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Since their advent over 2 decades ago, autonomous Argo floats have revolutionized the field of oceanography, and, more recently, the addition of biogeochemical and biological sensors to these floats has greatly improved our understanding of carbon, nutrient, and oxygen cycling in the ocean. While Argo floats offer unprecedented horizontal, vertical, and temporal coverage of the global ocean, uncertainties remain about whether Argo sampling frequency and density capture the true spatiotemporal variability in physical, biogeochemical, and biological properties. As the true distributions of, e.g., temperature or oxygen are unknown, these uncertainties remain difficult to address with Argo floats alone. Numerical models with synthetic observing systems offer one potential avenue to address these uncertainties. Here, we implement synthetic biogeochemical Argo floats into the Energy Exascale Earth System Model version 2 (E3SMv2), which build on the Lagrangian In Situ Global High-Performance Particle Tracking (LIGHT) module in E3SMv2 (E3SMv2-LIGHT-bgcArgo-1.0). Since the synthetic floats sample the model fields at model run time, the end user defines the sampling protocol ahead of any model simulation, including the number and distribution of synthetic floats to be deployed, their sampling frequency, and the prognostic or diagnostic model fields to be sampled. Using a 6-year proof-of-concept simulation, we illustrate the utility of the synthetic floats in different case studies. In particular, we quantify the impact of (i) sampling density on the float-derived detection of deep-ocean change in temperature or oxygen and on float-derived estimates of phytoplankton phenology, (ii) sampling frequency and sea-ice cover on float trajectory lengths and hence float-derived estimates of current velocities, and (iii) short-term variability in ecosystem stressors on estimates of their seasonal variability.

The Southern Ocean modulates the climate system by exchanging heat and carbon dioxide (CO2) between the atmosphere and deep ocean. While this region plays an outsized role in the global oceanic anthropogenic carbon uptake, CO2 is also released to the atmosphere across large swaths of the Antarctic Circumpolar Current (ACC). Southern Ocean outgassing has long been attributed to remineralized carbon from upwelled deep water, but the precise mechanisms by which this water reaches the surface are not well constrained from observations. Using data from a novel array of autonomous biogeochemical profiling floats, we examine Southern Ocean air–sea CO2 fluxes and the pathways that transfer carbon from the ocean interior into the mixed layer where air–sea exchange occurs. These float-based flux estimates of unprecedented spatial resolution indicate that carbon outgassing occurs predominantly in the Indo-Pacific sector of the ACC due to variations in the mean surface ocean partial pressure of CO2 (pCO2). We show that this zonal asymmetry in surface pCO2, and consequently air–sea carbon fluxes, stems primarily from regional variability in the mixed-layer entrainment of upwelled carbon-rich deep water. These results suggest that a sustained circumpolar observing system is crucial to monitor future changes in oceanic carbon release and uptake.