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Close to a saddle-node bifurcation, when two invariant solutions collide and disappear, the behavior of a dynamical system can closely resemble that of a solution which is no longer present at the chosen parameter value. For bifurcating equilibria in low-dimensional ODEs, the influence of such 'ghosts' on the temporal behavior of the system, namely delayed transitions, has been studied previously. We consider spatio-temporal PDEs and characterize the phenomenon of ghosts by defining representative state-space structures, which we term 'ghost states,' as minima of appropriately chosen cost functions. Using recently developed variational methods, we can compute and parametrically continue ghost states of equilibria, periodic orbits, and other invariant solutions. We demonstrate the relevance of ghost states to the observed dynamics in various nonlinear systems including chaotic maps, the Lorenz ODE system, the spatio-temporally chaotic Kuramoto-Sivashinsky PDE, the buckling of an elastic arc, and 3D Rayleigh-B\'enard convection.

Interface-type resistive switching (RS) devices with lower operation current and more reliable switching repeatability exhibits great potential in the applications for data storage devices and ultra-low-energy computing. However, the working mechanism of such interface-type RS devices are much less studied compared to that of the filament-type devices, which hinders the design and application of the novel interface-type devices. In this work, we fabricate a metal/TiOx/TiN/Si (001) thin film memristor by using a one-step pulsed laser deposition. In situ transmission electron microscopy (TEM) imaging and current-voltage (I-V) characteristic demonstrate that the device is switched between high resistive state (HRS) and low resistive state (LRS) in a bipolar fashion with sweeping the applied positive and negative voltages. In situ scanning transmission electron microscopy (STEM) experiments with electron energy loss spectroscopy (EELS) reveal that the charged defects (such as oxygen vacancies) can migrate along the intrinsic grain boundaries of TiOx insulating phase under electric field without forming obvious conductive filaments, resulting in the modulation of Schottky barriers at the metal/semiconductor interfaces. The fundamental insights gained from this study presents a novel perspective on RS processes and opens up new technological opportunities for fabricating ultra-low-energy nitride-based memristive devices.

Recent years have witnessed a steady progress towards blending 2D quantum materials into technology, with future applications often rooted in the electronic structure. Since crossings and inversions of electronic bands with different orbital characters determine intrinsic quantum transport properties, knowledge of the orbital character is essential. Here, we benchmark angle-resolved photoelectron emission spectroscopy (ARPES) as a tool to experimentally derive orbital characters. For this purpose we study the valence electronic structure of two technologically relevant quantum materials, graphene and WSe$_2$, and focus on circular dichroism that is believed to provide sensitivity to the orbital angular momentum. We analyze the contributions related to angular atomic photoionization profiles, interatomic interference, and multiple scattering. Regimes in which initial-state properties could be disentangled from the ARPES maps are critically discussed and the potential of using circular-dichroic ARPES as a tool to investigate the spin polarization of initial bands is explored. For the purpose of generalization, results from two additional materials, GdMn$_6$Sn$_6$ and PtTe$_2$ are presented in addition. This research demonstrates rich complexity of the underlying physics of circular-dichroic ARPES, providing new insights that will shape the interpretation of both past and future circular-dichroic ARPES studies., Comment: 12 pages, 7 figures

Dynamical backaction cooling has been demonstrated to be a successful method for achieving the motional quantum ground state of a mechanical oscillator in the resolved sideband regime, where the mechanical frequency is significantly larger than the cavity decay rate. Nevertheless, as mechanical systems increase in size, their frequencies naturally decrease, thus bringing them into the unresolved sideband regime, where the effectiveness of the sideband cooling approach decreases. Here, we will demonstrate, however, that this cooling technique in the unresolved sideband regime can be significantly enhanced by utilizing a nonlinear cavity as shown in the experimental work of Zoepfl et. al. (PRL, 2023). The above arises due to the increased asymmetry between the cooling and heating processes, thereby improving the cooling efficiency., Comment: 16 pages, 12 figures

Protecting qubits from environmental noise while maintaining strong coupling for fast high-fidelity control is a central challenge for quantum information processing. Here, we demonstrate a novel control scheme for superconducting fluxonium qubits that eliminates qubit decay through the control channel by reducing the environmental density of states at the transition frequency. Adding a low-pass filter on the flux line allows for flux-biasing and at the same time coherently controlling the fluxonium qubit by parametrically driving it at integer fractions of its transition frequency. We compare the filtered to the unfiltered configuration and find a five times longer $T_1$, and ten times improved $T_2$-echo time in the protected case. We demonstrate coherent control with up to 11-photon sub-harmonic drives, highlighting the strong non-linearity of the fluxonium potential. We experimentally determine Rabi frequencies and drive-induced frequency shifts in excellent agreement with numerical and analytical calculations. Furthermore, we show the equivalence of a 3-photon sub-harmonic drive to an on-resonance drive by benchmarking sub-harmonic gate fidelities above 99.94 %. These results open up a scalable path for full qubit control via a single protected channel, strongly suppressing qubit decoherence caused by control lines., Comment: 18 pages, 9 figures

Neutral sodium (Na I) is an alkali metal with a favorable absorption cross section such that tenuous gases are easily illuminated at select transiting exoplanet systems. We examine both the time-averaged and time-series alkali spectral flux individually, over 4 nights at a hot Saturn system on a $\sim$ 2.8 day orbit about a Sun-like star WASP-49 A. Very Large Telescope/ESPRESSO observations are analyzed, providing new constraints. We recover the previously confirmed residual sodium flux uniquely when averaged, whereas night-to-night Na I varies by more than an order of magnitude. On HARPS/3.6-m Epoch II, we report a Doppler redshift at $v_{ \Gamma, \mathrm{NaD}} =$ +9.7 $\pm$ 1.6 km/s with respect to the planet's rest frame. Upon examining the lightcurves, we confirm night-to-night variability, on the order of $\sim$ 1-4 % in NaD rarely coinciding with exoplanet transit, not readily explained by stellar activity, starspots, tellurics, or the interstellar medium. Coincident with the $\sim$+10 km/s Doppler redshift, we detect a transient sodium absorption event dF$_{\mathrm{NaD}}$/F$_{\star}$ = 3.6 $\pm$ 1 % at a relative difference of $\Delta F_{\mathrm{NaD}} (t) \sim$ 4.4 $\pm$ 1 %, enduring $\Delta t_{\mathrm{NaD}} \gtrsim$ 40 minutes. Since exoplanetary alkali signatures are blueshifted due to the natural vector of radiation pressure, estimated here at roughly $\sim$ -5.7 km/s, the radial velocity is rather at +15.4 km/s, far larger than any known exoplanet system. Given that the redshift magnitude v$_{\Gamma}$ is in between the Roche limit and dynamically stable satellite orbits, the transient sodium may be a putative indication of a natural satellite orbiting WASP-49 A b., Comment: Accepted to ApJ Letters (2024 August 2)

Unstable periodic orbits (UPOs) are believed to be the underlying dynamical structures of spatio-temporal chaos and turbulence. Finding these UPOs is however notoriously difficult. Matrix-free loop convergence algorithms deform entire space-time fields (loops) until they satisfy the evolution equations. Initial guesses for these robust variational convergence algorithms are thus periodic space-time fields in a high-dimensional state space, rendering their generation highly challenging. Usually guesses are generated with recurrency methods, which are most suited to shorter and more stable periodic orbits. Here we propose an alternative, data-driven method for generating initial guesses: while the dimension of the space used to discretize fluid flows is prohibitively large to construct suitable initial guesses, the dissipative dynamics will collapse onto a chaotic attractor of far lower dimension. We use an autoencoder to obtain a low-dimensional representation of the discretized physical space for the one-dimensional Kuramoto-Sivashinksy equation, in chaotic and hyperchaotic regimes. In this low-dimensional latent space, we construct loops based on the latent POD modes with random periodic coefficients, which are then decoded to physical space and used as initial guesses. These loops are found to be realistic initial guesses and, together with variational convergence algorithms, these guesses help us to quickly converge to UPOs. We further attempt to 'glue' known UPOs in the latent space to create guesses for longer ones. This gluing procedure is successful and points towards a hierarchy of UPOs where longer UPOs shadow sequences of shorter ones.

The Birman-Williams theorem gives a connection between the collection of unstable periodic orbits (UPOs) contained within a chaotic attractor and the topology of that attractor, for three-dimensional systems. In certain cases, the fractal dimension of a chaotic attractor in a partial differential equation (PDE) is less than three, even though that attractor is embedded within an infinite-dimensional space. Here we study the Kuramoto-Sivashinsky PDE at the onset of chaos. We use two different dimensionality-reduction techniques -- proper orthogonal decomposition and an autoencoder neural network -- to find two different mappings of the chaotic attractor into three dimensions. By finding the image of the attractor's UPOs in these reduced spaces and examining their linking numbers, we construct templates for the branched manifold which encodes the topological properties of the attractor. The templates obtained using two different dimensionality reduction methods are equivalent. The organization of the periodic orbits is identical and consistent symbolic sequences for low-period UPOs are derived. While this is not a formal mathematical proof, this agreement is strong evidence that the dimensional reduction is robust, in this case, and that an accurate topological characterization of the chaotic attractor of the chaotic PDE has been achieved., Comment: 14 pages, 14 figures

Waveguide quantum electrodynamics, the study of atomic systems interacting with propagating electromagnetic fields, is a powerful platform for understanding the complex interplay between light and matter. Qubit control is an indispensable tool in this field, and most experiments have so far focused on narrowband electromagnetic waves that interact with qubits at specific frequencies. This interaction, however, changes significantly with fast, broadband pulses, as waveguide properties like dispersion affect the pulse evolution and its impact on the qubit. Here, we use dispersion to achieve spatial addressing of superconducting qubits separated by a sub-wavelength distance within a microwave waveguide. This novel approach relies on a self-focusing effect to create a position-dependent interaction between the pulse and the qubits. This experiment emphasizes the importance of dispersion in the design and analysis of quantum experiments, and offers new avenues for the rapid control of quantum states.

As quantum information technologies advance they face challenges in scaling and connectivity. In particular, two necessities remain independent of the technological implementation: the need for connectivity between distant qubits and the need for efficient generation of entanglement. Perfect State Transfer is a technique which realises the time optimal transfer of a quantum state between distant nodes of qubit lattices with only nearest-neighbour couplings, hence providing an important tool to improve device connectivity. Crucially, the transfer protocol results in effective parity-dependent non-local interactions, extending its utility to the efficient generation of entangled states. Here, we experimentally demonstrate Perfect State Transfer and the generation of multi-qubit entanglement on a chain of superconducting qubits. The system consists of six fixed-frequency transmon qubits connected by tunable couplers, where the couplings are controlled via parametric drives. By simultaneously activating all couplings and engineering their individual amplitudes and frequencies, we implement Perfect State Transfer on up to six qubits and observe the respective single-excitation dynamics for different initial states. We then apply the protocol in the presence of multiple excitations and verify its parity-dependent property, where the number of excitations within the chain controls the phase of the transferred state. Finally, we utilise this property to prepare a multi-qubit Greenberger-Horne-Zeilinger state using only a single transfer operation, demonstrating its application for efficient entanglement generation., Comment: 16 pages, 10 figures

We investigate the effect of selected N and Ti point defects in $B$1 TiN on N 1s and Ti 2p$_{3/2}$ binding energies (BE) by experiments and ab initio calculations. X-ray photoelectron spectroscopy (XPS) measurements of Ti-deficient TiN films reveal additional N 1s spectral components at lower binding energies. Ab initio calculations predict that these components are caused by either Ti vacancies, which induce a N 1s BE shift of $-0.53$ eV in its first N neighbors, and/or N tetrahedral interstitials, which have their N 1s BE shifted by $-1.18$ eV and also shift BE of their first N neighbors by $-0.53$ eV. However, the {\it ab initio} calculations also reveal that the tetrahedral N interstitial is unstable at room temperature. We, therefore, unambiguously attribute the detected signal to Ti vacancies. Furthermore, the vacancy concentration in Ti-deficient TiN was quantified with XPS supported by ab initio calculations. The largest BE shifts of $-1.53$, $-1.80$ and $-2.28$ eV for Ti 2p$_{3/2}$ electrons are predicted for the Ti tetrahedral, split (10$\overline{1}$)-aligned and split (111)-aligned interstitial atoms, respectively, and we, therefore, propose XPS could detect them. Other defects such as N vacancy or N split (10$\overline{1}$)-aligned interstitial introduce smaller N 1s and Ti 2p$_{3/2}$ BE shifts and are unlikely to be detectable experimentally. Our work highlights the potential of ab initio-guided XPS measurements in detecting and quantifying point defects in $B$1 TiN.

In a vertical channel driven by an imposed horizontal temperature gradient, numerical simulations have previously shown steady, time-periodic and chaotic dynamics. We explore the observed dynamics by constructing invariant solutions of the three-dimensional Oberbeck-Boussinesq equations, characterizing the stability of these equilibria and periodic orbits, and following the bifurcation structure of the solution branches under parametric continuation in Rayleigh number. We find that in a narrow vertically-periodic domain of aspect ratio ten, the flow is dominated by the competition between three and four co-rotating rolls. We demonstrate that branches of three and four-roll equilibria are connected and can be understood in terms of their discrete symmetries. Specifically, the D4 symmetry of the four-roll branch dictates the existence of qualitatively different intermediate branches that themselves connect to the three-roll branch in a transcritical bifurcation due to D3 symmetry. The physical appearance, disappearance, merging and splitting of rolls along the connecting branch provide a physical and phenomenological illustration of the equivariant theory of D3-D4 mode interaction. We observe other manifestations of the competition between three and four rolls, in which the symmetry in time or in the transverse direction is broken, leading to limit cycles or wavy rolls, respectively. Our work highlights the interest of combining numerical simulations, bifurcation theory, and group theory, in order to understand the transitions between and origin of flow patterns.

Vertical thermal convection is a non-equilibrium system in which both buoyancy and shear forces play a role in driving the convective flow. Beyond the onset of convection, the driven dissipative system exhibits chaotic dynamics and turbulence. In a three-dimensional domain extended in both the vertical and the transverse dimensions, Gao et al. (2018) have observed a variety of convection patterns which are not described by linear stability analysis. We investigate the fully non-linear dynamics of vertical convection using a dynamical-systems approach based on the Oberbeck-Boussinesq equations. We compute the invariant solutions of these equations and the bifurcations that are responsible for the creation and termination of various branches. We map out a sequence of local bifurcations from the laminar base state, including simultaneous bifurcations involving patterned steady states with different symmetries. This atypical phenomenon of multiple branches simultaneously bifurcating from a single parent branch is explained by the role of D4 symmetry. In addition, two global bifurcations are identified: first, a homoclinic cycle from modulated transverse rolls and second, a heteroclinic cycle linking two symmetry-related diamond-roll patterns. These are confirmed by phase space projections as well as the functional form of the divergence of the period close to the bifurcation points. The heteroclinic orbit is shown to be robust and to result from a 1:2 mode interaction. The intricacy of this bifurcation diagram highlights the essential role played by dynamical systems theory and computation in hydrodynamic configurations.

A two-dimensional extension of a recently developed formalism for slow-fast quasilinear (QL) systems subject to fast instabilities is derived. Prior work has demonstrated that the emergent dynamics of these systems is characterized by a slow evolution of mean fields coupled to marginally stable, fast fluctuation fields. By exploiting this emergent behavior, an efficient fast-eigenvalue/slow-initial-value solution algorithm can be developed in which the amplitude of the fast fluctuations is slaved to the slowly evolving mean fields to ensure marginal stability (and temporal scale separation) is maintained. For 2D systems that are spatially-extended in one direction, the fluctuation eigenfunctions are labeled by their wavenumbers characterizing spatial variability in that direction, and the marginal mode(s) also must coincide with the fastest-growing mode(s) over all admissible wavenumbers. Here, we introduce two equivalent procedures for deriving an ordinary differential equation governing the slow evolution of the wavenumber of the fastest-growing fluctuation mode that simultaneously must be slaved to the mean dynamics to ensure the mode has zero growth rate. We illustrate the procedure in the context of a 2D model partial differential equation that shares certain attributes with the equations governing strongly stratified shear flows. The slaved evolution follows one or more marginal stability manifolds, which constitute select state-space structures that are not invariant under the full flow dynamics yet capture quasi-coherent states in physical space in a manner analogous to invariant solutions identified in, e.g., transitionally-turbulent shear flows. Accordingly, we propose that marginal stability manifolds are central organizing structures in a dynamical systems description of certain classes of multiscale flows where scale separation justifies a QL approximation of the dynamics.

We present first results derived from the largest collection of contemporaneously recorded Jovian sodium nebula and Io plasma torus (IPT) in [S II] 673.1 nm images assembled to date. The data were recorded by the Planetary Science Institute's Io Input/Output observatory (IoIO) and provide important context to Io geologic and atmospheric studies as well as the Juno mission and supporting observations. Enhancements in the observed emission are common, typically lasting 1 -- 3 months, such that the average flux of material from Io is determined by the enhancements, not any quiescent state. The enhancements are not seen at periodicities associated with modulation in solar insolation of Io's surface, thus physical process(es) other than insolation-driven sublimation must ultimately drive the bulk of Io's atmospheric escape. We suggest that geologic activity, likely involving volcanic plumes, drives escape., Comment: 29 pages, 4 figures, submitted to Journal of Geophysical Research (Space Physics)

Ultrafast electric-field control of emergent electronic and magnetic states at oxide interfaces offers exciting prospects for the development of new generations of energy-efficient devices. Here, we demonstrate that the electronic structure and emergent ferromagnetic interfacial state in epitaxial LaNiO3/CaMnO3 superlattices can be effectively controlled using intense single-cycle THz electric-field pulses. We employ a combination of polarization-dependent X-ray absorption spectroscopy with magnetic circular dichroism and X-ray resonant magnetic reflectivity to measure a detailed magneto-optical profile and thickness of the ferromagnetic interfacial layer. Then, we use time-resolved and temperature-dependent magneto-optical Kerr effect, along with transient optical reflectivity and transmissivity measurements, to disentangle multiple correlated electronic and magnetic processes driven by ultrafast high-field (~1 MV/cm) THz pulses. These processes include an initial sub-picosecond electronic response, consistent with non-equilibrium Joule heating; a rapid (~270 fs) demagnetization of the ferromagnetic interfacial layer, driven by THz-field-induced nonequilibrium spin-polarized currents; and subsequent multi-picosecond dynamics, possibly indicative of a change in the magnetic state of the superlattice due to the transfer of spin angular momentum to the lattice. Our findings shed light on the intricate interplay of electronic and magnetic phenomena in this strongly correlated material system, suggesting a promising avenue for efficient control of two-dimensional ferromagnetic states at oxide interfaces using ultrafast electric-field pulses.

Refractory inclusions in chondritic meteorites, namely amoeboid olivine aggregates (AOAs) and Ca-Al-rich inclusions (CAIs), are among the first solids to have formed in the solar system. The isotopic composition of CAIs is distinct from bulk meteorites, which either results from extreme processing of presolar carriers in the CAI-forming region, or reflects an inherited heterogeneity from the Sun's parental molecular cloud. Amoeboid olivine aggregates are less refractory than CAIs and provide a record of how the isotopic composition of solid material in the disk may have changed in time and space. However, the isotopic composition of AOAs and how this composition relates to that of CAIs and later-formed solids is unknown. Here, using new O, Ti, and Cr isotopic data for eight AOAs from the Allende CV3 chondrite, we show that CAIs and AOAs share a common isotopic composition, indicating a close genetic link and formation from the same isotopic reservoir. Because AOAs are less refractory than CAIs, this observation is difficult to reconcile with a thermal processing origin of the isotope anomalies. Instead, the common isotopic composition of CAIs and AOAs is readily accounted for in a model in which the isotopic composition of infalling material from the Sun's parental molecular cloud changed over time. In this model, CAIs and AOAs record the isotopic composition of the early infall, while later-formed solids contain a larger fraction of the later, isotopically distinct infall. This model implies that CAIs and AOAs record the isotopic composition of the Sun and suggests that the nucleosynthetic isotope heterogeneity of the solar system is predominantly produced by mixing of solar nebula condensates, which acquired their distinct isotopic compositions as a result of time-varied infall from the protosolar cloud., Comment: Published gold open access in Earth and Planetary Science Letters

Developing novel lead-free ferroelectric materials is crucial for next-generation microelectronic technologies that are energy efficient and environment friendly. However, materials discovery and property optimization are typically time-consuming due to the limited throughput of traditional synthesis methods. In this work, we use a high-throughput combinatorial synthesis approach to fabricate lead-free ferroelectric superlattices and solid solutions of (Ba0.7Ca0.3)TiO3 (BCT) and Ba(Zr0.2Ti0.8)O3 (BZT) phases with continuous variation of composition and layer thickness. High-resolution X-ray diffraction (XRD) and analytical scanning transmission electron microscopy (STEM) demonstrate high film quality and well-controlled compositional gradients. Ferroelectric and dielectric property measurements identify the optimal property point achieved at the morphotropic phase boundary (MPB) with a composition of 48BZT-52BCT. Displacement vector maps reveal that ferroelectric domain sizes are tunable by varying {BCT-BZT}N superlattice geometry. This high-throughput synthesis approach can be applied to many other material systems to expedite new materials discovery and properties optimization, allowing for the exploration of a large area of phase space within a single growth., Comment: submitted

For its potential as a catalyst, nanoporous gold (NPG) prepared through dealloying of bulk Ag-Au alloys has been extensively investigated. NPG thin films can offer ease of handling, better tunability of the chemistry and microstructure of the nanoporous structure, and represent a more sustainable usage of scarce resources. These films are however prone to intergranular cracking during dealloying, limiting their stability and potential applications. Here, we set out to systematically investigate the grain boundaries in Au28Ag72 thin films. We observe that a sample synthesized at 400 {\deg}C is at least 2.5 times less prone to cracking compared to a sample synthesized at room temperature. This correlates with a higher density of coincident site lattice grain boundaries, especially the density of coherent sigma 3, increased, which appear resistant against cracking. Nanoscale compositional analysis of random high-angle grain boundaries reveals prominent Ag enrichment up to 77 at.%, whereas sigma 3 coherent twin boundaries show Au enrichment of up to 30 at.%. The misorientation and the chemistry of grain boundaries hence affect their dealloying behavior, which in turn controls the cracking, and the possible longevity of NPG thin films for application in electrocatalysis.

The interplay between chirality and magnetism has been a source of fascination among scientists for over a century. In recent years, chirality-induced spin selectivity (CISS) has attracted renewed interest. It has been observed that electron transport through layers of homochiral molecules leads to a significant spin polarization of several tens of percent. Despite the abundant experimental evidence gathered through mesoscopic transport measurements, the exact mechanism behind CISS remains elusive. In this study, we report spin-selective electron transport through single helical aromatic hydrocarbons that were sublimed in vacuo onto ferromagnetic cobalt surfaces and examined with spin-polarized scanning tunneling microscopy (SP-STM) at a temperature of 5 K. Direct comparison of two enantiomers under otherwise identical conditions revealed magnetochiral conductance asymmetries of up to 50% when either the molecular handedness was exchanged or the magnetization direction of the STM tip or Co substrate was reversed. Importantly, our results rule out electron-phonon coupling and ensemble effects as primary mechanisms responsible for CISS., Comment: 15 pages, 4 figures, plus Supporting Information

A new potential class of nanolaminated and structurally complex materials, herein conceived as the Zigzag IntermetAllic (ZIA) phases, is proposed. A study of the constituent phases of a specific Nb--Si--Ni intermetallic alloy revealed that its ternary H-phase, \textit{i.e.}, the Nb$_3$SiNi$_2$ intermetallic compound (IMC), is a crystalline solid with the close-packed \textit{fcc} Bravais lattice, the 312 MAX phase stoichiometry and a layered atomic arrangement that may define an entire class of nanolaminated IMCs analogous to the nanolaminated ceramic compounds known today as the MAX phases. The electron microscopy investigation of the Nb$_{3}$SiNi$_{2}$ compound -- the first candidate ZIA phase -- revealed a remarkable structural complexity, as its ordered unit cell is made of 96 atoms. The ZIA phases extend the concept of nanolaminated crystalline solids well beyond the MAX phases family of early transition metal carbides/nitrides, most likely broadening the spectrum of achievable material properties into domains typically not covered by the MAX phases. Furthermore, this work uncovers that both families of nanolaminated crystalline solids, \textit{i.e.}, the herein introduced \textit{fcc} ZIA phases and all known variants of the \textit{hcp} MAX phases, obey the same overarching stoichiometric rule $P_{x+y}A_xN_y$, where $x$ and $y$ are integers ranging from 1 to 6.

Nucleosynthetic isotope anomalies in meteorites allow distinguishing between the non-carbonaceous (NC) and carbonaceous (CC) meteorite reservoirs and show that correlated isotope anomalies exist in both reservoirs. It is debated, however, whether these anomalies reflect thermal processing of presolar dust in the disk or are primordial heterogeneities inherited from the Solar System's parental molecular cloud. Here, using new high-precision 84Sr isotope data, we show that NC meteorites, Mars, and the Earth and Moon are characterized by the same 84Sr isotopic composition. This 84Sr homogeneity of the inner Solar System contrasts with the well-resolved and correlated isotope anomalies among NC meteorites observed for other elements, and most likely reflects correlated s- and (r-, p-)-process heterogeneities leading to 84Sr excess and deficits of similar magnitude which cancel each other. For the same reason there is no clearly resolved 84Sr difference between NC and CC meteorites, because in some carbonaceous chondrites the characteristic 84Sr excess of the CC reservoir is counterbalanced by an 84Sr deficit resulting from s-process variations. Nevertheless, most carbonaceous chondrites exhibit 84Sr excesses, which reflect admixture of refractory inclusions and more pronounced s-process heterogeneities in these samples. Together, the correlated variations of s-, (r-, p-)-process nuclides revealed by the 84Sr data of this study refute an origin of these isotope anomalies solely by processing of presolar dust grains, but points to primordial mixing of isotopically distinct dust reservoirs as the dominant process producing the isotopic heterogeneity of the Solar System., Comment: 18 pages 4 Figures

Electron magnetic circular dichroism (EMCD) is a powerful technique for estimating element-specific magnetic moments of materials on nanoscale with the potential to reach atomic resolution in transmission electron microscopes. However, the fundamentally weak EMCD signal strength complicates quantification of magnetic moments, as this requires very high precision, especially in the denominator of the sum rules. Here, we employ a statistical resampling technique known as bootstrapping to an experimental EMCD dataset to produce an empirical estimate of the noise dependent error distribution resulting from application of EMCD sum rules to bcc iron in a 3 beam orientation. We observe clear experimental evidence that noisy EMCD signals preferentially bias the estimation of magnetic moments, further supporting this with error distributions produced by Monte-Carlo simulations. Finally, we propose guidelines for the recognition and minimization of this bias in the estimation of magnetic moments.

Composite quasi-particles with emergent functionalities in spintronic and quantum information science can be realized in correlated materials due to entangled charge, spin, orbital, and lattice degrees of freedom. Here we show that by reducing the lateral dimension of correlated antiferromagnet NiPS3 flakes to tens of nanometers, we can switch-off the bulk spin-orbit entangled exciton in the near-infrared (1.47 eV) and activate visible-range (1.8 to 2.2 eV) transitions with charge-transfer character. These ultra-sharp lines (<120 ueV at 4.2 K) share the spin-correlated nature of the bulk exciton by displaying a Neel temperature dependent linear polarization. Furthermore, exciton photoluminescence lineshape analysis reveals a polaronic character via coupling with at-least 3 phonon modes and a comb-like Stark effect through discretization of charges in each layer. These findings augment the knowledge on the many-body nature of excitonic quasi-particles in correlated antiferromagnets and also establish the nanoscale platform as promising for maturing integrated magneto-optic devices.

Invariant solutions of the Navier-Stokes equations play an important role in the spatiotemporally chaotic dynamics of turbulent shear flows. Despite the significance of these solutions, their identification remains a computational challenge, rendering many solutions inaccessible and thus hindering progress towards a dynamical description of turbulence in terms of invariant solutions. We compute equilibria of three-dimensional wall-bounded shear flows using an adjoint-based matrix-free variational approach. To address the challenge of computing pressure in the presence of solid walls, we develop a formulation that circumvents the explicit construction of pressure and instead employs the influence matrix method. Together with a data-driven convergence acceleration technique based on dynamic mode decomposition, this yields a practically feasible alternative to state-of-the-art Newton methods for converging equilibrium solutions. We compute multiple equilibria of plane Couette flow starting from inaccurate guesses extracted from a turbulent time series. The variational method outperforms Newton(-hookstep) iterations in successfully converging from poor initial guesses, suggesting a larger convergence radius.

Motivated by frequently reported deviations from stoichiometry in cubic transition metal nitride (TMNx) thin films, the effect of N-vacancy concentration on the elastic properties of cubic TiNx, ZrNx, VNx, NbNx, and MoNx (0.72

Polycarbonate (PC) and protective (Ti,Al)N coatings exhibit extremely different material properties, specifically crystal structure, thermal stability, elastic and plastic behavior as well as thermal expansion coefficients. These differences present formidable challenges for the deposition process development as low-temperature synthesis routes have to be explored to avoid a thermal overload of the polymer substrate. Here, a large-area sputtering process is developed to address the challenges by systematically adjusting target peak power density and duty cycle. Adhering (Ti,Al)N coatings with a critical residual tensile stress of 2.2 +/- 0.2 GPa are obtained in the pulsed direct current magnetron sputtering range, whereas depositions at higher target peak power densities, realized by high power pulsed magnetron sputtering, lead to stress-induced adhesive and/or cohesive failure. The stress-optimized (Ti,Al)N coatings deposited onto PC with a target peak power density of 0.036 kW cm-2 and a duty cycle of 5.3% were investigated by cross-cut test confirming adhesion. By investigating the bond formation at the PC | (Ti,Al)N interface, mostly interfacial CNx bonds and a small fraction of (C-O)-(Ti,Al) bonds are identified by X-ray photoelectron spectroscopy, indicating reactions at the hydrocarbon and the carbonate groups during deposition. Nanoindentation reveals an elastic modulus of 296 +/- 18 GPa for the (Ti,Al)N coating, while a Ti-Al-O layer is formed during electrochemical impedance spectroscopy in a borate buffer solution, indicating protective passivation. This work demonstrates that the challenge posed by the extremely different material properties at the interface of soft polymer substrates and hard coatings can be addressed by systematical variation of the pulsing parameters to reduce the residual film stress.

Interfacial bond formation during sputter deposition of metal oxide thin films onto polycarbonate (PC) is investigated by ab initio molecular dynamics simulations and X-ray photoelectron spectroscopy (XPS) analysis of PC | X interfaces (X = Al$_2$O$_3$, TiO$_2$, TiAlO$_2$). Generally, the predicted bond formation is consistent with the experimental data. For all three interfaces, the majority of bonds identified by XPS are (C-O)-metal bonds, whereas C-metal bonds are the minority. Compared to the PC | Al$_2$O$_3$ interface, the PC | TiO$_2$ and PC | TiAlO$_2$ interfaces exhibit a reduction in the measured interfacial bond density by ~ 75 and ~ 65%, respectively. Multiplying the predicted bond strength with the corresponding experimentally determined interfacial bond density shows that Al$_2$O$_3$ exhibits the strongest interface with PC, while TiO$_2$ and TiAlO$_2$ exhibit ~ 70 and ~ 60% weaker interfaces, respectively. This can be understood by considering the complex interplay between the metal oxide composition, the bond strength as well as the population of bonds that are formed across the interface.