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Calcite aggregates were deformed to high strain using high-pressure torsion and applying confining pressures of 1–6 GPa and temperatures between room temperature and 450 °C. The run products were characterized by X-ray diffraction, and key microstructural parameters were extracted employing X-ray line profile analysis. The dominant slip system was determined as r{101¯4}⟨2¯021⟩ with edge dislocation character. The resulting dislocation density and the size of the coherently scattering domains (CSD) exhibit a systematic dependence on the P-T conditions of deformation. While high pressure generally impedes recovery through reducing point defect mobility, the picture is complicated by pressure-induced phase transformations in the CaCO3 system. Transition from the calcite stability field to those of the high-pressure polymorphs CaCO3-II, CaCO3-III and CaCO3-IIIb leads to a change of the microstructural evolution with deformation. At 450 °C and pressures within the calcite stability field, dislocation densities and CSD sizes saturate at shear strains exceeding 10 in agreement with earlier studies at lower pressures. In the stability field of CaCO3-II, the dislocation density exhibits a more complex behavior. Furthermore, at a given strain and strain rate, the dislocation density increases and the CSD size decreases with increasing pressure within the stability fields of either calcite or of the high-pressure polymorphs. There is, however, a jump from high dislocation densities and small CSDs in the upper pressure region of the calcite stability field to lower dislocation densities and larger CSDs in the low-pressure region of the CaCO3-II stability field. This jump is more pronounced at higher temperatures and less so at room temperature. The pressure influence on the deformation-induced evolution of dislocation densities implies that pressure variations may change the rheology of carbonate rocks. In particular, a weakening is expected to occur at the transition from the calcite to the CaCO3-II stability field, if aragonite does not form.

The mechanical properties comprising the stress-strain characteristics under uniaxial tensile deformation, the acoustic properties from mechanical resonance spectroscopy and—in parallel—the microstructural evolution during deformation of a nonequiatomic high-entropy alloy (HEA) Fe50Mn30Co10Cr10 have been studied in a wide temperature range, including ultralow temperatures down to 0.5 K. In the temperature range 300 to 4.2 K, a strong temperature dependence of the tensile strength occurs, hinting at the thermally activated nature of plastic deformation. Within the range of extremely low temperatures (4.2–0.5 K), however, the alloy exhibits anomalies of the yield strength, as well as discontinuous plasticity. Over the whole temperature range, the dynamic Young's modulus of tensile deformed samples shows a reduction of absolute values compared to those of the undeformed ones, and at temperatures < 30 K a change of the temperature dependence from almost linear to power-law type. At all temperatures down to 0.5 K, the alloy's plasticity stays as high as 50% as a consequence of a deformation driven martensitic phase transformation from fcc to hcp lattice (TRIP effect). Considering the ultralow deformation temperatures, the tensile strength reaches record values of 1513 MPa at 4.2 K, and still of 1274 MPa at 0.5 K, each being paired with significant strain hardening. These results suggest the HEA Fe50Mn30Co10Cr10 as a promising structural material for use in cryogenic environments down to extremely low temperatures. [ABSTRACT FROM AUTHOR]

The dislocation densities, arrangements and long-range internal stresses in cold rolled polycrystalline Cu, Ni, and Al, as well as in cold torsioned Fe, were determined by X-ray diffraction profile analysis using synchrotron radiation. The results suggest that if the mobility is high, marked static recovery takes place between the single deformation passes, which results in decreases of both dislocation density and local internal stress, and no formation of PTWs is observed.