94 results on '"Savić, Veljko"'
Search Results
2. The crystal growth of NASICON phase from the lithium germanium phosphate glass
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Matijašević Srđan D., Topalović Vladimir S., Savić Veljko V., Labus Nebojša J., Nikolić Jelena D., Zildžović Snežana N., and Grujić Snežana R.
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lithium germanium-phosphate glass ,crystal growth ,sem ,Chemical technology ,TP1-1185 - Abstract
The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined experimentally and theoretically.
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- 2023
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3. The analysis of the nucleation process of the lithium germanium phosphate glass
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Matijašević Srđan D., Grujić Snežana R., Nikolić Jelena D., Topalović Vladimir S., Savić Veljko V., Zildžović Snežana N., and Labus Nebojša J.
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lithium germanium-phosphate glass ,nucleation ,dta ,sem ,Chemical technology ,TP1-1185 - Abstract
The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.
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- 2022
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4. Crystal growth of La2SrB10O19 from undercooled melt
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Smiljanić, Sonja V., Grujić, Snežana R., Matijašević, Srđan, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, and Popović, Daniela Ž.
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- 2021
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5. Sintering, crystallization and foaming of La2O3•SrO•5B2O3 glass powders: effect of the holding time
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Karamanov, Alexander, Smiljanić, Sonja, Karamanova, Emilia, Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, and Grujić, Snežana
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- 2020
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6. The thermophysical properties of primary phase in lithium germanium phosphate glass
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Matijašević Srđan D., Topalović Vladimir S., Grujić Snežana R., Savić Veljko V., Nikolić Jelena D., Labus Nebojša J., and Zildžović Snežana N.
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lithium germanium-phosphate glass ,dta ,dilatation ,dsc. ,Chemical technology ,TP1-1185 - Abstract
The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the Vogel-Fulcher-Tammann (VFT) equation
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- 2021
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7. The effect of sintering temperature on cavitation erosion in glass–ceramics based on coal fly ash
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Savić, Veljko, Dojčinović, Marina, Topalović, Vladimir, Cvijović-Alagić, Ivana, Stojanović, Jovica, Matijašević, Srđan, Grujić, Snežana, Savić, Veljko, Dojčinović, Marina, Topalović, Vladimir, Cvijović-Alagić, Ivana, Stojanović, Jovica, Matijašević, Srđan, and Grujić, Snežana
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The incombustible portion of coal that remains after burning is known as bottom or fly ash, and it has a detrimental influence on the environment. One of the possible alternatives for reducing the amount of ash deposited in landfills might be the production of useful glass–ceramic from vitrified fly ash. Glass–ceramic was synthesized using fly ash from the thermal power plant "Nikola Tesla" and fluxing additives. Sinter crystallization of the parent glass resulted in glass ceramics. The glass was created by melting a combination of coal fly ash (CFA), Na2CO3, and CaCO3 at T = 1500 °C and quenching the melt in the air. Glass powders were sintered at temperatures 850 and 900 °C. The resulting glass–ceramics were characterized microstructurally, physically, and mechanically. The cavitation erosion of samples was evaluated. The cavitation rate was 0.015 mg/min for the sample sintered at 850 °C and 0.0053 mg/min for the sample sintered at 900 °C. The leaching of heavy metals in glass–ceramic samples was determined using Toxicity Characteristic Leaching Procedure. A low concentration of heavy metals in the leaching solution showed that heavy metals were successfully incorporated in the glass matrix and that obtained glass–ceramics are ecologically safe for usage. Both samples exhibit good resistance to cavitation erosion, suggesting their potential as possible replacements for structural ceramics commonly employed components of hydraulic machinery.
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- 2024
8. Characterisation of strontium-substituted hydroxyapatite as potential biomedical material
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Đošić, Marija, Nikolić, Jelena, Stojanović, Jovica, Vuković, Nikola, Marković, Marija, Savić, Veljko, Topalović, Vladimir, Đošić, Marija, Nikolić, Jelena, Stojanović, Jovica, Vuković, Nikola, Marković, Marija, Savić, Veljko, and Topalović, Vladimir
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INTRODUCTION: Owing to its similarity to the inorganic part of the natural bone, excellent bioactivity, biocompatibility, and ability to stimulate the osteoconductive process, synthetic hydroxyapatite (HAP) is very often the material of choice for biomedical applications. Diverse ions can be found as substitutes within natural bone structures, each playing a distinct and crucial role in the physiological processes governing the lifecycle of bones [1]. Among them, strontium ion has a very important role for the acceleration of osteogenesis and the inhibition of osteoclasts activity [2]. Current research aims to provide physico-chemical characterization of synthesized HAP and strontium substituted HAP (Sr-HAP) powders obtained by varying strontium concentration (10, 20 and 40 mol.%) in the starting solutions. EXPERIMENTAL: HAP powder was synthesized by wet chemical precipitation, using aqueous solutions of Ca(NO3)2 4H2O (Merck, p.a.) and (NH4)2HPO4 (Sigma-Aldrich, ≥99 %). By adding NH4OH (CENTROHEM, p.a.), pH value was adjusted to 10. The obtained precipitate was heated up to 90 °C. The same procedure was followed for Sr-HAP powder syntheses, by adding Sr(NO3)2 (Sigma-Aldrich ≥99.0 %) and maintaining the (Ca + Sr)/P ratio at 1.67 in the mixed Ca2+/Sr2+ solution. Synthesized powders were characterised by FTIR spectroscopy (Nicolet IS-10, Thermo Fisher Scientific), XRD analysis (Philips PW 1710, Philips, The Netherlands), TG analysis (Netzsch STA 449 F5 Jupiter instrument), and FE-SEM analysis (JSM-7001F, JEOL Ltd, Japan). RESULTS AND DISCUSSION: FTIR spectra revealed the presence of carbonate-substituted hydroxyapatite in both pure and Sr-substituted HAP powders. The powders showed a granular, homogeneous morphology without the Sr separation. XRD analysis revealed that the amount of incorporated Sr in the HAP structure increased with increased Sr concentration in the starting solutions. Thermal stability of the Sr-HAP powders decreased with increased Sr concentration.
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- 2024
9. Chemical durability evaluation of sintered fly ash based chemical durability evaluation of sintered fly ash based glass
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Savić, Veljko, Nikolić, Jelena, Topalović, Vladimir, Đošić, Marija, Marković, Marija, Matijašević, Srđan, Grujić, Snežana, Savić, Veljko, Nikolić, Jelena, Topalović, Vladimir, Đošić, Marija, Marković, Marija, Matijašević, Srđan, and Grujić, Snežana
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In order to preserve the environment, the strategy of economic development in the world is based on the use of waste as a raw material for obtaining new products. Waste can be used in the same industry in which it was produced or in other industries. This paper presents an examination of the chemical durability of glass-ceramics obtained by sintering fly ash glass at characteristic temperatures (850 and 900°C). The chemical stability of the glass-ceramics was tested in three solvents, distilled water, HCl (0.01 mol/dm3) and NaOH (0.01 mol/dm3). The results indicate that the chemical durability of glass sintered at 900°C is slightly lower than glass-ceramic sintered at 850°C. The higher chemical durability of the glass-ceramic sintered at 850°C can be attributed to the presence of wollastonite, which was not detected in the glass-ceramic sintered at 900°C. The obtained glassceramics has a high chemical durability, with mass changes below 1%. FTIR and SEM analysis of the samples after dissolution revealed that there was no disruption of the structure.
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- 2024
10. Effect of phosphate glass and biochar on rose growth chemical durability evaluation of sintered fly ash based glass
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Topalović, Vladimir, Antanasković, Anja, Savić, Veljko, Đošić, Marija, Lopičić, Zorica, Vujošević, Ana, Nikolić, Jelena, Topalović, Vladimir, Antanasković, Anja, Savić, Veljko, Đošić, Marija, Lopičić, Zorica, Vujošević, Ana, and Nikolić, Jelena
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Fertilizers with controlled release (CRF) are materials that have nutrients for the plant and can be dissolved after a certain time from the moment they are introduced into the soil. They are available to the plant much longer than conventional fertilizers. Phosphate glasses (PG) are quite interesting for controlled release systems due to their low chemical durability. Although pure PG have highly hygroscopic nature, their chemical durability can be compositionally controlled [1,2]. Biochar is the product of biomass pyrolysis, a process where organic substances are broken down at temperatures ranging from 350 °C to 900 °C in a reduced oxygen thermal process. Biochar applications have an effect on soil improvement, waste management, climate change mitigation and energy, and consequently might have social and economic benefits. Biochar improves soil physiology and increases productivity, assisting with crop residue management [3,4]. This paper presents the results of testing the effect of PG and biochar from plum stones (PSB) on rose plantings (sort Lavaglut). The control sample were rose plantings without fertilizer addition. The phosphate glass (45.4P2O5•25.6K2O•14.5CaO•3.1SiO2•9.3MgO•1.2ZnO•0.9MnO2) was prepared from reagent grade raw materials. The glass mixture was melted at T = 1230 °C for t = 1h in an open porcelaine crucible in an electric furnace and the melt was quenched on a steel plate. Phosphate glass and biochar were added in a variety of dosages. The application of 1 g of phosphate glass and the application of 10 g of PSB had the greatest effect on increasing the average height of plants. The application of PG and biochar had no significant effect on the average number of formed branches in the crown, as well as on the average number of newly formed branches. Higher doses of PG (3 g) and PSB (10 g) have a favorable effect on increasing the average number of formed flowers. The chemical analysis of the plant material at the end of the vegetative cycle de
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- 2024
11. Structure and microstructure characterization of the La2SrB10O19 glass-ceramics
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Stojanović Jovica N., Smiljanić Sonja V., Grujić Snežana R., Vulić Predrag J., Matijašević Srđan D., Nikolić Jelena D., and Savić Veljko
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glass-ceramics ,sintering ,x-ray diffraction ,crystal structure and microstructure ,rietveld refinement ,Chemical technology ,TP1-1185 - Abstract
The crystal structure of new lanthanum strontium borate glass-ceramics was refined by the Rietveld method. The results showed that La2SrB10O19 has the monoclinic crystal structure, space group C2 (No. 5) with a = 11.1170(6), b = 6.5667(3), c = 9.2363(3) Å, β = 91.481°, V = 674.04(7) Å3, two formula units per unit-cell, and density 3.830 g cm−3. The main building units of the crystal structure are BO4 tetrahedra and BO3 triangles. Clusters composed of [B5O12] form an infinite double layer running perpendicular to the c-axis. Lanthanum atoms, situated in [B5O12]n layers, are coordinated with 10 oxygen atom in a form of LaO10 polyhedra, while Sr atoms, located between [B5O12]n layers, are coordinated with 8 oxygen atoms in a form of SrO8 polyhedra. Microstructural measurements contain both crystallite domain sizes and microstrain calculations obtained by the Warren-Averbach and the simplified integral-breadth methods. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. OI172004 and Grant no. TR34001]
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- 2019
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12. Non-isothermal crystallization of lithium germanophosphate glass studied by different kinetic methods
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Matijašević Srđan D., Grujić Snežana R., Topalović Vladimir S., Nikolić Jelena D., Smiljanić Sonja V., Labus Nebojša J., and Savić Veljko V.
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lithium germanophosphate glass ,crystallization kinetics ,DTA ,nucleation ,Chemical technology ,TP1-1185 - Abstract
Crystallization kinetics of 22.5Li2O•10Al2O3•30GeO2•37.5P2O5 (mol%) glass was studied under non-isothermal condition using the differential thermal analysis (DTA). The study was performed by using the first crystallization peak temperature (Tp1) which belongs to the precipitation of LiGe2(PO4)3 phase in the glass. The activation energy of glass crystallization (Ea) was determined using different isokinetic methods. The dependence of Ea on the degree of glass-crystal transformation (α) was studied using model-free isoconversional linear integral KAS (Kissinger-Akahira-Sunose) and FWO (Flynn-Wall-Ozawa) methods. It was shown that the Ea varies with α and hence with temperature and consequently the glass/crystal transformation can be described as a complex process involving different mechanisms of nucleation and growth. [Project of the Serbian Ministry of Education, Science and Technological Development, Grant no. 34001 and Grant no. 172004]
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- 2018
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13. Crystallization characteristics of bioactive polyphosphate glasses
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Topalović, Vladimir, Matijašević, Srđan, Savić, Veljko, Nikolić, Jelena, Stojanović, Jovica, Zildžović, Snežana, Grujić, Snežana, Topalović, Vladimir, Matijašević, Srđan, Savić, Veljko, Nikolić, Jelena, Stojanović, Jovica, Zildžović, Snežana, and Grujić, Snežana
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- 2023
14. The crystal growth of NASICON phase from the lithium germanium phosphate glass
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Matijašević, Srđan D., Topalović, Vladimir S., Savić, Veljko V., Labus, Nebojša J., Nikolić, Jelena D., Zildžović, Snežana N., Grujić, Snežana R., Matijašević, Srđan D., Topalović, Vladimir S., Savić, Veljko V., Labus, Nebojša J., Nikolić, Jelena D., Zildžović, Snežana N., and Grujić, Snežana R.
- Abstract
The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined experimentally and theoretically.
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- 2023
15. Foam glasses made from waste flat glasses and sugar beet factory lime with the addition of borax and water glass
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Savić, Veljko, Grujić, Snežana, Savić, Veljko, and Grujić, Snežana
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Foam glass is a lightweight and high-strength material that can be used for thermal and acoustic insulation. Foam glass with suitable properties for use as an insulating material was prepared using waste flat glass, a glass waste not normally used for the production of glass foam, and sugar beet factory lime (S), a CaCO3-rich waste, as a novel foaming agent.Three mixtures were prepared: Glass powder mixed with S (FG-S), glass powder mixed with S and borax (FG-S-B), and glass powder mixed with S and water glass (FG-S-WG). The mixtures were homogenized, pressed into pellets in a hydraulic press, and foamed at 800 °C for 30 min. The prepared samples were characterized mechanically, thermally, and microstructurally. All samples exhibit very low crystallinity. FG-B has the lowest total porosity but much higher compressive strength than FG-S and FG-S-WG. In addition to the total porosity, the pore size distribution of the samples also has a strong influence on the compressive strength. FG-S-B has smaller pores compared to FG-S and FG-S-WG, where the intense foaming of S and water glass leads to the rupture of the pore walls and their coalescence. The thermal conductivity follows the same trends as the total porosity. FG-S and FG-S- WG have a thermal conductivity of 0.044 W/m.K and FG-B has 0.059 W/m.K. All samples have good thermal properties as insulators, but FG-S-WG has poor mechanical properties.
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- 2023
16. The Crystal Growth of NASICON Phase from the Lithium Germanium Phosphate Glass
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Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojša, Nikolić, Jelena, Zildžović, Snežana, Grujić, Snežana, Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojša, Nikolić, Jelena, Zildžović, Snežana, and Grujić, Snežana
- Abstract
The crystal growth rate of LiGe2(PO4)3 phase from lithium germanium-phosphate glass was studied. The glass have been homogenized using the previously established temperature-time conditions, which make it possible to remove volatile substances from the glass melt. The atomic absorption spectrophotometry (AAS) was used to determine the chemical content of the obtained glass and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth. The crystal growth rates were determined experimentally and theoretically.
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- 2023
17. Recycling of glass waste into foam glass: A review
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Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, Grujić, Snežana, Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, and Grujić, Snežana
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Waste glass can be transformed into a foam by addition of suitable substance (foaming agent) which generated gaseous products by decomposition or reaction at temperatures above its softening temperature (corresponding to a viscosity of 106.6 Pas). This paper provides a concise overview of the latest research in the field of improving the glass foam production process. Some of the possibilities for reducing the environmental impact of glass foam production are also presented. Some of the new production techniques, new foaming agents as well as the possibility of including other solid waste in the composition of glass foams are presented. At the end, the glass foam produced in the Laboratory for glass and ceramics, Institute for Technology of Nuclear and other Mineral Raw Materials, was shown.
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- 2023
18. Nanocrystallization of potassium niobium germanate glasses
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Matijašević, Srđan, Grujić, Snežana, Topalović, Vladimir, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, Zildžović, Snežana, Matijašević, Srđan, Grujić, Snežana, Topalović, Vladimir, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, and Zildžović, Snežana
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This paper presents the effect of K2O content on phase composition of the nanocrystallized niobium germanate glasses. It was shown that the exothermal peak temperature, Tp, shifted toward the higher temperatures with increasing content of K2O. Such increase of K2O content causes a decrease of GeO2 content in the primary phases. The crystals below 100 nm were detected in the samples.
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- 2023
19. Dissolution of polyphosphate glass: Impact of pH on diffusion coefficients of modifying cations at low temperatures
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Nikolić, Jelena, Topalović, Vladimir, Đošić, Marija, Savić, Veljko, Obradović, Milena, Matijašević, Srđan, Grujić, Snežana, Nikolić, Jelena, Topalović, Vladimir, Đošić, Marija, Savić, Veljko, Obradović, Milena, Matijašević, Srđan, and Grujić, Snežana
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This paper shows the dissolution behavior of polyphosphate glass in demineralized water and 2% citric acid solution at temperatures: 15, 20, 30, 37 and 50 °C. The influence of the solvent type on the diffusion coefficients of the modifying cations, under static conditions, is also presented. The diffusion coefficients, determined from concentration profiles of the modifying cations, are calculated to be in the range of 0.27 to 350x10-14 m2/h for dissolution in demineralized water, and in the range of 3.6 to 148x10-12 m2/h for the dissolution in 2% citric acid solution. The values of activation energy of cations diffusion in demineralized water are in the range from 68.32 to 105.41 kJ/mol, while for 2% citric acid solution they are in the range from 39.28 to 55.34 kJ/mol.
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- 2023
20. Thermal characterization of bioactive polyphosphate glass with strontium addition
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Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, Đošić, Marija, Grujić, sn, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, Đošić, Marija, and Grujić, sn
- Abstract
Polyphosphate glasses are a class of bioactive glasses that have gained significant attention in recent years due to their unique properties and potential applications in various fields, particularly in the area of biomedical engineering. These glasses exhibit excellent biocompatibility, which is a crucial requirement for biomaterials. Furthermore, their dissolution and degradation rates can be tailored by modifying their composition, allowing for control over their bioactivity and biodegradability. Polyphosphate glasses also have the ability to form a hydroxyapatite-like layer on their surface when in contact with biological fluids, which facilitates their integration with surrounding tissues. The unique properties of polyphosphate glasses make them promising candidates for various biomedical applications, including bone tissue engineering, drug delivery, and wound healing. This paper presents the thermal characterization of two bioactive polyphosphate glass compositions with the addition of strontium, to investigate the sintering and crystallization processes. The samples were synthesized using the melt-quenching method and then sintered at various temperatures. Differential scanning calorimetry (DSC) and X-ray diffraction (XRD) were used to analyze the thermal behavior and crystalline phases formed during sintering. Our results showed that sintering and crystallization are separate processes for both compositions. The addition of strontium to the glass improved its sintering behavior, resulting in a denser glass structure. Moreover, strontium incorporation did not affect the formation of the crystalline phase during sintering. These findings provide useful insights into the design and development of bioactive polyphosphate glass compositions for bone tissue engineering applications.
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- 2023
21. Recycling of flat glass for glass foam production
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Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Đošić, Marija, Matijašević, Srđan, Grujić, Snežana, Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Đošić, Marija, Matijašević, Srđan, and Grujić, Snežana
- Abstract
Open loop glass recycling is a process where the glass is recycled into a new product. Glass recycling helps reduce landfill waste. Glass takes up significant space in landfills and does not decompose. In many countries, landfills are filling up faster than we can create new ones. Recycling glass reduces the volume of waste, and increases the lifespan of landfills. One of examples of open loop recycling of glass is glass foam produciton. Glass foam production is a process that involves the creation of a light-weight glass material with a foam-like consistency. This type of glass is made by mixing a foaming agent with glass powder and heating to temperatures where decomposition of a foaming agent and sintering of glass happens. This results in the creation of a material that is light, strong, and has thermally-insulating properties. Milled flat glass was mixed with sugar beet factory lime, a CaCO3 – rich waste wich has role of a foaming agent, in order to enter 5% CaCO3 in mixture and pressed at 20 MPa in hydraulic press. Raw pellets were sintered at 800 °C for 30 min. In obtained glass foam phase composition, pore size distribution, compressive strength and thermal conducitivity were determined. Glass foam is emerging as a flexible, cost-effective, and sustainable material that can be utilized in numerous applications to promote sustainable development. Its features such as high insulation capacity, lightweight, and durability make it an ideal material for a wide range of industries.
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- 2023
22. Dobijanje poroznih 3D bioaktivnih staklokeramičkih nosača/Fabrication of porous 3D bioactive phosphate glass-ceramic scaffolds
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Topalović, Vladimir, Savić, Veljko, Nikolić, Jelena, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, Grujić, Snežana, Topalović, Vladimir, Savić, Veljko, Nikolić, Jelena, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, and Grujić, Snežana
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- 2022
23. Phophate glassy fertilizers
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Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Savić, Veljko, Đošić, Marija, Vujošević, Ana, Grujić, Snežana, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Savić, Veljko, Đošić, Marija, Vujošević, Ana, and Grujić, Snežana
- Abstract
The main goal of agricultural production should be the production of a sufficient amount of agricultural products with the least possible impact on the environment. In traditional agricultural production, in order to obtain a satisfactory yield, artificial fertilizers are used, which have multiple negative impacts on the environment. Glassy fertilizers are a type of fertilizer that, at least according to previous research, do not have a negative impact on the environment and the same time the use of these fertilizers yields not less than when using traditional fertilizers. Glassy fertilizers are fertilizers with controlled dissolution, they do not pollute groundwater or surface water, the pH of the soil does not change with their use, by changing the composition they can adapt to the requirements of each crop individually, etc. The paper presents three phosphate glassy fertilizers of different chemical composition, obtained at the Center for Inorganic Technologies, ITNMS. The method of obtaining of glassy fertilizers, their dissolution rates in a medium that simulates soil conditions, the changes in pH values of solutions for different dissolution times and the effect of temperature on dissolution rates are shown. Also, the results of the influence of glass fertilizers on plant cultures in real conditions are presented.
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- 2022
24. Ispitivanje uticaja pH i granulacije na početnu brzinu rastvaranja fosfatnog stakla/ Investigation of the influence of pH and granulation on the initial dissolution rate of phosphate glass
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Nikolić, Jelena, Topalović, Vladimir, Matijašević, Srđan, Savić, Veljko, Đošić, Marija, Zildžović, Snežana, Grujić, Snežana, Nikolić, Jelena, Topalović, Vladimir, Matijašević, Srđan, Savić, Veljko, Đošić, Marija, Zildžović, Snežana, and Grujić, Snežana
- Abstract
Fosfatna stakla imaju jedinstveno svojstvo da se mogu potpuno rastvoriti u vodenim rastvorima, a brzina rastvaranja može da se kontroliše. Proces rastvaranja stakla počinje razmenom katjona sa površine stakla sa protonima iz rastvora (H+ ili H3O+) i hidratacijom staklene mreže. Početna brzina rastvaranja je osnovna karakteristika rastvaranja stakla. Analiza početnih brzina rastvaranja fosfatnog stakla, koje je dobijeno topljenjem, pokazuje da su brzine značajno veće u kiseloj sredini u odnosu na brzine rastvaranja u neutralnoj. Granulacija uzorka ima veći uticaj na početne brzine u neutralnoj sredini. Granulacija uzorka ne utiče na vrednost energije aktivacija početnih brzina rastvaranja u obe sredine. U neutralnoj sredini temperatura manje utiče na hidrolizu, a više na difuziju katjona, dok je u kiseloj sredini suprotno.
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- 2022
25. Use of agricultural waste as raw materials for obtaining glass and glass-ceramics: A review
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Topalović, Vladimir, Nikolić, Jelena, Savić, Veljko, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, Grujić, Snežana, Topalović, Vladimir, Nikolić, Jelena, Savić, Veljko, Matijašević, Srđan, Đošić, Marija, Zildžović, Snežana, and Grujić, Snežana
- Abstract
Global trends are moving towards a circular economy to replace the deeply grounded one linear economics and waste management. Circular economy implies and the protection of human rights through sustainable development, global security natural resources, combating climate change, energy security, insurance sufficient amounts of food, reducing inequalities, preservation of health and a cleaner environment and the rights of future generations to resources, etc. The policy of procurement of raw materials in the circular economy is focused on the use of secondary raw materials. A big challenge for modern production is to use different types of waste to obtain new products without the use of raw materials. This kind of production requires new knowledge, adaptation of existing technologies or new technologies, new jobs, etc. Large amounts of vegetative residues are produced annually by agriculture. Agricultural waste is very often incinerated or disposed of on land and is still not used. Most of the agricultural waste ashes consist of silicon dioxide along with other oxides which may vary according to region and atmosphere of the local conditions. This paper gives an overview of the possibilities of using agricultural waste for obtaining glass and glass ceramics. Previous research has shown that various types of glass and glass-ceramics can be successfully obtained from agricultural waste, which can be used in construction, medicine, various composites, etc.
- Published
- 2022
26. The efect of La2O3 addition on the crystallization characteristics of polyphosphate glasses
- Author
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Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, Đošić, Marija, Grujić, Snežana, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Savić, Veljko, Đošić, Marija, and Grujić, Snežana
- Abstract
The purpose of this study is to investigate the influence of La2O3 addition on the crystallization characteristics of polyphosphate glasses. Differential scanning calorimetry (DSC), and X-ray diffraction (XRD) methods were used to investigate the crystallization behavior of glasses. The addition of La2O3 (1-5%), at the expense of phosphate mole fraction in polyphosphate glass, raises the characteristic temperature of glasses, and resistance to crystallization. The glasses show complex crystallization leading to the formation of several crystalline phases
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- 2022
27. Sinter-crystallization of coal fly ash based glass
- Author
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Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Zildžović, Snežana, Grujić, Snežana, Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Zildžović, Snežana, and Grujić, Snežana
- Abstract
The increasing production of coal fly ash waste from thermal power plants has compounded environmental and economical problems worldwide. In this research coal fly ash was mixed with glass cullet and CaCO3 and melted at T= 1500 °C. The glass was milled, pressed and sintered at T= 900 °C to obtain glass- ceramic. Obtained glass- ceramic was well sintered with low crystallinity. This material, produced from secondary raw materials, could find potential application in building industry as substitute for commercial wall and floor tiles.
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- 2022
28. The analysis of the crystal growth process of the lithium germanium phosphate glass
- Author
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Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojsa, Nikolić, Jelena, Zildžović, Snežana, Grujić, Snežana, Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojsa, Nikolić, Jelena, Zildžović, Snežana, and Grujić, Snežana
- Abstract
The crystal growth rate of lithium germanium-phosphate glass was studied. The glasses have been homogenized using the previously established temperature-time conditions, which make it possible to remove a volatile substances from the glass melt. The AAS was used to determine the chemical content of obtained glass, the differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth, respectively. It has been found that the experimental determined crystal growth rate has a tendency toward of exponentially increase with an increase the temperature.
- Published
- 2022
29. Complex crystallization of the potassium-niobium-germanate system
- Author
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Matijašević, Srđan, Savić, Veljko, Topalović, Vladimir, Stojanović, Jovica, Nikolić, Jelena, Zildžović, Snežana, Grujić, Snežana, Matijašević, Srđan, Savić, Veljko, Topalović, Vladimir, Stojanović, Jovica, Nikolić, Jelena, Zildžović, Snežana, and Grujić, Snežana
- Abstract
Potassium germanate glass with the molar ratio 30K2O·34Nb2O·36GeO2 have been synthesized by the standard melt-quenching method. The crystallization behavior under the non-isothermal crystallization conditions was investigated by the DTA and XRD methods. The results showed that this glass exposed a complex primary crystallization.
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- 2022
30. The Analysis of the Nucleation Process of the Lithium Germanium Phosphate Glass
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Matijašević, Srđan, Grujić, Snežana R., Nikolić, Jelena, Topalović, Vladimir, Savić, Veljko, Zildžović, Snežana, Labus, Nebojša, Matijašević, Srđan, Grujić, Snežana R., Nikolić, Jelena, Topalović, Vladimir, Savić, Veljko, Zildžović, Snežana, and Labus, Nebojša
- Abstract
The nucleation process of lithium germanium-phosphate glass was studied to determine the temperature range of nucleation and the temperature of the maximum nucleation rate. The differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the nonisothermal and isothermal process of nucleation, respectively. The crystallization process occurred at a high homogeneous nucleation rate and the spherulitic crystal growth morphology. Nanostructured samples were obtained.
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- 2022
31. The analysis of the crystal growth process of the lithium germanium phosphate glass : [invited presentation]
- Author
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Matijašević, Srđan, Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojša, Nikolić, Jelena D., Zildžović, Snežana, Grujić, Snežana, Matijašević, Srđan, Matijašević, Srđan, Topalović, Vladimir, Savić, Veljko, Labus, Nebojša, Nikolić, Jelena D., Zildžović, Snežana, and Grujić, Snežana
- Abstract
The crystal growth rate of lithium germanium-phosphate glass was studied. The glasses have been homogenized using the previously established temperature-time conditions, which make it possible to remove a volatile substances from the glass melt. The AAS was used to determine the chemical content of obtained glass, the differential thermal analysis (DTA), and scanning electron microscope (SEM) were used to reveal the isothermal process of crystal growth, respectively. It has been found that the experimental determined crystal growth rate has a tendency toward of exponentially increase with an increase the temperature.
- Published
- 2022
32. The influence of the particle size on crystallization of glass powders from the system Li2O-Al2O3-GeO2-P2O5
- Author
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Topalović, Vladimir, Matijašević, Srđan, Grujić, Snežana, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, Zildžović, Snežana, Topalović, Vladimir, Matijašević, Srđan, Grujić, Snežana, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, and Zildžović, Snežana
- Published
- 2021
33. The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass
- Author
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Matijašević, Srdjan D., Topalović, Vladimir S., Grujić, Snežana, Savić, Veljko V., Nikolić, Jelena D., Labus, Nebojsa J., Zildzović, Snezana N., Matijašević, Srdjan D., Topalović, Vladimir S., Grujić, Snežana, Savić, Veljko V., Nikolić, Jelena D., Labus, Nebojsa J., and Zildzović, Snezana N.
- Abstract
The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.
- Published
- 2021
34. Primena ultra-fosfatnog stakla za ishranu biljaka
- Author
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Nikolić, Jelena, Grujić, Snežana, Matijašević, Srđan, Smiljanić, Sonja, Savić, Veljko, Topalović, Vladimir, Vujošević, Ana, Popović, Daniela, Nikolić, Jelena, Grujić, Snežana, Matijašević, Srđan, Smiljanić, Sonja, Savić, Veljko, Topalović, Vladimir, Vujošević, Ana, and Popović, Daniela
- Published
- 2021
35. Reactivity of polyphosphate glass in different medium
- Author
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Topalović, Vladimir, Nikolić, Jelena, Savić, Veljko, Matijašević, Srđan, Đošić, Marija, Smiljanić, Sonja, Grujić, Snežana, Topalović, Vladimir, Nikolić, Jelena, Savić, Veljko, Matijašević, Srđan, Đošić, Marija, Smiljanić, Sonja, and Grujić, Snežana
- Abstract
Information about the dissolution process and ion release of phosphate glasses in different environments is important for a wide range of engineering applications, from biomaterial design to environmental technologies. The dissolution of glass is a complex phenomenon and the kinetics of this process depend on the glass properties (composition, structure, surface condition, etc.) and environment (the type of solvent, leaching solution volume, pH, temperature, etc.). The dissolution behavior of glass is determined by the reactions of the glass network and the release of different ions to the solution. Surface conditions and layer formation, saturation effects, and solution chemistry must also be taken into account when describing the dissolution processes. Mechanism of chemical reactivity of a polyphosphate glass (45P2O5·3SiO2·25K2O·15CaO·10MgO·1ZnO·1MnO (mol %)) in distilled water, an aqueous solution of 2% citric acid and SBF, under static and non-saturated conditions were presented. The leaching tests were performed with glass powder samples (0.3–0.65 mm) at T=37 °C for times up to 720 h. The mass loss of the samples, the changes of pH, the concentration of elements (P, K, Ca, Mg, Zn, and Mn) in solution, and the initial release rates (r0i) and rate of glass hydrolysis (rhi) were determined. The time dependence of the normalized concentration of ions in solution indicates that the dissolution of examined glass, for all investigated environments, occurs in three stages. For shorter times (stage I), the changes of the normalized concentration of ions in solution were linear with time, corresponding to the highest dissolution rates. During stage II, the changes of the normalized concentration of ions in solution with time were smaller due to lower dissolution rates. In stage III, the changes of the normalized concentration of ions in solution were very small and the dissolution rates were more than ten times lower compared to the initial rates. The initial release rat
- Published
- 2021
36. Thermal properties of lithium germanate phosphate glass studied by DTA
- Author
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Topalović, Vladimir, Matijašević, Srđan, Grujić, Snežana, Savić, Veljko, Nikolić, Jelena, Smiljanić, Sonja, Zildžović, Snežana, Topalović, Vladimir, Matijašević, Srđan, Grujić, Snežana, Savić, Veljko, Nikolić, Jelena, Smiljanić, Sonja, and Zildžović, Snežana
- Abstract
The DTA data collected for 22.5Li2O·10Al2O3∙30GeO2∙37.5P2O5 (mol%) glass sample was reported and discussed. The ease of glass formation has been studied. It was determined that the DTA exothermal temperature peaks revealed the crystallization of LiGe2(PO4)3 and GeO2 phases. The activation energy of crystallization and viscous flow was determined. The value of the Avrami exponent and reduced glass transition temperature indicates that the LiGe2(PO4)3 phase has three-dimensional growth.
- Published
- 2021
37. Dissolution of glass made from coal fly ash, glass cullet and calcium carbonate
- Author
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Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Zildžović, Snežana, Grujić, Snežana, Smiljanić, Sonja, Savić, Veljko, Topalović, Vladimir, Nikolić, Jelena, Matijašević, Srđan, Zildžović, Snežana, Grujić, Snežana, and Smiljanić, Sonja
- Abstract
Coal fly ash represents huge ecological problem and its reutilization should be considered. Vitrification of coal fly ash could be one of the solutions. The glass was obtained by melting a mixture of coal fly ash, glass cullet and CaCO3 at T = 1500 oC and quenching the melt in air. The chemical durability of the glass was determined by dissolution test in distilled water, HCl and NaOH at T = 95 0C for t = 2 h. It was shown that dissolution rate of glass in distillated water and NaOH is negligible, while in HCl solution was shown significant mass loss.
- Published
- 2021
38. Effect of sintering temperature on the compressive strength and microstructure of glass foam made from waste materials
- Author
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Savić, Veljko, Matijašević, Srđan, Topalović, Vladimir, Nikolić, Jelena, Smiljanić, Sonja, Zildžović, Snežana, Grujić, Snežana, Savić, Veljko, Matijašević, Srđan, Topalović, Vladimir, Nikolić, Jelena, Smiljanić, Sonja, Zildžović, Snežana, and Grujić, Snežana
- Abstract
Glass foams were produced from a green beer bottle and sugar beet factory lime (SBFL) as the foaming agent. The sintering temperature was in 750-900 oC range. Porosity and compressive strength were determined. Results showed that glass foam sintered at 750 °C has the best compressive strength and even distribution of pores throughout the volume of the sample. The increase of temperature from 800 to 900 °C compressive strength was improved while porosity has slightly dropped. Pores with diameters greater than 1000 µm were formed due to pore agglomeration. Obtained glass foams have properties comparable to commercial ones and could be used for sound and thermal insulation.
- Published
- 2021
39. The Thermophysical Properties of Primary Phase in Lithium Germanium Phosphate Glass
- Author
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Matijašević, Srđan, Topalović, Vladimir, Grujić, Snežana R., Savić, Veljko, Nikolić, Jelena, Labus, Nebojša, Zildžović, Snežana, Matijašević, Srđan, Topalović, Vladimir, Grujić, Snežana R., Savić, Veljko, Nikolić, Jelena, Labus, Nebojša, and Zildžović, Snežana
- Abstract
The selected lithium germanium-phosphate glass was prepared by a conventional melt-quenching technique. The XRD method was employed to confirm the glass was obtained and to reveal crystalline phases during heat treatment. The dilatometry (DIL), differential thermal analysis (DTA), and differential scanning calorimetry (DSC) were used to determine the characteristic temperatures and enthalpies of crystallization and melting of the crystalline phase. The DTA and DIL were used to obtain the viscosity curves by applying the VogelFulcher-Tammann (VFT) equation.
- Published
- 2021
40. Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand
- Author
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Savić, Veljko, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Grujić, Snežana, Zildžović, Snežana, Radulović, Aleksandra, Savić, Veljko, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Grujić, Snežana, Zildžović, Snežana, and Radulović, Aleksandra
- Abstract
In this study, the glass-composite was prepared using glass cullet and waste foundry sand as raw materials. The powder technology route was employed. The mixtures containing 10-50 wt% of the sand were sintered at T = 750 degrees C for t =1h. XRD and DTA analyses were performed. The chemical durability of the resulting glass-composite was determined by leaching test in HCl, H2SO4, NaOH and distilled water at T = 95 degrees C for t =1h. It was shown that the sintering process carried out without the crystallization of the glass matrix. The lowest chemical durability was determined in alkali solution of glasscomposite.
- Published
- 2021
41. Crystal growth of La(2)SrB(10)O(19)from undercooled melt
- Author
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Smiljanić, Sonja, Grujić, Snežana R., Matijašević, Srđan, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, Popović, Daniela Z., Smiljanić, Sonja, Grujić, Snežana R., Matijašević, Srđan, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, and Popović, Daniela Z.
- Abstract
The crystal growth rate of La(2)SrB(10)O(19)in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La(2)SrB(10)O(19)crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 x 10(-8)to 2.77 x 10(-7)m s(-1)in the temperature interval (700-780 degrees C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.
- Published
- 2021
42. Chemical durability of sintered glass-composite prepared from glass cullet and waste foundry sand
- Author
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Savić, Veljko, primary, Topalović, Vladimir, primary, Matijašević, Srđan, primary, Nikolić, Jelena, primary, Grujić, Snežana, primary, Zildžović, Snežana, primary, and Radulović, Aleksandra, primary
- Published
- 2020
- Full Text
- View/download PDF
43. Sintering, crystallization and foaming of La2O3 center dot SrO center dot 5B(2)O(3) glass powders: effect of the holding time
- Author
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Karamanov, Alexander, Smiljanić, Sonja, Karamanova, Emilia, Matijašević, Srđan D., Nikolić, Jelena, Savić, Veljko, and Grujić, Snežana
- Subjects
Sintering ,Structure ,Glass-ceramic - Abstract
Sintering, crystallization and foaming of nano glass powders with composition La2O3 center dot SrO center dot 5B(2)O(3) were studied by hot stage microscopy (HSM) and simultaneous thermal analysis (DTA-TG) under non-isothermal regime at 10 degrees C/min and by optical contactless dilatometer under isothermal conditions at 700 degrees C up to 10 hours for different times. After the thermal treatments, specimens were characterized by gas pycnometry, X-ray Powder Diffraction (XRD) and Field Emission Scanning Electron Microscopes (FE-SEM). The results demonstrate that the densification completed before the crystallization process, thus forming well sintered samples. Then, during the phase formation gas is released, which leads to foaming process. After holding of 160 minutes at 700 degrees C the degree of crystallization reached about 0.8 and the foaming stopped. The obtained sample had high closed porosity and quite intriguing structure composed of two fairly different crystal arrangements. The first was "sponge-like", while the second was denser and consisted of "sheets", 10-30 nm thick. The subsequent holding led to re-crystallization, formation of larger denser zones that reached even 10-15 mu m and an increase in open porosity. These results highlight that in the case of sinter crystallization of nano powders, some intriguing features can be expected.
- Published
- 2020
44. Crystal growth of la(2)srb(10)o(19)from undercooled melt
- Author
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Smiljanić, Sonja, Grujić, Snežana, Matijašević, Srđan D., Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, Popović, Daniela, Smiljanić, Sonja, Grujić, Snežana, Matijašević, Srđan D., Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, and Popović, Daniela
- Abstract
The crystal growth rate of La(2)SrB(10)O(19)in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La(2)SrB(10)O(19)crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 x 10(-8)to 2.77 x 10(-7)m s(-1)in the temperature interval (700-780 degrees C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated.
- Published
- 2020
45. Crystal growth of La2SrB10O19 from undercooled melt.
- Author
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Smiljanić, Sonja V., Grujić, Snežana R., Matijašević, Srđan, Stojanović, Jovica, Nikolić, Jelena, Savić, Veljko, and Popović, Daniela Ž.
- Subjects
CRYSTAL growth ,CRYSTAL models ,CRYSTALLIZATION ,MELTING - Abstract
The crystal growth rate of La
2 SrB10 O19 in an undercooled melt of stoichiometric composition was studied. The crystallization of the bulk samples was performed in a single-stage regime under isothermal conditions at the selected temperatures for the different time periods. The surface crystallization was observed and in all crystallized samples, the La2 SrB10 O19 crystalline phase was identified. Based on the dependence of the crystalline layer thickness on treatment time at selected temperature, crystal growth rate was obtained. The crystal growth rates were from 1.65 × 10−8 to 2.77 × 10−7 m s−1 in the temperature interval (700–780 °C). The experimental values were compared to the calculated values using theoretical model of the crystal growth. The experimental growth rate followed the same trend as the calculated growth rate, but the experimental values were higher than the calculated. [ABSTRACT FROM AUTHOR]- Published
- 2021
- Full Text
- View/download PDF
46. Accounting evaluation of cash flows in the enterprise Valamar Riviera d.d. Poreč
- Author
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Savić, Veljko and Peruško, Ticijan
- Subjects
expenses ,SOCIAL SCIENCES. Economics. Accounting ,analiza financijskih izvještaja ,money ,izdaci ,izvještaj o novčanom toku ,receipts ,cash flow statement ,DRUŠTVENE ZNANOSTI. Ekonomija. Računovodstvo ,novac ,primici ,analysis of financial statements - Abstract
Jedan od najvažnijih čimbenika poslovanja u današnjem poslovnom svijetu je novac. Sposobnost poduzeća da stvara dovoljne količine novca znači da će ono uredno podmirivati obaveze, a eventualni viškovi novca omogućuju poduzeću investiranje i razvoj. Sve navedeno je preduvjet opstanka i dugoročne perspektive poduzeća na tržištu. Izviještaj o novčanim tokovima je onaj koji svim zainteresiranim unutarnjim i vanjskim dionicima pruža informacije o izvorima pribavljanja novca te načinu trošenja prikupljenih sredstava. Cilj ovog rada je teoretski pojasniti knjiženje novčanih tokova te ih prikazati na primjeru odabranog poduzeća. Rezultati istraživanja pokazuju uspješno poslovanje poduzeća. One of the most important business factors in today's business is money. The ability of a company to generate sufficient amounts of money means that a company will properly settle its obligations, possible surpluses of money will enable the company to invest and develop, all of which is a prerequisite for survival and a long-term business perspective on the market. The Statement of Cash Flow is a report that provides information to all stakeholders interested in internal and external information on the sources of money and how the funds are spent. The aim of this paper is to clarify the theoretical outline of cash flows and to present them on an example of a selected company. Research results show the successful business of the company.
- Published
- 2018
47. Characterization of different bioactive phosphate glasses
- Author
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Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Đošić, Marija, Savić, Veljko, Smiljanić, Sonja, Grujić, Snežana, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Đošić, Marija, Savić, Veljko, Smiljanić, Sonja, and Grujić, Snežana
- Published
- 2019
48. Characterization of lanthanum-doped phosphate glass
- Author
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Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Đošić, Marija, Savić, Veljko, Smiljanić, Sonja, Grujić, Snežana, Topalović, Vladimir, Matijašević, Srđan, Nikolić, Jelena, Đošić, Marija, Savić, Veljko, Smiljanić, Sonja, and Grujić, Snežana
- Published
- 2019
49. The Crystallization of Glass Samples from the System P2O5-CaO-SrO-Na2O-TiO2
- Author
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Topalović, Vladimir, Matijašević, Srđan, Đošić, Marija, Nikolić, Jelena, Savić, Veljko, Smiljanić, Sonja, Grujić, Snežana, Topalović, Vladimir, Matijašević, Srđan, Đošić, Marija, Nikolić, Jelena, Savić, Veljko, Smiljanić, Sonja, and Grujić, Snežana
- Published
- 2019
50. Polyphosphate glass as fertilizer for plant seedlings
- Author
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Vujošević, Ana, Matijašević, Srđan D., Smiljanić, Sonja, Nikolić, Jelena, Zečević, Bogoljub, Topalović, Vladimir, Savić, Veljko, Vujošević, Ana, Matijašević, Srđan D., Smiljanić, Sonja, Nikolić, Jelena, Zečević, Bogoljub, Topalović, Vladimir, and Savić, Veljko
- Abstract
Due to the dissolution properties the phosphate glasses can be promising materials for the development of new ecologically safe fertilizers. The complex polyphosphate glass with a molar ratio (M2O + MO)/P2O5 gt 1 and addition of microelements Zn2+, Mn2+, Fe3+ and Cu2+ were used in substrate for production of flower and vegetables seedlings. Dissolution tests were conducted in deionized water and 2% citric acid. The effects of the reaction time on the normalized glass mass loss (fm) and the normalized concentrations of the ions (fi) at 20, 30, 37 and 50°C were determined. Dissolution rate constants (kw - deionized water, kc -2% citric acid) were also determined (kw-0.0028-0.0094 gm-2, kc-0.029-0.011 gm-2). Values of kc were higher than those of kw, which confirms a significant effect of solvent type and temperature on the dissolution kinetics of glass. The experiments with plants (one vegetable and one flower) showed that the addition of phosphate glass caused an increase in yield and quality of plants. The applied dose of polyphosphate glass of 1gl-1 showed the best effect on the growth of the examined plant seedlings., Polifosfatno staklo, u kome je molski odnos (M2O + MO)/P2O5 gt 1, koje sadrži i mikroelemente Zn2+, Mn2+, Fe3+ i Cu2+, korišćeno je u supstratu za proizvodnju rasada cveća i povrća. Eksperimenti su izvedeni u stakleniku na Poljoprivrednom fakultetu u Beogradu i u laboratorijama ITNMS. Ispitivano je ponašanje polifosfatnog stakla prilikom rastvaranja u dejonizovanoj vodi i 2% rastvoru limunske kiseline na temperaturama od 20, 30, 37 i 50 °C. Ispitan je uticaj vremena rastvaranja na normalizovani gubitak mase (fm) i normalizovane koncentracije jona (fi). Određene su i konstante brzina rastvaranja(kw-dejonizovana voda, kc -2% rastvor limunske kiseline). Vrednosti kc su veće od vrednosti za kw, što potvrđuje uticaj rastvarača i temperature na proces rastvaranja. Rezultati su pokazali pozitivan efekat polifosfatnog stakla na rast i kvalitet ispitivanih biljaka. Primenjena doza polifosfatnog stakla od 1 gl-1 pokazala je najbolji efekat na rast ispitivanih biljaka-rasada.
- Published
- 2019
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