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BACKGROUND: A city's industrial area's air quality has become a major priority. PM2.5-bound polycyclic aromatic hydrocarbons (PAHs) are one of the most common pollutants in urban-industrial area, and can be linked to health problems. AIM: This study aims to 1) investigate PM2.5 and PAHs emitted from roadside area (RS) and industrial estate (IE) in Rayong city 2) assess the inhalation of PM2.5 and PAHs on the human health of the age group. METHODS: PM2.5-bound PAHs were investigated and thier carcinogenic risk was evalued in this study. PM2.5 samples were collected on quartz filters contained in a mini-volume air sampler and analyzed for PAHs by GC-MS. RESULTS: The average PM2.5 concentrations at RS and IE were 43.3±26.8 and 40.4±21.7 µg/m3, while the values of total PAHs in both sites were 1.68±1.53 and 1.34±1.22 ng/m3, respectively. However, it was found that the PM2.5 and PAHs values were not significantly different (p>0.05). The results revealed that the individual lifetime cancer risk (Ric) of PM2.5 values for children and adults at both sites indicated acceptable cancer risk (10-6 to10-4). According to the incremental lifetime cancer risk (ILCR) values of PAHs for different age groups, exposure to PAHs in PM2.5 through the inhalation pathway was a negligible (

The Eastern Economic Corridor (EEC) project initiative has an adverse impact on the increasing problem of air pollution. This research aims to determine ambient NO2, O3, and SO2 levels in the industrial area (IT) and urban area (UB) in Rayong city as part of a health risk assessment from 2018 to 2020. The average NO2, O3, and SO2 concentrations at IT site were ranged from 23.5–24.7 μg/m3, 42.7–56.7 μg/m3, and 12.5–14.0 μg/m3, while those at UB site were 14.8–20.7 μg/m3, 42.5–68.3 μg/m3, and 3.2–4.7 μg/m3, respectively. Their concentrations in dry season were higher than those in wet season at both IT and UB sites. The days in the IT site exceeded the daily WHO guideline of NO2 was 34.8–44.0%, while those in the UB site were 10.8–34.5%. The hazard quotient (HQ) values for a non-carcinogenic risk to human health caused by NO2 exposure indicated a medium hazard (HQ = 1.1–10.0), whereas the HQ values for SO2 and O3 indicated a negligible risk (HQ < 1.0). The total non-carcinogenic risk (HI) from air pollutants contamination being exposed concurrently, on the other hand, indicated risk levels that are likely to affect health, particularly children. Therefore, environmental management and protection in Rayong city are important for people who live in industrial and urban areas, especially during dry period.

Objective: There are few studies on fractional exhaled nitric oxide (FeNO) among children in subtropical areas. We studied associations between FeNO and respiratory symptoms, reported diagnosed allergies and indoor and outdoor environmental factors in first grade junior high school students (N = 270) in upper northern Thailand. Methods: Data on demographics, health and home environment were collected by a questionnaire distributed in dry season (February-March 2018). FeNO was measured when the research team visited the school. Daily outdoor pollution data (PM10 and ozone) were collected from the nearest monitoring station 3 days (lag 3) and 7 days (lag 7) before the FeNO measurements. Two-level (student, school) linear mixed models were used to analyze associations, adjusting for gender and family education level. Results: In total, 29.6% had elevated FeNO level (>20 ppb) and 7.8% reported any allergy diagnosed by a doctor. Male gender (p = 0.02), diagnosed allergy (p = 0.001), especially to cat (p = 0.001) and house dust mite (HDM) allergies (p = 0.001) were associated with FeNO. Eye symptoms (p = 0.01), rhinitis symptoms (p = 0.03) and dyspnea (p = 0.05) in the last 3 days were associated with FeNO. Household indoor mold (p = 0.03), gas cooking (p = 0.03) and PM10 (lag 3 and lag 7) were negatively (protective) associated with FeNO. Conclusions: Diagnosed allergy, especially to cat and HDM, can be associated with increased FeNO. Indoor mold and gas cooking can be associated with lower FeNO. Ocular, nasal and dyspnea symptoms reported by students in dry season in northern Thailand can be associated with FeNO, a biomarker of Th2 driven airway inflammation.

This study aimed to identify the contributing sources of PM2.5 in Chiang Mai Province during February to April 2016. We therefore investigated the chemical compositions of PM2.5 at two different sites. An urban site is in Chiang Mai University (CMU) while a rural site is in Mae Chaem (MC) District where frequent intensive biomass burning was reported. Thirty pair samples of 24-h PM2.5 were analyzed for organic carbon (OC), elemental carbon (EC), levoglucosan and stable carbon isotope (δ13C). The mean concentrations (Mean ± SD) of PM2.5, OC and EC at the CMU vs MC sites were not significant different (P >0.05) including 44.5 ± 32.1 vs 40.5 ± 21.2 µg/m3; 14.9 ± 12.5 vs 14.8 ± 10.0 µg/m3; and 1.80 ± 1.60 vs 1.62 ± 0.80 µg/m3, respectively. Levoglucosan concentrations, a tracer of biomass burning from both sites were not significant different (P >0.05) and the mean ± SD concentrations at CMU vs MC sites were 0.46 ± 0.56 µg/m3 vs 0.55 ± 0.67 µg/m3, respectively. Meanwhile, the mean values of δ13C in total carbon (TC) at CMU vs MC sites were -27.9 ± 0.68 vs -27.6 ± 0.60‰, respectively which major data (n = 48, 85.4%) fell within the ranged of C3-type plants and minor data (n = 48, 14.6%) in C3-type plants and motor vehicle sources. This finding corresponds to the vast biomass burning area from satellite data. Forest plants in northern Thailand, Chiang Mai particular are mostly mixed deciduous forest i.e. C3-type plants which falling leaves in dry season and easily causing fire. The results of this study therefore strongly suggest that the burning of C3-type forest plants attribute to airborne PM2.5 pollutants in Chiang Mai Province. Keywords: Air pollution, Biomass burning, C3-type plants, Levoglucosan, Stable carbon isotope

The concentrations of PM2.5 and metallic elements were measured in Rayong during the dry season (November 2021 to April 2022). The mean PM2.5 concentration was 20.1 ± 10.9 µg/m3 (4.9–52.3 µg/m3). Moreover, the percentages of days when those PM2.5 concentrations exceeded the daily WHO and US-EPA NAAQS limit were 56.8% and 10.2%, respectively. However, the levels did not exceed 50 µg/m3, which is the limit of the 24 h standard defined by the PCD in Thailand. The dominant heavy metals and elements in PM2.5 samples were Cr, Cu, Fe, Mn, Pb, V, and Zn, which constituted 70%. In Rayong, the PCA results showed that industrial emissions (Cd, Cu, Fe, Mn, Pb, and Zn) and traffic emissions (As, Cd, Cr, K, and Ni) were the major sources of PM2.5-bound heavy metals. Exposure to toxic metals in PM2.5 through the inhalation pathway in Rayong obviously entails a high potential risk of cancer (>10−4) based on the total lung cancer risk (TCRinh). It was found that the TCRinh values of Cr for combined age groups were higher than 10−6, which implies a high cancer risk in Rayong.

Ammonia (NH3) is an important agent involved in atmospheric chemistry and nitrogen cycling. Current estimates of NH3 emissions from biomass burning (BB) differ by more than a factor of 2, impeding a reliable assessment of their environmental consequences. Combining highresolution satellite observations of NH3 columns with network measurements of the concentration and stable nitrogen isotope composition (δ15N) of NH3, we present coherent estimates of the amount of NH3 derived from BB in the heartland of Southeast Asia, a tropical monsoon environment. Our results reveal a strong variability in atmospheric NH3 levels in time and space across different landscapes. All of the evidence on hand suggests that anthropogenic activities are the most important modulating control with respect to the observed patterns of NH3 distribution in the study area. Nisotope balance considerations revealed that during the intensive fire period, the atmospheric input from BB accounts for no more than 21 ± 5 % (1s) of the ambient NH3, even at the rural sites and in the proximity of burning areas. Our N-isotope-based assessment of the variation in the relative contribution of BB-derived NH3 is further validated independently through the measurements of particulate KC, a chemical tracer of BB. Our findings underscore that BB-induced NH3 emissions in tropical monsoon environments can be much lower than previously anticipated, with important implications for future modeling studies to better constrain the climate and air quality effects of wildfires., SCOPUS: ar.j, info:eu-repo/semantics/published

We performed a repeated questionnaire study on home environment and health (six medical symptoms) in 1159 junior high school students (age 12.8 ± 0.7 years) in upper northern Thailand in wet and dry seasons. Data on outdoor temperature, relative humidity (RH), and air pollution were collected from nearest monitoring station. Odds ratios (OR) were calculated by multi-level logistic regression. Most common symptoms were rhinitis (62.5%), headache (49.8%), throat (42.8%), and ocular symptoms (42.5%). Ocular symptoms were more common at lower RH and rhinitis more common in dry season. Water leakage (28.2%), indoor mold (7.1%), mold odor (4.1%), and windowpane condensation (13.6%) were associated with all six symptoms (ORs: 1.3-3.5). Other risk factors included cat keeping, environmental tobacco smoke (ETS), other odor than mold odor, gas cooking, and cooking with biomass fire. Biomass burning inside and outside the home for other reasons than cooking was associated with all six symptoms (ORs: 1.5-2.6). Associations between home environment exposure and rhinitis were stronger in wet season. In conclusion, dampness-related exposure, windowpane condensation, cat keeping, ETS, gas cooking, and biomass burning can impair adolescent health in upper northern Thailand. In subtropical areas, environmental health effects should be investigated in wet and dry seasons.

Multiple pesticides are used in vegetable and fruit cultivation worldwide, including in Thailand. A survey series on pesticide residues in vegetable and fruit samples sourced from markets in urban and rural areas of upper northern Thailand during 2007–2013. Sixteen different vegetables (n = 412) and 11 different fruits (n = 301) were analyzed for 43 pesticide residues including 20 organophosphates (OP), 6 synthetic pyrethroids, 12 carbamates, 2 abamectins, imidacloprid, dithiocarbamates, and carbendazim. Out of the 412 vegetable samples, 235 (57%) had pesticide residues and 185 (45%) had pesticide residues that exceeded the maximum residue limits (MRLs). For the fruit samples, 245 (81%) of the 301 samples had pesticide residues and 165 (55%) had pesticide residues that exceeded the MRLs. The vegetable and the fruit samples had multiple synthetic pyrethroid residues and higher levels of residues than OP and other pesticides. Among the OP pesticides, chlorpyrifos was the most frequently detected pesticide. Residue detection in the rural samples was higher than that in the urban samples. The present study found very high numbers of samples to be above the MRLs: 45% of the vegetable samples and 55% of the fruit samples. Therefore, multi-residue methods are proposed as a regular monitoring system to ensure coverage of the multiple pesticides that are commonly used in agriculture and secure the national food safety policy.

Smoke haze from biomass burning has been a crisis in northern Thailand. There have been plenty of reports on ambient PM 10 and PAHs but not on individual exposure during smoke haze episodes. The present study aimed to quantify urinary 1-OHP, a predominant biomarker of PAH exposure, among 200 rural school children in Om Koi and Mae Chaem districts, Chiang Mai Province, northern Thailand. Questionnaires for information regarding environmental exposure and health diaries were given out. Urine samples were collected to measure 1-OHP using high-performance liquid chromatography-fluorescence detection, HPLC-FLD (HP1100 Series/HP1046A). Proficiency testing materials were obtained from the participation of German External Quality Assessment Scheme (G-EQUAS, Erlangen, Germany) and analyzed as part of the method validation of our urinary 1-OHP method. The median urinary 1-OHP level in the school children from Om Koi District was significantly higher than that in Mae Chaem District (0.70 versus 0.24 μmol/mol cr). The present study showed the evidence that urinary 1-OHP level among school children from the selected study sites during haze episode in northern Thailand is higher than those reported in other region of Thailand and other countries.

This study investigates the chemical components of biomass burning (BB) aerosols obtained from Doi Ang Khang (DAK; near BB source) and Chiang Mai University (CMU; an urban location) over northern Southeast Asia in dry season (March to mid-April) 2014. PM_(2.5) (particulate matter with an aerodynamic diameter less than or equal to 2.5 μm) samples were collected over a 24-h sampling period as a part of the Seven South East Asian Studies (7-SEAS)/BASELInE (BB Aerosols & Stratocumulus Environment: Lifecycles & Interactions Experiment) campaign. The collected aerosols were analyzed for mass concentrations of ions, metals and levoglucosan. The influence of air mass movements on aerosol species was also analyzed. The average PM_(2.5) mass concentrations at DAK (80.8-83.3 μg m^(-3)) and CMU (90.7-93.1 μg m^(-3)) were not significantly different (p ＞ 0.05) and well correlated (r = 0.8), and likely originated from similar source origins. The number of fire hotspots was particularly high during 20-21 March (greater than 200) and, consequently, peaks of PM_(2.5) were recorded at both sites. The most abundant elements at both sampling sites were K (49-50% of total elements), Al (26-31%), Mg (16%) and Zn (4-7%), whereas SO_4^(2-) (30-38% of total ions), NO_3^- (13-20%), Na^+ (16-20%) and NH_4^+ (14-15%) were the most abundant ions. Concentrations of levoglucosan and K^+ (BB tracers) were well correlated (r = 0.5 for CMU and 0.7 for DAK) confirming that the PM_(2.5) detected in these areas were mainly influenced by BB activity. Principal component analysis (PCA) revealed that BB, road traffic, agricultural activity and soil re-suspension were plausible sources of PM_(2.5) over the study locations. Apart from local sources, the influence of long-range transport was also investigated by way of three-day backward trajectory analysis.

Southeast Asia is one of the major regions of biomass burning in the world. To investigate the light absorption properties of carbonaceous aerosols produced from biomass burning, mass concentrations of PM2.5 and its major chemical compositions were obtained by filter sampling, and aerosol absorption coefficient (bap) at 370 nm (bap-370nm) and at 880 nm (bap-880nm) were synchronously determined for the sampled filters using a transmissometer in urban Chiang Mai of Northern Thailand during the dry season in 2019. On campaign average, the reconstructed PM2.5 mass from the measured chemical components accounted for 99% of the measured PM2.5 mass, in which organic matters (OM) accounted for 64 ± 10%. Hardwood burning was identified as the dominant source of carbonaceous aerosols. The measured aerosol absorption Angstrom exponent (AAE) at 370–880 nm (AAE370–880nm) was 1.71 ± 0.24. Mass absorption efficiency (MAE) of elemental carbon (EC) and organic carbon (OC) was estimated using a multiple linear regression model between bap and mass concentrations of EC and OC, resulting in campaign-average values of 8.11 m2 g−1 and 0.24 m2 g−1 at 880 nm and 21.06 m2 g−1 and 2.57 m2 g−1 at 370 nm, respectively, which were evidently larger than those in other cities worldwide. The contributions of EC to bap in 370–880 nm spectrum region ranged from 49 ± 5% to 79 ± 3%, and those of OC ranged from 51 ± 5% to 21 ± 3%. Results from this study suggested a potentially significant impact of carbonaceous aerosols on direct radiative forcings in the dry season over Southeast Asia and downwind regions.