1. Investigation of electron-induced cross-linking of self-assembled monolayers by scanning tunneling microscopy
- Author
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Patrick Stohmann, Sascha Koch, Yang Yang, Christopher David Kaiser, Julian Ehrens, Jürgen Schnack, Niklas Biere, Dario Anselmetti, Armin Gölzhäuser, and Xianghui Zhang
- Subjects
carbon nanomembranes ,electron-induced cross-linking ,scanning tunneling microscopy ,self-assembled monolayers ,subnanometer pores ,Technology ,Chemical technology ,TP1-1185 ,Science ,Physics ,QC1-999 - Abstract
Ultrathin membranes with subnanometer pores enabling molecular size-selective separation were generated on surfaces via electron-induced cross-linking of self-assembled monolayers (SAMs). The evolution of p-terphenylthiol (TPT) SAMs on Au(111) surfaces into cross-linked monolayers was observed with a scanning tunneling microscope. As the irradiation dose was increased, the cross-linked regions continued to grow and a large number of subnanometer voids appeared. Their equivalent diameter is 0.5 ± 0.2 nm and the areal density is ≈1.7 × 1017 m−2. Supported by classical molecular dynamics simulations, we propose that these voids may correspond to free volumes inside a cross-linked monolayer.
- Published
- 2022
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