximum N2O concentrations that are relevant to current and future space-based telescopes. We calculate the detectability of N2O spectral features for high-flux scenarios for TRAPPIST-1e with JWST. We review potential false positives, including chemodenitrification and abiotic production via stellar activity, and identify key spectral and contextual discriminants to confirm or refute the biogenicity of the observed N2O., Comment: 22 pages, 17 figures; ApJ, 937, 109

The first potential exoplanet biosignature detections are likely to be ambiguous due to the potential for false positives: abiotic planetary processes that produce observables similar to those anticipated from a global biosphere. Here we propose a class of methylated gases as corroborative `capstone' biosignatures. Capstone biosignatures are metabolic products that may be less immediately detectable, but have substantially lower false positive potential, and can thus serve as confirmation for a primary biosignature such as O$_2$. CH$_3$Cl has previously been established as a biosignature candidate, and other halomethane gases such as CH$_3$Br and CH$_3$I have similar potential. These gases absorb in the mid infrared at wavelengths that are likely to be captured while observing primary biosignatures such as O$_3$ or CH$_4$. We quantitatively explore CH$_3$Br as a new capstone biosignature through photochemical and spectral modeling of Earth-like planets orbiting FGKM stellar hosts. We also re-examine the biosignature potential of CH$_3$Cl over the same set of parameters using our updated model. We show that CH$_3$Cl and CH$_3$Br can build up to relatively high levels in M dwarf environments and analyze synthetic spectra of TRAPPIST-1e. Our results suggest that there is a co-additive spectral effect from multiple CH$_3$X gases in an atmosphere, leading to increased signal-to-noise and greater ability to detect a methylated gas feature. These capstone biosignatures are plausibly detectable in exoplanetary atmospheres, have low false positive potential, and would provide strong evidence for life in conjunction with other well established biosignature candidates., Comment: 18 pages, 11 figures, appendix. Published in ApJ

Accurately measuring and modeling the Lyman-$\alpha$ (Ly$\alpha$; $\lambda$1215.67 \AA) emission line from low mass stars is vital for our ability to build predictive high energy stellar spectra, yet interstellar medium (ISM) absorption of this line typically prevents model-measurement comparisons. Ly$\alpha$ also controls the photodissociation of important molecules, like water and methane, in exoplanet atmospheres such that any photochemical models assessing potential biosignatures or atmospheric abundances require accurate Ly$\alpha$ host star flux estimates. Recent observations of three early M and K stars (K3, M0, M1) with exceptionally high radial velocities (>100 km s$^{-1}$) reveal the intrinsic profiles of these types of stars as most of their Ly$\alpha$ flux is shifted away from the geocoronal line core and contamination from the ISM. These observations indicate that previous stellar spectra computed with the PHOENIX atmosphere code have underpredicted the core of Ly$\alpha$ in these types of stars. With these observations, we have been able to better understand the microphysics in the upper atmosphere and improve the predictive capabilities of the PHOENIX atmosphere code. Since these wavelengths drive the photolysis of key molecular species, we also present results analyzing the impact of the resulting changes to the synthetic stellar spectra on observable chemistry in terrestrial planet atmospheres., Comment: 17 pages, 12 figures

Technosignatures refer to observational manifestations of technology that could be detected through astronomical means. Most previous searches for technosignatures have focused on searches for radio signals, but many current and future observing facilities could also constrain the prevalence of some non-radio technosignatures. This search could thus benefit from broader participation by the astronomical community, as contributions to technosignature science can also take the form of negative results that provide statistically meaningful quantitative upper limits on the presence of a signal. This paper provides a synthesis of the recommendations of the 2020 TechnoClimes workshop, which was an online event intended to develop a research agenda to prioritize and guide future theoretical and observational studies technosignatures. The paper provides a high-level overview of the use of current and future missions to detect exoplanetary technosignatures at ultraviolet, optical, or infrared wavelengths, which specifically focuses on the detectability of atmospheric technosignatures, artificial surface modifications, optical beacons, space engineering and megastructures, and interstellar flight. This overview does not derive any new quantitative detection limits but is intended to provide additional science justification for the use of current and planned observing facilities as well as to inspire astronomers conducting such observations to consider the relevance of their ongoing observations to technosignature science. This synthesis also identifies possible technology gaps with the ability of current and planned missions to search for technosignatures, which suggests the need to consider technosignature science cases in the design of future mission concepts., Comment: Accepted for publication in Acta Astronautica

Agriculture is one of the oldest forms of technology on Earth. The cultivation of plants requires a terrestrial planet with active hydrological and carbon cycles and depends on the availability of nitrogen in soil. The technological innovation of agriculture is the active management of this nitrogen cycle by applying fertilizer to soil, at first through the production of manure excesses but later by the Haber-Bosch industrial process. The use of such fertilizers has increased the atmospheric abundance of nitrogen-containing species such as NH$_3$ and N$_2$O as agricultural productivity intensifies in many parts of the world. Both NH$_3$ and N$_2$O are effective greenhouse gases, and the combined presence of these gases in the atmosphere of a habitable planet could serve as a remotely detectable spectral signature of technology. Here we use a synthetic spectral generator to assess the detectability of NH$_3$ and N$_2$O that would arise from present-day and future global-scale agriculture. We show that present-day Earth abundances of NH$_3$ and N$_2$O would be difficult to detect but hypothetical scenarios involving a planet with 30-100 billion people could show a change in transmittance of about 50-70% compared to pre-agricultural Earth. These calculations suggest the possibility of considering the simultaneous detection of NH$_3$ and N$_2$O in an atmosphere that also contains H$_2$O, O$_2$, and CO$_2$ as a technosignature for extraterrestrial agriculture. The technology of agriculture is one that could be sustainable across geologic timescales, so the spectral signature of such an "ExoFarm" is worth considering in the search for technosignatures., Comment: Accepted by ApJL, 12 pages, 1 figure

Radial velocity (RV) surveys have discovered giant exoplanets on au-scale orbits with a broad distribution of eccentricities. Those with the most eccentric orbits are valuable laboratories for testing theories of high eccentricity migration. However, few such exoplanets transit their host stars thus removing the ability to apply constraints on formation from their bulk internal compositions. We report the discovery of Kepler-1704 b, a transiting 4.15 $M_{\rm J}$ giant planet on a 988.88 day orbit with the extreme eccentricity of $0.921^{+0.010}_{-0.015}$. Our decade-long RV baseline from the Keck I telescope allows us to measure the orbit and bulk heavy element composition of Kepler-1704 b and place limits on the existence of undiscovered companions. Kepler-1704 b is a failed hot Jupiter that was likely excited to high eccentricity by scattering events that possibly began during its gas accretion phase. Its final periastron distance was too large to allow for tidal circularization, so now it orbits it host from distances spanning 0.16 - 3.9 au. The maximum difference in planetary equilibrium temperature resulting from this elongated orbit is over 700 K. A simulation of the thermal phase curve of Kepler-1704 b during periastron passage demonstrates that it is a remarkable target for atmospheric characterization from the James Webb Space Telescope, which could potentially also measure the planet's rotational period as the hot spot from periastron rotates in and out of view. Continued characterization of the Kepler-1704 system promises to refine theories explaining the formation of hot Jupiters and cool giant planets like those in the solar system., Comment: 27 pages, 16 figures, published in AJ (2021, 162, 154). This version includes updated planet ephemeris (Tables 2, 3, and 4) as described in erratum to be published in AJ

L 98-59 is an M3V dwarf star that hosts three small (R < 1.6 Earth radii) planets. The host star is bright (K = 7.1) and nearby (10.6 pc), making the system a prime target for follow-up characterization with the Hubble Space Telescope (HST) and the upcoming James Webb Space Telescope (JWST). Herein, we use simulated transmission spectroscopy to evaluate the detectability of spectral features with HST and JWST assuming diverse atmospheric scenarios (e.g., atmospheres dominated by H2, H2O, CO2, or O2). We find that H2O and CH4 present in a low mean-molecular weight atmosphere could be detected with HST in 1 transit for the two outermost planets, while H2O in a clear steam atmosphere could be detected in 6 transits or fewer with HST for all three planets. We predict that observations using JWST/NIRISS would be capable of detecting a clear steam atmosphere in 1 transit for each planet, and H2O absorption in a hazy steam atmosphere in 2 transits or less. In a clear, desiccated atmosphere, O2 absorption may be detectable for all three planets with NIRISS. If the L 98-59 planets possess a clear, Venus-like atmosphere, NIRSpec could detect CO2 within 26 transits for each planet, but the presence of H2SO4 clouds would significantly suppress CO2 absorption. The L 98-59 system is an excellent laboratory for comparative planetary studies of transiting multiplanet systems, and observations of the system via HST and JWST would present a unique opportunity to test the accuracy of the models presented in this study., Comment: Submitted to AJ

The observation of a 266.94 GHz feature in the Venus spectrum has been attributed to PH$_3$ in the Venus clouds, suggesting unexpected geological, chemical or even biological processes. Since both PH$_3$ and SO$_2$ are spectrally active near 266.94 GHz, the contribution to this line from SO$_2$ must be determined before it can be attributed, in whole or part, to PH$_3$. An undetected SO$_2$ reference line, interpreted as an unexpectedly low SO$_2$ abundance, suggested that the 266.94 GHz feature could be attributed primarily to PH$_3$. However, the low SO$_2$ and the inference that PH$_3$ was in the cloud deck posed an apparent contradiction. Here we use a radiative transfer model to analyze the PH$_3$ discovery, and explore the detectability of different vertical distributions of PH$_3$ and SO$_2$. We find that the 266.94 GHz line does not originate in the clouds, but above 80 km in the Venus mesosphere. This level of line formation is inconsistent with chemical modeling that assumes generation of PH$_3$ in the Venus clouds. Given the extremely short chemical lifetime of PH$_3$ in the Venus mesosphere, an implausibly high source flux would be needed to maintain the observed value of 20$\pm$10 ppb. We find that typical Venus SO$_2$ vertical distributions and abundances fit the JCMT 266.94 GHz feature, and the resulting SO$_2$ reference line at 267.54 GHz would have remained undetectable in the ALMA data due to line dilution. We conclude that nominal mesospheric SO$_2$ is a more plausible explanation for the JCMT and ALMA data than PH$_3$., Comment: 12 pages, 5 figures, accepted to ApJL

Despite the severe bias of the transit method of exoplanet discovery toward short orbital periods, a modest sample of transiting exoplanets with orbital periods greater than 100 days is known. Long-term radial velocity (RV) surveys are pivotal to confirming these signals and generating a set of planetary masses and densities for planets receiving moderate to low irradiation from their host stars. Here, we conduct RV observations of Kepler-1514 from the Keck I telescope using the High Resolution Echelle Spectrometer. From these data, we measure the mass of the statistically validated giant ($1.108\pm0.023$ $R_{\rm J}$) exoplanet Kepler-1514 b with a 218 day orbital period as $5.28\pm0.22$ $M_{\rm J}$. The bulk density of this cool ($\sim$390 K) giant planet is $4.82^{+0.26}_{-0.25}$ g cm$^{-3}$, consistent with a core supported by electron degeneracy pressure. We also infer an orbital eccentricity of $0.401^{+0.013}_{-0.014}$ from the RV and transit observations, which is consistent with planet-planet scattering and disk cavity migration models. The Kepler-1514 system contains an Earth-size, Kepler Object of Interest on a 10.5 day orbit that we statistically validate against false positive scenarios, including those involving a neighboring star. The combination of the brightness ($V$=11.8) of the host star and the long period, low irradiation, and high density of Kepler-1514 b places this system among a rare group of known exoplanetary systems and one that is amenable to continued study., Comment: 18 pages, 9 figures, accepted for publication in the Astronomical Journal

The search for exoplanetary life must encompass the complex geological processes reflected in an exoplanet's atmosphere, or we risk reporting false positive and false negative detections. To do this, we must nurture the nascent discipline of "exogeoscience" to fully integrate astronomers, astrophysicists, geoscientists, oceanographers, atmospheric chemists and biologists. Increased funding for interdisciplinary research programs, supporting existing and future multidisciplinary research nodes, and developing research incubators is key to transforming true exogeoscience from an aspiration to a reality., Comment: Submitted as white paper to 2023-2033 Planetary Science and Astrobiology Decadal Survey; Updated to include all co-authors

We present a study of the photochemistry of abiotic habitable planets with anoxic CO$_2$-N$_2$ atmospheres. Such worlds are representative of early Earth, Mars and Venus, and analogous exoplanets. H$_2$O photodissociation controls the atmospheric photochemistry of these worlds through production of reactive OH, which dominates the removal of atmospheric trace gases. The near-UV (NUV; $>200$ nm) absorption cross-sections of H$_2$O play an outsized role in OH production; these cross-sections were heretofore unmeasured at habitable temperatures ($<373$ K). We present the first measurements of NUV H$_2$O absorption at $292$ K, and show it to absorb orders of magnitude more than previously assumed. To explore the implications of these new cross-sections, we employ a photochemical model; we first intercompare it with two others and resolve past literature disagreement. The enhanced OH production due to these higher cross-sections leads to efficient recombination of CO and O$_2$, suppressing both by orders of magnitude relative to past predictions and eliminating the low-outgassing "false positive" scenario for O$_2$ as a biosignature around solar-type stars. Enhanced [OH] increases rainout of reductants to the surface, relevant to prebiotic chemistry, and may also suppress CH$_4$ and H$_2$; the latter depends on whether burial of reductants is inhibited on the underlying planet, as is argued for abiotic worlds. While we focus on CO$_2$-rich worlds, our results are relevant to anoxic planets in general. Overall, our work advances the state-of-the-art of photochemical models by providing crucial new H$_2$O cross-sections and resolving past disagreement in the literature, and suggests that detection of spectrally active trace gases like CO in rocky exoplanet atmospheres may be more challenging than previously considered., Comment: Manuscript (this version) accepted to ApJ. Cross-section data available at https://github.com/sukritranjan/ranjanschwietermanharman2020. Feedback continues to be solicited

The collision-induced fundamental vibration-rotation band at 6.4 um is the most significant absorption feature from O2 in the infrared (Timofeyev and Tonkov, 1978; Rinslandet al., 1982, 1989), yet it has not been previously incorporated into exoplanet spectral analyses for several reasons. Either CIAs were not included or incomplete/obsolete CIA databases were used. Also, the current version of HITRAN does not include CIAs at 6.4 um with other collision partners (O2-X). We include O2-X CIA features in our transmission spectroscopy simulations by parameterizing the 6.4 um O2-N2 CIA based on Rinsland et al.(1989) and the O2-CO2 CIA based on Baranov et al. (2004). Here we report that the O2-X CIA may be the most detectable O2 feature for transit observations. For a potentialTRAPPIST-1e analogue system within 5 pc of the Sun, it could be the only O2 detectable signature with JWST (using MIRI LRS) for a modern Earth-like cloudy atmosphere with biological quantities of O2. Also, we show that the 6.4 um O2-X CIA would be prominent for O2-rich desiccated atmospheres (Luger and Barnes, 2015) and could be detectable with JWST in just a few transits. For systems beyond 5 pc, this feature could therefore be a powerful discriminator of uninhabited planets with non-biological "false positive" O2 in their atmospheres - as they would only be detectable at those higher O2 pressures., Comment: Published in Nature Astronomy

Earthshine is the dominant source of natural illumination on the surface of the Moon during lunar night, and at locations within permanently shadowed regions that never receive direct sunlight. As such, earthshine may enable the exploration of areas of the Moon that are hidden from solar illumination. The heat flux from earthshine may also influence the transport and cold trapping of volatiles present in the very coldest areas. In this study, Earth's spectral radiance at the Moon is examined using a suite of Earth spectral models created using the Virtual Planetary Laboratory (VPL) three dimensional modeling capability. At the Moon, the broadband, hemispherical irradiance from Earth near 0 phase is approximately 0.15 watts per square meter, with comparable contributions from solar reflectance and thermal emission. Over the simulation timeframe, spanning two lunations, Earth's thermal irradiance changes less than a few mW per square meter as a result of cloud variability and the south-to-north motion of sub-observer position. In solar band, Earth's diurnally averaged light curve at phase angles < 60 degrees is well fit using a Henyey Greenstein integral phase function. At wavelengths > 0.7 microns, near the well known vegetation "red edge", Earth's reflected solar radiance shows significant diurnal modulation as a result of the longitudinal asymmetry in projected landmass, as well as from the distribution of clouds. A simple formulation with adjustable coefficients is presented for estimating Earth's hemispherical irradiance at the Moon as a function of wavelength, phase angle and sub-observer coordinates. It is demonstrated that earthshine is sufficiently bright to serve as a natural illumination source for optical measurements from the lunar surface., Comment: 27 pages, 15 figures, 1 table

Some atmospheric gases have been proposed as counter indicators to the presence of life on an exoplanet if remotely detectable at sufficient abundance (i.e., antibiosignatures), informing the search for biosignatures and potentially fingerprinting uninhabited habitats. However, the quantitative extent to which putative antibiosignatures could exist in the atmospheres of inhabited planets is not well understood. The most commonly referenced potential antibiosignature is CO, because it represents a source of free energy and reduced carbon that is readily exploited by life on Earth and is thus often assumed to accumulate only in the absence of life. Yet, biospheres actively produce CO through biomass burning, photooxidation processes, and release of gases that are photochemically converted into CO in the atmosphere. We demonstrate with a 1D ecosphere-atmosphere model that reducing biospheres can maintain CO levels of ~100 ppmv even at low H2 fluxes due to the impact of hybrid photosynthetic ecosystems. Additionally, we show that photochemistry around M dwarf stars is particularly favorable for the buildup of CO, with plausible concentrations for inhabited, oxygen-rich planets extending from hundreds of ppm to several percent. Since CH4 buildup is also favored on these worlds, and because O2 and O3 are likely not detectable with the James Webb Space Telescope, the presence of high CO (>100 ppmv) may discriminate between oxygen-rich and reducing biospheres with near-future transmission observations. These results suggest that spectroscopic detection of CO can be compatible with the presence of life and that a comprehensive contextual assessment is required to validate the significance of potential antibiosignatures., Comment: 10 pages, 5 figures, 2 tables. Published Open Access in ApJ